#------------------------------------------------------------------------------
#$Date: 2015-01-27 21:58:39 +0200 (Tue, 27 Jan 2015) $
#$Revision: 130149 $
#$URL: svn://www.crystallography.net/cod/cif/4/06/18/4061825.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4061825
_journal_name_full               Organometallics
_journal_paper_doi               10.1021/om050418b
_journal_year                    2005
_chemical_formula_sum            'C114 H110 Ag Au4 Cl7 O4 P4'
_chemical_formula_weight         2811.79
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                90.689(5)
_cell_angle_beta                 98.936(5)
_cell_angle_gamma                102.289(5)
_cell_formula_units_Z            4
_cell_length_a                   15.0818(8)
_cell_length_b                   17.2044(11)
_cell_length_c                   42.493(3)
_cell_measurement_temperature    133(2)
_cell_volume                     10630.8(12)
_diffrn_ambient_temperature      133(2)
_exptl_crystal_density_diffrn    1.757
_cod_depositor_comments
;
The following automatic conversions were performed:
'_geom_bond_publ_flag' value 'Y' changed to 'y' according to
'/home/saulius/struct/CIF-dictionaries/cif_core.dic' dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29 (113 times).

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_database_code               4061825
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.96488(3) 0.34224(2) 0.423972(9) 0.02676(12) Uani 1 1 d . . .
Au2 Au 0.53318(3) 0.24386(2) 0.379943(10) 0.02932(12) Uani 1 1 d . . .
Au3 Au 0.72833(3) 0.13353(2) 0.375916(9) 0.02893(12) Uani 1 1 d . . .
Au4 Au 0.69429(3) 0.48942(2) 0.412580(10) 0.03046(12) Uani 1 1 d . . .
Ag1 Ag 0.74663(5) 0.32155(4) 0.401377(18) 0.0314(2) Uani 1 1 d . . .
P1 P 1.05817(19) 0.30676(15) 0.46616(6) 0.0268(7) Uani 1 1 d . . .
P2 P 0.4281(2) 0.15856(16) 0.40302(7) 0.0315(8) Uani 1 1 d . . .
P3 P 0.7402(2) 0.06650(16) 0.33083(6) 0.0312(8) Uani 1 1 d . . .
P4 P 0.63655(19) 0.57750(15) 0.38020(7) 0.0293(8) Uani 1 1 d . . .
C1 C 0.8948(6) 0.3731(5) 0.3841(2) 0.025(3) Uiso 1 1 d . . .
C2 C 0.8612(6) 0.3915(5) 0.3586(2) 0.024(3) Uiso 1 1 d . . .
C3 C 0.8222(6) 0.4148(5) 0.3275(2) 0.019(2) Uiso 1 1 d . . .
C4 C 0.8777(7) 0.4506(5) 0.3062(2) 0.024(3) Uiso 1 1 d . . .
C5 C 0.8363(7) 0.4660(5) 0.2753(2) 0.032(3) Uiso 1 1 d . . .
C6 C 0.7412(7) 0.4472(5) 0.2670(2) 0.024(3) Uiso 1 1 d . . .
C7 C 0.6850(7) 0.4167(5) 0.2891(2) 0.028(3) Uiso 1 1 d . . .
C8 C 0.7253(6) 0.3959(5) 0.3187(2) 0.019(2) Uiso 1 1 d . . .
C9 C 0.6675(7) 0.3572(5) 0.3409(2) 0.024(3) Uiso 1 1 d . . .
C10 C 0.6188(7) 0.3178(5) 0.3567(2) 0.028(3) Uiso 1 1 d . . .
C11 C 0.9802(6) 0.4703(6) 0.3159(2) 0.040(3) Uiso 1 1 d . . .
H11A H 1.0035 0.5276 0.3144 0.048 Uiso 1 1 calc R . .
H11B H 1.0081 0.4409 0.3017 0.048 Uiso 1 1 calc R . .
H11C H 0.9960 0.4553 0.3379 0.048 Uiso 1 1 calc R . .
C12 C 0.9001(7) 0.5025(6) 0.2523(2) 0.055(4) Uiso 1 1 d . . .
H12A H 0.9270 0.4613 0.2439 0.067 Uiso 1 1 calc R . .
H12B H 0.9492 0.5448 0.2637 0.067 Uiso 1 1 calc R . .
H12C H 0.8651 0.5251 0.2347 0.067 Uiso 1 1 calc R . .
C13 C 0.6965(7) 0.4622(6) 0.2339(2) 0.053(3) Uiso 1 1 d . . .
H13A H 0.7439 0.4778 0.2204 0.064 Uiso 1 1 calc R . .
H13B H 0.6633 0.5050 0.2351 0.064 Uiso 1 1 calc R . .
H13C H 0.6533 0.4135 0.2246 0.064 Uiso 1 1 calc R . .
C14 C 0.5815(6) 0.4040(5) 0.2809(2) 0.036(3) Uiso 1 1 d . . .
H14A H 0.5533 0.3793 0.2986 0.044 Uiso 1 1 calc R . .
H14B H 0.5597 0.3691 0.2616 0.044 Uiso 1 1 calc R . .
