#------------------------------------------------------------------------------
#$Date: 2016-03-21 01:21:50 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178377 $
#$URL: svn://www.crystallography.net/cod/cif/4/00/16/4001675.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4001675
loop_
_publ_author_name
'Liu, Yu'
'Pan, Mei'
'Yang, Qing-Yuan'
'Fu, Lei'
'Li, Kang'
'Wei, Shi-Chao'
'Su, Cheng-Yong'
_publ_section_title
;
 Dual-Emission from a Single-Phase Eu--Ag Metal--Organic Framework: An
 Alternative Way to Get White-Light Phosphor
;
_journal_issue                   10
_journal_name_full               'Chemistry of Materials'
_journal_page_first              1954
_journal_paper_doi               10.1021/cm3008254
_journal_volume                  24
_journal_year                    2012
_chemical_formula_sum            'C94 H89 Ag3 Cl6 Eu N25 O25'
_chemical_formula_weight         2657.17
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 97.592(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   14.2437(3)
_cell_length_b                   25.8296(7)
_cell_length_c                   27.8391(8)
_cell_measurement_reflns_used    14029
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      29.7132
_cell_measurement_theta_min      2.6912
_cell_volume                     10152.5(5)
_computing_cell_refinement
;
CrysAlis RED, Oxford Diffraction Ltd.,
Version 1.171.32.5 (release 08-05-2007 CrysAlis171 .NET)
(compiled May  8 2007,13:10:02)
;
_computing_data_collection
;
CrysAlis CCD, Oxford Diffraction Ltd.,
Version 1.171.32.5 (release 08-05-2007 CrysAlis171 .NET)
(compiled May  8 2007,13:10:02)
;
_computing_data_reduction
;
CrysAlis RED, Oxford Diffraction Ltd.,
Version 1.171.32.5 (release 08-05-2007 CrysAlis171 .NET)
(compiled May  8 2007,13:10:02)
;
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      150(2)
_diffrn_detector_area_resol_mean 16.0855
_diffrn_measured_fraction_theta_full 0.983
_diffrn_measured_fraction_theta_max 0.983
_diffrn_measurement_device_type  'Oxfor Germini S Ultra'
_diffrn_measurement_method       'ω and π scan'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'Enhance (Mo) X-ray Source'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0465
_diffrn_reflns_av_sigmaI/netI    0.0808
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       31
_diffrn_reflns_limit_k_min       -34
_diffrn_reflns_limit_l_max       33
_diffrn_reflns_limit_l_min       -36
_diffrn_reflns_number            85511
_diffrn_reflns_theta_full        28.00
_diffrn_reflns_theta_max         28.00
_diffrn_reflns_theta_min         2.70
_exptl_absorpt_coefficient_mu    1.426
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.79212
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlis RED, Oxford Diffraction Ltd.,
Version 1.171.32.5 (release 08-05-2007 CrysAlis171 .NET)
(compiled May  8 2007,13:10:02)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            Colorless
_exptl_crystal_density_diffrn    1.738
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Block
_exptl_crystal_F_000             5336
_exptl_crystal_size_max          0.40
_exptl_crystal_size_mid          0.40
_exptl_crystal_size_min          0.20
_refine_diff_density_max         2.629
_refine_diff_density_min         -5.190
_refine_diff_density_rms         0.222
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.006
_refine_ls_hydrogen_treatment    reom
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1391
_refine_ls_number_reflns         24073
_refine_ls_number_restraints     102
_refine_ls_restrained_S_all      1.012
_refine_ls_R_factor_all          0.1365
_refine_ls_R_factor_gt           0.0733
_refine_ls_shift/su_max          0.052
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0450P)²+150.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1734
_refine_ls_wR_factor_ref         0.1936
_reflns_number_gt                14177
_reflns_number_total             24073
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            cm3008254_si_001.cif
_cod_data_source_block           2-Eu-Ag
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_sg_symbol_H-M      P2(1)/c
_cod_database_code               4001675
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 1.522242(17) 0.584857(10) 0.780939(9) 0.01862(5) Uani 1 1 d . . .
Ag1 Ag 2.07392(4) 0.52020(2) 0.92649(2) 0.04435(14) Uani 1 1 d . . .
Ag2 Ag 1.91786(4) 0.61498(2) 0.46745(2) 0.05069(15) Uani 1 1 d . . .
Ag3 Ag 0.98428(6) 0.76053(3) 0.68381(3) 0.0821(2) Uani 1 1 d . . .
N1 N 1.7094(3) 0.58689(16) 0.78529(14) 0.0171(9) Uani 1 1 d . . .
N2 N 1.6134(3) 0.51418(17) 0.82851(15) 0.0212(10) Uani 1 1 d . . .
N3 N 1.7171(3) 0.45031(17) 0.82428(16) 0.0241(11) Uani 1 1 d . . .
N4 N 2.0151(4) 0.4504(2) 0.8934(2) 0.0414(14) Uani 1 1 d . . .
N5 N 1.5894(3) 0.57692(17) 0.70225(15) 0.0209(10) Uani 1 1 d . . .
N6 N 1.6808(3) 0.61705(17) 0.65413(15) 0.0224(10) Uani 1 1 d . . .
N7 N 1.9056(3) 0.6022(2) 0.54798(18) 0.0355(13) Uani 1 1 d . . .
N8 N 1.6075(3) 0.66295(17) 0.81972(15) 0.0211(10) Uani 1 1 d . . .
N9 N 1.7108(3) 0.68269(17) 0.88448(15) 0.0223(10) Uani 1 1 d . . .
N10 N 1.9272(4) 0.8071(2) 0.92849(18) 0.0365(13) Uani 1 1 d . . .
N11 N 1.3340(3) 0.58438(17) 0.77409(14) 0.0187(9) Uani 1 1 d . . .
N12 N 1.4375(3) 0.50088(17) 0.75496(15) 0.0215(10) Uani 1 1 d . . .
N13 N 1.3495(3) 0.44189(18) 0.78670(16) 0.0269(11) Uani 1 1 d . . .
N14 N 1.0871(5) 0.3230(3) 0.7802(2) 0.0622(19) Uani 1 1 d . . .
N15 N 1.4340(3) 0.64984(17) 0.72481(15) 0.0221(10) Uani 1 1 d . . .
N16 N 1.3342(3) 0.64916(18) 0.65520(16) 0.0270(11) Uani 1 1 d . . .
N17 N 1.0498(4) 0.7163(3) 0.6313(2) 0.0569(18) Uani 1 1 d . . .
N18 N 1.4489(3) 0.60177(17) 0.85678(15) 0.0198(10) Uani 1 1 d . . .
N19 N 1.3546(3) 0.65773(17) 0.88900(15) 0.0223(10) Uani 1 1 d . . .
N20 N 1.1185(4) 0.5982(2) 0.9449(2) 0.0398(14) Uani 1 1 d . . .
N21 N 2.0576(5) 0.5636(3) 0.4646(3) 0.064(2) Uani 1 1 d U . .
N22 N 0.7411(6) 0.4872(3) 0.6650(3) 0.087(3) Uani 1 1 d U . .
N23 N 0.7163(6) 0.6233(3) 0.4604(3) 0.080(3) Uani 1 1 d . . .
N24 N 0.7601(5) 0.7519(3) 0.7820(3) 0.067(2) Uani 1 1 d . . .
N25 N 0.2966(4) 0.5096(3) 0.9124(2) 0.0514(17) Uani 1 1 d . . .
C1 C 1.7445(3) 0.5337(2) 0.78140(18) 0.0211(12) Uani 1 1 d . . .
H1A H 1.8133 0.5323 0.7929 0.025 Uiso 1 1 calc R . .
H1B H 1.7343 0.5222 0.7472 0.025 Uiso 1 1 calc R . .
