#------------------------------------------------------------------------------
#$Date: 2016-02-21 02:03:34 +0200 (Sun, 21 Feb 2016) $
#$Revision: 176798 $
#$URL: svn://www.crystallography.net/cod/cif/2/23/70/2237003.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2237003
loop_
_publ_author_name
'Thames, Anthony T.'
'White, Frankie D.'
'Pham, Lam N.'
'Xiang, Kang Rui'
'Sykora, Richard E.'
_publ_section_title
;
 Tris(thiocyanato-κN)tris(triphenylphosphine
 oxide-κO)europium(III)--(nitrato-κ²O,O')bis(thiocyanato-κN)tris(triphenylphosphine
 oxide-κO)europium(III) (1/1)
;
_journal_coeditor_code           QM2089
_journal_issue                   12
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m1530
_journal_paper_doi               10.1107/S1600536812047472
_journal_volume                  68
_journal_year                    2012
_chemical_formula_iupac
'[Eu (N C S)3 (C18 H15 O P)3] [Eu (N C S)2 (N O3) (C18 H15 O P)3]'
_chemical_formula_moiety
'C56 H45 Eu N3 O6 P3 S2, C57 H45 Eu N3 O3 P3 S3'
_chemical_formula_sum            'C113 H90 Eu2 N6 O9 P6 S5'
_chemical_formula_weight         2325.95
_chemical_name_systematic
;
Tris(thiocyanato-κN)tris(triphenylphosphine
oxide-κO)europium(III)--
(nitrato-κ²O,O')bis(thiocyanato-
κN)tris(triphenylphosphine
oxide-κO)europium(III) (1/1)
;
_space_group_crystal_system      trigonal
_space_group_IT_number           146
_space_group_name_Hall           'R 3'
_space_group_name_H-M_alt        'R 3'
_symmetry_space_group_name_Hall  'R 3'
_symmetry_space_group_name_H-M   'R 3 :H'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method
;
Olex2 1.1
(compiled 2011.11.01 svn.r2039, GUI svn.r3906)
;
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                120.00
_cell_formula_units_Z            3
_cell_length_a                   20.3249(7)
_cell_length_b                   20.3249(7)
_cell_length_c                   22.3186(6)
_cell_measurement_reflns_used    5442
_cell_measurement_temperature    180(2)
_cell_measurement_theta_max      25.0325
_cell_measurement_theta_min      3.1888
_cell_volume                     7984.6(4)
_computing_cell_refinement
;
CrysAlis PRO (Agilent, 2012)
;
_computing_data_collection
;
CrysAlis PRO (Agilent, 2012)
;
_computing_data_reduction
;
CrysAlis PRO (Agilent, 2012)
;
_computing_molecular_graphics
;
OLEX2 (Dolomanov et al., 2009)
;
_computing_publication_material
;
publCIF (Westrip, 2010)
;
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      180(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Agilent Xcalibur Eos'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0517
_diffrn_reflns_limit_h_max       23
_diffrn_reflns_limit_h_min       -24
_diffrn_reflns_limit_k_max       24
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_number            15970
_diffrn_reflns_theta_full        25.09
_diffrn_reflns_theta_max         25.09
_diffrn_reflns_theta_min         3.20
_exptl_absorpt_coefficient_mu    1.416
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.89227
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
(CrysAlis PRO; Agilent, 2012)
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.451
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             3534
_exptl_crystal_size_max          0.118
_exptl_crystal_size_mid          0.072
_exptl_crystal_size_min          0.046
_refine_diff_density_max         1.303
_refine_diff_density_min         -0.896
_refine_ls_abs_structure_details 'Flack (1983), 3154 Friedel pairs'
_refine_ls_abs_structure_Flack   -0.045(9)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.020
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     439
_refine_ls_number_reflns         6325
_refine_ls_number_restraints     8
_refine_ls_restrained_S_all      1.020
_refine_ls_R_factor_all          0.0519
_refine_ls_R_factor_gt           0.0424
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0112P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0595
_refine_ls_wR_factor_ref         0.0653
_reflns_number_gt                5614
_reflns_number_total             6325
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            qm2089.cif
_cod_data_source_block           I
_cod_original_cell_volume        7984.7(4)
_cod_database_code               2237003
_cod_database_fobs_code          2237003
loop_
_space_group_symop_id
_space_group_symop_operation_xyz
1 'x, y, z'
2 '-y, x-y, z'
3 '-x+y, -x, z'
4 'x+2/3, y+1/3, z+1/3'
5 '-y+2/3, x-y+1/3, z+1/3'
6 '-x+y+2/3, -x+1/3, z+1/3'
7 'x+1/3, y+2/3, z+2/3'
8 '-y+1/3, x-y+2/3, z+2/3'
9 '-x+y+1/3, -x+2/3, z+2/3'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu Eu1 0.6667 0.3333 0.305072(13) 0.02675(13) Uani d S 1 3 . .
