#------------------------------------------------------------------------------
#$Date: 2016-03-05 04:07:44 +0200 (Sat, 05 Mar 2016) $
#$Revision: 177592 $
#$URL: svn://www.crystallography.net/cod/cif/2/24/15/2241589.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2241589
loop_
_publ_author_name
'Nimthong-Roldán, Arunpatcha'
'Ratthiwan, Janejira'
'Lakmas, Sawanya'
'Wattanakanjana, Yupa'
_publ_section_title
;
 Crystal structure of
 bis[(acetato-κO)(imidazolidine-2-thione-κS)bis(triphenylphosphane-κP)silver(I)]
 di-μ-imidazolidine-2-thione-κ⁴S:S-bis[(imidazolidine-2-thione-κS)bis(triphenylphosphane-κP)silver(I)]
 diacetate acetonitrile disolvate tetrahydrate
;
_journal_issue                   4
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              444
_journal_page_last               447
_journal_paper_doi               10.1107/S205698901600308X
_journal_volume                  72
_journal_year                    2016
_chemical_formula_iupac
;
[Ag2 (C3 H6 N2 S)4 (C18 H15 P)2] (C2 H3 O2)2,
[Ag (C2 H3 O2) (C3 H6 N2 S) (C18 H15 P)2]2, 2C2 H3 N, 4H2 O
;
_chemical_formula_moiety
;
C48 H54 Ag2 N8 P2 S4 2+, 2(C2 H3 O2 -), 2(C41 H39 Ag N2 O2 P2 S), 2(C2 H3 N),
4(H2 O)
;
_chemical_formula_sum            'C138 H152 Ag4 N14 O12 P6 S6'
_chemical_formula_weight         3008.39
_chemical_name_systematic
;Bis[(acetato-κO)(imidazolidine-2-thione-κS)bis(triphenylphosphane-κP)silver(I)]
di-μ-imidazolidine-2-thione-κ⁴S:S-bis[(imidazolidine-2-thione-κS)bis(triphenylphosphane-κP)silver(I)] diacetate
acetonitrile disolvate tetrahydrate
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-2014/7
_cell_angle_alpha                104.179(2)
_cell_angle_beta                 94.449(2)
_cell_angle_gamma                91.992(2)
_cell_formula_units_Z            1
_cell_length_a                   9.5867(4)
_cell_length_b                   16.3018(7)
_cell_length_c                   22.8548(10)
_cell_measurement_reflns_used    9707
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      30.5516
_cell_measurement_theta_min      2.3993
_cell_volume                     3447.2(3)
_computing_cell_refinement
;
SAINT (Bruker, 2014)
;
_computing_data_collection
;
APEX2 (Bruker, 2014)
;
_computing_data_reduction
;
SAINT (Bruker, 2014)
;
_computing_molecular_graphics
;
Mercury (Macrae et al.,  2008)
;
_computing_publication_material
;
SHELXL2014 (Sheldrick, 2015) and
publCIF (Westrip, 2010)
;
_computing_structure_refinement
;
SHELXL2014 (Sheldrick, 2015) and
SHELXLE (Hübschle et al.,  2011)
;
_computing_structure_solution
;
SHELXS97 (Sheldrick, 2008)
;
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.988
_diffrn_measurement_device_type  'Bruker AXS D8 Quest CMOS'
_diffrn_measurement_method       'ω and φ scans'
_diffrn_radiation_monochromator  'laterally graded multilayer (Goebel) mirror'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0257
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       23
_diffrn_reflns_limit_k_min       -23
_diffrn_reflns_limit_l_max       32
_diffrn_reflns_limit_l_min       -32
_diffrn_reflns_number            71762
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         30.584
_diffrn_reflns_theta_min         2.249
_exptl_absorpt_coefficient_mu    0.784
_exptl_absorpt_correction_T_max  0.903
_exptl_absorpt_correction_T_min  0.882
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
(SADABS; Bruker, 2014)
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.449
