#------------------------------------------------------------------------------
#$Date: 2021-05-15 07:50:58 +0300 (Sat, 15 May 2021) $
#$Revision: 265247 $
#$URL: file:///home/coder/svn-repositories/cod/cif/2/24/38/2243833.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2243833
loop_
_publ_author_name
'Smirnov, Daniil E.'
'Tatarin, Sergei V.'
'Bezzubov, Stanislav I.'
_publ_section_title
;
 Synthesis and crystal structures of N-H, N-phenyl and
 N-benzyl-2-(4-hexyloxyphenyl)benzimidazoles
;
_journal_coeditor_code           MW2176
_journal_issue                   6
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              618
_journal_page_last               622
_journal_paper_doi               10.1107/S2056989021004898
_journal_volume                  77
_journal_year                    2021
_chemical_formula_iupac          'C26 H28 N2 O'
_chemical_formula_moiety         'C26 H28 N2 O'
_chemical_formula_sum            'C26 H28 N2 O'
_chemical_formula_weight         384.50
_chemical_name_systematic
;
2-(4-Hexyloxyphenyl)-1H-benzimidazole
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_audit_creation_method
;
Olex2 1.3
(compiled Nov 21 2019 18:26:39 for OlexSys, GUI svn.r6003)
;
_cell_angle_alpha                90
_cell_angle_beta                 108.977(3)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   14.3057(13)
_cell_length_b                   9.6392(7)
_cell_length_c                   16.3024(13)
_cell_measurement_reflns_used    5668
_cell_measurement_temperature    150.0
_cell_measurement_theta_max      26.10
_cell_measurement_theta_min      2.304
_cell_volume                     2125.8(3)
_computing_cell_refinement
;
APEX3 (Bruker, 2016)
;
_computing_data_collection
;
APEX3 (Bruker, 2016)
;
_computing_data_reduction
;
SAINT (Bruker, 2016)
;
_computing_molecular_graphics
;
OLEX2 (Dolomanov et al.,  2009)
;
_computing_publication_material
;
OLEX2 (Dolomanov et al.,  2009)
;
_computing_structure_refinement
;
SHELXL2018/3 (Sheldrick, 2015b)
;
_computing_structure_solution
;
SHELXT2014/5 (Sheldrick, 2015a)
;
_diffrn_ambient_temperature      150.0
_diffrn_detector                 'Bruker PHOTON III CMOS'
_diffrn_detector_area_resol_mean 10.4
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device       '3-circle diffractometer'
_diffrn_measurement_device_type  'Bruker D8 Venture'
_diffrn_measurement_method       ω-scan
_diffrn_radiation_monochromator  'focusing mirrors'
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0514
_diffrn_reflns_av_unetI/netI     0.0418
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            20533
_diffrn_reflns_theta_full        25.148
_diffrn_reflns_theta_max         25.148
_diffrn_reflns_theta_min         2.303
_diffrn_source                   'microfocus sealed X-ray tube'
_diffrn_source_current           1.4
_diffrn_source_power             0.07
_diffrn_source_voltage           50.0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    0.073
_exptl_absorpt_correction_T_max  0.7454
_exptl_absorpt_correction_T_min  0.6942
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
(SADABS; Bruker, 2016)
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.201
_exptl_crystal_description       plate
_exptl_crystal_F_000             824
_exptl_crystal_size_max          0.32
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.03
_refine_diff_density_max         0.516
_refine_diff_density_min         -0.253
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.032
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     263
_refine_ls_number_reflns         3813
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.032
_refine_ls_R_factor_all          0.0680
_refine_ls_R_factor_gt           0.0454
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0499P)²+0.8451P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1061
_refine_ls_wR_factor_ref         0.1162
_reflns_number_gt                2875
_reflns_number_total             3813
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            mw2176sup1.cif
_cod_data_source_block           3
_cod_database_code               2243833
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.977
_shelx_estimated_absorpt_t_max   0.998
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
O O1 0.35057(10) 0.68007(13) 0.63440(8) 0.0346(3) Uani d 1 . .
N N2 0.71150(11) 0.25231(14) 0.65132(9) 0.0245(3) Uani d 1 . .
N N1 0.57463(11) 0.13503(15) 0.57646(9) 0.0265(3) Uani d 1 . .
