#------------------------------------------------------------------------------
#$Date: 2016-02-21 02:03:34 +0200 (Sun, 21 Feb 2016) $
#$Revision: 176798 $
#$URL: svn://www.crystallography.net/cod/cif/2/23/24/2232488.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2232488
loop_
_publ_author_name
'Wang, Zhiliang'
'Zhou, Xianju'
_publ_section_title
;
 Di-μ-benzoato-κ³O,O':O';κ³O:O,O'-bis[aquabis(benzoato-κ²O,O')(dimethylformamide-κO)europium(III)]
;
_journal_coeditor_code           VN2018
_journal_issue                   11
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m1579
_journal_page_last               m1580
_journal_paper_doi               10.1107/S1600536811042735
_journal_volume                  67
_journal_year                    2011
_chemical_formula_iupac          '[Eu2 (C7 H5 O2)6 (C3 H7 N O)2 (H2 O)2]'
_chemical_formula_moiety         'C48 H48 Eu2 N2 O16'
_chemical_formula_sum            'C48 H48 Eu2 N2 O16'
_chemical_formula_weight         1212.80
_chemical_name_systematic
;
Di-μ-benzoato-
κ³O,O':O';κ³O:O,O'-
bis[aquabis(benzoato-κ²O,O')(dimethylformamide-
κO)europium(III)]
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL97
_cell_angle_alpha                90.00
_cell_angle_beta                 101.460(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   11.6395(2)
_cell_length_b                   8.36920(10)
_cell_length_c                   25.5235(4)
_cell_measurement_reflns_used    5244
_cell_measurement_temperature    291(2)
_cell_measurement_theta_max      67.4874
_cell_measurement_theta_min      3.5309
_cell_volume                     2436.76(7)
_computing_cell_refinement       'CrysAlis PRO (Oxford Diffraction, 2010)'
_computing_data_collection       'CrysAlis PRO (Oxford Diffraction, 2010)'
_computing_data_reduction        'CrysAlis PRO (Oxford Diffraction, 2010)'
_computing_molecular_graphics    'DIAMOND (Brandenburg, 1999)'
_computing_publication_material  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      291(2)
_diffrn_detector_area_resol_mean 15.9149
_diffrn_measured_fraction_theta_full 0.978
_diffrn_measured_fraction_theta_max 0.978
_diffrn_measurement_device_type  'Oxford Gemini S Ultra'
_diffrn_measurement_method       ω
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_source         'Enhance Ultra (Cu) X-ray source'
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54184
_diffrn_reflns_av_R_equivalents  0.0347
_diffrn_reflns_av_sigmaI/netI    0.0471
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       5
_diffrn_reflns_limit_k_min       -9
_diffrn_reflns_limit_l_max       30