_exptl_crystal_description       block
_exptl_crystal_F_000             1548
_exptl_crystal_size_max          0.160
_exptl_crystal_size_mid          0.150
_exptl_crystal_size_min          0.130
_refine_diff_density_max         1.054
_refine_diff_density_min         -0.973
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.259
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     826
_refine_ls_number_reflns         20957
_refine_ls_number_restraints     6
_refine_ls_restrained_S_all      1.259
_refine_ls_R_factor_all          0.0483
_refine_ls_R_factor_gt           0.0421
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0001P)²+7.6382P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0859
_refine_ls_wR_factor_ref         0.0880
_reflns_number_gt                18898
_reflns_number_total             20957
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            wm5275sup1.cif
_cod_data_source_block           I
_cod_database_code               2241589
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.885
_shelx_estimated_absorpt_t_max   0.905
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_occupancy
Ag Ag1 0.35807(2) 0.29775(2) 0.13070(2) 0.01524(4) Uani d 1
Ag Ag2 0.00978(2) 0.12147(2) 0.53974(2) 0.01655(4) Uani d 1
S S1 0.19225(6) 0.01029(4) 0.50712(3) 0.01504(10) Uani d 1
S S2 -0.08966(6) 0.20987(4) 0.47189(3) 0.01634(11) Uani d 1
S S3 0.51845(7) 0.36676(4) 0.07081(3) 0.02254(13) Uani d 1
P P1 0.05184(6) 0.15244(4) 0.64996(3) 0.01168(10) Uani d 1
P P2 0.41455(6) 0.32402(4) 0.24144(3) 0.01230(10) Uani d 1
P P3 0.21550(6) 0.17470(4) 0.07067(3) 0.01362(11) Uani d 1
N N1 0.3296(2) 0.11367(13) 0.45141(10) 0.0187(4) Uani d 1
H H1 0.2904 0.1591 0.4711 0.022 Uiso calc 1
N N2 0.3752(2) -0.01974(14) 0.42198(10) 0.0212(4) Uani d 1
H H2 0.3663 -0.0748 0.4178 0.025 Uiso calc 1
N N3 0.0389(2) 0.34962(14) 0.54878(11) 0.0213(4) Uani d 1
H H3 0.1202 0.3263 0.5496 0.026 Uiso calc 1
N N4 -0.1850(2) 0.36111(14) 0.52721(11) 0.0237(5) Uani d 1
H H4 -0.2693 0.3491 0.5081 0.028 Uiso calc 1
N N5 0.6169(2) 0.53077(15) 0.10791(12) 0.0261(5) Uani d 1
H H5 0.6987 0.5204 0.0935 0.031 Uiso calc 1
N N6 0.4141(2) 0.50600(14) 0.13962(11) 0.0218(4) Uani d 1
H H6 0.3336 0.4795 0.1415 0.026 Uiso calc 1
C C1 0.3025(2) 0.03624(14) 0.45799(10) 0.0140(4) Uani d 1
C C2 0.4331(3) 0.11450(16) 0.40730(11) 0.0200(5) Uani d 1
H H2A 0.5159 0.1527 0.4258 0.024 Uiso calc 1
H H2B 0.3917 0.1322 0.3716 0.024 Uiso calc 1
C C3 0.4719(3) 0.02121(17) 0.39010(12) 0.0213(5) Uani d 1
H H3A 0.4573 -0.0029 0.3458 0.026 Uiso calc 1
H H3B 0.5706 0.0154 0.4041 0.026 Uiso calc 1
C C4 -0.0783(2) 0.31014(15) 0.51795(11) 0.0161(4) Uani d 1
C C5 0.0153(3) 0.43661(19) 0.58100(17) 0.0362(8) Uani d 1
H H5A 0.0616 0.4782 0.5626 0.043 Uiso calc 1
H H5B 0.0499 0.4480 0.6243 0.043 Uiso calc 1
C C6 -0.1436(3) 0.43931(17) 0.57316(14) 0.0265(6) Uani d 1
H H6A -0.1855 0.4400 0.6115 0.032 Uiso calc 1
H H6B -0.1717 0.4896 0.5591 0.032 Uiso calc 1
C C7 0.5159(3) 0.47123(16) 0.10718(12) 0.0190(5) Uani d 1
N N7 0.2420(3) 0.76608(18) 0.14911(13) 0.0381(6) Uani d 1
C C8 0.5723(3) 0.61517(18) 0.13593(16) 0.0312(6) Uani d 1
H H8A 0.5381 0.6447 0.1050 0.037 Uiso calc 1
H H8B 0.6492 0.6504 0.1629 0.037 Uiso calc 1
C C9 0.4533(3) 0.59427(17) 0.17195(13) 0.0246(5) Uani d 1
H H9A 0.4864 0.5991 0.2148 0.030 Uiso calc 1
H H9B 0.3743 0.6313 0.1701 0.030 Uiso calc 1
C C11 -0.0123(2) 0.24930(14) 0.69579(10) 0.0142(4) Uani d 1
