#------------------------------------------------------------------------------
#$Date: 2016-02-21 02:03:34 +0200 (Sun, 21 Feb 2016) $
#$Revision: 176798 $
#$URL: svn://www.crystallography.net/cod/cif/2/23/02/2230242.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2230242
loop_
_publ_author_name
'Keng, Thy Chun'
'Lo, Kong Mun'
'Ng, Seik Weng'
_publ_section_title
;
 Chloridobis(2-chlorobenzyl)(quinolin-8-olato-κ²N,O)tin(IV)
;
_journal_coeditor_code           BT5528
_journal_issue                   6
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m663
_journal_paper_doi               10.1107/S160053681101573X
_journal_volume                  67
_journal_year                    2011
_chemical_formula_iupac          '[Sn (C7 H6 Cl)2 (C9 H6 N O) Cl]'
_chemical_formula_moiety         'C23 H18 Cl3 N O Sn'
_chemical_formula_sum            'C23 H18 Cl3 N O Sn'
_chemical_formula_weight         549.42
_chemical_name_systematic
;
Chloridobis(2-chlorobenzyl)(quinolin-8-olato-κ²N,O)tin(IV)
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 100.3433(6)
_cell_angle_gamma                90.00
_cell_formula_units_Z            12
_cell_length_a                   10.25040(10)
_cell_length_b                   41.2573(6)
_cell_length_c                   15.3882(2)
_cell_measurement_reflns_used    9252
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      28.33
_cell_measurement_theta_min      2.39
_cell_volume                     6401.98(14)
_computing_cell_refinement       'SAINT (Bruker, 2009)'
_computing_data_collection       'APEX2 (Bruker, 2009)'
_computing_data_reduction        'SAINT (Bruker, 2009)'
_computing_molecular_graphics    'X-SEED (Barbour, 2001)'
_computing_publication_material  'publCIF (Westrip, 2010)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.993
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device_type  'Bruker SMART APEX'
_diffrn_measurement_method       ω
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0242
_diffrn_reflns_av_sigmaI/netI    0.0293
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       40
_diffrn_reflns_limit_k_min       -53
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            41105
_diffrn_reflns_theta_full        27.50
_diffrn_reflns_theta_max         27.50
_diffrn_reflns_theta_min         0.99
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.588
_exptl_absorpt_correction_T_max  0.7966
_exptl_absorpt_correction_T_min  0.6923
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Sheldrick, 1996)'
_exptl_crystal_colour            Colorless
_exptl_crystal_density_diffrn    1.710
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Block
_exptl_crystal_F_000             3264
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.15
_refine_diff_density_max         1.273
_refine_diff_density_min         -1.416
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.107
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     784
_refine_ls_number_reflns         14589
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.107
_refine_ls_R_factor_all          0.0430
_refine_ls_R_factor_gt           0.0370
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0318P)²+14.3485P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0832
_refine_ls_wR_factor_ref         0.0856
_reflns_number_gt                13128
_reflns_number_total             14589
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            bt5528.cif
_cod_data_source_block           I
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               2230242
_cod_database_fobs_code          2230242
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_disorder_assembly
_atom_site_disorder_group
Sn Sn1 0.51891(2) 0.342454(5) 0.664659(14) 0.01383(5) Uani d . 1 1 . .
Sn Sn2 0.51124(2) 0.325014(5) 0.306586(14) 0.01375(5) Uani d . 1 1 . .
Sn Sn3 0.49861(2) 0.005273(5) 0.701013(14) 0.01335(5) Uani d . 1 1 . .
Cl Cl1 0.35889(8) 0.30078(2) 0.60004(6) 0.02297(17) Uani d . 1 1 . .
Cl Cl2 0.28721(9) 0.35808(3) 0.86345(6) 0.0307(2) Uani d . 1 1 . .
Cl Cl3 0.37714(9) 0.41474(2) 0.73481(6) 0.02583(18) Uani d . 1 1 . .
Cl Cl4 0.66348(8) 0.36906(2) 0.36650(6) 0.02405(18) Uani d . 1 1 . .
Cl Cl5 0.65041(10) 0.24788(2) 0.24180(6) 0.0301(2) Uani d . 1 1 . .
Cl Cl6 0.76770(9) 0.31831(2) 0.15379(6) 0.02775(19) Uani d . 1 1 . .
Cl Cl7 0.33400(8) -0.036560(19) 0.64966(6) 0.02048(16) Uani d . 1 1 . .
Cl Cl8 0.38458(10) 0.09956(2) 0.74145(6) 0.0296(2) Uani d . 1 1 . .
Cl Cl9 0.26222(8) 0.02390(2) 0.83358(5) 0.02545(18) Uani d . 1 1 . .
O O1 0.6547(2) 0.31709(5) 0.60960(14) 0.0158(4) Uani d . 1 1 . .
O O2 0.3754(2) 0.34906(5) 0.36442(14) 0.0160(4) Uani d . 1 1 . .
O O3 0.6230(2) -0.01859(5) 0.63342(15) 0.0172(5) Uani d . 1 1 . .
N N1 0.7171(3) 0.37103(6) 0.70561(17) 0.0152(5) Uani d . 1 1 . .
N N2 0.3191(3) 0.29384(6) 0.27310(17) 0.0149(5) Uani d . 1 1 . .
N N3 0.6961(3) 0.03576(6) 0.72578(17) 0.0155(5) Uani d . 1 1 . .
C C1 0.5196(4) 0.32487(8) 0.7971(2) 0.0228(7) Uani d . 1 1 . .
H H1A 0.4312 0.3154 0.7984 0.027 Uiso calc R 1 1 . .
H H1B 0.5847 0.3070 0.8083 0.027 Uiso calc R 1 1 . .
C C2 0.5502(3) 0.34804(8) 0.8716(2) 0.0181(7) Uani d . 1 1 . .
C C3 0.6818(4) 0.35385(10) 0.9111(3) 0.0296(8) Uani d . 1 1 . .
H H3 0.7503 0.3422 0.8907 0.036 Uiso calc R 1 1 . .
C C4 0.7155(4) 0.37575(11) 0.9782(3) 0.0390(11) Uani d . 1 1 . .
H H4 0.8062 0.3792 1.0030 0.047 Uiso calc R 1 1 . .
C C5 0.6192(5) 0.39269(10) 1.0095(2) 0.0403(12) Uani d . 1 1 . .
H H5 0.6430 0.4080 1.0557 0.048 Uiso calc R 1 1 . .
C C6 0.4858(5) 0.38745(9) 0.9736(2) 0.0321(9) Uani d . 1 1 . .
H H6 0.4180 0.3989 0.9955 0.039 Uiso calc R 1 1 . .
