#------------------------------------------------------------------------------
#$Date: 2016-02-21 02:03:34 +0200 (Sun, 21 Feb 2016) $
#$Revision: 176798 $
#$URL: svn://www.crystallography.net/cod/cif/2/23/63/2236339.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2236339
loop_
_publ_author_name
'Yeh, Chun-Wei'
'Ho, Yuh-Wen'
'Lee, Hsun-Tsing'
'Wang, Ju-Chun'
'Suen, Maw-Cherng'
_publ_section_title
;
 Tetrakis[μ-1,3-bis(4,5-dihydro-1,3-oxazol-2-yl)benzene-κ²N:N']trisilver(I)
 tris(hexafluoridophosphate)
;
_journal_coeditor_code           HY2575
_journal_issue                   9
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m1170
_journal_paper_doi               10.1107/S1600536812034721
_journal_volume                  68
_journal_year                    2012
_chemical_formula_iupac          '[Ag3 (C12 H12 N2 O2)4] (P F6)3'
_chemical_formula_moiety         'C48 H48 Ag3 N8 O8 3+, 3(F6 P -)'
_chemical_formula_sum            'C48 H48 Ag3 F18 N8 O8 P3'
_chemical_formula_weight         1623.46
_chemical_name_systematic
;
Tetrakis[μ-1,3-bis(4,5-dihydro-1,3-oxazol-2-yl)benzene-
κ²N:N']trisilver(I) tris(hexafluoridophosphate)
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 116.014(7)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   22.7473(16)
_cell_length_b                   11.4521(19)
_cell_length_c                   24.1382(15)
_cell_measurement_reflns_used    36
_cell_measurement_temperature    298(2)
_cell_measurement_theta_max      12.53
_cell_measurement_theta_min      4.82
_cell_volume                     5651.0(11)
_computing_cell_refinement       'XSCANS (Siemens, 1995)'
_computing_data_collection       'XSCANS (Siemens, 1995)'
_computing_data_reduction        'XSCANS (Siemens, 1995)'
_computing_molecular_graphics    'DIAMOND (Brandenburg, 1999)'
_computing_publication_material  'SHELXTL (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      298(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Siemens P4 four-circle'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0200
_diffrn_reflns_av_sigmaI/netI    0.0316
_diffrn_reflns_limit_h_max       26
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_limit_l_min       -28
_diffrn_reflns_number            5107
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         1.99
_diffrn_standards_decay_%        2.03
_diffrn_standards_interval_count 297
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    1.234
_exptl_absorpt_correction_T_max  0.9642
_exptl_absorpt_correction_T_min  0.6343
