#------------------------------------------------------------------------------
#$Date: 2016-03-21 06:05:04 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178489 $
#$URL: svn://www.crystallography.net/cod/cif/4/06/00/4060065.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4060065
loop_
_publ_author_name
'Carsten Cornelissen'
'Gerhard Erker'
'Gerald Kehr'
'Roland Fröhlich'
_publ_section_title
;
 Chemistry of Metal-Metal-Bonded Early-Late Heterobimetallics:
 Cooperative Reactions of Functional Groups at a Persistent
 Organometallic Zr-Rh Framework
;
_journal_name_full               Organometallics
_journal_page_first              214
_journal_page_last               225
_journal_paper_doi               10.1021/om049346z
_journal_volume                  24
_journal_year                    2005
_chemical_formula_sum            'C44 H63 O2 P2 Rh Zr'
_chemical_formula_weight         880.01
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 130.74(1)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   33.117(1)
_cell_length_b                   15.246(1)
_cell_length_c                   21.888(1)
_cell_measurement_temperature    198(2)
_cell_volume                     8373.3(7)
_computing_cell_refinement       'Collect (Nonius B.V., 1998)'
_computing_data_collection       'Collect (Nonius B.V., 1998)'
_computing_data_reduction        'Denzo-SMN (Otwinowski & Minor, 1997)'
_computing_molecular_graphics    'Diamond (Brandenburg, 1997)'
_computing_publication_material  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      198(2)
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'Nonius KappaCCD'
_diffrn_measurement_method       'ω and φ scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'rotating anode Nonius FR591'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0580
_diffrn_reflns_av_sigmaI/netI    0.0781
_diffrn_reflns_limit_h_max       43
_diffrn_reflns_limit_h_min       -31
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       28
_diffrn_reflns_limit_l_min       -28
_diffrn_reflns_number            27335
_diffrn_reflns_theta_full        27.86
_diffrn_reflns_theta_max         27.86
_diffrn_reflns_theta_min         1.56
_exptl_absorpt_coefficient_mu    0.754
_exptl_absorpt_correction_T_max  0.9284
_exptl_absorpt_correction_T_min  0.8339
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   'SORRTAV (Blessing, 1995 & 1997)'
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.396
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             3664
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.10
_refine_diff_density_max         1.198
_refine_diff_density_min         -0.655
_refine_diff_density_rms         0.104
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.035
_refine_ls_hydrogen_treatment    riding
_refine_ls_matrix_type           full
_refine_ls_number_parameters     420
_refine_ls_number_reflns         9924
_refine_ls_number_restraints     9
_refine_ls_restrained_S_all      1.050
_refine_ls_R_factor_all          0.0918
_refine_ls_R_factor_gt           0.0497
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0470P)²+15.9142P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1037
_refine_ls_wR_factor_ref         0.1177
_reflns_number_gt                6656
_reflns_number_total             9924
_reflns_threshold_expression     >2sigma(I)
_cod_original_sg_symbol_H-M      C2/c
_cod_database_code               4060065
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh Rh 0.234515(11) 0.735043(19) 0.704571(18) 0.02608(9) Uani 1 1 d . . .
Zr Zr 0.271936(14) 0.82419(2) 0.85000(2) 0.02571(10) Uani 1 1 d . . .
P1 P 0.15757(4) 0.80998(6) 0.65851(6) 0.0258(2) Uani 1 1 d . . .
P2 P 0.31127(4) 0.80357(7) 0.74437(6) 0.0282(2) Uani 1 1 d . . .
C1 C 0.29185(19) 0.7193(3) 0.9424(3) 0.0470(11) Uani 1 1 d . . .
H1A H 0.3046 0.7481 0.9923 0.071 Uiso 1 1 calc R . .
H1B H 0.3196 0.6801 0.9541 0.071 Uiso 1 1 calc R . .
H1C H 0.2598 0.6851 0.9200 0.071 Uiso 1 1 calc R . .
C2 C 0.25391(16) 0.6424(3) 0.7750(3) 0.0352(10) Uani 1 1 d . . .
O2 O 0.26505(15) 0.5781(2) 0.8108(2) 0.0622(10) Uani 1 1 d . . .
C3 C 0.20821(17) 0.6859(3) 0.6042(3) 0.0393(10) Uani 1 1 d . . .
O3 O 0.19191(15) 0.6564(2) 0.5437(2) 0.0656(10) Uani 1 1 d . . .
C11 C 0.17536(14) 0.8599(2) 0.7480(2) 0.0279(8) Uani 1 1 d . . .
C12 C 0.20372(15) 0.9405(2) 0.7822(2) 0.0317(9) Uani 1 1 d . . .
H12 H 0.2072 0.9844 0.7551 0.038 Uiso 1 1 calc R . .
C13 C 0.22564(16) 0.9436(3) 0.8632(3) 0.0397(10) Uani 1 1 d . . .
H13 H 0.2462 0.9905 0.8998 0.048 Uiso 1 1 calc R . .
C14 C 0.21223(17) 0.8669(3) 0.8806(3) 0.0421(11) Uani 1 1 d . . .
H14 H 0.2218 0.8522 0.9307 0.051 Uiso 1 1 calc R . .
C15 C 0.18190(16) 0.8146(3) 0.8104(2) 0.0363(10) Uani 1 1 d . . .
H15 H 0.1681 0.7581 0.8058 0.044 Uiso 1 1 calc R . .
C16 C 0.34265(15) 0.8507(3) 0.8421(2) 0.0298(9) Uani 1 1 d . . .
C17 C 0.36719(15) 0.8013(3) 0.9139(2) 0.0337(9) Uani 1 1 d . . .
H17 H 0.3796 0.7426 0.9227 0.040 Uiso 1 1 calc R . .
C18 C 0.36999(16) 0.8533(3) 0.9695(2) 0.0388(10) Uani 1 1 d . . .
H18 H 0.3851 0.8362 1.0224 0.047 Uiso 1 1 calc R . .
C19 C 0.34680(16) 0.9344(3) 0.9338(3) 0.0401(10) Uani 1 1 d . . .
H19 H 0.3433 0.9820 0.9581 0.048 Uiso 1 1 calc R . .
C20 C 0.32941(16) 0.9333(3) 0.8552(2) 0.0338(9) Uani 1 1 d . . .
H20 H 0.3118 0.9801 0.8174 0.041 Uiso 1 1 calc R . .
C21 C 0.13512(17) 0.9068(3) 0.5919(2) 0.0366(10) Uani 1 1 d . . .
H21 H 0.1671 0.9458 0.6202 0.044 Uiso 1 1 calc R . .
