#------------------------------------------------------------------------------
#$Date: 2021-03-08 11:39:57 +0200 (Mon, 08 Mar 2021) $
#$Revision: 262861 $
#$URL: file:///home/coder/svn-repositories/cod/cif/3/00/02/3000292.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_3000292
loop_
_publ_author_name
'Asamiya, Yuki'
'Yamada, Takahiro'
'Yamane, Hisanori'
_publ_section_title
;
 Synthesis and characterization of NaCd0.92Sn1.08, Na(Cd0.28Sn0.72)2, and
 Na2CdSn5 with three-dimensional Cd-Sn frameworks
;
_journal_name_full               Inorganics
_journal_page_first              19
_journal_paper_doi               10.3390/inorganics9030019
_journal_volume                  9
_journal_year                    2021
_chemical_formula_sum            'Cd0.92 Na Sn1.08'
_chemical_formula_weight         254.58
_space_group_crystal_system      hexagonal
_space_group_IT_number           187
_space_group_name_Hall           'P -6 2'
_space_group_name_H-M_alt        'P -6 m 2'
_audit_creation_method           SHELXL-2018/3
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                120
_cell_formula_units_Z            3
_cell_length_a                   4.93260(10)
_cell_length_b                   4.93260(10)
_cell_length_c                   10.8508(3)
_cell_measurement_reflns_used    2003
_cell_measurement_temperature    300(2)
_cell_measurement_theta_max      36.3535
_cell_measurement_theta_min      2.626
_cell_volume                     228.636(9)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'VESTA v3.5.2 (Momma & Izumi, 2011)'
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_diffrn_ambient_temperature      300(2)
_diffrn_detector_area_resol_mean 7.3910
_diffrn_measured_fraction_theta_full 0.983
_diffrn_measured_fraction_theta_max 0.988
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0322
_diffrn_reflns_av_unetI/netI     0.0214
_diffrn_reflns_Laue_measured_fraction_full 0.983
_diffrn_reflns_Laue_measured_fraction_max 0.988
_diffrn_reflns_limit_h_max       6
_diffrn_reflns_limit_h_min       -6
_diffrn_reflns_limit_k_max       4
_diffrn_reflns_limit_k_min       -6
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            3258
_diffrn_reflns_point_group_measured_fraction_full 0.985
_diffrn_reflns_point_group_measured_fraction_max 0.989
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         28.261
_diffrn_reflns_theta_min         3.756
_diffrn_source                   'micro focus sealed tube'
_exptl_absorpt_coefficient_mu    15.064
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS 2016/2'
_exptl_crystal_colour            dark-silver
_exptl_crystal_density_diffrn    5.547
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             327
_exptl_crystal_size_max          0.134
_exptl_crystal_size_mid          0.086
_exptl_crystal_size_min          0.028
_exptl_transmission_factor_max   0.7471
_exptl_transmission_factor_min   0.4563
_refine_diff_density_max         1.023
_refine_diff_density_min         -1.554
_refine_diff_density_rms         0.182
_refine_ls_abs_structure_details
;
 Refined as an inversion twin.
;
_refine_ls_abs_structure_Flack   0.4(4)
_refine_ls_extinction_coef       0.011(2)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     'SHELXL-2018/3 (Sheldrick 2018)'
_refine_ls_goodness_of_fit_ref   1.163
_refine_ls_matrix_type           full
_refine_ls_number_parameters     18
_refine_ls_number_reflns         271
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.163
_refine_ls_R_factor_all          0.0178
_refine_ls_R_factor_gt           0.0178
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0151P)²+1.0884P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0408
_refine_ls_wR_factor_ref         0.0408
_reflns_Friedel_coverage         0.715
_reflns_Friedel_fraction_full    0.988
_reflns_Friedel_fraction_max     0.991
_reflns_number_gt                271
_reflns_number_total             271
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            NaCd0p92Sn1p08.cif
_cod_data_source_block           shelx
_cod_depositor_comments
;Releasing structure 3000292 into public domain as published material.