C2 C 1.6924(3) 0.4991(2) 0.81154(18) 0.0205(11) Uani 1 1 d . . .
C3 C 1.5857(4) 0.4713(2) 0.85398(18) 0.0234(12) Uani 1 1 d . . .
C4 C 1.5081(4) 0.4653(2) 0.87920(19) 0.0270(13) Uani 1 1 d . . .
H4A H 1.4652 0.4929 0.8822 0.032 Uiso 1 1 calc R . .
C5 C 1.4964(4) 0.4170(2) 0.8997(2) 0.0327(14) Uani 1 1 d . . .
H5A H 1.4437 0.4112 0.9167 0.039 Uiso 1 1 calc R . .
C6 C 1.5616(5) 0.3767(2) 0.8958(2) 0.0395(16) Uani 1 1 d . . .
H6A H 1.5514 0.3441 0.9102 0.047 Uiso 1 1 calc R . .
C7 C 1.6385(4) 0.3829(2) 0.8721(2) 0.0328(15) Uani 1 1 d . . .
H7A H 1.6822 0.3555 0.8698 0.039 Uiso 1 1 calc R . .
C8 C 1.6504(4) 0.4316(2) 0.85124(19) 0.0270(13) Uani 1 1 d . . .
C9 C 1.7934(4) 0.4202(2) 0.8072(2) 0.0329(14) Uani 1 1 d . . .
H9A H 1.8122 0.4374 0.7781 0.039 Uiso 1 1 calc R . .
H9B H 1.7685 0.3855 0.7971 0.039 Uiso 1 1 calc R . .
C10 C 1.8815(4) 0.4133(2) 0.8443(2) 0.0299(13) Uani 1 1 d . . .
C11 C 1.9092(5) 0.3657(3) 0.8609(3) 0.052(2) Uani 1 1 d . . .
H11A H 1.8729 0.3359 0.8505 0.062 Uiso 1 1 calc R . .
C12 C 1.9925(6) 0.3610(3) 0.8936(3) 0.063(2) Uani 1 1 d . . .
H12A H 2.0131 0.3279 0.9056 0.075 Uiso 1 1 calc R . .
C13 C 2.0425(4) 0.4031(3) 0.9077(2) 0.0397(17) Uani 1 1 d . . .
H13A H 2.1002 0.3991 0.9287 0.048 Uiso 1 1 calc R . .
C14 C 1.9341(5) 0.4536(3) 0.8619(3) 0.0445(18) Uani 1 1 d . . .
H14A H 1.9131 0.4872 0.8515 0.053 Uiso 1 1 calc R . .
C15 C 1.7352(3) 0.6181(2) 0.74422(18) 0.0222(12) Uani 1 1 d . . .
H15A H 1.8012 0.6106 0.7389 0.027 Uiso 1 1 calc R . .
H15B H 1.7301 0.6555 0.7513 0.027 Uiso 1 1 calc R . .
C16 C 1.6682(3) 0.6039(2) 0.70020(18) 0.0206(11) Uani 1 1 d . . .
C17 C 1.5477(3) 0.5719(2) 0.65423(19) 0.0233(12) Uani 1 1 d . . .
C18 C 1.4644(4) 0.5475(2) 0.6347(2) 0.0289(13) Uani 1 1 d . . .
H18A H 1.4262 0.5294 0.6546 0.035 Uiso 1 1 calc R . .
C19 C 1.4391(4) 0.5506(2) 0.5847(2) 0.0347(15) Uani 1 1 d . . .
H19A H 1.3826 0.5343 0.5702 0.042 Uiso 1 1 calc R . .
C20 C 1.4961(4) 0.5775(3) 0.5554(2) 0.0413(17) Uani 1 1 d . . .
H20A H 1.4760 0.5796 0.5216 0.050 Uiso 1 1 calc R . .
C21 C 1.5794(4) 0.6007(3) 0.5740(2) 0.0356(15) Uani 1 1 d . . .
H21A H 1.6183 0.6182 0.5541 0.043 Uiso 1 1 calc R . .
C22 C 1.6038(4) 0.5970(2) 0.62404(19) 0.0238(12) Uani 1 1 d . . .
C23 C 1.7538(4) 0.6514(2) 0.6393(2) 0.0287(13) Uani 1 1 d . . .
H23A H 1.7835 0.6710 0.6679 0.034 Uiso 1 1 calc R . .
H23B H 1.7237 0.6766 0.6153 0.034 Uiso 1 1 calc R . .
C24 C 1.8297(4) 0.6219(2) 0.6175(2) 0.0293(14) Uani 1 1 d . . .
C25 C 1.8949(4) 0.5908(3) 0.6454(2) 0.0468(18) Uani 1 1 d . . .
H25A H 1.8927 0.5869 0.6791 0.056 Uiso 1 1 calc R . .
C26 C 1.9625(5) 0.5660(3) 0.6235(3) 0.053(2) Uani 1 1 d . . .
H26A H 2.0061 0.5434 0.6418 0.064 Uiso 1 1 calc R . .
C27 C 1.9673(4) 0.5736(3) 0.5757(2) 0.0414(17) Uani 1 1 d . . .
H27A H 2.0172 0.5576 0.5616 0.050 Uiso 1 1 calc R . .
C28 C 1.8386(4) 0.6264(2) 0.5693(2) 0.0320(14) Uani 1 1 d . . .
H28A H 1.7947 0.6479 0.5498 0.038 Uiso 1 1 calc R . .
C29 C 1.7520(3) 0.6098(2) 0.83190(18) 0.0217(12) Uani 1 1 d . . .
H29A H 1.7581 0.5830 0.8576 0.026 Uiso 1 1 calc R . .
H29B H 1.8159 0.6233 0.8288 0.026 Uiso 1 1 calc R . .
C30 C 1.6904(3) 0.6522(2) 0.84485(18) 0.0203(11) Uani 1 1 d . . .
C31 C 1.5713(4) 0.7042(2) 0.8443(2) 0.0252(12) Uani 1 1 d . . .
C32 C 1.4876(4) 0.7321(2) 0.8332(2) 0.0296(14) Uani 1 1 d . . .
H32A H 1.4458 0.7259 0.8042 0.036 Uiso 1 1 calc R . .
C33 C 1.4679(4) 0.7694(2) 0.8662(2) 0.0308(14) Uani 1 1 d . . .
H33A H 1.4116 0.7894 0.8598 0.037 Uiso 1 1 calc R . .
C34 C 1.5292(4) 0.7780(2) 0.9087(2) 0.0354(15) Uani 1 1 d . . .
H34A H 1.5122 0.8029 0.9312 0.042 Uiso 1 1 calc R . .
C35 C 1.6139(4) 0.7517(2) 0.9193(2) 0.0301(14) Uani 1 1 d . . .
H35A H 1.6558 0.7581 0.9482 0.036 Uiso 1 1 calc R . .
C36 C 1.6341(4) 0.7159(2) 0.88580(19) 0.0236(12) Uani 1 1 d . . .
C37 C 1.7953(4) 0.6803(2) 0.9210(2) 0.0274(13) Uani 1 1 d . . .
H37A H 1.8244 0.6456 0.9202 0.033 Uiso 1 1 calc R . .
H37B H 1.7760 0.6852 0.9536 0.033 Uiso 1 1 calc R . .
C38 C 1.8678(4) 0.7209(2) 0.9128(2) 0.0305(14) Uani 1 1 d . . .
C39 C 1.9374(4) 0.7115(3) 0.8832(3) 0.0464(19) Uani 1 1 d . . .
H39A H 1.9413 0.6789 0.8677 0.056 Uiso 1 1 calc R . .
C40 C 2.0007(4) 0.7508(3) 0.8769(3) 0.053(2) Uani 1 1 d . . .
