#------------------------------------------------------------------------------
#$Date: 2016-02-21 02:03:34 +0200 (Sun, 21 Feb 2016) $
#$Revision: 176798 $
#$URL: svn://www.crystallography.net/cod/cif/2/23/28/2232824.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2232824
loop_
_publ_author_name
'Davis, Wade L.'
'Meijboom, Reinout'
_publ_section_title
;
 cis-Bis(benzyldiphenylphosphane-κP)dichloridoplatinum(II)
 dichloromethane sesquisolvate
;
_journal_coeditor_code           KP2365
_journal_issue                   12
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m1800
_journal_paper_doi               10.1107/S1600536811049269
_journal_volume                  67
_journal_year                    2011
_chemical_formula_iupac          '[Pt Cl2 (C19 H17 P)2]2, 3C H2 Cl2'
_chemical_formula_moiety         '2(C38 H34 Cl2 P2 Pt), 3(C H2 Cl2)'
_chemical_formula_sum            'C79 H74 Cl10 P4 Pt2'
_chemical_formula_weight         1891.92
_chemical_name_systematic
;
cis-Bis(benzyldiphenylphosphane-κP)dichloridoplatinum(II)
dichloromethane sesquisolvate
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           'WinGX routine CIF_UPDATE'
_cell_angle_alpha                108.079(2)
_cell_angle_beta                 100.438(2)
_cell_angle_gamma                99.438(2)
_cell_formula_units_Z            2
_cell_length_a                   11.4087(9)
_cell_length_b                   18.6187(14)
_cell_length_c                   19.3802(15)
_cell_measurement_reflns_used    9569
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      28.42
_cell_measurement_theta_min      2.29
_cell_volume                     3740.4(5)
_computing_cell_refinement       'SAINT (Bruker 2008)'
_computing_data_collection       'APEX2 (Bruker 2010)'
_computing_data_reduction        'SAINT (Bruker 2008)'
_computing_molecular_graphics    'DIAMOND (Brandenburg & Putz, 2005)'
_computing_publication_material
'publCIF (Westrip, 2010) and WinGX (Farrugia, 1999)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SIR97 (Altomare, et al., 1999)'
_diffrn_ambient_temperature      100(2)
_diffrn_detector_area_resol_mean 8.4
_diffrn_measured_fraction_theta_full 0.993
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device_type  'Bruker APEX DUO 4K CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.029
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       24
_diffrn_reflns_limit_k_min       -24
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_number            101998
_diffrn_reflns_theta_full        28.43
_diffrn_reflns_theta_max         28.43
_diffrn_reflns_theta_min         1.14
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    4.223
_exptl_absorpt_correction_T_max  0.5514
_exptl_absorpt_correction_T_min  0.3952
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
(SADABS; Bruker, 2008)
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.68
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       cuboid
_exptl_crystal_F_000             1867.5
_exptl_crystal_size_max          0.27
_exptl_crystal_size_mid          0.22
_exptl_crystal_size_min          0.16
_refine_diff_density_max         1.595
_refine_diff_density_min         -1.552
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.953
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     866
_refine_ls_number_reflns         18701
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      0.957
_refine_ls_R_factor_all          0.0216
_refine_ls_R_factor_gt           0.0196
_refine_ls_shift/su_max          0.011
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0192P)²+8.2100P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0471
_refine_ls_wR_factor_ref         0.0486
_reflns_number_gt                17589
_reflns_number_total             18701
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            kp2365.cif
_cod_data_source_block           I
_cod_database_code               2232824
_cod_database_fobs_code          2232824
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_disorder_assembly
_atom_site_disorder_group
Cl Cl5 0.09600(7) 0.53139(4) 0.11524(5) 0.04068(16) Uani d . 1 1 . .
Cl Cl6 0.16152(6) 0.44051(5) 0.20840(4) 0.03724(15) Uani d . 1 1 . .
C C1 0.0417(2) 0.47117(15) 0.16229(16) 0.0291(5) Uani d . 1 1 . .
H H1A -0.0202 0.4250 0.1258 0.035 Uiso calc R 1 1 . .
H H1B 0.0012 0.4997 0.1995 0.035 Uiso calc R 1 1 . .
Pt Pt2 0.426409(6) 0.842345(4) 1.116009(4) 0.01044(2) Uani d . 1 1 . .
Cl Cl3 0.52446(5) 0.90607(3) 1.24390(3) 0.02036(10) Uani d . 1 1 . .
Cl Cl4 0.31192(5) 0.93912(3) 1.13021(3) 0.01753(9) Uani d . 1 1 . .
P P3 0.30995(5) 0.78101(3) 0.99824(3) 0.01162(9) Uani d . 1 1 . .
P P4 0.56353(5) 0.76804(3) 1.11485(3) 0.01164(9) Uani d . 1 1 . .
C C311 0.07713(19) 0.74922(12) 1.03150(12) 0.0163(4) Uani d . 1 1 . .
C C312 0.1177(2) 0.76454(12) 1.10846(12) 0.0172(4) Uani d . 1 1 . .
H H31 0.1929 0.8011 1.1360 0.021 Uiso calc R 1 1 . .
C C313 0.0491(2) 0.72681(13) 1.14505(13) 0.0205(4) Uani d . 1 1 . .
H H31A 0.0782 0.7371 1.1971 0.025 Uiso calc R 1 1 . .
C C314 -0.0615(2) 0.67420(13) 1.10544(15) 0.0243(5) Uani d . 1 1 . .
H H31B -0.1083 0.6484 1.1303 0.029 Uiso calc R 1 1 . .
C C315 -0.1037(2) 0.65925(13) 1.02965(16) 0.0262(5) Uani d . 1 1 . .
H H31C -0.1799 0.6235 1.0027 0.031 Uiso calc R 1 1 . .
C C316 -0.0347(2) 0.69640(13) 0.99276(14) 0.0210(4) Uani d . 1 1 . .
H H31D -0.0641 0.6856 0.9406 0.025 Uiso calc R 1 1 . .
C C317 0.14923(19) 0.78890(13) 0.98994(12) 0.0170(4) Uani d . 1 1 . .
H H31F 0.1488 0.8447 1.0081 0.020 Uiso calc R 1 1 . .
H H31E 0.1059 0.7670 0.9362 0.020 Uiso calc R 1 1 . .
C C321 0.29161(18) 0.67630(11) 0.95580(11) 0.0135(4) Uani d . 1 1 . .
C C322 0.31064(19) 0.64179(12) 0.88477(12) 0.0160(4) Uani d . 1 1 . .
H H32 0.3380 0.6734 0.8580 0.019 Uiso calc R 1 1 . .
C C323 0.2896(2) 0.56132(13) 0.85327(13) 0.0191(4) Uani d . 1 1 . .