 There is a typo on the journal name. "Inorganic" was corrected to be
 "Inorganics"
;
_cod_original_cell_volume        228.636(11)
_cod_database_code               3000292
_shelx_shelxl_version_number     2018/3
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-y, x-y, z'
'-x+y, -x, z'
'x, y, -z'
'-y, x-y, -z'
'-x+y, -x, -z'
'-y, -x, z'
'-x+y, y, z'
'x, x-y, z'
'-y, -x, -z'
'-x+y, y, -z'
'x, x-y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Sn1 Sn 0.000000 0.000000 0.000000 0.0147(3) Uani 1 12 d S T P . .
Sn2 Sn 0.666667 0.333333 0.36068(8) 0.0122(3) Uani 1 6 d S T P . .
Cd3 Cd 0.666667 0.333333 0.000000 0.0265(4) Uani 0.92 12 d S T P . .
Sn3 Sn 0.666667 0.333333 0.000000 0.0265(4) Uani 0.08 12 d S T P . .
Cd4 Cd 0.000000 0.000000 0.29945(15) 0.0236(3) Uani 0.92 6 d S T P . .
Sn4 Sn 0.000000 0.000000 0.29945(15) 0.0236(3) Uani 0.08 6 d S T P . .
Na1 Na 0.333333 0.666667 0.500000 0.0242(18) Uani 1 12 d S T P . .
Na2 Na 0.333333 0.666667 0.1654(6) 0.0242(12) Uani 1 6 d S T P . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Na Na 0.0362 0.0249 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cd Cd -0.8075 1.2024 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sn Sn -0.6537 1.4246 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
Cd3 Sn1 Cd3 120.0 1_445 .
Cd3 Sn1 Cd3 120.0 1_445 1_455
Cd3 Sn1 Cd3 120.0 . 1_455
Cd3 Sn1 Cd4 90.0 1_445 4
Cd3 Sn1 Cd4 90.0 . 4
Cd3 Sn1 Cd4 90.0 1_455 4
Cd3 Sn1 Cd4 90.0 1_445 .
Cd3 Sn1 Cd4 90.0 . .
Cd3 Sn1 Cd4 90.0 1_455 .
Cd4 Sn1 Cd4 180.0 4 .
Cd3 Sn1 Na2 64.97(3) 1_445 4_445
Cd3 Sn1 Na2 147.78(9) . 4_445
Cd3 Sn1 Na2 64.97(3) 1_455 4_445
Cd4 Sn1 Na2 57.78(9) 4 4_445
Cd4 Sn1 Na2 122.22(9) . 4_445
Cd3 Sn1 Na2 147.78(9) 1_445 4
Cd3 Sn1 Na2 64.97(3) . 4
Cd3 Sn1 Na2 64.97(3) 1_455 4
Cd4 Sn1 Na2 57.78(9) 4 4
Cd4 Sn1 Na2 122.22(9) . 4
Na2 Sn1 Na2 94.23(12) 4_445 4
Cd3 Sn1 Na2 64.97(3) 1_445 1_445
Cd3 Sn1 Na2 147.78(9) . 1_445
Cd3 Sn1 Na2 64.97(3) 1_455 1_445
Cd4 Sn1 Na2 122.22(9) 4 1_445
Cd4 Sn1 Na2 57.78(9) . 1_445
Na2 Sn1 Na2 64.43(18) 4_445 1_445
Na2 Sn1 Na2 129.95(5) 4 1_445
Cd3 Sn1 Na2 147.78(9) 1_445 .
Cd3 Sn1 Na2 64.97(3) . .
Cd3 Sn1 Na2 64.97(3) 1_455 .
Cd4 Sn1 Na2 122.22(9) 4 .
Cd4 Sn1 Na2 57.78(9) . .
Na2 Sn1 Na2 129.95(5) 4_445 .
Na2 Sn1 Na2 64.43(18) 4 .
Na2 Sn1 Na2 94.23(12) 1_445 .
Cd3 Sn1 Na2 64.97(3) 1_445 1_545
Cd3 Sn1 Na2 64.97(3) . 1_545
Cd3 Sn1 Na2 147.78(9) 1_455 1_545
Cd4 Sn1 Na2 122.22(9) 4 1_545
Cd4 Sn1 Na2 57.78(9) . 1_545
Na2 Sn1 Na2 129.95(5) 4_445 1_545
Na2 Sn1 Na2 129.95(5) 4 1_545
Na2 Sn1 Na2 94.23(12) 1_445 1_545
Na2 Sn1 Na2 94.23(12) . 1_545
Cd4 Sn2 Cd4 115.00(2) 1_655 .
