#------------------------------------------------------------------------------
#$Date: 2016-02-21 02:03:34 +0200 (Sun, 21 Feb 2016) $
#$Revision: 176798 $
#$URL: svn://www.crystallography.net/cod/cif/2/23/72/2237290.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2237290
loop_
_publ_author_name
'Foladi, Shahrbano'
'Khazaei, Parivash'
'Attar Gharamaleki, Jafar'
'Notash, Behrouz'
'Rofouei, Mohammad Kazem'
_publ_section_title
;
 Dichloridodi-μ₂-hydroxido-di-μ₃-oxido-octaphenyltetratin(IV)
 dimethyl sulfoxide disolvate
;
_journal_coeditor_code           CV5369
_journal_issue                   2
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m91
_journal_paper_doi               10.1107/S1600536812051744
_journal_volume                  69
_journal_year                    2013
_chemical_formula_iupac          '[Sn4 (C6 H5)8 Cl2 O2 (O H)2], 2C2 H6 O S'
_chemical_formula_moiety         'C48 H42 Cl2 O4 Sn4, 2(C2 H6 O S)'
_chemical_formula_sum            'C52 H54 Cl2 O6 S2 Sn4'
_chemical_formula_weight         1384.73
_chemical_name_systematic
;
Dichloridodi-μ₂-hydroxido-di-μ₃-oxido-octaphenyltetratin(IV)
dimethyl sulfoxide disolvate
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 93.61(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   11.521(2)
_cell_length_b                   19.372(4)
_cell_length_c                   11.854(2)
_cell_measurement_reflns_used    7108
_cell_measurement_temperature    298(2)
_cell_measurement_theta_max      29.19
_cell_measurement_theta_min      2.02
_cell_volume                     2640.4(8)
_computing_cell_refinement       'X-Area (Stoe & Cie, 2005)'
_computing_data_collection       'X-Area (Stoe & Cie, 2005)'
_computing_data_reduction        'X-Area (Stoe & Cie, 2005)'
_computing_molecular_graphics    'ORTEP-3 for Windows (Farrugia, 2012)'
_computing_publication_material  'WinGX (Farrugia, 2012)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      298(2)
_diffrn_detector_area_resol_mean 0.15
_diffrn_measured_fraction_theta_full 0.994
_diffrn_measured_fraction_theta_max 0.994
_diffrn_measurement_device_type  'STOE IPDS 2T'
_diffrn_measurement_method       'rotation method'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0952
_diffrn_reflns_av_sigmaI/netI    0.0549
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       26
_diffrn_reflns_limit_k_min       -26
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            28831
_diffrn_reflns_theta_full        29.19
_diffrn_reflns_theta_max         29.19
_diffrn_reflns_theta_min         2.02
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    2.097
_exptl_absorpt_correction_T_max  0.4521
_exptl_absorpt_correction_T_min  0.4203
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   '(X-RED32; Stoe & Cie, 2005)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.742