H14C H 0.5646 0.4554 0.2771 0.044 Uiso 1 1 calc R . .
C15 C 0.7291(7) 0.1821(5) 0.4181(2) 0.029(3) Uiso 1 1 d . . .
C16 C 0.7341(6) 0.2058(5) 0.4457(2) 0.021(2) Uiso 1 1 d . . .
C17 C 0.7450(6) 0.2295(5) 0.4794(2) 0.017(2) Uiso 1 1 d . . .
C18 C 0.7446(7) 0.1708(5) 0.5022(2) 0.028(3) Uiso 1 1 d . . .
C19 C 0.7574(7) 0.1949(6) 0.5348(2) 0.034(3) Uiso 1 1 d . . .
C20 C 0.7673(7) 0.2736(6) 0.5435(2) 0.030(3) Uiso 1 1 d . . .
C21 C 0.7630(6) 0.3314(5) 0.5210(2) 0.026(3) Uiso 1 1 d . . .
C22 C 0.7532(6) 0.3093(5) 0.4891(2) 0.022(3) Uiso 1 1 d . . .
C23 C 0.7437(6) 0.3664(5) 0.4645(2) 0.023(3) Uiso 1 1 d . . .
C24 C 0.7319(7) 0.4135(5) 0.4448(2) 0.030(3) Uiso 1 1 d . . .
C25 C 0.7310(7) 0.0845(5) 0.4914(2) 0.041(3) Uiso 1 1 d . . .
H25A H 0.6917 0.0749 0.4705 0.049 Uiso 1 1 calc R . .
H25B H 0.7016 0.0504 0.5069 0.049 Uiso 1 1 calc R . .
H25C H 0.7908 0.0722 0.4899 0.049 Uiso 1 1 calc R . .
C26 C 0.7575(7) 0.1308(6) 0.5595(2) 0.050(3) Uiso 1 1 d . . .
H26A H 0.8082 0.1492 0.5772 0.060 Uiso 1 1 calc R . .
H26B H 0.7654 0.0817 0.5495 0.060 Uiso 1 1 calc R . .
H26C H 0.6990 0.1206 0.5677 0.060 Uiso 1 1 calc R . .
C27 C 0.7776(7) 0.2968(6) 0.5786(2) 0.047(3) Uiso 1 1 d . . .
H27A H 0.7261 0.2654 0.5876 0.056 Uiso 1 1 calc R . .
H27B H 0.7778 0.3536 0.5811 0.056 Uiso 1 1 calc R . .
H27C H 0.8355 0.2866 0.5899 0.056 Uiso 1 1 calc R . .
C28 C 0.7710(7) 0.4165(5) 0.5310(2) 0.044(3) Uiso 1 1 d . . .
H28A H 0.7670 0.4483 0.5120 0.052 Uiso 1 1 calc R . .
H28B H 0.8302 0.4364 0.5448 0.052 Uiso 1 1 calc R . .
H28C H 0.7209 0.4206 0.5427 0.052 Uiso 1 1 calc R . .
C31 C 1.0414(4) 0.3363(4) 0.50544(12) 0.024(3) Uiso 1 1 d G . .
C32 C 1.0547(4) 0.4170(3) 0.51336(14) 0.046(3) Uiso 1 1 d G . .
H32 H 1.0704 0.4552 0.4981 0.055 Uiso 1 1 calc R . .
C33 C 1.0451(5) 0.4418(3) 0.54366(16) 0.056(4) Uiso 1 1 d G . .
H33 H 1.0542 0.4970 0.5491 0.068 Uiso 1 1 calc R . .
C34 C 1.0222(5) 0.3859(4) 0.56604(12) 0.029(3) Uiso 1 1 d G . .
C35 C 1.0089(5) 0.3051(4) 0.55812(14) 0.052(3) Uiso 1 1 d G . .
H35 H 0.9932 0.2669 0.5734 0.063 Uiso 1 1 calc R . .
C36 C 1.0185(5) 0.2803(3) 0.52782(16) 0.047(3) Uiso 1 1 d G . .
H36 H 1.0094 0.2252 0.5224 0.056 Uiso 1 1 calc R . .
C37 C 1.0122(7) 0.4141(6) 0.5985(2) 0.045(3) Uiso 1 1 d . . .
H37A H 0.9601 0.4403 0.5968 0.054 Uiso 1 1 calc R . .
H37B H 1.0686 0.4520 0.6080 0.054 Uiso 1 1 calc R . .
H37C H 1.0014 0.3685 0.6121 0.054 Uiso 1 1 calc R . .
C41 C 1.1786(3) 0.3481(3) 0.46400(16) 0.023(3) Uiso 1 1 d G . .
C42 C 1.2032(4) 0.3519(3) 0.43377(13) 0.040(3) Uiso 1 1 d G . .
H42 H 1.1582 0.3330 0.4156 0.048 Uiso 1 1 calc R . .
C43 C 1.2938(5) 0.3835(4) 0.43020(12) 0.049(3) Uiso 1 1 d G . .
H43 H 1.3106 0.3861 0.4095 0.058 Uiso 1 1 calc R . .
C44 C 1.3596(3) 0.4112(3) 0.45685(17) 0.031(3) Uiso 1 1 d G . .
