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#$Date: 2016-03-21 06:28:09 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178512 $
#$URL: svn://www.crystallography.net/cod/cif/4/06/15/4061564.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4061564
_journal_name_full               Organometallics
_journal_paper_doi               10.1021/om0503489
_journal_year                    2005
_chemical_formula_sum            'C57 H57 B F24 O P3 Rh'
_chemical_formula_weight         1420.66
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 90.30(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   12.786(3)
_cell_length_b                   26.238(5)
_cell_length_c                   17.885(4)
_cell_measurement_temperature    150(2)
_cell_volume                     6000(2)
_diffrn_ambient_temperature      150(2)
_exptl_crystal_density_diffrn    1.573
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               4061564
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1 Rh 0.63594(3) 0.157790(12) 0.772384(18) 0.03300(13) Uani 1 1 d . . .
P1 P 0.70329(14) 0.05630(6) 0.74628(9) 0.0290(4) Uani 0.645(3) 1 d P A 1
H1 H 0.6375 0.0365 0.7543 0.035 Uiso 0.645(3) 1 calc PR A 1
P1A P 0.6175(3) 0.06418(13) 0.74506(18) 0.0389(10) Uani 0.355(3) 1 d P A 2
P2 P 0.80792(14) 0.14247(7) 0.83807(9) 0.0340(5) Uani 0.645(3) 1 d P A 1
P2A P 0.8283(3) 0.10872(12) 0.79646(17) 0.0355(9) Uani 0.355(3) 1 d P A 2
H2A H 0.8587 0.1220 0.8443 0.043 Uiso 0.355(3) 1 calc PR A 2
P3 P 0.75025(10) 0.15342(4) 0.66030(6) 0.0360(3) Uani 1 1 d . A .
F1 F 0.9607(3) -0.1146(3) 0.5654(2) 0.0642(14) Uani 0.913(11) 1 d P B 1
F2 F 1.0584(3) -0.0995(2) 0.4723(3) 0.086(2) Uani 0.913(11) 1 d P B 1
F3 F 0.9869(3) -0.17146(19) 0.4838(3) 0.0726(18) Uani 0.913(11) 1 d P B 1
F4 F 1.2775(5) -0.2839(3) 0.5065(5) 0.086(3) Uani 0.731(15) 1 d PU C 1
F5 F 1.4275(5) -0.2422(2) 0.5296(4) 0.0647(18) Uani 0.731(15) 1 d P C 1
F6 F 1.3482(5) -0.28739(18) 0.6133(4) 0.0700(18) Uani 0.731(15) 1 d P C 1
F7 F 1.6763(6) -0.0682(2) 0.6107(4) 0.096(2) Uani 0.737(8) 1 d PU D 1
F7A F 1.6287(10) -0.0942(6) 0.5875(7) 0.061(4) Uiso 0.263(8) 1 d P D 2
F8 F 1.7683(3) -0.1243(3) 0.6671(3) 0.0801(18) Uani 0.737(8) 1 d PU D 1
F8A F 1.7389(10) -0.0658(5) 0.6613(8) 0.061(4) Uiso 0.263(8) 1 d P D 2
F9 F 1.6473(4) -0.1454(2) 0.5961(2) 0.0756(19) Uani 0.737(8) 1 d P D 1
F9A F 1.7296(14) -0.1462(6) 0.6439(9) 0.072(5) Uiso 0.263(8) 1 d P D 2
F10 F 1.7024(3) -0.1113(5) 0.9328(2) 0.072(2) Uani 0.92(2) 1 d P E 1
F11 F 1.5537(4) -0.0857(3) 0.9684(2) 0.0494(13) Uani 0.92(2) 1 d P E 1
F12 F 1.5791(8) -0.16506(15) 0.9500(2) 0.067(2) Uani 0.92(2) 1 d P E 1