_exptl_absorpt_correction_type   psi-scan
_exptl_absorpt_process_details   '(XSCANS; Siemens, 1995)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.908
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             3216
_exptl_crystal_size_max          0.60
_exptl_crystal_size_mid          0.40
_exptl_crystal_size_min          0.30
_refine_diff_density_max         1.017
_refine_diff_density_min         -0.809
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.009
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     425
_refine_ls_number_reflns         4976
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.009
_refine_ls_R_factor_all          0.0668
_refine_ls_R_factor_gt           0.0503
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0628P)²+34.3783P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1250
_refine_ls_wR_factor_ref         0.1366
_reflns_number_gt                3885
_reflns_number_total             4976
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            hy2575.cif
_cod_data_source_block           I
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               2236339
_cod_database_fobs_code          2236339
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_symmetry_multiplicity
Ag Ag1 0.5000 0.06276(6) 0.2500 0.0564(2) Uani d S 1 2
Ag Ag2 0.18074(2) 0.04964(5) 0.26872(2) 0.05790(18) Uani d . 1 1
O O11 0.31412(19) -0.1417(4) 0.19947(19) 0.0637(11) Uani d . 1 1
O O31 0.3068(2) -0.0441(4) 0.45572(19) 0.0675(12) Uani d . 1 1
O O41 0.3592(2) 0.2537(5) 0.08323(18) 0.0694(13) Uani d . 1 1
O O61 0.14979(18) 0.1693(4) 0.09064(16) 0.0532(9) Uani d . 1 1
N N11 0.4086(2) -0.0591(4) 0.2133(2) 0.0488(11) Uani d . 1 1
N N31 0.2312(2) 0.0070(4) 0.3628(2) 0.0507(11) Uani d . 1 1
N N41 0.4514(2) 0.1949(5) 0.1635(2) 0.0558(12) Uani d . 1 1
N N61 0.1478(2) 0.1039(4) 0.1765(2) 0.0491(11) Uani d . 1 1
C C11 0.3711(2) -0.0898(5) 0.2366(3) 0.0458(12) Uani d . 1 1
C C12 0.3785(3) -0.0977(6) 0.1487(3) 0.0580(15) Uani d . 1 1
H H12A 0.4034 -0.1606 0.1423 0.070 Uiso calc R 1 1
H H12B 0.3753 -0.0337 0.1212 0.070 Uiso calc R 1 1
C C13 0.3111(3) -0.1394(7) 0.1382(3) 0.0712(19) Uani d . 1 1
H H13A 0.2774 -0.0860 0.1116 0.085 Uiso calc R 1 1
H H13B 0.3021 -0.2166 0.1198 0.085 Uiso calc R 1 1
C C21 0.3827(3) -0.0752(5) 0.3012(3) 0.0465(12) Uani d . 1 1
C C22 0.3315(3) -0.0577(5) 0.3166(2) 0.0457(12) Uani d . 1 1
H H22A 0.2888 -0.0556 0.2856 0.055 Uiso calc R 1 1
C C23 0.3426(3) -0.0434(5) 0.3773(2) 0.0469(12) Uani d . 1 1