H40A H 2.0488 0.7455 0.8568 0.064 Uiso 1 1 calc R . .
C41 C 1.9937(5) 0.7972(3) 0.8996(2) 0.0453(18) Uani 1 1 d . . .
H41A H 2.0378 0.8237 0.8948 0.054 Uiso 1 1 calc R . .
C42 C 1.8673(4) 0.7687(2) 0.9352(2) 0.0334(15) Uani 1 1 d . . .
H42A H 1.8217 0.7745 0.9567 0.040 Uiso 1 1 calc R . .
C43 C 1.3018(3) 0.5344(2) 0.79158(19) 0.0240(12) Uani 1 1 d . . .
H43A H 1.2354 0.5280 0.7774 0.029 Uiso 1 1 calc R . .
H43B H 1.3044 0.5354 0.8273 0.029 Uiso 1 1 calc R . .
C44 C 1.3635(3) 0.4921(2) 0.77756(18) 0.0232(12) Uani 1 1 d . . .
C45 C 1.4750(4) 0.4520(2) 0.74755(19) 0.0252(13) Uani 1 1 d . . .
C46 C 1.5538(4) 0.4372(2) 0.7252(2) 0.0283(13) Uani 1 1 d . . .
H46A H 1.5900 0.4619 0.7103 0.034 Uiso 1 1 calc R . .
C47 C 1.5760(5) 0.3855(2) 0.7259(2) 0.0385(16) Uani 1 1 d . . .
H47A H 1.6281 0.3742 0.7105 0.046 Uiso 1 1 calc R . .
C48 C 1.5246(5) 0.3490(2) 0.7483(2) 0.0419(17) Uani 1 1 d . . .
H48A H 1.5444 0.3139 0.7491 0.050 Uiso 1 1 calc R . .
C49 C 1.4457(5) 0.3622(2) 0.7696(2) 0.0375(16) Uani 1 1 d . . .
H49A H 1.4099 0.3371 0.7842 0.045 Uiso 1 1 calc R . .
C50 C 1.4216(4) 0.4147(2) 0.7683(2) 0.0288(13) Uani 1 1 d . . .
C51 C 1.2813(4) 0.4200(2) 0.8166(2) 0.0340(14) Uani 1 1 d . . .
H51A H 1.2568 0.4481 0.8357 0.041 Uiso 1 1 calc R . .
H51B H 1.3144 0.3948 0.8397 0.041 Uiso 1 1 calc R . .
C52 C 1.1978(4) 0.3930(2) 0.7863(2) 0.0337(15) Uani 1 1 d . . .
C53 C 1.1543(5) 0.4123(3) 0.7440(3) 0.071(3) Uani 1 1 d . . .
H53A H 1.1759 0.4434 0.7310 0.086 Uiso 1 1 calc R . .
C54 C 1.0760(6) 0.3853(4) 0.7196(4) 0.089(3) Uani 1 1 d . . .
H54A H 1.0460 0.3968 0.6890 0.106 Uiso 1 1 calc R . .
C55 C 1.0451(5) 0.3428(3) 0.7406(3) 0.062(2) Uani 1 1 d . . .
H55A H 0.9891 0.3266 0.7255 0.074 Uiso 1 1 calc R . .
C56 C 1.1657(6) 0.3474(3) 0.8023(3) 0.059(2) Uani 1 1 d . . .
H56A H 1.1998 0.3319 0.8303 0.071 Uiso 1 1 calc R . .
C57 C 1.2951(3) 0.5918(2) 0.72241(18) 0.0243(12) Uani 1 1 d . . .
H57A H 1.2960 0.5586 0.7047 0.029 Uiso 1 1 calc R . .
H57B H 1.2288 0.6041 0.7198 0.029 Uiso 1 1 calc R . .
C58 C 1.3542(4) 0.6306(2) 0.70110(19) 0.0256(13) Uani 1 1 d . . .
C59 C 1.4679(4) 0.6835(2) 0.6913(2) 0.0276(13) Uani 1 1 d . . .
C60 C 1.5507(4) 0.7136(2) 0.6957(2) 0.0317(14) Uani 1 1 d . . .
H60A H 1.5914 0.7160 0.7255 0.038 Uiso 1 1 calc R . .
C61 C 1.5702(5) 0.7395(2) 0.6550(2) 0.0393(16) Uani 1 1 d . . .
H61A H 1.6258 0.7601 0.6566 0.047 Uiso 1 1 calc R . .
C62 C 1.5090(5) 0.7360(2) 0.6110(2) 0.0454(17) Uani 1 1 d . . .
H62A H 1.5260 0.7535 0.5833 0.054 Uiso 1 1 calc R . .
C63 C 1.4251(4) 0.7081(2) 0.6063(2) 0.0379(15) Uani 1 1 d . . .
H63A H 1.3832 0.7068 0.5768 0.045 Uiso 1 1 calc R . .
C64 C 1.4067(4) 0.6824(2) 0.6475(2) 0.0289(13) Uani 1 1 d . . .
C65 C 1.2602(4) 0.6298(3) 0.6185(2) 0.0343(15) Uani 1 1 d . . .
H65A H 1.2376 0.5961 0.6296 0.041 Uiso 1 1 calc R . .
H65B H 1.2883 0.6233 0.5884 0.041 Uiso 1 1 calc R . .
C66 C 1.1758(4) 0.6650(2) 0.6065(2) 0.0311(14) Uani 1 1 d . . .
C67 C 1.1401(5) 0.6731(3) 0.5588(2) 0.0461(19) Uani 1 1 d . . .
H67A H 1.1705 0.6582 0.5337 0.055 Uiso 1 1 calc R . .
C68 C 1.0603(5) 0.7029(3) 0.5474(3) 0.055(2) Uani 1 1 d . . .
H68A H 1.0361 0.7098 0.5146 0.066 Uiso 1 1 calc R . .
C69 C 1.0171(5) 0.7223(3) 0.5840(3) 0.052(2) Uani 1 1 d . . .
H69A H 0.9600 0.7412 0.5758 0.062 Uiso 1 1 calc R . .
C70 C 1.1294(5) 0.6869(3) 0.6410(3) 0.057(2) Uani 1 1 d . . .
H70A H 1.1542 0.6814 0.6740 0.068 Uiso 1 1 calc R . .
C71 C 1.3047(3) 0.6271(2) 0.80395(19) 0.0249(13) Uani 1 1 d . . .
H71A H 1.2388 0.6215 0.8106 0.030 Uiso 1 1 calc R . .
H71B H 1.3072 0.6604 0.7865 0.030 Uiso 1 1 calc R . .
C72 C 1.3697(3) 0.6287(2) 0.85012(18) 0.0215(12) Uani 1 1 d . . .
C73 C 1.4900(3) 0.6143(2) 0.90445(18) 0.0214(12) Uani 1 1 d . . .
C74 C 1.5746(3) 0.5972(2) 0.93079(19) 0.0236(12) Uani 1 1 d . . .
H74A H 1.6137 0.5725 0.9179 0.028 Uiso 1 1 calc R . .
C75 C 1.5987(4) 0.6181(2) 0.97670(19) 0.0276(13) Uani 1 1 d . . .
H75A H 1.6555 0.6073 0.9958 0.033 Uiso 1 1 calc R . .
C76 C 1.5404(4) 0.6549(2) 0.99539(19) 0.0297(14) Uani 1 1 d . . .
H76A H 1.5602 0.6693 1.0265 0.036 Uiso 1 1 calc R . .
C77 C 1.4554(4) 0.6707(2) 0.97002(19) 0.0262(13) Uani 1 1 d . . .
H77A H 1.4154 0.6949 0.9831 0.031 Uiso 1 1 calc R . .
