#------------------------------------------------------------------------------
#$Date: 2016-03-21 01:21:50 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178377 $
#$URL: svn://www.crystallography.net/cod/cif/4/00/14/4001443.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4001443
loop_
_publ_author_name
'Zhang, Jian'
'Yao, Yuan-Gen'
'Bu, Xianhui'
_publ_section_title
;
 Comparative Study of Homochiral and Racemic Chiral Metal-Organic
 Frameworks Built from Camphoric Acid
;
_journal_issue                   21
_journal_name_full               'Chemistry of Materials'
_journal_page_first              5083
_journal_paper_doi               10.1021/cm071689a
_journal_volume                  19
_journal_year                    2007
_chemical_absolute_configuration rm
_chemical_formula_sum            'C30 H36 Cu2 N2 O8'
_chemical_formula_weight         679.71
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           5
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  'C 2y'
_symmetry_space_group_name_H-M   'C 1 2 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 121.843(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   21.2692(16)
_cell_length_b                   12.5647(6)
_cell_length_c                   13.4995(10)
_cell_measurement_reflns_used    4543
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      27.48
_cell_measurement_theta_min      3.03
_cell_volume                     3064.7(4)
_computing_cell_refinement       'Siemens SMART & SAINT'
_computing_data_collection       'Siemens SMART'
_computing_data_reduction        'Siemens XPREP'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'Siemens SHELXTL'
_computing_structure_solution    'Siemens SHELXTL'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Bruker P4'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0165
_diffrn_reflns_av_sigmaI/netI    0.0347
_diffrn_reflns_limit_h_max       27
_diffrn_reflns_limit_h_min       -27
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       8
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            11559
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_diffrn_reflns_theta_min         3.03
_diffrn_standards_decay_%        none
_diffrn_standards_interval_count none
_diffrn_standards_interval_time  none
_diffrn_standards_number         none
_exptl_absorpt_coefficient_mu    1.439
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_correction_T_min  0.7056
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   'SADABS (Sheldrick, 1996)'
_exptl_crystal_colour            Green
_exptl_crystal_density_diffrn    1.473
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Prism
_exptl_crystal_F_000             1408
_exptl_crystal_size_max          0.4000
_exptl_crystal_size_mid          0.3000
_exptl_crystal_size_min          0.1000
_refine_diff_density_max         0.903
_refine_diff_density_min         -0.331
_refine_diff_density_rms         0.079
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.013(13)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.030
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     385
_refine_ls_number_reflns         6685
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      1.030
_refine_ls_R_factor_gt           0.0402
_refine_ls_shift/su_max          0.008
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0771P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1085
_refine_ls_wR_factor_ref         0.1112
_reflns_number_gt                6211
_reflns_number_total             6685
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            cm071689a-file004.cif
_cod_data_source_block           a
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_sg_symbol_H-M      C2
_cod_database_code               4001443
#BEGIN Tags that were not found in dictionaries:
_refine_ls_r_factor_ref          0.0432
#END Tags that were not found in dictionaries
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Cu1 Cu -0.67704(2) 0.01122(3) -1.17538(3) 0.02702(11) Uani 1 1 d .
Cu2 Cu -0.81040(2) 0.08968(3) -1.32170(3) 0.02927(12) Uani 1 1 d .
O1 O -0.64662(14) 0.0558(2) -1.2839(2) 0.0389(6) Uani 1 1 d .
O2 O -0.76185(14) 0.1044(2) -1.4124(2) 0.0380(6) Uani 1 1 d .
O3 O -0.77698(15) 0.3811(2) -1.7345(2) 0.0401(6) Uani 1 1 d .
O4 O -0.66186(15) 0.4429(2) -1.6164(2) 0.0401(6) Uani 1 1 d .
O5 O -0.64811(15) 0.1513(2) -1.1021(2) 0.0396(6) Uani 1 1 d .
