#------------------------------------------------------------------------------
#$Date: 2016-09-06 13:40:02 +0300 (Tue, 06 Sep 2016) $
#$Revision: 186180 $
#$URL: file:///home/coder/svn-repositories/cod/cif/2/24/18/2241838.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2241838
loop_
_publ_author_name
'Lee, See Mun'
'Lo, Kong Mun'
'Tan, Sang Loon'
'Tiekink, Edward R. T.'
_publ_section_title
;
 (Tris{2-[(5-chloro-2-oxidobenzylidene-κO)amino-κN]ethyl}amine)ytterbium(III):
 crystal structure and Hirshfeld surface analysis
;
_journal_coeditor_code           HB7612
_journal_issue                   10
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              1390
_journal_page_last               1395
_journal_paper_doi               10.1107/S2056989016013748
_journal_volume                  72
_journal_year                    2016
_chemical_formula_moiety         'C27 H24 Cl3 N4 O3 Yb'
_chemical_formula_sum            'C27 H24 Cl3 N4 O3 Yb'
_chemical_formula_weight         731.89
_chemical_name_systematic
(Tris{2-[(5-chloro-2-oxidobenzylidene-κO)amino-κN]ethyl}amine)ytterbium(III)
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_cell_angle_alpha                90
_cell_angle_beta                 101.2210(10)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   10.0452(2)
_cell_length_b                   13.1510(2)
_cell_length_c                   21.0926(4)
_cell_measurement_reflns_used    9874
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      30.49
_cell_measurement_theta_min      2.51
_cell_volume                     2733.16(9)
_computing_cell_refinement
;
SMART (Bruker, 2008)
;
_computing_data_collection
;
SMART (Bruker, 2008)
;
_computing_data_reduction
;
SAINT (Bruker, 2008)
;
_computing_molecular_graphics
;
ORTEP-3 for Windows (Farrugia, 2012), QMol (Gans & Shalloway,
2001) and
DIAMOND (Brandenburg, 2006)
;
_computing_publication_material
;
publCIF (Westrip, 2010)
;
_computing_structure_refinement
;
SHELXL2014 (Sheldrick, 2015)
;
_computing_structure_solution
;
SHELXS97 (Sheldrick, 2008)
;
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.944
_diffrn_measurement_device_type  'Bruker SMART APEX CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0283
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       30
_diffrn_reflns_limit_l_min       -30
_diffrn_reflns_number            29037
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         30.516
_diffrn_reflns_theta_min         1.835
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    3.752
_exptl_absorpt_correction_T_max  0.864
_exptl_absorpt_correction_T_min  0.337
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
(SADABS; Sheldrick, 1996)
;
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.779
_exptl_crystal_description       needle
_exptl_crystal_F_000             1436
_exptl_crystal_size_max          0.37
_exptl_crystal_size_mid          0.06
_exptl_crystal_size_min          0.04
_refine_diff_density_max         1.652
_refine_diff_density_min         -0.445
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.053
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     343
_refine_ls_number_reflns         7882
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.053
_refine_ls_R_factor_all          0.0341
_refine_ls_R_factor_gt           0.0224
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0236P)²+2.0547P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0491
_refine_ls_wR_factor_ref         0.0545
_reflns_number_gt                6584
_reflns_number_total             7882
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            hb7612sup1.cif
_cod_data_source_block           I
_cod_database_code               2241838
