#------------------------------------------------------------------------------
#$Date: 2016-03-21 01:21:50 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178377 $
#$URL: svn://www.crystallography.net/cod/cif/4/00/10/4001041.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4001041
loop_
_publ_author_name
'Goforth, Andrea M.'
'Hope, Håkon'
'Condron, Cathie L.'
'Kauzlarich, Susan M.'
'Jensen, Newell'
'Klavins, Peter'
'MaQuilon, Samuel'
'Fisk, Zachary'
_publ_section_title
;
 Magnetism and Negative Magnetoresistance of Two Magnetically Ordering,
 Rare-Earth-Containing Zintl phases with a New Structure Type: EuGa2Pn2(Pn
 = P, As)
;
_journal_issue                   19
_journal_name_full               'Chemistry of Materials'
_journal_page_first              4480
_journal_paper_doi               10.1021/cm901219u
_journal_volume                  21
_journal_year                    2009
_chemical_formula_sum            'As2 Eu Ga2'
_chemical_formula_weight         441.24
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           10
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2y'
_symmetry_space_group_name_H-M   'P 1 2/m 1'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 95.3040(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   9.4953(7)
_cell_length_b                   4.0294(3)
_cell_length_c                   12.4237(9)
_cell_measurement_temperature    100(1)
_cell_volume                     473.30(6)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      100(1)
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'Bruker SMART APEXII'
_diffrn_measurement_method       ω
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0272
_diffrn_reflns_av_sigmaI/netI    0.0200
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       5
_diffrn_reflns_limit_k_min       -5
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            6040
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_diffrn_reflns_theta_min         2.59
_exptl_absorpt_coefficient_mu    38.065
_exptl_absorpt_correction_T_max  0.15
_exptl_absorpt_correction_T_min  0.05
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS (multi-scan)'
_exptl_crystal_colour            'silver metallic'
_exptl_crystal_density_diffrn    6.192
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       parallelpiped
_exptl_crystal_F_000             764
_exptl_crystal_size_max          0.16
_exptl_crystal_size_mid          0.07
_exptl_crystal_size_min          0.05
_refine_diff_density_max         1.740
_refine_diff_density_min         -0.898
_refine_diff_density_rms         0.265
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.261
_refine_ls_matrix_type           full
_refine_ls_number_parameters     66
_refine_ls_number_reflns         1240
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.261
_refine_ls_R_factor_all          0.0161
_refine_ls_R_factor_gt           0.0155
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0065P)²+1.2900P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0315
_refine_ls_wR_factor_ref         0.0317
_reflns_number_gt                1219
_reflns_number_total             1240
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            cm901219u_si_001.cif
_cod_data_source_block           hh460as
_cod_database_code               4001041
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z'
'-x, -y, -z'
'x, -y, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Eu1 Eu 0.20004(2) 0.0000 0.276540(18) 0.00673(7) Uani 1 2 d S
Eu2 Eu 0.5000 0.5000 0.5000 0.00580(8) Uani 1 4 d S
Eu3 Eu 0.0000 0.5000 0.0000 0.00583(8) Uani 1 4 d S
Ga1 Ga -0.10862(5) 0.5000 0.43691(4) 0.00591(11) Uani 1 2 d S
Ga2 Ga 0.60436(5) 0.0000 0.28102(4) 0.00580(11) Uani 0.9863(7) 2 d SP
Ga3 Ga -0.19480(5) 0.0000 0.17527(4) 0.00597(11) Uani 0.9863(7) 2 d SP
Ga4 Ga 0.39829(5) 0.5000 0.05440(4) 0.00600(11) Uani 1 2 d S
As1 As -0.04984(5) 0.5000 0.24166(4) 0.00542(10) Uani 1 2 d S
As2 As 0.44668(5) 0.5000 0.25577(4) 0.00536(10) Uani 1 2 d S
As3 As 0.26186(5) 0.0000 0.53228(4) 0.00550(10) Uani 1 2 d S
As4 As 0.24058(5) 0.0000 0.02570(4) 0.00530(10) Uani 1 2 d S
Eu4P Eu -0.2959(18) 0.0000 0.2236(14) 0.007 Uiso 0.0137(7) 2 d SP
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ga Ga 0.2307 1.6083 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
As As 0.0499 2.0058 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
As1 Eu1 As1 80.683(13) 1_545 .
