#------------------------------------------------------------------------------
#$Date: 2016-02-20 22:30:07 +0200 (Sat, 20 Feb 2016) $
#$Revision: 176789 $
#$URL: svn://www.crystallography.net/cod/cif/2/22/83/2228399.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_2228399
loop_
_publ_author_name
'Tian, Da-Min'
'Shi, Chong-Yu'
_publ_section_title
;
 [μ-1,3-Bis(3,5-dimethyl-1H-pyrazol-1-yl-κN²)propan-2-olato-κ²O:O]bis[(ethanol-κO)zinc(II)]
 bis(perchlorate)
;
_journal_coeditor_code           HY2370
_journal_issue                   12
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m1520
_journal_paper_doi               10.1107/S160053681004479X
_journal_volume                  66
_journal_year                    2010
_chemical_formula_iupac          '[Zn2 (C13 H19 N4 O)2 (C2 H6 O)2] (Cl O4)2'
_chemical_formula_moiety         'C30 H50 N8 O4 Zn2 2+, 2(Cl O4 -)'
_chemical_formula_sum            'C30 H50 Cl2 N8 O12 Zn2'
_chemical_formula_weight         916.42
_chemical_name_systematic
;
[μ-1,3-Bis(3,5-dimethyl-1H-pyrazol-1-yl-κN²)propan-
2-olato-κ²O:O]bis[(ethanol-κO)zinc(II)]
bis(perchlorate)
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL97
_cell_angle_alpha                111.13(3)
_cell_angle_beta                 100.40(3)
_cell_angle_gamma                100.11(3)
_cell_formula_units_Z            1
_cell_length_a                   8.8570(18)
_cell_length_b                   11.148(2)
_cell_length_c                   11.300(2)
_cell_measurement_reflns_used    2230
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      25.74
_cell_measurement_theta_min      2.29
_cell_volume                     987.8(5)
_computing_cell_refinement       'SAINT (Bruker, 2007)'
_computing_data_collection       'SMART (Bruker, 2007)'
_computing_data_reduction        'SAINT (Bruker, 2007)'
_computing_molecular_graphics
;
SHELXTL (Sheldrick, 2008) and DIAMOND (Brandenburg, 1999)
;
_computing_publication_material  'SHELXTL (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'Bruker APEX CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0169
_diffrn_reflns_av_sigmaI/netI    0.0212
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_number            7788
_diffrn_reflns_theta_full        25.01
_diffrn_reflns_theta_max         25.01
_diffrn_reflns_theta_min         3.27
_exptl_absorpt_coefficient_mu    1.417
_exptl_absorpt_correction_T_max  0.7647
_exptl_absorpt_correction_T_min  0.7647
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Sheldrick, 1996)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.541
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             476
_exptl_crystal_size_max          0.22
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.20
_refine_diff_density_max         0.504
_refine_diff_density_min         -0.222
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.066
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     249
_refine_ls_number_reflns         3482
_refine_ls_number_restraints     2
_refine_ls_restrained_S_all      1.066
_refine_ls_R_factor_all          0.0332
_refine_ls_R_factor_gt           0.0299
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w = 1/[σ²(Fo²)+(0.0486P)²+0.4173P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0812
_refine_ls_wR_factor_ref         0.0830
_reflns_number_gt                3172
_reflns_number_total             3482
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            hy2370.cif
_cod_data_source_block           I
_cod_database_code               2228399
_cod_database_fobs_code          2228399
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Zn Zn1 0.44360(3) -0.13668(2) 0.00434(2) 0.03250(11) Uani d . 1 . .
N N1 0.3373(2) -0.18995(19) 0.13387(19) 0.0385(4) Uani d . 1 . .
N N2 0.3198(2) -0.09350(19) 0.24246(19) 0.0364(4) Uani d . 1 . .
O O6 0.40890(17) 0.04471(14) 0.07488(15) 0.0331(3) Uani d . 1 . .
O O7 0.6260(2) -0.21497(19) 0.07459(19) 0.0528(5) Uani d D 1 . .
H H7A 0.6208 -0.2359 0.1393 0.079 Uiso d RD 1 . .
C C5 0.2447(4) -0.4353(3) 0.0179(3) 0.0597(7) Uani d . 1 . .
H H5A 0.2756 -0.4202 -0.0538 0.089 Uiso calc R 1 . .
H H5B 0.1397 -0.4941 -0.0135 0.089 Uiso calc R 1 . .
H H5C 0.3182 -0.4748 0.0544 0.089 Uiso calc R 1 . .