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.337
_shelx_estimated_absorpt_t_max   0.864
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_occupancy
Yb Yb 0.46352(2) 0.75973(2) 0.57731(2) 0.01267(3) Uani d 1
Cl Cl1 0.12533(9) 1.28195(5) 0.58909(5) 0.0416(2) Uani d 1
Cl Cl2 -0.02898(6) 0.51120(5) 0.75694(3) 0.02505(14) Uani d 1
Cl Cl3 0.36458(6) 0.53255(4) 0.23696(3) 0.01926(12) Uani d 1
O O1 0.29667(17) 0.85663(12) 0.58719(8) 0.0167(3) Uani d 1
O O2 0.33581(17) 0.62842(12) 0.58381(8) 0.0164(3) Uani d 1
O O3 0.38891(18) 0.76939(12) 0.47425(8) 0.0159(3) Uani d 1
N N1 0.7240(2) 0.76956(14) 0.63698(10) 0.0151(4) Uani d 1
N N2 0.5557(2) 0.93115(14) 0.58045(10) 0.0154(4) Uani d 1
N N3 0.4951(2) 0.72213(14) 0.69249(10) 0.0148(4) Uani d 1
N N4 0.6072(2) 0.64484(14) 0.52919(10) 0.0148(4) Uani d 1
C C1 0.7729(2) 0.87631(18) 0.64050(12) 0.0175(5) Uani d 1
H H1A 0.8721 0.8773 0.6424 0.021 Uiso calc 1
H H1B 0.7546 0.9087 0.6803 0.021 Uiso calc 1
C C2 0.7024(2) 0.93543(18) 0.58208(13) 0.0184(5) Uani d 1
H H2A 0.7338 1.0069 0.5851 0.022 Uiso calc 1
H H2B 0.7234 0.9053 0.5422 0.022 Uiso calc 1
C C3 0.4962(3) 1.01700(17) 0.58504(12) 0.0171(5) Uani d 1
H H3 0.5514 1.0762 0.5881 0.021 Uiso calc 1
C C4 0.3547(3) 1.03227(17) 0.58600(11) 0.0164(5) Uani d 1
C C5 0.3105(3) 1.13402(18) 0.58747(12) 0.0208(5) Uani d 1
H H5 0.3743 1.1880 0.5900 0.025 Uiso calc 1
C C6 0.1758(3) 1.15543(19) 0.58521(14) 0.0246(6) Uani d 1
C C7 0.0807(3) 1.0776(2) 0.58029(14) 0.0252(6) Uani d 1
H H7 -0.0127 1.0932 0.5772 0.030 Uiso calc 1
C C8 0.1222(3) 0.97781(19) 0.57992(13) 0.0217(5) Uani d 1
H H8 0.0562 0.9253 0.5766 0.026 Uiso calc 1
C C9 0.2601(2) 0.95123(17) 0.58435(11) 0.0148(4) Uani d 1
C C10 0.7392(3) 0.72872(18) 0.70367(12) 0.0178(5) Uani d 1
H H10A 0.8250 0.7538 0.7304 0.021 Uiso calc 1
H H10B 0.7432 0.6535 0.7026 0.021 Uiso calc 1
C C11 0.6200(3) 0.76202(18) 0.73361(12) 0.0176(5) Uani d 1
H H11A 0.6300 0.7347 0.7780 0.021 Uiso calc 1
H H11B 0.6163 0.8371 0.7357 0.021 Uiso calc 1
C C12 0.4136(2) 0.67362(17) 0.72151(12) 0.0162(5) Uani d 1
H H12 0.4367 0.6702 0.7673 0.019 Uiso calc 1
C C13 0.2894(2) 0.62359(17) 0.69055(12) 0.0158(5) Uani d 1
C C14 0.2018(3) 0.59174(17) 0.73117(13) 0.0177(5) Uani d 1
H H14 0.2243 0.6056 0.7762 0.021 Uiso calc 1
C C15 0.0842(3) 0.54082(18) 0.70628(13) 0.0190(5) Uani d 1
C C16 0.0522(2) 0.51588(17) 0.64104(13) 0.0187(5) Uani d 1
H H16 -0.0277 0.4782 0.6245 0.022 Uiso calc 1
C C17 0.1368(2) 0.54595(17) 0.60038(13) 0.0176(5) Uani d 1
H H17 0.1141 0.5285 0.5559 0.021 Uiso calc 1
C C18 0.2572(2) 0.60244(16) 0.62333(12) 0.0157(5) Uani d 1
C C19 0.8079(3) 0.70835(18) 0.60012(12) 0.0178(5) Uani d 1
H H19A 0.8942 0.6891 0.6289 0.021 Uiso calc 1
H H19B 0.8297 0.7496 0.5642 0.021 Uiso calc 1
C C20 0.7321(3) 0.61317(18) 0.57314(12) 0.0176(5) Uani d 1
H H20A 0.7890 0.5719 0.5495 0.021 Uiso calc 1
H H20B 0.7098 0.5714 0.6087 0.021 Uiso calc 1
C C21 0.5862(2) 0.60742(17) 0.47208(12) 0.0164(5) Uani d 1
H H21 0.6498 0.5586 0.4632 0.020 Uiso calc 1
C C22 0.4753(2) 0.63213(17) 0.41975(11) 0.0137(4) Uani d 1
C C23 0.4692(3) 0.57793(17) 0.36155(12) 0.0164(5) Uani d 1
H H23 0.5354 0.5275 0.3586 0.020 Uiso calc 1
C C24 0.3680(3) 0.59760(17) 0.30922(12) 0.0161(5) Uani d 1
C C25 0.2680(3) 0.66999(18) 0.31321(12) 0.0175(5) Uani d 1
H H25 0.1961 0.6813 0.2774 0.021 Uiso calc 1
C C26 0.2742(2) 0.72490(17) 0.36935(12) 0.0159(5) Uani d 1
H H26 0.2058 0.7739 0.3716 0.019 Uiso calc 1
C C27 0.3794(2) 0.71038(17) 0.42369(12) 0.0147(4) Uani d 1
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Yb Yb -0.3850 5.5486 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_publ_flag
O1 Yb N2 75.38(6) y
O2 Yb N3 74.91(6) y
O3 Yb N4 74.67(6) y
O1 Yb N4 160.51(7) y
O2 Yb N2 164.04(7) y
O3 Yb N3 165.13(7) y
O1 Yb O3 86.46(6) ?
