#------------------------------------------------------------------------------
#$Date: 2016-03-21 06:05:04 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178489 $
#$URL: svn://www.crystallography.net/cod/cif/4/06/00/4060061.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4060061
loop_
_publ_author_name
'Carsten Cornelissen'
'Gerhard Erker'
'Gerald Kehr'
'Roland Fröhlich'
_publ_section_title
;
 Chemistry of Metal-Metal-Bonded Early-Late Heterobimetallics:
 Cooperative Reactions of Functional Groups at a Persistent
 Organometallic Zr-Rh Framework
;
_journal_name_full               Organometallics
_journal_page_first              214
_journal_page_last               225
_journal_paper_doi               10.1021/om049346z
_journal_volume                  24
_journal_year                    2005
_chemical_formula_sum            'C28 H48 Cl6 P2 Zr'
_chemical_formula_weight         750.52
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 96.65(1)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   24.693(1)
_cell_length_b                   17.604(1)
_cell_length_c                   8.137(1)
_cell_measurement_temperature    198(2)
_cell_volume                     3513.3(5)
_computing_cell_refinement       'Collect (Nonius B.V., 1998)'
_computing_data_collection       'Collect (Nonius B.V., 1998)'
_computing_data_reduction        'Denzo-SMN (Otwinowski & Minor, 1997)'
_computing_molecular_graphics    'Diamond (Brandenburg, 1997)'
_computing_publication_material  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      198(2)
_diffrn_measured_fraction_theta_full 0.993
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device_type  'Nonius KappaCCD'
_diffrn_measurement_method       'ω and φ scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'rotating anode Nonius FR591'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0319
_diffrn_reflns_av_sigmaI/netI    0.0296
_diffrn_reflns_limit_h_max       32
_diffrn_reflns_limit_h_min       -24
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_k_min       -23
_diffrn_reflns_limit_l_max       10
_diffrn_reflns_limit_l_min       -8
_diffrn_reflns_number            13483
_diffrn_reflns_theta_full        27.86
_diffrn_reflns_theta_max         27.86
_diffrn_reflns_theta_min         2.31
_exptl_absorpt_coefficient_mu    0.878
_exptl_absorpt_correction_T_max  0.8440
_exptl_absorpt_correction_T_min  0.7203
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   'SORTAV (Blessing, 1995 & 1997)'
_exptl_crystal_colour            'light yellow'
_exptl_crystal_density_diffrn    1.419
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1552
_exptl_crystal_size_max          0.40
_exptl_crystal_size_mid          0.30
_exptl_crystal_size_min          0.20
_refine_diff_density_max         0.333
_refine_diff_density_min         -0.429
_refine_diff_density_rms         0.054
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.072
_refine_ls_hydrogen_treatment    riding
_refine_ls_matrix_type           full
_refine_ls_number_parameters     174
_refine_ls_number_reflns         4172
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.072
_refine_ls_R_factor_all          0.0279
_refine_ls_R_factor_gt           0.0239
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0219P)²+3.1852P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0611
_refine_ls_wR_factor_ref         0.0630
_reflns_number_gt                3775
_reflns_number_total             4172
_reflns_threshold_expression     >2sigma(I)
_cod_original_sg_symbol_H-M      C2/c
_cod_database_code               4060061
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Zr Zr 0.0000 0.150441(11) 0.2500 0.01833(6) Uani 1 2 d S
Cl1 Cl 0.068454(16) 0.05541(2) 0.34790(5) 0.03133(10) Uani 1 1 d .
C1 C 0.05649(6) 0.24739(8) 0.10825(17) 0.0206(3) Uani 1 1 d .
C2 C 0.07232(6) 0.17453(9) 0.05556(18) 0.0238(3) Uani 1 1 d .
H2 H 0.1077 0.1531 0.0790 0.029 Uiso 1 1 calc R
C3 C 0.02763(7) 0.13909(9) -0.03666(18) 0.0266(3) Uani 1 1 d .
H3 H 0.0275 0.0898 -0.0845 0.032 Uiso 1 1 calc R
C4 C -0.01690(6) 0.18970(9) -0.04543(18) 0.0265(3) Uani 1 1 d .
H4 H -0.0521 0.1810 -0.1027 0.032 Uiso 1 1 calc R
C5 C -0.00007(6) 0.25519(9) 0.04538(17) 0.0224(3) Uani 1 1 d .