H H32A 0.3011 0.5381 0.8046 0.023 Uiso calc R 1 1 . .
C C324 0.2520(2) 0.51488(13) 0.89280(13) 0.0208(4) Uani d . 1 1 . .
H H32B 0.2388 0.4600 0.8714 0.025 Uiso calc R 1 1 . .
C C325 0.2336(2) 0.54840(13) 0.96345(13) 0.0197(4) Uani d . 1 1 . .
H H32C 0.2080 0.5165 0.9904 0.024 Uiso calc R 1 1 . .
C C326 0.25271(19) 0.62869(12) 0.99487(12) 0.0159(4) Uani d . 1 1 . .
H H32D 0.2393 0.6514 1.0431 0.019 Uiso calc R 1 1 . .
C C331 0.3570(2) 0.82443(12) 0.93283(11) 0.0146(4) Uani d . 1 1 . .
C C332 0.2896(2) 0.80125(13) 0.85824(12) 0.0197(4) Uani d . 1 1 . .
H H33 0.2155 0.7620 0.8406 0.024 Uiso calc R 1 1 . .
C C333 0.3310(2) 0.83555(14) 0.81013(13) 0.0242(5) Uani d . 1 1 . .
H H33A 0.2861 0.8187 0.7593 0.029 Uiso calc R 1 1 . .
C C334 0.4375(2) 0.89418(14) 0.83576(14) 0.0243(5) Uani d . 1 1 . .
H H33B 0.4651 0.9176 0.8026 0.029 Uiso calc R 1 1 . .
C C335 0.5037(2) 0.91855(13) 0.90961(13) 0.0214(4) Uani d . 1 1 . .
H H33C 0.5762 0.9591 0.9273 0.026 Uiso calc R 1 1 . .
C C336 0.4639(2) 0.88362(12) 0.95798(12) 0.0169(4) Uani d . 1 1 . .
H H33D 0.5099 0.9002 1.0085 0.020 Uiso calc R 1 1 . .
C C411 0.77288(19) 0.88269(12) 1.12318(12) 0.0157(4) Uani d . 1 1 . .
C C412 0.72357(19) 0.94544(12) 1.11816(12) 0.0167(4) Uani d . 1 1 . .
H H41 0.6552 0.9547 1.1383 0.020 Uiso calc R 1 1 . .
C C413 0.7734(2) 0.99428(13) 1.08405(14) 0.0231(5) Uani d . 1 1 . .
H H41A 0.7383 1.0362 1.0802 0.028 Uiso calc R 1 1 . .
C C414 0.8743(3) 0.98196(16) 1.05555(19) 0.0355(6) Uani d . 1 1 . .
H H41B 0.9082 1.0150 1.0318 0.043 Uiso calc R 1 1 . .
C C415 0.9255(3) 0.92084(17) 1.0620(2) 0.0404(8) Uani d . 1 1 . .
H H41C 0.9958 0.9128 1.0436 0.048 Uiso calc R 1 1 . .
C C416 0.8746(2) 0.87141(14) 1.09529(16) 0.0275(5) Uani d . 1 1 . .
H H41D 0.9098 0.8295 1.0989 0.033 Uiso calc R 1 1 . .
C C417 0.72126(18) 0.82813(12) 1.15978(12) 0.0149(4) Uani d . 1 1 . .
H H41F 0.7238 0.8595 1.2119 0.018 Uiso calc R 1 1 . .
H H41E 0.7765 0.7927 1.1624 0.018 Uiso calc R 1 1 . .
C C421 0.54231(19) 0.70687(12) 1.17084(11) 0.0143(4) Uani d . 1 1 . .
C C422 0.6373(2) 0.67576(12) 1.19754(12) 0.0174(4) Uani d . 1 1 . .
H H42 0.7153 0.6879 1.1876 0.021 Uiso calc R 1 1 . .
C C423 0.6181(2) 0.62729(13) 1.23853(12) 0.0196(4) Uani d . 1 1 . .
H H42A 0.6833 0.6071 1.2572 0.024 Uiso calc R 1 1 . .
C C424 0.5041(2) 0.60853(13) 1.25217(13) 0.0216(4) Uani d . 1 1 . .
H H42B 0.4909 0.5751 1.2798 0.026 Uiso calc R 1 1 . .
C C425 0.4087(2) 0.63845(13) 1.22554(13) 0.0204(4) Uani d . 1 1 . .
H H42C 0.3303 0.6249 1.2344 0.024 Uiso calc R 1 1 . .
C C426 0.4283(2) 0.68829(13) 1.18575(12) 0.0171(4) Uani d . 1 1 . .
H H42D 0.3636 0.7097 1.1687 0.021 Uiso calc R 1 1 . .
C C431 0.57838(18) 0.70326(12) 1.02637(11) 0.0137(4) Uani d . 1 1 . .
C C432 0.55661(19) 0.62287(12) 1.00940(12) 0.0169(4) Uani d . 1 1 . .
H H43 0.5323 0.6009 1.0442 0.020 Uiso calc R 1 1 . .
C C433 0.5703(2) 0.57502(13) 0.94190(13) 0.0206(4) Uani d . 1 1 . .
H H43A 0.5544 0.5204 0.9305 0.025 Uiso calc R 1 1 . .
C C434 0.6071(2) 0.60651(14) 0.89103(13) 0.0237(5) Uani d . 1 1 . .
H H43B 0.6167 0.5735 0.8450 0.028 Uiso calc R 1 1 . .
C C435 0.6299(2) 0.68622(14) 0.90744(13) 0.0231(5) Uani d . 1 1 . .
H H43C 0.6557 0.7078 0.8727 0.028 Uiso calc R 1 1 . .
C C436 0.6151(2) 0.73483(13) 0.97460(12) 0.0182(4) Uani d . 1 1 . .
H H43D 0.6299 0.7894 0.9853 0.022 Uiso calc R 1 1 . .
Cl Cl8A 0.0990(5) 1.1023(2) 0.24154(15) 0.0967(9) Uani d P 0.413(2) 1 A 1
Cl Cl7 0.11313(11) 1.18247(7) 0.14127(7) 0.0696(3) Uani d . 1 1 A .
Cl Cl8B 0.2143(3) 1.12252(14) 0.25605(10) 0.0967(9) Uani d P 0.587(2) 1 A 2
C C2 0.1885(5) 1.1177(3) 0.1689(3) 0.0803(16) Uani d . 1 1 . .
H H2AB 0.2769 1.1412 0.1923 0.096 Uiso calc PR 0.413(2) 1 A 1
H H2AA 0.1782 1.0688 0.1268 0.096 Uiso calc PR 0.413(2) 1 A 1
H H2BC 0.1405 1.0645 0.1376 0.096 Uiso calc PR 0.587(2) 1 A 2
H H2BD 0.2688 1.1240 0.1560 0.096 Uiso calc PR 0.587(2) 1 A 2
Pt Pt1 -0.034074(7) 0.681952(4) 0.411236(4) 0.01360(2) Uani d . 1 1 . .