C C7 0.61008(13) 0.25349(18) 0.61454(11) 0.0251(4) Uani d 1 . .
C C9 0.83510(13) 0.43825(17) 0.65779(11) 0.0239(4) Uani d 1 . .
C C6 0.74261(13) 0.12185(17) 0.63539(11) 0.0241(4) Uani d 1 . .
C C15 0.54652(13) 0.37098(18) 0.61908(11) 0.0254(4) Uani d 1 . .
C C1 0.65666(13) 0.05056(18) 0.58863(11) 0.0251(4) Uani d 1 . .
C C17 0.50564(14) 0.61502(19) 0.61353(11) 0.0289(4) Uani d 1 . .
H H17 0.522454 0.708718 0.606838 0.035 Uiso calc 1 . .
C C18 0.41772(13) 0.58396(19) 0.62720(11) 0.0281(4) Uani d 1 . .
C C8 0.77685(13) 0.35755(18) 0.70438(11) 0.0265(4) Uani d 1 . .
H H8A 0.823789 0.311896 0.755747 0.032 Uiso calc 1 . .
H H8B 0.736704 0.423506 0.725444 0.032 Uiso calc 1 . .
C C5 0.83572(13) 0.06191(19) 0.65827(11) 0.0272(4) Uani d 1 . .
H H5 0.893481 0.111446 0.690252 0.033 Uiso calc 1 . .
C C19 0.39190(14) 0.44582(19) 0.63417(12) 0.0307(4) Uani d 1 . .
H H19 0.330604 0.424005 0.642021 0.037 Uiso calc 1 . .
C C2 0.66237(14) -0.08558(18) 0.56151(12) 0.0287(4) Uani d 1 . .
H H2 0.604818 -0.134800 0.528710 0.034 Uiso calc 1 . .
C C14 0.91141(13) 0.52387(18) 0.70620(12) 0.0287(4) Uani d 1 . .
H H14 0.925754 0.530467 0.767205 0.034 Uiso calc 1 . .
C C10 0.81481(14) 0.43126(18) 0.56852(11) 0.0278(4) Uani d 1 . .
H H10 0.762893 0.373364 0.534517 0.033 Uiso calc 1 . .
C C20 0.45566(14) 0.34143(19) 0.62962(11) 0.0298(4) Uani d 1 . .
H H20 0.437451 0.247555 0.633726 0.036 Uiso calc 1 . .
C C16 0.56943(14) 0.50850(18) 0.60961(11) 0.0275(4) Uani d 1 . .
H H16 0.629935 0.530316 0.600256 0.033 Uiso calc 1 . .
C C4 0.84007(14) -0.07356(19) 0.63211(12) 0.0303(4) Uani d 1 . .
H H4 0.902394 -0.118716 0.646990 0.036 Uiso calc 1 . .
C C3 0.75487(15) -0.14613(19) 0.58417(12) 0.0315(4) Uani d 1 . .
H H3 0.760861 -0.238922 0.566880 0.038 Uiso calc 1 . .
C C11 0.86981(14) 0.50819(19) 0.52880(12) 0.0322(5) Uani d 1 . .
H H11 0.854981 0.503161 0.467686 0.039 Uiso calc 1 . .
C C13 0.96659(14) 0.59952(19) 0.66617(13) 0.0327(5) Uani d 1 . .
H H13 1.018967 0.656944 0.699922 0.039 Uiso calc 1 . .
C C12 0.94587(14) 0.59196(19) 0.57721(13) 0.0337(5) Uani d 1 . .
H H12 0.983728 0.644025 0.549780 0.040 Uiso calc 1 . .
C C21 0.37783(15) 0.82380(19) 0.63491(13) 0.0363(5) Uani d 1 . .
H H21A 0.380986 0.851037 0.577313 0.044 Uiso calc 1 . .
H H21B 0.443518 0.839772 0.678704 0.044 Uiso calc 1 . .
C C24 0.12096(16) 0.9823(2) 0.61640(14) 0.0414(5) Uani d 1 . .
H H24A 0.054475 0.959653 0.575868 0.050 Uiso calc 1 . .
H H24B 0.121849 0.957698 0.675606 0.050 Uiso calc 1 . .