H5 H -0.0225 0.2977 0.0624 0.027 Uiso 1 1 calc R
P1 P 0.095292(15) 0.33023(2) 0.19464(5) 0.02128(9) Uani 1 1 d .
C11 C 0.10379(7) 0.38152(10) -0.0070(2) 0.0324(4) Uani 1 1 d .
C12 C 0.14933(9) 0.44087(11) 0.0241(2) 0.0449(5) Uani 1 1 d .
H12A H 0.1845 0.4151 0.0477 0.067 Uiso 1 1 calc R
H12B H 0.1428 0.4726 0.1187 0.067 Uiso 1 1 calc R
H12C H 0.1498 0.4728 -0.0744 0.067 Uiso 1 1 calc R
C13 C 0.11406(10) 0.33103(12) -0.1527(2) 0.0498(5) Uani 1 1 d .
H13A H 0.1173 0.3627 -0.2501 0.075 Uiso 1 1 calc R
H13B H 0.0836 0.2956 -0.1768 0.075 Uiso 1 1 calc R
H13C H 0.1479 0.3024 -0.1247 0.075 Uiso 1 1 calc R
C14 C 0.05020(9) 0.42526(12) -0.0509(3) 0.0524(5) Uani 1 1 d .
H14A H 0.0536 0.4587 -0.1455 0.079 Uiso 1 1 calc R
H14B H 0.0424 0.4558 0.0443 0.079 Uiso 1 1 calc R
H14C H 0.0204 0.3892 -0.0796 0.079 Uiso 1 1 calc R
C21 C 0.16364(6) 0.29283(9) 0.2899(2) 0.0267(3) Uani 1 1 d .
C22 C 0.15147(7) 0.23246(10) 0.4169(2) 0.0345(4) Uani 1 1 d .
H22A H 0.1854 0.2185 0.4851 0.052 Uiso 1 1 calc R
H22B H 0.1358 0.1874 0.3589 0.052 Uiso 1 1 calc R
H22C H 0.1255 0.2530 0.4878 0.052 Uiso 1 1 calc R
C23 C 0.20264(7) 0.25953(11) 0.1740(2) 0.0380(4) Uani 1 1 d .
H23A H 0.2128 0.2993 0.0991 0.057 Uiso 1 1 calc R
H23B H 0.1844 0.2180 0.1092 0.057 Uiso 1 1 calc R
H23C H 0.2355 0.2402 0.2400 0.057 Uiso 1 1 calc R
C24 C 0.19191(7) 0.35925(10) 0.3888(2) 0.0349(4) Uani 1 1 d .
H24A H 0.1676 0.3795 0.4650 0.052 Uiso 1 1 calc R
H24B H 0.2005 0.3993 0.3123 0.052 Uiso 1 1 calc R
H24C H 0.2256 0.3411 0.4519 0.052 Uiso 1 1 calc R
C31 C 0.17594(8) -0.02664(11) 0.1587(2) 0.0390(4) Uani 1 1 d .
H31A H 0.1399 -0.0017 0.1345 0.047 Uiso 1 1 calc R
H31B H 0.1869 -0.0459 0.0530 0.047 Uiso 1 1 calc R
Cl32 Cl 0.17012(2) -0.10341(3) 0.29311(7) 0.05257(14) Uani 1 1 d .
Cl33 Cl 0.22399(2) 0.04074(3) 0.24256(6) 0.05030(13) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zr Zr -2.9673 0.5597 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
Cl1 Zr Cl1 93.66(2) 2 .
Cl1 Zr C5 110.04(4) 2 .
Cl1 Zr C5 132.30(3) . .
Cl1 Zr C5 132.30(3) 2 2
Cl1 Zr C5 110.04(4) . 2
C5 Zr C5 84.15(7) . 2
Cl1 Zr C4 80.97(4) 2 .
Cl1 Zr C4 122.46(4) . .
C5 Zr C4 32.84(5) . .
C5 Zr C4 115.35(5) 2 .
Cl1 Zr C4 122.46(4) 2 2
Cl1 Zr C4 80.97(4) . 2
C5 Zr C4 115.35(5) . 2
C5 Zr C4 32.84(5) 2 2
C4 Zr C4 147.77(8) . 2
Cl1 Zr C3 83.97(4) 2 .
Cl1 Zr C3 89.78(4) . .