C22 C 0.1196(2) 0.8851(3) 0.5110(3) 0.0546(13) Uani 1 1 d . . .
H22A H 0.1492 0.8531 0.5203 0.066 Uiso 1 1 calc R . .
H22B H 0.0880 0.8463 0.4799 0.066 Uiso 1 1 calc R . .
C23 C 0.1071(2) 0.9677(4) 0.4622(3) 0.0688(16) Uani 1 1 d . . .
H23A H 0.1403 1.0018 0.4892 0.083 Uiso 1 1 calc R . .
H23B H 0.0938 0.9507 0.4081 0.083 Uiso 1 1 calc R . .
C24 C 0.0662(2) 1.0249(4) 0.4527(3) 0.0678(16) Uani 1 1 d . . .
H24A H 0.0621 1.0801 0.4254 0.081 Uiso 1 1 calc R . .
H24B H 0.0313 0.9944 0.4181 0.081 Uiso 1 1 calc R . .
C25 C 0.0813(2) 1.0460(3) 0.5318(3) 0.0604(14) Uani 1 1 d . . .
H25A H 0.0523 1.0799 0.5226 0.073 Uiso 1 1 calc R . .
H25B H 0.1138 1.0828 0.5638 0.073 Uiso 1 1 calc R . .
C26 C 0.09164(18) 0.9632(3) 0.5787(3) 0.0416(11) Uani 1 1 d . . .
H26A H 0.0583 0.9288 0.5489 0.050 Uiso 1 1 calc R . .
H26B H 0.1028 0.9794 0.6316 0.050 Uiso 1 1 calc R . .
C31 C 0.09519(17) 0.7462(3) 0.6105(3) 0.0445(11) Uani 1 1 d . . .
H31 H 0.0731 0.7637 0.5526 0.053 Uiso 1 1 calc R . .
C32 C 0.06012(17) 0.7726(3) 0.6278(3) 0.0490(12) Uani 1 1 d . . .
H32A H 0.0800 0.7643 0.6861 0.059 Uiso 1 1 calc R . .
H32B H 0.0519 0.8359 0.6159 0.059 Uiso 1 1 calc R . .
C33 C 0.00898(19) 0.7231(4) 0.5812(3) 0.0616(15) Uani 1 1 d . . .
H33A H -0.0069 0.7336 0.6063 0.074 Uiso 1 1 calc R . .
H33B H -0.0159 0.7473 0.5259 0.074 Uiso 1 1 calc R . .
C34 C 0.0130(2) 0.6300(4) 0.5759(5) 0.090(2) Uani 1 1 d . . .
H34A H -0.0233 0.6067 0.5329 0.108 Uiso 1 1 calc R . .
H34B H 0.0263 0.6031 0.6273 0.108 Uiso 1 1 calc R . .
C35 C 0.04816(19) 0.6005(3) 0.5590(4) 0.0631(15) Uani 1 1 d . . .
H35A H 0.0285 0.6070 0.5006 0.076 Uiso 1 1 calc R . .
H35B H 0.0565 0.5375 0.5726 0.076 Uiso 1 1 calc R . .
C36 C 0.0998(2) 0.6517(3) 0.6061(4) 0.0734(18) Uani 1 1 d . . .
H36A H 0.1248 0.6283 0.6617 0.088 Uiso 1 1 calc R . .
H36B H 0.1159 0.6411 0.5813 0.088 Uiso 1 1 calc R . .
C41 C 0.30550(16) 0.8998(3) 0.6877(2) 0.0357(10) Uani 1 1 d . . .
H41 H 0.2829 0.9425 0.6883 0.043 Uiso 1 1 calc R . .
C42 C 0.35648(18) 0.9503(3) 0.7223(3) 0.0508(12) Uani 1 1 d . . .
H42A H 0.3796 0.9135 0.7189 0.061 Uiso 1 1 calc R . .
H42B H 0.3763 0.9636 0.7799 0.061 Uiso 1 1 calc R . .
C43 C 0.3432(2) 1.0361(3) 0.6758(3) 0.0610(15) Uani 1 1 d . . .
H43A H 0.3218 1.0744 0.6819 0.073 Uiso 1 1 calc R . .
H43B H 0.3765 1.0673 0.6984 0.073 Uiso 1 1 calc R . .
C44 C 0.3117(2) 1.0171(4) 0.5863(3) 0.0632(15) Uani 1 1 d . . .
H44A H 0.3019 1.0730 0.5566 0.076 Uiso 1 1 calc R . .
H44B H 0.3342 0.9832 0.5798 0.076 Uiso 1 1 calc R . .
C45 C 0.2618(2) 0.9656(3) 0.5516(3) 0.0641(15) Uani 1 1 d . . .
H45A H 0.2429 0.9517 0.4944 0.077 Uiso 1 1 calc R . .
H45B H 0.2379 1.0021 0.5534 0.077 Uiso 1 1 calc R . .
C46 C 0.2743(2) 0.8802(3) 0.5979(3) 0.0524(13) Uani 1 1 d . . .
H46A H 0.2957 0.8413 0.5923 0.063 Uiso 1 1 calc R . .
H46B H 0.2407 0.8496 0.5749 0.063 Uiso 1 1 calc R . .
C51 C 0.36279(17) 0.7271(3) 0.7650(3) 0.0491(12) Uani 1 1 d . . .
H51 H 0.3640 0.6814 0.7988 0.059 Uiso 1 1 calc R . .
C52 C 0.3432(2) 0.6739(3) 0.6907(3) 0.0564(13) Uani 1 1 d . . .
H52A H 0.3080 0.6480 0.6656 0.068 Uiso 1 1 calc R . .
H52B H 0.3387 0.7134 0.6507 0.068 Uiso 1 1 calc R . .
C53 C 0.3822(2) 0.6006(4) 0.7126(5) 0.095(2) Uani 1 1 d . . .
H53A H 0.3782 0.5526 0.7388 0.114 Uiso 1 1 calc R . .
H53B H 0.3722 0.5769 0.6622 0.114 Uiso 1 1 calc R . .
C54 C 0.4381(3) 0.6264(5) 0.7658(4) 0.101(2) Uani 1 1 d . . .
H54A H 0.4440 0.6644 0.7356 0.121 Uiso 1 1 calc R . .
H54B H 0.4604 0.5734 0.7829 0.121 Uiso 1 1 calc R . .
C55 C 0.4552(2) 0.6739(5) 0.8384(4) 0.092(2) Uani 1 1 d . . .
H55A H 0.4924 0.6941 0.8697 0.111 Uiso 1 1 calc R . .
H55B H 0.4545 0.6330 0.8728 0.111 Uiso 1 1 calc R . .