C C26 0.05543(16) 1.2226(2) 0.62688(14) 0.0416(5) Uani d 1 . .
H H26A -0.007303 1.199254 0.582282 0.062 Uiso calc 1 . .
H H26B 0.069379 1.321545 0.623109 0.062 Uiso calc 1 . .
H H26C 0.050857 1.202249 0.684342 0.062 Uiso calc 1 . .
C C25 0.13774(16) 1.1376(2) 0.61283(15) 0.0445(6) Uani d 1 . .
H H25A 0.200929 1.162309 0.657797 0.053 Uiso calc 1 . .
H H25B 0.143581 1.161314 0.555610 0.053 Uiso calc 1 . .
C C23 0.19767(16) 0.8929(2) 0.59333(14) 0.0448(5) Uani d 1 . .
H H23A 0.177602 0.794288 0.591145 0.054 Uiso calc 1 . .
H H23B 0.198534 0.919180 0.534875 0.054 Uiso calc 1 . .
C C22 0.29974(16) 0.9082(2) 0.65685(14) 0.0466(6) Uani d 1 . .
H H22A 0.298728 0.880129 0.714969 0.056 Uiso calc 1 . .
H H22B 0.318687 1.007348 0.660047 0.056 Uiso calc 1 . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
_geom_angle_publ_flag
C18 O1 C21 . . 117.15(15) ?
C7 N2 C6 . . 106.42(14) ?
C7 N2 C8 . . 129.33(14) ?
C6 N2 C8 . . 124.01(15) ?
C7 N1 C1 . . 105.21(15) ?
N2 C7 C15 . . 124.45(16) ?
N1 C7 N2 . . 112.75(15) ?
N1 C7 C15 . . 122.76(16) ?
C14 C9 C8 . . 118.62(15) ?
C10 C9 C8 . . 122.63(16) ?
C10 C9 C14 . . 118.74(16) ?
N2 C6 C1 . . 105.60(15) ?
N2 C6 C5 . . 131.77(17) ?
C5 C6 C1 . . 122.63(16) ?
C20 C15 C7 . . 117.75(16) ?
C16 C15 C7 . . 123.98(16) ?
C16 C15 C20 . . 118.20(16) ?
N1 C1 C6 . . 110.01(15) ?
N1 C1 C2 . . 129.78(17) ?
C2 C1 C6 . . 120.21(16) ?
C18 C17 H17 . . 120.2 ?
C18 C17 C16 . . 119.61(17) ?
C16 C17 H17 . . 120.2 ?
O1 C18 C17 . . 124.75(17) ?
O1 C18 C19 . . 115.30(16) ?
C17 C18 C19 . . 119.95(17) ?
N2 C8 C9 . . 114.30(14) ?
N2 C8 H8A . . 108.7 ?
N2 C8 H8B . . 108.7 ?
C9 C8 H8A . . 108.7 ?
C9 C8 H8B . . 108.7 ?
H8A C8 H8B . . 107.6 ?
C6 C5 H5 . . 121.7 ?
C4 C5 C6 . . 116.52(17) ?
C4 C5 H5 . . 121.7 ?
C18 C19 H19 . . 120.2 ?
C20 C19 C18 . . 119.69(17) ?
C20 C19 H19 . . 120.2 ?
C1 C2 H2 . . 121.2 ?
C3 C2 C1 . . 117.51(18) ?
C3 C2 H2 . . 121.2 ?
C9 C14 H14 . . 119.7 ?
C13 C14 C9 . . 120.51(17) ?
C13 C14 H14 . . 119.7 ?
C9 C10 H10 . . 119.8 ?
C11 C10 C9 . . 120.42(18) ?
C11 C10 H10 . . 119.8 ?
C15 C20 H20 . . 119.4 ?
C19 C20 C15 . . 121.19(17) ?
C19 C20 H20 . . 119.4 ?
C15 C16 C17 . . 121.28(17) ?
C15 C16 H16 . . 119.4 ?
C17 C16 H16 . . 119.4 ?
C5 C4 H4 . . 119.2 ?
C5 C4 C3 . . 121.69(17) ?
C3 C4 H4 . . 119.2 ?
C2 C3 C4 . . 121.43(17) ?
C2 C3 H3 . . 119.3 ?
