#------------------------------------------------------------------------------
#$Date: 2016-02-21 02:03:34 +0200 (Sun, 21 Feb 2016) $
#$Revision: 176798 $
#$URL: svn://www.crystallography.net/cod/cif/2/23/72/2237271.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2237271
loop_
_publ_author_name
'Ke, Fang'
'Wu, Wen'
_publ_section_title
;
 catena-Poly[μ₂-iodido-diiodidobis(μ₃-pyridine-2-thione-κ³S:S:S)(μ₂-pyridine-2-thione-κ²S:S)tricopper(I)]
;
_journal_coeditor_code           BH2469
_journal_issue                   2
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m87
_journal_paper_doi               10.1107/S1600536812052051
_journal_volume                  69
_journal_year                    2013
_chemical_formula_iupac          '[Cu3 I3 (C5 H5 N S)3]'
_chemical_formula_moiety         'C15 H15 Cu3 I3 N3 S3'
_chemical_formula_sum            'C15 H15 Cu3 I3 N3 S3'
_chemical_formula_weight         904.80
_chemical_name_systematic
;
catena-Poly[μ₂-iodido-diiodidobis(μ₃-pyridine-2-thione-
κ³S:S:S)(μ₂-pyridine-2-thione-
κ²S:S)tricopper(I)]
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL97
_cell_angle_alpha                105.956(2)
_cell_angle_beta                 100.088(3)
_cell_angle_gamma                109.377(3)
_cell_formula_units_Z            2
_cell_length_a                   10.0350(10)
_cell_length_b                   10.9220(11)
_cell_length_c                   12.2500(15)
_cell_measurement_reflns_used    3445
_cell_measurement_temperature    298(2)
_cell_measurement_theta_max      26.001
_cell_measurement_theta_min      2.238
_cell_volume                     1164.1(2)
_computing_cell_refinement       'SAINT (Siemens, 1996)'
_computing_data_collection       'SMART (Siemens, 1996)'
_computing_data_reduction        'SAINT (Siemens, 1996)'
_computing_molecular_graphics    'SHELXTL (Sheldrick, 2008)'
_computing_publication_material  'SHELXTL (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      298(2)
_diffrn_measured_fraction_theta_full 0.980
_diffrn_measured_fraction_theta_max 0.980
_diffrn_measurement_device_type  'Bruker SMART CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0276
_diffrn_reflns_av_sigmaI/netI    0.0509
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       10
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            6013
_diffrn_reflns_theta_full        25.01
_diffrn_reflns_theta_max         25.01
_diffrn_reflns_theta_min         1.81
_exptl_absorpt_coefficient_mu    6.970
_exptl_absorpt_correction_T_max  0.4212
_exptl_absorpt_correction_T_min  0.1670
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Sheldrick, 1996)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    2.581
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             840
_exptl_crystal_size_max          0.40
_exptl_crystal_size_mid          0.23
_exptl_crystal_size_min          0.15
_refine_diff_density_max         1.326
_refine_diff_density_min         -1.454
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.056