C45 C 1.3349(4) 0.4074(3) 0.48707(13) 0.042(3) Uiso 1 1 d G . .
H45 H 1.3799 0.4263 0.5053 0.050 Uiso 1 1 calc R . .
C46 C 1.2444(4) 0.3758(3) 0.49065(12) 0.031(3) Uiso 1 1 d G . .
H46 H 1.2276 0.3732 0.5113 0.037 Uiso 1 1 calc R . .
C47 C 1.4598(7) 0.4496(6) 0.4526(2) 0.046(3) Uiso 1 1 d . . .
H47A H 1.4685 0.5077 0.4535 0.056 Uiso 1 1 calc R . .
H47B H 1.4711 0.4318 0.4318 0.056 Uiso 1 1 calc R . .
H47C H 1.5029 0.4335 0.4696 0.056 Uiso 1 1 calc R . .
C51 C 1.0482(4) 0.1988(2) 0.46516(14) 0.025(3) Uiso 1 1 d G . .
C52 C 1.1227(3) 0.1651(3) 0.47602(13) 0.026(3) Uiso 1 1 d G . .
H52 H 1.1801 0.1982 0.4850 0.032 Uiso 1 1 calc R . .
C53 C 1.1131(4) 0.0830(3) 0.47381(13) 0.029(3) Uiso 1 1 d G . .
H53 H 1.1640 0.0600 0.4812 0.035 Uiso 1 1 calc R . .
C54 C 1.0290(4) 0.0345(2) 0.46074(14) 0.030(3) Uiso 1 1 d G . .
C55 C 0.9545(3) 0.0682(3) 0.44988(13) 0.026(3) Uiso 1 1 d G . .
H55 H 0.8970 0.0350 0.4409 0.031 Uiso 1 1 calc R . .
C56 C 0.9641(4) 0.1503(3) 0.45209(13) 0.028(3) Uiso 1 1 d G . .
H56 H 0.9132 0.1733 0.4447 0.034 Uiso 1 1 calc R . .
C57 C 1.0188(7) -0.0563(5) 0.4580(2) 0.040(3) Uiso 1 1 d . . .
H57A H 1.0699 -0.0685 0.4486 0.048 Uiso 1 1 calc R . .
H57B H 0.9605 -0.0804 0.4445 0.048 Uiso 1 1 calc R . .
H57C H 1.0196 -0.0778 0.4793 0.048 Uiso 1 1 calc R . .
C61 C 0.4543(5) 0.1699(4) 0.44632(11) 0.031(3) Uiso 1 1 d G . .
C62 C 0.4367(4) 0.1057(3) 0.46569(16) 0.054(4) Uiso 1 1 d G . .
H62 H 0.4090 0.0540 0.4564 0.064 Uiso 1 1 calc R . .
C63 C 0.4597(5) 0.1171(3) 0.49864(15) 0.056(4) Uiso 1 1 d G . .
H63 H 0.4477 0.0732 0.5119 0.067 Uiso 1 1 calc R . .
C64 C 0.5003(5) 0.1927(4) 0.51221(11) 0.043(3) Uiso 1 1 d G . .
C65 C 0.5178(4) 0.2569(3) 0.49284(15) 0.036(3) Uiso 1 1 d G . .
H65 H 0.5456 0.3085 0.5021 0.044 Uiso 1 1 calc R . .
C66 C 0.4948(4) 0.2455(3) 0.45990(14) 0.037(3) Uiso 1 1 d G . .
H66 H 0.5068 0.2893 0.4467 0.044 Uiso 1 1 calc R . .
C67 C 0.5294(8) 0.2070(7) 0.5481(3) 0.071(4) Uiso 1 1 d . . .
H67A H 0.4761 0.2121 0.5579 0.085 Uiso 1 1 calc R . .
H67B H 0.5770 0.2561 0.5525 0.085 Uiso 1 1 calc R . .
H67C H 0.5538 0.1620 0.5569 0.085 Uiso 1 1 calc R . .
C71 C 0.4227(5) 0.0544(3) 0.39300(15) 0.032(3) Uiso 1 1 d G . .
C72 C 0.5017(4) 0.0253(3) 0.40183(14) 0.034(3) Uiso 1 1 d G . .
H72 H 0.5549 0.0585 0.4139 0.041 Uiso 1 1 calc R . .
C73 C 0.5030(4) -0.0525(4) 0.39304(15) 0.044(3) Uiso 1 1 d G . .
H73 H 0.5570 -0.0724 0.3991 0.053 Uiso 1 1 calc R . .
C74 C 0.4252(5) -0.1012(3) 0.37541(15) 0.036(3) Uiso 1 1 d G . .
C75 C 0.3462(4) -0.0721(3) 0.36658(14) 0.036(3) Uiso 1 1 d G . .
H75 H 0.2930 -0.1054 0.3545 0.043 Uiso 1 1 calc R . .
C76 C 0.3449(4) 0.0057(4) 0.37537(15) 0.037(3) Uiso 1 1 d G . .
H76 H 0.2909 0.0256 0.3693 0.045 Uiso 1 1 calc R . .
C77 C 0.4278(8) -0.1849(6) 0.3650(3) 0.058(4) Uiso 1 1 d . . .