C C24 0.4070(3) -0.0470(6) 0.4234(3) 0.0657(17) Uani d . 1 1
H H24A 0.4155 -0.0356 0.4644 0.079 Uiso calc R 1 1
C C25 0.4578(3) -0.0674(6) 0.4080(3) 0.0710(19) Uani d . 1 1
H H25A 0.5003 -0.0719 0.4390 0.085 Uiso calc R 1 1
C C26 0.4465(3) -0.0810(6) 0.3481(3) 0.0639(17) Uani d . 1 1
H H26A 0.4813 -0.0942 0.3384 0.077 Uiso calc R 1 1
C C31 0.2900(3) -0.0254(5) 0.3960(2) 0.0506(13) Uani d . 1 1
C C32 0.1977(3) 0.0162(6) 0.4034(3) 0.0629(16) Uani d . 1 1
H H32A 0.1619 -0.0390 0.3911 0.075 Uiso calc R 1 1
H H32B 0.1809 0.0944 0.4023 0.075 Uiso calc R 1 1
C C33 0.2505(4) -0.0123(8) 0.4664(3) 0.080(2) Uani d . 1 1
H H33A 0.2603 0.0549 0.4936 0.096 Uiso calc R 1 1
H H33B 0.2374 -0.0768 0.4846 0.096 Uiso calc R 1 1
C C41 0.3914(3) 0.2206(5) 0.1427(2) 0.0464(12) Uani d . 1 1
C C42 0.4700(3) 0.2166(8) 0.1130(3) 0.081(2) Uani d . 1 1
H H42A 0.4845 0.1450 0.1013 0.098 Uiso calc R 1 1
H H42B 0.5049 0.2738 0.1252 0.098 Uiso calc R 1 1
C C43 0.4086(3) 0.2623(8) 0.0603(3) 0.080(2) Uani d . 1 1
H H43A 0.4142 0.3426 0.0508 0.096 Uiso calc R 1 1
H H43B 0.3968 0.2150 0.0237 0.096 Uiso calc R 1 1
C C51 0.3518(2) 0.2183(5) 0.1772(2) 0.0429(12) Uani d . 1 1
C C52 0.2861(2) 0.1886(5) 0.1481(2) 0.0430(12) Uani d . 1 1
H H52A 0.2663 0.1709 0.1062 0.052 Uiso calc R 1 1
C C53 0.2499(2) 0.1855(4) 0.1822(2) 0.0407(11) Uani d . 1 1
C C54 0.2793(3) 0.2170(5) 0.2441(2) 0.0469(13) Uani d . 1 1
H H54A 0.2550 0.2162 0.2667 0.056 Uiso calc R 1 1
C C55 0.3442(3) 0.2492(5) 0.2721(3) 0.0516(14) Uani d . 1 1
H H55A 0.3635 0.2712 0.3134 0.062 Uiso calc R 1 1
C C56 0.3809(3) 0.2492(5) 0.2392(3) 0.0495(13) Uani d . 1 1
H H56A 0.4249 0.2697 0.2584 0.059 Uiso calc R 1 1
C C61 0.1804(2) 0.1498(5) 0.1510(2) 0.0427(12) Uani d . 1 1
C C62 0.0795(3) 0.0839(7) 0.1278(3) 0.0641(18) Uani d . 1 1
H H62A 0.0479 0.1267 0.1368 0.077 Uiso calc R 1 1
H H62B 0.0684 0.0015 0.1238 0.077 Uiso calc R 1 1
C C63 0.0821(3) 0.1300(6) 0.0701(3) 0.0555(14) Uani d . 1 1
H H63A 0.0713 0.0690 0.0393 0.067 Uiso calc R 1 1
H H63B 0.0518 0.1943 0.0527 0.067 Uiso calc R 1 1
P P1 0.5000 0.4236(2) 0.7500 0.0619(6) Uani d S 1 2
F F1 0.5316(14) 0.3242(15) 0.7277(12) 0.136(9) Uani d P 0.50 1
F F2 0.4658(10) 0.5162(10) 0.7741(9) 0.102(4) Uani d P 0.50 1
F F3 0.5624(8) 0.503(2) 0.7726(12) 0.172(9) Uani d P 0.50 1
F F4 0.4740(10) 0.490(2) 0.6891(7) 0.151(6) Uani d P 0.50 1
F F5 0.5275(10) 0.3615(19) 0.8141(7) 0.135(5) Uani d P 0.50 1
F F6 0.4354(9) 0.3566(19) 0.7311(13) 0.156(8) Uani d P 0.50 1
P P2 0.12182(9) 0.19994(18) 0.52246(10) 0.0733(5) Uani d . 1 1