_diffrn_reflns_limit_l_min       -30
_diffrn_reflns_number            8782
_diffrn_reflns_theta_full        67.60
_diffrn_reflns_theta_max         67.60
_diffrn_reflns_theta_min         3.53
_exptl_absorpt_coefficient_mu    18.841
_exptl_absorpt_correction_T_max  0.0650
_exptl_absorpt_correction_T_min  0.0562
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(CrysAlis PRO; Oxford Diffraction, 2010)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.653
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1208
_exptl_crystal_size_max          0.36
_exptl_crystal_size_mid          0.32
_exptl_crystal_size_min          0.32
_refine_diff_density_max         1.198
_refine_diff_density_min         -1.916
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.028
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     315
_refine_ls_number_reflns         4294
_refine_ls_number_restraints     3
_refine_ls_restrained_S_all      1.028
_refine_ls_R_factor_all          0.0489
_refine_ls_R_factor_gt           0.0445
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w = 1/[σ²(Fo²)+(0.0781P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1140
_refine_ls_wR_factor_ref         0.1200
_reflns_number_gt                3860
_reflns_number_total             4294
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            vn2018.cif
_cod_data_source_block           I
_cod_original_cell_volume        2436.76(6)
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               2232488
_cod_database_fobs_code          2232488
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_symmetry_multiplicity
Eu Eu1 0.58936(2) 0.32204(3) 0.555114(10) 0.02985(13) Uani d . 1 1
O O1 0.7648(3) 0.4223(4) 0.62602(15) 0.0471(8) Uani d . 1 1
O O5 0.5539(3) 0.2337(5) 0.64080(14) 0.0455(8) Uani d . 1 1
O O8 0.7148(3) 0.0976(5) 0.55948(16) 0.0499(9) Uani d . 1 1
O O2 0.6119(3) 0.5789(4) 0.59914(14) 0.0426(8) Uani d . 1 1
O O7 0.5164(4) 0.2066(5) 0.46868(15) 0.0460(8) Uani d D 1 1
O O4 0.4078(3) 0.4576(4) 0.53174(15) 0.0450(8) Uani d . 1 1
O O6 0.4632(3) 0.0941(4) 0.57245(14) 0.0442(8) Uani d . 1 1
O O3 0.7419(3) 0.4010(5) 0.50855(15) 0.0530(10) Uani d . 1 1
C C1 0.7736(4) 0.6905(6) 0.65945(19) 0.0347(11) Uani d . 1 1
N N1 0.8798(4) -0.0405(6) 0.5577(2) 0.0521(11) Uani d . 1 1
C C8 0.7618(4) 0.5287(6) 0.42852(19) 0.0379(10) Uani d . 1 1
C C15 0.4233(4) 0.0286(6) 0.6587(2) 0.0414(11) Uani d . 1 1
C C14 0.6945(4) 0.4870(6) 0.47094(19) 0.0366(10) Uani d . 1 1
C C16 0.4494(5) 0.0601(8) 0.7132(2) 0.0546(14) Uani d . 1 1
H H16 0.5050 0.1374 0.7265 0.065 Uiso calc R 1 1