Cl Cl1 -0.05791(5) 0.62306(3) 0.28114(3) 0.02298(11) Uani d . 1 1 . .
Cl Cl2 -0.21334(5) 0.58974(3) 0.39871(3) 0.02022(10) Uani d . 1 1 . .
P P1 0.15125(5) 0.75067(3) 0.41467(3) 0.01512(10) Uani d . 1 1 . .
P P2 -0.04173(5) 0.74042(3) 0.52993(3) 0.01434(10) Uani d . 1 1 . .
C C111 0.2781(2) 0.62945(13) 0.39782(14) 0.0221(5) Uani d . 1 1 . .
C C112 0.1958(2) 0.56482(13) 0.39696(14) 0.0233(5) Uani d . 1 1 . .
H H11 0.1121 0.5538 0.3712 0.028 Uiso calc R 1 1 . .
C C113 0.2349(2) 0.51629(15) 0.43345(16) 0.0300(5) Uani d . 1 1 . .
H H11A 0.1780 0.4725 0.4328 0.036 Uiso calc R 1 1 . .
C C114 0.3570(3) 0.53179(17) 0.4708(2) 0.0416(7) Uani d . 1 1 . .
H H11B 0.3837 0.4993 0.4967 0.050 Uiso calc R 1 1 . .
C C115 0.4403(3) 0.59498(18) 0.4704(2) 0.0448(8) Uani d . 1 1 . .
H H11C 0.5243 0.6049 0.4951 0.054 Uiso calc R 1 1 . .
C C116 0.4014(2) 0.64370(15) 0.43417(17) 0.0312(6) Uani d . 1 1 . .
H H11D 0.4588 0.6868 0.4341 0.037 Uiso calc R 1 1 . .
C C117 0.2362(2) 0.68539(13) 0.36231(13) 0.0200(4) Uani d . 1 1 . .
H H11E 0.1832 0.6550 0.3116 0.024 Uiso calc R 1 1 . .
H H11F 0.3091 0.7177 0.3564 0.024 Uiso calc R 1 1 . .
C C121 0.26497(19) 0.80155(13) 0.50346(12) 0.0169(4) Uani d . 1 1 . .
C C122 0.2966(2) 0.75976(14) 0.55022(13) 0.0220(4) Uani d . 1 1 . .
H H12 0.2523 0.7077 0.5379 0.026 Uiso calc R 1 1 . .
C C123 0.3921(2) 0.79383(16) 0.61437(14) 0.0271(5) Uani d . 1 1 . .
H H12A 0.4132 0.7649 0.6455 0.032 Uiso calc R 1 1 . .
C C124 0.4567(2) 0.86991(17) 0.63316(14) 0.0283(5) Uani d . 1 1 . .
H H12B 0.5226 0.8930 0.6768 0.034 Uiso calc R 1 1 . .
C C125 0.4248(2) 0.91219(15) 0.58819(14) 0.0248(5) Uani d . 1 1 . .
H H12C 0.4684 0.9646 0.6015 0.030 Uiso calc R 1 1 . .
C C126 0.3296(2) 0.87859(13) 0.52366(13) 0.0197(4) Uani d . 1 1 . .
H H12D 0.3085 0.9081 0.4932 0.024 Uiso calc R 1 1 . .
C C131 0.1427(2) 0.81863(12) 0.36458(12) 0.0167(4) Uani d . 1 1 . .
C C132 0.0304(2) 0.83561(13) 0.34178(12) 0.0182(4) Uani d . 1 1 . .
H H13 -0.0403 0.8132 0.3540 0.022 Uiso calc R 1 1 . .
C C133 0.0220(2) 0.88532(13) 0.30106(13) 0.0215(4) Uani d . 1 1 . .
H H13A -0.0543 0.8972 0.2861 0.026 Uiso calc R 1 1 . .
C C134 0.1248(2) 0.91756(14) 0.28222(13) 0.0238(5) Uani d . 1 1 . .
H H13B 0.1185 0.9512 0.2542 0.029 Uiso calc R 1 1 . .
C C135 0.2368(2) 0.90074(14) 0.30427(13) 0.0224(5) Uani d . 1 1 . .
H H13C 0.3071 0.9228 0.2914 0.027 Uiso calc R 1 1 . .
C C136 0.2457(2) 0.85163(13) 0.34508(12) 0.0195(4) Uani d . 1 1 . .
H H13D 0.3224 0.8402 0.3600 0.023 Uiso calc R 1 1 . .
C C211 -0.25526(19) 0.79796(13) 0.50304(13) 0.0176(4) Uani d . 1 1 . .
C C212 -0.2580(2) 0.87310(14) 0.54565(13) 0.0229(5) Uani d . 1 1 . .
H H21 -0.2222 0.8928 0.5981 0.027 Uiso calc R 1 1 . .
C C213 -0.3129(2) 0.91931(15) 0.51203(15) 0.0272(5) Uani d . 1 1 . .
H H21A -0.3142 0.9704 0.5415 0.033 Uiso calc R 1 1 . .
C C214 -0.3656(2) 0.89102(15) 0.43559(15) 0.0257(5) Uani d . 1 1 . .
H H21B -0.4039 0.9224 0.4128 0.031 Uiso calc R 1 1 . .
C C215 -0.3624(2) 0.81671(14) 0.39252(14) 0.0248(5) Uani d . 1 1 . .
H H21C -0.3977 0.7974 0.3401 0.030 Uiso calc R 1 1 . .
C C216 -0.3076(2) 0.77037(13) 0.42605(13) 0.0209(4) Uani d . 1 1 . .
H H21D -0.3057 0.7195 0.3963 0.025 Uiso calc R 1 1 . .
C C217 -0.1977(2) 0.74752(13) 0.54004(12) 0.0176(4) Uani d . 1 1 . .
H H21E -0.2516 0.6945 0.5189 0.021 Uiso calc R 1 1 . .
H H21F -0.1947 0.7680 0.5941 0.021 Uiso calc R 1 1 . .
C C221 0.0035(2) 0.68681(13) 0.59019(13) 0.0188(4) Uani d . 1 1 . .
C C222 0.0541(2) 0.62382(14) 0.56271(14) 0.0224(5) Uani d . 1 1 . .
H H22 0.0640 0.6096 0.5130 0.027 Uiso calc R 1 1 . .
C C223 0.0904(2) 0.58132(15) 0.60731(16) 0.0286(5) Uani d . 1 1 . .
H H22A 0.1260 0.5389 0.5883 0.034 Uiso calc R 1 1 . .
C C224 0.0741(2) 0.60135(16) 0.67949(16) 0.0311(6) Uani d . 1 1 . .