As1 Eu1 As2 97.988(10) 1_545 1_545
As1 Eu1 As2 167.300(14) . 1_545
As1 Eu1 As2 167.299(14) 1_545 .
As1 Eu1 As2 97.988(10) . .
As2 Eu1 As2 80.505(13) 1_545 .
As1 Eu1 As4 91.339(12) 1_545 .
As1 Eu1 As4 91.340(12) . .
As2 Eu1 As4 76.035(11) 1_545 .
As2 Eu1 As4 76.035(11) . .
As1 Eu1 As3 101.960(12) 1_545 .
As1 Eu1 As3 101.959(12) . .
As2 Eu1 As3 90.687(12) 1_545 .
As2 Eu1 As3 90.687(12) . .
As4 Eu1 As3 162.466(14) . .
As1 Eu1 Eu1 130.342(7) 1_545 1_565
As1 Eu1 Eu1 49.659(7) . 1_565
As2 Eu1 Eu1 130.253(7) 1_545 1_565
As2 Eu1 Eu1 49.748(7) . 1_565
As4 Eu1 Eu1 90.0 . 1_565
As3 Eu1 Eu1 90.0 . 1_565
As1 Eu1 Eu1 49.659(7) 1_545 1_545
As1 Eu1 Eu1 130.342(7) . 1_545
As2 Eu1 Eu1 49.747(7) 1_545 1_545
As2 Eu1 Eu1 130.252(7) . 1_545
As4 Eu1 Eu1 90.0 . 1_545
As3 Eu1 Eu1 90.0 . 1_545
Eu1 Eu1 Eu1 180.0 1_565 1_545
As1 Eu1 Eu3 46.087(9) 1_545 1_545
As1 Eu1 Eu3 85.227(9) . 1_545
As2 Eu1 Eu3 84.853(9) 1_545 1_545
As2 Eu1 Eu3 121.299(11) . 1_545
As4 Eu1 Eu3 45.265(7) . 1_545
As3 Eu1 Eu3 146.225(7) . 1_545
Eu1 Eu1 Eu3 118.127(3) 1_565 1_545
Eu1 Eu1 Eu3 61.874(3) 1_545 1_545
As1 Eu1 Eu3 85.227(10) 1_545 .
As1 Eu1 Eu3 46.088(9) . .
As2 Eu1 Eu3 121.300(11) 1_545 .
As2 Eu1 Eu3 84.853(9) . .
As4 Eu1 Eu3 45.265(7) . .
As3 Eu1 Eu3 146.225(7) . .
Eu1 Eu1 Eu3 61.874(3) 1_565 .
Eu1 Eu1 Eu3 118.127(3) 1_545 .
Eu3 Eu1 Eu3 56.253(5) 1_545 .
As1 Eu1 Eu2 147.759(11) 1_545 .
As1 Eu1 Eu2 103.768(8) . .
As2 Eu1 Eu2 84.158(10) 1_545 .
As2 Eu1 Eu2 44.889(9) . .
As4 Eu1 Eu2 120.100(10) . .
As3 Eu1 Eu2 45.802(7) . .
Eu1 Eu1 Eu2 62.000(3) 1_565 .
Eu1 Eu1 Eu2 117.999(3) 1_545 .
Eu3 Eu1 Eu2 163.834(6) 1_545 .
Eu3 Eu1 Eu2 121.186(4) . .
As1 Eu1 Eu2 103.768(8) 1_545 1_545
As1 Eu1 Eu2 147.758(11) . 1_545
As2 Eu1 Eu2 44.889(9) 1_545 1_545
As2 Eu1 Eu2 84.158(10) . 1_545
As4 Eu1 Eu2 120.100(10) . 1_545
As3 Eu1 Eu2 45.802(7) . 1_545
Eu1 Eu1 Eu2 117.999(3) 1_565 1_545
Eu1 Eu1 Eu2 62.000(3) 1_545 1_545
Eu3 Eu1 Eu2 121.186(4) 1_545 1_545
Eu3 Eu1 Eu2 163.834(6) . 1_545
Eu2 Eu1 Eu2 55.999(5) . 1_545
As2 Eu2 As2 180.0 3_666 .
As2 Eu2 As3 85.778(11) 3_666 .