C C9 0.8819(5) 0.5075(8) 0.4393(2) 0.0503(14) Uani d . 1 1
H H9 0.9175 0.4610 0.4716 0.060 Uiso calc R 1 1
C C22 0.8222(5) 0.0822(7) 0.5720(3) 0.0530(13) Uani d . 1 1
H H22 0.8650 0.1618 0.5926 0.064 Uiso calc R 1 1
C C21 0.4839(4) 0.1220(6) 0.62194(19) 0.0378(10) Uani d . 1 1
C C20 0.3412(5) -0.0855(8) 0.6391(3) 0.0540(14) Uani d . 1 1
H H20 0.3239 -0.1083 0.6027 0.065 Uiso calc R 1 1
C C6 0.8917(6) 0.6821(7) 0.6827(3) 0.0544(16) Uani d . 1 1
H H6 0.9329 0.5878 0.6808 0.065 Uiso calc R 1 1
C C7 0.7149(4) 0.5550(6) 0.62677(18) 0.0366(10) Uani d . 1 1
C C10 0.9505(6) 0.5531(9) 0.4038(3) 0.0681(19) Uani d . 1 1
H H10 1.0315 0.5405 0.4122 0.082 Uiso calc R 1 1
C C19 0.2840(6) -0.1669(8) 0.6742(4) 0.070(2) Uani d . 1 1
H H19 0.2274 -0.2430 0.6611 0.084 Uiso calc R 1 1
C C18 0.3111(6) -0.1349(10) 0.7283(3) 0.070(2) Uani d . 1 1
H H18 0.2733 -0.1902 0.7516 0.084 Uiso calc R 1 1
C C13 0.7090(6) 0.5896(8) 0.3796(2) 0.0622(17) Uani d . 1 1
H H13 0.6281 0.6020 0.3713 0.075 Uiso calc R 1 1
C C17 0.3936(6) -0.0219(9) 0.7476(3) 0.0668(18) Uani d . 1 1
H H17 0.4120 -0.0005 0.7841 0.080 Uiso calc R 1 1
C C24 1.0054(6) -0.0566(11) 0.5768(4) 0.088(3) Uani d . 1 1
H H24B 1.0207 -0.1451 0.6011 0.132 Uiso calc R 1 1
H H24A 1.0358 0.0396 0.5949 0.132 Uiso calc R 1 1
H H24C 1.0428 -0.0750 0.5470 0.132 Uiso calc R 1 1
C C5 0.9487(7) 0.8130(9) 0.7088(3) 0.071(2) Uani d . 1 1
H H5 1.0283 0.8074 0.7237 0.085 Uiso calc R 1 1
C C4 0.8876(7) 0.9514(9) 0.7128(3) 0.077(2) Uani d . 1 1
H H4 0.9261 1.0399 0.7300 0.093 Uiso calc R 1 1
C C12 0.7762(8) 0.6330(10) 0.3423(3) 0.085(3) Uani d . 1 1
H H12 0.7403 0.6717 0.3089 0.102 Uiso calc R 1 1
C C23 0.8170(8) -0.1668(8) 0.5251(4) 0.078(2) Uani d . 1 1
H H23B 0.8175 -0.2616 0.5463 0.118 Uiso calc R 1 1
H H23A 0.8545 -0.1886 0.4956 0.118 Uiso calc R 1 1
H H23C 0.7376 -0.1339 0.5119 0.118 Uiso calc R 1 1
C C2 0.7126(6) 0.8298(7) 0.6634(3) 0.0581(16) Uani d . 1 1
H H2 0.6336 0.8371 0.6475 0.070 Uiso calc R 1 1
C C11 0.8975(8) 0.6176(10) 0.3556(3) 0.082(2) Uani d . 1 1
H H11 0.9431 0.6514 0.3317 0.098 Uiso calc R 1 1
C C3 0.7697(7) 0.9596(8) 0.6914(3) 0.078(2) Uani d . 1 1
H H3 0.7280 1.0519 0.6955 0.093 Uiso calc R 1 1
H H7B 0.527(8) 0.112(5) 0.458(4) 0.117 Uiso d D 1 1
H H7A 0.470(7) 0.253(10) 0.443(3) 0.117 Uiso d D 1 1
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -8.9294 11.1857 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
O8 Eu1 O4 . . 154.52(13)
O8 Eu1 O7 . . 80.01(13)
O4 Eu1 O7 . . 80.00(13)
O8 Eu1 O2 . . 132.46(13)
O4 Eu1 O2 . . 72.54(12)
O7 Eu1 O2 . . 140.39(13)
O8 Eu1 O3 . . 74.58(14)
O4 Eu1 O3 . . 116.81(13)
