#------------------------------------------------------------------------------
#$Date: 2016-02-21 02:03:34 +0200 (Sun, 21 Feb 2016) $
#$Revision: 176798 $
#$URL: svn://www.crystallography.net/cod/cif/2/23/74/2237482.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2237482
loop_
_publ_author_name
'Zhu, Gang'
'Jiao, Bao-Juan'
_publ_section_title
;
 Bis{2-bromo-4-chloro-6-[(E)-(2,6-dimethylphenyl)iminomethyl]phenolato-κ²N,O}cobalt(II)
;
_journal_coeditor_code           HB7032
_journal_issue                   3
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m156
_journal_paper_doi               10.1107/S1600536813003747
_journal_volume                  69
_journal_year                    2013
_chemical_formula_iupac          '[Co (C15 H12 Br Cl N O)2]'
_chemical_formula_moiety         'C30 H24 Br2 Cl2 Co N2 O2'
_chemical_formula_sum            'C30 H24 Br2 Cl2 Co N2 O2'
_chemical_formula_weight         734.16
_chemical_name_systematic
Bis{2-bromo-4-chloro-6-[(E)-(2,6-dimethylphenyl)iminomethyl]phenolato-κ²N,O}cobalt(II)
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 114.380(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   11.608(2)
_cell_length_b                   24.157(4)
_cell_length_c                   11.354(2)
_cell_measurement_reflns_used    10097
_cell_measurement_temperature    153(2)
_cell_measurement_theta_max      29.123
_cell_measurement_theta_min      2.103
_cell_volume                     2899.9(9)
_computing_cell_refinement       'CrystalClear (Rigaku, 2008)'
_computing_data_collection       'CrystalClear (Rigaku, 2008)'
_computing_data_reduction        'CrystalClear (Rigaku, 2008)'
_computing_molecular_graphics    'SHELTXL (Sheldrick, 2008)'
_computing_publication_material  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      153(2)
_diffrn_detector_area_resol_mean 28.5714
_diffrn_measured_fraction_theta_full 0.990
_diffrn_measured_fraction_theta_max 0.990
_diffrn_measurement_device_type  'Rigaku AFC10/Saturn724+'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'Rotating Anode'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0469
_diffrn_reflns_av_sigmaI/netI    0.0440
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       32
_diffrn_reflns_limit_k_min       -33
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            32947
_diffrn_reflns_theta_full        29.12
_diffrn_reflns_theta_max         29.12
_diffrn_reflns_theta_min         2.27
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    3.563
_exptl_absorpt_correction_T_max  0.6827
_exptl_absorpt_correction_T_min  0.2742
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(CrystalClear; Rigaku, 2008)'
_exptl_crystal_colour            Red
_exptl_crystal_density_diffrn    1.682
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Chunk
_exptl_crystal_F_000             1460
_exptl_crystal_size_max          0.49
_exptl_crystal_size_mid          0.27
_exptl_crystal_size_min          0.12
_refine_diff_density_max         0.539
_refine_diff_density_min         -0.634
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.001