As2 Eu2 As3 94.223(11) . .
As2 Eu2 As3 94.221(11) 3_666 3_666
As2 Eu2 As3 85.778(11) . 3_666
As3 Eu2 As3 180.0 . 3_666
As2 Eu2 As3 94.221(11) 3_666 3_656
As2 Eu2 As3 85.778(11) . 3_656
As3 Eu2 As3 98.367(13) . 3_656
As3 Eu2 As3 81.633(13) 3_666 3_656
As2 Eu2 As3 85.779(11) 3_666 1_565
As2 Eu2 As3 94.222(11) . 1_565
As3 Eu2 As3 81.633(13) . 1_565
As3 Eu2 As3 98.367(13) 3_666 1_565
As3 Eu2 As3 180.000(17) 3_656 1_565
As2 Eu2 Ga2 43.515(9) 3_666 3_666
As2 Eu2 Ga2 136.485(9) . 3_666
As3 Eu2 Ga2 90.630(10) . 3_666
As3 Eu2 Ga2 89.369(10) 3_666 3_666
As3 Eu2 Ga2 136.149(12) 3_656 3_666
As3 Eu2 Ga2 43.851(12) 1_565 3_666
As2 Eu2 Ga2 43.515(9) 3_666 3_656
As2 Eu2 Ga2 136.485(9) . 3_656
As3 Eu2 Ga2 43.850(12) . 3_656
As3 Eu2 Ga2 136.149(12) 3_666 3_656
As3 Eu2 Ga2 89.369(10) 3_656 3_656
As3 Eu2 Ga2 90.631(10) 1_565 3_656
Ga2 Eu2 Ga2 68.120(10) 3_666 3_656
As2 Eu2 Ga2 136.485(9) 3_666 1_565
As2 Eu2 Ga2 43.515(9) . 1_565
As3 Eu2 Ga2 136.150(12) . 1_565
As3 Eu2 Ga2 43.851(12) 3_666 1_565
As3 Eu2 Ga2 90.631(10) 3_656 1_565
As3 Eu2 Ga2 89.369(10) 1_565 1_565
Ga2 Eu2 Ga2 111.880(10) 3_666 1_565
Ga2 Eu2 Ga2 180.0 3_656 1_565
As2 Eu2 Ga2 136.485(9) 3_666 .
As2 Eu2 Ga2 43.515(9) . .
As3 Eu2 Ga2 89.370(10) . .
As3 Eu2 Ga2 90.630(10) 3_666 .
As3 Eu2 Ga2 43.850(12) 3_656 .
As3 Eu2 Ga2 136.150(12) 1_565 .
Ga2 Eu2 Ga2 180.0 3_666 .
Ga2 Eu2 Ga2 111.880(10) 3_656 .
Ga2 Eu2 Ga2 68.120(10) 1_565 .
As2 Eu2 Eu2 90.0 3_666 1_565
As2 Eu2 Eu2 90.0 . 1_565
As3 Eu2 Eu2 130.817(6) . 1_565
As3 Eu2 Eu2 49.183(6) 3_666 1_565
As3 Eu2 Eu2 130.817(7) 3_656 1_565
As3 Eu2 Eu2 49.183(6) 1_565 1_565
Ga2 Eu2 Eu2 55.940(5) 3_666 1_565
Ga2 Eu2 Eu2 124.060(5) 3_656 1_565
Ga2 Eu2 Eu2 55.940(5) 1_565 1_565
Ga2 Eu2 Eu2 124.060(5) . 1_565
As2 Eu2 Eu2 90.0 3_666 1_545
As2 Eu2 Eu2 90.0 . 1_545
As3 Eu2 Eu2 49.183(6) . 1_545
As3 Eu2 Eu2 130.817(6) 3_666 1_545
As3 Eu2 Eu2 49.183(6) 3_656 1_545
As3 Eu2 Eu2 130.817(7) 1_565 1_545
Ga2 Eu2 Eu2 124.060(5) 3_666 1_545
Ga2 Eu2 Eu2 55.940(5) 3_656 1_545
Ga2 Eu2 Eu2 124.060(5) 1_565 1_545
Ga2 Eu2 Eu2 55.940(5) . 1_545
Eu2 Eu2 Eu2 180.0 1_565 1_545
As4 Eu3 As4 96.999(13) . 3
As4 Eu3 As4 83.001(13) . 1_565
As4 Eu3 As4 180.000(17) 3 1_565
As4 Eu3 As4 180.0 . 3_565
As4 Eu3 As4 83.001(13) 3 3_565
As4 Eu3 As4 96.999(13) 1_565 3_565
As4 Eu3 As1 85.458(11) . 3_565
As4 Eu3 As1 94.543(11) 3 3_565
As4 Eu3 As1 85.457(11) 1_565 3_565
As4 Eu3 As1 94.543(11) 3_565 3_565
As4 Eu3 As1 94.542(11) . .