C5 Zr C3 54.28(5) . .
C5 Zr C3 134.58(5) 2 .
C4 Zr C3 32.75(5) . .
C4 Zr C3 152.27(5) 2 .
Cl1 Zr C3 89.78(4) 2 2
Cl1 Zr C3 83.97(4) . 2
C5 Zr C3 134.59(5) . 2
C5 Zr C3 54.28(5) 2 2
C4 Zr C3 152.27(5) . 2
C4 Zr C3 32.75(5) 2 2
C3 Zr C3 170.87(7) . 2
Cl1 Zr C2 114.72(4) 2 .
Cl1 Zr C2 78.98(4) . .
C5 Zr C2 53.70(5) . .
C5 Zr C2 110.22(5) 2 .
C4 Zr C2 53.63(5) . .
C4 Zr C2 120.06(5) 2 .
C3 Zr C2 32.22(5) . .
C3 Zr C2 150.75(5) 2 .
Cl1 Zr C2 78.98(4) 2 2
Cl1 Zr C2 114.72(4) . 2
C5 Zr C2 110.22(5) . 2
C5 Zr C2 53.70(5) 2 2
C4 Zr C2 120.06(5) . 2
C4 Zr C2 53.63(5) 2 2
C3 Zr C2 150.74(5) . 2
C3 Zr C2 32.22(5) 2 2
C2 Zr C2 160.89(7) . 2
Cl1 Zr C1 102.16(3) 2 2
Cl1 Zr C1 134.52(3) . 2
C5 Zr C1 81.32(5) . 2
C5 Zr C1 33.05(4) 2 2
C4 Zr C1 102.16(5) . 2
C4 Zr C1 54.51(5) 2 2
C3 Zr C1 133.75(5) . 2
C3 Zr C1 54.16(5) 2 2
C2 Zr C1 128.64(5) . 2
C2 Zr C1 32.26(5) 2 2
Cl1 Zr C1 134.52(3) 2 .
Cl1 Zr C1 102.15(3) . .
C5 Zr C1 33.05(4) . .
C5 Zr C1 81.32(5) 2 .
C4 Zr C1 54.51(5) . .
C4 Zr C1 102.16(5) 2 .
C3 Zr C1 54.16(5) . .
C3 Zr C1 133.75(5) 2 .
C2 Zr C1 32.26(5) . .
C2 Zr C1 128.64(5) 2 .
C1 Zr C1 96.44(6) 2 .
C2 C1 C5 105.58(13) . .
C2 C1 P1 132.96(11) . .
C5 C1 P1 120.13(11) . .
C2 C1 Zr 73.60(8) . .
C5 C1 Zr 70.52(8) . .
P1 C1 Zr 130.01(7) . .
C3 C2 C1 109.58(13) . .
C3 C2 Zr 72.26(8) . .
C1 C2 Zr 74.14(8) . .
C2 C3 C4 107.79(14) . .
C2 C3 Zr 75.53(8) . .
C4 C3 Zr 72.71(8) . .
C5 C4 C3 108.06(13) . .
C5 C4 Zr 73.37(8) . .
C3 C4 Zr 74.53(8) . .
C4 C5 C1 108.95(13) . .
C4 C5 Zr 73.79(8) . .
C1 C5 Zr 76.43(8) . .
C1 P1 C21 106.33(7) . .
C1 P1 C11 98.68(7) . .
C21 P1 C11 109.61(7) . .
C13 C11 C12 109.89(16) . .
C13 C11 C14 109.10(17) . .
C12 C11 C14 106.98(15) . .
C13 C11 P1 115.95(12) . .
C12 C11 P1 109.41(12) . .
C14 C11 P1 105.06(12) . .
C22 C21 C23 109.48(14) . .
C22 C21 C24 106.61(14) . .
C23 C21 C24 109.34(13) . .
C22 C21 P1 106.36(10) . .
C23 C21 P1 118.24(12) . .
C24 C21 P1 106.19(11) . .
Cl32 C31 Cl33 112.18(10) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Zr Cl1 2.4450(4) 2
Zr Cl1 2.4451(4) .
Zr C5 2.4843(14) .
Zr C5 2.4843(14) 2
Zr C4 2.4896(15) .
Zr C4 2.4896(15) 2
Zr C3 2.5129(15) .