F13 F 1.3501(5) -0.2394(2) 0.9634(4) 0.111(3) Uani 0.798(11) 1 d P F 1
F14 F 1.2737(7) -0.2873(2) 0.8859(4) 0.091(2) Uani 0.798(11) 1 d P F 1
F15 F 1.2005(5) -0.2672(3) 0.9920(4) 0.105(3) Uani 0.798(11) 1 d PU F 1
F16 F 0.9368(5) -0.0828(2) 0.8799(5) 0.104(3) Uani 0.724(10) 1 d PU G 1
F17 F 0.8845(3) -0.1598(3) 0.8693(4) 0.101(3) Uani 0.724(10) 1 d P G 1
F18 F 0.9386(7) -0.1294(3) 0.9742(5) 0.093(3) Uani 0.724(10) 1 d P G 1
F19 F 1.1799(7) 0.10776(17) 0.8673(3) 0.101(2) Uani 0.787(9) 1 d PU H 1
F19A F 1.1042(14) 0.0881(7) 0.8699(9) 0.064(5) Uiso 0.213(9) 1 d P H 2
F20 F 1.1301(6) 0.0381(2) 0.9143(3) 0.105(3) Uani 0.787(9) 1 d P H 1
F20A F 1.2084(18) 0.0392(7) 0.9301(10) 0.063(5) Uiso 0.213(9) 1 d P H 2
F21 F 1.2862(6) 0.0566(3) 0.9194(3) 0.125(3) Uani 0.787(9) 1 d P H 1
F21A F 1.2703(13) 0.1032(6) 0.8826(9) 0.060(5) Uiso 0.213(9) 1 d P H 2
F22 F 1.1477(7) 0.0332(2) 0.5494(3) 0.105(3) Uani 0.642(8) 1 d PU I 1
F22A F 1.1260(11) 0.0778(6) 0.5913(8) 0.095(5) Uiso 0.358(8) 1 d P I 2
F23 F 1.2955(7) 0.0609(4) 0.5531(4) 0.113(3) Uani 0.642(8) 1 d PU I 1
F23A F 1.2436(7) 0.0364(3) 0.5411(4) 0.040(2) Uiso 0.358(8) 1 d P I 2
F24 F 1.1673(6) 0.10362(19) 0.5989(3) 0.077(2) Uani 0.642(8) 1 d P I 1
F24A F 1.2855(8) 0.1026(4) 0.5952(6) 0.069(3) Uiso 0.358(8) 1 d P I 2
O1 O 0.7859(4) 0.01402(17) 0.7250(3) 0.0406(12) Uani 0.645(3) 1 d PD A 1
O1A O 0.9162(7) 0.0696(4) 0.7713(5) 0.051(2) Uani 0.355(3) 1 d P A 2
C1 C 0.7181(4) 0.08761(17) 0.8242(3) 0.0431(11) Uani 1 1 d . A .
C2 C 0.8179(3) 0.16447(16) 0.7442(2) 0.0356(10) Uani 1 1 d . A .
C3 C 0.6684(4) 0.10058(17) 0.6733(2) 0.0384(10) Uani 1 1 d . A .
C4 C 0.7020(5) 0.05760(19) 0.8999(3) 0.0551(14) Uani 1 1 d . . .
C5 C 0.5927(5) 0.0339(2) 0.9053(3) 0.0642(17) Uani 1 1 d . A .
H5A H 0.5864 0.0156 0.9528 0.096 Uiso 1 1 calc R . .
H5B H 0.5822 0.0100 0.8637 0.096 Uiso 1 1 calc R . .
H5C H 0.5398 0.0608 0.9027 0.096 Uiso 1 1 calc R . .
C6 C 0.7216(5) 0.0906(2) 0.9687(3) 0.0671(17) Uani 1 1 d . A .
H6A H 0.6761 0.1206 0.9668 0.101 Uiso 1 1 calc R . .
H6B H 0.7949 0.1015 0.9696 0.101 Uiso 1 1 calc R . .
H6C H 0.7064 0.0709 1.0139 0.101 Uiso 1 1 calc R . .
C7 C 0.7836(6) 0.0136(2) 0.8998(4) 0.088(2) Uani 1 1 d . A .
H7A H 0.8542 0.0279 0.8974 0.131 Uiso 1 1 calc R . .
H7B H 0.7714 -0.0084 0.8563 0.131 Uiso 1 1 calc R . .
H7C H 0.7764 -0.0065 0.9457 0.131 Uiso 1 1 calc R . .
C8 C 0.8991(4) 0.20910(18) 0.7423(3) 0.0430(11) Uani 1 1 d . . .
C9 C 0.8818(5) 0.2459(2) 0.6772(4) 0.0701(18) Uani 1 1 d . A .
H9A H 0.9333 0.2735 0.6800 0.105 Uiso 1 1 calc R . .
H9B H 0.8112 0.2603 0.6801 0.105 Uiso 1 1 calc R . .
H9C H 0.8897 0.2276 0.6298 0.105 Uiso 1 1 calc R . .