H H22B 0.0992 0.5728 0.7101 0.037 Uiso calc R 1 1 . .
C C225 0.0216(2) 0.66279(16) 0.70709(14) 0.0292(5) Uani d . 1 1 . .
H H22C 0.0097 0.6757 0.7564 0.035 Uiso calc R 1 1 . .
C C226 -0.0141(2) 0.70577(14) 0.66287(13) 0.0236(5) Uani d . 1 1 . .
H H22D -0.0502 0.7479 0.6820 0.028 Uiso calc R 1 1 . .
C C231 0.04475(19) 0.84080(12) 0.57503(12) 0.0152(4) Uani d . 1 1 . .
C C232 0.03151(19) 0.89170(12) 0.53567(12) 0.0171(4) Uani d . 1 1 . .
H H23 -0.0233 0.8737 0.4874 0.020 Uiso calc R 1 1 . .
C C233 0.0981(2) 0.96848(13) 0.56689(13) 0.0196(4) Uani d . 1 1 . .
H H23A 0.0890 1.0028 0.5400 0.023 Uiso calc R 1 1 . .
C C234 0.1780(2) 0.99501(13) 0.63740(13) 0.0211(4) Uani d . 1 1 . .
H H23B 0.2243 1.0474 0.6584 0.025 Uiso calc R 1 1 . .
C C235 0.1902(2) 0.94532(14) 0.67714(13) 0.0222(5) Uani d . 1 1 . .
H H23C 0.2441 0.9639 0.7257 0.027 Uiso calc R 1 1 . .
C C236 0.1241(2) 0.86841(14) 0.64629(12) 0.0205(4) Uani d . 1 1 . .
H H23D 0.1330 0.8345 0.6738 0.025 Uiso calc R 1 1 . .
Cl Cl 0.65614(15) 0.66456(15) 0.68851(11) 0.1016(7) Uani d P 0.754(3) 1 B 2
Cl Cl9B 0.4093(3) 0.6313(3) 0.7090(2) 0.0673(8) Uani d PD 0.561(5) 1 B 1
Cl Cl9A 0.4227(4) 0.6689(3) 0.7294(3) 0.0673(8) Uani d P 0.439(5) 1 B 2
Cl Cl0A 0.5980(5) 0.5947(5) 0.6825(4) 0.1016(7) Uani d PD 0.246(3) 1 B 1
C C3 0.4945(8) 0.5929(4) 0.6778(4) 0.147(4) Uani d D 1 1 . .
H H 0.4492 0.5477 0.6367 0.177 Uiso calc PR 0.246(3) 1 B 1
H H3A 0.4484 0.5661 0.6248 0.177 Uiso calc PR 0.754(3) 1 B 2
H H3B 0.5051 0.5543 0.7024 0.177 Uiso calc PR 0.754(3) 1 B 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0 0 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.006 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_publ_flag
Cl5 C1 Cl6 111.73(14) ?
Cl5 C1 H1A 109.3 ?
Cl6 C1 H1A 109.3 ?
Cl5 C1 H1B 109.3 ?
Cl6 C1 H1B 109.3 ?
H1A C1 H1B 107.9 ?
P2 Pt1 P1 99.22(2) ?
P2 Pt1 Cl1 170.89(2) ?
P1 Pt1 Cl1 86.95(2) ?
P2 Pt1 Cl2 87.33(2) ?
P1 Pt1 Cl2 169.39(2) ?
Cl1 Pt1 Cl2 87.59(2) ?
C121 P1 C131 107.25(10) ?
C121 P1 C117 101.08(10) ?
C131 P1 C117 101.70(10) ?
C121 P1 Pt1 120.48(7) ?
C131 P1 Pt1 113.76(7) ?
C117 P1 Pt1 110.26(8) ?
C231 P2 C221 108.18(10) ?
C231 P2 C217 102.33(10) ?
C221 P2 C217 102.96(10) ?
C231 P2 Pt1 115.95(7) ?
C221 P2 Pt1 112.65(8) ?
C217 P2 Pt1 113.53(7) ?
C112 C111 C116 119.1(2) ?
C112 C111 C117 121.4(2) ?
C116 C111 C117 119.4(2) ?
C113 C112 C111 120.6(2) ?
C113 C112 H11 119.7 ?
C111 C112 H11 119.7 ?
C114 C113 C112 119.9(2) ?
C114 C113 H11A 120.0 ?
C112 C113 H11A 120.0 ?
C113 C114 C115 119.8(3) ?
C113 C114 H11B 120.1 ?
C115 C114 H11B 120.1 ?
C116 C115 C114 120.3(3) ?
C116 C115 H11C 119.8 ?
C114 C115 H11C 119.8 ?
C115 C116 C111 120.2(2) ?
C115 C116 H11D 119.9 ?
C111 C116 H11D 119.9 ?
C111 C117 P1 115.25(16) ?
C111 C117 H11E 108.5 ?
P1 C117 H11E 108.5 ?
C111 C117 H11F 108.5 ?
P1 C117 H11F 108.5 ?
H11E C117 H11F 107.5 ?
C126 C121 C122 118.7(2) ?
C126 C121 P1 122.45(17) ?
C122 C121 P1 118.61(17) ?
C123 C122 C121 120.5(2) ?
C123 C122 H12 119.7 ?
C121 C122 H12 119.7 ?
C124 C123 C122 120.2(2) ?
C124 C123 H12A 119.9 ?
C122 C123 H12A 119.9 ?
C125 C124 C123 119.8(2) ?
C125 C124 H12B 120.1 ?
C123 C124 H12B 120.1 ?
C124 C125 C126 120.5(2) ?
C124 C125 H12C 119.7 ?
C126 C125 H12C 119.7 ?
C125 C126 C121 120.3(2) ?
C125 C126 H12D 119.9 ?
C121 C126 H12D 119.9 ?
C132 C131 C136 118.9(2) ?
C132 C131 P1 119.70(17) ?
C136 C131 P1 121.28(17) ?
C133 C132 C131 120.1(2) ?
C133 C132 H13 119.9 ?
C131 C132 H13 119.9 ?
C134 C133 C132 120.3(2) ?
C134 C133 H13A 119.9 ?
C132 C133 H13A 119.9 ?
C135 C134 C133 120.1(2) ?
C135 C134 H13B 120.0 ?
C133 C134 H13B 120.0 ?
C136 C135 C134 119.9(2) ?
C136 C135 H13C 120.1 ?
C134 C135 H13C 120.1 ?
C135 C136 C131 120.7(2) ?
C135 C136 H13D 119.6 ?
C131 C136 H13D 119.6 ?
C212 C211 C216 118.8(2) ?
C212 C211 C217 120.3(2) ?
C216 C211 C217 120.9(2) ?
C213 C212 C211 120.5(2) ?