Zr C3 2.5130(15) 2
Zr C2 2.5547(14) .
Zr C2 2.5547(14) 2
Zr C1 2.5616(14) 2
Zr C1 2.5616(14) .
C1 C2 1.421(2) .
C1 C5 1.437(2) .
C1 P1 1.8392(15) .
C2 C3 1.407(2) .
C3 C4 1.411(2) .
C4 C5 1.406(2) .
P1 C21 1.8919(15) .
P1 C11 1.9057(16) .
C11 C13 1.526(3) .
C11 C12 1.534(2) .
C11 C14 1.537(3) .
C21 C22 1.536(2) .
C21 C23 1.540(2) .
C21 C24 1.540(2) .
C31 Cl32 1.7551(19) .
C31 Cl33 1.759(2) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
Cl1 Zr C1 C2 -62.69(10) 2
Cl1 Zr C1 C2 44.97(9) .
C5 Zr C1 C2 -113.65(12) .
C5 Zr C1 C2 153.74(9) 2
C4 Zr C1 C2 -76.42(9) .
C4 Zr C1 C2 128.21(9) 2
C3 Zr C1 C2 -35.81(9) .
C3 Zr C1 C2 138.26(9) 2
C2 Zr C1 C2 -178.98(3) 2
C1 Zr C1 C2 -176.78(10) 2
Cl1 Zr C1 C5 50.96(10) 2
Cl1 Zr C1 C5 158.62(8) .
C5 Zr C1 C5 -92.62(10) 2
C4 Zr C1 C5 37.23(8) .
C4 Zr C1 C5 -118.15(9) 2
C3 Zr C1 C5 77.84(9) .
C3 Zr C1 C5 -108.10(9) 2
C2 Zr C1 C5 113.65(12) .
C2 Zr C1 C5 -65.33(10) 2
C1 Zr C1 C5 -63.13(8) 2
Cl1 Zr C1 P1 164.43(6) 2
Cl1 Zr C1 P1 -87.91(9) .
C5 Zr C1 P1 113.47(13) .
C5 Zr C1 P1 20.86(9) 2
C4 Zr C1 P1 150.70(12) .
C4 Zr C1 P1 -4.68(10) 2
C3 Zr C1 P1 -168.69(12) .
C3 Zr C1 P1 5.38(13) 2
C2 Zr C1 P1 -132.88(14) .
C2 Zr C1 P1 48.14(11) 2
C1 Zr C1 P1 50.34(7) 2
C5 C1 C2 C3 0.36(16) .
P1 C1 C2 C3 -166.01(12) .
Zr C1 C2 C3 64.07(10) .
C5 C1 C2 Zr -63.71(9) .
P1 C1 C2 Zr 129.92(13) .
Cl1 Zr C2 C3 18.60(10) 2
Cl1 Zr C2 C3 107.56(9) .
C5 Zr C2 C3 -78.86(10) .
C5 Zr C2 C3 -144.96(9) 2
C4 Zr C2 C3 -37.78(9) .
C4 Zr C2 C3 -179.73(9) 2
C3 Zr C2 C3 163.05(14) 2
C2 Zr C2 C3 -114.73(9) 2
C1 Zr C2 C3 -113.07(10) 2
C1 Zr C2 C3 -117.17(13) .
Cl1 Zr C2 C1 135.77(8) 2
Cl1 Zr C2 C1 -135.26(8) .
C5 Zr C2 C1 38.31(8) .
C5 Zr C2 C1 -27.78(10) 2
C4 Zr C2 C1 79.39(9) .
C4 Zr C2 C1 -62.56(10) 2
C3 Zr C2 C1 117.17(13) .
C3 Zr C2 C1 -79.78(13) 2
C2 Zr C2 C1 2.44(8) 2
C1 Zr C2 C1 4.10(13) 2
C1 C2 C3 C4 0.83(17) .
Zr C2 C3 C4 66.10(10) .
C1 C2 C3 Zr -65.27(10) .
Cl1 Zr C3 C2 -163.06(9) 2
Cl1 Zr C3 C2 -69.36(9) .
C5 Zr C3 C2 76.91(10) .
C5 Zr C3 C2 49.16(12) 2
C4 Zr C3 C2 114.26(13) .
C4 Zr C3 C2 0.49(17) 2
C3 Zr C3 C2 -116.04(9) 2
C2 Zr C3 C2 142.53(14) 2
C1 Zr C3 C2 95.87(10) 2
C1 Zr C3 C2 35.86(8) .
