#------------------------------------------------------------------------------
#$Date: 2019-03-01 05:54:06 +0200 (Fri, 01 Mar 2019) $
#$Revision: 213917 $
#$URL: file:///home/coder/svn-repositories/cod/cif/2/24/28/2242861.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2242861
loop_
_publ_author_name
'Cigler, Andrew J.'
'Kaduk, James A.'
_publ_section_title
;
 Crystal structure of dilithium potassium citrate, Li₂KC₆H₅O₇
 determined from powder diffraction data and DFT calculations
;
_journal_coeditor_code           HB7800
_journal_issue                   3
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              410
_journal_page_last               413
_journal_paper_doi               10.1107/S2056989019002809
_journal_volume                  75
_journal_year                    2019
_chemical_formula_iupac          '[Li2 K (C6 H5 O7)]'
_chemical_formula_moiety         'C6 H5 K Li2 O7'
_chemical_formula_structural     'Li2 K C6 H5 O7'
_chemical_formula_sum            'C6 H5 K Li2 O7'
_chemical_formula_weight         242.08
_chemical_name_common            'dilithium potassium citrate'
_chemical_name_systematic        'dilithium potassium citrate'
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_audit_creation_method           'from EXP file using GSAS2CIF'
_cell_angle_alpha                87.637(4)
_cell_angle_beta                 80.606(4)
_cell_angle_gamma                83.109(4)
_cell_formula_units_Z            2
_cell_length_a                   6.4842(3)
_cell_length_b                   6.6833(3)
_cell_length_c                   9.8171(4)
_cell_measurement_temperature    302
_cell_volume                     416.59(3)
_computing_data_collection
;
Data Collector (PANalytical, 2011)
;
_computing_data_reduction
;
PowDLL (Kourkoumelis, 2013)
;
_computing_molecular_graphics
;
Mercury (Macrae et al.,  2008), DIAMOND (Putz & Brandenburg,
2015)
;
_computing_publication_material
;
publCIF (Westrip, 2010)
;
_computing_structure_refinement
;
GSAS (Larson & Von Dreele, 2004)
;
_computing_structure_solution
;
EXPO2014 (Altomare et al.,  2013)
;
_diffrn_ambient_temperature      302
_diffrn_detector                 'Si strip'
_diffrn_measurement_device_type  'PANalytical Empyrean'
_diffrn_radiation_probe          x-ray
_diffrn_source                   'sealed X-ray tube'
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  1.00000
_exptl_absorpt_process_details
;   GSAS Absorption/surface roughness correction: function number 0
 No correction is applied.
;
_exptl_crystal_density_diffrn    1.930
_pd_block_id                     2019-01-12T10:23|KADU1665|James_A._Kaduk|NCCPAN
_pd_calc_method                  'Rietveld Refinement'
_pd_char_colour                  white
_pd_instr_dist_spec/detc         240
_pd_instr_dist_src/spec          240
_pd_meas_2theta_range_inc        0.01671
_pd_meas_2theta_range_max        49.98834
_pd_meas_2theta_range_min        1.0084
_pd_meas_number_of_points        2932
_pd_meas_scan_method             step
_pd_phase_name                   'Li2 K C6 H5 O7'
_pd_prep_temperature             423
_pd_proc_2theta_range_inc        0.01671
_pd_proc_2theta_range_max        49.98834
_pd_proc_2theta_range_min        1.0084
_pd_proc_info_datetime           2019-01-12T10:23:27
_pd_proc_info_excluded_regions
;
1-3 degrees.  The asymmetry of the low-angle peak made it hard to model.
;
_pd_proc_ls_background_function
;   GSAS Background function number 1 with  1 terms.
 Shifted Chebyshev function of 1st kind
      1:    2122.50
;
_pd_proc_ls_peak_cutoff          0.01000
_pd_proc_ls_profile_function
;
CW Profile function number 3 with  19 terms
Pseudovoigt profile coefficients as parameterized in
Thompson <i>et al.</i> (1987).
Asymmetry correction of Finger <i>et al.</i> (1994).