C56 C 0.4192(2) 0.7545(4) 0.8175(4) 0.0804(19) Uani 1 1 d . . .
H56A H 0.4300 0.7805 0.8678 0.096 Uiso 1 1 calc R . .
H56B H 0.4236 0.7996 0.7898 0.096 Uiso 1 1 calc R . .
C61 C -0.0158(3) 1.1249(4) 0.2400(7) 0.077(4) Uiso 0.50 1 d PGD A 1
H61 H -0.0079 1.0641 0.2506 0.092 Uiso 0.50 1 calc PR A 1
C62 C -0.0684(3) 1.1532(6) 0.1920(7) 0.124(12) Uiso 0.50 1 d PGD A 1
H62 H -0.0963 1.1119 0.1697 0.149 Uiso 0.50 1 calc PR A 1
C63 C -0.0801(3) 1.2422(6) 0.1765(5) 0.080(4) Uiso 0.50 1 d PGD A 1
H63 H -0.1160 1.2616 0.1437 0.096 Uiso 0.50 1 calc PR A 1
C64 C -0.0392(4) 1.3027(4) 0.2091(7) 0.109(5) Uiso 0.50 1 d PGD . 1
H64 H -0.0472 1.3635 0.1985 0.131 Uiso 0.50 1 calc PR A 1
C65 C 0.0133(3) 1.2744(5) 0.2571(7) 0.103(5) Uiso 0.50 1 d PGD A 1
H65 H 0.0413 1.3157 0.2793 0.124 Uiso 0.50 1 calc PR A 1
C66 C 0.0250(2) 1.1854(6) 0.2726(5) 0.062(3) Uiso 0.50 1 d PGD . 1
C67 C 0.0803(8) 1.1652(12) 0.3211(11) 0.103(8) Uiso 0.50 1 d PD B 1
H67A H 0.0968 1.1638 0.3780 0.155 Uiso 0.50 1 calc PR B 1
H67B H 0.0977 1.2101 0.3132 0.155 Uiso 0.50 1 calc PR B 1
H67C H 0.0843 1.1078 0.3055 0.155 Uiso 0.50 1 calc PR B 1
C71 C -0.0126(5) 0.5324(6) 0.2627(7) 0.149(7) Uiso 0.50 1 d PGD C 1
H71 H -0.0355 0.4831 0.2359 0.179 Uiso 0.50 1 calc PR C 1
C72 C 0.0263(5) 0.5332(7) 0.3463(7) 0.179(9) Uiso 0.50 1 d PGD C 1
H72 H 0.0300 0.4845 0.3767 0.215 Uiso 0.50 1 calc PR C 1
C73 C 0.0597(4) 0.6053(8) 0.3855(6) 0.104(6) Uiso 0.50 1 d PGD C 1
H73 H 0.0863 0.6059 0.4426 0.125 Uiso 0.50 1 calc PR C 1
C74 C 0.0543(4) 0.6766(7) 0.3410(7) 0.135(7) Uiso 0.50 1 d PGD C 1
H74 H 0.0771 0.7259 0.3678 0.162 Uiso 0.50 1 calc PR C 1
C75 C 0.0154(4) 0.6758(6) 0.2574(7) 0.110(5) Uiso 0.50 1 d PGD C 1
H75 H 0.0116 0.7245 0.2270 0.132 Uiso 0.50 1 calc PR C 1
C76 C -0.0181(4) 0.6037(7) 0.2182(6) 0.115(6) Uiso 0.50 1 d PGD C 1
C77 C -0.0540(6) 0.5841(14) 0.1123(6) 0.28(2) Uiso 0.50 1 d PGD C 1
H77A H -0.0721 0.6380 0.0817 0.415 Uiso 0.50 1 calc PR C 1
H77B H -0.0805 0.5376 0.0926 0.415 Uiso 0.50 1 calc PR C 1
H77C H -0.0289 0.5659 0.1052 0.415 Uiso 0.50 1 calc PR C 1
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zr Zr -2.9673 0.5597 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C2 Rh C3 107.78(18) . .
C2 Rh P2 109.09(13) . .
C3 Rh P2 99.98(13) . .
C2 Rh P1 114.60(13) . .
C3 Rh P1 98.36(13) . .
P2 Rh P1 123.97(4) . .
C2 Rh Zr 77.15(12) . .
C3 Rh Zr 175.05(13) . .
P2 Rh Zr 78.37(3) . .
P1 Rh Zr 78.95(3) . .
C1 Zr C12 130.60(16) . .
C1 Zr C20 130.79(15) . .
C12 Zr C20 85.36(14) . .
C1 Zr C11 113.70(15) . .
C12 Zr C11 33.46(12) . .
C20 Zr C11 113.21(13) . .
C1 Zr C16 115.38(15) . .
C12 Zr C16 112.04(13) . .
C20 Zr C16 33.33(13) . .
C11 Zr C16 128.22(13) . .
C1 Zr C17 83.03(15) . .
C12 Zr C17 139.66(14) . .
C20 Zr C17 54.36(14) . .
C11 Zr C17 160.90(13) . .
C16 Zr C17 33.15(13) . .
C1 Zr C15 81.83(16) . .
C12 Zr C15 54.41(14) . .
C20 Zr C15 139.50(14) . .
C11 Zr C15 32.90(13) . .
C16 Zr C15 160.91(13) . .
C17 Zr C15 164.81(14) . .
C1 Zr C13 104.32(16) . .
C12 Zr C13 32.94(13) . .
C20 Zr C13 90.92(14) . .
C11 Zr C13 54.66(13) . .
C16 Zr C13 124.18(14) . .
C17 Zr C13 132.60(14) . .
C15 Zr C13 53.52(14) . .
C1 Zr C19 103.90(16) . .
C12 Zr C19 92.19(14) . .
C20 Zr C19 32.78(13) . .
C11 Zr C19 125.64(14) . .
C16 Zr C19 54.68(13) . .
C17 Zr C19 53.59(14) . .
C15 Zr C19 132.12(14) . .
C13 Zr C19 79.53(14) . .
C1 Zr C18 77.15(16) . .
C12 Zr C18 123.09(14) . .
C20 Zr C18 53.77(14) . .
C11 Zr C18 155.97(14) . .
C16 Zr C18 54.36(13) . .
C17 Zr C18 32.26(13) . .
C15 Zr C18 142.72(13) . .
C13 Zr C18 102.69(14) . .
C19 Zr C18 31.89(14) . .
C1 Zr C14 76.96(16) . .
C12 Zr C14 53.97(14) . .
C20 Zr C14 121.39(14) . .
C11 Zr C14 54.31(13) . .