H77A H 0.3657 -0.2134 0.3555 0.069 Uiso 1 1 calc R . .
H77B H 0.4503 -0.2129 0.3835 0.069 Uiso 1 1 calc R . .
H77C H 0.4689 -0.1827 0.3491 0.069 Uiso 1 1 calc R . .
C81 C 0.3117(3) 0.1737(4) 0.39037(15) 0.029(3) Uiso 1 1 d G . .
C82 C 0.2951(4) 0.2164(3) 0.36333(14) 0.037(3) Uiso 1 1 d G . .
H82 H 0.3435 0.2367 0.3518 0.045 Uiso 1 1 calc R . .
C83 C 0.2075(5) 0.2295(3) 0.35315(12) 0.042(3) Uiso 1 1 d G . .
H83 H 0.1962 0.2587 0.3347 0.050 Uiso 1 1 calc R . .
C84 C 0.1366(3) 0.1999(4) 0.37000(15) 0.034(3) Uiso 1 1 d G . .
C85 C 0.1532(4) 0.1572(3) 0.39705(14) 0.036(3) Uiso 1 1 d G . .
H85 H 0.1047 0.1369 0.4086 0.043 Uiso 1 1 calc R . .
C86 C 0.2407(5) 0.1441(3) 0.40723(12) 0.036(3) Uiso 1 1 d G . .
H86 H 0.2521 0.1149 0.4257 0.043 Uiso 1 1 calc R . .
C87 C 0.0421(7) 0.2139(6) 0.3589(3) 0.056(4) Uiso 1 1 d . . .
H87A H 0.0112 0.2176 0.3774 0.067 Uiso 1 1 calc R . .
H87B H 0.0064 0.1696 0.3444 0.067 Uiso 1 1 calc R . .
H87C H 0.0469 0.2637 0.3477 0.067 Uiso 1 1 calc R . .
C91 C 0.6343(4) 0.0240(3) 0.30421(15) 0.032(3) Uiso 1 1 d G . .
C92 C 0.5514(5) 0.0130(4) 0.31576(12) 0.041(3) Uiso 1 1 d G . .
H92 H 0.5506 0.0292 0.3372 0.049 Uiso 1 1 calc R . .
C93 C 0.4697(4) -0.0216(4) 0.29601(17) 0.052(3) Uiso 1 1 d G . .
H93 H 0.4130 -0.0291 0.3039 0.062 Uiso 1 1 calc R . .
C94 C 0.4709(4) -0.0452(4) 0.26471(16) 0.053(3) Uiso 1 1 d G . .
C95 C 0.5538(5) -0.0342(4) 0.25316(12) 0.043(3) Uiso 1 1 d G . .
H95 H 0.5546 -0.0504 0.2318 0.052 Uiso 1 1 calc R . .
C96 C 0.6355(4) 0.0004(4) 0.27291(16) 0.043(3) Uiso 1 1 d G . .
H96 H 0.6922 0.0079 0.2650 0.051 Uiso 1 1 calc R . .
C97 C 0.3822(8) -0.0823(6) 0.2422(3) 0.071(4) Uiso 1 1 d . . .
H97A H 0.3671 -0.0434 0.2267 0.085 Uiso 1 1 calc R . .
H97B H 0.3320 -0.0977 0.2545 0.085 Uiso 1 1 calc R . .
H97C H 0.3907 -0.1295 0.2309 0.085 Uiso 1 1 calc R . .
C101 C 0.7943(4) -0.0164(3) 0.34168(16) 0.036(3) Uiso 1 1 d G . .
C102 C 0.8707(5) -0.0014(3) 0.36560(14) 0.042(3) Uiso 1 1 d G . .
H102 H 0.8896 0.0491 0.3767 0.050 Uiso 1 1 calc R . .
C103 C 0.9195(4) -0.0604(4) 0.37331(14) 0.053(3) Uiso 1 1 d G . .
H103 H 0.9717 -0.0502 0.3897 0.064 Uiso 1 1 calc R . .
C104 C 0.8919(5) -0.1344(4) 0.35710(17) 0.048(3) Uiso 1 1 d G . .
C105 C 0.8155(5) -0.1494(3) 0.33317(15) 0.048(3) Uiso 1 1 d G . .
H105 H 0.7966 -0.1999 0.3221 0.058 Uiso 1 1 calc R . .
C106 C 0.7666(4) -0.0903(4) 0.32546(13) 0.040(3) Uiso 1 1 d G . .
H106 H 0.7144 -0.1005 0.3091 0.047 Uiso 1 1 calc R . .
C107 C 0.9428(9) -0.1991(7) 0.3665(3) 0.086(5) Uiso 1 1 d . . .
H10A H 0.9074 -0.2370 0.3793 0.103 Uiso 1 1 calc R . .
H10B H 1.0031 -0.1754 0.3790 0.103 Uiso 1 1 calc R . .
H10C H 0.9512 -0.2268 0.3472 0.103 Uiso 1 1 calc R . .
C111 C 0.8175(4) 0.1250(3) 0.30670(13) 0.027(3) Uiso 1 1 d G . .
C112 C 0.8756(4) 0.0914(3) 0.29103(14) 0.030(3) Uiso 1 1 d G . .