As4 Eu3 As1 85.457(11) 3 .
As4 Eu3 As1 94.543(11) 1_565 .
As4 Eu3 As1 85.457(11) 3_565 .
As1 Eu3 As1 180.0 3_565 .
As4 Eu3 Ga3 89.352(11) . .
As4 Eu3 Ga3 43.099(12) 3 .
As4 Eu3 Ga3 136.901(12) 1_565 .
As4 Eu3 Ga3 90.648(11) 3_565 .
As1 Eu3 Ga3 136.279(8) 3_565 .
As1 Eu3 Ga3 43.721(8) . .
As4 Eu3 Ga3 43.099(12) . 3
As4 Eu3 Ga3 89.352(11) 3 3
As4 Eu3 Ga3 90.648(11) 1_565 3
As4 Eu3 Ga3 136.901(12) 3_565 3
As1 Eu3 Ga3 43.721(8) 3_565 3
As1 Eu3 Ga3 136.279(9) . 3
Ga3 Eu3 Ga3 111.958(10) . 3
As4 Eu3 Ga3 136.901(12) . 1_565
As4 Eu3 Ga3 90.648(11) 3 1_565
As4 Eu3 Ga3 89.352(11) 1_565 1_565
As4 Eu3 Ga3 43.099(12) 3_565 1_565
As1 Eu3 Ga3 136.279(8) 3_565 1_565
As1 Eu3 Ga3 43.721(8) . 1_565
Ga3 Eu3 Ga3 68.042(10) . 1_565
Ga3 Eu3 Ga3 180.000(14) 3 1_565
As4 Eu3 Ga3 90.648(11) . 3_565
As4 Eu3 Ga3 136.901(12) 3 3_565
As4 Eu3 Ga3 43.099(12) 1_565 3_565
As4 Eu3 Ga3 89.352(10) 3_565 3_565
As1 Eu3 Ga3 43.721(8) 3_565 3_565
As1 Eu3 Ga3 136.279(8) . 3_565
Ga3 Eu3 Ga3 180.0 . 3_565
Ga3 Eu3 Ga3 68.042(10) 3 3_565
Ga3 Eu3 Ga3 111.958(10) 1_565 3_565
As4 Eu3 Eu3 131.501(7) . 1_565
As4 Eu3 Eu3 131.501(7) 3 1_565
As4 Eu3 Eu3 48.499(7) 1_565 1_565
As4 Eu3 Eu3 48.499(7) 3_565 1_565
As1 Eu3 Eu3 90.0 3_565 1_565
As1 Eu3 Eu3 90.0 . 1_565
Ga3 Eu3 Eu3 124.021(5) . 1_565
Ga3 Eu3 Eu3 124.021(5) 3 1_565
Ga3 Eu3 Eu3 55.979(5) 1_565 1_565
Ga3 Eu3 Eu3 55.979(5) 3_565 1_565
As4 Eu3 Eu3 48.499(7) . 1_545
As4 Eu3 Eu3 48.499(7) 3 1_545
As4 Eu3 Eu3 131.501(7) 1_565 1_545
As4 Eu3 Eu3 131.501(7) 3_565 1_545
As1 Eu3 Eu3 90.0 3_565 1_545
As1 Eu3 Eu3 90.0 . 1_545
Ga3 Eu3 Eu3 55.979(5) . 1_545
Ga3 Eu3 Eu3 55.979(5) 3 1_545
Ga3 Eu3 Eu3 124.021(5) 1_565 1_545
Ga3 Eu3 Eu3 124.021(5) 3_565 1_545
Eu3 Eu3 Eu3 180.0 1_565 1_545
Ga1 Ga1 As3 111.17(2) 3_566 3_556
Ga1 Ga1 As3 111.17(2) 3_566 3_566
As3 Ga1 As3 105.27(3) 3_556 3_566
Ga1 Ga1 As1 111.19(3) 3_566 .