Eu Eu2 0.0000 0.0000 0.462118(16) 0.04265(17) Uani d S 1 3 . .
P P2 0.16058(9) 0.14280(10) 0.55807(6) 0.0392(4) Uani d . 1 1 . .
C C20 0.1572(3) 0.1238(3) 0.6370(2) 0.0325(13) Uani d . 1 1 A .
C C26 0.1639(3) 0.2324(3) 0.5478(2) 0.0422(15) Uani d . 1 1 A .
C C27 0.0969(4) 0.2320(4) 0.5345(2) 0.0556(18) Uani d . 1 1 . .
H H27 0.0511 0.1848 0.5302 0.067 Uiso calc R 1 1 A .
C C25 0.1888(3) 0.1809(3) 0.6797(2) 0.0433(15) Uani d . 1 1 . .
H H25 0.2129 0.2327 0.6680 0.052 Uiso calc R 1 1 A .
C C23 0.1489(3) 0.0872(3) 0.7568(2) 0.0476(16) Uani d . 1 1 . .
H H23 0.1458 0.0748 0.7981 0.057 Uiso calc R 1 1 A .
C C21 0.1214(3) 0.0488(3) 0.6551(2) 0.0416(15) Uani d . 1 1 . .
H H21 0.0993 0.0096 0.6259 0.050 Uiso calc R 1 1 A .
C C5 0.6419(4) 0.6382(4) 0.3299(3) 0.063(2) Uani d . 1 1 . .
H H5 0.6622 0.6894 0.3173 0.075 Uiso calc R 1 1 . .
C C7 0.6563(3) 0.5304(3) 0.3457(2) 0.0447(15) Uani d . 1 1 . .
H H7 0.6869 0.5072 0.3435 0.054 Uiso calc R 1 1 . .
C C22 0.1170(3) 0.0297(3) 0.7152(2) 0.0484(16) Uani d . 1 1 A .
H H22 0.0926 -0.0220 0.7274 0.058 Uiso calc R 1 1 . .
C C24 0.1848(3) 0.1616(3) 0.7400(2) 0.0538(17) Uani d . 1 1 A .
H H24 0.2071 0.2004 0.7694 0.065 Uiso calc R 1 1 . .
C C3 0.5402(3) 0.5249(4) 0.3722(2) 0.0508(16) Uani d . 1 1 . .
H H3 0.4900 0.4981 0.3879 0.061 Uiso calc R 1 1 . .
C C31 0.2310(4) 0.3011(4) 0.5537(2) 0.0543(18) Uani d . 1 1 . .
H H31 0.2775 0.3025 0.5619 0.065 Uiso calc R 1 1 A .
C C4 0.5701(4) 0.5993(4) 0.3524(3) 0.069(2) Uani d . 1 1 . .
H H4 0.5402 0.6232 0.3545 0.083 Uiso calc R 1 1 . .
C C32 0.2453(3) 0.1481(3) 0.5283(3) 0.0455(15) Uani d . 1 1 A .
C C28 0.0957(6) 0.2984(5) 0.5274(3) 0.076(3) Uani d . 1 1 A .