C10 C 1.0071(4) 0.1843(2) 0.7315(3) 0.0598(15) Uani 1 1 d . A .
H10A H 1.0072 0.1649 0.6847 0.090 Uiso 1 1 calc R . .
H10B H 1.0219 0.1614 0.7734 0.090 Uiso 1 1 calc R . .
H10C H 1.0608 0.2109 0.7293 0.090 Uiso 1 1 calc R . .
C11 C 0.9025(5) 0.2394(3) 0.8154(3) 0.0716(18) Uani 1 1 d . A .
H11A H 0.9192 0.2164 0.8570 0.107 Uiso 1 1 calc R . .
H11B H 0.8343 0.2553 0.8240 0.107 Uiso 1 1 calc R . .
H11C H 0.9563 0.2659 0.8121 0.107 Uiso 1 1 calc R . .
C12 C 0.6055(4) 0.0837(2) 0.6027(3) 0.0506(13) Uani 1 1 d . . .
C13 C 0.6794(5) 0.0557(2) 0.5498(3) 0.0596(15) Uani 1 1 d . A .
H13A H 0.6405 0.0445 0.5054 0.089 Uiso 1 1 calc R . .
H13B H 0.7092 0.0260 0.5753 0.089 Uiso 1 1 calc R . .
H13C H 0.7358 0.0788 0.5347 0.089 Uiso 1 1 calc R . .
C14 C 0.5604(5) 0.1289(2) 0.5618(4) 0.0737(18) Uani 1 1 d . A .
H14A H 0.6167 0.1527 0.5493 0.111 Uiso 1 1 calc R . .
H14B H 0.5094 0.1461 0.5939 0.111 Uiso 1 1 calc R . .
H14C H 0.5258 0.1174 0.5159 0.111 Uiso 1 1 calc R . .
C15 C 0.5184(5) 0.0456(3) 0.6236(4) 0.083(2) Uani 1 1 d . A .
H15A H 0.4722 0.0612 0.6607 0.125 Uiso 1 1 calc R . .
H15B H 0.5499 0.0147 0.6446 0.125 Uiso 1 1 calc R . .
H15C H 0.4778 0.0368 0.5788 0.125 Uiso 1 1 calc R . .
C16 C 0.8999(9) 0.0353(5) 0.6997(6) 0.067(4) Uani 0.645(3) 1 d P A 1
H16A H 0.8956 0.0568 0.6543 0.080 Uiso 0.645(3) 1 calc PR A 1
H16B H 0.9356 0.0543 0.7403 0.080 Uiso 0.645(3) 1 calc PR A 1
C16A C 0.8982(15) 0.0250(7) 0.7206(9) 0.031(4) Uiso 0.355(3) 1 d P A 2
H16C H 0.8264 0.0128 0.7306 0.038 Uiso 0.355(3) 1 calc PR A 2
H16D H 0.8977 0.0386 0.6689 0.038 Uiso 0.355(3) 1 calc PR A 2
C17 C 0.9519(10) -0.0168(5) 0.6843(9) 0.087(4) Uani 0.645(3) 1 d PDU A 1
H17A H 0.9355 -0.0404 0.7249 0.131 Uiso 0.645(3) 1 calc PR A 1
H17B H 1.0279 -0.0124 0.6811 0.131 Uiso 0.645(3) 1 calc PR A 1
H17C H 0.9254 -0.0306 0.6369 0.131 Uiso 0.645(3) 1 calc PR A 1
C17A C 0.9571(16) -0.0145(7) 0.7198(10) 0.052(4) Uiso 0.355(3) 1 d P A 2
H17D H 0.9453 -0.0346 0.7652 0.079 Uiso 0.355(3) 1 calc PR A 2
H17E H 1.0305 -0.0039 0.7179 0.079 Uiso 0.355(3) 1 calc PR A 2
H17F H 0.9404 -0.0353 0.6758 0.079 Uiso 0.355(3) 1 calc PR A 2
C18 C 0.5268(11) 0.1667(5) 0.8630(12) 0.046(5) Uani 0.645(3) 1 d PD A 1
H18 H 0.5758 0.1488 0.8933 0.055 Uiso 0.645(3) 1 calc PR A 1
C18A C 0.6156(10) 0.2030(5) 0.8685(7) 0.041(3) Uiso 0.355(3) 1 d PD A 2
H18A H 0.6859 0.1922 0.8757 0.050 Uiso 0.355(3) 1 calc PR A 2