C C7 0.4539(3) 0.36523(8) 0.9056(2) 0.0197(7) Uani d . 1 1 . .
C C8 0.4283(3) 0.37879(8) 0.5727(2) 0.0195(7) Uani d . 1 1 . .
H H8A 0.4374 0.3717 0.5126 0.023 Uiso calc R 1 1 . .
H H8B 0.3323 0.3792 0.5747 0.023 Uiso calc R 1 1 . .
C C9 0.4790(3) 0.41255(8) 0.5851(2) 0.0165(6) Uani d . 1 1 . .
C C10 0.5479(4) 0.42694(9) 0.5246(2) 0.0227(7) Uani d . 1 1 . .
H H10 0.5657 0.4146 0.4759 0.027 Uiso calc R 1 1 . .
C C11 0.5910(4) 0.45888(10) 0.5344(3) 0.0302(8) Uani d . 1 1 . .
H H11 0.6367 0.4682 0.4921 0.036 Uiso calc R 1 1 . .
C C12 0.5676(4) 0.47723(9) 0.6057(2) 0.0265(8) Uani d . 1 1 . .
H H12 0.5977 0.4990 0.6123 0.032 Uiso calc R 1 1 . .
C C13 0.5003(3) 0.46368(8) 0.6667(2) 0.0210(7) Uani d . 1 1 . .
H H13 0.4830 0.4760 0.7155 0.025 Uiso calc R 1 1 . .
C C14 0.4584(3) 0.43187(8) 0.6559(2) 0.0161(6) Uani d . 1 1 . .
C C15 0.7455(3) 0.39726(8) 0.7550(2) 0.0178(6) Uani d . 1 1 . .
H H15 0.6763 0.4076 0.7781 0.021 Uiso calc R 1 1 . .
C C16 0.8738(3) 0.41027(8) 0.7745(2) 0.0221(7) Uani d . 1 1 . .
H H16 0.8910 0.4289 0.8109 0.027 Uiso calc R 1 1 . .
C C17 0.9739(3) 0.39583(8) 0.7406(2) 0.0214(7) Uani d . 1 1 . .
H H17 1.0609 0.4046 0.7530 0.026 Uiso calc R 1 1 . .
C C18 0.9483(3) 0.36779(8) 0.6871(2) 0.0162(6) Uani d . 1 1 . .
C C19 1.0442(3) 0.35066(8) 0.6496(2) 0.0193(7) Uani d . 1 1 . .
H H19 1.1330 0.3583 0.6577 0.023 Uiso calc R 1 1 . .
C C20 1.0088(3) 0.32306(9) 0.6017(2) 0.0211(7) Uani d . 1 1 . .
H H20 1.0742 0.3117 0.5772 0.025 Uiso calc R 1 1 . .
C C21 0.8782(3) 0.31108(8) 0.5878(2) 0.0171(6) Uani d . 1 1 . .
H H21 0.8569 0.2917 0.5549 0.020 Uiso calc R 1 1 . .
C C22 0.7806(3) 0.32750(8) 0.62184(19) 0.0144(6) Uani d . 1 1 . .
C C23 0.8163(3) 0.35615(8) 0.67214(19) 0.0144(6) Uani d . 1 1 . .
C C24 0.4908(4) 0.34026(8) 0.1706(2) 0.0223(7) Uani d . 1 1 . .
H H24A 0.4032 0.3508 0.1536 0.027 Uiso calc R 1 1 . .
H H24B 0.5592 0.3569 0.1670 0.027 Uiso calc R 1 1 . .
C C25 0.5024(3) 0.31453(8) 0.1037(2) 0.0165(6) Uani d . 1 1 . .
C C26 0.3891(4) 0.30107(9) 0.0511(2) 0.0248(8) Uani d . 1 1 . .
H H26 0.3037 0.3085 0.0575 0.030 Uiso calc R 1 1 . .
C C27 0.4002(4) 0.27714(10) -0.0099(2) 0.0302(9) Uani d . 1 1 . .
H H27 0.3223 0.2685 -0.0451 0.036 Uiso calc R 1 1 . .
C C28 0.5223(4) 0.26566(9) -0.0205(2) 0.0300(9) Uani d . 1 1 . .
H H28 0.5287 0.2490 -0.0621 0.036 Uiso calc R 1 1 . .
C C29 0.6358(4) 0.27858(9) 0.0299(2) 0.0250(8) Uani d . 1 1 . .
H H29 0.7207 0.2709 0.0232 0.030 Uiso calc R 1 1 . .
C C30 0.6244(3) 0.30281(8) 0.0901(2) 0.0179(6) Uani d . 1 1 . .
C C31 0.6184(3) 0.29074(8) 0.3978(2) 0.0211(7) Uani d . 1 1 . .
H H31A 0.7108 0.2902 0.3871 0.025 Uiso calc R 1 1 . .
H H31B 0.6217 0.2995 0.4580 0.025 Uiso calc R 1 1 . .
C C32 0.5725(3) 0.25673(8) 0.3986(2) 0.0165(6) Uani d . 1 1 . .
C C33 0.5197(4) 0.24448(10) 0.4697(2) 0.0270(8) Uani d . 1 1 . .
H H33 0.5067 0.2588 0.5158 0.032 Uiso calc R 1 1 . .
C C34 0.4858(4) 0.21223(11) 0.4750(3) 0.0345(9) Uani d . 1 1 . .
H H34 0.4518 0.2046 0.5247 0.041 Uiso calc R 1 1 . .
C C35 0.5013(4) 0.19110(10) 0.4077(3) 0.0313(9) Uani d . 1 1 . .
H H35 0.4785 0.1689 0.4115 0.038 Uiso calc R 1 1 . .
C C36 0.5498(4) 0.20224(9) 0.3353(2) 0.0244(7) Uani d . 1 1 . .
H H36 0.5591 0.1880 0.2883 0.029 Uiso calc R 1 1 . .
C C37 0.5848(3) 0.23456(8) 0.3323(2) 0.0174(6) Uani d . 1 1 . .
C C38 0.2936(3) 0.26708(8) 0.2257(2) 0.0183(6) Uani d . 1 1 . .
H H38 0.3630 0.2573 0.2014 0.022 Uiso calc R 1 1 . .
C C39 0.1678(4) 0.25257(8) 0.2101(2) 0.0227(7) Uani d . 1 1 . .
H H39 0.1524 0.2334 0.1754 0.027 Uiso calc R 1 1 . .
C C40 0.0673(3) 0.26633(8) 0.2456(2) 0.0217(7) Uani d . 1 1 . .
H H40 -0.0182 0.2566 0.2355 0.026 Uiso calc R 1 1 . .
C C41 0.0902(3) 0.29479(8) 0.2971(2) 0.0185(7) Uani d . 1 1 . .