C C12 0.0554(3) 0.29479(15) 0.75139(11) 0.0180(4) Uani d 1
H H12 0.1400 0.2756 0.7666 0.022 Uiso calc 1
C C13 -0.0003(3) 0.36812(17) 0.78470(12) 0.0232(5) Uani d 1
H H13 0.0460 0.3985 0.8224 0.028 Uiso calc 1
C C14 -0.1231(3) 0.39624(17) 0.76243(14) 0.0264(6) Uani d 1
H H14 -0.1606 0.4464 0.7847 0.032 Uiso calc 1
C C15 -0.1915(3) 0.35125(17) 0.70770(14) 0.0261(6) Uani d 1
H H15 -0.2767 0.3703 0.6930 0.031 Uiso calc 1
C C16 -0.1362(3) 0.27823(16) 0.67406(12) 0.0207(5) Uani d 1
H H16 -0.1831 0.2482 0.6363 0.025 Uiso calc 1
C C21 0.2363(2) 0.15765(14) 0.67815(10) 0.0136(4) Uani d 1
C C22 0.2822(3) 0.13182(16) 0.72991(11) 0.0175(4) Uani d 1
H H22 0.2181 0.1040 0.7494 0.021 Uiso calc 1
C C23 0.4223(3) 0.14682(17) 0.75313(12) 0.0222(5) Uani d 1
H H23 0.4528 0.1304 0.7889 0.027 Uiso calc 1
C C24 0.5172(3) 0.18550(17) 0.72422(12) 0.0229(5) Uani d 1
H H24 0.6122 0.1965 0.7405 0.027 Uiso calc 1
C C25 0.4728(3) 0.20824(17) 0.67126(12) 0.0212(5) Uani d 1
H H25 0.5384 0.2333 0.6508 0.025 Uiso calc 1
C C26 0.3329(2) 0.19467(15) 0.64797(11) 0.0170(4) Uani d 1
H H26 0.3032 0.2104 0.6118 0.020 Uiso calc 1
C C31 -0.0272(2) 0.06841(14) 0.67890(10) 0.0131(4) Uani d 1
C C30 0.3989(2) 0.33050(16) 0.51551(11) 0.0175(4) Uani d 1
C C32 -0.1146(2) 0.08315(16) 0.72606(11) 0.0175(4) Uani d 1
H H32 -0.1337 0.1395 0.7457 0.021 Uiso calc 1
C C33 -0.1739(3) 0.01499(18) 0.74438(12) 0.0225(5) Uani d 1
H H33 -0.2336 0.0251 0.7764 0.027 Uiso calc 1
C C34 -0.1459(3) -0.06732(18) 0.71596(12) 0.0235(5) Uani d 1
H H34 -0.1862 -0.1134 0.7287 0.028 Uiso calc 1
C C35 -0.0590(3) -0.08267(16) 0.66897(12) 0.0218(5) Uani d 1
H H35 -0.0397 -0.1392 0.6497 0.026 Uiso calc 1
C C36 -0.0004(3) -0.01517(15) 0.65027(11) 0.0172(4) Uani d 1
H H36 0.0582 -0.0258 0.6179 0.021 Uiso calc 1
C C41 0.5210(2) 0.42249(15) 0.27211(10) 0.0145(4) Uani d 1
C C40 0.3705(3) 0.41859(18) 0.50781(15) 0.0291(6) Uani d 1
H H40A 0.4002 0.4241 0.4688 0.044 Uiso calc 1
H H40B 0.4229 0.4611 0.5407 0.044 Uiso calc 1
H H40C 0.2700 0.4273 0.5089 0.044 Uiso calc 1
C C42 0.6444(3) 0.43300(16) 0.24514(12) 0.0190(5) Uani d 1
H H42 0.6721 0.3887 0.2135 0.023 Uiso calc 1
C C43 0.7267(3) 0.50853(17) 0.26481(13) 0.0232(5) Uani d 1
H H43 0.8117 0.5149 0.2472 0.028 Uiso calc 1
C C44 0.6852(3) 0.57443(17) 0.30988(13) 0.0251(5) Uani d 1
H H44 0.7412 0.6259 0.3229 0.030 Uiso calc 1
C C45 0.5623(3) 0.56490(16) 0.33580(12) 0.0237(5) Uani d 1
H H45 0.5330 0.6103 0.3662 0.028 Uiso calc 1
C C46 0.4808(3) 0.48901(16) 0.31759(11) 0.0195(5) Uani d 1
H H46 0.3973 0.4826 0.3363 0.023 Uiso calc 1
C C51 0.5182(2) 0.24246(15) 0.26282(10) 0.0141(4) Uani d 1
C C50 0.0661(2) 0.41834(15) 0.11199(11) 0.0161(4) Uani d 1
C C52 0.4795(3) 0.15807(15) 0.23323(11) 0.0171(4) Uani d 1
H H52 0.4037 0.1458 0.2025 0.021 Uiso calc 1
C C53 0.5502(3) 0.09187(17) 0.24805(12) 0.0217(5) Uani d 1
H H53 0.5226 0.0348 0.2277 0.026 Uiso calc 1
C C54 0.6620(3) 0.10971(17) 0.29293(12) 0.0218(5) Uani d 1
H H54 0.7109 0.0648 0.3032 0.026 Uiso calc 1
C C55 0.7016(3) 0.19306(18) 0.32251(12) 0.0227(5) Uani d 1
H H55 0.7778 0.2050 0.3530 0.027 Uiso calc 1
C C56 0.6304(3) 0.25949(17) 0.30779(11) 0.0195(5) Uani d 1
H H56 0.6581 0.3164 0.3283 0.023 Uiso calc 1
C C61 0.2704(2) 0.33088(14) 0.29028(10) 0.0138(4) Uani d 1
C C60 -0.0750(3) 0.39096(18) 0.12854(13) 0.0230(5) Uani d 1
H H60A -0.1242 0.3505 0.0935 0.034 Uiso calc 1
H H60B -0.1308 0.4406 0.1405 0.034 Uiso calc 1