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_constraints    0
_refine_ls_number_parameters     244
_refine_ls_number_reflns         4009
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.056
_refine_ls_R_factor_all          0.0516
_refine_ls_R_factor_gt           0.0404
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0556P)²+2.5913P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1075
_refine_ls_wR_factor_ref         0.1154
_reflns_number_gt                3215
_reflns_number_total             4009
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            bh2469.cif
_cod_data_source_block           I
_cod_database_code               2237271
_cod_database_fobs_code          2237271
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_symmetry_multiplicity
Cu Cu1 0.48634(11) 0.50567(10) 0.61815(8) 0.0417(3) Uani d . 1 1
Cu Cu2 0.79614(11) 0.58824(10) 0.71789(8) 0.0432(3) Uani d . 1 1
Cu Cu3 0.14805(12) 0.65287(11) 0.57965(8) 0.0495(3) Uani d . 1 1
I I1 0.58333(6) 0.39571(5) 0.75952(5) 0.04314(17) Uani d . 1 1
I I2 0.95579(7) 0.79131(6) 0.91260(5) 0.0568(2) Uani d . 1 1
I I3 0.16049(6) 0.90228(5) 0.63917(5) 0.04906(18) Uani d . 1 1
N N1 0.1790(7) 0.0857(6) 0.3003(6) 0.0479(17) Uani d . 1 1
H H1 0.1089 0.1095 0.2766 0.057 Uiso calc R 1 1
N N2 1.0746(7) 0.3244(7) 0.6514(6) 0.0422(15) Uani d . 1 1
H H2 1.0476 0.2886 0.5751 0.051 Uiso calc R 1 1
N N3 0.3203(7) 0.7738(6) 0.8801(5) 0.0410(15) Uani d . 1 1
H H3 0.2341 0.7575 0.8377 0.049 Uiso calc R 1 1
S S1 0.3069(2) 0.35003(18) 0.43695(15) 0.0328(4) Uani d . 1 1
S S2 0.9240(2) 0.4776(2) 0.61847(16) 0.0403(5) Uani d . 1 1
S S3 0.3492(2) 0.6317(2) 0.67672(16) 0.0422(5) Uani d . 1 1
C C1 0.3003(8) 0.1836(7) 0.3837(6) 0.0325(16) Uani d . 1 1
C C2 0.4146(10) 0.1418(8) 0.4198(7) 0.047(2) Uani d . 1 1
H H2A 0.5022 0.2054 0.4778 0.057 Uiso calc R 1 1
C C3 0.3937(11) 0.0047(9) 0.3675(8) 0.055(2) Uani d . 1 1
H H3A 0.4690 -0.0231 0.3900 0.066 Uiso calc R 1 1
C C4 0.2641(11) -0.0914(8) 0.2828(8) 0.053(2) Uani d . 1 1
H H4 0.2506 -0.1836 0.2491 0.063 Uiso calc R 1 1
C C5 0.1579(11) -0.0491(8) 0.2500(9) 0.058(2) Uani d . 1 1
H H5 0.0695 -0.1122 0.1926 0.069 Uiso calc R 1 1
C C6 1.0204(8) 0.4156(8) 0.7040(6) 0.0360(16) Uani d . 1 1
C C7 1.0588(9) 0.4641(8) 0.8276(7) 0.0438(19) Uani d . 1 1
H H7 1.0206 0.5237 0.8674 0.053 Uiso calc R 1 1
C C8 1.1536(11) 0.4235(10) 0.8911(8) 0.061(3) Uani d . 1 1
H H8 1.1787 0.4547 0.9736 0.073 Uiso calc R 1 1
C C9 1.2119(11) 0.3342(11) 0.8293(9) 0.063(3) Uani d . 1 1
H H9 1.2795 0.3095 0.8705 0.075 Uiso calc R 1 1
C C10 1.1695(10) 0.2871(9) 0.7138(9) 0.055(2) Uani d . 1 1
H H10 1.2054 0.2260 0.6729 0.066 Uiso calc R 1 1
C C11 0.4100(8) 0.7287(7) 0.8249(6) 0.0334(16) Uani d . 1 1
C C12 0.5518(9) 0.7651(8) 0.8966(7) 0.045(2) Uani d . 1 1
H H12 0.6184 0.7385 0.8625 0.053 Uiso calc R 1 1
C C13 0.5946(11) 0.8381(9) 1.0143(8) 0.061(3) Uani d . 1 1
H H13 0.6904 0.8635 1.0603 0.074 Uiso calc R 1 1
C C14 0.4937(11) 0.8752(9) 1.0667(7) 0.056(2) Uani d . 1 1
H H14 0.5207 0.9219 1.1482 0.067 Uiso calc R 1 1