Cd4 Sn2 Cd4 115.00(2) 1_655 1_665
Cd4 Sn2 Cd4 115.00(2) . 1_665
Cd4 Sn2 Sn2 103.13(3) 1_655 4_556
Cd4 Sn2 Sn2 103.13(3) . 4_556
Cd4 Sn2 Sn2 103.13(3) 1_665 4_556
Cd4 Sn2 Na1 165.17(3) 1_655 .
Cd4 Sn2 Na1 71.121(17) . .
Cd4 Sn2 Na1 71.121(17) 1_665 .
Sn2 Sn2 Na1 62.039(14) 4_556 .
Cd4 Sn2 Na1 71.121(17) 1_655 1_655
Cd4 Sn2 Na1 165.17(3) . 1_655
Cd4 Sn2 Na1 71.122(17) 1_665 1_655
Sn2 Sn2 Na1 62.040(14) 4_556 1_655
Na1 Sn2 Na1 99.803(17) . 1_655
Cd4 Sn2 Na1 71.121(17) 1_655 1_545
Cd4 Sn2 Na1 71.122(17) . 1_545
Cd4 Sn2 Na1 165.17(3) 1_665 1_545
Sn2 Sn2 Na1 62.040(14) 4_556 1_545
Na1 Sn2 Na1 99.803(17) . 1_545
Na1 Sn2 Na1 99.802(17) 1_655 1_545
Cd4 Sn2 Na2 58.246(18) 1_655 1_545
Cd4 Sn2 Na2 58.247(18) . 1_545
Cd4 Sn2 Na2 130.21(9) 1_665 1_545
Sn2 Sn2 Na2 126.66(8) 4_556 1_545
Na1 Sn2 Na2 129.362(13) . 1_545
Na1 Sn2 Na2 129.361(13) 1_655 1_545
Na1 Sn2 Na2 64.62(8) 1_545 1_545
Cd4 Sn2 Na2 58.246(18) 1_655 1_655
Cd4 Sn2 Na2 130.21(9) . 1_655
Cd4 Sn2 Na2 58.247(18) 1_665 1_655
Sn2 Sn2 Na2 126.66(8) 4_556 1_655
Na1 Sn2 Na2 129.362(13) . 1_655
Na1 Sn2 Na2 64.62(8) 1_655 1_655
Na1 Sn2 Na2 129.361(13) 1_545 1_655
Na2 Sn2 Na2 88.02(12) 1_545 1_655
Cd4 Sn2 Na2 130.21(9) 1_655 .
Cd4 Sn2 Na2 58.246(18) . .
Cd4 Sn2 Na2 58.246(18) 1_665 .
Sn2 Sn2 Na2 126.65(8) 4_556 .
Na1 Sn2 Na2 64.62(8) . .
Na1 Sn2 Na2 129.362(13) 1_655 .
Na1 Sn2 Na2 129.362(13) 1_545 .
Na2 Sn2 Na2 88.02(12) 1_545 .
Na2 Sn2 Na2 88.02(12) 1_655 .
Sn1 Cd3 Sn1 120.0 1_655 1_665
Sn1 Cd3 Sn1 120.0 1_655 .
Sn1 Cd3 Sn1 120.0 1_665 .
Sn1 Cd3 Na2 147.78(9) 1_655 4
Sn1 Cd3 Na2 64.97(3) 1_665 4
Sn1 Cd3 Na2 64.97(3) . 4
Sn1 Cd3 Na2 147.78(9) 1_655 .
Sn1 Cd3 Na2 64.97(3) 1_665 .
Sn1 Cd3 Na2 64.97(3) . .
Na2 Cd3 Na2 64.43(18) 4 .