H H60C -0.0614 0.3641 0.1624 0.034 Uiso calc 1
C C62 0.2795(3) 0.30307(16) 0.34366(11) 0.0178(4) Uani d 1
H H62 0.3643 0.2817 0.3566 0.021 Uiso calc 1
C C63 0.1651(3) 0.30661(16) 0.37794(11) 0.0193(5) Uani d 1
H H63 0.1717 0.2873 0.4140 0.023 Uiso calc 1
C C64 0.0407(3) 0.33849(16) 0.35943(11) 0.0199(5) Uani d 1
H H64 -0.0376 0.3406 0.3827 0.024 Uiso calc 1
C C65 0.0315(3) 0.36712(18) 0.30680(12) 0.0223(5) Uani d 1
H H65 -0.0528 0.3897 0.2945 0.027 Uiso calc 1
C C66 0.1455(3) 0.36293(17) 0.27185(11) 0.0188(5) Uani d 1
H H66 0.1382 0.3818 0.2356 0.023 Uiso calc 1
C C71 0.2823(2) 0.07331(15) 0.07579(10) 0.0159(4) Uani d 1
C C72 0.4256(3) 0.06359(19) 0.07134(13) 0.0255(5) Uani d 1
H H72 0.4830 0.1080 0.0640 0.031 Uiso calc 1
C C73 0.4845(3) -0.0111(2) 0.07757(15) 0.0324(6) Uani d 1
H H73 0.5818 -0.0176 0.0740 0.039 Uiso calc 1
C C74 0.4020(3) -0.07579(19) 0.08886(13) 0.0299(6) Uani d 1
H H74 0.4428 -0.1263 0.0937 0.036 Uiso calc 1
C C75 0.2597(3) -0.06688(18) 0.09311(13) 0.0283(6) Uani d 1
H H75 0.2027 -0.1115 0.1004 0.034 Uiso calc 1
C C76 0.2004(3) 0.00746(17) 0.08673(12) 0.0224(5) Uani d 1
H H76 0.1028 0.0133 0.0899 0.027 Uiso calc 1
C C81 0.0388(2) 0.17016(15) 0.09452(11) 0.0161(4) Uani d 1
C C82 0.0243(3) 0.17916(18) 0.15620(12) 0.0234(5) Uani d 1
H H82 0.1054 0.1864 0.1840 0.028 Uiso calc 1
C C83 -0.1077(3) 0.1775(2) 0.17707(13) 0.0307(6) Uani d 1
H H83 -0.1167 0.1828 0.2189 0.037 Uiso calc 1
C C84 -0.2265(3) 0.1683(2) 0.13677(14) 0.0336(7) Uani d 1
H H84 -0.3169 0.1678 0.1510 0.040 Uiso calc 1
C C85 -0.2131(3) 0.1599(2) 0.07591(14) 0.0320(7) Uani d 1
H H85 -0.2947 0.1537 0.0485 0.038 Uiso calc 1
C C86 -0.0806(3) 0.16040(18) 0.05428(12) 0.0238(5) Uani d 1
H H86 -0.0723 0.1541 0.0123 0.029 Uiso calc 1
C C91 0.1855(2) 0.16749(15) -0.00985(10) 0.0146(4) Uani d 1
C C92 0.1600(2) 0.09072(16) -0.05353(11) 0.0168(4) Uani d 1
H H92 0.1673 0.0387 -0.0421 0.020 Uiso calc 1
C C93 0.1239(3) 0.09019(18) -0.11384(11) 0.0218(5) Uani d 1
H H93 0.1083 0.0379 -0.1436 0.026 Uiso calc 1
C C94 0.1108(3) 0.16631(18) -0.13052(11) 0.0231(5) Uani d 1
H H94 0.0826 0.1659 -0.1714 0.028 Uiso calc 1
C C95 0.1388(3) 0.24292(17) -0.08762(12) 0.0224(5) Uani d 1
H H95 0.1314 0.2948 -0.0993 0.027 Uiso calc 1
C C96 0.1776(3) 0.24370(16) -0.02761(11) 0.0197(5) Uani d 1
H H96 0.1989 0.2961 0.0015 0.024 Uiso calc 1
O O1 0.29782(18) 0.28441(11) 0.52369(8) 0.0178(3) Uani d 1
O O2 0.52335(19) 0.30909(13) 0.51366(10) 0.0287(4) Uani d 1
O O4 0.17335(17) 0.40868(11) 0.14454(8) 0.0181(3) Uani d 1
O O6 0.0685(2) 0.45087(16) 0.06758(10) 0.0339(5) Uani d 1
O O7 -0.1503(2) 0.54379(13) 0.04566(9) 0.0258(4) Uani d 1
H H7A -0.088(3) 0.5092(18) 0.0496(16) 0.031 Uiso d 1
H H7B -0.153(4) 0.543(2) 0.0086(6) 0.031 Uiso d 1
O O8 0.6376(2) 0.17707(13) 0.54856(9) 0.0254(4) Uani d 1
H H8C 0.591(3) 0.2133(17) 0.5363(15) 0.030 Uiso d 1
H H8D 0.699(3) 0.172(2) 0.5241(12) 0.030 Uiso d 1
C C10 0.2216(3) 0.71407(19) 0.10551(14) 0.0289(6) Uani d 1
C C20 0.1970(4) 0.6458(2) 0.05039(15) 0.0396(8) Uani d 1
H H20A 0.1073 0.6525 0.0288 0.059 Uiso calc 1
H H20B 0.1943 0.5911 0.0610 0.059 Uiso calc 1
H H20C 0.2728 0.6480 0.0243 0.059 Uiso calc 1
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_3
_geom_angle
P3 Ag1 P2 . 123.16(2)
P3 Ag1 S3 . 114.75(2)
P2 Ag1 S3 . 118.40(2)
P3 Ag1 O4 . 99.89(4)
P2 Ag1 O4 . 91.92(4)
S3 Ag1 O4 . 97.56(4)
P1 Ag2 S2 . 130.88(2)
P1 Ag2 S1 . 100.98(2)
S2 Ag2 S1 . 122.99(2)
P1 Ag2 S1 2_556 112.706(19)
S2 Ag2 S1 2_556 92.547(19)