C C15 0.3594(11) 0.8436(9) 0.9995(7) 0.053(2) Uani d . 1 1
H H15 0.2922 0.8689 1.0337 0.064 Uiso calc R 1 1
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
I I -0.4742 1.8119 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
S3 Cu1 S1 . . 95.70(7)
S3 Cu1 S1 . 2_666 109.08(8)
S1 Cu1 S1 . 2_666 105.53(6)
S3 Cu1 I1 . . 118.52(7)
S1 Cu1 I1 . . 116.47(6)
S1 Cu1 I1 2_666 . 110.13(5)
S3 Cu1 Cu2 . . 126.14(6)
S1 Cu1 Cu2 . . 135.86(6)
S1 Cu1 Cu2 2_666 . 52.03(5)
I1 Cu1 Cu2 . . 58.89(3)
S3 Cu1 Cu1 . 2_666 110.90(7)
S1 Cu1 Cu1 . 2_666 54.69(6)
S1 Cu1 Cu1 2_666 2_666 50.84(5)
I1 Cu1 Cu1 . 2_666 130.56(5)
Cu2 Cu1 Cu1 . 2_666 93.24(5)
S2 Cu2 S1 . 2_666 97.69(7)
S2 Cu2 I2 . . 114.82(7)
S1 Cu2 I2 2_666 . 115.43(6)
S2 Cu2 I1 . . 107.63(7)
S1 Cu2 I1 2_666 . 110.49(6)
I2 Cu2 I1 . . 110.04(4)
S2 Cu2 Cu1 . . 120.62(6)
S1 Cu2 Cu1 2_666 . 55.70(5)
I2 Cu2 Cu1 . . 124.49(4)
I1 Cu2 Cu1 . . 55.59(3)
S3 Cu3 S2 . 2_666 110.21(7)
S3 Cu3 I3 . . 114.83(7)
S2 Cu3 I3 2_666 . 118.15(7)
S3 Cu3 S2 . 1_455 104.12(8)
S2 Cu3 S2 2_666 1_455 92.93(8)
I3 Cu3 S2 . 1_455 113.75(6)
Cu1 I1 Cu2 . . 65.52(3)
C1 N1 C5 . . 124.8(7)
C1 N1 H1 . . 117.6
C5 N1 H1 . . 117.6
C10 N2 C6 . . 122.8(7)
C10 N2 H2 . . 118.6
C6 N2 H2 . . 118.6
C11 N3 C15 . . 123.5(7)
C11 N3 H3 . . 118.3
C15 N3 H3 . . 118.3
C1 S1 Cu1 . . 117.6(3)
C1 S1 Cu2 . 2_666 111.4(2)
Cu1 S1 Cu2 . 2_666 125.91(8)
C1 S1 Cu1 . 2_666 104.9(3)
Cu1 S1 Cu1 . 2_666 74.47(6)
Cu2 S1 Cu1 2_666 2_666 72.26(6)
C6 S2 Cu3 . 2_666 112.1(3)
C6 S2 Cu2 . . 112.9(3)
Cu3 S2 Cu2 2_666 . 126.77(9)
C6 S2 Cu3 . 1_655 98.9(3)
Cu3 S2 Cu3 2_666 1_655 87.07(8)
Cu2 S2 Cu3 . 1_655 112.17(9)
C11 S3 Cu3 . . 112.4(3)
C11 S3 Cu1 . . 113.8(3)
Cu3 S3 Cu1 . . 133.81(9)
N1 C1 C2 . . 116.4(6)
N1 C1 S1 . . 118.1(5)
C2 C1 S1 . . 125.6(6)
C3 C2 C1 . . 118.9(8)
C3 C2 H2A . . 120.6
C1 C2 H2A . . 120.6
C4 C3 C2 . . 121.5(8)
C4 C3 H3A . . 119.3
C2 C3 H3A . . 119.3
C5 C4 C3 . . 118.5(7)
C5 C4 H4 . . 120.8
C3 C4 H4 . . 120.8
C4 C5 N1 . . 120.0(8)
C4 C5 H5 . . 120.0
N1 C5 H5 . . 120.0
N2 C6 C7 . . 117.0(7)
N2 C6 S2 . . 119.4(5)
C7 C6 S2 . . 123.3(6)
C8 C7 C6 . . 120.0(8)
C8 C7 H7 . . 120.0
C6 C7 H7 . . 120.0
C7 C8 C9 . . 119.3(8)
C7 C8 H8 . . 120.4
C9 C8 H8 . . 120.4
C10 C9 C8 . . 119.0(8)
C10 C9 H9 . . 120.5
C8 C9 H9 . . 120.5
C9 C10 N2 . . 121.9(8)
C9 C10 H10 . . 119.1
N2 C10 H10 . . 119.1
N3 C11 C12 . . 116.0(7)
N3 C11 S3 . . 120.9(6)
C12 C11 S3 . . 123.1(6)
C13 C12 C11 . . 121.5(8)
C13 C12 H12 . . 119.2
C11 C12 H12 . . 119.2
C12 C13 C14 . . 119.5(8)
C12 C13 H13 . . 120.3
C14 C13 H13 . . 120.3
C15 C14 C13 . . 119.7(8)
C15 C14 H14 . . 120.1
C13 C14 H14 . . 120.1
C14 C15 N3 . . 119.7(8)
C14 C15 H15 . . 120.1
N3 C15 H15 . . 120.1
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
Cu1 S3 . 2.315(2) y
Cu1 S1 . 2.356(2) y
Cu1 S1 2_666 2.480(2) y
Cu1 I1 . 2.5917(11) y
Cu1 Cu2 . 2.8590(14) y
Cu1 Cu1 2_666 2.928(2) y
Cu2 S2 . 2.315(2) y
Cu2 S1 2_666 2.367(2) y
Cu2 I2 . 2.5632(11) y
Cu2 I1 . 2.6896(12) y
Cu3 S3 . 2.273(2) y
Cu3 S2 2_666 2.290(2) y
Cu3 I3 . 2.5726(11) y
Cu3 S2 1_455 2.639(3) y
N1 C1 . 1.330(9) ?