Sn1 Cd3 Na2 64.97(3) 1_655 4_545
Sn1 Cd3 Na2 147.78(9) 1_665 4_545
Sn1 Cd3 Na2 64.97(3) . 4_545
Na2 Cd3 Na2 94.23(12) 4 4_545
Na2 Cd3 Na2 129.95(5) . 4_545
Sn1 Cd3 Na2 64.97(3) 1_655 1_655
Sn1 Cd3 Na2 64.97(3) 1_665 1_655
Sn1 Cd3 Na2 147.78(9) . 1_655
Na2 Cd3 Na2 129.95(5) 4 1_655
Na2 Cd3 Na2 94.23(12) . 1_655
Na2 Cd3 Na2 129.95(5) 4_545 1_655
Sn1 Cd3 Na2 64.97(3) 1_655 4_655
Sn1 Cd3 Na2 64.97(3) 1_665 4_655
Sn1 Cd3 Na2 147.78(9) . 4_655
Na2 Cd3 Na2 94.23(12) 4 4_655
Na2 Cd3 Na2 129.95(5) . 4_655
Na2 Cd3 Na2 94.23(12) 4_545 4_655
Na2 Cd3 Na2 64.43(18) 1_655 4_655
Sn1 Cd3 Na2 64.97(3) 1_655 1_545
Sn1 Cd3 Na2 147.78(9) 1_665 1_545
Sn1 Cd3 Na2 64.97(3) . 1_545
Na2 Cd3 Na2 129.95(5) 4 1_545
Na2 Cd3 Na2 94.23(12) . 1_545
Na2 Cd3 Na2 64.43(18) 4_545 1_545
Na2 Cd3 Na2 94.23(12) 1_655 1_545
Na2 Cd3 Na2 129.95(5) 4_655 1_545
Sn2 Cd4 Sn2 115.00(2) 1_445 .
Sn2 Cd4 Sn2 115.00(2) 1_445 1_455
Sn2 Cd4 Sn2 115.00(2) . 1_455
Sn2 Cd4 Na2 70.71(5) 1_445 1_445
Sn2 Cd4 Na2 166.07(11) . 1_445
Sn2 Cd4 Na2 70.72(5) 1_455 1_445
Sn2 Cd4 Na2 166.07(11) 1_445 .
Sn2 Cd4 Na2 70.72(5) . .
Sn2 Cd4 Na2 70.72(5) 1_455 .
Na2 Cd4 Na2 100.93(13) 1_445 .
Sn2 Cd4 Na2 70.72(5) 1_445 1_545
Sn2 Cd4 Na2 70.72(5) . 1_545
Sn2 Cd4 Na2 166.07(11) 1_455 1_545
Na2 Cd4 Na2 100.93(13) 1_445 1_545
Na2 Cd4 Na2 100.93(13) . 1_545
Sn2 Cd4 Sn1 103.13(3) 1_445 .
Sn2 Cd4 Sn1 103.13(3) . .
Sn2 Cd4 Sn1 103.13(3) 1_455 .
Na2 Cd4 Sn1 62.94(10) 1_445 .
Na2 Cd4 Sn1 62.94(10) . .
Na2 Cd4 Sn1 62.94(10) 1_545 .
Sn2 Cd4 Na1 58.342(14) 1_445 1_445
Sn2 Cd4 Na1 129.48(5) . 1_445
Sn2 Cd4 Na1 58.343(14) 1_455 1_445
Na2 Cd4 Na1 64.45(10) 1_445 1_445
Na2 Cd4 Na1 129.05(5) . 1_445
Na2 Cd4 Na1 129.05(5) 1_545 1_445
Sn1 Cd4 Na1 127.38(2) . 1_445
Sn2 Cd4 Na1 129.48(5) 1_445 .
Sn2 Cd4 Na1 58.342(14) . .
Sn2 Cd4 Na1 58.343(14) 1_455 .
Na2 Cd4 Na1 129.05(5) 1_445 .
Na2 Cd4 Na1 64.45(10) . .
Na2 Cd4 Na1 129.05(5) 1_545 .
Sn1 Cd4 Na1 127.38(2) . .
Na1 Cd4 Na1 86.96(3) 1_445 .
Sn2 Cd4 Na1 58.343(14) 1_445 1_545
Sn2 Cd4 Na1 58.342(14) . 1_545
Sn2 Cd4 Na1 129.49(5) 1_455 1_545
Na2 Cd4 Na1 129.05(5) 1_445 1_545
Na2 Cd4 Na1 129.05(5) . 1_545
Na2 Cd4 Na1 64.44(10) 1_545 1_545
Sn1 Cd4 Na1 127.38(2) . 1_545
Na1 Cd4 Na1 86.96(3) 1_445 1_545
Na1 Cd4 Na1 86.96(3) . 1_545
Sn2 Na1 Sn2 55.92(3) 4_556 .