C C42 -0.0053(3) 0.31081(9) 0.3369(2) 0.0218(7) Uani d . 1 1 . .
H H42 -0.0920 0.3020 0.3322 0.026 Uiso calc R 1 1 . .
C C43 0.0271(3) 0.33903(9) 0.3824(2) 0.0218(7) Uani d . 1 1 . .
H H43 -0.0385 0.3498 0.4081 0.026 Uiso calc R 1 1 . .
C C44 0.1552(3) 0.35252(9) 0.3923(2) 0.0193(7) Uani d . 1 1 . .
H H44 0.1746 0.3722 0.4240 0.023 Uiso calc R 1 1 . .
C C45 0.2524(3) 0.33724(8) 0.35614(19) 0.0144(6) Uani d . 1 1 . .
C C46 0.2201(3) 0.30805(8) 0.3085(2) 0.0151(6) Uani d . 1 1 . .
C C47 0.3890(3) 0.04155(8) 0.6179(2) 0.0177(6) Uani d . 1 1 . .
H H47A 0.3528 0.0315 0.5602 0.021 Uiso calc R 1 1 . .
H H47B 0.3127 0.0483 0.6450 0.021 Uiso calc R 1 1 . .
C C48 0.4642(3) 0.07106(8) 0.6015(2) 0.0158(6) Uani d . 1 1 . .
C C49 0.5337(3) 0.07149(9) 0.5316(2) 0.0232(7) Uani d . 1 1 . .
H H49 0.5317 0.0530 0.4947 0.028 Uiso calc R 1 1 . .
C C50 0.6058(4) 0.09847(11) 0.5153(3) 0.0334(9) Uani d . 1 1 . .
H H50 0.6516 0.0985 0.4668 0.040 Uiso calc R 1 1 . .
C C51 0.6113(4) 0.12534(10) 0.5691(3) 0.0311(9) Uani d . 1 1 . .
H H51 0.6623 0.1436 0.5582 0.037 Uiso calc R 1 1 . .
C C52 0.5433(4) 0.12588(9) 0.6389(2) 0.0244(7) Uani d . 1 1 . .
H H52 0.5463 0.1444 0.6757 0.029 Uiso calc R 1 1 . .
C C53 0.4706(3) 0.09875(8) 0.6540(2) 0.0175(6) Uani d . 1 1 . .
C C54 0.5296(4) -0.00778(8) 0.8390(2) 0.0211(7) Uani d . 1 1 . .
H H54A 0.4609 -0.0237 0.8482 0.025 Uiso calc R 1 1 . .
H H54B 0.6170 -0.0185 0.8551 0.025 Uiso calc R 1 1 . .
C C55 0.5246(3) 0.02044(8) 0.8991(2) 0.0182(7) Uani d . 1 1 . .
C C56 0.6380(4) 0.03202(9) 0.9556(2) 0.0238(7) Uani d . 1 1 . .
H H56 0.7202 0.0212 0.9572 0.029 Uiso calc R 1 1 . .
C C57 0.6332(4) 0.05867(10) 1.0089(2) 0.0292(9) Uani d . 1 1 . .
H H57 0.7115 0.0658 1.0467 0.035 Uiso calc R 1 1 . .
C C58 0.5157(4) 0.07504(9) 1.0076(2) 0.0280(8) Uani d . 1 1 . .
H H58 0.5136 0.0936 1.0437 0.034 Uiso calc R 1 1 . .
C C59 0.3999(4) 0.06433(9) 0.9535(2) 0.0234(7) Uani d . 1 1 . .
H H59 0.3181 0.0753 0.9524 0.028 Uiso calc R 1 1 . .
C C60 0.4070(3) 0.03732(8) 0.9013(2) 0.0178(7) Uani d . 1 1 . .
C C61 0.7283(3) 0.06276(8) 0.7710(2) 0.0194(7) Uani d . 1 1 . .
H H61 0.6642 0.0728 0.7996 0.023 Uiso calc R 1 1 . .
C C62 0.8548(4) 0.07705(8) 0.7782(2) 0.0243(7) Uani d . 1 1 . .
H H62 0.8755 0.0964 0.8115 0.029 Uiso calc R 1 1 . .
C C63 0.9477(3) 0.06275(9) 0.7366(2) 0.0236(7) Uani d . 1 1 . .
H H63 1.0329 0.0723 0.7408 0.028 Uiso calc R 1 1 . .
C C64 0.9170(3) 0.03384(8) 0.6874(2) 0.0193(7) Uani d . 1 1 . .
C C65 1.0060(3) 0.01673(9) 0.6442(2) 0.0234(7) Uani d . 1 1 . .
H H65 1.0927 0.0250 0.6447 0.028 Uiso calc R 1 1 . .
C C66 0.9673(3) -0.01177(9) 0.6017(2) 0.0217(7) Uani d . 1 1 . .
H H66 1.0287 -0.0234 0.5741 0.026 Uiso calc R 1 1 . .
C C67 0.8383(3) -0.02427(9) 0.5979(2) 0.0191(7) Uani d . 1 1 . .
H H67 0.8140 -0.0441 0.5680 0.023 Uiso calc R 1 1 . .
C C68 0.7474(3) -0.00779(8) 0.6374(2) 0.0161(6) Uani d . 1 1 . .
C C69 0.7877(3) 0.02121(8) 0.6840(2) 0.0153(6) Uani d . 1 1 . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sn Sn -0.6537 1.4246 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
_geom_angle_publ_flag
O1 Sn1 C8 . . 109.26(11) ?
O1 Sn1 C1 . . 109.37(11) ?
C8 Sn1 C1 . . 141.32(13) ?
O1 Sn1 N1 . . 75.30(9) ?
C8 Sn1 N1 . . 94.45(11) ?
C1 Sn1 N1 . . 93.41(12) ?
O1 Sn1 Cl1 . . 85.92(7) ?
C8 Sn1 Cl1 . . 92.48(9) ?
C1 Sn1 Cl1 . . 92.04(10) ?
N1 Sn1 Cl1 . . 161.20(7) ?
O2 Sn2 C31 . . 110.12(11) ?
O2 Sn2 C24 . . 109.04(11) ?
C31 Sn2 C24 . . 140.67(13) ?
O2 Sn2 N2 . . 75.47(9) ?
C31 Sn2 N2 . . 95.38(11) ?
C24 Sn2 N2 . . 90.89(12) ?
O2 Sn2 Cl4 . . 85.07(7) ?
C31 Sn2 Cl4 . . 91.48(9) ?
C24 Sn2 Cl4 . . 95.31(10) ?
N2 Sn2 Cl4 . . 160.53(7) ?
O3 Sn3 C47 . . 109.91(11) ?
O3 Sn3 C54 . . 112.76(11) ?