;
_pd_proc_ls_prof_R_factor        0.0162
_pd_proc_ls_prof_wR_expected     0.0134
_pd_proc_ls_prof_wR_factor       0.0214
_pd_proc_number_of_points        2932
_pd_spec_mounting                'glass capillary'
_pd_spec_mount_mode              transmission
_pd_spec_shape                   cylinder
_pd_spec_size_axial              12
_pd_spec_size_equat              1
_pd_spec_size_thick              1
_refine_ls_goodness_of_fit_all   1.65
_refine_ls_hydrogen_treatment    refU
_refine_ls_matrix_type           full
_refine_ls_number_constraints    3
_refine_ls_number_parameters     79
_refine_ls_number_restraints     29
_refine_ls_shift/su_max          0.06
_refine_ls_shift/su_mean         0.00
_refine_ls_weighting_scheme      sigma
_reflns_number_total             1564
_cod_data_source_file            hb7800sup1.cif
_cod_data_source_block           KADU1665_publ
_cod_original_cell_volume        416.59(2)
_cod_database_code               2242861
loop_
_symmetry_equiv_pos_site_id
_symmetry_equiv_pos_as_xyz
1 +x,+y,+z
2 -x,-y,-z
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_thermal_displace_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
C C1 -0.155(3) 0.066(3) 0.3268(18) 0.060(3) Uiso 1.0 2
C C2 -0.029(3) 0.232(3) 0.353(2) 0.023(5) Uiso 1.0 2
C C3 0.187(3) 0.251(2) 0.2633(18) 0.023(5) Uiso 1.0 2
C C4 0.246(3) 0.429(3) 0.3377(18) 0.023(5) Uiso 1.0 2
C C5 0.435(3) 0.528(3) 0.268(2) 0.060(3) Uiso 1.0 2
C C6 0.118(4) 0.348(3) 0.129(2) 0.060(3) Uiso 1.0 2
H H7 -0.00317 0.21693 0.46524 0.030(7) Uiso 1.0 2
H H8 -0.12279 0.38491 0.33912 0.030(7) Uiso 1.0 2
H H9 0.27605 0.37435 0.44502 0.030(7) Uiso 1.0 2
H H10 0.10903 0.55430 0.35021 0.030(7) Uiso 1.0 2
O O11 -0.309(2) 0.025(2) 0.4174(18) 0.060(3) Uiso 1.0 2
O O12 -0.108(2) -0.033(2) 0.2162(14) 0.060(3) Uiso 1.0 2
O O13 0.536(3) 0.667(3) 0.2988(15) 0.060(3) Uiso 1.0 2
O O14 0.547(3) 0.4306(19) 0.1691(15) 0.060(3) Uiso 1.0 2
O O15 0.006(3) 0.520(2) 0.1405(14) 0.060(3) Uiso 1.0 2
O O16 0.208(3) 0.215(2) 0.0417(16) 0.060(3) Uiso 1.0 2
O O17 0.327(2) 0.073(2) 0.2251(17) 0.060(3) Uiso 1.0 2
H H18 0.47033 0.13035 0.22684 0.069(3) Uiso 1.0 2
K K19 0.7405(10) 0.1861(9) -0.0297(6) 0.046(3) Uiso 1.0 2
Li Li20 0.743(9) 0.746(7) 0.163(5) 0.05 Uiso 1.0 2
Li Li21 -0.449(8) 0.101(7) 0.638(5) 0.05 Uiso 1.0 2
loop_
_atom_type_symbol
_atom_type_number_in_cell
_atom_type_scat_Cromer_Mann_a1
_atom_type_scat_Cromer_Mann_a2
_atom_type_scat_Cromer_Mann_a3
_atom_type_scat_Cromer_Mann_a4
_atom_type_scat_Cromer_Mann_b1
_atom_type_scat_Cromer_Mann_b2
_atom_type_scat_Cromer_Mann_b3