O7 Eu1 O3 . . 79.55(15)
O2 Eu1 O3 . . 87.86(14)
O8 Eu1 O5 . . 85.94(14)
O4 Eu1 O5 . . 94.03(13)
O7 Eu1 O5 . . 127.89(13)
O2 Eu1 O5 . . 82.75(13)
O3 Eu1 O5 . . 143.29(13)
O8 Eu1 O6 . . 76.39(14)
O4 Eu1 O6 . . 83.33(13)
O7 Eu1 O6 . . 75.10(13)
O2 Eu1 O6 . . 127.60(12)
O3 Eu1 O6 . . 144.16(14)
O5 Eu1 O6 . . 52.81(12)
O8 Eu1 O1 . . 80.26(13)
O4 Eu1 O1 . . 124.21(12)
O7 Eu1 O1 . . 149.22(13)
O2 Eu1 O1 . . 52.24(11)
O3 Eu1 O1 . . 72.56(13)
O5 Eu1 O1 . . 73.68(12)
O6 Eu1 O1 . . 122.27(12)
O8 Eu1 C21 . . 80.78(14)
O4 Eu1 C21 . . 87.89(13)
O7 Eu1 C21 . . 101.45(15)
O2 Eu1 C21 . . 105.40(14)
O3 Eu1 C21 . . 154.81(14)
O5 Eu1 C21 . . 26.48(14)
O6 Eu1 C21 . . 26.34(13)
O1 Eu1 C21 . . 98.42(13)
O8 Eu1 C7 . . 106.16(14)
O4 Eu1 C7 . . 98.69(13)
O7 Eu1 C7 . . 154.32(14)
O2 Eu1 C7 . . 26.30(12)
O3 Eu1 C7 . . 78.27(14)
O5 Eu1 C7 . . 77.76(13)
O6 Eu1 C7 . . 130.46(12)
O1 Eu1 C7 . . 25.97(12)
C21 Eu1 C7 . . 104.14(14)
O8 Eu1 O4 . 3_666 116.21(12)
O4 Eu1 O4 . 3_666 69.30(12)
O7 Eu1 O4 . 3_666 66.92(12)
O2 Eu1 O4 . 3_666 76.82(11)
O3 Eu1 O4 . 3_666 47.66(11)
O5 Eu1 O4 . 3_666 156.69(11)
O6 Eu1 O4 . 3_666 136.02(11)
O1 Eu1 O4 . 3_666 101.67(11)
C21 Eu1 O4 . 3_666 155.54(12)
C7 Eu1 O4 . 3_666 88.47(12)
O8 Eu1 C14 . . 93.62(13)
O4 Eu1 C14 . . 93.99(13)
O7 Eu1 C14 . . 69.44(14)
O2 Eu1 C14 . . 84.36(13)
O3 Eu1 C14 . . 23.22(13)
O5 Eu1 C14 . . 162.04(12)
O6 Eu1 C14 . . 144.35(12)
O1 Eu1 C14 . . 88.52(12)
C21 Eu1 C14 . . 170.15(14)
C7 Eu1 C14 . . 85.15(13)
O4 Eu1 C14 3_666 . 24.70(11)
C7 O1 Eu1 . . 89.7(3)
C21 O5 Eu1 . . 95.4(3)
C22 O8 Eu1 . . 132.7(4)
C7 O2 Eu1 . . 96.9(3)
Eu1 O7 H7B . . 128(6)
Eu1 O7 H7A . . 126(6)
H7B O7 H7A . . 106(5)
C14 O4 Eu1 3_666 . 166.2(3)
C14 O4 Eu1 3_666 3_666 83.0(3)
Eu1 O4 Eu1 . 3_666 110.70(12)
C21 O6 Eu1 . . 92.0(3)
C14 O3 Eu1 . . 106.4(3)
C2 C1 C6 . . 119.4(5)
C2 C1 C7 . . 119.9(5)
C6 C1 C7 . . 120.5(5)
C22 N1 C23 . . 120.1(5)
C22 N1 C24 . . 120.9(6)
C23 N1 C24 . . 118.9(6)
C13 C8 C9 . . 118.7(5)
C13 C8 C14 . . 122.6(5)
C9 C8 C14 . . 118.6(5)
C20 C15 C16 . . 119.7(5)
C20 C15 C21 . . 120.9(5)
C16 C15 C21 . . 119.4(5)
O3 C14 O4 . 3_666 121.6(4)
O3 C14 C8 . . 118.7(4)
O4 C14 C8 3_666 . 119.8(4)
O3 C14 Eu1 . . 50.3(2)
O4 C14 Eu1 3_666 . 72.3(3)
C8 C14 Eu1 . . 165.4(3)
C17 C16 C15 . . 120.5(6)
C17 C16 H16 . . 119.7
C15 C16 H16 . . 119.7
C10 C9 C8 . . 121.9(6)
C10 C9 H9 . . 119.0
C8 C9 H9 . . 119.0
O8 C22 N1 . . 123.7(6)
O8 C22 H22 . . 118.2
N1 C22 H22 . . 118.2
O6 C21 O5 . . 119.8(4)
O6 C21 C15 . . 120.7(5)
O5 C21 C15 . . 119.5(4)
O6 C21 Eu1 . . 61.7(3)
O5 C21 Eu1 . . 58.1(2)
C15 C21 Eu1 . . 175.2(4)
C15 C20 C19 . . 119.5(6)
C15 C20 H20 . . 120.3