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     356
_refine_ls_number_reflns         7718
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.001
_refine_ls_R_factor_all          0.0530
_refine_ls_R_factor_gt           0.0438
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0651P)²+0.5160P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1126
_refine_ls_wR_factor_ref         0.1194
_reflns_number_gt                6813
_reflns_number_total             7718
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            hb7032.cif
_cod_data_source_block           I
_cod_original_cell_volume        2899.8(9)
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               2237482
_cod_database_fobs_code          2237482
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_symmetry_multiplicity
Co Co1 0.26654(3) 0.662257(15) 0.69368(3) 0.02274(10) Uani d . 1 1
Br Br1 0.57530(3) 0.644847(13) 1.13829(3) 0.03965(10) Uani d . 1 1
Br Br2 -0.09274(3) 0.764024(13) 0.69082(3) 0.04195(10) Uani d . 1 1
Cl Cl1 0.36329(7) 0.44165(3) 1.15246(7) 0.03762(18) Uani d . 1 1
Cl Cl2 -0.01848(7) 0.91557(3) 0.36421(7) 0.03602(17) Uani d . 1 1
O O1 0.37754(18) 0.64192(7) 0.86650(17) 0.0264(4) Uani d . 1 1
O O2 0.14215(17) 0.71526(7) 0.68464(18) 0.0272(4) Uani d . 1 1
N N1 0.2067(2) 0.58493(9) 0.6390(2) 0.0234(5) Uani d . 1 1
N N2 0.34280(19) 0.70873(9) 0.60062(19) 0.0208(4) Uani d . 1 1
C C1 0.2975(2) 0.54925(11) 0.8618(2) 0.0231(5) Uani d . 1 1
C C2 0.2949(2) 0.50225(11) 0.9335(3) 0.0270(6) Uani d . 1 1
H H2 0.2416 0.4720 0.8913 0.032 Uiso calc R 1 1
C C3 0.3687(2) 0.49968(11) 1.0639(3) 0.0277(6) Uani d . 1 1
C C4 0.4516(3) 0.54284(12) 1.1261(3) 0.0287(6) Uani d . 1 1
H H4 0.5049 0.5406 1.2158 0.034 Uiso calc R 1 1
C C5 0.4548(3) 0.58833(11) 1.0562(2) 0.0259(6) Uani d . 1 1
C C6 0.3753(2) 0.59526(10) 0.9230(2) 0.0225(5) Uani d . 1 1
C C7 0.2230(2) 0.54617(11) 0.7227(3) 0.0254(5) Uani d . 1 1
H H7 0.1819 0.5119 0.6900 0.030 Uiso calc R 1 1
C C8 0.1440(2) 0.57063(11) 0.5034(2) 0.0239(5) Uani d . 1 1
C C9 0.2103(3) 0.53997(11) 0.4467(3) 0.0291(6) Uani d . 1 1
C C10 0.1533(3) 0.53156(12) 0.3131(3) 0.0326(6) Uani d . 1 1
H H10 0.1964 0.5108 0.2726 0.039 Uiso calc R 1 1
C C11 0.0347(3) 0.55301(12) 0.2391(3) 0.0320(6) Uani d . 1 1
H H11 -0.0025 0.5475 0.1481 0.038 Uiso calc R 1 1
C C12 -0.0294(3) 0.58239(11) 0.2975(3) 0.0297(6) Uani d . 1 1
H H12 -0.1105 0.5971 0.2456 0.036 Uiso calc R 1 1
C C13 0.0222(3) 0.59107(12) 0.4314(3) 0.0280(6) Uani d . 1 1
C C14 0.3415(3) 0.51866(15) 0.5239(3) 0.0443(8) Uani d . 1 1
H H14A 0.3946 0.5487 0.5766 0.053 Uiso calc R 1 1
H H14B 0.3773 0.5047 0.4651 0.053 Uiso calc R 1 1
H H14C 0.3382 0.4886 0.5804 0.053 Uiso calc R 1 1
C C15 -0.0532(3) 0.62008(16) 0.4928(3) 0.0455(8) Uani d . 1 1
H H15A -0.0562 0.5971 0.5626 0.055 Uiso calc R 1 1
H H15B -0.1394 0.6265 0.4277 0.055 Uiso calc R 1 1
H H15C -0.0134 0.6556 0.5282 0.055 Uiso calc R 1 1
C C16 0.1773(2) 0.77951(10) 0.5396(2) 0.0210(5) Uani d . 1 1
C C17 0.1093(2) 0.75899(10) 0.6102(2) 0.0208(5) Uani d . 1 1
C C18 0.0010(2) 0.78977(11) 0.5987(3) 0.0247(5) Uani d . 1 1