H112 H 0.8759 0.0365 0.2928 0.036 Uiso 1 1 calc R . .
C113 C 0.9334(4) 0.1383(4) 0.27284(14) 0.033(3) Uiso 1 1 d G . .
H113 H 0.9731 0.1154 0.2621 0.040 Uiso 1 1 calc R . .
C114 C 0.9330(4) 0.2187(3) 0.27032(13) 0.032(3) Uiso 1 1 d G . .
C115 C 0.8749(4) 0.2523(3) 0.28599(15) 0.038(3) Uiso 1 1 d G . .
H115 H 0.8747 0.3072 0.2843 0.045 Uiso 1 1 calc R . .
C116 C 0.8171(4) 0.2054(3) 0.30418(13) 0.028(3) Uiso 1 1 d G . .
H116 H 0.7774 0.2283 0.3149 0.034 Uiso 1 1 calc R . .
C117 C 0.9986(7) 0.2710(6) 0.2515(2) 0.054(4) Uiso 1 1 d . . .
H11D H 1.0592 0.2877 0.2648 0.065 Uiso 1 1 calc R . .
H11E H 0.9747 0.3181 0.2450 0.065 Uiso 1 1 calc R . .
H11F H 1.0042 0.2409 0.2324 0.065 Uiso 1 1 calc R . .
C121 C 0.6629(5) 0.6764(3) 0.39954(17) 0.030(3) Uiso 1 1 d G . .
C122 C 0.6703(5) 0.6821(4) 0.43255(17) 0.067(4) Uiso 1 1 d G . .
H122 H 0.6605 0.6351 0.4442 0.080 Uiso 1 1 calc R . .
C123 C 0.6921(5) 0.7564(5) 0.44844(13) 0.081(4) Uiso 1 1 d G . .
H123 H 0.6972 0.7603 0.4710 0.097 Uiso 1 1 calc R . .
C124 C 0.7065(5) 0.8251(3) 0.43134(18) 0.052(3) Uiso 1 1 d G . .
C125 C 0.6991(5) 0.8194(3) 0.39834(18) 0.054(4) Uiso 1 1 d G . .
H125 H 0.7089 0.8664 0.3866 0.065 Uiso 1 1 calc R . .
C126 C 0.6773(5) 0.7451(4) 0.38244(12) 0.064(4) Uiso 1 1 d G . .
H126 H 0.6722 0.7412 0.3599 0.077 Uiso 1 1 calc R . .
C127 C 0.7274(8) 0.9073(6) 0.4477(2) 0.057(4) Uiso 1 1 d . . .
H12D H 0.7865 0.9157 0.4621 0.068 Uiso 1 1 calc R . .
H12E H 0.6787 0.9115 0.4600 0.068 Uiso 1 1 calc R . .
H12F H 0.7306 0.9477 0.4316 0.068 Uiso 1 1 calc R . .
C131 C 0.6738(5) 0.5944(3) 0.34194(12) 0.030(3) Uiso 1 1 d G . .
C132 C 0.6163(3) 0.6148(3) 0.31600(16) 0.034(3) Uiso 1 1 d G . .
H132 H 0.5529 0.6108 0.3169 0.040 Uiso 1 1 calc R . .
C133 C 0.6513(4) 0.6409(4) 0.28867(13) 0.040(3) Uiso 1 1 d G . .
H133 H 0.6120 0.6547 0.2709 0.048 Uiso 1 1 calc R . .
C134 C 0.7440(5) 0.6466(4) 0.28729(13) 0.044(3) Uiso 1 1 d G . .
C135 C 0.8015(3) 0.6263(4) 0.31323(17) 0.046(3) Uiso 1 1 d G . .
H135 H 0.8648 0.6302 0.3123 0.055 Uiso 1 1 calc R . .
C136 C 0.7664(4) 0.6002(3) 0.34056(13) 0.036(3) Uiso 1 1 d G . .
H136 H 0.8058 0.5863 0.3583 0.044 Uiso 1 1 calc R . .
C137 C 0.7835(7) 0.6812(6) 0.2587(2) 0.059(4) Uiso 1 1 d . . .
H13D H 0.8477 0.7090 0.2654 0.071 Uiso 1 1 calc R . .
H13E H 0.7479 0.7189 0.2491 0.071 Uiso 1 1 calc R . .
H13F H 0.7805 0.6383 0.2429 0.071 Uiso 1 1 calc R . .
C141 C 0.5115(3) 0.5485(4) 0.37248(15) 0.024(3) Uiso 1 1 d G . .
C142 C 0.4570(5) 0.5989(3) 0.38066(14) 0.052(3) Uiso 1 1 d G . .
H142 H 0.4849 0.6500 0.3904 0.063 Uiso 1 1 calc R . .
C143 C 0.3618(5) 0.5745(4) 0.37454(16) 0.056(4) Uiso 1 1 d G . .
H143 H 0.3245 0.6089 0.3801 0.067 Uiso 1 1 calc R . .
C144 C 0.3210(3) 0.4997(4) 0.36023(16) 0.043(3) Uiso 1 1 d G . .
C145 C 0.3755(4) 0.4493(3) 0.35205(14) 0.035(3) Uiso 1 1 d G . .