C213 C212 H21 119.7 ?
C211 C212 H21 119.7 ?
C214 C213 C212 120.2(2) ?
C214 C213 H21A 119.9 ?
C212 C213 H21A 119.9 ?
C213 C214 C215 119.8(2) ?
C213 C214 H21B 120.1 ?
C215 C214 H21B 120.1 ?
C214 C215 C216 120.1(2) ?
C214 C215 H21C 120.0 ?
C216 C215 H21C 120.0 ?
C215 C216 C211 120.6(2) ?
C215 C216 H21D 119.7 ?
C211 C216 H21D 119.7 ?
C211 C217 P2 115.62(15) ?
C211 C217 H21E 108.4 ?
P2 C217 H21E 108.4 ?
C211 C217 H21F 108.4 ?
P2 C217 H21F 108.4 ?
H21E C217 H21F 107.4 ?
C222 C221 C226 119.0(2) ?
C222 C221 P2 119.04(18) ?
C226 C221 P2 121.89(18) ?
C221 C222 C223 120.8(2) ?
C221 C222 H22 119.6 ?
C223 C222 H22 119.6 ?
C224 C223 C222 119.6(3) ?
C224 C223 H22A 120.2 ?
C222 C223 H22A 120.2 ?
C225 C224 C223 120.3(2) ?
C225 C224 H22B 119.8 ?
C223 C224 H22B 119.8 ?
C224 C225 C226 120.3(2) ?
C224 C225 H22C 119.9 ?
C226 C225 H22C 119.9 ?
C225 C226 C221 120.0(2) ?
C225 C226 H22D 120.0 ?
C221 C226 H22D 120.0 ?
C236 C231 C232 119.2(2) ?
C236 C231 P2 122.74(17) ?
C232 C231 P2 118.03(16) ?
C233 C232 C231 120.2(2) ?
C233 C232 H23 119.9 ?
C231 C232 H23 119.9 ?
C234 C233 C232 120.0(2) ?
C234 C233 H23A 120.0 ?
C232 C233 H23A 120.0 ?
C235 C234 C233 120.1(2) ?
C235 C234 H23B 120.0 ?
C233 C234 H23B 120.0 ?
C234 C235 C236 120.3(2) ?
C234 C235 H23C 119.9 ?
C236 C235 H23C 119.9 ?
C235 C236 C231 120.2(2) ?
C235 C236 H23D 119.9 ?
C231 C236 H23D 119.9 ?
P3 Pt2 P4 99.115(19) y
P3 Pt2 Cl3 172.666(19) y
P4 Pt2 Cl3 85.919(19) ?
P3 Pt2 Cl4 88.952(19) ?
P4 Pt2 Cl4 169.871(19) ?
Cl3 Pt2 Cl4 86.653(19) y
C331 P3 C321 107.13(10) ?
C331 P3 C317 102.76(10) ?
C321 P3 C317 101.84(10) ?
C331 P3 Pt2 112.67(7) ?
C321 P3 Pt2 118.52(7) ?
C317 P3 Pt2 112.28(7) ?
C421 P4 C431 104.93(9) ?
C421 P4 C417 103.24(10) ?
C431 P4 C417 103.04(10) ?
C421 P4 Pt2 112.41(7) ?
C431 P4 Pt2 120.23(7) ?
C417 P4 Pt2 111.31(7) ?
C316 C311 C312 118.4(2) ?
C316 C311 C317 119.4(2) ?
C312 C311 C317 122.28(19) ?
C313 C312 C311 120.8(2) ?
C313 C312 H31 119.6 ?
C311 C312 H31 119.6 ?
C314 C313 C312 119.9(2) ?
C314 C313 H31A 120.0 ?
C312 C313 H31A 120.0 ?
C315 C314 C313 120.0(2) ?
C315 C314 H31B 120.0 ?
C313 C314 H31B 120.0 ?
C314 C315 C316 120.2(2) ?
C314 C315 H31C 119.9 ?
C316 C315 H31C 119.9 ?
C311 C316 C315 120.7(2) ?
C311 C316 H31D 119.7 ?
C315 C316 H31D 119.7 ?
C311 C317 P3 116.36(15) ?
C311 C317 H31F 108.2 ?
P3 C317 H31F 108.2 ?
C311 C317 H31E 108.2 ?
P3 C317 H31E 108.2 ?
H31F C317 H31E 107.4 ?
C322 C321 C326 119.04(19) ?
C322 C321 P3 122.43(16) ?
C326 C321 P3 118.49(16) ?
C323 C322 C321 120.3(2) ?
C323 C322 H32 119.9 ?
C321 C322 H32 119.9 ?
C324 C323 C322 120.1(2) ?
C324 C323 H32A 119.9 ?
C322 C323 H32A 119.9 ?
C325 C324 C323 120.2(2) ?
C325 C324 H32B 119.9 ?
C323 C324 H32B 119.9 ?
C324 C325 C326 120.1(2) ?
C324 C325 H32C 120.0 ?
C326 C325 H32C 120.0 ?
C325 C326 C321 120.3(2) ?
C325 C326 H32D 119.8 ?
C321 C326 H32D 119.8 ?
C336 C331 C332 118.88(19) ?
C336 C331 P3 118.63(16) ?
C332 C331 P3 122.48(17) ?
C333 C332 C331 120.1(2) ?
C333 C332 H33 120.0 ?
C331 C332 H33 120.0 ?
C334 C333 C332 120.4(2) ?
C334 C333 H33A 119.8 ?
C332 C333 H33A 119.8 ?
C335 C334 C333 120.0(2) ?
C335 C334 H33B 120.0 ?
C333 C334 H33B 120.0 ?
C334 C335 C336 120.0(2) ?
C334 C335 H33C 120.0 ?
C336 C335 H33C 120.0 ?
C335 C336 C331 120.6(2) ?
C335 C336 H33D 119.7 ?
C331 C336 H33D 119.7 ?
C416 C411 C412 118.7(2) ?
C416 C411 C417 118.89(19) ?
C412 C411 C417 122.35(19) ?
C413 C412 C411 120.7(2) ?
C413 C412 H41 119.6 ?
C411 C412 H41 119.6 ?
C414 C413 C412 120.1(2) ?
C414 C413 H41A 120.0 ?
C412 C413 H41A 120.0 ?
C413 C414 C415 119.4(2) ?
C413 C414 H41B 120.3 ?
C415 C414 H41B 120.3 ?
C416 C415 C414 120.4(2) ?
C416 C415 H41C 119.8 ?
C414 C415 H41C 119.8 ?
C411 C416 C415 120.6(2) ?
C411 C416 H41D 119.7 ?
C415 C416 H41D 119.7 ?
C411 C417 P4 117.30(15) ?
C411 C417 H41F 108.0 ?
P4 C417 H41F 108.0 ?