H H28 0.0494 0.2968 0.5175 0.091 Uiso calc R 1 1 . .
C C6 0.6848(4) 0.6037(4) 0.3256(2) 0.0566(19) Uani d . 1 1 . .
H H6 0.7343 0.6304 0.3088 0.068 Uiso calc R 1 1 . .
C C15 0.4249(3) 0.2996(3) 0.3298(2) 0.0411(14) Uani d . 1 1 . .
H H15 0.4606 0.2973 0.3037 0.049 Uiso calc R 1 1 . .
C C14 0.4488(3) 0.3405(3) 0.3818(2) 0.0339(13) Uani d . 1 1 . .
C C19 0.3959(3) 0.3451(3) 0.4193(2) 0.0471(16) Uani d . 1 1 . .
H H19 0.4122 0.3741 0.4552 0.057 Uiso calc R 1 1 . .
C C17 0.2956(4) 0.2656(4) 0.3514(3) 0.0572(18) Uani d . 1 1 . .
H H17 0.2434 0.2404 0.3405 0.069 Uiso calc R 1 1 . .
C C18 0.3194(3) 0.3069(4) 0.4038(3) 0.0521(17) Uani d . 1 1 . .
H H18 0.2834 0.3093 0.4294 0.063 Uiso calc R 1 1 . .
C C16 0.3476(4) 0.2612(3) 0.3151(3) 0.0507(17) Uani d . 1 1 . .
H H16 0.3309 0.2316 0.2796 0.061 Uiso calc R 1 1 . .
C C2 0.5837(3) 0.4902(3) 0.3689(2) 0.0341(13) Uani d . 1 1 . .
P P1 0.54959(10) 0.39503(10) 0.39594(7) 0.0340(4) Uani d . 1 1 . .
C C33 0.2450(4) 0.1274(4) 0.4703(3) 0.069(2) Uani d . 1 1 . .
H H33 0.2013 0.1138 0.4464 0.083 Uiso calc R 1 1 A .
C C35 0.3655(6) 0.1416(6) 0.4787(4) 0.106(3) Uani d . 1 1 . .
H H35 0.4063 0.1373 0.4622 0.127 Uiso calc R 1 1 A .
C C34 0.3056(5) 0.1254(5) 0.4453(4) 0.096(3) Uani d . 1 1 A .
H H34 0.3046 0.1126 0.4042 0.115 Uiso calc R 1 1 . .
C C36 0.3692(5) 0.1647(6) 0.5374(4) 0.128(4) Uani d . 1 1 A .
H H36 0.4139 0.1800 0.5603 0.153 Uiso calc R 1 1 . .
C C8 0.5630(3) 0.3996(3) 0.4755(2) 0.0345(13) Uani d . 1 1 . .
C C9 0.5823(3) 0.4644(3) 0.5082(2) 0.0465(16) Uani d . 1 1 . .
H H9 0.5902 0.5090 0.4882 0.056 Uiso calc R 1 1 . .
C C13 0.5536(4) 0.3365(4) 0.5059(3) 0.083(3) Uani d . 1 1 . .
H H13 0.5412 0.2913 0.4846 0.100 Uiso calc R 1 1 . .
C C12 0.5624(5) 0.3390(4) 0.5682(3) 0.089(3) Uani d . 1 1 . .
H H12 0.5555 0.2952 0.5889 0.107 Uiso calc R 1 1 . .
C C37 0.3063(4) 0.1655(5) 0.5630(3) 0.093(3) Uani d . 1 1 . .
H H37 0.3068 0.1781 0.6040 0.112 Uiso calc R 1 1 A .
C C11 0.5805(4) 0.4029(4) 0.5991(3) 0.060(2) Uani d . 1 1 . .
H H11 0.5862 0.4040 0.6414 0.072 Uiso calc R 1 1 . .
C C10 0.5904(4) 0.4652(4) 0.5695(2) 0.0555(17) Uani d . 1 1 . .
H H10 0.6031 0.5102 0.5912 0.067 Uiso calc R 1 1 . .