C19 C 0.4814(5) 0.1411(3) 0.8023(4) 0.0408(17) Uani 0.645(3) 1 d PD A 1
H19 H 0.4998 0.1064 0.7947 0.049 Uiso 0.645(3) 1 calc PR A 1
C19A C 0.5351(18) 0.1671(12) 0.873(3) 0.054(11) Uiso 0.355(3) 1 d PD A 2
H19A H 0.5539 0.1329 0.8838 0.065 Uiso 0.355(3) 1 calc PR A 2
C20 C 0.4054(7) 0.1652(3) 0.7486(7) 0.065(3) Uani 0.645(3) 1 d PD A 1
H20A H 0.3377 0.1700 0.7742 0.079 Uiso 0.645(3) 1 calc PR A 1
H20B H 0.3936 0.1416 0.7062 0.079 Uiso 0.645(3) 1 calc PR A 1
C20A C 0.4220(13) 0.1784(7) 0.8612(9) 0.066(4) Uiso 0.355(3) 1 d PD A 2
H20C H 0.4050 0.2106 0.8872 0.079 Uiso 0.355(3) 1 calc PR A 2
H20D H 0.3805 0.1510 0.8848 0.079 Uiso 0.355(3) 1 calc PR A 2
C21 C 0.4423(6) 0.2167(3) 0.7179(5) 0.054(2) Uani 0.645(3) 1 d PD A 1
H21A H 0.4164 0.2205 0.6659 0.065 Uiso 0.645(3) 1 calc PR A 1
H21B H 0.4109 0.2443 0.7482 0.065 Uiso 0.645(3) 1 calc PR A 1
C21A C 0.3889(17) 0.1831(11) 0.7808(11) 0.098(9) Uiso 0.355(3) 1 d PD A 2
H21C H 0.3442 0.1535 0.7679 0.117 Uiso 0.355(3) 1 calc PR A 2
H21D H 0.3458 0.2142 0.7752 0.117 Uiso 0.355(3) 1 calc PR A 2
C22 C 0.5572(9) 0.2226(4) 0.7186(7) 0.043(5) Uani 0.645(3) 1 d PD A 1
H22 H 0.5921 0.2116 0.6747 0.051 Uiso 0.645(3) 1 calc PR A 1
C22A C 0.4770(12) 0.1856(7) 0.7267(8) 0.053(4) Uiso 0.355(3) 1 d PD A 2
H22A H 0.4833 0.1577 0.6931 0.063 Uiso 0.355(3) 1 calc PR A 2
C23 C 0.6203(5) 0.2419(2) 0.7743(4) 0.0376(16) Uani 0.645(3) 1 d PD A 1
H23 H 0.6931 0.2448 0.7647 0.045 Uiso 0.645(3) 1 calc PR A 1
C23A C 0.552(3) 0.2245(12) 0.720(2) 0.092(18) Uiso 0.355(3) 1 d PD A 2
H23A H 0.6023 0.2243 0.6808 0.110 Uiso 0.355(3) 1 calc PR A 2
C24 C 0.5812(12) 0.2588(3) 0.8494(5) 0.045(3) Uani 0.645(3) 1 d PD A 1
H24A H 0.5480 0.2928 0.8443 0.054 Uiso 0.645(3) 1 calc PR A 1
H24B H 0.6412 0.2622 0.8842 0.054 Uiso 0.645(3) 1 calc PR A 1
C24A C 0.548(2) 0.2665(9) 0.7770(13) 0.098(7) Uiso 0.355(3) 1 d PD A 2
H24C H 0.5827 0.2967 0.7553 0.118 Uiso 0.355(3) 1 calc PR A 2
H24D H 0.4731 0.2757 0.7838 0.118 Uiso 0.355(3) 1 calc PR A 2
C25 C 0.5016(7) 0.2213(3) 0.8826(5) 0.056(2) Uani 0.645(3) 1 d PD A 1
H25A H 0.5009 0.2251 0.9376 0.068 Uiso 0.645(3) 1 calc PR A 1
H25B H 0.4308 0.2298 0.8635 0.068 Uiso 0.645(3) 1 calc PR A 1
C25A C 0.593(4) 0.2580(10) 0.8529(19) 0.120(17) Uiso 0.355(3) 1 d PD A 2
H25C H 0.5443 0.2711 0.8910 0.144 Uiso 0.355(3) 1 calc PR A 2
H25D H 0.6593 0.2776 0.8574 0.144 Uiso 0.355(3) 1 calc PR A 2
C26 C 1.2550(3) -0.13749(14) 0.6649(2) 0.0224(7) Uani 1 1 d . . .