C78 C 1.4320(4) 0.6494(2) 0.92451(18) 0.0222(12) Uani 1 1 d . . .
C79 C 1.2764(4) 0.6932(2) 0.8941(2) 0.0300(14) Uani 1 1 d . . .
H79A H 1.2406 0.7003 0.8618 0.036 Uiso 1 1 calc R . .
H79B H 1.3019 0.7264 0.9079 0.036 Uiso 1 1 calc R . .
C80 C 1.2106(4) 0.6701(2) 0.9267(2) 0.0315(14) Uani 1 1 d . . .
C81 C 1.1867(5) 0.6961(3) 0.9663(3) 0.0538(19) Uani 1 1 d . . .
H81A H 1.2111 0.7298 0.9740 0.065 Uiso 1 1 calc R . .
C82 C 1.1269(6) 0.6728(3) 0.9949(3) 0.066(2) Uani 1 1 d . . .
H82A H 1.1081 0.6905 1.0220 0.079 Uiso 1 1 calc R . .
C83 C 1.0950(5) 0.6239(3) 0.9836(3) 0.055(2) Uani 1 1 d . . .
H83A H 1.0549 0.6075 1.0037 0.067 Uiso 1 1 calc R . .
C84 C 1.1742(4) 0.6222(3) 0.9174(2) 0.0359(15) Uani 1 1 d . . .
H84A H 1.1894 0.6047 0.8894 0.043 Uiso 1 1 calc R . .
C85 C 2.1260(5) 0.5414(3) 0.4678(3) 0.052(2) Uani 1 1 d . . .
C86 C 2.2156(6) 0.5133(3) 0.4702(3) 0.062(2) Uani 1 1 d . . .
H86A H 2.2186 0.4869 0.4957 0.093 Uiso 1 1 calc R . .
H86B H 2.2685 0.5375 0.4776 0.093 Uiso 1 1 calc R . .
H86C H 2.2198 0.4965 0.4390 0.093 Uiso 1 1 calc R . .
C87 C 0.7829(7) 0.4515(4) 0.6611(3) 0.068(3) Uani 1 1 d . . .
C88 C 0.8299(8) 0.4014(4) 0.6557(4) 0.113(4) Uani 1 1 d U . .
H88A H 0.8940 0.4074 0.6477 0.169 Uiso 1 1 calc R . .
H88B H 0.7935 0.3815 0.6297 0.169 Uiso 1 1 calc R . .
H88C H 0.8336 0.3820 0.6862 0.169 Uiso 1 1 calc R . .
C89 C 0.6477(6) 0.6078(3) 0.4394(3) 0.054(2) Uani 1 1 d . . .
C90 C 0.5641(6) 0.5883(3) 0.4115(4) 0.079(3) Uani 1 1 d . . .
H90A H 0.5477 0.6100 0.3827 0.119 Uiso 1 1 calc R . .
H90B H 0.5118 0.5887 0.4311 0.119 Uiso 1 1 calc R . .
H90C H 0.5751 0.5527 0.4014 0.119 Uiso 1 1 calc R . .
C91 C 0.7417(5) 0.7855(3) 0.8040(2) 0.0426(17) Uani 1 1 d . . .
C92 C 0.7167(6) 0.8291(3) 0.8324(3) 0.057(2) Uani 1 1 d . . .
H92A H 0.7739 0.8489 0.8441 0.085 Uiso 1 1 calc R . .
H92B H 0.6875 0.8165 0.8602 0.085 Uiso 1 1 calc R . .
H92C H 0.6718 0.8514 0.8123 0.085 Uiso 1 1 calc R . .
C93 C 0.3268(4) 0.5217(3) 0.9502(2) 0.0372(16) Uani 1 1 d . . .
C94 C 0.3636(6) 0.5379(3) 0.9976(2) 0.063(2) Uani 1 1 d . . .
H94A H 0.3169 0.5597 1.0108 0.095 Uiso 1 1 calc R . .
H94B H 0.4219 0.5578 0.9963 0.095 Uiso 1 1 calc R . .
H94C H 0.3776 0.5075 1.0184 0.095 Uiso 1 1 calc R . .
Cl1 Cl 0.30554(11) 0.66132(6) 0.46155(6) 0.0384(4) Uani 1 1 d . . .
Cl2 Cl 0.20874(12) 0.73299(7) 0.26099(7) 0.0488(5) Uani 1 1 d . . .
Cl3 Cl 0.23698(10) 0.28528(6) 0.92991(5) 0.0303(3) Uani 1 1 d . . .
Cl5 Cl 0.19767(12) 0.47459(6) 0.62836(7) 0.0471(4) Uani 1 1 d . . .
Cl6 Cl 0.16029(10) 0.46933(6) 0.04433(6) 0.0399(4) Uani 1 1 d . . .
O1 O 0.2125(4) 0.6760(2) 0.4416(2) 0.0658(17) Uani 1 1 d . . .
O2 O 0.3023(4) 0.6255(2) 0.4996(2) 0.0655(17) Uani 1 1 d . . .
O3 O 0.3549(4) 0.7065(2) 0.4804(2) 0.0619(16) Uani 1 1 d . . .
O4 O 0.3535(4) 0.6379(2) 0.4257(2) 0.0721(17) Uani 1 1 d . . .
O5 O 0.1410(5) 0.7701(3) 0.2691(4) 0.118(3) Uani 1 1 d . . .
O6 O 0.2880(6) 0.7563(4) 0.2456(4) 0.151(4) Uani 1 1 d U . .
O7 O 0.2537(8) 0.7178(5) 0.3039(4) 0.173(4) Uani 1 1 d U . .
O8 O 0.1663(6) 0.6937(3) 0.2367(4) 0.134(3) Uani 1 1 d U . .
O9 O 0.2906(4) 0.3275(2) 0.91484(18) 0.0581(15) Uani 1 1 d . . .
O10 O 0.2990(3) 0.24747(19) 0.95494(17) 0.0486(13) Uani 1 1 d . . .
O11 O 0.1730(4) 0.3038(2) 0.96087(17) 0.0546(14) Uani 1 1 d . . .
O12 O 0.1845(3) 0.26214(16) 0.88756(14) 0.0351(11) Uani 1 1 d . . .
O17 O 0.1597(4) 0.5074(2) 0.6606(3) 0.080(2) Uani 1 1 d . . .
O18 O 0.2886(4) 0.4589(2) 0.6523(3) 0.082(2) Uani 1 1 d . . .
O19 O 0.1403(4) 0.4305(2) 0.6193(2) 0.0673(17) Uani 1 1 d . . .
O20 O 0.2064(5) 0.5018(3) 0.5856(2) 0.095(2) Uani 1 1 d U . .
O21 O 0.2400(4) 0.4817(2) 0.07839(18) 0.0601(16) Uani 1 1 d . . .
O22 O 0.1019(4) 0.4359(2) 0.0678(3) 0.078(2) Uani 1 1 d . . .
O23 O 0.1103(4) 0.5146(2) 0.0277(2) 0.0754(18) Uani 1 1 d . . .
O24 O 0.1939(4) 0.4438(3) 0.0048(2) 0.080(2) Uani 1 1 d . . .
O25 O 0.9238(5) 0.7016(3) 0.7283(4) 0.125(3) Uani 1 1 d U . .
Cl4 Cl 0.02618(16) 0.57625(16) 0.78185(11) 0.0799(11) Uani 0.80 1 d PU A 1
O13 O 0.0934(4) 0.5511(3) 0.8192(2) 0.091(2) Uani 1 1 d U A 1
O14 O -0.0323(6) 0.6058(5) 0.8037(4) 0.171(4) Uani 1 1 d U A 1
O15 O -0.0369(5) 0.5393(4) 0.7598(3) 0.112(3) Uani 1 1 d U A 1
O16 O 0.0754(4) 0.5963(3) 0.7465(3) 0.095(2) Uani 1 1 d U A 1
Cl4' Cl 0.0345(7) 0.5795(4) 0.7920(4) 0.043(2) Uiso 0.20 1 d P B 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N5 Eu1 N15 74.28(14) . .