S1 Ag2 S1 2_556 86.195(19)
C1 S1 Ag2 . 113.31(8)
C1 S1 Ag2 2_556 117.47(8)
Ag2 S1 Ag2 2_556 93.806(19)
C4 S2 Ag2 . 103.55(8)
C7 S3 Ag1 . 101.86(9)
C11 P1 C21 . 103.14(10)
C11 P1 C31 . 103.96(10)
C21 P1 C31 . 103.77(10)
C11 P1 Ag2 . 119.00(8)
C21 P1 Ag2 . 114.48(8)
C31 P1 Ag2 . 110.90(7)
C51 P2 C41 . 104.65(11)
C51 P2 C61 . 102.56(10)
C41 P2 C61 . 104.66(11)
C51 P2 Ag1 . 113.13(8)
C41 P2 Ag1 . 111.70(7)
C61 P2 Ag1 . 118.76(7)
C91 P3 C71 . 105.22(11)
C91 P3 C81 . 103.32(11)
C71 P3 C81 . 103.63(11)
C91 P3 Ag1 . 116.27(8)
C71 P3 Ag1 . 114.34(8)
C81 P3 Ag1 . 112.68(8)
C1 N1 C2 . 111.9(2)
C1 N1 H1 . 124.0
C2 N1 H1 . 124.0
C1 N2 C3 . 111.8(2)
C1 N2 H2 . 124.1
C3 N2 H2 . 124.1
C4 N3 C5 . 111.5(2)
C4 N3 H3 . 124.3
C5 N3 H3 . 124.3
C4 N4 C6 . 111.2(2)
C4 N4 H4 . 124.4
C6 N4 H4 . 124.4
C7 N5 C8 . 110.7(2)
C7 N5 H5 . 124.6
C8 N5 H5 . 124.6
C7 N6 C9 . 111.3(2)
C7 N6 H6 . 124.4
C9 N6 H6 . 124.4
N1 C1 N2 . 110.7(2)
N1 C1 S1 . 125.64(18)
N2 C1 S1 . 123.62(18)
N1 C2 C3 . 102.27(19)
N1 C2 H2A . 111.3
C3 C2 H2A . 111.3
N1 C2 H2B . 111.3
C3 C2 H2B . 111.3
H2A C2 H2B . 109.2
N2 C3 C2 . 102.88(19)
N2 C3 H3A . 111.2
C2 C3 H3A . 111.2
N2 C3 H3B . 111.2
C2 C3 H3B . 111.2
H3A C3 H3B . 109.1
N3 C4 N4 . 110.2(2)
N3 C4 S2 . 124.90(19)
N4 C4 S2 . 124.93(19)
N3 C5 C6 . 102.7(2)
N3 C5 H5A . 111.2
C6 C5 H5A . 111.2
N3 C5 H5B . 111.2
C6 C5 H5B . 111.2
H5A C5 H5B . 109.1
N4 C6 C5 . 102.9(2)
N4 C6 H6A . 111.2
C5 C6 H6A . 111.2
N4 C6 H6B . 111.2
C5 C6 H6B . 111.2
H6A C6 H6B . 109.1
N6 C7 N5 . 109.7(2)
N6 C7 S3 . 125.12(19)
N5 C7 S3 . 125.2(2)
N5 C8 C9 . 101.7(2)
N5 C8 H8A . 111.4
C9 C8 H8A . 111.4
N5 C8 H8B . 111.4
C9 C8 H8B . 111.4
H8A C8 H8B . 109.3
N6 C9 C8 . 101.2(2)
N6 C9 H9A . 111.5
C8 C9 H9A . 111.5
N6 C9 H9B . 111.5
C8 C9 H9B . 111.5
H9A C9 H9B . 109.4
C16 C11 C12 . 119.0(2)
C16 C11 P1 . 117.51(18)
C12 C11 P1 . 123.49(18)
C13 C12 C11 . 120.6(2)
C13 C12 H12 . 119.7
C11 C12 H12 . 119.7
C14 C13 C12 . 119.7(2)
C14 C13 H13 . 120.2
C12 C13 H13 . 120.2
C13 C14 C15 . 120.1(2)
C13 C14 H14 . 120.0
C15 C14 H14 . 120.0
C14 C15 C16 . 120.5(3)
C14 C15 H15 . 119.7
C16 C15 H15 . 119.7
C11 C16 C15 . 120.0(2)
C11 C16 H16 . 120.0
C15 C16 H16 . 120.0
C22 C21 C26 . 119.6(2)
C22 C21 P1 . 122.98(18)
C26 C21 P1 . 117.27(17)
C21 C22 C23 . 120.0(2)
C21 C22 H22 . 120.0
C23 C22 H22 . 120.0
C24 C23 C22 . 120.4(2)
C24 C23 H23 . 119.8
C22 C23 H23 . 119.8
C23 C24 C25 . 119.7(2)
C23 C24 H24 . 120.2
C25 C24 H24 . 120.2
C24 C25 C26 . 120.6(2)
C24 C25 H25 . 119.7
C26 C25 H25 . 119.7
C25 C26 C21 . 119.6(2)
C25 C26 H26 . 120.2
C21 C26 H26 . 120.2
C32 C31 C36 . 119.2(2)
C32 C31 P1 . 123.68(18)
C36 C31 P1 . 117.06(17)
O2 C30 O1 . 124.5(2)
O2 C30 C40 . 117.0(2)
O1 C30 C40 . 118.5(2)
C31 C32 C33 . 120.0(2)
C31 C32 H32 . 120.0
C33 C32 H32 . 120.0
C34 C33 C32 . 120.2(2)
C34 C33 H33 . 119.9
C32 C33 H33 . 119.9
C33 C34 C35 . 120.2(2)
C33 C34 H34 . 119.9
C35 C34 H34 . 119.9
C34 C35 C36 . 119.9(2)
C34 C35 H35 . 120.1
C36 C35 H35 . 120.1
C35 C36 C31 . 120.4(2)
C35 C36 H36 . 119.8
C31 C36 H36 . 119.8
C46 C41 C42 . 119.1(2)
C46 C41 P2 . 123.41(19)
C42 C41 P2 . 117.39(18)
C30 C40 H40A . 109.5
C30 C40 H40B . 109.5
H40A C40 H40B . 109.5
C30 C40 H40C . 109.5
H40A C40 H40C . 109.5
H40B C40 H40C . 109.5
C43 C42 C41 . 119.9(2)
C43 C42 H42 . 120.0
C41 C42 H42 . 120.0
C44 C43 C42 . 120.5(2)
C44 C43 H43 . 119.8
C42 C43 H43 . 119.8
C45 C44 C43 . 119.7(2)
C45 C44 H44 . 120.1
C43 C44 H44 . 120.1
C44 C45 C46 . 120.4(2)
C44 C45 H45 . 119.8