O6 O -0.75811(16) 0.2197(2) -1.2302(2) 0.0432(7) Uani 1 1 d .
O7 O -0.84478(15) 0.0536(2) -1.2156(2) 0.0433(7) Uani 1 1 d .
O8 O -0.73244(14) -0.0132(2) -1.0945(2) 0.0403(7) Uani 1 1 d .
N1 N -0.58718(16) -0.0710(3) -1.0226(3) 0.0380(7) Uani 1 1 d .
N2 N -0.40377(17) -0.3271(3) -0.4702(3) 0.0400(8) Uani 1 1 d .
C1 C -0.6825(2) 0.2571(3) -1.6055(3) 0.0382(8) Uani 1 1 d .
C2 C -0.6653(2) 0.2470(3) -1.4779(3) 0.0451(10) Uani 1 1 d .
C3 C -0.6732(2) 0.1253(3) -1.4655(3) 0.0413(9) Uani 1 1 d .
H3A H -0.6244 0.0941 -1.4368 0.050 Uiso 1 1 calc R
C4 C -0.7241(4) 0.0812(4) -1.5871(4) 0.0723(16) Uani 1 1 d .
H4A H -0.7681 0.0508 -1.5939 0.087 Uiso 1 1 calc R
H4B H -0.6990 0.0261 -1.6038 0.087 Uiso 1 1 calc R
C5 C -0.7446(3) 0.1737(4) -1.6713(4) 0.0656(14) Uani 1 1 d .
H5A H -0.7922 0.2031 -1.6921 0.079 Uiso 1 1 calc R
H5B H -0.7470 0.1507 -1.7419 0.079 Uiso 1 1 calc R
C6 C -0.6155(4) 0.2300(5) -1.6149(6) 0.088(2) Uani 1 1 d .
H6A H -0.6315 0.2194 -1.6953 0.133 Uiso 1 1 calc R
H6B H -0.5925 0.1661 -1.5717 0.133 Uiso 1 1 calc R
H6C H -0.5805 0.2874 -1.5835 0.133 Uiso 1 1 calc R
C7 C -0.5878(4) 0.2808(6) -1.3875(5) 0.108(3) Uani 1 1 d .
H7A H -0.5599 0.2918 -1.4240 0.162 Uiso 1 1 calc R
H7B H -0.5646 0.2264 -1.3292 0.162 Uiso 1 1 calc R
H7C H -0.5894 0.3459 -1.3517 0.162 Uiso 1 1 calc R
C8 C -0.7257(4) 0.3126(4) -1.4705(5) 0.0730(19) Uani 1 1 d .
H8A H -0.7210 0.2995 -1.3968 0.110 Uiso 1 1 calc R
H8B H -0.7741 0.2912 -1.5324 0.110 Uiso 1 1 calc R
H8C H -0.7190 0.3871 -1.4778 0.110 Uiso 1 1 calc R
C9 C -0.7084(2) 0.3706(3) -1.6558(3) 0.0344(8) Uani 1 1 d .
C10 C -0.69538(17) 0.0933(3) -1.3806(3) 0.0278(6) Uani 1 1 d .
C11 C -0.6692(2) 0.3345(3) -1.0797(4) 0.0371(8) Uani 1 1 d .
C12 C -0.7217(2) 0.3750(3) -1.0410(3) 0.0401(8) Uani 1 1 d .
C13 C -0.6755(2) 0.4633(3) -0.9537(3) 0.0360(8) Uani 1 1 d .
H13A H -0.6742 0.5239 -0.9983 0.043 Uiso 1 1 calc R
C14 C -0.5957(3) 0.4144(5) -0.8834(5) 0.0733(17) Uani 1 1 d .
H14A H -0.5588 0.4685 -0.8668 0.088 Uiso 1 1 calc R
H14B H -0.5858 0.3848 -0.8102 0.088 Uiso 1 1 calc R
C15 C -0.5937(3) 0.3282(4) -0.9597(4) 0.0632(14) Uani 1 1 d .