O1 Yb O2 89.08(6) ?
O3 Yb O2 90.96(6) ?
O3 Yb N2 91.64(6) ?
O1 Yb N3 88.64(7) ?
N2 Yb N3 100.70(7) ?
O2 Yb N4 86.47(6) ?
N2 Yb N4 109.39(7) ?
N3 Yb N4 108.41(7) ?
O1 Yb N1 129.46(6) ?
O3 Yb N1 125.89(6) ?
O2 Yb N1 122.97(6) ?
N2 Yb N1 67.08(6) ?
N3 Yb N1 67.39(7) ?
N4 Yb N1 67.84(6) ?
C9 O1 Yb 141.74(16) ?
C27 O3 Yb 137.88(15) ?
C18 O2 Yb 133.58(15) ?
C1 N1 C10 108.82(19) ?
C1 N1 C19 108.78(19) ?
C10 N1 C19 109.54(18) ?
C1 N1 Yb 110.66(14) ?
C10 N1 Yb 109.81(14) ?
C19 N1 Yb 109.20(14) ?
C3 N2 C2 116.2(2) ?
C3 N2 Yb 129.32(17) ?
C2 N2 Yb 114.26(14) ?
C12 N3 C11 116.4(2) ?
C12 N3 Yb 127.19(17) ?
C11 N3 Yb 116.37(15) ?
C21 N4 C20 116.7(2) ?
C21 N4 Yb 128.79(16) ?
C20 N4 Yb 114.50(15) ?
N1 C1 C2 110.35(19) ?
N1 C1 H1A 109.6 ?
C2 C1 H1A 109.6 ?
N1 C1 H1B 109.6 ?
C2 C1 H1B 109.6 ?
H1A C1 H1B 108.1 ?
N2 C2 C1 107.95(19) ?
N2 C2 H2A 110.1 ?
C1 C2 H2A 110.1 ?
N2 C2 H2B 110.1 ?
C1 C2 H2B 110.1 ?
H2A C2 H2B 108.4 ?
N2 C3 C4 126.6(2) ?
N2 C3 H3 116.7 ?
C4 C3 H3 116.7 ?
C5 C4 C9 119.9(2) ?
C5 C4 C3 116.6(2) ?
C9 C4 C3 123.5(2) ?
C6 C5 C4 120.3(2) ?
C6 C5 H5 119.8 ?
C4 C5 H5 119.8 ?
C5 C6 C7 120.6(2) ?
C5 C6 Cl1 119.1(2) ?
C7 C6 Cl1 120.2(2) ?
C8 C7 C6 119.8(3) ?
C8 C7 H7 120.1 ?
C6 C7 H7 120.1 ?
C7 C8 C9 121.9(2) ?
C7 C8 H8 119.0 ?
C9 C8 H8 119.0 ?
O1 C9 C8 120.4(2) ?
O1 C9 C4 122.4(2) ?
C8 C9 C4 117.2(2) ?
N1 C10 C11 110.14(19) ?
N1 C10 H10A 109.6 ?
C11 C10 H10A 109.6 ?
N1 C10 H10B 109.6 ?
C11 C10 H10B 109.6 ?
H10A C10 H10B 108.1 ?
N3 C11 C10 107.5(2) ?
N3 C11 H11A 110.2 ?
C10 C11 H11A 110.2 ?
N3 C11 H11B 110.2 ?
C10 C11 H11B 110.2 ?
H11A C11 H11B 108.5 ?
N3 C12 C13 125.8(2) ?
N3 C12 H12 117.1 ?
C13 C12 H12 117.1 ?
C14 C13 C18 120.2(2) ?
