#------------------------------------------------------------------------------
#$Date: 2019-12-25 22:20:29 +0200 (Wed, 25 Dec 2019) $
#$Revision: 245873 $
#$URL: file:///home/coder/svn-repositories/cod/cif/2/31/14/2311423.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2311423
loop_
_publ_author_name
'Kuan, Fong Sheen'
'Jotani, Mukesh M.'
'Tiekink, Edward R. T.'
_publ_section_title
;
 New monoclinic form of {O-Ethyl
 N-(4-nitro-phen-yl)thio-carbamato-κS}(tri-4-tolyl-phosphane-κP)gold(I):
 crystal structure and Hirshfeld surface analysis.
;
_journal_coeditor_code           HB7703
_journal_issue                   'Pt 10'
_journal_name_full
'Acta crystallographica. Section E, Crystallographic communications'
_journal_page_first              1465
_journal_page_last               1471
_journal_paper_doi               10.1107/S2056989017012865
_journal_volume                  73
_journal_year                    2017
_chemical_formula_iupac          '[Au (C9 H9 N2 O3 S) (C21 H21 P)]'
_chemical_formula_moiety         'C30 H30 Au N2 O3 P S'
_chemical_formula_sum            'C30 H30 Au N2 O3 P S'
_chemical_formula_weight         726.55
_chemical_name_systematic
;{O-Ethyl
N-(4-nitrophenyl)thiocarbamato-κS}(tri-4-tolylphosphane-κP)gold(I)
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_cell_angle_alpha                90
_cell_angle_beta                 99.924(2)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   9.8815(6)
_cell_length_b                   14.0448(9)
_cell_length_c                   21.2332(13)
_cell_measurement_reflns_used    7098
_cell_measurement_temperature    223(2)
_cell_measurement_theta_max      28.221
_cell_measurement_theta_min      2.429
_cell_volume                     2902.7(3)
_computing_cell_refinement
;
SAINT (Bruker, 2000)
;
_computing_data_collection
;
SMART (Bruker, 2000)
;
_computing_data_reduction
;
SAINT (Bruker, 2000)
;
_computing_molecular_graphics
;
ORTEP-3 for Windows (Farrugia, 2012),  DIAMOND (Brandenburg,
2006)
and QMol (Gans & Shalloway, 2001)
;
_computing_publication_material
;
publCIF (Westrip, 2010)
;
_computing_structure_refinement
;
SHELXL2014/7 (Sheldrick, 2015)
;
_computing_structure_solution
;
SHELXS97 (Sheldrick, 2008)
;
_diffrn_ambient_temperature      223(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Bruker AXS SMART CCD'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71069
_diffrn_reflns_av_R_equivalents  0.0399
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -29
_diffrn_reflns_number            23909
_diffrn_reflns_theta_full        25.240
_diffrn_reflns_theta_max         29.971
_diffrn_reflns_theta_min         1.947
_diffrn_standards_decay_%        0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    5.229
_exptl_absorpt_correction_T_max  1
_exptl_absorpt_correction_T_min  0.421
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
(SADABS; Bruker, 2000)
;
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.663
_exptl_crystal_description       block