As3 Ga1 As1 108.920(18) 3_556 .
As3 Ga1 As1 108.920(18) 3_566 .
Ga1 Ga1 Eu4P 141.3(2) 3_566 1_565
As3 Ga1 Eu4P 107.4(2) 3_556 1_565
As3 Ga1 Eu4P 54.8(2) 3_566 1_565
As1 Ga1 Eu4P 56.1(3) . 1_565
Ga1 Ga1 Eu4P 141.3(2) 3_566 .
As3 Ga1 Eu4P 54.8(2) 3_556 .
As3 Ga1 Eu4P 107.4(2) 3_566 .
As1 Ga1 Eu4P 56.1(3) . .
Eu4P Ga1 Eu4P 66.9(3) 1_565 .
Ga3 Ga2 As2 115.071(18) 1_655 .
Ga3 Ga2 As2 115.071(17) 1_655 1_545
As2 Ga2 As2 106.62(3) . 1_545
Ga3 Ga2 As3 98.25(2) 1_655 3_656
As2 Ga2 As3 110.857(18) . 3_656
As2 Ga2 As3 110.857(18) 1_545 3_656
Ga3 Ga2 Eu2 134.297(15) 1_655 .
As2 Ga2 Eu2 56.129(13) . .
As2 Ga2 Eu2 109.931(19) 1_545 .
As3 Ga2 Eu2 57.231(12) 3_656 .
Ga3 Ga2 Eu2 134.297(15) 1_655 1_545
As2 Ga2 Eu2 109.931(19) . 1_545
As2 Ga2 Eu2 56.128(13) 1_545 1_545
As3 Ga2 Eu2 57.231(12) 3_656 1_545
Eu2 Ga2 Eu2 68.120(10) . 1_545
Ga2 Ga3 As4 118.13(3) 1_455 3
Ga2 Ga3 As1 104.803(19) 1_455 .
As4 Ga3 As1 111.401(18) 3 .
Ga2 Ga3 As1 104.804(19) 1_455 1_545
As4 Ga3 As1 111.400(18) 3 1_545
As1 Ga3 As1 105.29(3) . 1_545
Eu4P Ga3 Eu3 142.8(3) . 1_545
Ga2 Ga3 Eu3 143.610(9) 1_455 1_545
As4 Ga3 Eu3 56.389(12) 3 1_545
As1 Ga3 Eu3 110.34(2) . 1_545
As1 Ga3 Eu3 57.193(13) 1_545 1_545
Ga2 Ga3 Eu3 143.610(9) 1_455 .
As4 Ga3 Eu3 56.389(12) 3 .
As1 Ga3 Eu3 57.193(13) . .
As1 Ga3 Eu3 110.34(2) 1_545 .
Eu3 Ga3 Eu3 68.042(10) 1_545 .
Ga4 Ga4 As2 117.97(3) 3_665 .
Ga4 Ga4 As4 114.193(19) 3_665 1_565
As2 Ga4 As4 101.164(18) . 1_565
Ga4 Ga4 As4 114.19(2) 3_665 .
As2 Ga4 As4 101.163(18) . .
As4 Ga4 As4 106.41(3) 1_565 .
Ga3 As1 Ga3 105.29(3) . 1_565
Ga3 As1 Ga1 98.638(18) . .
Ga3 As1 Ga1 98.638(18) 1_565 .
Ga1 As1 Eu4P 80.6(3) . .
Ga1 As1 Eu4P 80.6(3) . 1_565
Eu4P As1 Eu4P 81.8(4) . 1_565
Ga3 As1 Eu3 79.086(16) . .
Ga3 As1 Eu3 79.086(16) 1_565 .
Ga1 As1 Eu3 176.15(2) . .
Eu4P As1 Eu3 96.5(3) . .
Eu4P As1 Eu3 96.5(3) 1_565 .
Ga3 As1 Eu1 85.115(12) . .
Ga3 As1 Eu1 160.73(2) 1_565 .
Ga1 As1 Eu1 95.687(16) . .
Eu4P As1 Eu1 98.6(2) . .
Eu4P As1 Eu1 176.2(3) 1_565 .