C47 Sn3 C54 . . 136.71(13) ?
O3 Sn3 N3 . . 75.07(9) ?
C47 Sn3 N3 . . 93.83(11) ?
C54 Sn3 N3 . . 90.22(11) ?
O3 Sn3 Cl7 . . 87.28(6) ?
C47 Sn3 Cl7 . . 92.43(9) ?
C54 Sn3 Cl7 . . 96.48(10) ?
N3 Sn3 Cl7 . . 162.35(7) ?
C22 O1 Sn1 . . 119.21(19) ?
C45 O2 Sn2 . . 119.16(19) ?
C68 O3 Sn3 . . 119.50(19) ?
C15 N1 C23 . . 118.8(3) ?
C15 N1 Sn1 . . 131.2(2) ?
C23 N1 Sn1 . . 110.0(2) ?
C38 N2 C46 . . 119.4(3) ?
C38 N2 Sn2 . . 131.1(2) ?
C46 N2 Sn2 . . 109.5(2) ?
C61 N3 C69 . . 119.3(3) ?
C61 N3 Sn3 . . 131.3(2) ?
C69 N3 Sn3 . . 109.4(2) ?
C2 C1 Sn1 . . 118.5(2) ?
C2 C1 H1A . . 107.7 ?
Sn1 C1 H1A . . 107.7 ?
C2 C1 H1B . . 107.7 ?
Sn1 C1 H1B . . 107.7 ?
H1A C1 H1B . . 107.1 ?
C7 C2 C3 . . 116.3(3) ?
C7 C2 C1 . . 123.6(3) ?
C3 C2 C1 . . 120.0(3) ?
C4 C3 C2 . . 122.3(4) ?
C4 C3 H3 . . 118.8 ?
C2 C3 H3 . . 118.8 ?
C5 C4 C3 . . 120.2(4) ?
C5 C4 H4 . . 119.9 ?
C3 C4 H4 . . 119.9 ?
C4 C5 C6 . . 120.0(4) ?
C4 C5 H5 . . 120.0 ?
C6 C5 H5 . . 120.0 ?
C7 C6 C5 . . 118.8(4) ?
C7 C6 H6 . . 120.6 ?
C5 C6 H6 . . 120.6 ?
C6 C7 C2 . . 122.3(3) ?
C6 C7 Cl2 . . 118.4(3) ?
C2 C7 Cl2 . . 119.3(3) ?
C9 C8 Sn1 . . 117.9(2) ?
C9 C8 H8A . . 107.8 ?
Sn1 C8 H8A . . 107.8 ?
C9 C8 H8B . . 107.8 ?
Sn1 C8 H8B . . 107.8 ?
H8A C8 H8B . . 107.2 ?
C14 C9 C10 . . 116.2(3) ?
C14 C9 C8 . . 122.4(3) ?
C10 C9 C8 . . 121.3(3) ?
C11 C10 C9 . . 121.3(3) ?
C11 C10 H10 . . 119.3 ?
C9 C10 H10 . . 119.3 ?
C12 C11 C10 . . 120.4(3) ?
C12 C11 H11 . . 119.8 ?
C10 C11 H11 . . 119.8 ?
C13 C12 C11 . . 119.7(3) ?
C13 C12 H12 . . 120.2 ?
C11 C12 H12 . . 120.2 ?
C12 C13 C14 . . 119.0(3) ?
C12 C13 H13 . . 120.5 ?
C14 C13 H13 . . 120.5 ?
C13 C14 C9 . . 123.3(3) ?
C13 C14 Cl3 . . 118.6(2) ?
C9 C14 Cl3 . . 118.1(3) ?
N1 C15 C16 . . 122.4(3) ?
N1 C15 H15 . . 118.8 ?
C16 C15 H15 . . 118.8 ?
C17 C16 C15 . . 119.4(3) ?
C17 C16 H16 . . 120.3 ?
C15 C16 H16 . . 120.3 ?
C16 C17 C18 . . 120.2(3) ?
C16 C17 H17 . . 119.9 ?
C18 C17 H17 . . 119.9 ?
C19 C18 C23 . . 118.6(3) ?
C19 C18 C17 . . 125.1(3) ?
C23 C18 C17 . . 116.4(3) ?
C20 C19 C18 . . 119.9(3) ?
C20 C19 H19 . . 120.1 ?
C18 C19 H19 . . 120.1 ?
C19 C20 C21 . . 121.8(3) ?
C19 C20 H20 . . 119.1 ?
C21 C20 H20 . . 119.1 ?
C22 C21 C20 . . 120.1(3) ?
C22 C21 H21 . . 120.0 ?
C20 C21 H21 . . 120.0 ?
O1 C22 C21 . . 122.1(3) ?
O1 C22 C23 . . 119.2(3) ?
C21 C22 C23 . . 118.6(3) ?
N1 C23 C18 . . 122.8(3) ?
N1 C23 C22 . . 116.3(3) ?
C18 C23 C22 . . 121.0(3) ?
C25 C24 Sn2 . . 117.0(2) ?
C25 C24 H24A . . 108.1 ?
Sn2 C24 H24A . . 108.1 ?
C25 C24 H24B . . 108.1 ?
Sn2 C24 H24B . . 108.1 ?
H24A C24 H24B . . 107.3 ?
C30 C25 C26 . . 116.6(3) ?
C30 C25 C24 . . 122.2(3) ?
C26 C25 C24 . . 121.1(3) ?
C27 C26 C25 . . 120.9(3) ?
C27 C26 H26 . . 119.5 ?
C25 C26 H26 . . 119.5 ?
C28 C27 C26 . . 121.0(3) ?
C28 C27 H27 . . 119.5 ?
C26 C27 H27 . . 119.5 ?
C27 C28 C29 . . 119.5(3) ?
C27 C28 H28 . . 120.2 ?
C29 C28 H28 . . 120.2 ?
C30 C29 C28 . . 119.4(3) ?
C30 C29 H29 . . 120.3 ?
C28 C29 H29 . . 120.3 ?
C29 C30 C25 . . 122.6(3) ?
C29 C30 Cl6 . . 118.7(3) ?
C25 C30 Cl6 . . 118.7(3) ?
C32 C31 Sn2 . . 120.2(2) ?
C32 C31 H31A . . 107.3 ?
Sn2 C31 H31A . . 107.3 ?
C32 C31 H31B . . 107.3 ?
Sn2 C31 H31B . . 107.3 ?
H31A C31 H31B . . 106.9 ?
C37 C32 C33 . . 115.7(3) ?
C37 C32 C31 . . 123.0(3) ?
C33 C32 C31 . . 121.2(3) ?
C34 C33 C32 . . 122.1(3) ?
C34 C33 H33 . . 119.0 ?