_exptl_crystal_F_000             1432
_exptl_crystal_size_max          0.270
_exptl_crystal_size_mid          0.120
_exptl_crystal_size_min          0.110
_refine_diff_density_max         1.159
_refine_diff_density_min         -0.784
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.947
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     347
_refine_ls_number_reflns         8412
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.947
_refine_ls_R_factor_all          0.0429
_refine_ls_R_factor_gt           0.0307
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0423P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0724
_refine_ls_wR_factor_ref         0.0780
_reflns_number_gt                6748
_reflns_number_total             8412
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            hb7703sup1.cif
_cod_data_source_block           I
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               2311423
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.333
_shelx_estimated_absorpt_t_max   0.597
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_occupancy
Au Au 0.12283(2) 0.07759(2) 0.34429(2) 0.03271(5) Uani d 1
S S1 0.18283(10) -0.03609(6) 0.42279(4) 0.03903(18) Uani d 1
P P1 0.06779(8) 0.19705(6) 0.27309(4) 0.03035(16) Uani d 1
O O1 0.1276(2) 0.12051(16) 0.47896(10) 0.0395(5) Uani d 1
O O2 0.6243(3) -0.3434(2) 0.61518(16) 0.0661(8) Uani d 1
O O3 0.4384(3) -0.3994(2) 0.63774(18) 0.0711(9) Uani d 1
N N1 0.2402(3) 0.0118(2) 0.54778(13) 0.0419(7) Uani d 1
N N2 0.5036(3) -0.3355(2) 0.61897(15) 0.0451(7) Uani d 1
C C1 0.1877(3) 0.0344(2) 0.49148(15) 0.0343(6) Uani d 1
C C2 0.3048(4) -0.0766(2) 0.56273(15) 0.0368(7) Uani d 1
C C3 0.2308(4) -0.1524(3) 0.58156(18) 0.0461(8) Uani d 1
H H3 0.1361 -0.1459 0.5815 0.055 Uiso calc 1
C C4 0.2960(4) -0.2371(3) 0.60035(19) 0.0473(9) Uani d 1
H H4 0.2462 -0.2887 0.6129 0.057 Uiso calc 1
C C5 0.4348(3) -0.2452(2) 0.60053(15) 0.0356(7) Uani d 1
C C6 0.5105(3) -0.1700(3) 0.58361(17) 0.0422(8) Uani d 1
H H6 0.6056 -0.1763 0.5848 0.051 Uiso calc 1
C C7 0.4448(4) -0.0855(2) 0.56491(19) 0.0449(8) Uani d 1
H H7 0.4956 -0.0335 0.5536 0.054 Uiso calc 1
C C8 0.1369(4) 0.1857(3) 0.53290(17) 0.0505(10) Uani d 1
H H8A 0.1311 0.1498 0.5719 0.061 Uiso calc 1
H H8B 0.0599 0.2307 0.5254 0.061 Uiso calc 1
C C9 0.2709(5) 0.2398(3) 0.5413(2) 0.0596(11) Uani d 1
H H9A 0.3469 0.1951 0.5477 0.089 Uiso calc 1
H H9B 0.2776 0.2812 0.5783 0.089 Uiso calc 1
H H9C 0.2744 0.2777 0.5035 0.089 Uiso calc 1
C C10 -0.0001(3) 0.2979(2) 0.31120(14) 0.0312(6) Uani d 1
C C11 0.0534(4) 0.3172(3) 0.37427(16) 0.0419(8) Uani d 1
H H11 0.1214 0.2772 0.3967 0.050 Uiso calc 1
C C12 0.0079(4) 0.3948(3) 0.40474(17) 0.0483(9) Uani d 1
H H12 0.0464 0.4074 0.4476 0.058 Uiso calc 1
C C13 -0.0930(4) 0.4540(3) 0.37347(17) 0.0416(8) Uani d 1
C C14 -0.1455(4) 0.4348(2) 0.31043(18) 0.0457(8) Uani d 1
H H14 -0.2145 0.4742 0.2882 0.055 Uiso calc 1
C C15 -0.0986(4) 0.3585(2) 0.27939(16) 0.0410(7) Uani d 1
H H15 -0.1342 0.3476 0.2360 0.049 Uiso calc 1