Eu3 As1 Eu1 87.243(11) . .
Ga3 As1 Eu1 160.73(2) . 1_565
Ga3 As1 Eu1 85.116(12) 1_565 1_565
Ga1 As1 Eu1 95.687(16) . 1_565
Eu4P As1 Eu1 176.2(3) . 1_565
Eu4P As1 Eu1 98.6(2) 1_565 1_565
Eu3 As1 Eu1 87.243(11) . 1_565
Eu1 As1 Eu1 80.682(13) . 1_565
Ga4 As2 Ga2 100.201(18) . 1_565
Ga4 As2 Ga2 100.202(18) . .
Ga2 As2 Ga2 106.62(3) 1_565 .
Ga4 As2 Eu2 179.04(2) . .
Ga2 As2 Eu2 80.357(16) 1_565 .
Ga2 As2 Eu2 80.356(16) . .
Ga4 As2 Eu1 90.735(15) . 1_565
Ga2 As2 Eu1 85.123(12) 1_565 1_565
Ga2 As2 Eu1 162.05(2) . 1_565
Eu2 As2 Eu1 88.532(11) . 1_565
Ga4 As2 Eu1 90.734(15) . .
Ga2 As2 Eu1 162.05(2) 1_565 .
Ga2 As2 Eu1 85.124(12) . .
Eu2 As2 Eu1 88.533(11) . .
Eu1 As2 Eu1 80.505(13) 1_565 .
Ga4 As2 Eu4P 87.0(3) . 1_665
Eu2 As2 Eu4P 93.8(3) . 1_665
Eu1 As2 Eu4P 101.0(2) 1_565 1_665
Eu1 As2 Eu4P 177.3(3) . 1_665
Ga4 As2 Eu4P 87.0(3) . 1_655
Eu2 As2 Eu4P 93.8(3) . 1_655
Eu1 As2 Eu4P 177.3(3) 1_565 1_655
Eu1 As2 Eu4P 101.0(2) . 1_655
Eu4P As2 Eu4P 77.5(4) 1_665 1_655
Ga1 As3 Ga1 105.27(3) 3_556 3_566
Ga1 As3 Ga2 96.184(18) 3_556 3_656
Ga1 As3 Ga2 96.184(18) 3_566 3_656
Ga1 As3 Eu4P 81.8(2) 3_556 3_556
Ga1 As3 Eu4P 81.8(2) 3_566 3_556
Ga1 As3 Eu2 167.795(18) 3_556 .
Ga1 As3 Eu2 86.469(11) 3_566 .
Ga2 As3 Eu2 78.919(14) 3_656 .
Eu4P As3 Eu2 96.8(3) 3_556 .
Ga1 As3 Eu2 86.469(11) 3_556 1_545
Ga1 As3 Eu2 167.795(18) 3_566 1_545
Ga2 As3 Eu2 78.919(14) 3_656 1_545
Eu4P As3 Eu2 96.8(2) 3_556 1_545
Eu2 As3 Eu2 81.633(13) . 1_545
Ga1 As3 Eu1 95.477(17) 3_556 .
Ga1 As3 Eu1 95.477(17) 3_566 .
Ga2 As3 Eu1 160.73(2) 3_656 .
Eu4P As3 Eu1 175.5(3) 3_556 .
Eu2 As3 Eu1 86.550(11) . .
Eu2 As3 Eu1 86.550(11) 1_545 .
Ga3 As4 Ga4 100.846(18) 3 1_545
Ga3 As4 Ga4 100.846(18) 3 .
Ga4 As4 Ga4 106.41(3) 1_545 .
Ga3 As4 Eu3 80.512(14) 3 1_545
Ga4 As4 Eu3 85.172(11) 1_545 1_545
Ga4 As4 Eu3 167.707(18) . 1_545
Ga3 As4 Eu3 80.512(14) 3 .
Ga4 As4 Eu3 167.707(18) 1_545 .
Ga4 As4 Eu3 85.172(11) . .
Eu3 As4 Eu3 83.002(13) 1_545 .
Ga3 As4 Eu1 163.08(2) 3 .
Ga4 As4 Eu1 89.169(16) 1_545 .
Ga4 As4 Eu1 89.169(16) . .
Eu3 As4 Eu1 86.848(11) 1_545 .