C14 C13 C12 116.5(2) ?
C18 C13 C12 123.2(2) ?
C15 C14 C13 120.5(2) ?
C15 C14 H14 119.8 ?
C13 C14 H14 119.8 ?
C14 C15 C16 120.7(2) ?
C14 C15 Cl2 119.3(2) ?
C16 C15 Cl2 120.01(19) ?
C17 C16 C15 119.8(2) ?
C17 C16 H16 120.1 ?
C15 C16 H16 120.1 ?
C16 C17 C18 121.7(2) ?
C16 C17 H17 119.2 ?
C18 C17 H17 119.2 ?
O2 C18 C13 122.7(2) ?
O2 C18 C17 120.1(2) ?
C13 C18 C17 117.1(2) ?
N1 C19 C20 110.4(2) ?
N1 C19 H19A 109.6 ?
C20 C19 H19A 109.6 ?
N1 C19 H19B 109.6 ?
C20 C19 H19B 109.6 ?
H19A C19 H19B 108.1 ?
N4 C20 C19 107.91(19) ?
N4 C20 H20A 110.1 ?
C19 C20 H20A 110.1 ?
N4 C20 H20B 110.1 ?
C19 C20 H20B 110.1 ?
H20A C20 H20B 108.4 ?
N4 C21 C22 126.4(2) ?
N4 C21 H21 116.8 ?
C22 C21 H21 116.8 ?
C23 C22 C27 120.1(2) ?
C23 C22 C21 116.6(2) ?
C27 C22 C21 123.2(2) ?
C24 C23 C22 120.3(2) ?
C24 C23 H23 119.8 ?
C22 C23 H23 119.8 ?
C23 C24 C25 120.6(2) ?
C23 C24 Cl3 119.79(19) ?
C25 C24 Cl3 119.66(19) ?
C26 C25 C24 119.7(2) ?
C26 C25 H25 120.1 ?
C24 C25 H25 120.1 ?
C25 C26 C27 121.9(2) ?
C25 C26 H26 119.1 ?
C27 C26 H26 119.1 ?
O3 C27 C26 120.4(2) ?
O3 C27 C22 122.3(2) ?
C26 C27 C22 117.3(2) ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_publ_flag
Yb O1 2.1476(16) y
Yb O2 2.1715(16) y
Yb O3 2.1608(17) y
Yb N1 2.677(2) y
Yb N2 2.4331(19) y
Yb N3 2.439(2) y
Yb N4 2.442(2) y
Cl1 C6 1.746(2) ?
Cl2 C15 1.749(3) ?
Cl3 C24 1.742(2) ?
O1 C9 1.295(3) ?
O3 C27 1.307(3) ?
O2 C18 1.300(3) ?
N1 C1 1.484(3) ?
N1 C10 1.485(3) ?
N1 C19 1.489(3) ?
N2 C3 1.290(3) ?
N2 C2 1.469(3) ?
N3 C12 1.283(3) ?
N3 C11 1.476(3) ?
N4 C21 1.280(3) ?
N4 C20 1.468(3) ?
C1 C2 1.511(3) ?
C1 H1A 0.9900 ?
C1 H1B 0.9900 ?
C2 H2A 0.9900 ?
C2 H2B 0.9900 ?
C3 C4 1.440(3) ?
C3 H3 0.9500 ?
C4 C5 1.412(3) ?
C4 C9 1.424(3) ?
C5 C6 1.374(4) ?
C5 H5 0.9500 ?
C6 C7 1.390(4) ?
C7 C8 1.377(4) ?
C7 H7 0.9500 ?
C8 C9 1.414(3) ?
C8 H8 0.9500 ?
C10 C11 1.522(4) ?
C10 H10A 0.9900 ?
C10 H10B 0.9900 ?
C11 H11A 0.9900 ?
C11 H11B 0.9900 ?
C12 C13 1.449(3) ?
C12 H12 0.9500 ?
C13 C14 1.406(3) ?
C13 C18 1.419(3) ?
C14 C15 1.371(4) ?
C14 H14 0.9500 ?
C15 C16 1.390(4) ?
C16 C17 1.378(4) ?
C16 H16 0.9500 ?
C17 C18 1.421(3) ?
C17 H17 0.9500 ?
C19 C20 1.517(3) ?
C19 H19A 0.9900 ?
C19 H19B 0.9900 ?
C20 H20A 0.9900 ?
C20 H20B 0.9900 ?
C21 C22 1.445(3) ?
C21 H21 0.9500 ?