C C16 -0.1475(5) 0.5364(3) 0.4073(2) 0.0593(11) Uani d 1
H H16A -0.2063 0.5125 0.4359 0.089 Uiso calc 1
H H16B -0.2001 0.5785 0.3760 0.089 Uiso calc 1
H H16C -0.0713 0.5713 0.4317 0.089 Uiso calc 1
C C17 0.2135(3) 0.2461(2) 0.24238(14) 0.0326(6) Uani d 1
C C18 0.2127(4) 0.3395(3) 0.22013(16) 0.0411(7) Uani d 1
H H18 0.1349 0.3781 0.2203 0.049 Uiso calc 1
C C19 0.3248(4) 0.3757(3) 0.19790(17) 0.0475(9) Uani d 1
H H19 0.3227 0.4387 0.1827 0.057 Uiso calc 1
C C20 0.4419(4) 0.3201(3) 0.19754(17) 0.0509(9) Uani d 1
C C21 0.4425(4) 0.2289(3) 0.21997(18) 0.0529(10) Uani d 1
H H21 0.5205 0.1907 0.2198 0.063 Uiso calc 1
C C22 0.3299(3) 0.1914(3) 0.24308(16) 0.0428(8) Uani d 1
H H22 0.3332 0.1289 0.2591 0.051 Uiso calc 1
C C23 0.5626(4) 0.3616(4) 0.1716(2) 0.0784(15) Uani d 1
H H23A 0.6203 0.3104 0.1608 0.118 Uiso calc 1
H H23B 0.6156 0.4021 0.2038 0.118 Uiso calc 1
H H23C 0.5292 0.3989 0.1337 0.118 Uiso calc 1
C C24 -0.0624(3) 0.1663(2) 0.20533(14) 0.0314(6) Uani d 1
C C25 -0.0789(4) 0.2143(3) 0.14741(15) 0.0403(7) Uani d 1
H H25 -0.0181 0.2635 0.1413 0.048 Uiso calc 1
C C26 -0.1852(4) 0.1897(3) 0.09838(17) 0.0477(9) Uani d 1
H H26 -0.1966 0.2236 0.0597 0.057 Uiso calc 1
C C27 -0.2745(4) 0.1164(3) 0.10531(17) 0.0447(8) Uani d 1
C C28 -0.2578(4) 0.0687(3) 0.1635(2) 0.0516(10) Uani d 1
H H28 -0.3182 0.0190 0.1693 0.062 Uiso calc 1
C C29 -0.1533(4) 0.0933(2) 0.21300(17) 0.0416(8) Uani d 1
H H29 -0.1438 0.0605 0.2521 0.050 Uiso calc 1
C C30 -0.3886(6) 0.0899(3) 0.0519(2) 0.0748(15) Uani d 1
H H30A -0.4521 0.1428 0.0430 0.112 Uiso calc 1
H H30B -0.4370 0.0348 0.0644 0.112 Uiso calc 1
H H30C -0.3506 0.0749 0.0139 0.112 Uiso calc 1
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_publ_flag
P1 Au S1 175.80(3) y
C1 S1 Au 100.18(11) y
C10 P1 C24 105.90(14) ?
C10 P1 C17 103.93(14) ?
C24 P1 C17 107.71(14) ?
C10 P1 Au 110.22(10) ?
C24 P1 Au 114.24(10) ?
C17 P1 Au 114.04(10) ?
C1 O1 C8 116.2(2) ?
C1 N1 C2 122.2(3) ?
O3 N2 O2 122.5(3) ?
O3 N2 C5 118.8(3) ?
O2 N2 C5 118.6(3) ?
N1 C1 O1 120.4(3) ?
N1 C1 S1 126.5(3) ?
O1 C1 S1 113.1(2) ?
C7 C2 N1 120.0(3) ?
C7 C2 C3 119.7(3) ?
N1 C2 C3 120.0(3) ?
C4 C3 C2 120.1(3) ?
C4 C3 H3 120.0 ?
C2 C3 H3 120.0 ?
C3 C4 C5 119.2(3) ?
C3 C4 H4 120.4 ?
C5 C4 H4 120.4 ?
C6 C5 C4 121.5(3) ?
C6 C5 N2 119.1(3) ?
C4 C5 N2 119.4(3) ?
C5 C6 C7 119.0(3) ?
C5 C6 H6 120.5 ?
C7 C6 H6 120.5 ?
C6 C7 C2 120.4(3) ?
C6 C7 H7 119.8 ?
C2 C7 H7 119.8 ?
O1 C8 C9 110.2(3) ?
O1 C8 H8A 109.6 ?
C9 C8 H8A 109.6 ?
O1 C8 H8B 109.6 ?
C9 C8 H8B 109.6 ?
H8A C8 H8B 108.1 ?
C8 C9 H9A 109.5 ?
C8 C9 H9B 109.5 ?
H9A C9 H9B 109.5 ?
C8 C9 H9C 109.5 ?
H9A C9 H9C 109.5 ?
H9B C9 H9C 109.5 ?
C11 C10 C15 118.3(3) ?
C11 C10 P1 118.5(2) ?
C15 C10 P1 123.1(2) ?
C12 C11 C10 120.5(3) ?
C12 C11 H11 119.7 ?
C10 C11 H11 119.7 ?
C13 C12 C11 121.2(3) ?
C13 C12 H12 119.4 ?
C11 C12 H12 119.4 ?
C12 C13 C14 118.0(3) ?
C12 C13 C16 121.4(3) ?
C14 C13 C16 120.5(4) ?
C15 C14 C13 121.0(3) ?
C15 C14 H14 119.5 ?
C13 C14 H14 119.5 ?
C14 C15 C10 120.8(3) ?
C14 C15 H15 119.6 ?
C10 C15 H15 119.6 ?