H15A H -0.5880 0.2589 -0.9242 0.076 Uiso 1 1 calc R
H15B H -0.5527 0.3396 -0.9706 0.076 Uiso 1 1 calc R
C16 C -0.6592(3) 0.4099(4) -1.1563(4) 0.0629(13) Uani 1 1 d .
H16A H -0.7067 0.4284 -1.2226 0.094 Uiso 1 1 calc R
H16B H -0.6299 0.3765 -1.1823 0.094 Uiso 1 1 calc R
H16C H -0.6347 0.4731 -1.1131 0.094 Uiso 1 1 calc R
C17 C -0.7947(3) 0.4209(4) -1.1411(4) 0.0612(13) Uani 1 1 d .
H17A H -0.8279 0.4335 -1.1144 0.092 Uiso 1 1 calc R
H17B H -0.8168 0.3711 -1.2046 0.092 Uiso 1 1 calc R
H17C H -0.7851 0.4867 -1.1670 0.092 Uiso 1 1 calc R
C18 C -0.7383(3) 0.2829(4) -0.9830(4) 0.0462(10) Uani 1 1 d .
H18A H -0.7542 0.3112 -0.9337 0.069 Uiso 1 1 calc R
H18B H -0.6944 0.2411 -0.9371 0.069 Uiso 1 1 calc R
H18C H -0.7767 0.2389 -1.0421 0.069 Uiso 1 1 calc R
C19 C -0.6947(2) 0.2264(3) -1.1427(3) 0.0328(8) Uani 1 1 d .
C20 C -0.79798(19) 0.0043(3) -1.1249(3) 0.0326(7) Uani 1 1 d .
C21 C -0.5466(2) -0.0172(4) -0.9240(4) 0.0467(10) Uani 1 1 d .
H21A H -0.5432 0.0562 -0.9284 0.056 Uiso 1 1 calc R
C22 C -0.5091(2) -0.0645(4) -0.8149(3) 0.0455(10) Uani 1 1 d .
H22A H -0.4807 -0.0233 -0.7486 0.055 Uiso 1 1 calc R
C23 C -0.51425(18) -0.1734(3) -0.8052(3) 0.0351(8) Uani 1 1 d .
C24 C -0.5525(3) -0.2294(4) -0.9091(4) 0.0557(13) Uani 1 1 d .
H24A H -0.5552 -0.3033 -0.9076 0.067 Uiso 1 1 calc R
C25 C -0.5870(3) -0.1763(4) -1.0155(4) 0.0539(12) Uani 1 1 d .
H25A H -0.6108 -0.2159 -1.0839 0.065 Uiso 1 1 calc R
C26 C -0.3989(4) -0.2239(4) -0.4820(4) 0.079(2) Uani 1 1 d .
H26A H -0.3711 -0.1839 -0.4145 0.095 Uiso 1 1 calc R
C27 C -0.4321(4) -0.1706(4) -0.5878(4) 0.093(3) Uani 1 1 d .
H27A H -0.4239 -0.0983 -0.5905 0.112 Uiso 1 1 calc R
C28 C -0.47742(19) -0.2263(3) -0.6885(3) 0.0373(9) Uani 1 1 d .
C29 C -0.4852(3) -0.3309(4) -0.6733(4) 0.0739(18) Uani 1 1 d .
H29A H -0.5163 -0.3726 -0.7380 0.089 Uiso 1 1 calc R
C30 C -0.4481(3) -0.3776(4) -0.5638(4) 0.0730(19) Uani 1 1 d .
H30A H -0.4558 -0.4496 -0.5583 0.088 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O5 Cu1 O3 170.21(11) . 4_342
O5 Cu1 O1 88.92(12) . .
O3 Cu1 O1 91.59(12) 4_342 .
O5 Cu1 O8 88.91(12) . .