C C29 0.1603(7) 0.3662(5) 0.5344(3) 0.089(3) Uani d . 1 1 . .
H H29 0.1592 0.4122 0.5304 0.107 Uiso calc R 1 1 A .
C C30 0.2286(5) 0.3681(4) 0.5475(3) 0.072(2) Uani d . 1 1 A .
H H30 0.2739 0.4157 0.5522 0.086 Uiso calc R 1 1 . .
O O1 0.5906(3) 0.3592(3) 0.36468(18) 0.0356(12) Uani d . 1 1 . .
O O2 0.0922(3) 0.0804(3) 0.52650(18) 0.0436(13) Uani d . 1 1 A .
N N1 0.5587(3) 0.2656(4) 0.2408(2) 0.0473(17) Uani d D 1 1 . .
C C1 0.5031(4) 0.2346(4) 0.2139(2) 0.0405(16) Uani d D 1 1 . .
S S1 0.42411(10) 0.18996(11) 0.17744(7) 0.0675(6) Uani d D 1 1 . .
N N2 0.0419(7) 0.1088(7) 0.4014(5) 0.059(4) Uani d PD 0.667 1 A 1
C C38 0.0671(12) 0.1696(9) 0.3841(9) 0.065(3) Uani d PD 0.667 1 A 1
S S2 0.0997(3) 0.25559(18) 0.36159(19) 0.0701(11) Uani d PD 0.667 1 A 1
O O3 0.0028(11) 0.1221(9) 0.4189(6) 0.086(5) Uani d PD 0.333 1 A 2
O O4 0.0805(12) 0.1092(11) 0.3900(8) 0.086(5) Uani d PD 0.333 1 A 2
O O5 0.0886(13) 0.2223(11) 0.3588(10) 0.065(3) Uani d PD 0.333 1 A 2
N N3 0.0614(15) 0.1602(12) 0.3857(12) 0.065(3) Uani d PD 0.333 1 A 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
O1 Eu1 O1 2_655 3_665 89.68(16)
O1 Eu1 O1 2_655 . 89.68(16)
O1 Eu1 O1 3_665 . 89.68(16)
O1 Eu1 N1 3_665 2_655 95.6(2)
O1 Eu1 N1 2_655 2_655 87.14(19)
O1 Eu1 N1 . 2_655 173.8(2)
O1 Eu1 N1 2_655 . 95.6(2)
O1 Eu1 N1 3_665 . 173.8(2)
O1 Eu1 N1 2_655 3_665 173.8(2)
O1 Eu1 N1 . . 87.14(19)
O1 Eu1 N1 . 3_665 95.6(2)
O1 Eu1 N1 3_665 3_665 87.14(19)
N1 Eu1 N1 2_655 . 87.9(2)
N1 Eu1 N1 2_655 3_665 87.9(2)
N1 Eu1 N1 . 3_665 87.9(2)
O2 Eu2 O2 . 2 84.41(16)
O2 Eu2 O2 . 3 84.41(16)
O2 Eu2 O2 2 3 84.41(16)
O2 Eu2 N2 2 2 84.7(3)
O2 Eu2 N2 . 2 166.8(3)
O2 Eu2 N2 3 2 101.9(3)
O2 Eu2 N2 . . 84.7(3)
O2 Eu2 N2 2 . 101.9(3)
O2 Eu2 N2 . 3 101.9(3)
O2 Eu2 N2 3 . 166.8(3)
O2 Eu2 N2 3 3 84.7(3)
O2 Eu2 N2 2 3 166.8(3)
O2 Eu2 O3 2 3 161.7(4)
O2 Eu2 O3 3 3 86.1(4)
O2 Eu2 O3 . 3 79.1(4)
O2 Eu2 O3 3 . 161.7(3)
O2 Eu2 O3 2 . 79.1(4)
O2 Eu2 O3 . . 86.1(4)
O2 Eu2 O3 3 2 79.1(4)