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1360
_exptl_crystal_size_max          0.50
_exptl_crystal_size_mid          0.47
_exptl_crystal_size_min          0.45
_refine_diff_density_max         0.916
_refine_diff_density_min         -0.832
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.050
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     304
_refine_ls_number_reflns         7108
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      1.051
_refine_ls_R_factor_all          0.0397
_refine_ls_R_factor_gt           0.0304
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0328P)²+0.0145P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0757
_refine_ls_wR_factor_ref         0.0789
_reflns_number_gt                6034
_reflns_number_total             7108
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            cv5369.cif
_cod_data_source_block           I
_cod_original_cell_volume        2640.4(9)
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               2237290
_cod_database_fobs_code          2237290
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_symmetry_multiplicity
Sn Sn1 0.923073(16) 0.109727(9) 0.801260(13) 0.03225(6) Uani d . 1 1
Sn Sn2 1.050659(15) 0.052478(9) 1.103601(13) 0.02920(5) Uani d . 1 1
Cl Cl1 0.98076(8) 0.20923(4) 0.92137(6) 0.05121(18) Uani d . 1 1
S S1 0.46511(8) 0.04222(5) 0.28731(8) 0.0587(2) Uani d . 1 1
O O1 0.96963(18) 0.04965(9) 0.93664(14) 0.0343(4) Uani d . 1 1
O O2 1.12468(17) -0.00375(10) 1.24848(15) 0.0344(4) Uani d D 1 1
O O3 0.3549(2) 0.02385(16) 0.3395(2) 0.0620(6) Uani d . 1 1
C C1 0.7530(3) 0.14934(15) 0.7610(2) 0.0386(6) Uani d . 1 1
C C2 0.6974(3) 0.19241(18) 0.8329(3) 0.0491(7) Uani d . 1 1
H H2 0.7309 0.2002 0.9052 0.059 Uiso calc R 1 1
C C3 0.5946(4) 0.2238(2) 0.8011(4) 0.0655(11) Uani d . 1 1
H H3 0.5579 0.2518 0.8517 0.079 Uiso calc R 1 1
C C4 0.5453(3) 0.2137(2) 0.6929(4) 0.0697(11) Uani d . 1 1
H H4 0.4764 0.2360 0.6697 0.084 Uiso calc R 1 1
C C5 0.5987(4) 0.1705(2) 0.6196(3) 0.0676(11) Uani d . 1 1
H H5 0.5652 0.1630 0.5472 0.081 Uiso calc R 1 1
C C6 0.7027(3) 0.13809(19) 0.6540(3) 0.0508(7) Uani d . 1 1
H H6 0.7383 0.1087 0.6046 0.061 Uiso calc R 1 1
C C7 1.0545(3) 0.11797(15) 0.6825(2) 0.0376(6) Uani d . 1 1
C C8 1.0729(3) 0.06512(18) 0.6064(2) 0.0463(7) Uani d . 1 1
H H8 1.0281 0.0253 0.6075 0.056 Uiso calc R 1 1
C C9 1.1578(3) 0.0713(2) 0.5289(3) 0.0558(8) Uani d . 1 1
H H9 1.1704 0.0354 0.4790 0.067 Uiso calc R 1 1
C C10 1.2236(3) 0.1309(2) 0.5260(3) 0.0581(9) Uani d . 1 1
H H10 1.2792 0.1357 0.4729 0.070 Uiso calc R 1 1
C C11 1.2069(3) 0.1829(2) 0.6012(3) 0.0605(9) Uani d . 1 1
H H11 1.2520 0.2227 0.5999 0.073 Uiso calc R 1 1
C C12 1.1228(3) 0.17680(18) 0.6797(3) 0.0510(8) Uani d . 1 1