N5 Eu1 N2 99.81(14) . .
N15 Eu1 N2 173.44(14) . .
N5 Eu1 N18 174.15(14) . .
N15 Eu1 N18 100.20(14) . .
N2 Eu1 N18 85.80(14) . .
N5 Eu1 N8 102.77(14) . .
N15 Eu1 N8 84.55(14) . .
N2 Eu1 N8 99.74(13) . .
N18 Eu1 N8 74.43(14) . .
N5 Eu1 N12 84.47(14) . .
N15 Eu1 N12 102.32(14) . .
N2 Eu1 N12 73.91(13) . .
N18 Eu1 N12 98.79(14) . .
N8 Eu1 N12 171.25(14) . .
N5 Eu1 N1 62.95(12) . .
N15 Eu1 N1 115.58(13) . .
N2 Eu1 N1 62.89(13) . .
N18 Eu1 N1 118.98(12) . .
N8 Eu1 N1 62.64(13) . .
N12 Eu1 N1 117.83(13) . .
N5 Eu1 N11 115.67(12) . .
N15 Eu1 N11 62.79(13) . .
N2 Eu1 N11 118.65(13) . .
N18 Eu1 N11 62.29(12) . .
N8 Eu1 N11 117.25(13) . .
N12 Eu1 N11 62.57(13) . .
N1 Eu1 N11 178.29(12) . .
N5 Eu1 C58 76.42(13) . .
N15 Eu1 C58 22.16(14) . .
N2 Eu1 C58 154.53(14) . .
N18 Eu1 C58 99.23(13) . .
N8 Eu1 C58 105.67(14) . .
N12 Eu1 C58 80.63(14) . .
N1 Eu1 C58 131.73(13) . .
N11 Eu1 C58 46.56(13) . .
N4 Ag1 N20 167.1(2) . 1_655
N7 Ag2 N10 127.12(19) . 4_575
N7 Ag2 N21 97.1(2) . .
N10 Ag2 N21 111.6(2) 4_575 .
N17 Ag3 O25 104.5(3) . .
N17 Ag3 N14 162.8(2) . 2_756
O25 Ag3 N14 90.7(3) . 2_756
C1 N1 C29 109.5(4) . .
C1 N1 C15 109.2(4) . .
C29 N1 C15 110.1(4) . .
C1 N1 Eu1 109.1(3) . .
C29 N1 Eu1 109.9(3) . .
C15 N1 Eu1 109.0(3) . .
C2 N2 C3 104.8(4) . .
C2 N2 Eu1 115.2(3) . .
C3 N2 Eu1 133.0(3) . .
C2 N3 C8 107.3(4) . .
C2 N3 C9 126.3(5) . .
C8 N3 C9 125.9(5) . .
C13 N4 C14 116.1(6) . .
C13 N4 Ag1 124.3(4) . .
C14 N4 Ag1 118.5(4) . .
C16 N5 C17 105.2(4) . .
C16 N5 Eu1 114.6(3) . .
C17 N5 Eu1 132.8(3) . .
C16 N6 C22 106.5(4) . .
C16 N6 C23 127.0(4) . .
C22 N6 C23 126.1(4) . .
C27 N7 C28 117.5(5) . .
C27 N7 Ag2 121.4(4) . .
C28 N7 Ag2 121.0(4) . .
C30 N8 C31 105.3(4) . .
C30 N8 Eu1 113.9(3) . .
C31 N8 Eu1 129.0(3) . .
C30 N9 C36 107.2(4) . .
C30 N9 C37 127.3(4) . .
C36 N9 C37 125.5(4) . .
C42 N10 C41 117.0(6) . .
C42 N10 Ag2 120.4(4) . 4_576
C41 N10 Ag2 122.6(4) . 4_576
C43 N11 C71 110.2(4) . .
C43 N11 C57 110.0(4) . .
C71 N11 C57 110.6(4) . .
C43 N11 Eu1 109.6(3) . .
C71 N11 Eu1 108.3(3) . .
C57 N11 Eu1 108.2(3) . .
C44 N12 C45 105.1(4) . .
C44 N12 Eu1 113.0(3) . .
C45 N12 Eu1 129.6(3) . .
C44 N13 C50 106.3(5) . .
C44 N13 C51 127.2(5) . .
C50 N13 C51 125.9(5) . .
C55 N14 C56 117.7(7) . .
C55 N14 Ag3 119.2(5) . 2_746
C56 N14 Ag3 122.1(5) . 2_746
C58 N15 C59 104.3(4) . .
C58 N15 Eu1 112.5(3) . .
C59 N15 Eu1 129.6(3) . .
C58 N16 C64 107.2(4) . .
C58 N16 C65 125.6(5) . .
C64 N16 C65 126.3(5) . .
C69 N17 C70 115.3(6) . .
C69 N17 Ag3 118.5(5) . .
C70 N17 Ag3 125.8(5) . .
C72 N18 C73 104.6(4) . .
C72 N18 Eu1 114.6(3) . .
C73 N18 Eu1 131.4(3) . .
C72 N19 C78 106.6(4) . .
C72 N19 C79 128.7(4) . .
C78 N19 C79 124.6(4) . .
C84 N20 C83 117.7(6) . .
C84 N20 Ag1 118.7(4) . 1_455
C83 N20 Ag1 123.7(5) . 1_455
C85 N21 Ag2 173.2(7) . .
N1 C1 C2 108.5(4) . .
N1 C1 H1A 110.0 . .
C2 C1 H1A 110.0 . .
N1 C1 H1B 110.0 . .
C2 C1 H1B 110.0 . .
H1A C1 H1B 108.4 . .
N2 C2 N3 112.6(5) . .
N2 C2 C1 122.2(4) . .
N3 C2 C1 125.3(5) . .
C8 C3 C4 121.5(5) . .
C8 C3 N2 108.9(5) . .
C4 C3 N2 129.6(5) . .
C5 C4 C3 116.9(5) . .
C5 C4 H4A 121.6 . .
C3 C4 H4A 121.6 . .
C4 C5 C6 121.0(6) . .
C4 C5 H5A 119.5 . .
C6 C5 H5A 119.5 . .
C7 C6 C5 122.1(6) . .
C7 C6 H6A 119.0 . .
C5 C6 H6A 119.0 . .
C6 C7 C8 117.0(6) . .
C6 C7 H7A 121.5 . .
C8 C7 H7A 121.5 . .
N3 C8 C3 106.3(5) . .
N3 C8 C7 132.2(5) . .
C3 C8 C7 121.4(5) . .
N3 C9 C10 114.8(5) . .
N3 C9 H9A 108.6 . .
C10 C9 H9A 108.6 . .
N3 C9 H9B 108.6 . .
C10 C9 H9B 108.6 . .
H9A C9 H9B 107.5 . .
C14 C10 C11 117.3(6) . .
C14 C10 C9 121.9(6) . .
C11 C10 C9 120.8(6) . .
C10 C11 C12 118.8(6) . .
C10 C11 H11A 120.6 . .
C12 C11 H11A 120.6 . .
C13 C12 C11 119.7(7) . .
C13 C12 H12A 120.1 . .
C11 C12 H12A 120.1 . .
N4 C13 C12 122.6(6) . .
N4 C13 H13A 118.7 . .
C12 C13 H13A 118.7 . .
C10 C14 N4 125.3(6) . .
C10 C14 H14A 117.4 . .