O3 Cu1 O8 88.05(13) 4_342 .
O1 Cu1 O8 164.85(10) . .
O5 Cu1 N1 93.61(12) . .
O3 Cu1 N1 95.29(13) 4_342 .
O1 Cu1 N1 111.60(11) . .
O8 Cu1 N1 83.50(11) . .
O5 Cu1 Cu2 88.25(8) . .
O3 Cu1 Cu2 81.98(8) 4_342 .
O1 Cu1 Cu2 88.98(7) . .
O8 Cu1 Cu2 75.97(7) . .
N1 Cu1 Cu2 159.36(9) . .
O7 Cu2 O4 87.13(13) . 4_342
O7 Cu2 O2 169.16(11) . .
O4 Cu2 O2 87.89(13) 4_342 .
O7 Cu2 O6 92.16(13) . .
O4 Cu2 O6 165.36(10) 4_342 .
O2 Cu2 O6 90.24(13) . .
O7 Cu2 N2 105.55(12) . 3_454
O4 Cu2 N2 97.65(12) 4_342 3_454
O2 Cu2 N2 84.65(11) . 3_454
O6 Cu2 N2 96.63(12) . 3_454
O7 Cu2 Cu1 91.97(8) . .
O4 Cu2 Cu1 86.07(8) 4_342 .
O2 Cu2 Cu1 78.09(7) . .
O6 Cu2 Cu1 79.34(8) . .
N2 Cu2 Cu1 162.22(9) 3_454 .
C10 O1 Cu1 117.7(2) . .
C10 O2 Cu2 129.8(2) . .
C9 O3 Cu1 125.2(3) . 4_352
C9 O4 Cu2 120.6(3) . 4_352
C19 O5 Cu1 119.2(2) . .
C19 O6 Cu2 128.0(3) . .
C20 O7 Cu2 114.4(2) . .
C20 O8 Cu1 132.0(2) . .
C25 N1 C21 117.4(4) . .
C25 N1 Cu1 120.4(3) . .
C21 N1 Cu1 119.0(3) . .
C30 N2 C26 115.7(4) . .
C30 N2 Cu2 120.3(3) . 3_546
C26 N2 Cu2 119.1(3) . 3_546
C6 C1 C5 110.5(4) . .
C6 C1 C9 107.4(3) . .
C5 C1 C9 111.9(3) . .
C6 C1 C2 112.6(4) . .
C5 C1 C2 102.1(3) . .
C9 C1 C2 112.3(3) . .
C7 C2 C3 109.0(4) . .
C7 C2 C1 112.9(4) . .
C3 C2 C1 102.8(3) . .
C7 C2 C8 112.5(5) . .
C3 C2 C8 111.6(4) . .
C1 C2 C8 107.6(4) . .
C10 C3 C4 113.3(4) . .
C10 C3 C2 116.1(3) . .
C4 C3 C2 107.4(3) . .
C10 C3 H3A 106.5 . .
C4 C3 H3A 106.5 . .
C2 C3 H3A 106.5 . .
C3 C4 C5 106.8(4) . .
C3 C4 H4A 110.4 . .
C5 C4 H4A 110.4 . .
C3 C4 H4B 110.4 . .
C5 C4 H4B 110.4 . .
H4A C4 H4B 108.6 . .
C4 C5 C1 105.5(4) . .
C4 C5 H5A 110.6 . .
C1 C5 H5A 110.6 . .
C4 C5 H5B 110.6 . .
C1 C5 H5B 110.6 . .
H5A C5 H5B 108.8 . .
C1 C6 H6A 109.5 . .
C1 C6 H6B 109.5 . .
H6A C6 H6B 109.5 . .
C1 C6 H6C 109.5 . .
H6A C6 H6C 109.5 . .
H6B C6 H6C 109.5 . .
C2 C7 H7A 109.5 . .
C2 C7 H7B 109.5 . .
H7A C7 H7B 109.5 . .