C C19 -0.0383(2) 0.83669(11) 0.5250(3) 0.0244(5) Uani d . 1 1
H H19 -0.1116 0.8560 0.5198 0.029 Uiso calc R 1 1
C C20 0.0307(2) 0.85564(11) 0.4578(3) 0.0250(5) Uani d . 1 1
C C21 0.1359(2) 0.82777(10) 0.4642(2) 0.0231(5) Uani d . 1 1
H H21 0.1815 0.8412 0.4173 0.028 Uiso calc R 1 1
C C22 0.2909(2) 0.75423(11) 0.5415(2) 0.0221(5) Uani d . 1 1
H H22 0.3315 0.7727 0.4952 0.027 Uiso calc R 1 1
C C23 0.4569(2) 0.68953(11) 0.5936(2) 0.0234(5) Uani d . 1 1
C C24 0.5715(2) 0.69448(11) 0.7039(3) 0.0269(6) Uani d . 1 1
C C25 0.6783(3) 0.67082(13) 0.6988(3) 0.0376(7) Uani d . 1 1
H H25 0.7568 0.6735 0.7721 0.045 Uiso calc R 1 1
C C26 0.6736(3) 0.64344(14) 0.5902(4) 0.0452(9) Uani d . 1 1
H H26 0.7476 0.6267 0.5900 0.054 Uiso calc R 1 1
C C27 0.5609(3) 0.64060(13) 0.4820(3) 0.0405(8) Uani d . 1 1
H H27 0.5586 0.6225 0.4067 0.049 Uiso calc R 1 1
C C28 0.4499(3) 0.66366(12) 0.4805(3) 0.0288(6) Uani d . 1 1
C C29 0.5791(3) 0.72459(13) 0.8230(3) 0.0357(7) Uani d . 1 1
H H29A 0.5418 0.7016 0.8693 0.043 Uiso calc R 1 1
H H29B 0.5325 0.7596 0.7977 0.043 Uiso calc R 1 1
H H29C 0.6678 0.7322 0.8794 0.043 Uiso calc R 1 1
C C30 0.3284(3) 0.66150(13) 0.3601(3) 0.0387(7) Uani d . 1 1
H H30A 0.2577 0.6540 0.3838 0.046 Uiso calc R 1 1
H H30B 0.3336 0.6320 0.3032 0.046 Uiso calc R 1 1
H H30C 0.3148 0.6971 0.3148 0.046 Uiso calc R 1 1
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Br Br -0.2901 2.4595 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_publ_flag
O2 Co1 O1 113.77(8) n
O2 Co1 N2 94.94(8) n
O1 Co1 N2 115.58(8) n
O2 Co1 N1 116.97(9) n
O1 Co1 N1 94.53(8) n
N2 Co1 N1 122.51(9) n
C6 O1 Co1 125.79(17) n
C17 O2 Co1 126.25(17) n
C7 N1 C8 117.8(2) ?
C7 N1 Co1 121.47(18) ?
C8 N1 Co1 120.72(17) ?
C22 N2 C23 119.1(2) ?
C22 N2 Co1 122.70(18) ?
C23 N2 Co1 118.14(16) ?
C2 C1 C6 120.7(2) ?
C2 C1 C7 116.2(2) ?
C6 C1 C7 122.9(2) ?
C3 C2 C1 120.6(3) ?
C3 C2 H2 119.7 ?
C1 C2 H2 119.7 ?
C2 C3 C4 120.3(2) ?
C2 C3 Cl1 120.3(2) ?
C4 C3 Cl1 119.4(2) ?
C5 C4 C3 119.0(2) ?
C5 C4 H4 120.5 ?
C3 C4 H4 120.5 ?
C4 C5 C6 123.5(3) ?
C4 C5 Br1 119.0(2) ?
C6 C5 Br1 117.4(2) ?
O1 C6 C5 119.4(2) ?
O1 C6 C1 125.1(2) ?
C5 C6 C1 115.6(2) ?
N1 C7 C1 127.0(2) ?
N1 C7 H7 116.5 ?
C1 C7 H7 116.5 ?
C13 C8 C9 122.2(2) ?
C13 C8 N1 118.7(2) ?
C9 C8 N1 119.0(2) ?
C10 C9 C8 118.1(2) ?
C10 C9 C14 119.8(3) ?
C8 C9 C14 122.0(2) ?
C11 C10 C9 120.8(3) ?
C11 C10 H10 119.6 ?
C9 C10 H10 119.6 ?
C12 C11 C10 119.9(3) ?
C12 C11 H11 120.0 ?
C10 C11 H11 120.0 ?
C11 C12 C13 121.7(3) ?
C11 C12 H12 119.2 ?
C13 C12 H12 119.2 ?
C8 C13 C12 117.2(3) ?
C8 C13 C15 122.5(2) ?
C12 C13 C15 120.3(2) ?
C9 C14 H14A 109.5 ?
C9 C14 H14B 109.5 ?
H14A C14 H14B 109.5 ?
C9 C14 H14C 109.5 ?
H14A C14 H14C 109.5 ?
H14B C14 H14C 109.5 ?
C13 C15 H15A 109.5 ?
C13 C15 H15B 109.5 ?
H15A C15 H15B 109.5 ?
C13 C15 H15C 109.5 ?
H15A C15 H15C 109.5 ?
H15B C15 H15C 109.5 ?
C21 C16 C17 120.0(2) ?
C21 C16 C22 116.1(2) ?
C17 C16 C22 123.9(2) ?
O2 C17 C18 119.5(2) ?
O2 C17 C16 124.3(2) ?
C18 C17 C16 116.2(2) ?
C19 C18 C17 123.2(2) ?
C19 C18 Br2 119.1(2) ?
C17 C18 Br2 117.72(19) ?
C18 C19 C20 119.0(2) ?
C18 C19 H19 120.5 ?
C20 C19 H19 120.5 ?
C21 C20 C19 120.7(2) ?