C C6 0.2460(3) -0.3054(2) 0.1218(2) 0.0413(5) Uani d . 1 . .
C C7 0.1694(3) -0.2813(3) 0.2213(3) 0.0453(6) Uani d . 1 . .
H H7 0.0970 -0.3442 0.2334 0.054 Uiso calc R 1 . .
C C8 0.2202(3) -0.1478(3) 0.2983(2) 0.0413(5) Uani d . 1 . .
C C9 0.1855(4) -0.0683(3) 0.4239(3) 0.0606(8) Uani d . 1 . .
H H9A 0.2773 -0.0431 0.4961 0.091 Uiso calc R 1 . .
H H9B 0.0971 -0.1210 0.4368 0.091 Uiso calc R 1 . .
H H9C 0.1599 0.0104 0.4193 0.091 Uiso calc R 1 . .
C C10 0.4166(3) 0.0433(2) 0.2899(2) 0.0381(5) Uani d . 1 . .
H H10A 0.5279 0.0435 0.3030 0.046 Uiso calc R 1 . .
H H10B 0.4016 0.0957 0.3743 0.046 Uiso calc R 1 . .
C C11 0.3753(3) 0.1084(2) 0.1951(2) 0.0331(5) Uani d . 1 . .
H H11 0.2605 0.0997 0.1770 0.040 Uiso calc R 1 . .
C C13 0.7924(3) -0.1751(4) 0.0899(3) 0.0641(8) Uani d . 1 . .
H H13A 0.8108 -0.1760 0.0076 0.077 Uiso calc R 1 . .
H H13B 0.8423 -0.2383 0.1110 0.077 Uiso calc R 1 . .
C C14 0.8653(5) -0.0412(4) 0.1945(6) 0.1128(18) Uani d . 1 . .
H H14A 0.8059 0.0190 0.1808 0.169 Uiso calc R 1 . .
H H14B 0.9729 -0.0113 0.1926 0.169 Uiso calc R 1 . .
H H14C 0.8647 -0.0439 0.2783 0.169 Uiso calc R 1 . .
C C12 0.4601(3) 0.2576(2) 0.2567(2) 0.0367(5) Uani d . 1 . .
H H12A 0.4222 0.2976 0.1977 0.044 Uiso calc R 1 . .
H H12B 0.4328 0.2998 0.3385 0.044 Uiso calc R 1 . .
N N3 0.7009(2) 0.25422(18) 0.17989(19) 0.0366(4) Uani d . 1 . .
N N4 0.6328(2) 0.28347(18) 0.28297(18) 0.0359(4) Uani d . 1 . .
C C1 0.7043(4) 0.3867(3) 0.5278(3) 0.0630(8) Uani d . 1 . .
H H1A 0.6439 0.4506 0.5295 0.094 Uiso calc R 1 . .
H H1B 0.8007 0.4283 0.5977 0.094 Uiso calc R 1 . .
H H1C 0.6428 0.3136 0.5389 0.094 Uiso calc R 1 . .
C C2 0.7442(3) 0.3366(2) 0.3990(2) 0.0437(6) Uani d . 1 . .
C C3 0.8885(3) 0.3381(3) 0.3704(3) 0.0501(6) Uani d . 1 . .
H H3 0.9877 0.3674 0.4306 0.060 Uiso calc R 1 . .
C C15 0.9736(3) 0.2689(3) 0.1524(3) 0.0614(8) Uani d . 1 . .
H H15A 0.9241 0.1944 0.0696 0.092 Uiso calc R 1 . .
H H15B 1.0653 0.2525 0.1974 0.092 Uiso calc R 1 . .
H H15C 1.0055 0.3479 0.1373 0.092 Uiso calc R 1 . .
C C4 0.8579(3) 0.2875(2) 0.2346(3) 0.0433(6) Uani d . 1 . .
O O1 0.7169(4) -0.2927(3) 0.4897(3) 0.1003(9) Uani d . 1 . .
O O2 0.5741(4) -0.4532(3) 0.2842(4) 0.1233(12) Uani d . 1 . .
O O3 0.6271(4) -0.2330(3) 0.3209(3) 0.0955(9) Uani d . 1 . .
O O4 0.8318(4) -0.3383(4) 0.3177(3) 0.1242(12) Uani d . 1 . .
Cl Cl1 0.68858(8) -0.33052(6) 0.35237(7) 0.05214(18) Uani d . 1 . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
_geom_angle_publ_flag
O6 Zn1 N3 . 2_655 112.71(8) ?