O2 Eu2 O3 . 2 161.7(3)
O2 Eu2 O3 2 2 86.1(4)
O2 Eu2 O4 2 . 119.1(4)
O2 Eu2 O4 . . 80.5(5)
O2 Eu2 O4 3 . 150.2(5)
O2 Eu2 O4 3 2 119.1(4)
O2 Eu2 O4 2 2 80.5(5)
O2 Eu2 O4 3 3 80.5(5)
O2 Eu2 O4 . 2 150.2(5)
O2 Eu2 O4 2 3 150.2(5)
O2 Eu2 O4 . 3 119.1(4)
N2 Eu2 N2 . 3 90.3(4)
N2 Eu2 N2 2 3 90.3(4)
N2 Eu2 N2 2 . 90.3(4)
N2 Eu2 O3 . 3 84.5(5)
N2 Eu2 O3 2 3 112.6(5)
N2 Eu2 O3 . . 23.1(4)
N2 Eu2 O3 3 . 112.6(5)
N2 Eu2 O3 3 3 23.1(4)
N2 Eu2 O3 2 . 84.5(5)
N2 Eu2 O3 2 2 23.1(4)
N2 Eu2 O3 3 2 84.5(5)
N2 Eu2 O3 . 2 112.6(5)
N2 Eu2 O4 2 2 18.6(5)
N2 Eu2 O4 3 3 18.6(5)
N2 Eu2 O4 3 . 73.6(5)
N2 Eu2 O4 . . 18.6(5)
N2 Eu2 O4 3 2 98.4(5)
N2 Eu2 O4 . 3 98.4(5)
N2 Eu2 O4 2 3 73.6(5)
N2 Eu2 O4 . 2 73.6(5)
N2 Eu2 O4 2 . 98.4(5)
O3 Eu2 O3 2 3 107.4(4)
O3 Eu2 O3 . 3 107.4(4)
O3 Eu2 O3 2 . 107.4(4)
O4 Eu2 O3 3 . 117.8(5)
O4 Eu2 O3 . 2 117.8(5)
O4 Eu2 O3 . . 41.5(5)
O4 Eu2 O3 2 . 66.0(6)
O4 Eu2 O3 3 2 66.0(6)
O4 Eu2 O3 3 3 41.5(5)
O4 Eu2 O3 . 3 66.0(6)
O4 Eu2 O3 2 2 41.5(5)
O4 Eu2 O3 2 3 117.8(5)
O4 Eu2 O4 2 . 84.7(7)
O4 Eu2 O4 . 3 84.7(7)
O4 Eu2 O4 2 3 84.7(7)
C20 P2 C26 . . 108.7(2)
C20 P2 C32 . . 107.9(3)
C32 P2 C26 . . 110.0(3)
O2 P2 C20 . . 110.9(3)
O2 P2 C26 . . 110.1(3)
O2 P2 C32 . . 109.3(3)
C25 C20 P2 . . 122.8(4)
C21 C20 P2 . . 117.8(4)
C21 C20 C25 . . 119.4(4)
C27 C26 P2 . . 118.7(5)
C31 C26 P2 . . 121.8(5)
C31 C26 C27 . . 119.5(6)
C26 C27 H27 . . 119.4
C28 C27 C26 . . 121.3(7)
C28 C27 H27 . . 119.4
C20 C25 H25 . . 120.3
C20 C25 C24 . . 119.3(5)
C24 C25 H25 . . 120.3
C22 C23 H23 . . 119.3
C24 C23 H23 . . 119.3
C24 C23 C22 . . 121.4(5)
C20 C21 H21 . . 119.4
C20 C21 C22 . . 121.1(5)
C22 C21 H21 . . 119.4
C4 C5 H5 . . 120.0
C4 C5 C6 . . 120.0(6)
C6 C5 H5 . . 120.0
C6 C7 H7 . . 119.7
C6 C7 C2 . . 120.6(6)
C2 C7 H7 . . 119.7
C23 C22 C21 . . 118.5(5)
C23 C22 H22 . . 120.7
C21 C22 H22 . . 120.7
C25 C24 H24 . . 119.9
C23 C24 C25 . . 120.2(5)
C23 C24 H24 . . 119.9
C4 C3 H3 . . 120.2
C2 C3 H3 . . 120.2
C2 C3 C4 . . 119.7(6)
C26 C31 H31 . . 120.7