H145 H 0.3476 0.3982 0.3423 0.042 Uiso 1 1 calc R . .
C146 C 0.4707(4) 0.4737(3) 0.35817(14) 0.030(3) Uiso 1 1 d G . .
H146 H 0.5079 0.4393 0.3526 0.037 Uiso 1 1 calc R . .
C147 C 0.2171(7) 0.4767(6) 0.3519(3) 0.062(4) Uiso 1 1 d . . .
H14D H 0.1996 0.4606 0.3292 0.075 Uiso 1 1 calc R . .
H14E H 0.1911 0.5224 0.3565 0.075 Uiso 1 1 calc R . .
H14F H 0.1936 0.4322 0.3647 0.075 Uiso 1 1 calc R . .
Au5 Au 0.28308(3) 0.02564(2) 0.149969(10) 0.03117(12) Uani 1 1 d . . .
Au8 Au 0.52737(3) 0.12233(2) 0.124577(10) 0.02977(12) Uani 1 1 d . . .
Au6 Au 0.51932(3) 0.32220(2) 0.083223(10) 0.03491(13) Uani 1 1 d . . .
Au7 Au 0.21739(3) 0.33882(2) 0.092363(11) 0.03792(13) Uani 1 1 d . . .
Ag2 Ag 0.35054(6) 0.19562(4) 0.109932(19) 0.0335(2) Uani 1 1 d . . .
P5 P 0.2555(2) -0.10848(15) 0.14167(7) 0.0296(7) Uani 1 1 d . . .
P6 P 0.6035(2) 0.33344(17) 0.04288(7) 0.0371(8) Uani 1 1 d . . .
P7 P 0.2161(2) 0.46660(16) 0.10663(7) 0.0383(8) Uani 1 1 d . . .
P8 P 0.6411(2) 0.14808(16) 0.16795(7) 0.0323(8) Uani 1 1 d . . .
C151 C 0.3073(7) 0.1414(6) 0.1610(2) 0.034(3) Uiso 1 1 d . . .
C152 C 0.3246(6) 0.2068(5) 0.1736(2) 0.023(3) Uiso 1 1 d . . .
C153 C 0.3503(7) 0.2858(5) 0.1900(2) 0.025(3) Uiso 1 1 d . . .
C154 C 0.3249(7) 0.2965(6) 0.2201(2) 0.030(3) Uiso 1 1 d . . .
C155 C 0.3518(7) 0.3732(6) 0.2353(2) 0.036(3) Uiso 1 1 d . . .
C156 C 0.3992(7) 0.4356(6) 0.2207(2) 0.032(3) Uiso 1 1 d . . .
C157 C 0.4297(7) 0.4254(5) 0.1917(2) 0.030(3) Uiso 1 1 d . . .
C158 C 0.4058(6) 0.3489(5) 0.1760(2) 0.025(3) Uiso 1 1 d . . .
C159 C 0.4329(6) 0.3338(5) 0.1464(2) 0.024(3) Uiso 1 1 d . . .
C160 C 0.4607(7) 0.3243(5) 0.1221(2) 0.031(3) Uiso 1 1 d . . .
C161 C 0.2696(7) 0.2280(6) 0.2353(3) 0.055(4) Uiso 1 1 d . . .
H16A H 0.2638 0.1786 0.2227 0.066 Uiso 1 1 calc R . .
H16B H 0.2083 0.2377 0.2361 0.066 Uiso 1 1 calc R . .
H16C H 0.3007 0.2231 0.2570 0.066 Uiso 1 1 calc R . .
C162 C 0.3209(8) 0.3842(6) 0.2677(2) 0.058(4) Uiso 1 1 d . . .
H16D H 0.3191 0.4401 0.2713 0.069 Uiso 1 1 calc R . .
H16E H 0.3645 0.3687 0.2848 0.069 Uiso 1 1 calc R . .
H16F H 0.2596 0.3507 0.2676 0.069 Uiso 1 1 calc R . .
C163 C 0.4224(8) 0.5194(6) 0.2358(3) 0.059(4) Uiso 1 1 d . . .
H16G H 0.3723 0.5463 0.2285 0.071 Uiso 1 1 calc R . .
H16H H 0.4794 0.5491 0.2295 0.071 Uiso 1 1 calc R . .
H16I H 0.4303 0.5168 0.2590 0.071 Uiso 1 1 calc R . .
C164 C 0.4873(7) 0.4925(6) 0.1766(2) 0.053(3) Uiso 1 1 d . . .
H16J H 0.5087 0.4713 0.1583 0.063 Uiso 1 1 calc R . .
H16K H 0.5404 0.5186 0.1923 0.063 Uiso 1 1 calc R . .
H16L H 0.4503 0.5312 0.1693 0.063 Uiso 1 1 calc R . .
C165 C 0.2202(7) 0.2319(6) 0.0751(2) 0.033(3) Uiso 1 1 d . . .
C166 C 0.2244(6) 0.1748(5) 0.0585(2) 0.026(3) Uiso 1 1 d . . .
C167 C 0.2210(7) 0.1145(5) 0.0347(2) 0.028(3) Uiso 1 1 d . . .