Cl1 Zr C3 C4 82.68(9) 2
Cl1 Zr C3 C4 176.38(9) .
C5 Zr C3 C4 -37.35(9) .
C5 Zr C3 C4 -65.10(11) 2
C4 Zr C3 C4 -113.77(17) 2
C3 Zr C3 C4 129.70(9) 2
C2 Zr C3 C4 -114.26(13) .
C2 Zr C3 C4 28.27(15) 2
C1 Zr C3 C4 -18.39(12) 2
C1 Zr C3 C4 -78.40(10) .
C2 C3 C4 C5 -1.72(17) .
Zr C3 C4 C5 66.26(10) .
C2 C3 C4 Zr -67.99(10) .
Cl1 Zr C4 C5 152.38(9) 2
Cl1 Zr C4 C5 -119.02(8) .
C5 Zr C4 C5 19.64(12) 2
C4 Zr C4 C5 12.30(8) 2
C3 Zr C4 C5 -114.73(13) .
C3 Zr C4 C5 80.47(14) 2
C2 Zr C4 C5 -77.60(9) .
C2 Zr C4 C5 80.78(10) 2
C1 Zr C4 C5 51.79(9) 2
C1 Zr C4 C5 -37.48(8) .
Cl1 Zr C4 C3 -92.89(9) 2
Cl1 Zr C4 C3 -4.29(11) .
C5 Zr C4 C3 114.73(13) .
C5 Zr C4 C3 134.37(9) 2
C4 Zr C4 C3 127.03(9) 2
C3 Zr C4 C3 -164.80(13) 2
C2 Zr C4 C3 37.13(9) .
C2 Zr C4 C3 -164.49(9) 2
C1 Zr C4 C3 166.52(9) 2
C1 Zr C4 C3 77.25(10) .
C3 C4 C5 C1 1.97(16) .
Zr C4 C5 C1 69.01(10) .
C3 C4 C5 Zr -67.04(10) .
C2 C1 C5 C4 -1.43(15) .
P1 C1 C5 C4 167.07(10) .
Zr C1 C5 C4 -67.26(10) .
C2 C1 C5 Zr 65.83(9) .
P1 C1 C5 Zr -125.67(9) .
Cl1 Zr C5 C4 -29.17(9) 2
Cl1 Zr C5 C4 85.90(9) .
C5 Zr C5 C4 -162.22(11) 2
C4 Zr C5 C4 -172.78(5) 2
C3 Zr C5 C4 37.25(9) .
C3 Zr C5 C4 -139.89(9) 2
C2 Zr C5 C4 77.36(10) .
C2 Zr C5 C4 -114.43(9) 2
C1 Zr C5 C4 -129.01(9) 2
C1 Zr C5 C4 114.71(13) .
Cl1 Zr C5 C1 -143.88(7) 2
Cl1 Zr C5 C1 -28.81(10) .
C5 Zr C5 C1 83.07(8) 2
C4 Zr C5 C1 -114.71(13) .
C4 Zr C5 C1 72.51(9) 2
C3 Zr C5 C1 -77.46(9) .
C3 Zr C5 C1 105.40(10) 2
C2 Zr C5 C1 -37.35(8) .
C2 Zr C5 C1 130.85(8) 2
C1 Zr C5 C1 116.27(9) 2
C2 C1 P1 C21 -23.22(16) .
C5 C1 P1 C21 171.99(11) .
Zr C1 P1 C21 82.92(10) .
C2 C1 P1 C11 90.27(15) .
C5 C1 P1 C11 -74.52(12) .
Zr C1 P1 C11 -163.59(9) .
C1 P1 C11 C13 -38.18(16) .
C21 P1 C11 C13 72.70(16) .
C1 P1 C11 C12 -163.11(13) .
C21 P1 C11 C12 -52.24(15) .
C1 P1 C11 C14 82.34(13) .
C21 P1 C11 C14 -166.78(12) .
C1 P1 C21 C22 -56.79(12) .
C11 P1 C21 C22 -162.54(11) .
C1 P1 C21 C23 66.73(13) .
C11 P1 C21 C23 -39.01(14) .
C1 P1 C21 C24 -170.08(11) .
C11 P1 C21 C24 84.17(12) .