C26 C31 C30 . . 118.6(7)
C30 C31 H31 . . 120.7
C5 C4 C3 . . 120.6(7)
C5 C4 H4 . . 119.7
C3 C4 H4 . . 119.7
C33 C32 P2 . . 118.4(5)
C37 C32 P2 . . 122.1(5)
C37 C32 C33 . . 119.3(6)
C27 C28 H28 . . 119.9
C29 C28 C27 . . 120.1(9)
C29 C28 H28 . . 119.9
C5 C6 C7 . . 120.1(6)
C5 C6 H6 . . 119.9
C7 C6 H6 . . 119.9
C14 C15 H15 . . 120.1
C14 C15 C16 . . 119.7(5)
C16 C15 H15 . . 120.1
C15 C14 C19 . . 119.7(5)
C15 C14 P1 . . 118.1(4)
C19 C14 P1 . . 121.8(4)
C14 C19 H19 . . 120.2
C18 C19 C14 . . 119.6(5)
C18 C19 H19 . . 120.2
C18 C17 H17 . . 120.2
C16 C17 H17 . . 120.2
C16 C17 C18 . . 119.6(6)
C19 C18 H18 . . 119.8
C17 C18 C19 . . 120.4(5)
C17 C18 H18 . . 119.8
C15 C16 H16 . . 119.6
C17 C16 C15 . . 120.9(5)
C17 C16 H16 . . 119.6
C7 C2 C3 . . 119.0(5)
C7 C2 P1 . . 119.1(4)
C3 C2 P1 . . 121.9(4)
C2 P1 C14 . . 108.1(3)
C8 P1 C14 . . 107.6(2)
C8 P1 C2 . . 108.0(3)
O1 P1 C14 . . 110.5(3)
O1 P1 C2 . . 110.5(3)
O1 P1 C8 . . 111.9(3)
C32 C33 H33 . . 119.0
C32 C33 C34 . . 122.0(7)
C34 C33 H33 . . 119.0
C34 C35 H35 . . 119.8
C34 C35 C36 . . 120.4(8)
C36 C35 H35 . . 119.8
C33 C34 H34 . . 120.3
C35 C34 C33 . . 119.5(8)
C35 C34 H34 . . 120.3
C35 C36 H36 . . 120.2
C35 C36 C37 . . 119.6(8)
C37 C36 H36 . . 120.2
C9 C8 P1 . . 122.5(4)
C13 C8 P1 . . 119.6(4)
C13 C8 C9 . . 117.9(5)
C8 C9 H9 . . 119.6
C10 C9 C8 . . 120.9(5)
C10 C9 H9 . . 119.6
C8 C13 H13 . . 120.0
C8 C13 C12 . . 120.0(6)
C12 C13 H13 . . 120.0
C13 C12 H12 . . 119.6
C11 C12 C13 . . 120.9(6)
C11 C12 H12 . . 119.6
C32 C37 C36 . . 118.9(7)
C32 C37 H37 . . 120.5
C36 C37 H37 . . 120.5
C12 C11 H11 . . 120.3
C12 C11 C10 . . 119.5(6)
C10 C11 H11 . . 120.3
C9 C10 H10 . . 119.5
C11 C10 C9 . . 120.9(6)
C11 C10 H10 . . 119.5
C28 C29 H29 . . 120.2
C28 C29 C30 . . 119.7(8)
C30 C29 H29 . . 120.2
C31 C30 C29 . . 120.8(8)
C31 C30 H30 . . 119.6
C29 C30 H30 . . 119.6
P1 O1 Eu1 . . 165.8(3)
P2 O2 Eu2 . . 168.6(3)
C1 N1 Eu1 . . 173.5(6)
N1 C1 S1 . . 178.8(7)
C38 N2 Eu2 . . 164.6(14)
N2 C38 S2 . . 177(2)