Sn2 Na1 Sn2 99.802(17) 4_556 4_566
Sn2 Na1 Sn2 127.584(7) . 4_566
Sn2 Na1 Sn2 127.584(7) 4_556 1_455
Sn2 Na1 Sn2 99.803(17) . 1_455
Sn2 Na1 Sn2 127.583(7) 4_566 1_455
Sn2 Na1 Sn2 99.802(17) 4_556 4_456
Sn2 Na1 Sn2 127.584(7) . 4_456
Sn2 Na1 Sn2 99.801(17) 4_566 4_456
Sn2 Na1 Sn2 55.92(3) 1_455 4_456
Sn2 Na1 Sn2 127.584(7) 4_556 1_565
Sn2 Na1 Sn2 99.803(17) . 1_565
Sn2 Na1 Sn2 55.92(3) 4_566 1_565
Sn2 Na1 Sn2 99.801(17) 1_455 1_565
Sn2 Na1 Sn2 127.583(7) 4_456 1_565
Sn2 Na1 Cd4 86.20(2) 4_556 .
Sn2 Na1 Cd4 50.536(8) . .
Sn2 Na1 Cd4 170.577(18) 4_566 .
Sn2 Na1 Cd4 50.537(8) 1_455 .
Sn2 Na1 Cd4 86.20(2) 4_456 .
Sn2 Na1 Cd4 114.66(3) 1_565 .
Sn2 Na1 Cd4 50.536(8) 4_556 4_666
Sn2 Na1 Cd4 86.20(2) . 4_666
Sn2 Na1 Cd4 50.536(8) 4_566 4_666
Sn2 Na1 Cd4 170.577(18) 1_455 4_666
Sn2 Na1 Cd4 114.66(3) 4_456 4_666
Sn2 Na1 Cd4 86.20(2) 1_565 4_666
Cd4 Na1 Cd4 133.182(14) . 4_666
Sn2 Na1 Cd4 114.65(3) 4_556 4_566
Sn2 Na1 Cd4 170.576(18) . 4_566
Sn2 Na1 Cd4 50.536(8) 4_566 4_566
Sn2 Na1 Cd4 86.20(2) 1_455 4_566
Sn2 Na1 Cd4 50.536(8) 4_456 4_566
Sn2 Na1 Cd4 86.20(2) 1_565 4_566
Cd4 Na1 Cd4 133.182(14) . 4_566
Cd4 Na1 Cd4 86.96(3) 4_666 4_566
Sn2 Na1 Cd4 170.577(18) 4_556 1_565
Sn2 Na1 Cd4 114.66(3) . 1_565
Sn2 Na1 Cd4 86.20(2) 4_566 1_565
Sn2 Na1 Cd4 50.536(8) 1_455 1_565
Sn2 Na1 Cd4 86.20(2) 4_456 1_565
Sn2 Na1 Cd4 50.536(8) 1_565 1_565
Cd4 Na1 Cd4 86.96(3) . 1_565
Cd4 Na1 Cd4 133.182(14) 4_666 1_565
Cd4 Na1 Cd4 74.77(4) 4_566 1_565
Sn2 Na1 Cd4 50.536(8) 4_556 4_556
Sn2 Na1 Cd4 86.20(2) . 4_556
Sn2 Na1 Cd4 114.66(3) 4_566 4_556
Sn2 Na1 Cd4 86.20(2) 1_455 4_556
Sn2 Na1 Cd4 50.537(8) 4_456 4_556
Sn2 Na1 Cd4 170.577(18) 1_565 4_556
Cd4 Na1 Cd4 74.77(4) . 4_556
Cd4 Na1 Cd4 86.96(3) 4_666 4_556
Cd4 Na1 Cd4 86.96(3) 4_566 4_556
Cd4 Na1 Cd4 133.182(14) 1_565 4_556
Cd4 Na2 Cd4 100.93(13) 1_565 1_665
Cd4 Na2 Cd4 100.93(13) 1_565 .
Cd4 Na2 Cd4 100.93(13) 1_665 .
Cd4 Na2 Sn1 59.28(3) 1_565 1_565
Cd4 Na2 Sn1 128.26(2) 1_665 1_565
Cd4 Na2 Sn1 128.26(2) . 1_565
Cd4 Na2 Sn1 128.26(2) 1_565 .