_atom_type_scat_Cromer_Mann_b4
_atom_type_scat_Cromer_Mann_c
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C 12.0 2.31000 20.8439 1.02000 10.2075 1.58860 0.56870 0.86500 51.6512 0.21560
0.000 0.000 International_Tables_Vol_C
H 10.0 0.49300 10.5109 0.32291 26.1257 0.14019 3.14236 0.04081 57.7997 0.00304
0.000 0.000 International_Tables_Vol_C
O 14.0 3.04850 13.2771 2.28680 5.70110 1.54630 0.32390 0.86700 32.9089 0.25080
0.000 0.000 International_Tables_Vol_C
K 2.0 8.21860 12.7949 7.43980 0.77480 1.05190 213.187 0.86590 41.6841 1.42280
0.000 0.000 International_Tables_Vol_C
Li 4.0 1.12820 3.95460 0.75080 1.05240 0.61750 85.3905 0.46530 168.261 0.03770
0.000 0.000 International_Tables_Vol_C
Si 0.0 6.29150 2.43860 3.03530 32.3337 1.98910 0.67850 1.54100 81.6937 1.14070
0.000 0.000 International_Tables_Vol_C
loop_
_diffrn_radiation_type
_diffrn_radiation_wavelength
K\a~1~ 0.709237
K\a~2~ 0.713647
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
_geom_angle_publ_flag
C2 C1 O11 1_555 1_555 119.6(15) n
C2 C1 O12 1_555 1_555 120.5(15) n
O11 C1 O12 1_555 1_555 119.9(17) n
C1 C2 C3 1_555 1_555 120.0(15) n
C2 C3 C4 1_555 1_555 97.8(12) n
C2 C3 C6 1_555 1_555 100.9(16) n
C2 C3 O17 1_555 1_555 119.5(14) n
C4 C3 C6 1_555 1_555 104.0(16) n
C4 C3 O17 1_555 1_555 124.1(16) n
C6 C3 O17 1_555 1_555 107.4(13) n
C3 C4 C5 1_555 1_555 116.9(15) n
C4 C5 O13 1_555 1_555 135.4(16) n
C4 C5 O14 1_555 1_555 114.8(16) n
O13 C5 O14 1_555 1_555 108.1(16) n
C3 C6 O15 1_555 1_555 116.7(14) n
C3 C6 O16 1_555 1_555 100.0(13) n
O15 C6 O16 1_555 1_555 143.3(19) n
C1 O11 Li21 1_555 1_555 139.(2) n
C1 O11 Li21 1_555 2_456 121.(3) n
Li21 O11 Li21 1_555 2_456 99.(2) n
C1 O12 K19 1_555 1_455 113.4(18) n
C1 O12 K19 1_555 2_655 139.2(14) n
C1 O12 Li20 1_555 1_445 126.4(19) n
K19 O12 K19 1_455 2_655 86.9(4) n
K19 O12 Li20 1_455 1_445 83.9(18) n
K19 O12 Li20 2_655 1_445 89.2(16) n
C5 O13 Li20 1_555 1_555 116.(2) n
C5 O13 Li21 1_555 2_566 131.(3) n
Li20 O13 Li21 1_555 2_566 97.(3) n
C5 O14 K19 1_555 1_555 171.2(13) n
C6 O15 K19 1_555 2_665 108.2(17) n
C6 O15 Li20 1_555 1_455 162.(2) n
K19 O15 Li20 2_665 1_455 88.7(14) n
C6 O16 K19 1_555 1_455 85.9(16) n
C6 O16 K19 1_555 2_655 137.0(15) n
C6 O16 Li20 1_555 2_665 125.(2) n
K19 O16 K19 1_455 2_655 85.7(5) n
K19 O16 Li20 1_455 2_665 78.7(18) n
K19 O16 Li20 2_655 2_665 93.8(16) n
C3 O17 K19 1_555 2_655 122.5(11) n
C3 O17 Li21 1_555 2_556 122.(2) n
K19 O17 Li21 2_655 2_556 104.8(14) n
O12 K19 O12 1_655 2_655 93.1(4) n
O12 K19 O14 1_655 1_555 80.2(4) n
O12 K19 O15 1_655 2_665 112.5(5) n
O12 K19 O16 1_655 1_655 58.1(4) n