C16 Zr C14 154.36(14) . .
C17 Zr C14 143.01(14) . .
C15 Zr C14 32.34(13) . .
C13 Zr C14 31.82(14) . .
C19 Zr C14 101.60(14) . .
C18 Zr C14 111.89(14) . .
C1 Zr Rh 108.08(12) . .
C12 Zr Rh 96.28(9) . .
C20 Zr Rh 97.54(9) . .
C11 Zr Rh 74.88(9) . .
C16 Zr Rh 75.33(9) . .
C17 Zr Rh 91.59(10) . .
C15 Zr Rh 91.93(9) . .
C13 Zr Rh 127.68(10) . .
C19 Zr Rh 128.56(10) . .
C18 Zr Rh 123.72(10) . .
C14 Zr Rh 124.04(10) . .
C11 P1 C21 101.34(18) . .
C11 P1 C31 106.78(19) . .
C21 P1 C31 104.1(2) . .
C11 P1 Rh 104.27(12) . .
C21 P1 Rh 119.53(14) . .
C31 P1 Rh 118.84(14) . .
C16 P2 C41 101.93(18) . .
C16 P2 C51 103.5(2) . .
C41 P2 C51 109.6(2) . .
C16 P2 Rh 105.37(13) . .
C41 P2 Rh 119.70(14) . .
C51 P2 Rh 114.44(16) . .
O2 C2 Rh 170.8(4) . .
O3 C3 Rh 179.3(4) . .
C15 C11 C12 106.3(3) . .
C15 C11 P1 125.3(3) . .
C12 C11 P1 124.7(3) . .
C15 C11 Zr 74.3(2) . .
C12 C11 Zr 72.4(2) . .
P1 C11 Zr 101.47(16) . .
C13 C12 C11 108.1(4) . .
C13 C12 Zr 75.5(2) . .
C11 C12 Zr 74.2(2) . .
C14 C13 C12 108.7(4) . .
C14 C13 Zr 75.5(2) . .
C12 C13 Zr 71.5(2) . .
C13 C14 C15 107.8(4) . .
C13 C14 Zr 72.7(2) . .
C15 C14 Zr 72.2(2) . .
C14 C15 C11 109.1(4) . .
C14 C15 Zr 75.5(2) . .
C11 C15 Zr 72.8(2) . .
C20 C16 C17 105.9(3) . .
C20 C16 P2 125.1(3) . .
C17 C16 P2 124.6(3) . .
C20 C16 Zr 72.7(2) . .
C17 C16 Zr 73.9(2) . .
P2 C16 Zr 100.21(16) . .
C18 C17 C16 109.0(4) . .
C18 C17 Zr 75.6(2) . .
C16 C17 Zr 72.9(2) . .
C19 C18 C17 108.3(4) . .
C19 C18 Zr 73.3(2) . .
C17 C18 Zr 72.1(2) . .
C18 C19 C20 108.0(4) . .
C18 C19 Zr 74.8(2) . .
C20 C19 Zr 71.4(2) . .
C19 C20 C16 108.8(4) . .
C19 C20 Zr 75.8(2) . .
C16 C20 Zr 74.0(2) . .
C22 C21 C26 109.9(3) . .
C22 C21 P1 113.5(3) . .
C26 C21 P1 116.1(3) . .
C23 C22 C21 111.5(4) . .
C24 C23 C22 112.5(4) . .
C25 C24 C23 112.0(4) . .
C24 C25 C26 111.4(4) . .
C25 C26 C21 111.2(4) . .
C36 C31 C32 114.6(4) . .
C36 C31 P1 115.2(3) . .
C32 C31 P1 118.3(3) . .
C33 C32 C31 114.4(4) . .
C34 C33 C32 115.6(5) . .
C33 C34 C35 116.2(5) . .
C34 C35 C36 113.0(5) . .
C31 C36 C35 115.7(4) . .
C42 C41 C46 109.5(4) . .
C42 C41 P2 118.0(3) . .
C46 C41 P2 113.1(3) . .
C41 C42 C43 110.7(4) . .
C44 C43 C42 110.4(4) . .
C45 C44 C43 110.4(4) . .
C44 C45 C46 112.0(4) . .
C45 C46 C41 110.3(4) . .
C56 C51 C52 115.0(4) . .
C56 C51 P2 120.3(4) . .
C52 C51 P2 112.8(3) . .
C53 C52 C51 111.6(5) . .
C54 C53 C52 115.2(5) . .
C53 C54 C55 112.8(6) . .
C54 C55 C56 112.8(5) . .
C51 C56 C55 110.0(5) . .
C62 C61 C66 120.0 . .
C63 C62 C61 120.0 . .
C64 C63 C62 120.0 . .
C65 C64 C63 120.0 . .
C65 C64 C64 19.2(3) . 2
C63 C64 C64 136.9(2) . 2
C64 C65 C66 120.0 . .
C61 C66 C62 79.2(7) 2 2
C61 C66 C66 76.4(9) 2 2
C62 C66 C66 155.6(4) 2 2
C61 C66 C65 152.6(11) 2 .
C62 C66 C65 125.4(3) 2 .
C66 C66 C65 78.13(5) 2 .
C61 C66 C61 35.9(10) 2 .
C62 C66 C61 114.3(3) 2 .
C66 C66 C61 41.88(7) 2 .
C65 C66 C61 120.0 . .
C61 C66 C67 91.0(11) 2 .
C62 C66 C67 11.9(10) 2 .
C66 C66 C67 167.4(10) 2 .
C65 C66 C67 114.2(10) . .
C61 C66 C67 125.8(10) . .
C61 C66 C63 135.5(11) 2 2
C62 C66 C63 56.3(5) 2 2
C66 C66 C63 147.9(3) 2 2
C65 C66 C63 70.0(3) . 2
C61 C66 C63 169.2(6) . 2
C67 C66 C63 44.6(10) . 2
C61 C66 C65 130.8(11) 2 2
C62 C66 C65 149.8(6) 2 2
C66 C66 C65 54.4(4) 2 2
C65 C66 C65 25.1(5) . 2
C61 C66 C65 95.8(5) . 2
C67 C66 C65 138.1(10) . 2
C63 C66 C65 93.5(2) 2 2
C61 C66 C64 176.8(14) 2 2
C62 C66 C64 103.3(7) 2 2
C66 C66 C64 101.0(6) 2 2
C65 C66 C64 24.3(6) . 2
C61 C66 C64 142.0(6) . 2
C67 C66 C64 91.6(9) . 2
C63 C66 C64 47.0(4) 2 2
C65 C66 C64 46.56(17) 2 2
C72 C71 C76 120.0 . .