C21 C20 Cl2 120.0(2) ?
C19 C20 Cl2 119.2(2) ?
C20 C21 C16 120.8(2) ?
C20 C21 H21 119.6 ?
C16 C21 H21 119.6 ?
N2 C22 C16 126.2(2) ?
N2 C22 H22 116.9 ?
C16 C22 H22 116.9 ?
C28 C23 C24 122.0(3) ?
C28 C23 N2 119.3(2) ?
C24 C23 N2 118.5(2) ?
C25 C24 C23 117.4(3) ?
C25 C24 C29 121.0(3) ?
C23 C24 C29 121.6(3) ?
C26 C25 C24 121.9(3) ?
C26 C25 H25 119.1 ?
C24 C25 H25 119.1 ?
C27 C26 C25 119.5(3) ?
C27 C26 H26 120.2 ?
C25 C26 H26 120.2 ?
C26 C27 C28 121.5(3) ?
C26 C27 H27 119.2 ?
C28 C27 H27 119.2 ?
C27 C28 C23 117.6(3) ?
C27 C28 C30 120.7(3) ?
C23 C28 C30 121.7(3) ?
C24 C29 H29A 109.5 ?
C24 C29 H29B 109.5 ?
H29A C29 H29B 109.5 ?
C24 C29 H29C 109.5 ?
H29A C29 H29C 109.5 ?
H29B C29 H29C 109.5 ?
C28 C30 H30A 109.5 ?
C28 C30 H30B 109.5 ?
H30A C30 H30B 109.5 ?
C28 C30 H30C 109.5 ?
H30A C30 H30C 109.5 ?
H30B C30 H30C 109.5 ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_publ_flag
Co1 O2 1.9006(18) y
Co1 O1 1.9144(18) y
Co1 N2 1.983(2) y
Co1 N1 2.000(2) y
Br1 C5 1.901(3) n
Br2 C18 1.898(3) n
Cl1 C3 1.742(3) n
Cl2 C20 1.746(3) n
O1 C6 1.302(3) ?
O2 C17 1.308(3) ?
N1 C7 1.291(3) ?
N1 C8 1.447(3) ?
N2 C22 1.299(3) ?
N2 C23 1.437(3) ?
C1 C2 1.405(4) ?
C1 C6 1.420(4) ?
C1 C7 1.456(4) ?
C2 C3 1.372(4) ?
C2 H2 0.9500 ?
C3 C4 1.397(4) ?
C4 C5 1.365(4) ?
C4 H4 0.9500 ?
C5 C6 1.420(4) ?
C7 H7 0.9500 ?
C8 C13 1.399(4) ?
C8 C9 1.402(4) ?
C9 C10 1.397(4) ?
C9 C14 1.500(4) ?
C10 C11 1.383(4) ?
C10 H10 0.9500 ?
C11 C12 1.381(4) ?
C11 H11 0.9500 ?
C12 C13 1.400(4) ?
C12 H12 0.9500 ?
C13 C15 1.499(4) ?
C14 H14A 0.9800 ?
C14 H14B 0.9800 ?
C14 H14C 0.9800 ?
C15 H15A 0.9800 ?
C15 H15B 0.9800 ?
C15 H15C 0.9800 ?
C16 C21 1.408(3) ?
C16 C17 1.426(4) ?
C16 C22 1.445(3) ?
C17 C18 1.420(3) ?
C18 C19 1.370(4) ?
C19 C20 1.392(4) ?
C19 H19 0.9500 ?
C20 C21 1.370(4) ?
C21 H21 0.9500 ?
C22 H22 0.9500 ?
C23 C28 1.400(4) ?
C23 C24 1.406(4) ?
C24 C25 1.387(4) ?
C24 C29 1.506(4) ?
C25 C26 1.381(5) ?
C25 H25 0.9500 ?
C26 C27 1.378(5) ?
C26 H26 0.9500 ?
C27 C28 1.397(4) ?
C27 H27 0.9500 ?
C28 C30 1.506(4) ?
C29 H29A 0.9800 ?
C29 H29B 0.9800 ?
C29 H29C 0.9800 ?
C30 H30A 0.9800 ?
C30 H30B 0.9800 ?