N4 C14 H14A 117.4 . .
N1 C15 C16 107.5(4) . .
N1 C15 H15A 110.2 . .
C16 C15 H15A 110.2 . .
N1 C15 H15B 110.2 . .
C16 C15 H15B 110.2 . .
H15A C15 H15B 108.5 . .
N5 C16 N6 112.9(4) . .
N5 C16 C15 123.0(5) . .
N6 C16 C15 124.2(4) . .
C18 C17 C22 120.2(5) . .
C18 C17 N5 130.6(5) . .
C22 C17 N5 109.2(4) . .
C17 C18 C19 117.4(5) . .
C17 C18 H18A 121.3 . .
C19 C18 H18A 121.3 . .
C18 C19 C20 121.0(5) . .
C18 C19 H19A 119.5 . .
C20 C19 H19A 119.5 . .
C21 C20 C19 122.3(5) . .
C21 C20 H20A 118.9 . .
C19 C20 H20A 118.9 . .
C20 C21 C22 116.0(6) . .
C20 C21 H21A 122.0 . .
C22 C21 H21A 122.0 . .
N6 C22 C21 130.5(5) . .
N6 C22 C17 106.2(4) . .
C21 C22 C17 123.2(5) . .
N6 C23 C24 112.3(5) . .
N6 C23 H23A 109.1 . .
C24 C23 H23A 109.1 . .
N6 C23 H23B 109.1 . .
C24 C23 H23B 109.1 . .
H23A C23 H23B 107.9 . .
C28 C24 C25 117.1(5) . .
C28 C24 C23 121.0(5) . .
C25 C24 C23 121.9(5) . .
C26 C25 C24 118.9(6) . .
C26 C25 H25A 120.6 . .
C24 C25 H25A 120.6 . .
C27 C26 C25 120.0(6) . .
C27 C26 H26A 120.0 . .
C25 C26 H26A 120.0 . .
N7 C27 C26 122.6(6) . .
N7 C27 H27A 118.7 . .
C26 C27 H27A 118.7 . .
N7 C28 C24 123.8(5) . .
N7 C28 H28A 118.1 . .
C24 C28 H28A 118.1 . .
C30 C29 N1 108.8(4) . .
C30 C29 H29A 109.9 . .
N1 C29 H29A 109.9 . .
C30 C29 H29B 109.9 . .
N1 C29 H29B 109.9 . .
H29A C29 H29B 108.3 . .
N8 C30 N9 112.9(4) . .
N8 C30 C29 123.0(4) . .
N9 C30 C29 124.0(4) . .
C32 C31 C36 120.3(5) . .
C32 C31 N8 130.2(5) . .
C36 C31 N8 109.4(4) . .
C33 C32 C31 117.1(5) . .
C33 C32 H32A 121.4 . .
C31 C32 H32A 121.4 . .
C32 C33 C34 121.1(5) . .
C32 C33 H33A 119.5 . .
C34 C33 H33A 119.5 . .
C35 C34 C33 122.3(6) . .
C35 C34 H34A 118.9 . .
C33 C34 H34A 118.9 . .
C36 C35 C34 116.3(5) . .
C36 C35 H35A 121.9 . .
C34 C35 H35A 121.9 . .
C35 C36 N9 132.0(5) . .
C35 C36 C31 122.7(5) . .
N9 C36 C31 105.2(4) . .
N9 C37 C38 112.3(4) . .
N9 C37 H37A 109.2 . .
C38 C37 H37A 109.2 . .
N9 C37 H37B 109.2 . .
C38 C37 H37B 109.2 . .
H37A C37 H37B 107.9 . .
C42 C38 C39 118.1(6) . .
C42 C38 C37 120.4(5) . .
C39 C38 C37 121.5(6) . .
C40 C39 C38 118.3(7) . .
C40 C39 H39A 120.9 . .
C38 C39 H39A 120.9 . .
C41 C40 C39 119.7(7) . .
C41 C40 H40A 120.1 . .
C39 C40 H40A 120.1 . .
N10 C41 C40 123.1(6) . .
N10 C41 H41A 118.5 . .
C40 C41 H41A 118.5 . .
N10 C42 C38 123.8(6) . .
N10 C42 H42A 118.1 . .
C38 C42 H42A 118.1 . .
N11 C43 C44 109.7(4) . .
N11 C43 H43A 109.7 . .
C44 C43 H43A 109.7 . .
N11 C43 H43B 109.7 . .
C44 C43 H43B 109.7 . .
H43A C43 H43B 108.2 . .
N12 C44 N13 114.0(5) . .
N12 C44 C43 122.5(5) . .
N13 C44 C43 123.6(5) . .
C50 C45 N12 108.8(5) . .
C50 C45 C46 120.4(5) . .
N12 C45 C46 130.8(5) . .
C47 C46 C45 117.0(6) . .
C47 C46 H46A 121.5 . .
C45 C46 H46A 121.5 . .
C46 C47 C48 122.1(6) . .
C46 C47 H47A 118.9 . .
C48 C47 H47A 118.9 . .
C49 C48 C47 122.1(6) . .
C49 C48 H48A 118.9 . .
C47 C48 H48A 118.9 . .
C48 C49 C50 116.1(6) . .
C48 C49 H49A 121.9 . .
C50 C49 H49A 121.9 . .
N13 C50 C45 105.8(5) . .
N13 C50 C49 132.0(6) . .
C45 C50 C49 122.2(6) . .
N13 C51 C52 112.6(5) . .
N13 C51 H51A 109.1 . .
C52 C51 H51A 109.1 . .
N13 C51 H51B 109.1 . .
C52 C51 H51B 109.1 . .
H51A C51 H51B 107.8 . .
C53 C52 C56 118.0(6) . .
C53 C52 C51 123.1(6) . .
C56 C52 C51 118.9(5) . .
C52 C53 C54 118.8(8) . .
C52 C53 H53A 120.6 . .
C54 C53 H53A 120.6 . .
C55 C54 C53 118.4(8) . .
C55 C54 H54A 120.8 . .
C53 C54 H54A 120.8 . .
N14 C55 C54 123.8(7) . .
N14 C55 H55A 118.1 . .
C54 C55 H55A 118.1 . .
C52 C56 N14 123.0(6) . .
C52 C56 H56A 118.5 . .
N14 C56 H56A 118.5 . .
C58 C57 N11 108.5(4) . .
C58 C57 H57A 110.0 . .
N11 C57 H57A 110.0 . .
C58 C57 H57B 110.0 . .
N11 C57 H57B 110.0 . .
H57A C57 H57B 108.4 . .
N15 C58 N16 113.2(5) . .
N15 C58 C57 123.1(5) . .
N16 C58 C57 123.7(5) . .
N15 C58 Eu1 45.3(3) . .
N16 C58 Eu1 144.3(4) . .
C57 C58 Eu1 83.5(3) . .
C64 C59 C60 120.3(5) . .
C64 C59 N15 109.6(5) . .
C60 C59 N15 130.0(5) . .
C61 C60 C59 117.2(6) . .
C61 C60 H60A 121.4 . .
C59 C60 H60A 121.4 . .
C60 C61 C62 121.1(6) . .
C60 C61 H61A 119.4 . .
C62 C61 H61A 119.4 . .
C63 C62 C61 122.7(6) . .
C63 C62 H62A 118.6 . .
C61 C62 H62A 118.6 . .
C64 C63 C62 115.3(6) . .
C64 C63 H63A 122.3 . .
C62 C63 H63A 122.3 . .
C63 C64 N16 130.9(5) . .
C63 C64 C59 123.3(5) . .
N16 C64 C59 105.6(5) . .
N16 C65 C66 115.4(5) . .
N16 C65 H65A 108.4 . .
C66 C65 H65A 108.4 . .