C27 C 1.1632(3) -0.12477(15) 0.6259(2) 0.0275(8) Uani 1 1 d . . .
H27 H 1.1241 -0.0961 0.6420 0.033 Uiso 1 1 calc R . .
C28 C 1.1273(3) -0.15232(15) 0.5650(2) 0.0275(8) Uani 1 1 d . B .
C29 C 1.1808(3) -0.19527(15) 0.5404(2) 0.0292(9) Uani 1 1 d . . .
H29 H 1.1565 -0.2143 0.4986 0.035 Uiso 1 1 calc R . .
C30 C 1.2701(3) -0.20950(15) 0.5785(2) 0.0299(9) Uani 1 1 d . C .
C31 C 1.3060(3) -0.18123(15) 0.6393(2) 0.0269(8) Uani 1 1 d . . .
H31 H 1.3677 -0.1921 0.6644 0.032 Uiso 1 1 calc R . .
C32 C 1.0331(3) -0.13397(18) 0.5227(2) 0.0377(10) Uani 1 1 d . . .
C33 C 1.3294(4) -0.25500(18) 0.5537(3) 0.0461(12) Uani 1 1 d . . .
C34 C 1.4175(3) -0.11004(14) 0.7563(2) 0.0249(8) Uani 1 1 d . . .
C35 C 1.4908(3) -0.10820(14) 0.6985(2) 0.0266(8) Uani 1 1 d . . .
H35 H 1.4668 -0.1060 0.6482 0.032 Uiso 1 1 calc R . .
C36 C 1.5977(3) -0.10951(14) 0.7127(2) 0.0276(8) Uani 1 1 d . D .
C37 C 1.6367(3) -0.11205(15) 0.7851(2) 0.0298(9) Uani 1 1 d . . .
H37 H 1.7098 -0.1134 0.7946 0.036 Uiso 1 1 calc R . .
C38 C 1.5656(3) -0.11261(15) 0.8432(2) 0.0282(8) Uani 1 1 d . E .
C39 C 1.4588(3) -0.11120(14) 0.8289(2) 0.0274(8) Uiso 1 1 d . . .
H39 H 1.4120 -0.1110 0.8699 0.033 Uiso 1 1 calc R . .
C40 C 1.6724(3) -0.1096(2) 0.6481(3) 0.0434(11) Uani 1 1 d . . .
C41 C 1.6020(3) -0.11832(19) 0.9226(2) 0.0398(11) Uani 1 1 d . . .
C42 C 1.2249(3) -0.13550(14) 0.8075(2) 0.0253(8) Uani 1 1 d . . .
C43 C 1.2613(3) -0.17935(16) 0.8433(2) 0.0320(9) Uani 1 1 d . . .
H43 H 1.3277 -0.1925 0.8295 0.038 Uiso 1 1 calc R . .
C44 C 1.2050(4) -0.20469(17) 0.8979(3) 0.0410(11) Uani 1 1 d . F .
C45 C 1.1066(4) -0.18731(18) 0.9189(3) 0.0452(12) Uani 1 1 d . . .
H45 H 1.0683 -0.2039 0.9572 0.054 Uiso 1 1 calc R . .
C46 C 1.0665(4) -0.14524(17) 0.8823(3) 0.0418(11) Uani 1 1 d . G .
C47 C 1.1248(3) -0.11992(16) 0.8286(2) 0.0329(9) Uani 1 1 d . . .
H47 H 1.0954 -0.0907 0.8052 0.039 Uiso 1 1 calc R . .
C48 C 1.2526(6) -0.2502(2) 0.9353(4) 0.0674(18) Uani 1 1 d . . .
C49 C 0.9559(5) -0.1277(2) 0.8999(4) 0.074(2) Uani 1 1 d . . .
C50 C 1.2623(3) -0.04595(14) 0.7371(2) 0.0253(8) Uani 1 1 d . . .
C51 C 1.2476(3) -0.01789(15) 0.8025(2) 0.0339(9) Uani 1 1 d . . .
H51 H 1.2553 -0.0346 0.8493 0.041 Uiso 1 1 calc R . .