C4 C3 H3 . . 119.3 ?
C10 C11 H11 . . 119.7 ?
C12 C11 C10 . . 120.56(18) ?
C12 C11 H11 . . 119.7 ?
C14 C13 H13 . . 119.8 ?
C14 C13 C12 . . 120.37(18) ?
C12 C13 H13 . . 119.8 ?
C11 C12 C13 . . 119.39(17) ?
C11 C12 H12 . . 120.3 ?
C13 C12 H12 . . 120.3 ?
O1 C21 H21A . . 110.2 ?
O1 C21 H21B . . 110.2 ?
O1 C21 C22 . . 107.40(16) ?
H21A C21 H21B . . 108.5 ?
C22 C21 H21A . . 110.2 ?
C22 C21 H21B . . 110.2 ?
H24A C24 H24B . . 107.6 ?
C25 C24 H24A . . 108.7 ?
C25 C24 H24B . . 108.7 ?
C25 C24 C23 . . 114.15(18) ?
C23 C24 H24A . . 108.7 ?
C23 C24 H24B . . 108.7 ?
H26A C26 H26B . . 109.5 ?
H26A C26 H26C . . 109.5 ?
H26B C26 H26C . . 109.5 ?
C25 C26 H26A . . 109.5 ?
C25 C26 H26B . . 109.5 ?
C25 C26 H26C . . 109.5 ?
C24 C25 H25A . . 109.0 ?
C24 C25 H25B . . 109.0 ?
C26 C25 C24 . . 112.80(18) ?
C26 C25 H25A . . 109.0 ?
C26 C25 H25B . . 109.0 ?
H25A C25 H25B . . 107.8 ?
C24 C23 H23A . . 109.0 ?
C24 C23 H23B . . 109.0 ?
H23A C23 H23B . . 107.8 ?
C22 C23 C24 . . 112.89(17) ?
C22 C23 H23A . . 109.0 ?
C22 C23 H23B . . 109.0 ?
C21 C22 H22A . . 108.7 ?
C21 C22 H22B . . 108.7 ?
C23 C22 C21 . . 114.30(18) ?
C23 C22 H22A . . 108.7 ?
C23 C22 H22B . . 108.7 ?
H22A C22 H22B . . 107.6 ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
O1 C18 . 1.367(2) ?
O1 C21 . 1.439(2) ?
N2 C7 . 1.378(2) ?
N2 C6 . 1.386(2) ?
N2 C8 . 1.458(2) ?
N1 C7 . 1.320(2) ?
N1 C1 . 1.389(2) ?
C7 C15 . 1.469(2) ?
C9 C8 . 1.513(2) ?
C9 C14 . 1.391(2) ?
C9 C10 . 1.390(2) ?
C6 C1 . 1.398(2) ?
C6 C5 . 1.387(2) ?
C15 C20 . 1.395(3) ?
C15 C16 . 1.386(3) ?
C1 C2 . 1.396(2) ?
C17 H17 . 0.9500 ?
C17 C18 . 1.380(3) ?
C17 C16 . 1.389(2) ?
C18 C19 . 1.396(3) ?
C8 H8A . 0.9900 ?
C8 H8B . 0.9900 ?
C5 H5 . 0.9500 ?
C5 C4 . 1.381(3) ?
C19 H19 . 0.9500 ?
C19 C20 . 1.376(3) ?
C2 H2 . 0.9500 ?
C2 C3 . 1.382(3) ?
C14 H14 . 0.9500 ?
C14 C13 . 1.384(3) ?
C10 H10 . 0.9500 ?
C10 C11 . 1.385(3) ?
C20 H20 . 0.9500 ?
C16 H16 . 0.9500 ?
C4 H4 . 0.9500 ?
C4 C3 . 1.402(3) ?
C3 H3 . 0.9500 ?
C11 H11 . 0.9500 ?
C11 C12 . 1.379(3) ?
C13 H13 . 0.9500 ?
C13 C12 . 1.385(3) ?
C12 H12 . 0.9500 ?
C21 H21A . 0.9900 ?
C21 H21B . 0.9900 ?
C21 C22 . 1.516(3) ?
C24 H24A . 0.9900 ?
C24 H24B . 0.9900 ?
C24 C25 . 1.520(3) ?