N1 C5 . 1.357(10) ?
N1 H1 . 0.8600 ?
N2 C10 . 1.353(10) ?
N2 C6 . 1.354(9) ?
N2 H2 . 0.8600 ?
N3 C11 . 1.355(9) ?
N3 C15 . 1.365(10) ?
N3 H3 . 0.8600 ?
S1 C1 . 1.728(7) ?
S1 Cu2 2_666 2.367(2) .
S1 Cu1 2_666 2.480(2) .
S2 C6 . 1.721(7) ?
S2 Cu3 2_666 2.290(2) .
S2 Cu3 1_655 2.639(3) .
S3 C11 . 1.708(7) ?
C1 C2 . 1.414(10) ?
C2 C3 . 1.384(11) ?
C2 H2A . 0.9300 ?
C3 C4 . 1.376(13) ?
C3 H3A . 0.9300 ?
C4 C5 . 1.337(13) ?
C4 H4 . 0.9300 ?
C5 H5 . 0.9300 ?
C6 C7 . 1.393(10) ?
C7 C8 . 1.385(12) ?
C7 H7 . 0.9300 ?
C8 C9 . 1.412(14) ?
C8 H8 . 0.9300 ?
C9 C10 . 1.300(13) ?
C9 H9 . 0.9300 ?
C10 H10 . 0.9300 ?
C11 C12 . 1.396(10) ?
C12 C13 . 1.351(12) ?
C12 H12 . 0.9300 ?
C13 C14 . 1.399(13) ?
C13 H13 . 0.9300 ?
C14 C15 . 1.326(13) ?
C14 H14 . 0.9300 ?
C15 H15 . 0.9300 ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
_geom_torsion
S3 Cu1 Cu2 S2 . . -164.32(10)
S1 Cu1 Cu2 S2 . . -6.01(13)
S1 Cu1 Cu2 S2 2_666 . -77.56(9)
I1 Cu1 Cu2 S2 . . 91.21(8)
Cu1 Cu1 Cu2 S2 2_666 . -45.38(9)
S3 Cu1 Cu2 S1 . 2_666 -86.77(10)
S1 Cu1 Cu2 S1 . 2_666 71.55(11)
I1 Cu1 Cu2 S1 . 2_666 168.77(6)
Cu1 Cu1 Cu2 S1 2_666 2_666 32.17(6)
S3 Cu1 Cu2 I2 . . 12.56(11)
S1 Cu1 Cu2 I2 . . 170.87(8)
S1 Cu1 Cu2 I2 2_666 . 99.32(7)
I1 Cu1 Cu2 I2 . . -91.91(5)
Cu1 Cu1 Cu2 I2 2_666 . 131.49(6)
S3 Cu1 Cu2 I1 . . 104.47(9)
S1 Cu1 Cu2 I1 . . -97.22(9)
S1 Cu1 Cu2 I1 2_666 . -168.77(6)
Cu1 Cu1 Cu2 I1 2_666 . -136.59(5)
S3 Cu1 I1 Cu2 . . -117.13(8)
S1 Cu1 I1 Cu2 . . 129.49(7)
S1 Cu1 I1 Cu2 2_666 . 9.41(5)
Cu1 Cu1 I1 Cu2 2_666 . 64.56(7)
S2 Cu2 I1 Cu1 . . -115.48(6)
S1 Cu2 I1 Cu1 2_666 . -9.89(5)
I2 Cu2 I1 Cu1 . . 118.74(4)
S3 Cu1 S1 C1 . . -149.4(3)
S1 Cu1 S1 C1 2_666 . 99.0(3)
I1 Cu1 S1 C1 . . -23.6(3)
Cu2 Cu1 S1 C1 . . 48.0(3)
Cu1 Cu1 S1 C1 2_666 . 99.0(3)
S3 Cu1 S1 Cu2 . 2_666 57.90(12)
S1 Cu1 S1 Cu2 2_666 2_666 -53.73(9)
I1 Cu1 S1 Cu2 . 2_666 -176.24(7)
Cu2 Cu1 S1 Cu2 . 2_666 -104.64(10)
Cu1 Cu1 S1 Cu2 2_666 2_666 -53.73(9)
S3 Cu1 S1 Cu1 . 2_666 111.63(8)
S1 Cu1 S1 Cu1 2_666 2_666 0.0