C46 C45 H45 . 119.8
C41 C46 C45 . 120.4(2)
C41 C46 H46 . 119.8
C45 C46 H46 . 119.8
C52 C51 C56 . 118.8(2)
C52 C51 P2 . 117.31(17)
C56 C51 P2 . 123.89(19)
O6 C50 O4 . 124.2(2)
O6 C50 C60 . 118.0(2)
O4 C50 C60 . 117.7(2)
C53 C52 C51 . 121.0(2)
C53 C52 H52 . 119.5
C51 C52 H52 . 119.5
C52 C53 C54 . 119.6(2)
C52 C53 H53 . 120.2
C54 C53 H53 . 120.2
C55 C54 C53 . 120.0(2)
C55 C54 H54 . 120.0
C53 C54 H54 . 120.0
C54 C55 C56 . 120.5(2)
C54 C55 H55 . 119.8
C56 C55 H55 . 119.8
C55 C56 C51 . 120.2(2)
C55 C56 H56 . 119.9
C51 C56 H56 . 119.9
C66 C61 C62 . 119.4(2)
C66 C61 P2 . 117.91(17)
C62 C61 P2 . 122.62(18)
C50 C60 H60A . 109.5
C50 C60 H60B . 109.5
H60A C60 H60B . 109.5
C50 C60 H60C . 109.5
H60A C60 H60C . 109.5
H60B C60 H60C . 109.5
C63 C62 C61 . 120.4(2)
C63 C62 H62 . 119.8
C61 C62 H62 . 119.8
C62 C63 C64 . 120.1(2)
C62 C63 H63 . 120.0
C64 C63 H63 . 120.0
C65 C64 C63 . 119.9(2)
C65 C64 H64 . 120.1
C63 C64 H64 . 120.1
C64 C65 C66 . 120.4(2)
C64 C65 H65 . 119.8
C66 C65 H65 . 119.8
C65 C66 C61 . 119.9(2)
C65 C66 H66 . 120.1
C61 C66 H66 . 120.1
C76 C71 C72 . 118.8(2)
C76 C71 P3 . 123.77(19)
C72 C71 P3 . 117.33(19)
C73 C72 C71 . 120.2(3)
C73 C72 H72 . 119.9
C71 C72 H72 . 119.9
C74 C73 C72 . 120.3(3)
C74 C73 H73 . 119.8
C72 C73 H73 . 119.8
C73 C74 C75 . 119.9(3)
C73 C74 H74 . 120.1
C75 C74 H74 . 120.1
C74 C75 C76 . 120.0(3)
C74 C75 H75 . 120.0
C76 C75 H75 . 120.0
C71 C76 C75 . 120.8(3)
C71 C76 H76 . 119.6
C75 C76 H76 . 119.6
C86 C81 C82 . 119.3(2)
C86 C81 P3 . 122.70(18)
C82 C81 P3 . 118.02(19)
C83 C82 C81 . 120.5(3)
C83 C82 H82 . 119.7
C81 C82 H82 . 119.7
C84 C83 C82 . 119.9(3)
C84 C83 H83 . 120.0
C82 C83 H83 . 120.0
C85 C84 C83 . 119.9(3)
C85 C84 H84 . 120.0
C83 C84 H84 . 120.0
C84 C85 C86 . 120.6(3)
C84 C85 H85 . 119.7
C86 C85 H85 . 119.7
C81 C86 C85 . 119.7(2)
C81 C86 H86 . 120.1
C85 C86 H86 . 120.1
C92 C91 C96 . 119.3(2)
C92 C91 P3 . 123.29(18)
C96 C91 P3 . 117.23(18)
C93 C92 C91 . 120.2(2)
C93 C92 H92 . 119.9
C91 C92 H92 . 119.9
C94 C93 C92 . 120.0(2)
C94 C93 H93 . 120.0
C92 C93 H93 . 120.0
C95 C94 C93 . 120.2(2)
C95 C94 H94 . 119.9
C93 C94 H94 . 119.9
C94 C95 C96 . 120.0(2)
C94 C95 H95 . 120.0
C96 C95 H95 . 120.0
C95 C96 C91 . 120.3(2)
C95 C96 H96 . 119.9
C91 C96 H96 . 119.9
C50 O4 Ag1 . 132.75(16)
H7A O7 H7B . 104(3)
H8C O8 H8D . 99(3)
N7 C10 C20 . 178.5(3)
C10 C20 H20A . 109.5
C10 C20 H20B . 109.5
H20A C20 H20B . 109.5
C10 C20 H20C . 109.5
H20A C20 H20C . 109.5
H20B C20 H20C . 109.5
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
Ag1 P3 . 2.4381(6)
Ag1 P2 . 2.4744(6)
Ag1 S3 . 2.5424(7)
Ag1 O4 . 2.5564(17)
Ag2 P1 . 2.4431(6)
Ag2 S2 . 2.5200(6)
Ag2 S1 . 2.5810(6)
Ag2 S1 2_556 2.7883(6)
S1 C1 . 1.715(2)
S1 Ag2 2_556 2.7883(6)
S2 C4 . 1.708(3)
S3 C7 . 1.704(3)
P1 C11 . 1.824(2)
P1 C21 . 1.826(2)
P1 C31 . 1.827(2)
P2 C51 . 1.824(2)
P2 C41 . 1.826(2)
P2 C61 . 1.832(2)
P3 C91 . 1.814(2)
P3 C71 . 1.820(3)
P3 C81 . 1.824(2)
N1 C1 . 1.327(3)
N1 C2 . 1.470(3)
N1 H1 . 0.8800
N2 C1 . 1.327(3)
N2 C3 . 1.462(3)
N2 H2 . 0.8800
N3 C4 . 1.333(3)
N3 C5 . 1.463(3)
N3 H3 . 0.8800
N4 C4 . 1.337(3)
N4 C6 . 1.460(4)
N4 H4 . 0.8800
N5 C7 . 1.343(3)
N5 C8 . 1.462(4)
N5 H5 . 0.8800
N6 C7 . 1.330(3)
N6 C9 . 1.468(3)
N6 H6 . 0.8800
C2 C3 . 1.541(4)
C2 H2A . 0.9900
C2 H2B . 0.9900
C3 H3A . 0.9900
C3 H3B . 0.9900
C5 C6 . 1.523(4)
C5 H5A . 0.9900
C5 H5B . 0.9900
C6 H6A . 0.9900
C6 H6B . 0.9900
N7 C10 . 1.138(4)
C8 C9 . 1.533(4)
C8 H8A . 0.9900
C8 H8B . 0.9900
C9 H9A . 0.9900
C9 H9B . 0.9900