O6 Zn1 O6 . 2_655 80.52(7) ?
N3 Zn1 O6 2_655 2_655 89.87(7) ?
O6 Zn1 N1 . . 91.69(7) ?
N3 Zn1 N1 2_655 . 106.21(8) ?
O6 Zn1 N1 2_655 . 163.86(7) ?
O6 Zn1 O7 . . 130.72(8) ?
N3 Zn1 O7 2_655 . 115.77(8) ?
O6 Zn1 O7 2_655 . 91.14(7) ?
N1 Zn1 O7 . . 83.23(8) ?
O6 Zn1 Zn1 . 2_655 40.88(4) ?
N3 Zn1 Zn1 2_655 2_655 104.37(6) ?
O6 Zn1 Zn1 2_655 2_655 39.63(4) ?
N1 Zn1 Zn1 . 2_655 131.04(6) ?
O7 Zn1 Zn1 . 2_655 115.79(6) ?
C6 N1 N2 . . 106.23(19) ?
C6 N1 Zn1 . . 132.19(16) ?
N2 N1 Zn1 . . 119.85(14) ?
C8 N2 N1 . . 110.49(19) ?
C8 N2 C10 . . 129.5(2) ?
N1 N2 C10 . . 119.68(18) ?
C11 O6 Zn1 . . 126.98(13) ?
C11 O6 Zn1 . 2_655 124.67(13) ?
Zn1 O6 Zn1 . 2_655 99.48(7) ?
C13 O7 Zn1 . . 128.78(17) ?
C13 O7 H7A . . 103.2 ?
Zn1 O7 H7A . . 118.4 ?
C6 C5 H5A . . 109.5 ?
C6 C5 H5B . . 109.5 ?
H5A C5 H5B . . 109.5 ?
C6 C5 H5C . . 109.5 ?
H5A C5 H5C . . 109.5 ?
H5B C5 H5C . . 109.5 ?
N1 C6 C7 . . 109.4(2) ?
N1 C6 C5 . . 121.1(2) ?
C7 C6 C5 . . 129.4(2) ?
C8 C7 C6 . . 107.2(2) ?
C8 C7 H7 . . 126.4 ?
C6 C7 H7 . . 126.4 ?
N2 C8 C7 . . 106.7(2) ?
N2 C8 C9 . . 123.0(2) ?
C7 C8 C9 . . 130.2(2) ?
C8 C9 H9A . . 109.5 ?
C8 C9 H9B . . 109.5 ?
H9A C9 H9B . . 109.5 ?
C8 C9 H9C . . 109.5 ?
H9A C9 H9C . . 109.5 ?
H9B C9 H9C . . 109.5 ?
N2 C10 C11 . . 112.67(19) ?
N2 C10 H10A . . 109.1 ?
C11 C10 H10A . . 109.1 ?
N2 C10 H10B . . 109.1 ?
C11 C10 H10B . . 109.1 ?
H10A C10 H10B . . 107.8 ?
O6 C11 C10 . . 111.91(18) ?
O6 C11 C12 . . 110.58(18) ?
C10 C11 C12 . . 111.32(19) ?
O6 C11 H11 . . 107.6 ?
C10 C11 H11 . . 107.6 ?
C12 C11 H11 . . 107.6 ?
O7 C13 C14 . . 111.5(3) ?
O7 C13 H13A . . 109.3 ?
C14 C13 H13A . . 109.3 ?
O7 C13 H13B . . 109.3 ?
C14 C13 H13B . . 109.3 ?
H13A C13 H13B . . 108.0 ?
C13 C14 H14A . . 109.5 ?
C13 C14 H14B . . 109.5 ?
H14A C14 H14B . . 109.5 ?
C13 C14 H14C . . 109.5 ?
H14A C14 H14C . . 109.5 ?
H14B C14 H14C . . 109.5 ?
N4 C12 C11 . . 112.81(18) ?
N4 C12 H12A . . 109.0 ?
C11 C12 H12A . . 109.0 ?
N4 C12 H12B . . 109.0 ?
C11 C12 H12B . . 109.0 ?
H12A C12 H12B . . 107.8 ?
C4 N3 N4 . . 105.54(19) ?
C4 N3 Zn1 . 2_655 134.36(17) ?
N4 N3 Zn1 . 2_655 117.88(14) ?
C2 N4 N3 . . 111.10(19) ?
C2 N4 C12 . . 129.4(2) ?
N3 N4 C12 . . 119.52(18) ?