C168 C 0.1504(7) 0.0981(5) 0.0079(2) 0.030(3) Uiso 1 1 d . . .
C169 C 0.1542(7) 0.0450(6) -0.0157(2) 0.038(3) Uiso 1 1 d . . .
C170 C 0.2278(7) 0.0083(6) -0.0152(2) 0.036(3) Uiso 1 1 d . . .
C171 C 0.2971(7) 0.0212(6) 0.0116(2) 0.033(3) Uiso 1 1 d . . .
C172 C 0.2952(7) 0.0734(5) 0.0364(2) 0.027(3) Uiso 1 1 d . . .
C173 C 0.3661(7) 0.0873(5) 0.0645(2) 0.027(3) Uiso 1 1 d . . .
C174 C 0.4276(7) 0.1004(5) 0.0866(2) 0.030(3) Uiso 1 1 d . . .
C175 C 0.0738(7) 0.1419(6) 0.0067(2) 0.047(3) Uiso 1 1 d . . .
H17A H 0.0761 0.1782 -0.0109 0.057 Uiso 1 1 calc R . .
H17B H 0.0808 0.1725 0.0268 0.057 Uiso 1 1 calc R . .
H17C H 0.0146 0.1036 0.0033 0.057 Uiso 1 1 calc R . .
C176 C 0.0780(7) 0.0280(6) -0.0444(2) 0.059(4) Uiso 1 1 d . . .
H17D H 0.0384 -0.0245 -0.0428 0.070 Uiso 1 1 calc R . .
H17E H 0.1050 0.0285 -0.0640 0.070 Uiso 1 1 calc R . .
H17F H 0.0415 0.0689 -0.0450 0.070 Uiso 1 1 calc R . .
C177 C 0.2346(8) -0.0445(6) -0.0431(2) 0.057(4) Uiso 1 1 d . . .
H17G H 0.2796 -0.0770 -0.0363 0.069 Uiso 1 1 calc R . .
H17H H 0.2542 -0.0113 -0.0604 0.069 Uiso 1 1 calc R . .
H17I H 0.1743 -0.0794 -0.0506 0.069 Uiso 1 1 calc R . .
C178 C 0.3767(7) -0.0193(6) 0.0139(2) 0.055(4) Uiso 1 1 d . . .
H17J H 0.3547 -0.0766 0.0157 0.066 Uiso 1 1 calc R . .
H17K H 0.4219 0.0024 0.0328 0.066 Uiso 1 1 calc R . .
H17L H 0.4055 -0.0099 -0.0052 0.066 Uiso 1 1 calc R . .
C181 C 0.3548(4) -0.1513(4) 0.15597(14) 0.026(3) Uiso 1 1 d G . .
C182 C 0.3440(4) -0.2251(3) 0.16952(15) 0.030(3) Uiso 1 1 d G . .
H182 H 0.2841 -0.2549 0.1710 0.036 Uiso 1 1 calc R . .
C183 C 0.4207(5) -0.2555(3) 0.18083(14) 0.045(3) Uiso 1 1 d G . .
H183 H 0.4133 -0.3060 0.1901 0.054 Uiso 1 1 calc R . .
C184 C 0.5082(4) -0.2120(4) 0.17859(15) 0.043(3) Uiso 1 1 d G . .
C185 C 0.5190(3) -0.1381(4) 0.16504(15) 0.042(3) Uiso 1 1 d G . .
H185 H 0.5788 -0.1083 0.1635 0.050 Uiso 1 1 calc R . .
C186 C 0.4423(5) -0.1077(3) 0.15373(14) 0.035(3) Uiso 1 1 d G . .
H186 H 0.4497 -0.0572 0.1445 0.042 Uiso 1 1 calc R . .
C187 C 0.5912(8) -0.2460(6) 0.1914(3) 0.070(4) Uiso 1 1 d . . .
H18A H 0.6230 -0.2558 0.1739 0.106 Uiso 1 1 calc R . .
H18B H 0.5707 -0.2962 0.2015 0.106 Uiso 1 1 calc R . .
H18C H 0.6332 -0.2080 0.2072 0.106 Uiso 1 1 calc R . .
C191 C 0.2200(4) -0.1410(4) 0.10023(11) 0.030(3) Uiso 1 1 d G . .
C192 C 0.2270(4) -0.2157(3) 0.08945(14) 0.036(3) Uiso 1 1 d G . .
H192 H 0.2511 -0.2505 0.1040 0.043 Uiso 1 1 calc R . .
C193 C 0.1988(4) -0.2395(3) 0.05744(15) 0.034(3) Uiso 1 1 d G . .
H193 H 0.2035 -0.2906 0.0501 0.041 Uiso 1 1 calc R . .
C194 C 0.1636(4) -0.1886(4) 0.03620(11) 0.041(3) Uiso 1 1 d G . .
C195 C 0.1566(4) -0.1138(3) 0.04698(13) 0.039(3) Uiso 1 1 d G . .
H195 H 0.1326 -0.0790 0.0325 0.046 Uiso 1 1 calc R . .
C196 C 0.1849(4) -0.0900(3) 0.07900(15) 0.027(3) Uiso 1 1 d G . .