C11 C16 . 1.394(3)
C11 C12 . 1.401(3)
C12 C13 . 1.398(3)
C12 H12 . 0.9500
C13 C14 . 1.384(4)
C13 H13 . 0.9500
C14 C15 . 1.386(4)
C14 H14 . 0.9500
C15 C16 . 1.396(4)
C15 H15 . 0.9500
C16 H16 . 0.9500
C21 C22 . 1.395(3)
C21 C26 . 1.400(3)
C22 C23 . 1.396(3)
C22 H22 . 0.9500
C23 C24 . 1.385(4)
C23 H23 . 0.9500
C24 C25 . 1.391(4)
C24 H24 . 0.9500
C25 C26 . 1.394(3)
C25 H25 . 0.9500
C26 H26 . 0.9500
C31 C32 . 1.396(3)
C31 C36 . 1.402(3)
C30 O2 . 1.255(3)
C30 O1 . 1.259(3)
C30 C40 . 1.520(4)
C32 C33 . 1.398(4)
C32 H32 . 0.9500
C33 C34 . 1.385(4)
C33 H33 . 0.9500
C34 C35 . 1.390(4)
C34 H34 . 0.9500
C35 C36 . 1.391(3)
C35 H35 . 0.9500
C36 H36 . 0.9500
C41 C46 . 1.394(3)
C41 C42 . 1.400(3)
C40 H40A . 0.9800
C40 H40B . 0.9800
C40 H40C . 0.9800
C42 C43 . 1.395(3)
C42 H42 . 0.9500
C43 C44 . 1.387(4)
C43 H43 . 0.9500
C44 C45 . 1.380(4)
C44 H44 . 0.9500
C45 C46 . 1.395(4)
C45 H45 . 0.9500
C46 H46 . 0.9500
C51 C52 . 1.399(3)
C51 C56 . 1.399(3)
C50 O6 . 1.256(3)
C50 O4 . 1.259(3)
C50 C60 . 1.514(3)
C52 C53 . 1.390(3)
C52 H52 . 0.9500
C53 C54 . 1.395(4)
C53 H53 . 0.9500
C54 C55 . 1.386(4)
C54 H54 . 0.9500
C55 C56 . 1.395(4)
C55 H55 . 0.9500
C56 H56 . 0.9500
C61 C66 . 1.399(3)
C61 C62 . 1.399(3)
C60 H60A . 0.9800
C60 H60B . 0.9800
C60 H60C . 0.9800
C62 C63 . 1.392(3)
C62 H62 . 0.9500
C63 C64 . 1.394(4)
C63 H63 . 0.9500
C64 C65 . 1.391(4)
C64 H64 . 0.9500
C65 C66 . 1.397(3)
C65 H65 . 0.9500
C66 H66 . 0.9500
C71 C76 . 1.391(3)
C71 C72 . 1.397(3)
C72 C73 . 1.394(4)
C72 H72 . 0.9500
C73 C74 . 1.382(5)
C73 H73 . 0.9500
C74 C75 . 1.385(4)
C74 H74 . 0.9500
C75 C76 . 1.391(4)
C75 H75 . 0.9500
C76 H76 . 0.9500
C81 C86 . 1.391(3)
C81 C82 . 1.400(3)
C82 C83 . 1.388(4)
C82 H82 . 0.9500
C83 C84 . 1.387(5)
C83 H83 . 0.9500
C84 C85 . 1.380(4)
C84 H84 . 0.9500
C85 C86 . 1.398(4)
C85 H85 . 0.9500
C86 H86 . 0.9500
C91 C92 . 1.397(3)
C91 C96 . 1.401(3)
C92 C93 . 1.393(3)
C92 H92 . 0.9500
C93 C94 . 1.391(4)
C93 H93 . 0.9500
C94 C95 . 1.389(4)
C94 H94 . 0.9500
C95 C96 . 1.390(3)
C95 H95 . 0.9500
C96 H96 . 0.9500
O7 H7A . 0.848(10)
O7 H7B . 0.844(10)
O8 H8C . 0.842(10)
O8 H8D . 0.837(10)
C10 C20 . 1.459(4)
C20 H20A . 0.9800
C20 H20B . 0.9800
C20 H20C . 0.9800
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_site_symmetry_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
N1 H1 O1 . 0.88 2.10 2.908(3) 152.8
N2 H2 O8 2_656 0.88 2.00 2.808(3) 152.1
N3 H3 O1 . 0.88 1.94 2.780(3) 159.5
N4 H4 O2 1_455 0.88 2.09 2.864(3) 145.8
N5 H5 O7 1_655 0.88 1.96 2.767(3) 151.6
N6 H6 O4 . 0.88 1.91 2.780(3) 172.2
O7 H7A O6 . 0.848(10) 1.878(12) 2.716(3) 169(4)
O7 H7B O6 2_565 0.844(10) 1.999(18) 2.782(3) 154(3)
O8 H8C O2 . 0.842(10) 1.881(13) 2.709(3) 167(3)
O8 H8D S2 1_655 0.837(10) 2.561(16) 3.357(2) 159(3)
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion_site_symmetry_1
_geom_torsion
C2 N1 C1 N2 . -0.9(3)
C2 N1 C1 S1 . 177.63(18)
C3 N2 C1 N1 . 5.0(3)
C3 N2 C1 S1 . -173.59(18)
Ag2 S1 C1 N1 . 22.0(2)
Ag2 S1 C1 N1 2_556 129.75(19)
Ag2 S1 C1 N2 . -159.64(18)
Ag2 S1 C1 N2 2_556 -51.9(2)
C1 N1 C2 C3 . -3.1(3)
C1 N2 C3 C2 . -6.6(3)
N1 C2 C3 N2 . 5.5(3)
C5 N3 C4 N4 . -2.1(3)
C5 N3 C4 S2 . 176.5(2)
C6 N4 C4 N3 . -6.6(3)
C6 N4 C4 S2 . 174.8(2)
Ag2 S2 C4 N3 . 54.9(2)
Ag2 S2 C4 N4 . -126.7(2)
C4 N3 C5 C6 . 9.1(4)
C4 N4 C6 C5 . 11.8(3)
N3 C5 C6 N4 . -11.9(3)
C9 N6 C7 N5 . -7.6(3)
C9 N6 C7 S3 . 171.8(2)
C8 N5 C7 N6 . -8.6(3)
C8 N5 C7 S3 . 172.0(2)
Ag1 S3 C7 N6 . -23.8(2)
Ag1 S3 C7 N5 . 155.5(2)
C7 N5 C8 C9 . 19.8(3)