C52 C 1.2221(4) 0.03378(16) 0.8015(2) 0.0365(10) Uani 1 1 d . H .
C53 C 1.2110(3) 0.05953(15) 0.7345(2) 0.0347(9) Uani 1 1 d . . .
H53 H 1.1920 0.0945 0.7336 0.042 Uiso 1 1 calc R . .
C54 C 1.2280(3) 0.03312(15) 0.6691(2) 0.0328(9) Uani 1 1 d . I .
C55 C 1.2544(3) -0.01840(15) 0.6706(2) 0.0273(8) Uani 1 1 d . . .
H55 H 1.2675 -0.0354 0.6246 0.033 Uiso 1 1 calc R . .
C56 C 1.2031(6) 0.0606(2) 0.8736(3) 0.0629(16) Uani 1 1 d . . .
C57 C 1.2126(4) 0.0603(2) 0.5967(3) 0.0523(13) Uani 1 1 d . . .
B1 B 1.2909(3) -0.10701(16) 0.7405(2) 0.0240(9) Uani 1 1 d . . .
F10A F 1.703(3) -0.0896(12) 0.918(3) 0.019(11) Uiso 0.08(2) 1 d P E 2
F12A F 1.632(4) -0.1586(15) 0.936(2) 0.028(12) Uiso 0.08(2) 1 d P E 2
F11A F 1.543(3) -0.1045(16) 0.975(2) 0.013(9) Uiso 0.08(2) 1 d P E 2
F2A F 1.033(3) -0.0825(12) 0.515(2) 0.041(10) Uiso 0.087(11) 1 d P B 2
F3A F 1.021(2) -0.1476(14) 0.4603(15) 0.027(9) Uiso 0.087(11) 1 d P B 2
F1A F 0.956(4) -0.1362(17) 0.552(3) 0.047(13) Uiso 0.087(11) 1 d P B 2
F15A F 1.1632(13) -0.2880(6) 0.9459(11) 0.058(5) Uiso 0.202(11) 1 d P F 2
F13A F 1.276(3) -0.2448(11) 0.9946(17) 0.107(9) Uiso 0.202(11) 1 d P F 2
F14A F 1.310(2) -0.2723(12) 0.9019(17) 0.081(9) Uiso 0.202(11) 1 d P F 2
F4A F 1.3134(10) -0.2639(5) 0.4761(6) 0.040(4) Uiso 0.269(15) 1 d P C 2
F5A F 1.4236(15) -0.2537(7) 0.5512(10) 0.052(5) Uiso 0.269(15) 1 d P C 2
F6A F 1.3160(15) -0.2935(7) 0.5871(11) 0.068(5) Uiso 0.269(15) 1 d P C 2
F16A F 0.9802(12) -0.0701(6) 0.9322(9) 0.080(5) Uiso 0.276(10) 1 d P G 2
F17A F 0.9050(12) -0.1087(7) 0.8430(9) 0.081(5) Uiso 0.276(10) 1 d P G 2
F18A F 0.9243(16) -0.1426(7) 0.9612(11) 0.053(5) Uiso 0.276(10) 1 d P G 2
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh1 C19 2.096(7) . ?
Rh1 C18A 2.105(13) . ?
Rh1 C18 2.157(17) . ?
Rh1 C22 2.196(11) . ?
Rh1 C23 2.217(6) . ?
Rh1 C19A 2.23(4) . ?
Rh1 C23A 2.26(4) . ?
Rh1 C22A 2.305(16) . ?
Rh1 C1 2.312(4) . ?
Rh1 C3 2.361(4) . ?
Rh1 C2 2.389(4) . ?
Rh1 P3 2.4898(14) . ?
P1 O1 1.579(5) . ?
P1 C1 1.628(5) . ?
P1 C3 1.801(5) . ?
P1A C3 1.730(5) . ?
P1A C1 2.005(6) . ?
P2 C2 1.781(5) . ?
P2 C1 1.857(6) . ?
P2A O1A 1.588(9) . ?
P2A C1 1.595(6) . ?
P2A C2 1.741(5) . ?
P3 C2 1.752(5) . ?
P3 C3 1.753(4) . ?
F1 C32 1.307(6) . ?
F2 C32 1.318(6) . ?
F3 C32 1.340(6) . ?
F4 C33 1.313(6) . ?
F5 C33 1.370(8) . ?
F6 C33 1.384(8) . ?
F7 C40 1.278(7) . ?
F7A C40 1.283(14) . ?