N16 C65 H65B 108.4 . .
C66 C65 H65B 108.4 . .
H65A C65 H65B 107.5 . .
C70 C66 C67 117.8(6) . .
C70 C66 C65 123.0(5) . .
C67 C66 C65 119.1(6) . .
C68 C67 C66 119.8(7) . .
C68 C67 H67A 120.1 . .
C66 C67 H67A 120.1 . .
C69 C68 C67 118.5(7) . .
C69 C68 H68A 120.7 . .
C67 C68 H68A 120.7 . .
N17 C69 C68 124.2(6) . .
N17 C69 H69A 117.9 . .
C68 C69 H69A 117.9 . .
C66 C70 N17 124.3(6) . .
C66 C70 H70A 117.8 . .
N17 C70 H70A 117.8 . .
N11 C71 C72 108.6(4) . .
N11 C71 H71A 110.0 . .
C72 C71 H71A 110.0 . .
N11 C71 H71B 110.0 . .
C72 C71 H71B 110.0 . .
H71A C71 H71B 108.4 . .
N18 C72 N19 113.7(4) . .
N18 C72 C71 122.2(5) . .
N19 C72 C71 124.1(4) . .
C78 C73 C74 120.8(5) . .
C78 C73 N18 109.3(4) . .
C74 C73 N18 129.9(5) . .
C75 C74 C73 116.9(5) . .
C75 C74 H74A 121.6 . .
C73 C74 H74A 121.6 . .
C74 C75 C76 121.1(5) . .
C74 C75 H75A 119.4 . .
C76 C75 H75A 119.4 . .
C77 C76 C75 122.1(5) . .
C77 C76 H76A 118.9 . .
C75 C76 H76A 118.9 . .
C76 C77 C78 116.1(5) . .
C76 C77 H77A 122.0 . .
C78 C77 H77A 122.0 . .
C77 C78 C73 123.0(5) . .
C77 C78 N19 131.2(5) . .
C73 C78 N19 105.7(4) . .
N19 C79 C80 110.7(5) . .
N19 C79 H79A 109.5 . .
C80 C79 H79A 109.5 . .
N19 C79 H79B 109.5 . .
C80 C79 H79B 109.5 . .
H79A C79 H79B 108.1 . .
C84 C80 C81 118.3(6) . .
C84 C80 C79 119.8(5) . .
C81 C80 C79 122.0(6) . .
C80 C81 C82 119.1(7) . .
C80 C81 H81A 120.4 . .
C82 C81 H81A 120.4 . .
C83 C82 C81 119.0(7) . .
C83 C82 H82A 120.5 . .
C81 C82 H82A 120.5 . .
N20 C83 C82 121.9(7) . .
N20 C83 H83A 119.0 . .
C82 C83 H83A 119.0 . .
N20 C84 C80 123.9(6) . .
N20 C84 H84A 118.0 . .
C80 C84 H84A 118.0 . .
N21 C85 C86 178.0(10) . .
C85 C86 H86A 109.5 . .
C85 C86 H86B 109.5 . .
H86A C86 H86B 109.5 . .
C85 C86 H86C 109.5 . .
H86A C86 H86C 109.5 . .
H86B C86 H86C 109.5 . .
N22 C87 C88 174.6(11) . .
C87 C88 H88A 109.5 . .
C87 C88 H88B 109.5 . .
H88A C88 H88B 109.5 . .
C87 C88 H88C 109.5 . .
H88A C88 H88C 109.5 . .
H88B C88 H88C 109.5 . .
N23 C89 C90 177.7(10) . .
C89 C90 H90A 109.5 . .
C89 C90 H90B 109.5 . .
H90A C90 H90B 109.5 . .
C89 C90 H90C 109.5 . .
H90A C90 H90C 109.5 . .
H90B C90 H90C 109.5 . .
N24 C91 C92 179.4(9) . .
C91 C92 H92A 109.5 . .
C91 C92 H92B 109.5 . .
H92A C92 H92B 109.5 . .
C91 C92 H92C 109.5 . .
H92A C92 H92C 109.5 . .
H92B C92 H92C 109.5 . .
N25 C93 C94 178.6(8) . .
C93 C94 H94A 109.5 . .
C93 C94 H94B 109.5 . .
H94A C94 H94B 109.5 . .
C93 C94 H94C 109.5 . .
H94A C94 H94C 109.5 . .
H94B C94 H94C 109.5 . .
O2 Cl1 O4 108.4(4) . .
O2 Cl1 O1 110.3(4) . .
O4 Cl1 O1 110.5(4) . .
O2 Cl1 O3 108.9(3) . .
O4 Cl1 O3 110.3(4) . .
O1 Cl1 O3 108.3(3) . .
O8 Cl2 O7 111.4(7) . .
O8 Cl2 O6 120.5(6) . .
O7 Cl2 O6 95.1(7) . .
O8 Cl2 O5 109.3(5) . .
O7 Cl2 O5 108.4(7) . .
O6 Cl2 O5 110.9(6) . .
O11 Cl3 O9 109.5(3) . .
O11 Cl3 O10 109.8(3) . .
O9 Cl3 O10 110.2(3) . .
O11 Cl3 O12 109.4(3) . .
O9 Cl3 O12 108.5(3) . .
O10 Cl3 O12 109.6(3) . .
O17 Cl5 O20 109.1(4) . .
O17 Cl5 O19 110.0(4) . .
O20 Cl5 O19 111.6(4) . .
O17 Cl5 O18 106.0(4) . .
O20 Cl5 O18 111.2(5) . .
O19 Cl5 O18 108.8(4) . .
O23 Cl6 O21 110.9(4) . .
O23 Cl6 O22 110.8(4) . .
O21 Cl6 O22 107.2(4) . .
O23 Cl6 O24 109.7(4) . .
O21 Cl6 O24 107.5(3) . .
O22 Cl6 O24 110.6(4) . .
O14 Cl4 O16 121.1(7) . .
O14 Cl4 O15 100.8(6) . .
O16 Cl4 O15 107.5(5) . .
O14 Cl4 O13 108.5(6) . .
O16 Cl4 O13 109.0(4) . .
O15 Cl4 O13 109.3(5) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 N5 2.512(4) .
Eu1 N15 2.514(4) .
Eu1 N2 2.514(4) .
Eu1 N18 2.514(4) .
Eu1 N8 2.523(4) .
Eu1 N12 2.541(4) .
Eu1 N1 2.653(4) .
Eu1 N11 2.662(4) .
Eu1 C58 3.265(5) .
Ag1 N4 2.143(5) .
Ag1 N20 2.154(5) 1_655
Ag2 N7 2.295(5) .
Ag2 N10 2.297(5) 4_575
Ag2 N21 2.402(7) .
Ag3 N17 2.160(6) .
Ag3 O25 2.209(9) .
Ag3 N14 2.215(6) 2_756
N1 C1 1.472(6) .
N1 C29 1.481(6) .
N1 C15 1.485(6) .
N2 C2 1.334(6) .
N2 C3 1.400(7) .
N3 C2 1.345(7) .
N3 C8 1.375(7) .
N3 C9 1.466(7) .
N4 C13 1.329(8) .
N4 C14 1.356(8) .
N5 C16 1.329(6) .
N5 C17 1.396(6) .
N6 C16 1.361(7) .
N6 C22 1.389(6) .
N6 C23 1.467(7) .
N7 C27 1.317(8) .
N7 C28 1.343(8) .
N8 C30 1.320(6) .
N8 C31 1.399(7) .
N9 C30 1.356(6) .
N9 C36 1.394(7) .
N9 C37 1.471(6) .
N10 C42 1.340(8) .
N10 C41 1.345(9) .
N10 Ag2 2.297(5) 4_576
N11 C43 1.474(7) .