Eu3 As4 Eu1 86.848(11) . .
Ga4 As4 Eu4P 89.33(19) 1_545 3
Ga4 As4 Eu4P 89.33(19) . 3
Eu3 As4 Eu4P 95.0(2) 1_545 3
Eu3 As4 Eu4P 95.0(2) . 3
Eu1 As4 Eu4P 177.5(3) . 3
Ga3 Eu4P Ga2 175.5(16) . 1_455
Ga3 Eu4P As3 119.7(10) . 3_556
Ga2 Eu4P As3 55.8(7) 1_455 3_556
Ga3 Eu4P As1 52.3(4) . .
Ga2 Eu4P As1 125.1(6) 1_455 .
As3 Eu4P As1 85.2(4) 3_556 .
Ga3 Eu4P As1 52.3(4) . 1_545
Ga2 Eu4P As1 125.1(6) 1_455 1_545
As3 Eu4P As1 85.2(4) 3_556 1_545
As1 Eu4P As1 81.8(4) . 1_545
Ga3 Eu4P As4 44.8(6) . 3
Ga2 Eu4P As4 139.8(10) 1_455 3
As3 Eu4P As4 164.4(6) 3_556 3
As1 Eu4P As4 83.0(4) . 3
As1 Eu4P As4 83.0(4) 1_545 3
Ga3 Eu4P As2 136.6(5) . 1_445
Ga2 Eu4P As2 45.4(4) 1_455 1_445
As3 Eu4P As2 83.5(4) 3_556 1_445
As1 Eu4P As2 168.6(6) . 1_445
As1 Eu4P As2 99.28(7) 1_545 1_445
As4 Eu4P As2 108.4(4) 3 1_445
Ga3 Eu4P As2 136.6(5) . 1_455
Ga2 Eu4P As2 45.4(4) 1_455 1_455
As3 Eu4P As2 83.5(4) 3_556 1_455
As1 Eu4P As2 99.28(7) . 1_455
As1 Eu4P As2 168.6(6) 1_545 1_455
As4 Eu4P As2 108.4(4) 3 1_455
As2 Eu4P As2 77.5(4) 1_445 1_455
Ga3 Eu4P Ga1 90.3(7) . 1_545
Ga2 Eu4P Ga1 85.9(7) 1_455 1_545
As3 Eu4P Ga1 43.3(2) 3_556 1_545
As1 Eu4P Ga1 89.6(4) . 1_545
As1 Eu4P Ga1 43.24(17) 1_545 1_545
As4 Eu4P Ga1 126.2(4) 3 1_545
As2 Eu4P Ga1 83.6(2) 1_445 1_545
As2 Eu4P Ga1 125.4(5) 1_455 1_545
Ga3 Eu4P Ga1 90.3(7) . .
Ga2 Eu4P Ga1 85.9(7) 1_455 .
As3 Eu4P Ga1 43.3(2) 3_556 .
As1 Eu4P Ga1 43.24(17) . .
As1 Eu4P Ga1 89.6(4) 1_545 .
As4 Eu4P Ga1 126.2(4) 3 .
As2 Eu4P Ga1 125.4(5) 1_445 .
As2 Eu4P Ga1 83.6(2) 1_455 .
Ga1 Eu4P Ga1 66.9(3) 1_545 .
Ga3 Eu4P Eu4P 90.000(1) . 1_565
Ga2 Eu4P Eu4P 90.0 1_455 1_565
As3 Eu4P Eu4P 90.0 3_556 1_565
As1 Eu4P Eu4P 49.1(2) . 1_565
As1 Eu4P Eu4P 130.9(2) 1_545 1_565
As4 Eu4P Eu4P 90.0 3 1_565
As2 Eu4P Eu4P 128.73(19) 1_445 1_565
As2 Eu4P Eu4P 51.27(19) 1_455 1_565
Ga1 Eu4P Eu4P 123.43(14) 1_545 1_565
Ga1 Eu4P Eu4P 56.57(15) . 1_565
As3 Eu4P Eu4P 90.0 3_556 1_545
As1 Eu4P Eu4P 130.9(2) . 1_545
As1 Eu4P Eu4P 49.1(2) 1_545 1_545
As4 Eu4P Eu4P 90.000(1) 3 1_545
As2 Eu4P Eu4P 51.27(19) 1_445 1_545
As2 Eu4P Eu4P 128.73(19) 1_455 1_545
Ga1 Eu4P Eu4P 56.57(15) 1_545 1_545
Ga1 Eu4P Eu4P 123.43(15) . 1_545
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 As1 3.1123(4) 1_545
Eu1 As1 3.1123(4) .