C2 C7 H7C 109.5 . .
H7A C7 H7C 109.5 . .
H7B C7 H7C 109.5 . .
C2 C8 H8A 109.5 . .
C2 C8 H8B 109.5 . .
H8A C8 H8B 109.5 . .
C2 C8 H8C 109.5 . .
H8A C8 H8C 109.5 . .
H8B C8 H8C 109.5 . .
O4 C9 O3 125.7(4) . .
O4 C9 C1 117.9(3) . .
O3 C9 C1 116.4(3) . .
O2 C10 O1 124.4(3) . .
O2 C10 C3 117.4(3) . .
O1 C10 C3 118.3(3) . .
C16 C11 C19 108.2(3) . .
C16 C11 C12 114.6(4) . .
C19 C11 C12 111.7(3) . .
C16 C11 C15 107.7(4) . .
C19 C11 C15 113.3(3) . .
C12 C11 C15 101.3(3) . .
C17 C12 C13 110.2(3) . .
C17 C12 C18 109.5(4) . .
C13 C12 C18 112.3(3) . .
C17 C12 C11 113.6(3) . .
C13 C12 C11 102.3(3) . .
C18 C12 C11 108.9(3) . .
C20 C13 C12 117.0(3) 4_353 .
C20 C13 C14 112.9(3) 4_353 .
C12 C13 C14 103.4(3) . .
C20 C13 H13A 107.7 4_353 .
C12 C13 H13A 107.7 . .
C14 C13 H13A 107.7 . .
C15 C14 C13 106.2(4) . .
C15 C14 H14A 110.5 . .
C13 C14 H14A 110.5 . .
C15 C14 H14B 110.5 . .
C13 C14 H14B 110.5 . .
H14A C14 H14B 108.7 . .
C14 C15 C11 106.6(4) . .
C14 C15 H15A 110.4 . .
C11 C15 H15A 110.4 . .
C14 C15 H15B 110.4 . .
C11 C15 H15B 110.4 . .
H15A C15 H15B 108.6 . .
C11 C16 H16A 109.5 . .
C11 C16 H16B 109.5 . .
H16A C16 H16B 109.5 . .
C11 C16 H16C 109.5 . .
H16A C16 H16C 109.5 . .
H16B C16 H16C 109.5 . .
C12 C17 H17A 109.5 . .
C12 C17 H17B 109.5 . .
H17A C17 H17B 109.5 . .
C12 C17 H17C 109.5 . .
H17A C17 H17C 109.5 . .
H17B C17 H17C 109.5 . .
C12 C18 H18A 109.5 . .
C12 C18 H18B 109.5 . .
H18A C18 H18B 109.5 . .
C12 C18 H18C 109.5 . .
H18A C18 H18C 109.5 . .
H18B C18 H18C 109.5 . .
O6 C19 O5 124.9(4) . .
O6 C19 C11 118.3(3) . .
O5 C19 C11 116.8(3) . .
O8 C20 O7 125.4(3) . .
O8 C20 C13 118.0(3) . 4_343
O7 C20 C13 116.6(3) . 4_343
N1 C21 C22 123.5(4) . .
N1 C21 H21A 118.2 . .
C22 C21 H21A 118.2 . .
C23 C22 C21 119.7(4) . .
C23 C22 H22A 120.2 . .
C21 C22 H22A 120.2 . .
C22 C23 C24 116.1(4) . .
C22 C23 C28 121.1(3) . .
C24 C23 C28 122.8(3) . .
C23 C24 C25 120.6(4) . .
C23 C24 H24A 119.7 . .
C25 C24 H24A 119.7 . .
N1 C25 C24 122.2(5) . .
N1 C25 H25A 118.9 . .
C24 C25 H25A 118.9 . .
N2 C26 C27 124.8(5) . .
N2 C26 H26A 117.6 . .
C27 C26 H26A 117.6 . .