C73 C72 C71 120.0 . .
C72 C73 C74 120.0 . .
C75 C74 C73 120.0 . .
C74 C75 C76 120.0 . .
C75 C76 C71 120.0 . .
C75 C76 C77 120.9 . .
C71 C76 C77 116.4 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Rh C2 1.869(4) .
Rh C3 1.911(4) .
Rh P2 2.3284(10) .
Rh P1 2.3372(10) .
Rh Zr 2.8925(5) .
Zr C1 2.312(4) .
Zr C12 2.465(4) .
Zr C20 2.474(4) .
Zr C11 2.488(4) .
Zr C16 2.491(4) .
Zr C17 2.504(4) .
Zr C15 2.508(4) .
Zr C13 2.516(4) .
Zr C19 2.530(4) .
Zr C18 2.549(4) .
Zr C14 2.551(4) .
P1 C11 1.806(4) .
P1 C21 1.855(4) .
P1 C31 1.866(4) .
P2 C16 1.808(4) .
P2 C41 1.849(4) .
P2 C51 1.863(4) .
C2 O2 1.155(5) .
C3 O3 1.147(5) .
C11 C15 1.415(5) .
C11 C12 1.426(5) .
C12 C13 1.413(5) .
C13 C14 1.390(6) .
C14 C15 1.410(6) .
C16 C20 1.424(5) .
C16 C17 1.425(5) .
C17 C18 1.405(6) .
C18 C19 1.395(6) .
C19 C20 1.413(6) .
C21 C22 1.524(6) .
C21 C26 1.535(6) .
C22 C23 1.524(7) .
C23 C24 1.509(7) .
C24 C25 1.490(7) .
C25 C26 1.518(6) .
C31 C36 1.458(6) .
C31 C32 1.495(6) .
C32 C33 1.491(6) .
C33 C34 1.438(8) .
C34 C35 1.504(8) .
C35 C36 1.516(6) .
C41 C42 1.532(6) .
C41 C46 1.539(6) .
C42 C43 1.535(6) .
C43 C44 1.532(7) .
C44 C45 1.512(7) .
C45 C46 1.531(6) .
C51 C56 1.476(7) .
C51 C52 1.531(6) .
C52 C53 1.530(7) .
C53 C54 1.456(9) .
C54 C55 1.481(9) .
C55 C56 1.558(8) .
C61 C62 1.3900 .
C61 C66 1.3900 .
C62 C63 1.3900 .
C63 C64 1.3900 .
C64 C65 1.3900 .
C64 C64 1.970(19) 2
C65 C66 1.3900 .
C66 C61 0.955(7) 2
C66 C62 1.204(13) 2
C66 C66 1.259(12) 2
C66 C67 1.426(18) .
C66 C63 1.632(11) 2
C66 C65 1.672(10) 2
C66 C64 1.826(4) 2
C71 C72 1.3900 .
C71 C76 1.3900 .
C72 C73 1.3900 .
C73 C74 1.3900 .
C74 C75 1.3900 .
C75 C76 1.3900 .
C76 C77 1.8120 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C2 Rh Zr C1 -4.40(18) . .
C3 Rh Zr C1 171.7(15) . .
P2 Rh Zr C1 -117.32(13) . .
P1 Rh Zr C1 114.26(13) . .
C2 Rh Zr C12 -140.84(16) . .
C3 Rh Zr C12 35.3(15) . .
P2 Rh Zr C12 106.24(10) . .
P1 Rh Zr C12 -22.18(10) . .
C2 Rh Zr C20 133.04(16) . .
C3 Rh Zr C20 -50.8(15) . .
P2 Rh Zr C20 20.11(10) . .
P1 Rh Zr C20 -108.31(10) . .
C2 Rh Zr C11 -114.88(16) . .
C3 Rh Zr C11 61.3(15) . .
P2 Rh Zr C11 132.20(10) . .
P1 Rh Zr C11 3.78(10) . .
C2 Rh Zr C16 107.97(16) . .
C3 Rh Zr C16 -75.9(15) . .
P2 Rh Zr C16 -4.95(9) . .
P1 Rh Zr C16 -133.37(10) . .
C2 Rh Zr C17 78.79(16) . .
C3 Rh Zr C17 -105.1(15) . .
P2 Rh Zr C17 -34.13(10) . .
P1 Rh Zr C17 -162.55(10) . .
C2 Rh Zr C15 -86.43(16) . .
C3 Rh Zr C15 89.7(15) . .
P2 Rh Zr C15 160.64(10) . .
P1 Rh Zr C15 32.22(10) . .
C2 Rh Zr C13 -129.92(19) . .
C3 Rh Zr C13 46.2(15) . .
P2 Rh Zr C13 117.16(14) . .
P1 Rh Zr C13 -11.26(14) . .
C2 Rh Zr C19 121.30(19) . .
C3 Rh Zr C19 -62.6(15) . .
P2 Rh Zr C19 8.38(14) . .
P1 Rh Zr C19 -120.04(14) . .
C2 Rh Zr C18 81.97(18) . .
C3 Rh Zr C18 -101.9(15) . .
P2 Rh Zr C18 -30.95(13) . .
P1 Rh Zr C18 -159.38(13) . .
C2 Rh Zr C14 -90.62(18) . .
C3 Rh Zr C14 85.5(15) . .
P2 Rh Zr C14 156.46(13) . .
P1 Rh Zr C14 28.03(13) . .
C2 Rh P1 C11 65.02(19) . .
C3 Rh P1 C11 179.03(19) . .
P2 Rh P1 C11 -72.91(14) . .
Zr Rh P1 C11 -5.19(13) . .
C2 Rh P1 C21 177.2(2) . .
C3 Rh P1 C21 -68.8(2) . .
P2 Rh P1 C21 39.25(16) . .
Zr Rh P1 C21 106.97(16) . .
C2 Rh P1 C31 -53.7(2) . .
C3 Rh P1 C31 60.3(2) . .
P2 Rh P1 C31 168.40(18) . .
Zr Rh P1 C31 -123.88(18) . .
C2 Rh P2 C16 -65.00(18) . .
C3 Rh P2 C16 -177.90(18) . .
P1 Rh P2 C16 74.85(14) . .
Zr Rh P2 C16 6.85(13) . .
C2 Rh P2 C41 -178.8(2) . .
C3 Rh P2 C41 68.3(2) . .
P1 Rh P2 C41 -38.95(17) . .
Zr Rh P2 C41 -106.95(16) . .
C2 Rh P2 C51 48.0(2) . .
C3 Rh P2 C51 -64.9(2) . .
P1 Rh P2 C51 -172.11(18) . .