F F7 0.0734(4) 0.1210(9) 0.4738(4) 0.231(5) Uani d . 1 1
F F8 0.0936(4) 0.2993(9) 0.4800(5) 0.241(6) Uani d . 1 1
F F9 0.1540(4) 0.1000(7) 0.5635(6) 0.266(7) Uani d . 1 1
F F10 0.0687(4) 0.2167(15) 0.5419(5) 0.290(8) Uani d . 1 1
F F11 0.1701(3) 0.2775(6) 0.5752(3) 0.156(3) Uani d . 1 1
F F12 0.1760(4) 0.1934(12) 0.5037(4) 0.248(6) Uani d . 1 1
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
N11 Ag1 N11 . 2_655 106.5(2)
N11 Ag1 N41 . 2_655 134.17(16)
N11 Ag1 N41 2_655 2_655 93.01(17)
N11 Ag1 N41 . . 93.01(17)
N11 Ag1 N41 2_655 . 134.17(16)
N41 Ag1 N41 2_655 . 102.5(3)
N31 Ag2 N61 . . 169.03(17)
C11 O11 C13 . . 105.7(4)
C31 O31 C33 . . 107.0(5)
C41 O41 C43 . . 105.9(5)
C61 O61 C63 . . 106.7(4)
C11 N11 C12 . . 107.2(4)
C11 N11 Ag1 . . 131.5(4)
C12 N11 Ag1 . . 120.5(3)
C31 N31 C32 . . 107.7(5)
C31 N31 Ag2 . . 132.2(4)
C32 N31 Ag2 . . 120.1(4)
C41 N41 C42 . . 106.4(5)
C41 N41 Ag1 . . 119.6(4)
C42 N41 Ag1 . . 129.0(4)
C61 N61 C62 . . 107.9(4)
C61 N61 Ag2 . . 128.5(4)
C62 N61 Ag2 . . 123.4(3)
N11 C11 O11 . . 118.0(5)
N11 C11 C21 . . 126.8(5)
O11 C11 C21 . . 115.2(5)
N11 C12 C13 . . 103.9(5)
N11 C12 H12A . . 111.0
C13 C12 H12A . . 111.0
N11 C12 H12B . . 111.0
C13 C12 H12B . . 111.0
H12A C12 H12B . . 109.0
O11 C13 C12 . . 104.0(5)
O11 C13 H13A . . 111.0
C12 C13 H13A . . 111.0
O11 C13 H13B . . 111.0
C12 C13 H13B . . 111.0
H13A C13 H13B . . 109.0
C22 C21 C26 . . 119.2(6)
C22 C21 C11 . . 121.3(5)
C26 C21 C11 . . 119.5(5)
C23 C22 C21 . . 121.1(5)
C23 C22 H22A . . 119.4
C21 C22 H22A . . 119.4
C22 C23 C24 . . 118.8(6)
C22 C23 C31 . . 123.2(5)
C24 C23 C31 . . 118.0(5)
C25 C24 C23 . . 119.9(6)
C25 C24 H24A . . 120.0
C23 C24 H24A . . 120.0
C26 C25 C24 . . 121.0(6)
C26 C25 H25A . . 119.5
C24 C25 H25A . . 119.5
C25 C26 C21 . . 119.9(6)
C25 C26 H26A . . 120.0
C21 C26 H26A . . 120.0
N31 C31 O31 . . 116.8(5)
N31 C31 C23 . . 128.2(5)
O31 C31 C23 . . 115.0(5)
N31 C32 C33 . . 103.9(5)
N31 C32 H32A . . 111.0
C33 C32 H32A . . 111.0
N31 C32 H32B . . 111.0
C33 C32 H32B . . 111.0
H32A C32 H32B . . 109.0
O31 C33 C32 . . 104.3(5)
O31 C33 H33A . . 110.9
C32 C33 H33A . . 110.9
O31 C33 H33B . . 110.9
C32 C33 H33B . . 110.9
H33A C33 H33B . . 108.9
N41 C41 O41 . . 118.5(5)
N41 C41 C51 . . 126.3(5)
O41 C41 C51 . . 115.2(5)
N41 C42 C43 . . 105.0(5)
N41 C42 H42A . . 110.8
C43 C42 H42A . . 110.8
N41 C42 H42B . . 110.8
C43 C42 H42B . . 110.8
H42A C42 H42B . . 108.8
O41 C43 C42 . . 103.9(5)
O41 C43 H43A . . 111.0
C42 C43 H43A . . 111.0
O41 C43 H43B . . 111.0
C42 C43 H43B . . 111.0