C19 C20 H20 . . 120.3
C5 C6 C1 . . 120.5(6)
C5 C6 H6 . . 119.8
C1 C6 H6 . . 119.8
O1 C7 O2 . . 121.0(5)
O1 C7 C1 . . 121.3(4)
O2 C7 C1 . . 117.7(4)
O1 C7 Eu1 . . 64.3(3)
O2 C7 Eu1 . . 56.8(2)
C1 C7 Eu1 . . 173.3(3)
C11 C10 C9 . . 118.9(7)
C11 C10 H10 . . 120.5
C9 C10 H10 . . 120.5
C18 C19 C20 . . 120.3(7)
C18 C19 H19 . . 119.9
C20 C19 H19 . . 119.9
C17 C18 C19 . . 119.9(6)
C17 C18 H18 . . 120.0
C19 C18 H18 . . 120.0
C8 C13 C12 . . 120.5(6)
C8 C13 H13 . . 119.8
C12 C13 H13 . . 119.8
C18 C17 C16 . . 120.1(7)
C18 C17 H17 . . 119.9
C16 C17 H17 . . 119.9
N1 C24 H24B . . 109.5
N1 C24 H24A . . 109.5
H24B C24 H24A . . 109.5
N1 C24 H24C . . 109.5
H24B C24 H24C . . 109.5
H24A C24 H24C . . 109.5
C4 C5 C6 . . 119.9(7)
C4 C5 H5 . . 120.1
C6 C5 H5 . . 120.1
C5 C4 C3 . . 120.2(6)
C5 C4 H4 . . 119.9
C3 C4 H4 . . 119.9
C11 C12 C13 . . 119.2(7)
C11 C12 H12 . . 120.4
C13 C12 H12 . . 120.4
N1 C23 H23B . . 109.5
N1 C23 H23A . . 109.5
H23B C23 H23A . . 109.5
N1 C23 H23C . . 109.5
H23B C23 H23C . . 109.5
H23A C23 H23C . . 109.5
C1 C2 C3 . . 119.8(6)
C1 C2 H2 . . 120.1
C3 C2 H2 . . 120.1
C10 C11 C12 . . 120.7(6)
C10 C11 H11 . . 119.7
C12 C11 H11 . . 119.7
C4 C3 C2 . . 120.1(7)
C4 C3 H3 . . 119.9
C2 C3 H3 . . 119.9
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
Eu1 O8 . 2.368(4) y
Eu1 O4 . 2.368(3) y
Eu1 O7 . 2.404(4) y
Eu1 O2 . 2.416(3) y
Eu1 O3 . 2.416(3) y
Eu1 O5 . 2.420(4) y
Eu1 O6 . 2.500(3) y
Eu1 O1 . 2.584(4) y
Eu1 C21 . 2.837(5) ?
Eu1 C7 . 2.867(5) ?
Eu1 O4 3_666 2.889(4) y
Eu1 C14 . 3.011(5) ?
O1 C7 . 1.255(6) ?
O5 C21 . 1.271(6) ?
O8 C22 . 1.235(7) ?
O2 C7 . 1.280(6) ?
O7 H7B . 0.86(2) ?
O7 H7A . 0.86(2) ?
O4 C14 3_666 1.267(5) ?
O4 Eu1 3_666 2.889(4) ?
O6 C21 . 1.260(6) ?
O3 C14 . 1.238(6) ?
C1 C2 . 1.379(8) ?
C1 C6 . 1.388(8) ?
C1 C7 . 1.490(7) ?
N1 C22 . 1.316(7) ?
N1 C23 . 1.450(9) ?
N1 C24 . 1.453(8) ?
C8 C13 . 1.376(8) ?
C8 C9 . 1.382(7) ?
C8 C14 . 1.498(6) ?
C15 C20 . 1.373(8) ?
C15 C16 . 1.388(8) ?
C15 C21 . 1.501(7) ?
C14 O4 3_666 1.267(5) ?
C16 C17 . 1.374(8) ?
C16 H16 . 0.9300 ?
C9 C10 . 1.377(8) ?
C9 H9 . 0.9300 ?
C22 H22 . 0.9300 ?
C20 C19 . 1.395(9) ?
C20 H20 . 0.9300 ?
C6 C5 . 1.380(10) ?
C6 H6 . 0.9300 ?
C10 C11 . 1.371(11) ?
C10 H10 . 0.9300 ?
C19 C18 . 1.380(12) ?
C19 H19 . 0.9300 ?
C18 C17 . 1.368(11) ?
C18 H18 . 0.9300 ?
C13 C12 . 1.394(9) ?
C13 H13 . 0.9300 ?
C17 H17 . 0.9300 ?
C24 H24B . 0.9600 ?
C24 H24A . 0.9600 ?
C24 H24C . 0.9600 ?
C5 C4 . 1.373(10) ?
C5 H5 . 0.9300 ?
C4 C3 . 1.374(10) ?
C4 H4 . 0.9300 ?
C12 C11 . 1.392(12) ?
C12 H12 . 0.9300 ?
C23 H23B . 0.9600 ?
C23 H23A . 0.9600 ?
C23 H23C . 0.9600 ?
C2 C3 . 1.393(9) ?