C411 C417 H41E 108.0 ?
P4 C417 H41E 108.0 ?
H41F C417 H41E 107.2 ?
C426 C421 C422 119.02(19) ?
C426 C421 P4 119.61(16) ?
C422 C421 P4 121.34(16) ?
C423 C422 C421 120.4(2) ?
C423 C422 H42 119.8 ?
C421 C422 H42 119.8 ?
C424 C423 C422 120.0(2) ?
C424 C423 H42A 120.0 ?
C422 C423 H42A 120.0 ?
C423 C424 C425 120.2(2) ?
C423 C424 H42B 119.9 ?
C425 C424 H42B 119.9 ?
C424 C425 C426 119.9(2) ?
C424 C425 H42C 120.0 ?
C426 C425 H42C 120.0 ?
C425 C426 C421 120.4(2) ?
C425 C426 H42D 119.8 ?
C421 C426 H42D 119.8 ?
C432 C431 C436 119.12(19) ?
C432 C431 P4 121.60(16) ?
C436 C431 P4 119.26(16) ?
C433 C432 C431 120.3(2) ?
C433 C432 H43 119.8 ?
C431 C432 H43 119.8 ?
C434 C433 C432 120.4(2) ?
C434 C433 H43A 119.8 ?
C432 C433 H43A 119.8 ?
C433 C434 C435 119.9(2) ?
C433 C434 H43B 120.1 ?
C435 C434 H43B 120.1 ?
C434 C435 C436 120.3(2) ?
C434 C435 H43C 119.8 ?
C436 C435 H43C 119.8 ?
C435 C436 C431 120.0(2) ?
C435 C436 H43D 120.0 ?
C431 C436 H43D 120.0 ?
Cl8B C2 Cl7 119.9(3) ?
Cl7 C2 Cl8A 98.7(2) ?
Cl8B C2 H2AB 72.4 ?
Cl7 C2 H2AB 112.0 ?
Cl8A C2 H2AB 112.0 ?
Cl8B C2 H2AA 122.6 ?
Cl7 C2 H2AA 112.0 ?
Cl8A C2 H2AA 112.0 ?
H2AB C2 H2AA 109.7 ?
Cl8B C2 H2BC 107.3 ?
Cl7 C2 H2BC 107.3 ?
Cl8A C2 H2BC 83.9 ?
H2AB C2 H2BC 134.0 ?
Cl8B C2 H2BD 107.3 ?
Cl7 C2 H2BD 107.3 ?
Cl8A C2 H2BD 146.8 ?
H2AA C2 H2BD 77.1 ?
H2BC C2 H2BD 106.9 ?
Cl0A C3 Cl9B 144.9(7) ?
Cl0A C3 Cl9A 128.6(6) ?
Cl9B C3 Cl 114.3(4) ?
Cl9A C3 Cl 97.2(3) ?
Cl0A C3 H 107.6 ?
Cl9B C3 H 107.6 ?
Cl9A C3 H 123.3 ?
Cl C3 H 128.7 ?
Cl0A C3 H3A 109.2 ?
Cl9B C3 H3A 101.8 ?
Cl9A C3 H3A 112.3 ?
Cl C3 H3A 112.3 ?
Cl0A C3 H3B 79.4 ?
Cl9B C3 H3B 105.4 ?
Cl9A C3 H3B 112.3 ?
Cl C3 H3B 112.3 ?
H C3 H3B 82.2 ?
H3A C3 H3B 109.9 ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_publ_flag
Cl5 C1 1.756(3) ?
Cl6 C1 1.767(3) ?
C1 H1A 0.9900 ?
C1 H1B 0.9900 ?
Pt1 P2 2.2436(6) y
Pt1 P1 2.2630(6) y
Pt1 Cl1 2.3602(6) y
Pt1 Cl2 2.3663(5) y
P1 C121 1.822(2) ?
P1 C131 1.822(2) ?
P1 C117 1.850(2) ?
P2 C231 1.816(2) ?
P2 C221 1.817(2) ?
P2 C217 1.846(2) ?
C111 C112 1.394(3) ?
C111 C116 1.395(3) ?
C111 C117 1.509(3) ?
C112 C113 1.389(4) ?
C112 H11 0.9500 ?
C113 C114 1.387(4) ?
C113 H11A 0.9500 ?
C114 C115 1.389(4) ?
C114 H11B 0.9500 ?
C115 C116 1.389(4) ?
C115 H11C 0.9500 ?
C116 H11D 0.9500 ?
C117 H11E 0.9900 ?
C117 H11F 0.9900 ?
C121 C126 1.398(3) ?
C121 C122 1.403(3) ?
C122 C123 1.389(3) ?
C122 H12 0.9500 ?
C123 C124 1.386(4) ?
C123 H12A 0.9500 ?
C124 C125 1.384(4) ?
C124 H12B 0.9500 ?
C125 C126 1.391(3) ?
C125 H12C 0.9500 ?
C126 H12D 0.9500 ?
C131 C132 1.396(3) ?
C131 C136 1.404(3) ?
C132 C133 1.394(3) ?
C132 H13 0.9500 ?
C133 C134 1.389(3) ?
C133 H13A 0.9500 ?
C134 C135 1.389(4) ?
C134 H13B 0.9500 ?
C135 C136 1.386(3) ?
C135 H13C 0.9500 ?
C136 H13D 0.9500 ?
C211 C212 1.395(3) ?
C211 C216 1.395(3) ?
C211 C217 1.509(3) ?
C212 C213 1.390(4) ?
C212 H21 0.9500 ?
C213 C214 1.387(4) ?
C213 H21A 0.9500 ?
C214 C215 1.387(3) ?
C214 H21B 0.9500 ?
C215 C216 1.391(3) ?
C215 H21C 0.9500 ?
C216 H21D 0.9500 ?
C217 H21E 0.9900 ?
C217 H21F 0.9900 ?
C221 C222 1.392(3) ?
C221 C226 1.402(3) ?
C222 C223 1.395(3) ?
C222 H22 0.9500 ?
C223 C224 1.387(4) ?
C223 H22A 0.9500 ?
C224 C225 1.384(4) ?
C224 H22B 0.9500 ?
C225 C226 1.395(3) ?
C225 H22C 0.9500 ?
C226 H22D 0.9500 ?
C231 C236 1.395(3) ?
C231 C232 1.399(3) ?
C232 C233 1.388(3) ?
C232 H23 0.9500 ?
C233 C234 1.387(3) ?
C233 H23A 0.9500 ?
C234 C235 1.384(3) ?
C234 H23B 0.9500 ?
C235 C236 1.388(3) ?
C235 H23C 0.9500 ?
C236 H23D 0.9500 ?
Pt2 P3 2.2505(5) y
Pt2 P4 2.2505(5) y
Pt2 Cl3 2.3531(5) y
Pt2 Cl4 2.3713(5) y
P3 C331 1.814(2) ?