H43A C43 H43B . . 109.0
C52 C51 C56 . . 120.5(5)
C52 C51 C41 . . 120.6(5)
C56 C51 C41 . . 118.9(5)
C51 C52 C53 . . 119.3(5)
C51 C52 H52A . . 120.3
C53 C52 H52A . . 120.3
C54 C53 C52 . . 119.8(5)
C54 C53 C61 . . 121.4(4)
C52 C53 C61 . . 118.8(5)
C55 C54 C53 . . 120.3(5)
C55 C54 H54A . . 119.9
C53 C54 H54A . . 119.9
C54 C55 C56 . . 120.3(5)
C54 C55 H55A . . 119.8
C56 C55 H55A . . 119.8
C55 C56 C51 . . 119.7(5)
C55 C56 H56A . . 120.1
C51 C56 H56A . . 120.1
N61 C61 O61 . . 117.7(5)
N61 C61 C53 . . 126.2(5)
O61 C61 C53 . . 116.1(4)
N61 C62 C63 . . 103.0(4)
N61 C62 H62A . . 111.2
C63 C62 H62A . . 111.2
N61 C62 H62B . . 111.2
C63 C62 H62B . . 111.2
H62A C62 H62B . . 109.1
O61 C63 C62 . . 104.7(4)
O61 C63 H63A . . 110.8
C62 C63 H63A . . 110.8
O61 C63 H63B . . 110.8
C62 C63 H63B . . 110.8
H63A C63 H63B . . 108.9
F4 P1 F4 2_656 . 120(2)
F4 P1 F6 2_656 . 116.9(11)
F4 P1 F6 . . 92.7(16)
F4 P1 F6 2_656 2_656 92.7(16)
F4 P1 F6 . 2_656 116.9(11)
F6 P1 F6 . 2_656 120.2(18)
F4 P1 F1 2_656 2_656 94.4(10)
F6 P1 F1 2_656 2_656 93.3(12)
F4 P1 F1 2_656 . 130.8(17)
F4 P1 F1 . . 94.4(10)
F6 P1 F1 . . 93.3(12)
F1 P1 F1 2_656 . 86.4(13)
F4 P1 F5 2_656 2_656 177.0(16)
F4 P1 F5 . 2_656 57.1(9)
F6 P1 F5 . 2_656 64.2(9)
F6 P1 F5 2_656 2_656 89.0(10)
F1 P1 F5 2_656 2_656 88.0(11)
F1 P1 F5 . 2_656 51.1(9)
F4 P1 F5 2_656 . 57.1(9)
F4 P1 F5 . . 177.0(17)
F6 P1 F5 . . 89.0(10)
F6 P1 F5 2_656 . 64.2(9)
F1 P1 F5 2_656 . 51.1(9)
F1 P1 F5 . . 88.0(11)
F5 P1 F5 2_656 . 125.9(18)
F4 P1 F3 2_656 . 57.7(9)
F4 P1 F3 . . 87.4(11)
F6 P1 F3 . . 173.3(12)
F6 P1 F3 2_656 . 65.4(11)
F1 P1 F3 2_656 . 141.7(17)
F1 P1 F3 . . 93.3(12)
F5 P1 F3 2_656 . 121.0(10)
F5 P1 F3 . . 90.6(16)
F4 P1 F3 2_656 2_656 87.4(11)
F4 P1 F3 . 2_656 57.7(9)
F6 P1 F3 . 2_656 65.4(11)
F6 P1 F3 2_656 2_656 173.3(12)
F1 P1 F3 2_656 2_656 93.3(12)
F1 P1 F3 . 2_656 141.7(17)
F5 P1 F3 2_656 2_656 90.6(16)
F5 P1 F3 . 2_656 121.0(10)
F3 P1 F3 . 2_656 109.4(18)
F4 P1 F2 2_656 . 49.6(8)
F4 P1 F2 . . 88.4(9)
F6 P1 F2 . . 83.2(11)
F6 P1 F2 2_656 . 142.3(15)
F1 P1 F2 2_656 . 89.3(8)
F1 P1 F2 . . 175.7(8)
F5 P1 F2 2_656 . 128.7(14)
F5 P1 F2 . . 89.3(8)
F3 P1 F2 . . 90.1(9)
F4 P1 F2 2_656 2_656 88.4(9)
F4 P1 F2 . 2_656 49.6(8)
F6 P1 F2 . 2_656 142.3(15)
F6 P1 F2 2_656 2_656 83.2(11)
F1 P1 F2 2_656 2_656 175.7(8)
F1 P1 F2 . 2_656 89.3(8)
F5 P1 F2 2_656 2_656 89.3(8)
F5 P1 F2 . 2_656 128.7(14)
F3 P1 F2 2_656 2_656 90.1(9)
F2 P1 F2 . 2_656 95.1(9)
F6 F1 F5 2_656 2_656 133(2)
F6 F1 P1 2_656 . 69.6(14)
F5 F1 P1 2_656 . 64.5(9)
F3 F2 F4 2_656 2_656 132.4(16)