C2 C1 H1A . . 109.5 ?
C2 C1 H1B . . 109.5 ?
H1A C1 H1B . . 109.5 ?
C2 C1 H1C . . 109.5 ?
H1A C1 H1C . . 109.5 ?
H1B C1 H1C . . 109.5 ?
N4 C2 C3 . . 106.6(2) ?
N4 C2 C1 . . 122.5(2) ?
C3 C2 C1 . . 130.8(2) ?
C2 C3 C4 . . 106.8(2) ?
C2 C3 H3 . . 126.6 ?
C4 C3 H3 . . 126.6 ?
C4 C15 H15A . . 109.5 ?
C4 C15 H15B . . 109.5 ?
H15A C15 H15B . . 109.5 ?
C4 C15 H15C . . 109.5 ?
H15A C15 H15C . . 109.5 ?
H15B C15 H15C . . 109.5 ?
N3 C4 C3 . . 109.9(2) ?
N3 C4 C15 . . 121.5(2) ?
C3 C4 C15 . . 128.6(2) ?
O2 Cl1 O4 . . 110.6(2) ?
O2 Cl1 O1 . . 110.3(2) ?
O4 Cl1 O1 . . 109.0(2) ?
O2 Cl1 O3 . . 107.9(2) ?
O4 Cl1 O3 . . 110.9(2) ?
O1 Cl1 O3 . . 108.07(18) ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
Zn1 N1 . 2.076(2) y
Zn1 N3 2_655 2.042(2) y
Zn1 O6 . 1.9908(16) y
Zn1 O6 2_655 2.0428(16) y
Zn1 O7 . 2.1292(18) y
Zn1 Zn1 2_655 3.0784(9) ?
N1 C6 . 1.340(3) ?
N1 N2 . 1.364(3) ?
N2 C8 . 1.353(3) ?
N2 C10 . 1.461(3) ?
O6 C11 . 1.401(3) ?
O6 Zn1 2_655 2.0428(16) ?
O7 C13 . 1.422(3) ?
O7 H7A . 0.8500 ?
C5 C6 . 1.496(4) ?
C5 H5A . 0.9600 ?
C5 H5B . 0.9600 ?
C5 H5C . 0.9600 ?
C6 C7 . 1.385(4) ?
C7 C8 . 1.366(4) ?
C7 H7 . 0.9300 ?
C8 C9 . 1.497(4) ?
C9 H9A . 0.9600 ?
C9 H9B . 0.9600 ?
C9 H9C . 0.9600 ?
C10 C11 . 1.522(3) ?
C10 H10A . 0.9700 ?
C10 H10B . 0.9700 ?
C11 C12 . 1.534(3) ?
C11 H11 . 0.9800 ?
C13 C14 . 1.468(6) ?
C13 H13A . 0.9700 ?
C13 H13B . 0.9700 ?
C14 H14A . 0.9600 ?
C14 H14B . 0.9600 ?
C14 H14C . 0.9600 ?
C12 N4 . 1.460(3) ?
C12 H12A . 0.9700 ?
C12 H12B . 0.9700 ?
N3 C4 . 1.341(3) ?
N3 N4 . 1.370(3) ?
N3 Zn1 2_655 2.042(2) ?
N4 C2 . 1.346(3) ?
C1 C2 . 1.491(4) ?
C1 H1A . 0.9600 ?
C1 H1B . 0.9600 ?
C1 H1C . 0.9600 ?
C2 C3 . 1.372(4) ?
C3 C4 . 1.385(4) ?
C3 H3 . 0.9300 ?
C15 C4 . 1.495(4) ?
C15 H15A . 0.9600 ?
C15 H15B . 0.9600 ?
C15 H15C . 0.9600 ?
O1 Cl1 . 1.414(3) ?
O2 Cl1 . 1.401(3) ?
O3 Cl1 . 1.422(3) ?
O4 Cl1 . 1.402(3) ?
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_site_symmetry_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_publ_flag
O7 H7A O3 . 0.85 2.03 2.860(3) 165 y
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion
_geom_torsion_publ_flag
O6 Zn1 N1 C6 . . . . 144.8(2) ?
N3 Zn1 N1 C6 2_655 . . . 30.5(2) ?
O6 Zn1 N1 C6 2_655 . . . -154.6(2) ?
O7 Zn1 N1 C6 . . . . -84.4(2) ?
Zn1 Zn1 N1 C6 2_655 . . . 157.08(19) ?
O6 Zn1 N1 N2 . . . . -18.00(17) ?