C2 H2 . 0.9300 ?
C11 H11 . 0.9300 ?
C3 H3 . 0.9300 ?
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_site_symmetry_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
O7 H7B O6 3_656 0.86(2) 1.90(2) 2.756(5) 174(9)
O7 H7A O2 3_666 0.86(2) 1.90(4) 2.724(5) 159(9)
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
_geom_torsion
O8 Eu1 O1 C7 . . 175.9(3)
O4 Eu1 O1 C7 . . -11.9(3)
O7 Eu1 O1 C7 . . 125.1(3)
O2 Eu1 O1 C7 . . -2.1(3)
O3 Eu1 O1 C7 . . 99.1(3)
O5 Eu1 O1 C7 . . -95.5(3)
O6 Eu1 O1 C7 . . -117.1(3)
C21 Eu1 O1 C7 . . -105.1(3)
O4 Eu1 O1 C7 3_666 . 60.9(3)
C14 Eu1 O1 C7 . . 81.9(3)
O8 Eu1 O5 C21 . . -77.4(3)
O4 Eu1 O5 C21 . . 77.0(3)
O7 Eu1 O5 C21 . . -3.4(4)
O2 Eu1 O5 C21 . . 148.8(3)
O3 Eu1 O5 C21 . . -134.7(3)
O6 Eu1 O5 C21 . . -1.4(3)
O1 Eu1 O5 C21 . . -158.4(3)
C7 Eu1 O5 C21 . . 175.1(3)
O4 Eu1 O5 C21 3_666 . 120.0(3)
C14 Eu1 O5 C21 . . -166.6(4)
O4 Eu1 O8 C22 . . 169.1(5)
O7 Eu1 O8 C22 . . 130.3(5)
O2 Eu1 O8 C22 . . -23.8(6)
O3 Eu1 O8 C22 . . 48.5(5)
O5 Eu1 O8 C22 . . -100.1(5)
O6 Eu1 O8 C22 . . -152.8(5)
O1 Eu1 O8 C22 . . -26.0(5)
C21 Eu1 O8 C22 . . -126.2(5)
C7 Eu1 O8 C22 . . -24.1(5)
O4 Eu1 O8 C22 3_666 . 72.3(5)
C14 Eu1 O8 C22 . . 61.9(5)
O8 Eu1 O2 C7 . . -0.7(4)
O4 Eu1 O2 C7 . . 173.6(3)
O7 Eu1 O2 C7 . . -138.2(3)
O3 Eu1 O2 C7 . . -67.4(3)
O5 Eu1 O2 C7 . . 77.0(3)
O6 Eu1 O2 C7 . . 106.9(3)
O1 Eu1 O2 C7 . . 2.1(3)
C21 Eu1 O2 C7 . . 90.8(3)
O4 Eu1 O2 C7 3_666 . -114.3(3)
C14 Eu1 O2 C7 . . -90.5(3)
O8 Eu1 O4 C14 . 3_666 78.9(14)
O7 Eu1 O4 C14 . 3_666 117.7(14)
O2 Eu1 O4 C14 . 3_666 -91.2(14)
O3 Eu1 O4 C14 . 3_666 -169.5(14)
O5 Eu1 O4 C14 . 3_666 -10.1(14)
O6 Eu1 O4 C14 . 3_666 41.7(14)
O1 Eu1 O4 C14 . 3_666 -83.1(14)
C21 Eu1 O4 C14 . 3_666 15.6(14)
C7 Eu1 O4 C14 . 3_666 -88.3(14)
O4 Eu1 O4 C14 3_666 3_666 -173.4(15)
C14 Eu1 O4 C14 . 3_666 -174.0(13)
O8 Eu1 O4 Eu1 . 3_666 -107.7(3)
O7 Eu1 O4 Eu1 . 3_666 -68.97(14)
O2 Eu1 O4 Eu1 . 3_666 82.15(14)
O3 Eu1 O4 Eu1 . 3_666 3.84(19)
O5 Eu1 O4 Eu1 . 3_666 163.24(13)