C13 C16 H16A 109.5 ?
C13 C16 H16B 109.5 ?
H16A C16 H16B 109.5 ?
C13 C16 H16C 109.5 ?
H16A C16 H16C 109.5 ?
H16B C16 H16C 109.5 ?
C22 C17 C18 118.9(3) ?
C22 C17 P1 119.7(3) ?
C18 C17 P1 121.3(2) ?
C17 C18 C19 120.4(3) ?
C17 C18 H18 119.8 ?
C19 C18 H18 119.8 ?
C18 C19 C20 120.9(4) ?
C18 C19 H19 119.6 ?
C20 C19 H19 119.6 ?
C21 C20 C19 118.4(3) ?
C21 C20 C23 122.1(4) ?
C19 C20 C23 119.5(4) ?
C20 C21 C22 121.4(4) ?
C20 C21 H21 119.3 ?
C22 C21 H21 119.3 ?
C17 C22 C21 119.9(4) ?
C17 C22 H22 120.0 ?
C21 C22 H22 120.0 ?
C20 C23 H23A 109.5 ?
C20 C23 H23B 109.5 ?
H23A C23 H23B 109.5 ?
C20 C23 H23C 109.5 ?
H23A C23 H23C 109.5 ?
H23B C23 H23C 109.5 ?
C29 C24 C25 118.8(3) ?
C29 C24 P1 117.9(2) ?
C25 C24 P1 123.2(2) ?
C26 C25 C24 120.1(3) ?
C26 C25 H25 119.9 ?
C24 C25 H25 119.9 ?
C27 C26 C25 121.4(3) ?
C27 C26 H26 119.3 ?
C25 C26 H26 119.3 ?
C26 C27 C28 118.3(3) ?
C26 C27 C30 121.0(4) ?
C28 C27 C30 120.6(4) ?
C29 C28 C27 120.9(3) ?
C29 C28 H28 119.6 ?
C27 C28 H28 119.6 ?
C28 C29 C24 120.5(3) ?
C28 C29 H29 119.8 ?
C24 C29 H29 119.8 ?
C27 C30 H30A 109.5 ?
C27 C30 H30B 109.5 ?
H30A C30 H30B 109.5 ?
C27 C30 H30C 109.5 ?
H30A C30 H30C 109.5 ?
H30B C30 H30C 109.5 ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_publ_flag
Au P1 2.2611(8) y
Au S1 2.3105(8) y
S1 C1 1.756(3) y
P1 C10 1.816(3) ?
P1 C24 1.809(3) ?
P1 C17 1.815(3) ?
O1 C1 1.354(4) ?
O1 C8 1.457(4) ?
O2 N2 1.215(4) ?
O3 N2 1.211(4) ?
N1 C1 1.259(4) y
N1 C2 1.407(4) ?
N2 C5 1.460(4) ?
C2 C7 1.381(5) ?
C2 C3 1.389(5) ?
C3 C4 1.379(5) ?
C3 H3 0.9400 ?
C4 C5 1.375(5) ?
C4 H4 0.9400 ?
C5 C6 1.377(5) ?
C6 C7 1.379(5) ?
C6 H6 0.9400 ?
C7 H7 0.9400 ?
C8 C9 1.510(6) ?
C8 H8A 0.9800 ?
C8 H8B 0.9800 ?
C9 H9A 0.9700 ?
C9 H9B 0.9700 ?
C9 H9C 0.9700 ?
C10 C11 1.379(4) ?
C10 C15 1.378(4) ?
C11 C12 1.382(5) ?
C11 H11 0.9400 ?
C12 C13 1.378(6) ?
C12 H12 0.9400 ?
C13 C14 1.377(5) ?
C13 C16 1.510(5) ?
C14 C15 1.380(5) ?
C14 H14 0.9400 ?
C15 H15 0.9400 ?
C16 H16A 0.9700 ?
C16 H16B 0.9700 ?
C16 H16C 0.9700 ?
C17 C22 1.382(5) ?
C17 C18 1.395(5) ?
C18 C19 1.374(5) ?
C18 H18 0.9400 ?
C19 C20 1.397(6) ?
C19 H19 0.9400 ?
C20 C21 1.366(6) ?
C20 C23 1.514(5) ?
C21 C22 1.395(5) ?
C21 H21 0.9400 ?
C22 H22 0.9400 ?
C23 H23A 0.9700 ?