I1 Cu1 S1 Cu1 . 2_666 -122.51(6)
Cu2 Cu1 S1 Cu1 . 2_666 -50.91(9)
S1 Cu2 S2 C6 2_666 . 179.4(3)
I2 Cu2 S2 C6 . . 56.7(3)
I1 Cu2 S2 C6 . . -66.2(3)
Cu1 Cu2 S2 C6 . . -126.1(3)
S1 Cu2 S2 Cu3 2_666 2_666 -34.96(14)
I2 Cu2 S2 Cu3 . 2_666 -157.63(10)
I1 Cu2 S2 Cu3 . 2_666 79.47(13)
Cu1 Cu2 S2 Cu3 . 2_666 19.54(16)
S1 Cu2 S2 Cu3 2_666 1_655 68.67(9)
I2 Cu2 S2 Cu3 . 1_655 -54.00(9)
I1 Cu2 S2 Cu3 . 1_655 -176.90(5)
Cu1 Cu2 S2 Cu3 . 1_655 123.16(7)
S2 Cu3 S3 C11 2_666 . 179.1(3)
I3 Cu3 S3 C11 . . 42.7(3)
S2 Cu3 S3 C11 1_455 . -82.3(3)
S2 Cu3 S3 Cu1 2_666 . -1.65(19)
I3 Cu3 S3 Cu1 . . -138.06(12)
S2 Cu3 S3 Cu1 1_455 . 96.91(15)
S1 Cu1 S3 C11 . . 162.0(3)
S1 Cu1 S3 C11 2_666 . -89.3(3)
I1 Cu1 S3 C11 . . 37.7(3)
Cu2 Cu1 S3 C11 . . -32.9(3)
Cu1 Cu1 S3 C11 2_666 . -143.7(3)
S1 Cu1 S3 Cu3 . . -17.16(16)
S1 Cu1 S3 Cu3 2_666 . 91.46(15)
I1 Cu1 S3 Cu3 . . -141.50(12)
Cu2 Cu1 S3 Cu3 . . 147.85(12)
Cu1 Cu1 S3 Cu3 2_666 . 37.13(17)
C5 N1 C1 C2 . . 0.8(12)
C5 N1 C1 S1 . . 179.9(7)
Cu1 S1 C1 N1 . . 162.9(5)
Cu2 S1 C1 N1 2_666 . -40.6(7)
Cu1 S1 C1 N1 2_666 . -117.0(6)
Cu1 S1 C1 C2 . . -18.1(8)
Cu2 S1 C1 C2 2_666 . 138.4(6)
Cu1 S1 C1 C2 2_666 . 61.9(7)
N1 C1 C2 C3 . . 0.0(12)
S1 C1 C2 C3 . . -179.0(7)
C1 C2 C3 C4 . . -0.9(14)
C2 C3 C4 C5 . . 1.1(15)
C3 C4 C5 N1 . . -0.3(15)
C1 N1 C5 C4 . . -0.7(15)
C10 N2 C6 C7 . . -4.2(12)
C10 N2 C6 S2 . . 169.9(7)
Cu3 S2 C6 N2 2_666 . 15.5(7)
Cu2 S2 C6 N2 . . 166.3(5)
Cu3 S2 C6 N2 1_655 . -75.0(6)
Cu3 S2 C6 C7 2_666 . -170.8(6)
Cu2 S2 C6 C7 . . -20.0(8)
Cu3 S2 C6 C7 1_655 . 98.7(7)
N2 C6 C7 C8 . . 2.8(12)
S2 C6 C7 C8 . . -171.0(7)
C6 C7 C8 C9 . . 0.7(14)
C7 C8 C9 C10 . . -3.2(15)
C8 C9 C10 N2 . . 2.0(15)
C6 N2 C10 C9 . . 1.8(14)
C15 N3 C11 C12 . . -3.8(11)
C15 N3 C11 S3 . . 175.5(6)
Cu3 S3 C11 N3 . . 19.6(7)
Cu1 S3 C11 N3 . . -159.8(5)
Cu3 S3 C11 C12 . . -161.2(6)
Cu1 S3 C11 C12 . . 19.4(8)
N3 C11 C12 C13 . . 1.5(12)
S3 C11 C12 C13 . . -177.8(7)
C11 C12 C13 C14 . . 1.7(14)
C12 C13 C14 C15 . . -2.8(14)
C13 C14 C15 N3 . . 0.7(14)
C11 N3 C15 C14 . . 2.7(13)