O12 K19 O16 1_655 2_655 64.6(5) n
O12 K19 O17 1_655 2_655 112.6(6) n
O12 K19 O14 2_655 1_555 151.6(4) n
O12 K19 O15 2_655 2_665 66.0(4) n
O12 K19 O16 2_655 1_655 59.4(4) n
O12 K19 O16 2_655 2_655 66.9(5) n
O12 K19 O17 2_655 2_655 64.5(5) n
O14 K19 O15 1_555 2_665 90.9(4) n
O14 K19 O16 1_555 1_655 94.4(5) n
O14 K19 O16 1_555 2_655 131.2(5) n
O14 K19 O17 1_555 2_655 143.4(5) n
O15 K19 O16 2_665 1_655 56.1(4) n
O15 K19 O16 2_665 2_655 132.5(6) n
O15 K19 O17 2_665 2_655 112.9(5) n
O16 K19 O16 1_655 2_655 94.3(5) n
O16 K19 O17 1_655 2_655 121.7(5) n
O16 K19 O17 2_655 2_655 48.0(5) n
O12 Li20 O13 1_665 1_555 114.(3) n
O12 Li20 O15 1_665 1_655 97.(3) n
O12 Li20 O16 1_665 2_665 100.(3) n
O13 Li20 O15 1_555 1_655 110.(2) n
O13 Li20 O16 1_555 2_665 138.(3) n
O15 Li20 O16 1_655 2_665 88.(2) n
O11 Li21 O13 1_555 2_566 127.(3) n
O11 Li21 O17 1_555 2_556 114.(2) n
O11 Li21 O13 2_556 2_566 110.(3) n
O11 Li21 O17 2_456 2_556 109.(2) n
O13 Li21 O17 2_566 2_556 111.(3) n
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
C1 C2 1_555 1.5101(16) n
C1 O11 1_555 1.274(5) n
C1 O12 1_555 1.273(5) n
C2 C1 1_555 1.5101(16) n
C2 C3 1_555 1.5407(16) n
C3 C2 1_555 1.5407(16) n
C3 C4 1_555 1.5404(16) n
C3 C6 1_555 1.5507(16) n
C3 O17 1_555 1.433(5) n
C4 C3 1_555 1.5404(16) n
C4 C5 1_555 1.5099(16) n
C5 C4 1_555 1.5099(16) n
C5 O13 1_555 1.271(5) n
C5 O14 1_555 1.270(5) n
C6 C3 1_555 1.5507(16) n
C6 O15 1_555 1.281(5) n
C6 O16 1_555 1.286(5) n
O11 C1 1_555 1.274(5) n
O11 Li21 1_555 2.26(5) n
O11 Li21 2_456 2.02(4) n
O12 C1 1_555 1.273(5) n
O12 K19 1_455 3.015(17) n
O12 K19 2_655 2.865(12) n
O12 Li20 1_445 1.99(5) n
O13 C5 1_555 1.271(5) n
O13 O14 1_555 2.06(2) n
O13 K19 2_665 3.473(16) n
O13 Li20 1_555 1.84(5) n
O13 Li21 2_566 1.69(4) n
O14 C5 1_555 1.270(5) n
O14 O13 1_555 2.06(2) n
O14 K19 1_555 2.650(12) n
O14 K19 2_665 3.364(16) n
O14 Li20 1_555 2.58(6) n
O15 C6 1_555 1.281(5) n
O15 K19 1_455 3.593(15) n
O15 K19 2_665 2.784(17) n
O15 Li20 1_455 2.12(5) n
O16 C3 1_555 2.18(2) n
O16 C6 1_555 1.286(5) n
O16 K19 1_455 3.251(19) n
O16 K19 1_555 3.39(2) n
O16 K19 2_655 2.664(15) n
O16 Li20 2_665 1.99(5) n
O17 C3 1_555 1.433(5) n
O17 K19 1_555 3.488(17) n
O17 K19 2_655 2.756(16) n
O17 Li21 2_556 1.95(4) n
K19 O12 1_655 3.015(17) n
K19 O12 2_655 2.865(12) n
K19 O13 2_665 3.473(16) n
K19 O14 1_555 2.650(12) n
K19 O14 2_665 3.364(16) n
K19 O15 1_655 3.593(15) n
K19 O15 2_665 2.784(17) n
K19 O16 1_555 3.39(2) n
K19 O16 1_655 3.251(19) n
K19 O16 2_655 2.664(15) n
K19 O17 1_555 3.488(17) n
K19 O17 2_655 2.756(16) n
Li20 O12 1_665 1.99(5) n
Li20 O13 1_555 1.84(5) n