H H12 1.1124 0.2124 0.7308 0.061 Uiso calc R 1 1
C C13 1.2033(2) 0.10738(14) 1.0699(2) 0.0343(5) Uani d . 1 1
C C14 1.2472(3) 0.10957(18) 0.9635(3) 0.0491(7) Uani d . 1 1
H H14 1.2115 0.0842 0.9045 0.059 Uiso calc R 1 1
C C15 1.3439(3) 0.1494(2) 0.9450(3) 0.0626(10) Uani d . 1 1
H H15 1.3732 0.1506 0.8736 0.075 Uiso calc R 1 1
C C16 1.3969(3) 0.1874(2) 1.0319(4) 0.0640(10) Uani d . 1 1
H H16 1.4614 0.2144 1.0186 0.077 Uiso calc R 1 1
C C17 1.3556(3) 0.18588(19) 1.1379(3) 0.0585(9) Uani d . 1 1
H H17 1.3923 0.2112 1.1965 0.070 Uiso calc R 1 1
C C18 1.2580(3) 0.14597(16) 1.1566(3) 0.0431(6) Uani d . 1 1
H H18 1.2290 0.1452 1.2281 0.052 Uiso calc R 1 1
C C19 0.9102(2) 0.09486(14) 1.1881(2) 0.0356(5) Uani d . 1 1
C C20 0.9278(3) 0.11474(17) 1.3006(2) 0.0489(8) Uani d . 1 1
H H20 0.9998 0.1075 1.3388 0.059 Uiso calc R 1 1
C C21 0.8387(4) 0.1453(2) 1.3562(3) 0.0680(12) Uani d . 1 1
H H21 0.8512 0.1586 1.4313 0.082 Uiso calc R 1 1
C C22 0.7322(4) 0.1558(2) 1.3006(4) 0.0762(14) Uani d . 1 1
H H22 0.6725 0.1759 1.3384 0.091 Uiso calc R 1 1
C C23 0.7139(4) 0.1373(2) 1.1918(4) 0.0757(13) Uani d . 1 1
H H23 0.6415 0.1450 1.1548 0.091 Uiso calc R 1 1
C C24 0.8021(3) 0.10635(18) 1.1330(3) 0.0501(8) Uani d . 1 1
H H24 0.7883 0.0937 1.0577 0.060 Uiso calc R 1 1
C C25 0.4630(5) -0.0023(3) 0.1581(4) 0.0878(16) Uani d . 1 1
H H25A 0.4487 -0.0504 0.1708 0.132 Uiso calc R 1 1
H H25B 0.5366 0.0031 0.1255 0.132 Uiso calc R 1 1
H H25C 0.4024 0.0161 0.1074 0.132 Uiso calc R 1 1
C C26 0.5777(4) -0.0069(3) 0.3584(4) 0.0856(15) Uani d . 1 1
H H26A 0.5851 0.0063 0.4366 0.128 Uiso calc R 1 1
H H26B 0.6498 0.0017 0.3243 0.128 Uiso calc R 1 1
H H26C 0.5590 -0.0551 0.3526 0.128 Uiso calc R 1 1
H H2A 1.1948(17) 0.000(2) 1.265(3) 0.056(11) Uiso d D 1 1
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sn Sn -0.6537 1.4246 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
O1 Sn1 C1 . . 125.30(10)
O1 Sn1 C7 . . 113.66(10)
C1 Sn1 C7 . . 120.35(11)
O1 Sn1 O2 . 3_757 74.05(7)
C1 Sn1 O2 . 3_757 93.75(10)
C7 Sn1 O2 . 3_757 93.94(9)
O1 Sn1 Cl1 . . 86.75(6)
C1 Sn1 Cl1 . . 93.34(9)
C7 Sn1 Cl1 . . 98.39(8)
O2 Sn1 Cl1 3_757 . 160.17(5)
O1 Sn2 C13 3_757 . 121.78(9)
O1 Sn2 C19 3_757 . 113.91(10)
C13 Sn2 C19 . . 124.24(11)
O1 Sn2 O1 3_757 . 73.87(8)
C13 Sn2 O1 . . 99.07(9)
C19 Sn2 O1 . . 98.37(10)
O1 Sn2 O2 3_757 . 74.43(7)
C13 Sn2 O2 . . 96.46(9)
C19 Sn2 O2 . . 95.42(9)
O1 Sn2 O2 . . 148.27(7)
O3 S1 C25 . . 106.2(2)
O3 S1 C26 . . 106.9(2)
C25 S1 C26 . . 96.9(3)
Sn1 O1 Sn2 . 3_757 110.49(8)
Sn1 O1 Sn2 . . 142.90(9)
Sn2 O1 Sn2 3_757 . 106.13(8)
Sn2 O2 Sn1 . 3_757 100.26(8)
Sn2 O2 H2A . . 118(3)
Sn1 O2 H2A 3_757 . 112(3)
C2 C1 C6 . . 118.6(3)
C2 C1 Sn1 . . 122.4(2)
C6 C1 Sn1 . . 118.5(2)
C3 C2 C1 . . 121.9(4)
C3 C2 H2 . . 119.0
C1 C2 H2 . . 119.0
C2 C3 C4 . . 119.5(4)
C2 C3 H3 . . 120.3
C4 C3 H3 . . 120.3