N11 C71 1.475(7) .
N11 C57 1.484(6) .
N12 C44 1.316(7) .
N12 C45 1.398(7) .
N13 C44 1.342(7) .
N13 C50 1.396(7) .
N13 C51 1.474(7) .
N14 C55 1.288(10) .
N14 C56 1.360(9) .
N14 Ag3 2.215(6) 2_746
N15 C58 1.333(7) .
N15 C59 1.405(7) .
N16 C58 1.359(7) .
N16 C64 1.382(7) .
N16 C65 1.457(7) .
N17 C69 1.348(10) .
N17 C70 1.363(9) .
N18 C72 1.318(6) .
N18 C73 1.415(6) .
N19 C72 1.357(7) .
N19 C78 1.397(6) .
N19 C79 1.464(7) .
N20 C84 1.327(8) .
N20 C83 1.346(9) .
N20 Ag1 2.154(5) 1_455
N21 C85 1.124(9) .
N22 C87 1.109(12) .
N23 C89 1.143(11) .
N24 C91 1.113(10) .
N25 C93 1.126(8) .
C1 C2 1.489(7) .
C1 H1A 0.9900 .
C1 H1B 0.9900 .
C3 C8 1.387(8) .
C3 C4 1.394(8) .
C4 C5 1.390(8) .
C4 H4A 0.9500 .
C5 C6 1.409(9) .
C5 H5A 0.9500 .
C6 C7 1.361(9) .
C6 H6A 0.9500 .
C7 C8 1.405(8) .
C7 H7A 0.9500 .
C9 C10 1.527(7) .
C9 H9A 0.9900 .
C9 H9B 0.9900 .
C10 C14 1.337(9) .
C10 C11 1.355(9) .
C11 C12 1.402(10) .
C11 H11A 0.9500 .
C12 C13 1.330(10) .
C12 H12A 0.9500 .
C13 H13A 0.9500 .
C14 H14A 0.9500 .
C15 C16 1.496(7) .
C15 H15A 0.9900 .
C15 H15B 0.9900 .
C17 C18 1.389(7) .
C17 C22 1.394(8) .
C18 C19 1.392(8) .
C18 H18A 0.9500 .
C19 C20 1.407(9) .
C19 H19A 0.9500 .
C20 C21 1.369(9) .
C20 H20A 0.9500 .
C21 C22 1.392(8) .
C21 H21A 0.9500 .
C23 C24 1.513(8) .
C23 H23A 0.9900 .
C23 H23B 0.9900 .
C24 C28 1.371(8) .
C24 C25 1.386(9) .
C25 C26 1.365(10) .
C25 H25A 0.9500 .
C26 C27 1.356(10) .
C26 H26A 0.9500 .
C27 H27A 0.9500 .
C28 H28A 0.9500 .
C29 C30 1.477(7) .
C29 H29A 0.9900 .
C29 H29B 0.9900 .
C31 C32 1.394(7) .
C31 C36 1.399(7) .
C32 C33 1.385(8) .
C32 H32A 0.9500 .
C33 C34 1.393(8) .
C33 H33A 0.9500 .
C34 C35 1.383(8) .
C34 H34A 0.9500 .
C35 C36 1.370(8) .
C35 H35A 0.9500 .
C37 C38 1.512(8) .
C37 H37A 0.9900 .
C37 H37B 0.9900 .
C38 C42 1.383(9) .
C38 C39 1.391(9) .
C39 C40 1.385(10) .
C39 H39A 0.9500 .
C40 C41 1.365(11) .
C40 H40A 0.9500 .
C41 H41A 0.9500 .
C42 H42A 0.9500 .
C43 C44 1.487(8) .
C43 H43A 0.9900 .
C43 H43B 0.9900 .
C45 C50 1.398(8) .
C45 C46 1.407(8) .
C46 C47 1.371(9) .
C46 H46A 0.9500 .
C47 C48 1.392(10) .
C47 H47A 0.9500 .
C48 C49 1.379(10) .
C48 H48A 0.9500 .
C49 C50 1.399(8) .
C49 H49A 0.9500 .
C51 C52 1.533(8) .
C51 H51A 0.9900 .
C51 H51B 0.9900 .
C52 C53 1.351(10) .
C52 C56 1.360(9) .
C53 C54 1.411(11) .
C53 H53A 0.9500 .
C54 C55 1.345(12) .
C54 H54A 0.9500 .
C55 H55A 0.9500 .
C56 H56A 0.9500 .
C57 C58 1.482(8) .
C57 H57A 0.9900 .
C57 H57B 0.9900 .
C59 C64 1.402(8) .
C59 C60 1.404(8) .
C60 C61 1.376(9) .
C60 H60A 0.9500 .
C61 C62 1.410(9) .
C61 H61A 0.9500 .
C62 C63 1.388(9) .
C62 H62A 0.9500 .
C63 C64 1.381(8) .
C63 H63A 0.9500 .
C65 C66 1.509(8) .
C65 H65A 0.9900 .
C65 H65B 0.9900 .
C66 C70 1.357(9) .
C66 C67 1.375(8) .
C67 C68 1.374(10) .
C67 H67A 0.9500 .
C68 C69 1.353(11) .
C68 H68A 0.9500 .
C69 H69A 0.9500 .
C70 H70A 0.9500 .
C71 C72 1.483(7) .
C71 H71A 0.9900 .
C71 H71B 0.9900 .
C73 C78 1.392(7) .
C73 C74 1.396(7) .
C74 C75 1.388(7) .
C74 H74A 0.9500 .
C75 C76 1.407(8) .
C75 H75A 0.9500 .
C76 C77 1.380(8) .
C76 H76A 0.9500 .
C77 C78 1.382(7) .
C77 H77A 0.9500 .
C79 C80 1.511(8) .
C79 H79A 0.9900 .
C79 H79B 0.9900 .
C80 C84 1.354(9) .
C80 C81 1.371(9) .
C81 C82 1.378(10) .
C81 H81A 0.9500 .
C82 C83 1.365(11) .
C82 H82A 0.9500 .
C83 H83A 0.9500 .
C84 H84A 0.9500 .
C85 C86 1.462(11) .
C86 H86A 0.9800 .
C86 H86B 0.9800 .
C86 H86C 0.9800 .
C87 C88 1.474(14) .
C88 H88A 0.9800 .
C88 H88B 0.9800 .
C88 H88C 0.9800 .
C89 C90 1.426(12) .
C90 H90A 0.9800 .
C90 H90B 0.9800 .
C90 H90C 0.9800 .
C91 C92 1.448(10) .
C92 H92A 0.9800 .
C92 H92B 0.9800 .
C92 H92C 0.9800 .
C93 C94 1.417(9) .
C94 H94A 0.9800 .
C94 H94B 0.9800 .
C94 H94C 0.9800 .
Cl1 O2 1.412(5) .
Cl1 O4 1.418(6) .
Cl1 O1 1.418(5) .
Cl1 O3 1.426(6) .
Cl2 O8 1.322(8) .
Cl2 O7 1.339(9) .
Cl2 O6 1.396(10) .
Cl2 O5 1.400(7) .
Cl3 O11 1.418(5) .
Cl3 O9 1.426(5) .
Cl3 O10 1.434(5) .
Cl3 O12 1.440(4) .
Cl5 O17 1.395(7) .
Cl5 O20 1.402(7) .
Cl5 O19 1.406(6) .
Cl5 O18 1.435(6) .
Cl6 O23 1.416(6) .
Cl6 O21 1.417(5) .
Cl6 O22 1.418(6) .
Cl6 O24 1.418(6) .
Cl4 O14 1.335(11) .
Cl4 O16 1.382(8) .
Cl4 O15 1.395(9) .
Cl4 O13 1.469(7) .