Zr Rh P2 C51 119.89(18) . .
C3 Rh C2 O2 11(3) . .
P2 Rh C2 O2 -96(2) . .
P1 Rh C2 O2 120(2) . .
Zr Rh C2 O2 -169(2) . .
C2 Rh C3 O3 94(41) . .
P2 Rh C3 O3 -152(41) . .
P1 Rh C3 O3 -26(41) . .
Zr Rh C3 O3 -82(42) . .
C21 P1 C11 C15 162.5(3) . .
C31 P1 C11 C15 53.9(4) . .
Rh P1 C11 C15 -72.8(3) . .
C21 P1 C11 C12 -42.3(4) . .
C31 P1 C11 C12 -150.9(3) . .
Rh P1 C11 C12 82.4(3) . .
C21 P1 C11 Zr -118.68(17) . .
C31 P1 C11 Zr 132.67(18) . .
Rh P1 C11 Zr 6.05(15) . .
C1 Zr C11 C15 15.4(3) . .
C12 Zr C11 C15 -113.3(3) . .
C20 Zr C11 C15 -149.4(2) . .
C16 Zr C11 C15 175.7(2) . .
C17 Zr C11 C15 165.0(4) . .
C13 Zr C11 C15 -75.8(3) . .
C19 Zr C11 C15 -114.3(3) . .
C18 Zr C11 C15 -97.5(4) . .
C14 Zr C11 C15 -36.4(2) . .
Rh Zr C11 C15 118.8(2) . .
C1 Zr C11 C12 128.7(2) . .
C20 Zr C11 C12 -36.0(3) . .
C16 Zr C11 C12 -71.0(3) . .
C17 Zr C11 C12 -81.7(5) . .
C15 Zr C11 C12 113.3(3) . .
C13 Zr C11 C12 37.5(2) . .
C19 Zr C11 C12 -1.0(3) . .
C18 Zr C11 C12 15.8(4) . .
C14 Zr C11 C12 76.9(3) . .
Rh Zr C11 C12 -127.9(2) . .
C1 Zr C11 P1 -108.35(19) . .
C12 Zr C11 P1 123.0(3) . .
C20 Zr C11 P1 86.94(18) . .
C16 Zr C11 P1 52.0(2) . .
C17 Zr C11 P1 41.3(5) . .
C15 Zr C11 P1 -123.7(3) . .
C13 Zr C11 P1 160.5(2) . .
C19 Zr C11 P1 122.03(17) . .
C18 Zr C11 P1 138.8(3) . .
C14 Zr C11 P1 -160.1(2) . .
Rh Zr C11 P1 -4.90(12) . .
C15 C11 C12 C13 -1.4(4) . .
P1 C11 C12 C13 -160.5(3) . .
Zr C11 C12 C13 -68.5(3) . .
C15 C11 C12 Zr 67.1(3) . .
P1 C11 C12 Zr -92.0(3) . .
C1 Zr C12 C13 43.6(3) . .
C20 Zr C12 C13 -98.9(3) . .
C11 Zr C12 C13 114.0(4) . .
C16 Zr C12 C13 -119.3(3) . .
C17 Zr C12 C13 -96.1(3) . .
C15 Zr C12 C13 76.1(3) . .
C19 Zr C12 C13 -66.8(3) . .
C18 Zr C12 C13 -58.4(3) . .
C14 Zr C12 C13 35.9(2) . .
Rh Zr C12 C13 164.0(2) . .
C1 Zr C12 C11 -70.3(3) . .
C20 Zr C12 C11 147.1(2) . .
C16 Zr C12 C11 126.7(2) . .
C17 Zr C12 C11 150.0(2) . .
C15 Zr C12 C11 -37.8(2) . .
C13 Zr C12 C11 -114.0(4) . .
C19 Zr C12 C11 179.2(2) . .
C18 Zr C12 C11 -172.4(2) . .
C14 Zr C12 C11 -78.0(3) . .
Rh Zr C12 C11 50.0(2) . .
C11 C12 C13 C14 0.7(4) . .
Zr C12 C13 C14 -66.9(3) . .
C11 C12 C13 Zr 67.6(3) . .
C1 Zr C13 C14 -31.5(3) . .
C12 Zr C13 C14 115.8(4) . .
C20 Zr C13 C14 -164.2(3) . .
C11 Zr C13 C14 77.7(3) . .
C16 Zr C13 C14 -166.5(2) . .
C17 Zr C13 C14 -125.2(3) . .
C15 Zr C13 C14 36.8(2) . .
C19 Zr C13 C14 -133.3(3) . .
C18 Zr C13 C14 -111.2(3) . .
Rh Zr C13 C14 95.6(2) . .
C1 Zr C13 C12 -147.3(3) . .
C20 Zr C13 C12 80.0(3) . .
C11 Zr C13 C12 -38.2(2) . .
C16 Zr C13 C12 77.6(3) . .
C17 Zr C13 C12 119.0(3) . .
C15 Zr C13 C12 -79.1(3) . .
C19 Zr C13 C12 110.9(3) . .
C18 Zr C13 C12 133.0(2) . .
C14 Zr C13 C12 -115.8(4) . .
Rh Zr C13 C12 -20.3(3) . .
C12 C13 C14 C15 0.3(5) . .
Zr C13 C14 C15 -64.1(3) . .
C12 C13 C14 Zr 64.3(3) . .
C1 Zr C14 C13 148.7(3) . .
C12 Zr C14 C13 -37.2(2) . .
C20 Zr C14 C13 18.6(3) . .
C11 Zr C14 C13 -78.9(3) . .
C16 Zr C14 C13 26.4(4) . .
C17 Zr C14 C13 89.7(3) . .
C15 Zr C14 C13 -115.9(4) . .
C19 Zr C14 C13 46.9(3) . .
C18 Zr C14 C13 78.6(3) . .
Rh Zr C14 C13 -108.1(2) . .
C1 Zr C14 C15 -95.3(3) . .
C12 Zr C14 C15 78.7(3) . .
C20 Zr C14 C15 134.5(3) . .
C11 Zr C14 C15 37.1(2) . .
C16 Zr C14 C15 142.4(3) . .
C17 Zr C14 C15 -154.4(3) . .
C13 Zr C14 C15 115.9(4) . .
C19 Zr C14 C15 162.9(3) . .
C18 Zr C14 C15 -165.5(2) . .
Rh Zr C14 C15 7.8(3) . .
C13 C14 C15 C11 -1.2(5) . .
Zr C14 C15 C11 -65.6(3) . .
C13 C14 C15 Zr 64.4(3) . .
C12 C11 C15 C14 1.6(4) . .
P1 C11 C15 C14 160.5(3) . .