P3 C321 1.825(2) ?
P3 C317 1.845(2) ?
P4 C421 1.818(2) ?
P4 C431 1.820(2) ?
P4 C417 1.848(2) ?
C311 C316 1.393(3) ?
C311 C312 1.401(3) ?
C311 C317 1.510(3) ?
C312 C313 1.392(3) ?
C312 H31 0.9500 ?
C313 C314 1.385(3) ?
C313 H31A 0.9500 ?
C314 C315 1.383(4) ?
C314 H31B 0.9500 ?
C315 C316 1.393(3) ?
C315 H31C 0.9500 ?
C316 H31D 0.9500 ?
C317 H31F 0.9900 ?
C317 H31E 0.9900 ?
C321 C322 1.400(3) ?
C321 C326 1.402(3) ?
C322 C323 1.392(3) ?
C322 H32 0.9500 ?
C323 C324 1.388(3) ?
C323 H32A 0.9500 ?
C324 C325 1.387(3) ?
C324 H32B 0.9500 ?
C325 C326 1.390(3) ?
C325 H32C 0.9500 ?
C326 H32D 0.9500 ?
C331 C336 1.396(3) ?
C331 C332 1.403(3) ?
C332 C333 1.390(3) ?
C332 H33 0.9500 ?
C333 C334 1.387(4) ?
C333 H33A 0.9500 ?
C334 C335 1.385(3) ?
C334 H33B 0.9500 ?
C335 C336 1.394(3) ?
C335 H33C 0.9500 ?
C336 H33D 0.9500 ?
C411 C416 1.386(3) ?
C411 C412 1.399(3) ?
C411 C417 1.511(3) ?
C412 C413 1.388(3) ?
C412 H41 0.9500 ?
C413 C414 1.386(4) ?
C413 H41A 0.9500 ?
C414 C415 1.390(4) ?
C414 H41B 0.9500 ?
C415 C416 1.389(4) ?
C415 H41C 0.9500 ?
C416 H41D 0.9500 ?
C417 H41F 0.9900 ?
C417 H41E 0.9900 ?
C421 C426 1.395(3) ?
C421 C422 1.402(3) ?
C422 C423 1.391(3) ?
C422 H42 0.9500 ?
C423 C424 1.385(3) ?
C423 H42A 0.9500 ?
C424 C425 1.391(3) ?
C424 H42B 0.9500 ?
C425 C426 1.394(3) ?
C425 H42C 0.9500 ?
C426 H42D 0.9500 ?
C431 C432 1.398(3) ?
C431 C436 1.402(3) ?
C432 C433 1.388(3) ?
C432 H43 0.9500 ?
C433 C434 1.385(3) ?
C433 H43A 0.9500 ?
C434 C435 1.386(3) ?
C434 H43B 0.9500 ?
C435 C436 1.393(3) ?
C435 H43C 0.9500 ?
C436 H43D 0.9500 ?
Cl8A C2 1.945(7) ?
Cl7 C2 1.747(4) ?
Cl8B C2 1.632(5) ?
C2 H2AB 0.9900 ?
C2 H2AA 0.9900 ?
C2 H2BC 0.9900 ?
C2 H2BD 0.9900 ?
Cl C3 2.026(8) ?
Cl9B C3 1.412(8) ?
Cl9B Cl0A 2.455(7) ?
Cl9A C3 1.862(9) ?
Cl0A C3 1.162(8) ?
C3 H 0.9500 ?
C3 H3A 0.9900 ?
C3 H3B 0.9900 ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
P4 Pt2 P3 C331 -94.06(8)
Cl4 Pt2 P3 C331 79.79(8)
P4 Pt2 P3 C321 32.13(8)
Cl4 Pt2 P3 C321 -154.03(8)
P4 Pt2 P3 C317 150.49(8)
Cl4 Pt2 P3 C317 -35.67(8)
P3 Pt2 P4 C421 -108.12(7)
Cl3 Pt2 P4 C421 66.51(8)
Cl4 Pt2 P4 C421 109.44(12)
P3 Pt2 P4 C431 16.13(8)
Cl3 Pt2 P4 C431 -169.25(8)
Cl4 Pt2 P4 C431 -126.32(12)
P3 Pt2 P4 C417 136.63(7)
Cl3 Pt2 P4 C417 -48.74(7)
Cl4 Pt2 P4 C417 -5.82(14)
C316 C311 C312 C313 1.2(3)
C317 C311 C312 C313 -179.8(2)
C311 C312 C313 C314 -0.9(3)
C312 C313 C314 C315 0.0(3)
C313 C314 C315 C316 0.6(4)
C312 C311 C316 C315 -0.6(3)
C317 C311 C316 C315 -179.6(2)
C314 C315 C316 C311 -0.3(4)
C316 C311 C317 P3 -126.29(19)
C312 C311 C317 P3 54.8(3)
C331 P3 C317 C311 173.28(16)
C321 P3 C317 C311 62.41(18)
Pt2 P3 C317 C311 -65.40(17)
C331 P3 C321 C322 -1.0(2)
C317 P3 C321 C322 106.48(18)
Pt2 P3 C321 C322 -129.82(16)
C331 P3 C321 C326 -178.66(16)
C317 P3 C321 C326 -71.16(18)
Pt2 P3 C321 C326 52.54(18)
C326 C321 C322 C323 0.8(3)
P3 C321 C322 C323 -176.83(17)
C321 C322 C323 C324 -1.3(3)
C322 C323 C324 C325 0.8(3)
C323 C324 C325 C326 0.1(3)
C324 C325 C326 C321 -0.6(3)
C322 C321 C326 C325 0.1(3)
P3 C321 C326 C325 177.85(17)
C321 P3 C331 C336 -125.49(17)
C317 P3 C331 C336 127.65(17)
Pt2 P3 C331 C336 6.60(19)
C321 P3 C331 C332 55.1(2)
C317 P3 C331 C332 -51.8(2)
Pt2 P3 C331 C332 -172.83(16)
C336 C331 C332 C333 1.7(3)
P3 C331 C332 C333 -178.86(18)
C331 C332 C333 C334 -1.6(4)
C332 C333 C334 C335 0.4(4)
C333 C334 C335 C336 0.6(4)
C334 C335 C336 C331 -0.5(3)
C332 C331 C336 C335 -0.7(3)
P3 C331 C336 C335 179.86(17)
C416 C411 C412 C413 1.7(3)
C417 C411 C412 C413 -179.9(2)
C411 C412 C413 C414 -1.0(4)
C412 C413 C414 C415 -0.6(5)
C413 C414 C415 C416 1.4(5)
C412 C411 C416 C415 -0.9(4)
C417 C411 C416 C415 -179.3(3)
C414 C415 C416 C411 -0.7(5)
C416 C411 C417 P4 -116.9(2)
C412 C411 C417 P4 64.8(2)