N3 Zn1 N1 N2 2_655 . . . -132.25(17) ?
O6 Zn1 N1 N2 2_655 . . . 42.6(3) ?
O7 Zn1 N1 N2 . . . . 112.83(18) ?
Zn1 Zn1 N1 N2 2_655 . . . -5.7(2) ?
C6 N1 N2 C8 . . . . 0.5(3) ?
Zn1 N1 N2 C8 . . . . 167.30(16) ?
C6 N1 N2 C10 . . . . 174.2(2) ?
Zn1 N1 N2 C10 . . . . -19.0(3) ?
N3 Zn1 O6 C11 2_655 . . . 126.18(16) ?
O6 Zn1 O6 C11 2_655 . . . -147.97(19) ?
N1 Zn1 O6 C11 . . . . 17.82(17) ?
O7 Zn1 O6 C11 . . . . -64.70(18) ?
Zn1 Zn1 O6 C11 2_655 . . . -147.97(19) ?
N3 Zn1 O6 Zn1 2_655 . . 2_655 -85.85(8) ?
O6 Zn1 O6 Zn1 2_655 . . 2_655 0.0 ?
N1 Zn1 O6 Zn1 . . . 2_655 165.79(8) ?
O7 Zn1 O6 Zn1 . . . 2_655 83.27(10) ?
O6 Zn1 O7 C13 . . . . -62.0(3) ?
N3 Zn1 O7 C13 2_655 . . . 106.8(2) ?
O6 Zn1 O7 C13 2_655 . . . 16.4(2) ?
N1 Zn1 O7 C13 . . . . -148.4(2) ?
Zn1 Zn1 O7 C13 2_655 . . . -15.8(2) ?
N2 N1 C6 C7 . . . . 1.0(3) ?
Zn1 N1 C6 C7 . . . . -163.53(18) ?
N2 N1 C6 C5 . . . . -175.6(2) ?
Zn1 N1 C6 C5 . . . . 20.0(4) ?
N1 C6 C7 C8 . . . . -2.0(3) ?
C5 C6 C7 C8 . . . . 174.1(3) ?
N1 N2 C8 C7 . . . . -1.8(3) ?
C10 N2 C8 C7 . . . . -174.6(2) ?
N1 N2 C8 C9 . . . . 176.0(2) ?
C10 N2 C8 C9 . . . . 3.1(4) ?
C6 C7 C8 N2 . . . . 2.3(3) ?
C6 C7 C8 C9 . . . . -175.3(3) ?
C8 N2 C10 C11 . . . . -120.3(3) ?
N1 N2 C10 C11 . . . . 67.4(3) ?
Zn1 O6 C11 C10 . . . . 17.7(2) ?
Zn1 O6 C11 C10 2_655 . . . -122.81(16) ?
Zn1 O6 C11 C12 . . . . 142.41(15) ?
Zn1 O6 C11 C12 2_655 . . . 1.9(2) ?
N2 C10 C11 O6 . . . . -64.4(2) ?
N2 C10 C11 C12 . . . . 171.27(17) ?
Zn1 O7 C13 C14 . . . . 67.8(4) ?
O6 C11 C12 N4 . . . . -60.2(2) ?
C10 C11 C12 N4 . . . . 64.9(2) ?
C4 N3 N4 C2 . . . . 1.5(2) ?
Zn1 N3 N4 C2 2_655 . . . 166.94(15) ?
C4 N3 N4 C12 . . . . -179.55(19) ?
Zn1 N3 N4 C12 2_655 . . . -14.1(2) ?
C11 C12 N4 C2 . . . . -111.0(3) ?
C11 C12 N4 N3 . . . . 70.2(3) ?
N3 N4 C2 C3 . . . . -1.9(3) ?
C12 N4 C2 C3 . . . . 179.3(2) ?
N3 N4 C2 C1 . . . . 175.6(2) ?
C12 N4 C2 C1 . . . . -3.3(4) ?
N4 C2 C3 C4 . . . . 1.5(3) ?
C1 C2 C3 C4 . . . . -175.6(3) ?
N4 N3 C4 C3 . . . . -0.5(3) ?
Zn1 N3 C4 C3 2_655 . . . -162.39(18) ?
N4 N3 C4 C15 . . . . 179.5(2) ?
Zn1 N3 C4 C15 2_655 . . . 17.6(4) ?
C2 C3 C4 N3 . . . . -0.7(3) ?
C2 C3 C4 C15 . . . . 179.4(3) ?