C22 C23 1.410(3) ?
C22 C27 1.423(3) ?
C23 C24 1.372(3) ?
C23 H23 0.9500 ?
C24 C25 1.398(3) ?
C25 C26 1.378(3) ?
C25 H25 0.9500 ?
C26 C27 1.412(3) ?
C26 H26 0.9500 ?
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_site_symmetry_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
C3 H3 O3 3_676 0.95 2.55 3.369(3) 144
C23 H23 O2 3_666 0.95 2.60 3.413(3) 144
C2 H2B Cg1 3_676 0.99 2.88 3.744(3) 146
C24 Cl3 Cg1 4_564 1.742(2) 3.4747(12) 5.109(3) 155.16(10)
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
C10 N1 C1 C2 -153.1(2)
C19 N1 C1 C2 87.6(2)
Yb N1 C1 C2 -32.3(2)
C3 N2 C2 C1 118.2(2)
Yb N2 C2 C1 -57.5(2)
N1 C1 C2 N2 58.5(3)
C2 N2 C3 C4 -178.6(2)
Yb N2 C3 C4 -3.6(4)
N2 C3 C4 C5 -176.3(2)
N2 C3 C4 C9 2.5(4)
C9 C4 C5 C6 -2.1(4)
C3 C4 C5 C6 176.8(2)
C4 C5 C6 C7 -1.2(4)
C4 C5 C6 Cl1 178.5(2)
C5 C6 C7 C8 2.3(4)
Cl1 C6 C7 C8 -177.3(2)
C6 C7 C8 C9 -0.1(4)
Yb O1 C9 C8 165.02(19)
Yb O1 C9 C4 -15.5(4)
C7 C8 C9 O1 176.5(2)
C7 C8 C9 C4 -3.1(4)
C5 C4 C9 O1 -175.4(2)
C3 C4 C9 O1 5.8(4)
C5 C4 C9 C8 4.1(3)
C3 C4 C9 C8 -174.7(2)
C1 N1 C10 C11 81.9(2)
C19 N1 C10 C11 -159.25(19)
Yb N1 C10 C11 -39.3(2)
C12 N3 C11 C10 129.8(2)
Yb N3 C11 C10 -51.8(2)
N1 C10 C11 N3 59.8(2)
C11 N3 C12 C13 -176.5(2)
Yb N3 C12 C13 5.3(3)
N3 C12 C13 C14 -168.2(2)
N3 C12 C13 C18 14.6(4)
C18 C13 C14 C15 -0.6(3)
C12 C13 C14 C15 -177.9(2)
C13 C14 C15 C16 2.8(4)
C13 C14 C15 Cl2 -174.95(18)
C14 C15 C16 C17 -2.5(4)
Cl2 C15 C16 C17 175.23(18)
C15 C16 C17 C18 0.0(3)
Yb O2 C18 C13 -36.9(3)
Yb O2 C18 C17 146.44(17)
C14 C13 C18 O2 -178.7(2)
C12 C13 C18 O2 -1.5(3)
C14 C13 C18 C17 -1.9(3)
C12 C13 C18 C17 175.2(2)
C16 C17 C18 O2 179.0(2)
C16 C17 C18 C13 2.2(3)
C1 N1 C19 C20 -158.2(2)
C10 N1 C19 C20 83.0(2)
Yb N1 C19 C20 -37.3(2)
C21 N4 C20 C19 126.9(2)
Yb N4 C20 C19 -54.7(2)
N1 C19 C20 N4 61.0(3)
C20 N4 C21 C22 -176.0(2)
Yb N4 C21 C22 5.9(4)
N4 C21 C22 C23 -177.3(2)
N4 C21 C22 C27 6.0(4)
C27 C22 C23 C24 -2.4(3)
C21 C22 C23 C24 -179.2(2)
C22 C23 C24 C25 -1.4(4)
C22 C23 C24 Cl3 178.20(18)
C23 C24 C25 C26 2.6(4)
Cl3 C24 C25 C26 -176.95(19)
C24 C25 C26 C27 0.0(4)
Yb O3 C27 C26 151.26(19)
Yb O3 C27 C22 -31.0(4)
C25 C26 C27 O3 174.3(2)
C25 C26 C27 C22 -3.6(3)
C23 C22 C27 O3 -173.0(2)
C21 C22 C27 O3 3.5(4)
C23 C22 C27 C26 4.8(3)
C21 C22 C27 C26 -178.6(2)

_cod_database_fobs_code 2241838