O6 Eu1 O4 Eu1 . 3_666 -144.95(14)
O1 Eu1 O4 Eu1 . 3_666 90.26(16)
C21 Eu1 O4 Eu1 . 3_666 -170.98(15)
C7 Eu1 O4 Eu1 . 3_666 85.03(14)
O4 Eu1 O4 Eu1 3_666 3_666 0.0
C14 Eu1 O4 Eu1 . 3_666 -0.67(15)
O8 Eu1 O6 C21 . . 96.7(3)
O4 Eu1 O6 C21 . . -98.8(3)
O7 Eu1 O6 C21 . . 179.8(3)
O2 Eu1 O6 C21 . . -36.9(3)
O3 Eu1 O6 C21 . . 133.4(3)
O5 Eu1 O6 C21 . . 1.5(3)
O1 Eu1 O6 C21 . . 27.8(3)
C7 Eu1 O6 C21 . . -3.0(4)
O4 Eu1 O6 C21 3_666 . -149.5(3)
C14 Eu1 O6 C21 . . 173.7(3)
O8 Eu1 O3 C14 . . 144.0(4)
O4 Eu1 O3 C14 . . -11.5(4)
O7 Eu1 O3 C14 . . 61.6(4)
O2 Eu1 O3 C14 . . -80.7(4)
O5 Eu1 O3 C14 . . -155.5(3)
O6 Eu1 O3 C14 . . 107.0(4)
O1 Eu1 O3 C14 . . -131.6(4)
C21 Eu1 O3 C14 . . 156.3(3)
C7 Eu1 O3 C14 . . -105.4(4)
O4 Eu1 O3 C14 3_666 . -6.6(3)
Eu1 O3 C14 O4 . 3_666 13.2(6)
Eu1 O3 C14 C8 . . -168.3(4)
C13 C8 C14 O3 . . 164.0(6)
C9 C8 C14 O3 . . -17.0(8)
C13 C8 C14 O4 . 3_666 -17.4(8)
C9 C8 C14 O4 . 3_666 161.5(5)
C13 C8 C14 Eu1 . . 125.8(12)
C9 C8 C14 Eu1 . . -55.2(15)
O8 Eu1 C14 O3 . . -34.6(4)
O4 Eu1 C14 O3 . . 169.7(4)
O7 Eu1 C14 O3 . . -112.5(4)
O2 Eu1 C14 O3 . . 97.8(4)
O5 Eu1 C14 O3 . . 53.4(6)
O6 Eu1 C14 O3 . . -106.1(4)
O1 Eu1 C14 O3 . . 45.6(4)
C7 Eu1 C14 O3 . . 71.3(4)
O4 Eu1 C14 O3 3_666 . 168.3(5)
O8 Eu1 C14 O4 . 3_666 157.2(3)
O4 Eu1 C14 O4 . 3_666 1.5(3)
O7 Eu1 C14 O4 . 3_666 79.3(3)
O2 Eu1 C14 O4 . 3_666 -70.5(3)
O3 Eu1 C14 O4 . 3_666 -168.3(5)
O5 Eu1 C14 O4 . 3_666 -114.8(4)
O6 Eu1 C14 O4 . 3_666 85.6(3)
O1 Eu1 C14 O4 . 3_666 -122.7(3)
C7 Eu1 C14 O4 . 3_666 -96.9(3)
O8 Eu1 C14 C8 . . 10.2(13)
O4 Eu1 C14 C8 . . -145.4(13)
O7 Eu1 C14 C8 . . -67.7(13)
O2 Eu1 C14 C8 . . 142.6(13)
O3 Eu1 C14 C8 . . 44.8(12)
O5 Eu1 C14 C8 . . 98.2(13)
O6 Eu1 C14 C8 . . -61.3(13)
O1 Eu1 C14 C8 . . 90.4(13)
C7 Eu1 C14 C8 . . 116.2(13)
O4 Eu1 C14 C8 3_666 . -146.9(14)
C20 C15 C16 C17 . . 0.0(9)
C21 C15 C16 C17 . . 178.9(5)
C13 C8 C9 C10 . . 3.4(10)
C14 C8 C9 C10 . . -175.5(6)
Eu1 O8 C22 N1 . . -159.4(4)
C23 N1 C22 O8 . . 0.5(10)
C24 N1 C22 O8 . . -175.8(6)