C32 C33 H33 . . 119.0 ?
C33 C34 C35 . . 119.9(3) ?
C33 C34 H34 . . 120.0 ?
C35 C34 H34 . . 120.0 ?
C36 C35 C34 . . 120.1(4) ?
C36 C35 H35 . . 120.0 ?
C34 C35 H35 . . 120.0 ?
C35 C36 C37 . . 118.8(3) ?
C35 C36 H36 . . 120.6 ?
C37 C36 H36 . . 120.6 ?
C36 C37 C32 . . 123.4(3) ?
C36 C37 Cl5 . . 118.1(3) ?
C32 C37 Cl5 . . 118.5(3) ?
N2 C38 C39 . . 122.3(3) ?
N2 C38 H38 . . 118.8 ?
C39 C38 H38 . . 118.8 ?
C40 C39 C38 . . 119.2(3) ?
C40 C39 H39 . . 120.4 ?
C38 C39 H39 . . 120.4 ?
C39 C40 C41 . . 120.4(3) ?
C39 C40 H40 . . 119.8 ?
C41 C40 H40 . . 119.8 ?
C42 C41 C40 . . 125.1(3) ?
C42 C41 C46 . . 118.3(3) ?
C40 C41 C46 . . 116.5(3) ?
C43 C42 C41 . . 119.8(3) ?
C43 C42 H42 . . 120.1 ?
C41 C42 H42 . . 120.1 ?
C42 C43 C44 . . 121.9(3) ?
C42 C43 H43 . . 119.1 ?
C44 C43 H43 . . 119.1 ?
C45 C44 C43 . . 120.2(3) ?
C45 C44 H44 . . 119.9 ?
C43 C44 H44 . . 119.9 ?
O2 C45 C44 . . 122.2(3) ?
O2 C45 C46 . . 119.2(3) ?
C44 C45 C46 . . 118.6(3) ?
N2 C46 C45 . . 116.7(3) ?
N2 C46 C41 . . 122.1(3) ?
C45 C46 C41 . . 121.2(3) ?
C48 C47 Sn3 . . 116.1(2) ?
C48 C47 H47A . . 108.3 ?
Sn3 C47 H47A . . 108.3 ?
C48 C47 H47B . . 108.3 ?
Sn3 C47 H47B . . 108.3 ?
H47A C47 H47B . . 107.4 ?
C49 C48 C53 . . 117.4(3) ?
C49 C48 C47 . . 119.6(3) ?
C53 C48 C47 . . 123.0(3) ?
C50 C49 C48 . . 121.0(3) ?
C50 C49 H49 . . 119.5 ?
C48 C49 H49 . . 119.5 ?
C51 C50 C49 . . 120.2(4) ?
C51 C50 H50 . . 119.9 ?
C49 C50 H50 . . 119.9 ?
C50 C51 C52 . . 120.5(3) ?
C50 C51 H51 . . 119.7 ?
C52 C51 H51 . . 119.7 ?
C51 C52 C53 . . 118.6(3) ?
C51 C52 H52 . . 120.7 ?
C53 C52 H52 . . 120.7 ?
C52 C53 C48 . . 122.3(3) ?
C52 C53 Cl8 . . 118.5(3) ?
C48 C53 Cl8 . . 119.2(3) ?
C55 C54 Sn3 . . 113.5(2) ?
C55 C54 H54A . . 108.9 ?
Sn3 C54 H54A . . 108.9 ?
C55 C54 H54B . . 108.9 ?
Sn3 C54 H54B . . 108.9 ?
H54A C54 H54B . . 107.7 ?
C60 C55 C56 . . 115.9(3) ?
C60 C55 C54 . . 121.9(3) ?
C56 C55 C54 . . 122.1(3) ?
C57 C56 C55 . . 121.7(3) ?
C57 C56 H56 . . 119.1 ?
C55 C56 H56 . . 119.1 ?
C56 C57 C58 . . 120.5(3) ?
C56 C57 H57 . . 119.8 ?
C58 C57 H57 . . 119.8 ?
C57 C58 C59 . . 120.1(3) ?
C57 C58 H58 . . 119.9 ?
C59 C58 H58 . . 119.9 ?
C60 C59 C58 . . 118.3(3) ?
C60 C59 H59 . . 120.8 ?
C58 C59 H59 . . 120.8 ?
C59 C60 C55 . . 123.4(3) ?
C59 C60 Cl9 . . 118.3(3) ?
C55 C60 Cl9 . . 118.2(3) ?
N3 C61 C62 . . 122.1(3) ?
N3 C61 H61 . . 118.9 ?
C62 C61 H61 . . 118.9 ?
C63 C62 C61 . . 119.2(3) ?
C63 C62 H62 . . 120.4 ?
C61 C62 H62 . . 120.4 ?
C62 C63 C64 . . 120.4(3) ?
C62 C63 H63 . . 119.8 ?
C64 C63 H63 . . 119.8 ?
C65 C64 C69 . . 118.6(3) ?
C65 C64 C63 . . 125.0(3) ?
C69 C64 C63 . . 116.5(3) ?
C66 C65 C64 . . 119.9(3) ?
C66 C65 H65 . . 120.0 ?
C64 C65 H65 . . 120.0 ?
C65 C66 C67 . . 121.5(3) ?
C65 C66 H66 . . 119.2 ?
C67 C66 H66 . . 119.2 ?
C68 C67 C66 . . 120.3(3) ?
C68 C67 H67 . . 119.9 ?
C66 C67 H67 . . 119.9 ?
O3 C68 C67 . . 121.9(3) ?
O3 C68 C69 . . 119.5(3) ?
C67 C68 C69 . . 118.7(3) ?
N3 C69 C64 . . 122.5(3) ?
N3 C69 C68 . . 116.5(3) ?
C64 C69 C68 . . 121.0(3) ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
Sn1 O1 . 2.043(2) ?
Sn1 C8 . 2.154(3) ?
Sn1 C1 . 2.162(3) ?
Sn1 N1 . 2.335(3) ?
Sn1 Cl1 . 2.4596(8) ?
Sn2 O2 . 2.039(2) ?
Sn2 C31 . 2.150(3) ?
Sn2 C24 . 2.159(3) ?
Sn2 N2 . 2.331(3) ?
Sn2 Cl4 . 2.4638(8) ?
Sn3 O3 . 2.038(2) ?
Sn3 C47 . 2.150(3) ?
Sn3 C54 . 2.159(3) ?
Sn3 N3 . 2.355(3) ?
Sn3 Cl7 . 2.4437(8) ?
Cl2 C7 . 1.740(4) ?
Cl3 C14 . 1.741(3) ?
Cl5 C37 . 1.741(3) ?
Cl6 C30 . 1.735(3) ?