Cd4 Na2 Sn1 128.26(2) 1_665 .
Cd4 Na2 Sn1 59.28(3) . .
Sn1 Na2 Sn1 94.23(12) 1_565 .
Cd4 Na2 Sn1 128.26(2) 1_565 1_665
Cd4 Na2 Sn1 59.28(3) 1_665 1_665
Cd4 Na2 Sn1 128.26(2) . 1_665
Sn1 Na2 Sn1 94.23(12) 1_565 1_665
Sn1 Na2 Sn1 94.23(12) . 1_665
Cd4 Na2 Cd3 174.85(19) 1_565 .
Cd4 Na2 Cd3 82.29(2) 1_665 .
Cd4 Na2 Cd3 82.29(2) . .
Sn1 Na2 Cd3 115.57(18) 1_565 .
Sn1 Na2 Cd3 50.05(5) . .
Sn1 Na2 Cd3 50.05(5) 1_665 .
Cd4 Na2 Cd3 82.29(2) 1_565 1_455
Cd4 Na2 Cd3 174.85(19) 1_665 1_455
Cd4 Na2 Cd3 82.29(2) . 1_455
Sn1 Na2 Cd3 50.05(5) 1_565 1_455
Sn1 Na2 Cd3 50.05(5) . 1_455
Sn1 Na2 Cd3 115.57(18) 1_665 1_455
Cd3 Na2 Cd3 94.23(12) . 1_455
Cd4 Na2 Cd3 82.29(2) 1_565 1_565
Cd4 Na2 Cd3 82.29(2) 1_665 1_565
Cd4 Na2 Cd3 174.85(19) . 1_565
Sn1 Na2 Cd3 50.05(5) 1_565 1_565
Sn1 Na2 Cd3 115.57(18) . 1_565
Sn1 Na2 Cd3 50.05(5) 1_665 1_565
Cd3 Na2 Cd3 94.23(12) . 1_565
Cd3 Na2 Cd3 94.23(12) 1_455 1_565
Cd4 Na2 Sn2 51.04(6) 1_565 1_565
Cd4 Na2 Sn2 51.04(6) 1_665 1_565
Cd4 Na2 Sn2 116.28(18) . 1_565
Sn1 Na2 Sn2 88.790(13) 1_565 1_565
Sn1 Na2 Sn2 175.56(17) . 1_565
Sn1 Na2 Sn2 88.790(13) 1_665 1_565
Cd3 Na2 Sn2 131.120(16) . 1_565
Cd3 Na2 Sn2 131.119(16) 1_455 1_565
Cd3 Na2 Sn2 68.870(15) 1_565 1_565
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Sn1 Cd3 2.84783(6) 1_445
Sn1 Cd3 2.84784(5) .
Sn1 Cd3 2.84786(5) 1_455
Sn1 Cd4 3.2493(16) 4
Sn1 Cd4 3.2493(16) .
Sn1 Na2 3.366(3) 4_445
Sn1 Na2 3.366(3) 4
Sn1 Na2 3.366(3) 1_445
Sn1 Na2 3.366(3) .
Sn1 Na2 3.366(3) 1_545
Sn2 Cd4 2.9243(3) 1_655
Sn2 Cd4 2.9243(3) .
Sn2 Cd4 2.9243(3) 1_665
Sn2 Sn2 3.0234(17) 4_556
Sn2 Na1 3.2242(4) .
Sn2 Na1 3.2242(4) 1_655
Sn2 Na1 3.2242(4) 1_545
Sn2 Na2 3.550(4) 1_545
Sn2 Na2 3.550(4) 1_655
Sn2 Na2 3.550(4) .
Cd3 Na2 3.366(3) 4
Cd3 Na2 3.366(3) .
Cd3 Na2 3.366(3) 4_545
Cd3 Na2 3.366(3) 1_655
Cd3 Na2 3.366(3) 4_655
Cd3 Na2 3.366(3) 1_545
Cd4 Na2 3.198(3) 1_445
Cd4 Na2 3.198(3) .
Cd4 Na2 3.198(3) 1_545
Cd4 Na1 3.5841(10) 1_445
Cd4 Na1 3.5841(10) .
Cd4 Na1 3.5841(10) 1_545