Eu1 O6 C21 O5 . . -2.5(5)
Eu1 O6 C21 C15 . . 175.2(4)
Eu1 O5 C21 O6 . . 2.6(5)
Eu1 O5 C21 C15 . . -175.1(4)
C20 C15 C21 O6 . . -2.2(8)
C16 C15 C21 O6 . . 179.0(5)
C20 C15 C21 O5 . . 175.5(5)
C16 C15 C21 O5 . . -3.3(8)
O8 Eu1 C21 O6 . . -77.9(3)
O4 Eu1 C21 O6 . . 79.2(3)
O7 Eu1 C21 O6 . . -0.2(3)
O2 Eu1 C21 O6 . . 150.4(3)
O3 Eu1 C21 O6 . . -89.9(4)
O5 Eu1 C21 O6 . . -177.4(5)
O1 Eu1 C21 O6 . . -156.5(3)
C7 Eu1 C21 O6 . . 177.6(3)
O4 Eu1 C21 O6 3_666 . 58.5(5)
O8 Eu1 C21 O5 . . 99.5(3)
O4 Eu1 C21 O5 . . -103.4(3)
O7 Eu1 C21 O5 . . 177.2(3)
O2 Eu1 C21 O5 . . -32.2(3)
O3 Eu1 C21 O5 . . 87.5(5)
O6 Eu1 C21 O5 . . 177.4(5)
O1 Eu1 C21 O5 . . 20.9(3)
C7 Eu1 C21 O5 . . -5.0(3)
O4 Eu1 C21 O5 3_666 . -124.1(3)
C16 C15 C20 C19 . . 0.7(9)
C21 C15 C20 C19 . . -178.1(5)
C2 C1 C6 C5 . . -1.3(11)
C7 C1 C6 C5 . . 174.0(7)
Eu1 O1 C7 O2 . . 3.6(5)
Eu1 O1 C7 C1 . . -175.9(4)
Eu1 O2 C7 O1 . . -3.9(5)
Eu1 O2 C7 C1 . . 175.7(4)
C2 C1 C7 O1 . . -173.9(5)
C6 C1 C7 O1 . . 10.8(8)
C2 C1 C7 O2 . . 6.5(7)
C6 C1 C7 O2 . . -168.7(5)
O8 Eu1 C7 O1 . . -4.2(3)
O4 Eu1 C7 O1 . . 170.1(3)
O7 Eu1 C7 O1 . . -104.9(4)
O2 Eu1 C7 O1 . . 176.3(5)
O3 Eu1 C7 O1 . . -74.2(3)
O5 Eu1 C7 O1 . . 77.8(3)
O6 Eu1 C7 O1 . . 81.5(3)
C21 Eu1 C7 O1 . . 80.1(3)
O4 Eu1 C7 O1 3_666 . -121.1(3)
C14 Eu1 C7 O1 . . -96.6(3)
O8 Eu1 C7 O2 . . 179.5(3)
O4 Eu1 C7 O2 . . -6.2(3)
O7 Eu1 C7 O2 . . 78.8(4)
O3 Eu1 C7 O2 . . 109.5(3)
O5 Eu1 C7 O2 . . -98.5(3)
O6 Eu1 C7 O2 . . -94.8(3)
O1 Eu1 C7 O2 . . -176.3(5)
C21 Eu1 C7 O2 . . -96.2(3)
O4 Eu1 C7 O2 3_666 . 62.6(3)
C14 Eu1 C7 O2 . . 87.1(3)
C8 C9 C10 C11 . . -1.8(11)
C15 C20 C19 C18 . . -1.1(10)
C20 C19 C18 C17 . . 0.6(11)
C9 C8 C13 C12 . . -1.7(10)
C14 C8 C13 C12 . . 177.2(6)
C19 C18 C17 C16 . . 0.2(11)
C15 C16 C17 C18 . . -0.5(10)
C1 C6 C5 C4 . . 1.4(13)
C6 C5 C4 C3 . . 0.7(14)
C8 C13 C12 C11 . . -1.6(12)
C6 C1 C2 C3 . . -0.9(10)
C7 C1 C2 C3 . . -176.2(6)
C9 C10 C11 C12 . . -1.6(12)
C13 C12 C11 C10 . . 3.3(13)
C5 C4 C3 C2 . . -2.9(13)
C1 C2 C3 C4 . . 3.0(12)