C28 C27 C26 118.9(5) . .
C28 C27 H27A 120.5 . .
C26 C27 H27A 120.5 . .
C29 C28 C27 115.0(4) . .
C29 C28 C23 123.6(4) . .
C27 C28 C23 121.4(4) . .
C28 C29 C30 121.7(5) . .
C28 C29 H29A 119.1 . .
C30 C29 H29A 119.1 . .
N2 C30 C29 123.6(5) . .
N2 C30 H30A 118.2 . .
C29 C30 H30A 118.2 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Cu1 O5 1.953(3) .
Cu1 O3 1.963(3) 4_342
Cu1 O1 1.970(2) .
Cu1 O8 2.008(3) .
Cu1 N1 2.194(3) .
Cu1 Cu2 2.6470(5) .
Cu2 O7 1.974(3) .
Cu2 O4 1.982(3) 4_342
Cu2 O2 1.983(2) .
Cu2 O6 1.995(3) .
Cu2 N2 2.203(3) 3_454
O1 C10 1.254(4) .
O2 C10 1.250(4) .
O3 C9 1.280(5) .
O3 Cu1 1.963(3) 4_352
O4 C9 1.238(5) .
O4 Cu2 1.982(3) 4_352
O5 C19 1.265(5) .
O6 C19 1.241(4) .
O7 C20 1.260(4) .
O8 C20 1.248(4) .
N1 C25 1.326(6) .
N1 C21 1.327(5) .
N2 C30 1.277(6) .
N2 C26 1.317(6) .
N2 Cu2 2.203(3) 3_546
C1 C6 1.535(7) .
C1 C5 1.547(6) .
C1 C9 1.550(5) .
C1 C2 1.566(5) .
C2 C7 1.505(7) .
C2 C3 1.557(6) .
C2 C8 1.574(7) .
C3 C10 1.506(5) .
C3 C4 1.515(6) .
C3 H3A 0.9800 .
C4 C5 1.520(7) .
C4 H4A 0.9700 .
C4 H4B 0.9700 .
C5 H5A 0.9700 .
C5 H5B 0.9700 .
C6 H6A 0.9600 .
C6 H6B 0.9600 .
C6 H6C 0.9600 .
C7 H7A 0.9600 .
C7 H7B 0.9600 .
C7 H7C 0.9600 .
C8 H8A 0.9600 .
C8 H8B 0.9600 .
C8 H8C 0.9600 .
C11 C16 1.499(6) .
C11 C19 1.542(5) .
C11 C12 1.547(5) .
C11 C15 1.570(6) .
C12 C17 1.534(6) .
C12 C13 1.537(5) .
C12 C18 1.539(6) .
C13 C20 1.530(5) 4_353
C13 C14 1.568(6) .
C13 H13A 0.9800 .
C14 C15 1.510(6) .
C14 H14A 0.9700 .
C14 H14B 0.9700 .
C15 H15A 0.9700 .
C15 H15B 0.9700 .
C16 H16A 0.9600 .
C16 H16B 0.9600 .
C16 H16C 0.9600 .
C17 H17A 0.9600 .
C17 H17B 0.9600 .
C17 H17C 0.9600 .
C18 H18A 0.9600 .
C18 H18B 0.9600 .
C18 H18C 0.9600 .
C20 C13 1.530(5) 4_343
C21 C22 1.385(5) .
C21 H21A 0.9300 .
C22 C23 1.384(6) .
C22 H22A 0.9300 .
C23 C24 1.386(6) .
C23 C28 1.495(4) .
C24 C25 1.391(6) .
C24 H24A 0.9300 .
C25 H25A 0.9300 .
C26 C27 1.386(7) .
C26 H26A 0.9300 .
C27 C28 1.373(7) .
C27 H27A 0.9300 .
C28 C29 1.354(7) .
C29 C30 1.385(6) .
C29 H29A 0.9300 .
C30 H30A 0.9300 .