C421 P4 C417 C411 175.69(16)
C431 P4 C417 C411 66.66(17)
Pt2 P4 C417 C411 -63.51(17)
C431 P4 C421 C426 -109.51(18)
C417 P4 C421 C426 142.88(17)
Pt2 P4 C421 C426 22.83(19)
C431 P4 C421 C422 68.46(19)
C417 P4 C421 C422 -39.16(19)
Pt2 P4 C421 C422 -159.21(15)
C426 C421 C422 C423 -0.2(3)
P4 C421 C422 C423 -178.19(17)
C421 C422 C423 C424 1.0(3)
C422 C423 C424 C425 -0.5(3)
C423 C424 C425 C426 -0.8(3)
C424 C425 C426 C421 1.6(3)
C422 C421 C426 C425 -1.1(3)
P4 C421 C426 C425 176.93(17)
C421 P4 C431 C432 8.6(2)
C417 P4 C431 C432 116.31(18)
Pt2 P4 C431 C432 -119.17(16)
C421 P4 C431 C436 -170.04(17)
C417 P4 C431 C436 -62.28(19)
Pt2 P4 C431 C436 62.23(19)
C436 C431 C432 C433 -0.5(3)
P4 C431 C432 C433 -179.09(17)
C431 C432 C433 C434 0.7(3)
C432 C433 C434 C435 -0.3(4)
C433 C434 C435 C436 -0.5(4)
C434 C435 C436 C431 0.7(4)
C432 C431 C436 C435 -0.2(3)
P4 C431 C436 C435 178.39(17)
P2 Pt1 P1 C121 22.16(9)
Cl1 Pt1 P1 C121 -164.58(9)
Cl2 Pt1 P1 C121 -105.45(13)
P2 Pt1 P1 C131 -107.28(8)
Cl1 Pt1 P1 C131 65.98(8)
Cl2 Pt1 P1 C131 125.11(12)
P2 Pt1 P1 C117 139.23(8)
Cl1 Pt1 P1 C117 -47.51(8)
Cl2 Pt1 P1 C117 11.62(14)
P1 Pt1 P2 C231 27.49(8)
Cl2 Pt1 P2 C231 -160.90(8)
P1 Pt1 P2 C221 -97.89(8)
Cl2 Pt1 P2 C221 73.71(8)
P1 Pt1 P2 C217 145.58(8)
Cl2 Pt1 P2 C217 -42.82(8)
C116 C111 C112 C113 1.7(4)
C117 C111 C112 C113 -176.5(2)
C111 C112 C113 C114 -0.3(4)
C112 C113 C114 C115 -1.2(5)
C113 C114 C115 C116 1.4(6)
C114 C115 C116 C111 0.0(5)
C112 C111 C116 C115 -1.5(4)
C117 C111 C116 C115 176.7(3)
C112 C111 C117 P1 73.8(3)
C116 C111 C117 P1 -104.4(2)
C121 P1 C117 C111 59.62(19)
C131 P1 C117 C111 170.05(17)
Pt1 P1 C117 C111 -68.94(18)
C131 P1 C121 C126 -0.6(2)
C117 P1 C121 C126 105.52(19)
Pt1 P1 C121 C126 -132.83(16)
C131 P1 C121 C122 -174.73(17)
C117 P1 C121 C122 -68.63(19)
Pt1 P1 C121 C122 53.0(2)
C126 C121 C122 C123 -1.4(3)
P1 C121 C122 C123 172.96(18)
C121 C122 C123 C124 0.5(4)
C122 C123 C124 C125 0.7(4)
C123 C124 C125 C126 -0.9(4)
C124 C125 C126 C121 0.0(4)
C122 C121 C126 C125 1.2(3)
P1 C121 C126 C125 -172.96(18)
C121 P1 C131 C132 -123.13(18)
C117 P1 C131 C132 131.22(18)
Pt1 P1 C131 C132 12.69(19)
C121 P1 C131 C136 60.0(2)
C117 P1 C131 C136 -45.6(2)
Pt1 P1 C131 C136 -164.15(15)
C136 C131 C132 C133 -0.7(3)
P1 C131 C132 C133 -177.66(17)
C131 C132 C133 C134 0.7(3)
C132 C133 C134 C135 -0.4(3)
C133 C134 C135 C136 0.1(4)
C134 C135 C136 C131 -0.1(3)
C132 C131 C136 C135 0.4(3)
P1 C131 C136 C135 177.31(17)
C216 C211 C212 C213 0.5(3)
C217 C211 C212 C213 -178.9(2)
C211 C212 C213 C214 0.1(4)
C212 C213 C214 C215 -0.7(4)
C213 C214 C215 C216 0.7(4)
C214 C215 C216 C211 -0.1(4)
C212 C211 C216 C215 -0.6(3)
C217 C211 C216 C215 178.9(2)
C212 C211 C217 P2 -101.4(2)
C216 C211 C217 P2 79.1(2)
C231 P2 C217 C211 60.85(18)
C221 P2 C217 C211 173.06(16)
Pt1 P2 C217 C211 -64.85(17)
C231 P2 C221 C222 -120.35(18)
C217 P2 C221 C222 131.82(18)
Pt1 P2 C221 C222 9.1(2)
C231 P2 C221 C226 61.3(2)
C217 P2 C221 C226 -46.5(2)
Pt1 P2 C221 C226 -169.15(17)
C226 C221 C222 C223 -1.9(3)
P2 C221 C222 C223 179.77(18)
C221 C222 C223 C224 1.0(4)
C222 C223 C224 C225 0.4(4)
C223 C224 C225 C226 -0.8(4)
C224 C225 C226 C221 -0.1(4)
C222 C221 C226 C225 1.4(3)
P2 C221 C226 C225 179.72(18)
C221 P2 C231 C236 -4.0(2)
C217 P2 C231 C236 104.22(19)
Pt1 P2 C231 C236 -131.67(17)
C221 P2 C231 C232 175.15(17)
C217 P2 C231 C232 -76.59(18)
Pt1 P2 C231 C232 47.52(19)
C236 C231 C232 C233 1.0(3)
P2 C231 C232 C233 -178.27(17)
C231 C232 C233 C234 -0.1(3)
C232 C233 C234 C235 -0.8(3)
C233 C234 C235 C236 1.0(4)
C234 C235 C236 C231 -0.1(4)
C232 C231 C236 C235 -0.8(3)
P2 C231 C236 C235 178.35(18)
Cl9B Cl0A C3 Cl9A 8.4(7)
Cl9B Cl0A C3 Cl 48.7(17)
Cl0A Cl9B C3 Cl9A -22.6(19)
Cl0A Cl9B C3 Cl -30.5(13)