C5 C4 C3 . . 119.8(3)
C5 C4 H4 . . 120.1
C3 C4 H4 . . 120.1
C4 C5 C6 . . 120.0(4)
C4 C5 H5 . . 120.0
C6 C5 H5 . . 120.0
C1 C6 C5 . . 120.2(4)
C1 C6 H6 . . 119.9
C5 C6 H6 . . 119.9
C12 C7 C8 . . 118.7(3)
C12 C7 Sn1 . . 120.2(2)
C8 C7 Sn1 . . 121.1(2)
C9 C8 C7 . . 120.6(3)
C9 C8 H8 . . 119.7
C7 C8 H8 . . 119.7
C10 C9 C8 . . 119.8(3)
C10 C9 H9 . . 120.1
C8 C9 H9 . . 120.1
C11 C10 C9 . . 119.9(3)
C11 C10 H10 . . 120.0
C9 C10 H10 . . 120.0
C10 C11 C12 . . 120.5(4)
C10 C11 H11 . . 119.8
C12 C11 H11 . . 119.8
C7 C12 C11 . . 120.4(3)
C7 C12 H12 . . 119.8
C11 C12 H12 . . 119.8
C14 C13 C18 . . 118.8(3)
C14 C13 Sn2 . . 122.8(2)
C18 C13 Sn2 . . 118.3(2)
C15 C14 C13 . . 120.3(3)
C15 C14 H14 . . 119.9
C13 C14 H14 . . 119.9
C16 C15 C14 . . 120.1(3)
C16 C15 H15 . . 119.9
C14 C15 H15 . . 119.9
C17 C16 C15 . . 120.7(3)
C17 C16 H16 . . 119.6
C15 C16 H16 . . 119.6
C16 C17 C18 . . 119.2(3)
C16 C17 H17 . . 120.4
C18 C17 H17 . . 120.4
C13 C18 C17 . . 120.8(3)
C13 C18 H18 . . 119.6
C17 C18 H18 . . 119.6
C24 C19 C20 . . 118.6(3)
C24 C19 Sn2 . . 121.9(2)
C20 C19 Sn2 . . 119.4(2)
C21 C20 C19 . . 120.4(4)
C21 C20 H20 . . 119.8
C19 C20 H20 . . 119.8
C22 C21 C20 . . 120.1(4)
C22 C21 H21 . . 119.9
C20 C21 H21 . . 119.9
C23 C22 C21 . . 120.2(3)
C23 C22 H22 . . 119.9
C21 C22 H22 . . 119.9
C22 C23 C24 . . 121.1(4)
C22 C23 H23 . . 119.5
C24 C23 H23 . . 119.5
C19 C24 C23 . . 119.5(4)
C19 C24 H24 . . 120.2
C23 C24 H24 . . 120.2
S1 C25 H25A . . 109.5
S1 C25 H25B . . 109.5
H25A C25 H25B . . 109.5
S1 C25 H25C . . 109.5
H25A C25 H25C . . 109.5
H25B C25 H25C . . 109.5
S1 C26 H26A . . 109.5
S1 C26 H26B . . 109.5
H26A C26 H26B . . 109.5
S1 C26 H26C . . 109.5
H26A C26 H26C . . 109.5
H26B C26 H26C . . 109.5
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
Sn1 O1 . 2.0271(18)
Sn1 C1 . 2.130(3)
Sn1 C7 . 2.137(3)
Sn1 O2 3_757 2.196(2)
Sn1 Cl1 . 2.4628(9)
Sn2 O1 3_757 2.0451(18)
Sn2 C13 . 2.115(3)
Sn2 C19 . 2.121(3)
Sn2 O1 . 2.1351(18)
Sn2 O2 . 2.1630(19)
S1 O3 . 1.490(3)
S1 C25 . 1.757(5)
S1 C26 . 1.777(4)
O1 Sn2 3_757 2.0451(18)
O2 Sn1 3_757 2.196(2)
O2 H2A . 0.824(19)
C1 C2 . 1.379(4)
C1 C6 . 1.379(4)
C2 C3 . 1.363(5)
C2 H2 . 0.9300
C3 C4 . 1.384(6)
C3 H3 . 0.9300
C4 C5 . 1.379(6)
C4 H4 . 0.9300
C5 C6 . 1.390(5)
C5 H5 . 0.9300
C6 H6 . 0.9300
C7 C12 . 1.387(4)
C7 C8 . 1.389(4)
C8 C9 . 1.389(4)
C8 H8 . 0.9300
C9 C10 . 1.384(6)
C9 H9 . 0.9300
C10 C11 . 1.367(6)
C10 H10 . 0.9300
C11 C12 . 1.389(5)
C11 H11 . 0.9300
C12 H12 . 0.9300
C13 C14 . 1.388(4)
C13 C18 . 1.390(4)
C14 C15 . 1.385(5)
C14 H14 . 0.9300
C15 C16 . 1.377(6)
C15 H15 . 0.9300
C16 C17 . 1.371(5)
C16 H16 . 0.9300
C17 C18 . 1.394(5)
C17 H17 . 0.9300
C18 H18 . 0.9300
C19 C24 . 1.387(4)
C19 C20 . 1.390(4)
C20 C21 . 1.387(5)
C20 H20 . 0.9300
C21 C22 . 1.370(7)
C21 H21 . 0.9300
C22 C23 . 1.343(7)
C22 H22 . 0.9300
C23 C24 . 1.402(5)