Zr C11 C15 C14 67.4(3) . .
C12 C11 C15 Zr -65.8(2) . .
P1 C11 C15 Zr 93.1(3) . .
C1 Zr C15 C14 78.5(3) . .
C12 Zr C15 C14 -77.2(3) . .
C20 Zr C15 C14 -69.5(3) . .
C11 Zr C15 C14 -115.7(4) . .
C16 Zr C15 C14 -126.1(4) . .
C17 Zr C15 C14 83.2(6) . .
C13 Zr C15 C14 -36.1(2) . .
C19 Zr C15 C14 -22.9(3) . .
C18 Zr C15 C14 22.5(4) . .
Rh Zr C15 C14 -173.5(2) . .
C1 Zr C15 C11 -165.8(3) . .
C12 Zr C15 C11 38.5(2) . .
C20 Zr C15 C11 46.2(3) . .
C16 Zr C15 C11 -10.4(5) . .
C17 Zr C15 C11 -161.1(5) . .
C13 Zr C15 C11 79.5(3) . .
C19 Zr C15 C11 92.8(3) . .
C18 Zr C15 C11 138.2(3) . .
C14 Zr C15 C11 115.7(4) . .
Rh Zr C15 C11 -57.8(2) . .
C41 P2 C16 C20 41.9(4) . .
C51 P2 C16 C20 155.7(3) . .
Rh P2 C16 C20 -83.8(3) . .
C41 P2 C16 C17 -164.8(3) . .
C51 P2 C16 C17 -51.0(4) . .
Rh P2 C16 C17 69.5(3) . .
C41 P2 C16 Zr 117.76(17) . .
C51 P2 C16 Zr -128.41(19) . .
Rh P2 C16 Zr -7.92(15) . .
C1 Zr C16 C20 -126.5(2) . .
C12 Zr C16 C20 39.2(3) . .
C11 Zr C16 C20 73.5(3) . .
C17 Zr C16 C20 -112.9(3) . .
C15 Zr C16 C20 80.7(5) . .
C13 Zr C16 C20 4.3(3) . .
C19 Zr C16 C20 -37.1(2) . .
C18 Zr C16 C20 -76.5(3) . .
C14 Zr C16 C20 -12.2(4) . .
Rh Zr C16 C20 130.2(2) . .
C1 Zr C16 C17 -13.6(3) . .
C12 Zr C16 C17 152.1(2) . .
C20 Zr C16 C17 112.9(3) . .
C11 Zr C16 C17 -173.6(2) . .
C15 Zr C16 C17 -166.4(4) . .
C13 Zr C16 C17 117.2(2) . .
C19 Zr C16 C17 75.8(3) . .
C18 Zr C16 C17 36.4(2) . .
C14 Zr C16 C17 100.7(4) . .
Rh Zr C16 C17 -117.0(2) . .
C1 Zr C16 P2 109.70(19) . .
C12 Zr C16 P2 -84.56(18) . .
C20 Zr C16 P2 -123.8(3) . .
C11 Zr C16 P2 -50.3(2) . .
C17 Zr C16 P2 123.3(3) . .
C15 Zr C16 P2 -43.1(5) . .
C13 Zr C16 P2 -119.52(17) . .
C19 Zr C16 P2 -160.9(2) . .
C18 Zr C16 P2 159.7(2) . .
C14 Zr C16 P2 -136.0(3) . .
Rh Zr C16 P2 6.35(12) . .
C20 C16 C17 C18 -1.5(4) . .
P2 C16 C17 C18 -159.1(3) . .
Zr C16 C17 C18 -67.7(3) . .
C20 C16 C17 Zr 66.1(3) . .
P2 C16 C17 Zr -91.4(3) . .
C1 Zr C17 C18 -76.9(3) . .
C12 Zr C17 C18 73.4(3) . .
C20 Zr C17 C18 76.9(3) . .
C11 Zr C17 C18 130.8(4) . .
C16 Zr C17 C18 115.4(3) . .
C15 Zr C17 C18 -81.6(6) . .
C13 Zr C17 C18 26.1(3) . .
C19 Zr C17 C18 36.1(2) . .
C14 Zr C17 C18 -19.6(4) . .
Rh Zr C17 C18 175.0(2) . .
C1 Zr C17 C16 167.6(3) . .
C12 Zr C17 C16 -42.0(3) . .
C20 Zr C17 C16 -38.5(2) . .
C11 Zr C17 C16 15.4(5) . .
C15 Zr C17 C16 163.0(5) . .
C13 Zr C17 C16 -89.3(3) . .
C19 Zr C17 C16 -79.4(3) . .
C18 Zr C17 C16 -115.4(3) . .
C14 Zr C17 C16 -135.0(3) . .
Rh Zr C17 C16 59.6(2) . .
C16 C17 C18 C19 1.0(4) . .
Zr C17 C18 C19 -64.8(3) . .
C16 C17 C18 Zr 65.9(3) . .
C1 Zr C18 C19 -146.4(3) . .
C12 Zr C18 C19 -16.0(3) . .
C20 Zr C18 C19 37.3(2) . .
C11 Zr C18 C19 -26.4(5) . .
C16 Zr C18 C19 78.8(3) . .
C17 Zr C18 C19 116.2(4) . .
C15 Zr C18 C19 -89.1(3) . .
C13 Zr C18 C19 -44.4(3) . .
C14 Zr C18 C19 -76.4(3) . .
Rh Zr C18 C19 110.2(2) . .
C1 Zr C18 C17 97.4(3) . .
C12 Zr C18 C17 -132.2(2) . .
C20 Zr C18 C17 -78.9(3) . .
C11 Zr C18 C17 -142.6(3) . .
C16 Zr C18 C17 -37.4(2) . .
C15 Zr C18 C17 154.7(3) . .
C13 Zr C18 C17 -160.6(2) . .
C19 Zr C18 C17 -116.2(4) . .
C14 Zr C18 C17 167.4(2) . .
Rh Zr C18 C17 -6.0(3) . .
C17 C18 C19 C20 -0.1(5) . .
Zr C18 C19 C20 -64.2(3) . .
C17 C18 C19 Zr 64.1(3) . .
C1 Zr C19 C18 33.7(3) . .
C12 Zr C19 C18 166.6(3) . .
C20 Zr C19 C18 -115.4(4) . .
C11 Zr C19 C18 167.1(2) . .
C16 Zr C19 C18 -77.7(3) . .
C17 Zr C19 C18 -36.5(2) . .
C15 Zr C19 C18 125.3(3) . .
C13 Zr C19 C18 136.1(3) . .
C14 Zr C19 C18 113.0(3) . .