Cl8 C53 . 1.736(3) ?
Cl9 C60 . 1.743(3) ?
O1 C22 . 1.341(4) ?
O2 C45 . 1.337(4) ?
O3 C68 . 1.342(4) ?
N1 C15 . 1.325(4) ?
N1 C23 . 1.365(4) ?
N2 C38 . 1.323(4) ?
N2 C46 . 1.367(4) ?
N3 C61 . 1.324(4) ?
N3 C69 . 1.368(4) ?
C1 C2 . 1.483(5) ?
C1 H1A . 0.9900 ?
C1 H1B . 0.9900 ?
C2 C7 . 1.391(5) ?
C2 C3 . 1.397(5) ?
C3 C4 . 1.368(6) ?
C3 H3 . 0.9500 ?
C4 C5 . 1.366(7) ?
C4 H4 . 0.9500 ?
C5 C6 . 1.397(6) ?
C5 H5 . 0.9500 ?
C6 C7 . 1.386(5) ?
C6 H6 . 0.9500 ?
C8 C9 . 1.487(5) ?
C8 H8A . 0.9900 ?
C8 H8B . 0.9900 ?
C9 C14 . 1.396(4) ?
C9 C10 . 1.397(5) ?
C10 C11 . 1.389(5) ?
C10 H10 . 0.9500 ?
C11 C12 . 1.388(5) ?
C11 H11 . 0.9500 ?
C12 C13 . 1.379(5) ?
C12 H12 . 0.9500 ?
C13 C14 . 1.382(5) ?
C13 H13 . 0.9500 ?
C15 C16 . 1.402(5) ?
C15 H15 . 0.9500 ?
C16 C17 . 1.369(5) ?
C16 H16 . 0.9500 ?
C17 C18 . 1.416(5) ?
C17 H17 . 0.9500 ?
C18 C19 . 1.415(5) ?
C18 C23 . 1.415(4) ?
C19 C20 . 1.370(5) ?
C19 H19 . 0.9500 ?
C20 C21 . 1.407(5) ?
C20 H20 . 0.9500 ?
C21 C22 . 1.387(4) ?
C21 H21 . 0.9500 ?
C22 C23 . 1.424(4) ?
C24 C25 . 1.498(5) ?
C24 H24A . 0.9900 ?
C24 H24B . 0.9900 ?
C25 C30 . 1.392(5) ?
C25 C26 . 1.405(5) ?
C26 C27 . 1.381(5) ?
C26 H26 . 0.9500 ?
C27 C28 . 1.375(6) ?
C27 H27 . 0.9500 ?
C28 C29 . 1.384(5) ?
C28 H28 . 0.9500 ?
C29 C30 . 1.382(5) ?
C29 H29 . 0.9500 ?
C31 C32 . 1.481(5) ?
C31 H31A . 0.9900 ?
C31 H31B . 0.9900 ?
C32 C37 . 1.393(4) ?
C32 C33 . 1.399(5) ?
C33 C34 . 1.381(6) ?
C33 H33 . 0.9500 ?
C34 C35 . 1.384(6) ?
C34 H34 . 0.9500 ?
C35 C36 . 1.378(5) ?
C35 H35 . 0.9500 ?
C36 C37 . 1.384(5) ?
C36 H36 . 0.9500 ?
C38 C39 . 1.403(5) ?
C38 H38 . 0.9500 ?
C39 C40 . 1.373(5) ?
C39 H39 . 0.9500 ?
C40 C41 . 1.412(5) ?
C40 H40 . 0.9500 ?
C41 C42 . 1.410(5) ?
C41 C46 . 1.421(4) ?
C42 C43 . 1.368(5) ?
C42 H42 . 0.9500 ?
C43 C44 . 1.408(5) ?
C43 H43 . 0.9500 ?
C44 C45 . 1.378(4) ?
C44 H44 . 0.9500 ?
C45 C46 . 1.418(4) ?
C47 C48 . 1.486(4) ?
C47 H47A . 0.9900 ?
C47 H47B . 0.9900 ?
C48 C49 . 1.393(5) ?
C48 C53 . 1.394(5) ?
C49 C50 . 1.384(5) ?
C49 H49 . 0.9500 ?
C50 C51 . 1.379(6) ?
C50 H50 . 0.9500 ?
C51 C52 . 1.381(5) ?
C51 H51 . 0.9500 ?
C52 C53 . 1.388(5) ?
C52 H52 . 0.9500 ?
C54 C55 . 1.493(5) ?
C54 H54A . 0.9900 ?
C54 H54B . 0.9900 ?
C55 C60 . 1.398(5) ?
C55 C56 . 1.405(5) ?
C56 C57 . 1.377(5) ?
C56 H56 . 0.9500 ?
C57 C58 . 1.379(6) ?
C57 H57 . 0.9500 ?
C58 C59 . 1.394(5) ?
C58 H58 . 0.9500 ?
C59 C60 . 1.383(5) ?
C59 H59 . 0.9500 ?
C61 C62 . 1.411(5) ?
C61 H61 . 0.9500 ?
C62 C63 . 1.372(5) ?
C62 H62 . 0.9500 ?
C63 C64 . 1.417(5) ?
C63 H63 . 0.9500 ?
C64 C65 . 1.411(5) ?
C64 C69 . 1.417(4) ?
C65 C66 . 1.369(5) ?
C65 H65 . 0.9500 ?
C66 C67 . 1.410(5) ?
C66 H66 . 0.9500 ?
C67 C68 . 1.380(4) ?
C67 H67 . 0.9500 ?
C68 C69 . 1.418(4) ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion
_geom_torsion_publ_flag
C8 Sn1 O1 C22 . . . . 89.9(2) ?
C1 Sn1 O1 C22 . . . . -88.1(2) ?
N1 Sn1 O1 C22 . . . . 0.3(2) ?
Cl1 Sn1 O1 C22 . . . . -178.8(2) ?
C31 Sn2 O2 C45 . . . . -91.2(2) ?
C24 Sn2 O2 C45 . . . . 85.1(2) ?
N2 Sn2 O2 C45 . . . . -0.7(2) ?
Cl4 Sn2 O2 C45 . . . . 179.0(2) ?
C47 Sn3 O3 C68 . . . . 91.4(2) ?
C54 Sn3 O3 C68 . . . . -81.2(2) ?
N3 Sn3 O3 C68 . . . . 2.7(2) ?
Cl7 Sn3 O3 C68 . . . . -177.0(2) ?
O1 Sn1 N1 C15 . . . . -178.2(3) ?
C8 Sn1 N1 C15 . . . . 73.1(3) ?
C1 Sn1 N1 C15 . . . . -69.0(3) ?
Cl1 Sn1 N1 C15 . . . . -175.6(2) ?