N3 O3 Eu2 . . 110.8(14)
N3 O4 Eu2 . . 115.3(14)
O4 N3 O3 . . 92.0(17)
O5 N3 O3 . . 134(2)
O5 N3 O4 . . 134(2)
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
Eu1 O1 2_655 2.292(4)
Eu1 O1 3_665 2.292(4)
Eu1 O1 . 2.292(4)
Eu1 N1 2_655 2.397(6)
Eu1 N1 . 2.397(6)
Eu1 N1 3_665 2.397(6)
Eu2 O2 . 2.277(4)
Eu2 O2 2 2.277(4)
Eu2 O2 3 2.277(4)
Eu2 N2 2 2.359(12)
Eu2 N2 . 2.359(12)
Eu2 N2 3 2.359(12)
Eu2 O3 3 2.637(16)
Eu2 O3 . 2.637(16)
Eu2 O3 2 2.637(16)
Eu2 O4 3 2.562(17)
Eu2 O4 . 2.562(18)
Eu2 O4 2 2.562(17)
P2 C20 . 1.799(5)
P2 C26 . 1.803(6)
P2 C32 . 1.799(6)
P2 O2 . 1.508(5)
C20 C25 . 1.387(7)
C20 C21 . 1.381(7)
C26 C27 . 1.390(8)
C26 C31 . 1.387(8)
C27 H27 . 0.9500
C27 C28 . 1.371(9)
C25 H25 . 0.9500
C25 C24 . 1.391(6)
C23 H23 . 0.9500
C23 C22 . 1.375(7)
C23 C24 . 1.363(7)
C21 H21 . 0.9500
C21 C22 . 1.387(6)
C5 H5 . 0.9500
C5 C4 . 1.361(8)
C5 C6 . 1.369(8)
C7 H7 . 0.9500
C7 C6 . 1.376(7)
C7 C2 . 1.381(7)
C22 H22 . 0.9500
C24 H24 . 0.9500
C3 H3 . 0.9500
C3 C4 . 1.390(8)
C3 C2 . 1.384(7)
C31 H31 . 0.9500
C31 C30 . 1.393(9)
C4 H4 . 0.9500
C32 C33 . 1.360(7)
C32 C37 . 1.350(8)
C28 H28 . 0.9500
C28 C29 . 1.356(11)
C6 H6 . 0.9500
C15 H15 . 0.9500
C15 C14 . 1.368(7)
C15 C16 . 1.400(7)
C14 C19 . 1.403(7)
C14 P1 . 1.804(5)
C19 H19 . 0.9500
C19 C18 . 1.390(7)
C17 H17 . 0.9500
C17 C18 . 1.379(7)
C17 C16 . 1.369(7)
C18 H18 . 0.9500
C16 H16 . 0.9500
C2 P1 . 1.800(6)
P1 C8 . 1.791(5)
P1 O1 . 1.522(4)
C33 H33 . 0.9500
C33 C34 . 1.372(8)
C35 H35 . 0.9500
C35 C34 . 1.321(10)
C35 C36 . 1.381(10)
C34 H34 . 0.9500
C36 H36 . 0.9500
C36 C37 . 1.407(9)
C8 C9 . 1.381(7)
C8 C13 . 1.377(7)
C9 H9 . 0.9500
C9 C10 . 1.376(6)
C13 H13 . 0.9500
C13 C12 . 1.399(7)
C12 H12 . 0.9500
C12 C11 . 1.348(8)
C37 H37 . 0.9500
C11 H11 . 0.9500
C11 C10 . 1.353(8)
C10 H10 . 0.9500
C29 H29 . 0.9500
C29 C30 . 1.401(11)
C30 H30 . 0.9500
N1 C1 . 1.150(8)
C1 S1 . 1.615(7)
N2 C38 . 1.144(14)
C38 S2 . 1.608(13)
O3 N3 . 1.283(19)
O4 N3 . 1.280(19)
O5 N3 . 1.249(16)