C7 N6 C9 C8 . 19.2(3)
N5 C8 C9 N6 . -22.1(3)
C21 P1 C11 C16 . 160.75(19)
C31 P1 C11 C16 . -91.2(2)
Ag2 P1 C11 C16 . 32.7(2)
C21 P1 C11 C12 . -20.0(2)
C31 P1 C11 C12 . 88.0(2)
Ag2 P1 C11 C12 . -148.05(18)
C16 C11 C12 C13 . 0.0(4)
P1 C11 C12 C13 . -179.19(19)
C11 C12 C13 C14 . -0.3(4)
C12 C13 C14 C15 . 0.8(4)
C13 C14 C15 C16 . -1.1(4)
C12 C11 C16 C15 . -0.3(4)
P1 C11 C16 C15 . 178.9(2)
C14 C15 C16 C11 . 0.9(4)
C11 P1 C21 C22 . 82.9(2)
C31 P1 C21 C22 . -25.3(2)
Ag2 P1 C21 C22 . -146.29(18)
C11 P1 C21 C26 . -92.77(19)
C31 P1 C21 C26 . 159.03(18)
Ag2 P1 C21 C26 . 38.0(2)
C26 C21 C22 C23 . 3.3(4)
P1 C21 C22 C23 . -172.32(19)
C21 C22 C23 C24 . -1.5(4)
C22 C23 C24 C25 . -1.0(4)
C23 C24 C25 C26 . 1.8(4)
C24 C25 C26 C21 . -0.1(4)
C22 C21 C26 C25 . -2.4(4)
P1 C21 C26 C25 . 173.39(19)
C11 P1 C31 C32 . -0.4(2)
C21 P1 C31 C32 . 107.2(2)
Ag2 P1 C31 C32 . -129.43(18)
C11 P1 C31 C36 . 177.69(18)
C21 P1 C31 C36 . -74.73(19)
Ag2 P1 C31 C36 . 48.66(19)
C36 C31 C32 C33 . 0.2(3)
P1 C31 C32 C33 . 178.25(19)
C31 C32 C33 C34 . 0.2(4)
C32 C33 C34 C35 . -0.2(4)
C33 C34 C35 C36 . -0.2(4)
C34 C35 C36 C31 . 0.6(4)
C32 C31 C36 C35 . -0.6(4)
P1 C31 C36 C35 . -178.78(19)
C51 P2 C41 C46 . -115.2(2)
C61 P2 C41 C46 . -7.7(2)
Ag1 P2 C41 C46 . 122.04(19)
C51 P2 C41 C42 . 69.4(2)
C61 P2 C41 C42 . 176.87(19)
Ag1 P2 C41 C42 . -53.4(2)
C46 C41 C42 C43 . 1.4(4)
P2 C41 C42 C43 . 177.1(2)
C41 C42 C43 C44 . -1.8(4)
C42 C43 C44 C45 . 0.6(4)
C43 C44 C45 C46 . 1.0(4)
C42 C41 C46 C45 . 0.1(4)
P2 C41 C46 C45 . -175.3(2)
C44 C45 C46 C41 . -1.3(4)
C41 P2 C51 C52 . -164.80(18)
C61 P2 C51 C52 . 86.16(19)
Ag1 P2 C51 C52 . -43.0(2)
C41 P2 C51 C56 . 17.0(2)
C61 P2 C51 C56 . -92.1(2)
Ag1 P2 C51 C56 . 138.78(19)
C56 C51 C52 C53 . 0.2(4)
P2 C51 C52 C53 . -178.08(19)
C51 C52 C53 C54 . -0.3(4)
C52 C53 C54 C55 . 0.1(4)
C53 C54 C55 C56 . 0.1(4)
C54 C55 C56 C51 . -0.1(4)
C52 C51 C56 C55 . 0.0(4)
P2 C51 C56 C55 . 178.18(19)
C51 P2 C61 C66 . -156.93(19)
C41 P2 C61 C66 . 94.0(2)
Ag1 P2 C61 C66 . -31.4(2)
C51 P2 C61 C62 . 21.0(2)
C41 P2 C61 C62 . -88.0(2)
Ag1 P2 C61 C62 . 146.59(17)
C66 C61 C62 C63 . 0.5(4)
P2 C61 C62 C63 . -177.46(19)
C61 C62 C63 C64 . -0.4(4)
C62 C63 C64 C65 . -0.3(4)
C63 C64 C65 C66 . 1.0(4)
C64 C65 C66 C61 . -0.9(4)
C62 C61 C66 C65 . 0.2(4)
P2 C61 C66 C65 . 178.2(2)
C91 P3 C71 C76 . -99.6(2)
C81 P3 C71 C76 . 8.6(2)
Ag1 P3 C71 C76 . 131.61(19)
C91 P3 C71 C72 . 83.7(2)
C81 P3 C71 C72 . -168.2(2)
Ag1 P3 C71 C72 . -45.1(2)
C76 C71 C72 C73 . 0.2(4)
P3 C71 C72 C73 . 177.2(2)
C71 C72 C73 C74 . -0.7(5)
C72 C73 C74 C75 . 1.0(5)
C73 C74 C75 C76 . -0.7(4)
C72 C71 C76 C75 . 0.0(4)
P3 C71 C76 C75 . -176.8(2)
C74 C75 C76 C71 . 0.3(4)
C91 P3 C81 C86 . 1.9(2)
C71 P3 C81 C86 . -107.7(2)
Ag1 P3 C81 C86 . 128.2(2)
C91 P3 C81 C82 . -176.4(2)
C71 P3 C81 C82 . 74.0(2)
Ag1 P3 C81 C82 . -50.1(2)
C86 C81 C82 C83 . 0.6(4)
P3 C81 C82 C83 . 179.0(2)
C81 C82 C83 C84 . -1.0(5)
C82 C83 C84 C85 . 0.6(5)
C83 C84 C85 C86 . 0.2(5)
C82 C81 C86 C85 . 0.1(4)
P3 C81 C86 C85 . -178.1(2)
C84 C85 C86 C81 . -0.5(5)
C71 P3 C91 C92 . 25.0(2)
C81 P3 C91 C92 . -83.4(2)
Ag1 P3 C91 C92 . 152.64(17)
C71 P3 C91 C96 . -159.91(19)
C81 P3 C91 C96 . 91.7(2)
Ag1 P3 C91 C96 . -32.3(2)
C96 C91 C92 C93 . -1.5(3)
P3 C91 C92 C93 . 173.51(19)
C91 C92 C93 C94 . -1.1(4)
C92 C93 C94 C95 . 2.5(4)
C93 C94 C95 C96 . -1.1(4)
C94 C95 C96 C91 . -1.5(4)
C92 C91 C96 C95 . 2.8(4)
P3 C91 C96 C95 . -172.5(2)
O6 C50 O4 Ag1 . -80.3(3)
C60 C50 O4 Ag1 . 101.4(2)

_cod_database_fobs_code 2241589