C24 C23 . 1.535(3) ?
C26 H26A . 0.9800 ?
C26 H26B . 0.9800 ?
C26 H26C . 0.9800 ?
C26 C25 . 1.512(3) ?
C25 H25A . 0.9900 ?
C25 H25B . 0.9900 ?
C23 H23A . 0.9900 ?
C23 H23B . 0.9900 ?
C23 C22 . 1.498(3) ?
C22 H22A . 0.9900 ?
C22 H22B . 0.9900 ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion
_geom_torsion_publ_flag
O1 C18 C19 C20 . . . . -178.63(16) ?
O1 C21 C22 C23 . . . . -60.9(2) ?
N2 C7 C15 C20 . . . . -141.71(17) ?
N2 C7 C15 C16 . . . . 41.3(3) ?
N2 C6 C1 N1 . . . . -0.27(18) ?
N2 C6 C1 C2 . . . . 179.56(15) ?
N2 C6 C5 C4 . . . . 179.23(16) ?
N1 C7 C15 C20 . . . . 36.1(2) ?
N1 C7 C15 C16 . . . . -140.91(18) ?
N1 C1 C2 C3 . . . . -178.94(16) ?
C7 N2 C6 C1 . . . . 0.31(17) ?
C7 N2 C6 C5 . . . . -178.80(17) ?
C7 N2 C8 C9 . . . . -105.68(19) ?
C7 N1 C1 C6 . . . . 0.12(18) ?
C7 N1 C1 C2 . . . . -179.70(17) ?
C7 C15 C20 C19 . . . . -179.81(16) ?
C7 C15 C16 C17 . . . . 179.22(16) ?
C9 C14 C13 C12 . . . . 0.6(3) ?
C9 C10 C11 C12 . . . . 0.5(3) ?
C6 N2 C7 N1 . . . . -0.26(18) ?
C6 N2 C7 C15 . . . . 177.70(15) ?
C6 N2 C8 C9 . . . . 80.8(2) ?
C6 C1 C2 C3 . . . . 1.3(2) ?
C6 C5 C4 C3 . . . . 0.6(2) ?
C1 N1 C7 N2 . . . . 0.09(18) ?
C1 N1 C7 C15 . . . . -177.91(15) ?
C1 C6 C5 C4 . . . . 0.2(2) ?
C1 C2 C3 C4 . . . . -0.4(3) ?
C17 C18 C19 C20 . . . . 1.7(3) ?
C18 O1 C21 C22 . . . . -171.66(15) ?
C18 C17 C16 C15 . . . . 0.1(3) ?
C18 C19 C20 C15 . . . . 0.7(3) ?
C8 N2 C7 N1 . . . . -174.66(15) ?
C8 N2 C7 C15 . . . . 3.3(3) ?
C8 N2 C6 C1 . . . . 175.08(14) ?
C8 N2 C6 C5 . . . . -4.0(3) ?
C8 C9 C14 C13 . . . . 179.99(16) ?
C8 C9 C10 C11 . . . . 179.44(16) ?
C5 C6 C1 N1 . . . . 178.94(15) ?
C5 C6 C1 C2 . . . . -1.2(2) ?
C5 C4 C3 C2 . . . . -0.6(3) ?
C14 C9 C8 N2 . . . . -169.16(15) ?
C14 C9 C10 C11 . . . . 0.1(3) ?
C14 C13 C12 C11 . . . . -0.1(3) ?
C10 C9 C8 N2 . . . . 11.5(2) ?
C10 C9 C14 C13 . . . . -0.6(3) ?
C10 C11 C12 C13 . . . . -0.5(3) ?
C20 C15 C16 C17 . . . . 2.3(3) ?
C16 C15 C20 C19 . . . . -2.7(3) ?
C16 C17 C18 O1 . . . . 178.27(16) ?
C16 C17 C18 C19 . . . . -2.1(3) ?
C21 O1 C18 C17 . . . . -5.4(2) ?
C21 O1 C18 C19 . . . . 174.93(16) ?
C24 C23 C22 C21 . . . . -178.67(18) ?
C25 C24 C23 C22 . . . . 64.6(3) ?
C23 C24 C25 C26 . . . . 174.14(18) ?

_cod_database_fobs_code 2243833