C30 H30C 0.9800 ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
O2 Co1 O1 C6 106.0(2)
N2 Co1 O1 C6 -145.6(2)
N1 Co1 O1 C6 -16.2(2)
O1 Co1 O2 C17 135.3(2)
N2 Co1 O2 C17 14.5(2)
N1 Co1 O2 C17 -115.9(2)
O2 Co1 N1 C7 -102.8(2)
O1 Co1 N1 C7 16.8(2)
N2 Co1 N1 C7 141.1(2)
O2 Co1 N1 C8 77.5(2)
O1 Co1 N1 C8 -162.86(19)
N2 Co1 N1 C8 -38.5(2)
O2 Co1 N2 C22 -10.4(2)
O1 Co1 N2 C22 -129.8(2)
N1 Co1 N2 C22 116.1(2)
O2 Co1 N2 C23 172.64(18)
O1 Co1 N2 C23 53.3(2)
N1 Co1 N2 C23 -60.8(2)
C6 C1 C2 C3 -0.8(4)
C7 C1 C2 C3 175.6(2)
C1 C2 C3 C4 -2.7(4)
C1 C2 C3 Cl1 179.1(2)
C2 C3 C4 C5 2.2(4)
Cl1 C3 C4 C5 -179.6(2)
C3 C4 C5 C6 1.9(4)
C3 C4 C5 Br1 -175.9(2)
Co1 O1 C6 C5 -173.34(18)
Co1 O1 C6 C1 6.3(4)
C4 C5 C6 O1 174.4(3)
Br1 C5 C6 O1 -7.7(3)
C4 C5 C6 C1 -5.2(4)
Br1 C5 C6 C1 172.68(19)
C2 C1 C6 O1 -175.1(3)
C7 C1 C6 O1 8.8(4)
C2 C1 C6 C5 4.5(4)
C7 C1 C6 C5 -171.6(2)
C8 N1 C7 C1 171.2(2)
Co1 N1 C7 C1 -8.4(4)
C2 C1 C7 N1 176.6(3)
C6 C1 C7 N1 -7.2(4)
C7 N1 C8 C13 110.2(3)
Co1 N1 C8 C13 -70.2(3)
C7 N1 C8 C9 -74.1(3)
Co1 N1 C8 C9 105.6(3)
C13 C8 C9 C10 2.2(4)
N1 C8 C9 C10 -173.4(2)
C13 C8 C9 C14 179.3(3)
N1 C8 C9 C14 3.7(4)
C8 C9 C10 C11 0.1(4)
C14 C9 C10 C11 -177.0(3)
C9 C10 C11 C12 -1.0(5)
C10 C11 C12 C13 -0.3(4)
C9 C8 C13 C12 -3.5(4)
N1 C8 C13 C12 172.1(2)
C9 C8 C13 C15 175.2(3)
N1 C8 C13 C15 -9.2(4)
C11 C12 C13 C8 2.5(4)
C11 C12 C13 C15 -176.1(3)
Co1 O2 C17 C18 169.79(18)
Co1 O2 C17 C16 -11.6(4)
C21 C16 C17 O2 -178.5(2)
C22 C16 C17 O2 0.2(4)
C21 C16 C17 C18 0.1(4)
C22 C16 C17 C18 178.8(2)
O2 C17 C18 C19 178.6(2)
C16 C17 C18 C19 -0.1(4)
O2 C17 C18 Br2 -1.4(3)
C16 C17 C18 Br2 179.94(18)
C17 C18 C19 C20 -0.2(4)
Br2 C18 C19 C20 179.80(19)
C18 C19 C20 C21 0.4(4)
C18 C19 C20 Cl2 -179.7(2)
C19 C20 C21 C16 -0.4(4)
Cl2 C20 C21 C16 179.75(19)
C17 C16 C21 C20 0.1(4)
C22 C16 C21 C20 -178.7(2)
C23 N2 C22 C16 -179.5(2)
Co1 N2 C22 C16 3.6(4)
C21 C16 C22 N2 -177.4(2)
C17 C16 C22 N2 3.8(4)
C22 N2 C23 C28 -76.9(3)
Co1 N2 C23 C28 100.1(2)
C22 N2 C23 C24 106.8(3)
Co1 N2 C23 C24 -76.1(3)
C28 C23 C24 C25 -2.3(4)
N2 C23 C24 C25 173.9(2)
C28 C23 C24 C29 177.2(3)
N2 C23 C24 C29 -6.6(4)
C23 C24 C25 C26 0.1(4)
C29 C24 C25 C26 -179.4(3)
C24 C25 C26 C27 1.8(5)
C25 C26 C27 C28 -1.6(5)
C26 C27 C28 C23 -0.5(5)
C26 C27 C28 C30 178.3(3)
C24 C23 C28 C27 2.5(4)
N2 C23 C28 C27 -173.7(2)
C24 C23 C28 C30 -176.3(3)
N2 C23 C28 C30 7.6(4)