O1 Sn1 N1 C23 . . . . -0.01(19) ?
C8 Sn1 N1 C23 . . . . -108.8(2) ?
C1 Sn1 N1 C23 . . . . 109.1(2) ?
Cl1 Sn1 N1 C23 . . . . 2.5(4) ?
O2 Sn2 N2 C38 . . . . 177.9(3) ?
C31 Sn2 N2 C38 . . . . -72.6(3) ?
C24 Sn2 N2 C38 . . . . 68.5(3) ?
Cl4 Sn2 N2 C38 . . . . 177.2(2) ?
O2 Sn2 N2 C46 . . . . 0.46(19) ?
C31 Sn2 N2 C46 . . . . 109.9(2) ?
C24 Sn2 N2 C46 . . . . -109.0(2) ?
Cl4 Sn2 N2 C46 . . . . -0.2(4) ?
O3 Sn3 N3 C61 . . . . 179.1(3) ?
C47 Sn3 N3 C61 . . . . 69.5(3) ?
C54 Sn3 N3 C61 . . . . -67.4(3) ?
Cl7 Sn3 N3 C61 . . . . -180.0(2) ?
O3 Sn3 N3 C69 . . . . -1.12(19) ?
C47 Sn3 N3 C69 . . . . -110.7(2) ?
C54 Sn3 N3 C69 . . . . 112.4(2) ?
Cl7 Sn3 N3 C69 . . . . -0.2(4) ?
O1 Sn1 C1 C2 . . . . 121.1(3) ?
C8 Sn1 C1 C2 . . . . -56.0(4) ?
N1 Sn1 C1 C2 . . . . 45.5(3) ?
Cl1 Sn1 C1 C2 . . . . -152.5(3) ?
Sn1 C1 C2 C7 . . . . 92.8(4) ?
Sn1 C1 C2 C3 . . . . -86.5(4) ?
C7 C2 C3 C4 . . . . -1.5(5) ?
C1 C2 C3 C4 . . . . 177.9(3) ?
C2 C3 C4 C5 . . . . 0.6(6) ?
C3 C4 C5 C6 . . . . 0.6(6) ?
C4 C5 C6 C7 . . . . -0.8(6) ?
C5 C6 C7 C2 . . . . -0.2(5) ?
C5 C6 C7 Cl2 . . . . 178.2(3) ?
C3 C2 C7 C6 . . . . 1.3(5) ?
C1 C2 C7 C6 . . . . -178.1(3) ?
C3 C2 C7 Cl2 . . . . -177.1(3) ?
C1 C2 C7 Cl2 . . . . 3.5(5) ?
O1 Sn1 C8 C9 . . . . -98.9(2) ?
C1 Sn1 C8 C9 . . . . 78.1(3) ?
N1 Sn1 C8 C9 . . . . -23.0(3) ?
Cl1 Sn1 C8 C9 . . . . 174.5(2) ?
Sn1 C8 C9 C14 . . . . -69.7(4) ?
Sn1 C8 C9 C10 . . . . 111.7(3) ?
C14 C9 C10 C11 . . . . -1.1(5) ?
C8 C9 C10 C11 . . . . 177.6(3) ?
C9 C10 C11 C12 . . . . 0.7(6) ?
C10 C11 C12 C13 . . . . -0.4(6) ?
C11 C12 C13 C14 . . . . 0.5(5) ?
C12 C13 C14 C9 . . . . -0.9(5) ?
C12 C13 C14 Cl3 . . . . 178.5(3) ?
C10 C9 C14 C13 . . . . 1.2(5) ?
C8 C9 C14 C13 . . . . -177.4(3) ?
C10 C9 C14 Cl3 . . . . -178.2(2) ?
C8 C9 C14 Cl3 . . . . 3.2(4) ?
C23 N1 C15 C16 . . . . -0.2(5) ?
Sn1 N1 C15 C16 . . . . 177.8(2) ?
N1 C15 C16 C17 . . . . 0.9(5) ?
C15 C16 C17 C18 . . . . -0.7(5) ?
C16 C17 C18 C19 . . . . -179.1(3) ?
C16 C17 C18 C23 . . . . -0.3(5) ?
C23 C18 C19 C20 . . . . -1.4(5) ?
C17 C18 C19 C20 . . . . 177.5(3) ?
C18 C19 C20 C21 . . . . 0.4(5) ?
C19 C20 C21 C22 . . . . 0.9(5) ?
Sn1 O1 C22 C21 . . . . 178.7(2) ?
Sn1 O1 C22 C23 . . . . -0.6(4) ?
C20 C21 C22 O1 . . . . 179.5(3) ?
C20 C21 C22 C23 . . . . -1.1(5) ?
C15 N1 C23 C18 . . . . -0.8(5) ?
Sn1 N1 C23 C18 . . . . -179.2(2) ?
C15 N1 C23 C22 . . . . 178.1(3) ?
Sn1 N1 C23 C22 . . . . -0.3(3) ?
C19 C18 C23 N1 . . . . 179.9(3) ?
C17 C18 C23 N1 . . . . 1.0(5) ?
C19 C18 C23 C22 . . . . 1.1(5) ?
C17 C18 C23 C22 . . . . -177.8(3) ?
O1 C22 C23 N1 . . . . 0.6(4) ?
C21 C22 C23 N1 . . . . -178.8(3) ?
O1 C22 C23 C18 . . . . 179.5(3) ?
C21 C22 C23 C18 . . . . 0.2(4) ?
O2 Sn2 C24 C25 . . . . -139.5(2) ?
C31 Sn2 C24 C25 . . . . 35.0(4) ?
N2 Sn2 C24 C25 . . . . -64.6(3) ?
Cl4 Sn2 C24 C25 . . . . 133.9(3) ?
Sn2 C24 C25 C30 . . . . -80.0(4) ?
Sn2 C24 C25 C26 . . . . 100.2(3) ?
C30 C25 C26 C27 . . . . 0.8(5) ?
C24 C25 C26 C27 . . . . -179.4(3) ?
C25 C26 C27 C28 . . . . 0.4(5) ?
C26 C27 C28 C29 . . . . -0.9(6) ?
C27 C28 C29 C30 . . . . 0.1(5) ?
C28 C29 C30 C25 . . . . 1.2(5) ?
C28 C29 C30 Cl6 . . . . 179.1(3) ?
C26 C25 C30 C29 . . . . -1.7(5) ?
C24 C25 C30 C29 . . . . 178.5(3) ?
C26 C25 C30 Cl6 . . . . -179.5(2) ?
C24 C25 C30 Cl6 . . . . 0.7(4) ?
O2 Sn2 C31 C32 . . . . 92.9(3) ?
C24 Sn2 C31 C32 . . . . -81.6(3) ?