F8 C40 1.328(6) . ?
F8A C40 1.450(14) . ?
F9 C40 1.358(7) . ?
F9A C40 1.208(16) . ?
F10 C41 1.308(6) . ?
F11 C41 1.338(6) . ?
F12 C41 1.354(8) . ?
F13 C48 1.371(10) . ?
F14 C48 1.343(9) . ?
F15 C48 1.295(7) . ?
F16 C49 1.254(8) . ?
F17 C49 1.356(9) . ?
F18 C49 1.350(10) . ?
F19 C56 1.277(7) . ?
F19A C56 1.457(17) . ?
F20 C56 1.325(8) . ?
F20A C56 1.158(18) . ?
F21 C56 1.342(9) . ?
F21A C56 1.417(17) . ?
F22 C57 1.379(8) . ?
F22A C57 1.203(15) . ?
F23 C57 1.319(9) . ?
F23A C57 1.242(9) . ?
F24 C57 1.277(7) . ?
F24A C57 1.451(11) . ?
O1 C16 1.628(14) . ?
O1A C16A 1.50(2) . ?
C1 C4 1.580(6) . ?
C2 C8 1.566(6) . ?
C3 C12 1.559(7) . ?
C4 C6 1.524(8) . ?
C4 C5 1.533(9) . ?
C4 C7 1.556(7) . ?
C8 C9 1.528(7) . ?
C8 C11 1.531(7) . ?
C8 C10 1.539(7) . ?
C12 C14 1.506(8) . ?
C12 C13 1.528(7) . ?
C12 C15 1.544(7) . ?
C16 C17 1.547(17) . ?
C16A C17A 1.28(3) . ?
C18 C19 1.399(18) . ?
C18 C25 1.511(13) . ?
C18A C19A 1.40(2) . ?
C18A C25A 1.50(2) . ?
C19 C20 1.503(10) . ?
C19A C20A 1.49(2) . ?
C20 C21 1.533(11) . ?
C20A C21A 1.501(18) . ?
C21 C22 1.478(13) . ?
C21A C22A 1.491(18) . ?
C22 C23 1.376(12) . ?
C22A C23A 1.41(2) . ?
C23 C24 1.502(11) . ?
C23A C24A 1.51(2) . ?
C24 C25 1.538(14) . ?
C24A C25A 1.49(2) . ?
C26 C31 1.398(5) . ?
C26 C27 1.401(5) . ?
C26 B1 1.636(6) . ?
C27 C28 1.384(5) . ?
C28 C29 1.391(6) . ?
C28 C32 1.498(6) . ?
C29 C30 1.378(6) . ?
C30 C31 1.391(5) . ?
C30 C33 1.484(6) . ?
C32 F1A 1.13(5) . ?
C32 F3A 1.18(3) . ?
C32 F2A 1.36(3) . ?
C33 F6A 1.187(18) . ?
C33 F5A 1.206(19) . ?
C33 F4A 1.421(12) . ?
C34 C39 1.399(5) . ?
C34 C35 1.401(5) . ?
C34 B1 1.643(6) . ?
C35 C36 1.389(5) . ?
C36 C37 1.387(6) . ?
C36 C40 1.503(6) . ?
C37 C38 1.384(6) . ?
C38 C39 1.388(5) . ?
C38 C41 1.499(6) . ?
C41 F12A 1.15(4) . ?
C41 F11A 1.26(4) . ?
C41 F10A 1.50(4) . ?
C42 C43 1.395(5) . ?
C42 C47 1.397(5) . ?
C42 B1 1.649(6) . ?
C43 C44 1.386(6) . ?
C44 C45 1.392(7) . ?
C44 C48 1.497(7) . ?
C45 C46 1.381(7) . ?
C46 C47 1.388(6) . ?
C46 C49 1.521(7) . ?
C48 F13A 1.11(3) . ?
C48 F14A 1.11(3) . ?
C48 F15A 1.525(18) . ?
C49 F18A 1.23(2) . ?
C49 F17A 1.305(17) . ?
C49 F16A 1.646(17) . ?
C50 C51 1.396(5) . ?
C50 C55 1.396(5) . ?
C50 B1 1.644(5) . ?
C51 C52 1.395(6) . ?
C52 C53 1.382(6) . ?
C52 C56 1.490(7) . ?
C53 C54 1.378(6) . ?
C54 C55 1.393(5) . ?
C54 C57 1.491(6) . ?