Li20 O14 1_555 2.58(6) n
Li20 O15 1_655 2.12(5) n
Li20 O16 2_665 1.99(5) n
Li21 O11 1_555 2.26(5) n
Li21 O11 2_456 2.02(4) n
Li21 O13 2_566 1.69(4) n
Li21 O17 2_556 1.95(4) n
loop_
_pd_proc_ls_weight
_pd_proc_intensity_bkg_calc
_pd_calc_intensity_total
_pd_meas_counts_total
. . . 2278.0
. . . 2416.0
. . . 2482.0
. . . 2471.0
. . . 2588.0
. . . 2489.0
. . . 2614.0
. . . 2725.0
. . . 2838.0
. . . 2864.0
. . . 2902.0
. . . 2937.0
. . . 2956.0
. . . 2959.0
. . . 3072.0
. . . 2996.0
. . . 3141.0
. . . 3127.0
. . . 3093.0
. . . 3011.0
. . . 3077.0
. . . 2948.0
. . . 3094.0
. . . 3011.0
. . . 3106.0
. . . 3094.0
. . . 3062.0
. . . 3163.0
. . . 3139.0
. . . 3087.0
. . . 2956.0
. . . 3080.0
. . . 3105.0
. . . 2945.0
. . . 2994.0
. . . 2999.0
. . . 3101.0
. . . 3058.0
. . . 2972.0
. . . 3088.0
. . . 2969.0
. . . 2980.0
. . . 2924.0
. . . 2889.0
. . . 2914.0
. . . 2979.0
. . . 2997.0
. . . 2996.0
. . . 2943.0
. . . 3014.0
. . . 3000.0
. . . 3096.0
. . . 2989.0
. . . 2933.0
. . . 2964.0
. . . 2933.0
. . . 2964.0
. . . 3036.0
. . . 2950.0
. . . 3021.0
. . . 2984.0
. . . 2954.0
. . . 2966.0
. . . 2955.0
. . . 2970.0
. . . 2935.0
. . . 3023.0
. . . 2954.0
. . . 2983.0
. . . 3012.0
. . . 2930.0
. . . 3067.0
. . . 2891.0
. . . 3075.0
. . . 2980.0
. . . 3010.0
. . . 3015.0
. . . 3025.0
. . . 2978.0
. . . 3007.0
. . . 3067.0
. . . 2999.0
. . . 3002.0
. . . 3046.0
. . . 3046.0
. . . 3052.0
. . . 3009.0
. . . 3098.0
. . . 3100.0
. . . 3154.0
. . . 3019.0
. . . 3004.0
. . . 3055.0
. . . 3036.0
. . . 3160.0
. . . 3007.0
. . . 3073.0
. . . 3073.0
. . . 3050.0
. . . 3129.0
. . . 3077.0
. . . 3231.0
. . . 3089.0
. . . 3102.0
. . . 3100.0
. . . 3131.0
. . . 3099.0
. . . 3192.0
. . . 3102.0
. . . 3209.0
. . . 3146.0
. . . 3223.0
. . . 3124.0
. . . 3269.0
. . . 3160.0
. . . 3227.0
. . . 3218.0
. . . 3367.0
. . . 3373.0
. . . 3281.0
0.0003047 2122.50000 3099.83447 3282.0
0.0003024 2122.50000 3126.01416 3307.0
0.0003005 2122.50000 3151.68994 3328.0
0.0003063 2122.50000 3176.87915 3265.0
0.0003050 2122.50000 3201.60400 3279.0
0.0003114 2122.50000 3225.82642 3211.0
0.0002956 2122.50000 3249.56738 3383.0
0.0003131 2122.50000 3272.80908 3194.0
0.0003051 2122.50000 3295.57129 3278.0
0.0003040 2122.50000 3317.84277 3290.0
0.0002926 2122.50000 3339.62280 3418.0
0.0002899 2122.50000 3360.92871 3449.0
0.0002937 2122.50000 3381.75879 3405.0
0.0002950 2122.50000 3402.09106 3390.0
0.0003023 2122.50000 3421.92529 3308.0
0.0002988 2122.50000 3441.28906 3347.0
0.0003012 2122.50000 3460.13647 3320.0
0.0002939 2122.50000 3478.53247 3403.0
0.0003025 2122.50000 3496.44043 3306.0