Rh Zr C19 C18 -93.6(3) . .
C1 Zr C19 C20 149.2(3) . .
C12 Zr C19 C20 -77.9(3) . .
C11 Zr C19 C20 -77.4(3) . .
C16 Zr C19 C20 37.7(2) . .
C17 Zr C19 C20 78.9(3) . .
C15 Zr C19 C20 -119.3(3) . .
C13 Zr C19 C20 -108.5(3) . .
C18 Zr C19 C20 115.4(4) . .
C14 Zr C19 C20 -131.6(3) . .
Rh Zr C19 C20 21.9(3) . .
C18 C19 C20 C16 -0.8(5) . .
Zr C19 C20 C16 -67.3(3) . .
C18 C19 C20 Zr 66.4(3) . .
C17 C16 C20 C19 1.4(4) . .
P2 C16 C20 C19 158.9(3) . .
Zr C16 C20 C19 68.5(3) . .
C17 C16 C20 Zr -67.0(3) . .
P2 C16 C20 Zr 90.4(3) . .
C1 Zr C20 C19 -41.1(3) . .
C12 Zr C20 C19 101.4(3) . .
C11 Zr C20 C19 120.3(3) . .
C16 Zr C20 C19 -114.7(4) . .
C17 Zr C20 C19 -76.4(3) . .
C15 Zr C20 C19 95.1(3) . .
C13 Zr C20 C19 68.9(3) . .
C18 Zr C20 C19 -36.3(2) . .
C14 Zr C20 C19 59.2(3) . .
Rh Zr C20 C19 -162.9(2) . .
C1 Zr C20 C16 73.6(3) . .
C12 Zr C20 C16 -144.0(2) . .
C11 Zr C20 C16 -125.0(2) . .
C17 Zr C20 C16 38.3(2) . .
C15 Zr C20 C16 -150.2(2) . .
C13 Zr C20 C16 -176.5(2) . .
C19 Zr C20 C16 114.7(4) . .
C18 Zr C20 C16 78.4(3) . .
C14 Zr C20 C16 173.9(2) . .
Rh Zr C20 C16 -48.2(2) . .
C11 P1 C21 C22 177.3(3) . .
C31 P1 C21 C22 -72.0(4) . .
Rh P1 C21 C22 63.5(4) . .
C11 P1 C21 C26 -54.0(3) . .
C31 P1 C21 C26 56.7(4) . .
Rh P1 C21 C26 -167.8(3) . .
C26 C21 C22 C23 54.2(6) . .
P1 C21 C22 C23 -174.0(4) . .
C21 C22 C23 C24 -53.2(7) . .
C22 C23 C24 C25 53.4(7) . .
C23 C24 C25 C26 -55.0(6) . .
C24 C25 C26 C21 57.1(6) . .
C22 C21 C26 C25 -56.4(5) . .
P1 C21 C26 C25 173.2(3) . .
C11 P1 C31 C36 -116.9(4) . .
C21 P1 C31 C36 136.4(4) . .
Rh P1 C31 C36 0.5(5) . .
C11 P1 C31 C32 24.1(4) . .
C21 P1 C31 C32 -82.6(4) . .
Rh P1 C31 C32 141.4(3) . .
C36 C31 C32 C33 -44.0(7) . .
P1 C31 C32 C33 174.9(4) . .
C31 C32 C33 C34 43.7(7) . .
C32 C33 C34 C35 -43.4(9) . .
C33 C34 C35 C36 41.9(8) . .
C32 C31 C36 C35 44.2(8) . .
P1 C31 C36 C35 -173.5(4) . .
C34 C35 C36 C31 -42.4(8) . .
C16 P2 C41 C42 56.3(4) . .
C51 P2 C41 C42 -52.9(4) . .
Rh P2 C41 C42 171.9(3) . .
C16 P2 C41 C46 -174.1(3) . .
C51 P2 C41 C46 76.7(4) . .
Rh P2 C41 C46 -58.5(4) . .
C46 C41 C42 C43 58.4(5) . .
P2 C41 C42 C43 -170.4(3) . .
C41 C42 C43 C44 -58.3(6) . .
C42 C43 C44 C45 56.6(6) . .
C43 C44 C45 C46 -56.5(6) . .
C44 C45 C46 C41 57.0(6) . .
C42 C41 C46 C45 -57.1(6) . .
P2 C41 C46 C45 169.1(4) . .
C16 P2 C51 C56 -43.3(5) . .
C41 P2 C51 C56 64.8(5) . .
Rh P2 C51 C56 -157.5(4) . .
C16 P2 C51 C52 175.8(3) . .
C41 P2 C51 C52 -76.1(4) . .
Rh P2 C51 C52 61.6(4) . .
C56 C51 C52 C53 47.2(7) . .
P2 C51 C52 C53 -169.8(4) . .
C51 C52 C53 C54 -45.8(8) . .
C52 C53 C54 C55 50.4(9) . .
C53 C54 C55 C56 -53.9(9) . .
C52 C51 C56 C55 -50.9(7) . .
P2 C51 C56 C55 169.0(4) . .
C54 C55 C56 C51 53.9(8) . .
C66 C61 C62 C63 0.0 . .
C61 C62 C63 C64 0.0 . .
C62 C63 C64 C65 0.0 . .
C62 C63 C64 C64 -11.8(14) . 2
C63 C64 C65 C66 0.0 . .
C64 C64 C65 C66 155(3) 2 .
C64 C65 C66 C61 23(3) . 2
C64 C65 C66 C62 174.0(16) . 2
C64 C65 C66 C66 1.0(7) . 2
C64 C65 C66 C61 0.0 . .
C64 C65 C66 C67 178.7(9) . .
C64 C65 C66 C63 -175.4(12) . 2
C64 C65 C66 C65 -16.7(17) . 2
C64 C65 C66 C64 -159(3) . 2
C62 C61 C66 C61 -162(2) . 2
C62 C61 C66 C62 -174.7(14) . 2
C62 C61 C66 C66 -1.4(10) . 2
C62 C61 C66 C65 0.0 . .
C62 C61 C66 C67 -178.5(10) . .
C62 C61 C66 C63 156(6) . 2
C62 C61 C66 C65 7.0(7) . 2
C62 C61 C66 C64 14.2(17) . 2
C76 C71 C72 C73 0.0 . .
C71 C72 C73 C74 0.0 . .
C72 C73 C74 C75 0.0 . .
C73 C74 C75 C76 0.0 . .
C74 C75 C76 C71 0.0 . .
C74 C75 C76 C77 -160.5 . .
C72 C71 C76 C75 0.0 . .
C72 C71 C76 C77 161.3 . .