C23 H23 . 0.9300
C24 H24 . 0.9300
C25 H25A . 0.9600
C25 H25B . 0.9600
C25 H25C . 0.9600
C26 H26A . 0.9600
C26 H26B . 0.9600
C26 H26C . 0.9600
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_site_symmetry_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_publ_flag
O2 H2A O3 1_656 0.824(19) 2.04(2) 2.851(3) 166(4) y
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
_geom_torsion
C1 Sn1 O1 Sn2 . 3_757 90.30(14)
C7 Sn1 O1 Sn2 . 3_757 -80.16(12)
O2 Sn1 O1 Sn2 3_757 3_757 7.14(8)
Cl1 Sn1 O1 Sn2 . 3_757 -177.90(9)
C1 Sn1 O1 Sn2 . . -99.31(19)
C7 Sn1 O1 Sn2 . . 90.23(19)
O2 Sn1 O1 Sn2 3_757 . 177.53(19)
Cl1 Sn1 O1 Sn2 . . -7.51(16)
O1 Sn2 O1 Sn1 3_757 . -170.6(2)
C13 Sn2 O1 Sn1 . . -50.03(19)
C19 Sn2 O1 Sn1 . . 76.80(19)
O2 Sn2 O1 Sn1 . . -168.40(12)
O1 Sn2 O1 Sn2 3_757 3_757 0.0
C13 Sn2 O1 Sn2 . 3_757 120.60(10)
C19 Sn2 O1 Sn2 . 3_757 -112.57(10)
O2 Sn2 O1 Sn2 . 3_757 2.2(2)
O1 Sn2 O2 Sn1 3_757 3_757 -6.35(7)
C13 Sn2 O2 Sn1 . 3_757 -127.59(9)
C19 Sn2 O2 Sn1 . 3_757 106.98(10)
O1 Sn2 O2 Sn1 . 3_757 -8.58(18)
O1 Sn1 C1 C2 . . 60.3(3)
C7 Sn1 C1 C2 . . -129.9(2)
O2 Sn1 C1 C2 3_757 . 133.3(2)
Cl1 Sn1 C1 C2 . . -28.1(2)
O1 Sn1 C1 C6 . . -127.6(2)
C7 Sn1 C1 C6 . . 42.3(3)
O2 Sn1 C1 C6 3_757 . -54.5(2)
Cl1 Sn1 C1 C6 . . 144.0(2)
C6 C1 C2 C3 . . 0.1(5)
Sn1 C1 C2 C3 . . 172.2(3)
C1 C2 C3 C4 . . -1.4(6)
C2 C3 C4 C5 . . 1.9(6)
C3 C4 C5 C6 . . -1.0(6)
C2 C1 C6 C5 . . 0.8(5)
Sn1 C1 C6 C5 . . -171.6(3)
C4 C5 C6 C1 . . -0.4(6)
O1 Sn1 C7 C12 . . -102.1(3)
C1 Sn1 C7 C12 . . 86.9(3)
O2 Sn1 C7 C12 3_757 . -176.4(3)
Cl1 Sn1 C7 C12 . . -12.0(3)
O1 Sn1 C7 C8 . . 78.2(3)
C1 Sn1 C7 C8 . . -92.8(3)
O2 Sn1 C7 C8 3_757 . 3.9(2)
Cl1 Sn1 C7 C8 . . 168.3(2)
C12 C7 C8 C9 . . -0.3(5)
Sn1 C7 C8 C9 . . 179.4(3)
C7 C8 C9 C10 . . -0.9(5)
C8 C9 C10 C11 . . 1.6(6)
C9 C10 C11 C12 . . -1.0(6)
C8 C7 C12 C11 . . 0.9(5)
Sn1 C7 C12 C11 . . -178.8(3)
C10 C11 C12 C7 . . -0.3(6)
O1 Sn2 C13 C14 3_757 . 53.5(3)
C19 Sn2 C13 C14 . . -129.8(2)
O1 Sn2 C13 C14 . . -23.1(3)
O2 Sn2 C13 C14 . . 129.2(2)
O1 Sn2 C13 C18 3_757 . -130.2(2)
C19 Sn2 C13 C18 . . 46.5(3)
O1 Sn2 C13 C18 . . 153.2(2)
O2 Sn2 C13 C18 . . -54.5(2)
C18 C13 C14 C15 . . 0.2(5)
Sn2 C13 C14 C15 . . 176.5(3)
C13 C14 C15 C16 . . -0.3(6)
C14 C15 C16 C17 . . 0.6(6)
C15 C16 C17 C18 . . -0.8(6)
C14 C13 C18 C17 . . -0.4(5)
Sn2 C13 C18 C17 . . -176.9(3)
C16 C17 C18 C13 . . 0.7(5)
O1 Sn2 C19 C24 3_757 . -70.8(3)
C13 Sn2 C19 C24 . . 112.2(3)
O1 Sn2 C19 C24 . . 5.2(3)
O2 Sn2 C19 C24 . . -146.2(2)
O1 Sn2 C19 C20 3_757 . 112.1(2)
C13 Sn2 C19 C20 . . -64.8(3)
O1 Sn2 C19 C20 . . -171.9(2)
O2 Sn2 C19 C20 . . 36.8(2)
C24 C19 C20 C21 . . 0.1(5)
Sn2 C19 C20 C21 . . 177.3(3)
C19 C20 C21 C22 . . 0.3(6)
C20 C21 C22 C23 . . -0.6(6)
C21 C22 C23 C24 . . 0.5(7)
C20 C19 C24 C23 . . -0.2(5)
Sn2 C19 C24 C23 . . -177.3(3)
C22 C23 C24 C19 . . -0.1(6)