C23 H23B 0.9700 ?
C23 H23C 0.9700 ?
C24 C29 1.391(5) ?
C24 C25 1.387(4) ?
C25 C26 1.389(5) ?
C25 H25 0.9400 ?
C26 C27 1.379(5) ?
C26 H26 0.9400 ?
C27 C28 1.391(5) ?
C27 C30 1.502(5) ?
C28 C29 1.384(5) ?
C28 H28 0.9400 ?
C29 H29 0.9400 ?
C30 H30A 0.9700 ?
C30 H30B 0.9700 ?
C30 H30C 0.9700 ?
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_site_symmetry_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
C4 H4 Cg1 3_556 0.94 2.64 3.528(4) 157
N2 O2 Cg2 3_656 1.215(4) 3.547(4) 83.1(2) 3.608(3)
N2 O3 Cg2 3_656 1.211(4) 3.833(4) 70.2(2) 3.608(3)
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
C2 N1 C1 O1 -179.4(3)
C2 N1 C1 S1 0.4(5)
C8 O1 C1 N1 4.3(5)
C8 O1 C1 S1 -175.5(3)
Au S1 C1 N1 -165.6(3)
Au S1 C1 O1 14.2(2)
C1 N1 C2 C7 92.7(4)
C1 N1 C2 C3 -93.8(4)
C7 C2 C3 C4 -2.1(6)
N1 C2 C3 C4 -175.6(3)
C2 C3 C4 C5 0.4(6)
C3 C4 C5 C6 1.3(6)
C3 C4 C5 N2 -178.6(3)
O3 N2 C5 C6 175.3(4)
O2 N2 C5 C6 -4.3(5)
O3 N2 C5 C4 -4.8(5)
O2 N2 C5 C4 175.6(4)
C4 C5 C6 C7 -1.3(5)
N2 C5 C6 C7 178.6(3)
C5 C6 C7 C2 -0.5(6)
N1 C2 C7 C6 175.7(3)
C3 C2 C7 C6 2.2(6)
C1 O1 C8 C9 85.1(4)
C24 P1 C10 C11 159.0(3)
C17 P1 C10 C11 -87.6(3)
Au P1 C10 C11 35.0(3)
C24 P1 C10 C15 -23.7(3)
C17 P1 C10 C15 89.6(3)
Au P1 C10 C15 -147.8(3)
C15 C10 C11 C12 0.7(5)
P1 C10 C11 C12 178.1(3)
C10 C11 C12 C13 0.9(6)
C11 C12 C13 C14 -1.2(6)
C11 C12 C13 C16 177.3(4)
C12 C13 C14 C15 -0.1(6)
C16 C13 C14 C15 -178.6(4)
C13 C14 C15 C10 1.7(6)
C11 C10 C15 C14 -2.0(5)
P1 C10 C15 C14 -179.3(3)
C10 P1 C17 C22 143.8(3)
C24 P1 C17 C22 -104.1(3)
Au P1 C17 C22 23.8(3)
C10 P1 C17 C18 -33.7(3)
C24 P1 C17 C18 78.3(3)
Au P1 C17 C18 -153.8(2)
C22 C17 C18 C19 1.5(5)
P1 C17 C18 C19 179.1(3)
C17 C18 C19 C20 -0.5(5)
C18 C19 C20 C21 -0.2(6)
C18 C19 C20 C23 178.9(4)
C19 C20 C21 C22 -0.2(6)
C23 C20 C21 C22 -179.3(4)
C18 C17 C22 C21 -1.9(5)
P1 C17 C22 C21 -179.5(3)
C20 C21 C22 C17 1.3(6)
C10 P1 C24 C29 -96.7(3)
C17 P1 C24 C29 152.6(3)
Au P1 C24 C29 24.8(3)
C10 P1 C24 C25 80.7(3)
C17 P1 C24 C25 -30.0(3)
Au P1 C24 C25 -157.8(3)
C29 C24 C25 C26 0.4(5)
P1 C24 C25 C26 -177.0(3)
C24 C25 C26 C27 -1.4(6)
C25 C26 C27 C28 1.5(6)
C25 C26 C27 C30 -179.6(4)
C26 C27 C28 C29 -0.7(6)
C30 C27 C28 C29 -179.5(4)
C27 C28 C29 C24 -0.3(6)
C25 C24 C29 C28 0.5(5)
P1 C24 C29 C28 177.9(3)