N2 Sn2 C31 C32 . . . . 16.4(3) ?
Cl4 Sn2 C31 C32 . . . . 178.2(3) ?
Sn2 C31 C32 C37 . . . . 72.5(4) ?
Sn2 C31 C32 C33 . . . . -110.9(3) ?
C37 C32 C33 C34 . . . . 1.9(5) ?
C31 C32 C33 C34 . . . . -174.9(3) ?
C32 C33 C34 C35 . . . . -1.3(6) ?
C33 C34 C35 C36 . . . . -0.4(6) ?
C34 C35 C36 C37 . . . . 1.3(6) ?
C35 C36 C37 C32 . . . . -0.6(5) ?
C35 C36 C37 Cl5 . . . . 178.2(3) ?
C33 C32 C37 C36 . . . . -1.0(5) ?
C31 C32 C37 C36 . . . . 175.8(3) ?
C33 C32 C37 Cl5 . . . . -179.7(3) ?
C31 C32 C37 Cl5 . . . . -2.9(4) ?
C46 N2 C38 C39 . . . . 0.1(5) ?
Sn2 N2 C38 C39 . . . . -177.2(2) ?
N2 C38 C39 C40 . . . . -0.6(5) ?
C38 C39 C40 C41 . . . . 0.1(5) ?
C39 C40 C41 C42 . . . . -179.6(3) ?
C39 C40 C41 C46 . . . . 0.6(5) ?
C40 C41 C42 C43 . . . . -177.3(3) ?
C46 C41 C42 C43 . . . . 2.4(5) ?
C41 C42 C43 C44 . . . . -1.2(5) ?
C42 C43 C44 C45 . . . . -0.3(5) ?
Sn2 O2 C45 C44 . . . . -179.0(2) ?
Sn2 O2 C45 C46 . . . . 0.9(4) ?
C43 C44 C45 O2 . . . . -179.5(3) ?
C43 C44 C45 C46 . . . . 0.5(5) ?
C38 N2 C46 C45 . . . . -178.0(3) ?
Sn2 N2 C46 C45 . . . . -0.2(3) ?
C38 N2 C46 C41 . . . . 0.8(5) ?
Sn2 N2 C46 C41 . . . . 178.6(2) ?
O2 C45 C46 N2 . . . . -0.5(4) ?
C44 C45 C46 N2 . . . . 179.5(3) ?
O2 C45 C46 C41 . . . . -179.2(3) ?
C44 C45 C46 C41 . . . . 0.7(5) ?
C42 C41 C46 N2 . . . . 179.2(3) ?
C40 C41 C46 N2 . . . . -1.1(5) ?
C42 C41 C46 C45 . . . . -2.2(5) ?
C40 C41 C46 C45 . . . . 177.6(3) ?
O3 Sn3 C47 C48 . . . . -74.1(2) ?
C54 Sn3 C47 C48 . . . . 95.8(3) ?
N3 Sn3 C47 C48 . . . . 1.4(2) ?
Cl7 Sn3 C47 C48 . . . . -162.1(2) ?
Sn3 C47 C48 C49 . . . . 87.5(3) ?
Sn3 C47 C48 C53 . . . . -91.6(3) ?
C53 C48 C49 C50 . . . . -0.2(5) ?
C47 C48 C49 C50 . . . . -179.3(3) ?
C48 C49 C50 C51 . . . . 0.9(6) ?
C49 C50 C51 C52 . . . . -1.2(6) ?
C50 C51 C52 C53 . . . . 0.6(6) ?
C51 C52 C53 C48 . . . . 0.2(5) ?
C51 C52 C53 Cl8 . . . . -179.7(3) ?
C49 C48 C53 C52 . . . . -0.4(5) ?
C47 C48 C53 C52 . . . . 178.7(3) ?
C49 C48 C53 Cl8 . . . . 179.5(2) ?
C47 C48 C53 Cl8 . . . . -1.4(4) ?
O3 Sn3 C54 C55 . . . . 138.4(2) ?
C47 Sn3 C54 C55 . . . . -31.3(3) ?
N3 Sn3 C54 C55 . . . . 64.5(2) ?
Cl7 Sn3 C54 C55 . . . . -131.8(2) ?
Sn3 C54 C55 C60 . . . . 68.4(4) ?
Sn3 C54 C55 C56 . . . . -110.4(3) ?
C60 C55 C56 C57 . . . . -0.8(5) ?
C54 C55 C56 C57 . . . . 178.0(3) ?
C55 C56 C57 C58 . . . . -0.5(5) ?
C56 C57 C58 C59 . . . . 1.2(5) ?
C57 C58 C59 C60 . . . . -0.5(5) ?
C58 C59 C60 C55 . . . . -0.9(5) ?
C58 C59 C60 Cl9 . . . . 180.0(3) ?
C56 C55 C60 C59 . . . . 1.5(5) ?
C54 C55 C60 C59 . . . . -177.3(3) ?
C56 C55 C60 Cl9 . . . . -179.3(2) ?
C54 C55 C60 Cl9 . . . . 1.8(4) ?
C69 N3 C61 C62 . . . . -0.4(5) ?
Sn3 N3 C61 C62 . . . . 179.3(2) ?
N3 C61 C62 C63 . . . . 0.5(5) ?
C61 C62 C63 C64 . . . . -0.4(5) ?
C62 C63 C64 C65 . . . . -178.2(3) ?
C62 C63 C64 C69 . . . . 0.3(5) ?
C69 C64 C65 C66 . . . . -1.2(5) ?
C63 C64 C65 C66 . . . . 177.2(3) ?
C64 C65 C66 C67 . . . . 1.6(5) ?
C65 C66 C67 C68 . . . . 0.1(5) ?
Sn3 O3 C68 C67 . . . . 175.5(2) ?
Sn3 O3 C68 C69 . . . . -4.0(4) ?
C66 C67 C68 O3 . . . . 178.4(3) ?
C66 C67 C68 C69 . . . . -2.0(5) ?
C61 N3 C69 C64 . . . . 0.3(5) ?
Sn3 N3 C69 C64 . . . . -179.5(2) ?
C61 N3 C69 C68 . . . . 179.4(3) ?
Sn3 N3 C69 C68 . . . . -0.4(3) ?
C65 C64 C69 N3 . . . . 178.4(3) ?
C63 C64 C69 N3 . . . . -0.2(5) ?
C65 C64 C69 C68 . . . . -0.7(5) ?
C63 C64 C69 C68 . . . . -179.3(3) ?
O3 C68 C69 N3 . . . . 2.8(4) ?
C67 C68 C69 N3 . . . . -176.8(3) ?
O3 C68 C69 C64 . . . . -178.1(3) ?
C67 C68 C69 C64 . . . . 2.3(5) ?