0.0002894 2122.50000 3513.86963 3456.0
0.0002902 2122.50000 3530.80322 3446.0
0.0002890 2122.50000 3547.29004 3460.0
0.0002795 2122.50000 3563.25342 3578.0
0.0002849 2122.50000 3578.79688 3510.0
0.0002859 2122.50000 3593.84912 3498.0
0.0002894 2122.50000 3608.41016 3455.0
0.0002852 2122.50000 3622.52222 3506.0
0.0002822 2122.50000 3636.17456 3543.0
0.0002800 2122.50000 3649.35010 3571.0
0.0002796 2122.50000 3662.06201 3576.0
0.0002746 2122.50000 3674.32642 3642.0
0.0002879 2122.50000 3686.15039 3474.0
0.0002807 2122.50000 3697.49561 3562.0
0.0002723 2122.50000 3708.41602 3672.0
0.0002753 2122.50000 3718.87744 3633.0
0.0002719 2122.50000 3728.89600 3678.0
0.0002711 2122.50000 3738.48975 3688.0
0.0002629 2122.50000 3747.64746 3804.0
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. . . 2160.0
. . . 2154.0
. . . 2128.0
. . . 2222.0
. . . 2144.0
. . . 2163.0
. . . 2005.0
. . . 2055.0
. . . 2129.0
. . . 2134.0
. . . 2154.0
. . . 2277.0
. . . 2138.0
. . . 2112.0
. . . 2206.0
. . . 2164.0
. . . 2160.0
. . . 2128.0
. . . 2083.0
. . . 2106.0
. . . 2096.0
. . . 2195.0
. . . 2111.0
. . . 2074.0
. . . 2129.0
. . . 2176.0
. . . 2161.0
. . . 2059.0
. . . 2055.0
. . . 2168.0
. . . 2085.0
. . . 2105.0
. . . 2087.0
. . . 2060.0
. . . 2084.0
. . . 2160.0
. . . 2107.0
. . . 2109.0
. . . 2105.0
. . . 2094.0
. . . 2062.0
. . . 2162.0
. . . 2062.0
. . . 2162.0
. . . 2159.0
. . . 2134.0
. . . 2170.0
. . . 2129.0
. . . 2186.0
. . . 2091.0
. . . 2070.0
. . . 2136.0
. . . 2074.0
. . . 2055.0
. . . 2117.0
. . . 2147.0
. . . 2077.0
. . . 2080.0
. . . 2074.0
. . . 1971.0
. . . 2006.0
. . . 2053.0
. . . 2039.0
. . . 2073.0
. . . 2155.0
. . . 2097.0
. . . 2135.0
. . . 2147.0
. . . 2057.0
. . . 2092.0
. . . 2091.0
. . . 2109.0
. . . 2067.0
. . . 2072.0
. . . 2048.0
. . . 2034.0
. . . 2077.0
. . . 2151.0
. . . 2036.0
. . . 2062.0
. . . 2104.0
. . . 2125.0
. . . 2047.0
. . . 2109.0
. . . 2006.0
. . . 2042.0
. . . 2096.0
. . . 2065.0
. . . 2105.0
. . . 2088.0
. . . 2125.0
. . . 2039.0
. . . 1975.0
. . . 2089.0
. . . 2002.0
. . . 2000.0
. . . 2050.0
. . . 2113.0
. . . 2045.0
. . . 2041.0
. . . 2098.0
. . . 2127.0
. . . 2077.0
. . . 2013.0
. . . 2007.0
. . . 2061.0
. . . 2033.0
. . . 1997.0
. . . 2069.0
. . . 1975.0
. . . 2038.0
. . . 1977.0
. . . 2104.0
. . . 2153.0
. . . 2093.0
. . . 2018.0
. . . 2001.0
. . . 2134.0
. . . 2002.0
. . . 2076.0
. . . 2004.0
. . . 2031.0
. . . 2020.0
. . . 2090.0
. . . 2057.0
. . . 2026.0
. . . 2026.0
. . . 2003.0
. . . 2055.0
. . . 1989.0
. . . 2013.0
. . . 2128.0
. . . 2005.0
. . . 2035.0
. . . 2039.0
. . . 2024.0