Eu1 As2 3.1180(4) 1_545
Eu1 As2 3.1180(4) .
Eu1 As4 3.1751(5) .
Eu1 As3 3.1772(6) .
Eu1 Eu1 4.0294(3) 1_565
Eu1 Eu1 4.0294(3) 1_545
Eu1 Eu3 4.2737(3) 1_545
Eu1 Eu3 4.2737(3) .
Eu1 Eu2 4.2915(3) .
Eu1 Eu2 4.2915(3) 1_545
Eu2 As2 3.0296(5) 3_666
Eu2 As2 3.0296(5) .
Eu2 As3 3.0823(4) .
Eu2 As3 3.0823(4) 3_666
Eu2 As3 3.0823(4) 3_656
Eu2 As3 3.0823(4) 1_565
Eu2 Ga2 3.5973(4) 3_666
Eu2 Ga2 3.5973(4) 3_656
Eu2 Ga2 3.5973(5) 1_565
Eu2 Ga2 3.5973(4) .
Eu2 Eu2 4.0294(3) 1_565
Eu2 Eu2 4.0294(3) 1_545
Eu3 As4 3.0405(4) .
Eu3 As4 3.0405(4) 3
Eu3 As4 3.0405(4) 1_565
Eu3 As4 3.0405(4) 3_565
Eu3 As1 3.0823(5) 3_565
Eu3 As1 3.0823(5) .
Eu3 Ga3 3.6009(5) .
Eu3 Ga3 3.6009(5) 3
Eu3 Ga3 3.6009(5) 1_565
Eu3 Ga3 3.6009(5) 3_565
Eu3 Eu3 4.0294(3) 1_565
Eu3 Eu3 4.0294(3) 1_545
Ga1 Ga1 2.4728(10) 3_566
Ga1 As3 2.5349(4) 3_556
Ga1 As3 2.5349(4) 3_566
Ga1 As1 2.5388(7) .
Ga1 Eu4P 3.657(14) 1_565
Ga1 Eu4P 3.657(14) .
Ga2 Ga3 2.4137(7) 1_655
Ga2 As2 2.5124(4) .
Ga2 As2 2.5124(4) 1_545
Ga2 As3 2.5395(7) 3_656
Ga2 Eu2 3.5973(4) 1_545
Ga3 Ga2 2.4138(7) 1_455
Ga3 As4 2.4945(7) 3
Ga3 As1 2.5346(4) .
Ga3 As1 2.5346(4) 1_545
Ga3 Eu3 3.6009(5) 1_545
Ga4 Ga4 2.4578(10) 3_665
Ga4 As2 2.5016(7) .
Ga4 As4 2.5159(4) 1_565
Ga4 As4 2.5159(4) .
As1 Ga3 2.5346(4) 1_565
As1 Eu4P 3.078(13) .
As1 Eu4P 3.078(13) 1_565
As1 Eu1 3.1123(4) 1_565
As2 Ga2 2.5124(4) 1_565
As2 Eu1 3.1180(4) 1_565
As2 Eu4P 3.220(14) 1_665
As2 Eu4P 3.220(14) 1_655
As3 Ga1 2.5349(4) 3_556
As3 Ga1 2.5349(4) 3_566
As3 Ga2 2.5395(7) 3_656
As3 Eu4P 3.020(17) 3_556
As3 Eu2 3.0823(4) 1_545
As4 Ga3 2.4945(7) 3
As4 Ga4 2.5159(4) 1_545
As4 Eu3 3.0405(4) 1_545
As4 Eu4P 3.190(17) 3
Eu4P As3 3.020(17) 3_556
Eu4P As1 3.078(13) 1_545
Eu4P As4 3.190(17) 3
Eu4P As2 3.220(14) 1_445
Eu4P As2 3.220(14) 1_455
Eu4P Ga1 3.657(14) 1_545
Eu4P Eu4P 4.0294(3) 1_565
Eu4P Eu4P 4.0294(3) 1_545