F3 F2 P1 2_656 . 70.6(13)
F4 F2 P1 2_656 . 63.5(8)
F2 F3 F4 2_656 2_656 116.2(18)
F2 F3 P1 2_656 . 70.9(11)
F4 F3 P1 2_656 . 59.8(8)
F2 F3 F6 2_656 2_656 96(2)
F4 F3 F6 2_656 2_656 89(2)
P1 F3 F6 . 2_656 56.5(9)
F2 F4 F5 2_656 2_656 104.8(12)
F2 F4 F3 2_656 2_656 105.1(17)
F5 F4 F3 2_656 2_656 97.0(18)
F2 F4 P1 2_656 . 66.9(8)
F5 F4 P1 2_656 . 62.7(7)
F3 F4 P1 2_656 . 62.5(8)
F1 F5 F4 2_656 2_656 106.5(13)
F1 F5 P1 2_656 . 64.4(8)
F4 F5 P1 2_656 . 60.2(7)
F1 F5 F6 2_656 2_656 97.1(15)
F4 F5 F6 2_656 2_656 90.2(15)
P1 F5 F6 . 2_656 57.2(7)
F1 F6 P1 2_656 . 72.1(15)
F1 F6 F5 2_656 2_656 107(2)
P1 F6 F5 . 2_656 58.6(7)
F1 F6 F3 2_656 2_656 113(3)
P1 F6 F3 . 2_656 58.1(8)
F5 F6 F3 2_656 2_656 84.0(17)
F8 P2 F9 . . 175.8(7)
F8 P2 F12 . . 89.7(6)
F9 P2 F12 . . 86.1(7)
F8 P2 F10 . . 87.3(7)
F9 P2 F10 . . 96.8(8)
F12 P2 F10 . . 175.4(9)
F8 P2 F7 . . 88.6(6)
F9 P2 F7 . . 92.0(6)
F12 P2 F7 . . 98.8(6)
F10 P2 F7 . . 84.6(6)
F8 P2 F11 . . 93.7(6)
F9 P2 F11 . . 85.9(5)
F12 P2 F11 . . 84.0(5)
F10 P2 F11 . . 92.8(6)
F7 P2 F11 . . 176.4(6)
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_publ_flag
Ag1 N11 2.331(4) y
Ag1 N41 2.418(5) y
Ag2 N31 2.104(5) y
Ag2 N61 2.106(4) y
O11 C11 1.348(6) ?
O11 C13 1.450(7) ?
O31 C31 1.335(7) ?
O31 C33 1.460(8) ?
O41 C41 1.348(7) ?
O41 C43 1.457(7) ?
O61 C61 1.329(6) ?
O61 C63 1.467(7) ?
N11 C11 1.260(7) ?
N11 C12 1.469(7) ?
N31 C31 1.276(8) ?
N31 C32 1.485(7) ?
N41 C41 1.264(7) ?
N41 C42 1.478(7) ?
N61 C61 1.269(7) ?
N61 C62 1.498(7) ?
C11 C21 1.474(8) ?
C12 C13 1.517(8) ?
C12 H12A 0.9700 ?
C12 H12B 0.9700 ?
C13 H13A 0.9700 ?
C13 H13B 0.9700 ?
C21 C22 1.384(8) ?
C21 C26 1.396(8) ?
C22 C23 1.383(8) ?
C22 H22A 0.9300 ?
C23 C24 1.398(8) ?
C23 C31 1.469(8) ?
C24 C25 1.380(10) ?
C24 H24A 0.9300 ?
C25 C26 1.363(10) ?
C25 H25A 0.9300 ?
C26 H26A 0.9300 ?
C32 C33 1.504(10) ?
C32 H32A 0.9700 ?
C32 H32B 0.9700 ?
C33 H33A 0.9700 ?
C33 H33B 0.9700 ?
C41 C51 1.472(7) ?
C42 C43 1.511(10) ?
C42 H42A 0.9700 ?
C42 H42B 0.9700 ?
C43 H43A 0.9700 ?
C43 H43B 0.9700 ?
C51 C52 1.387(7) ?
C51 C56 1.391(7) ?
C52 C53 1.396(7) ?
C52 H52A 0.9300 ?
C53 C54 1.391(7) ?
C53 C61 1.479(7) ?
C54 C55 1.378(8) ?
C54 H54A 0.9300 ?
C55 C56 1.382(7) ?
C55 H55A 0.9300 ?
C56 H56A 0.9300 ?
C62 C63 1.515(8) ?
C62 H62A 0.9700 ?
C62 H62B 0.9700 ?
C63 H63A 0.9700 ?
C63 H63B 0.9700 ?
P1 F4 1.527(12) ?
P1 F6 1.539(16) ?
P1 F1 1.562(13) ?
P1 F5 1.564(11) ?
P1 F3 1.566(16) ?
P1 F2 1.570(11) ?
P2 F8 1.476(8) ?
P2 F9 1.481(7) ?
P2 F12 1.488(8) ?
P2 F10 1.490(7) ?
P2 F7 1.509(7) ?
P2 F11 1.546(6) ?