H196 H 0.1801 -0.0390 0.0864 0.033 Uiso 1 1 calc R . .
C197 C 0.1389(7) -0.2126(6) 0.0006(2) 0.055(4) Uiso 1 1 d . . .
H19A H 0.0976 -0.1803 -0.0098 0.083 Uiso 1 1 calc R . .
H19B H 0.1081 -0.2690 -0.0021 0.083 Uiso 1 1 calc R . .
H19C H 0.1951 -0.2038 -0.0089 0.083 Uiso 1 1 calc R . .
C201 C 0.1666(4) -0.1613(3) 0.16280(15) 0.025(3) Uiso 1 1 d G . .
C202 C 0.1670(4) -0.1331(3) 0.19362(15) 0.044(3) Uiso 1 1 d G . .
H202 H 0.2072 -0.0843 0.2017 0.053 Uiso 1 1 calc R . .
C203 C 0.1085(5) -0.1762(4) 0.21254(12) 0.053(3) Uiso 1 1 d G . .
H203 H 0.1087 -0.1570 0.2336 0.063 Uiso 1 1 calc R . .
C204 C 0.0496(4) -0.2476(4) 0.20064(15) 0.045(3) Uiso 1 1 d G . .
C205 C 0.0493(4) -0.2758(3) 0.16983(16) 0.044(3) Uiso 1 1 d G . .
H205 H 0.0091 -0.3246 0.1617 0.053 Uiso 1 1 calc R . .
C206 C 0.1078(4) -0.2327(4) 0.15091(12) 0.033(3) Uiso 1 1 d G . .
H206 H 0.1076 -0.2520 0.1298 0.040 Uiso 1 1 calc R . .
C207 C -0.0131(8) -0.2951(6) 0.2213(3) 0.062(4) Uiso 1 1 d . . .
H20A H -0.0654 -0.2702 0.2223 0.094 Uiso 1 1 calc R . .
H20B H 0.0209 -0.2964 0.2428 0.094 Uiso 1 1 calc R . .
H20C H -0.0356 -0.3496 0.2121 0.094 Uiso 1 1 calc R . .
C211 C 0.6270(5) 0.4347(3) 0.02950(17) 0.038(3) Uiso 1 1 d G . .
C212 C 0.6074(4) 0.4528(3) -0.00227(15) 0.053(3) Uiso 1 1 d G . .
H212 H 0.5760 0.4120 -0.0178 0.063 Uiso 1 1 calc R . .
C213 C 0.6339(5) 0.5306(4) -0.01135(12) 0.046(3) Uiso 1 1 d G . .
H213 H 0.6205 0.5430 -0.0331 0.055 Uiso 1 1 calc R . .
C214 C 0.6799(5) 0.5903(3) 0.01135(17) 0.044(3) Uiso 1 1 d G . .
C215 C 0.6995(4) 0.5722(3) 0.04312(15) 0.053(3) Uiso 1 1 d G . .
H215 H 0.7309 0.6131 0.0586 0.064 Uiso 1 1 calc R . .
C216 C 0.6730(5) 0.4945(4) 0.05220(12) 0.048(3) Uiso 1 1 d G . .
H216 H 0.6864 0.4821 0.0739 0.058 Uiso 1 1 calc R . .
C217 C 0.7140(8) 0.6741(6) 0.0014(3) 0.079(4) Uiso 1 1 d . . .
H21A H 0.7796 0.6826 0.0001 0.119 Uiso 1 1 calc R . .
H21B H 0.7046 0.7124 0.0172 0.119 Uiso 1 1 calc R . .
H21C H 0.6798 0.6816 -0.0195 0.119 Uiso 1 1 calc R . .
C221 C 0.7156(4) 0.3133(4) 0.05745(15) 0.027(3) Uiso 1 1 d G . .
C222 C 0.7967(5) 0.3616(3) 0.05114(14) 0.043(3) Uiso 1 1 d G . .
H222 H 0.7946 0.4074 0.0390 0.051 Uiso 1 1 calc R . .
C223 C 0.8808(4) 0.3431(4) 0.06263(16) 0.043(3) Uiso 1 1 d G . .
H223 H 0.9361 0.3762 0.0583 0.051 Uiso 1 1 calc R . .
C224 C 0.8838(4) 0.2762(4) 0.08044(15) 0.042(3) Uiso 1 1 d G . .
C225 C 0.8028(5) 0.2279(3) 0.08675(14) 0.041(3) Uiso 1 1 d G . .
H225 H 0.8049 0.1821 0.0989 0.050 Uiso 1 1 calc R . .
C226 C 0.7187(4) 0.2464(3) 0.07526(15) 0.042(3) Uiso 1 1 d G . .
H226 H 0.6633 0.2133 0.0796 0.051 Uiso 1 1 calc R . .
C227 C 0.9737(8) 0.2544(7) 0.0926(3) 0.092(5) Uiso 1 1 d . . .
H22A H 1.0044 0.2457 0.0745 0.138 Uiso 1 1 calc R . .
H22B H 0.9626 0.2055 0.1043 0.138 Uiso 1 1 calc R . .
H22C H 1.0130 0.2977 0.1068 0.138 Uiso 1 1 calc R . .
C231 C 0.5572(5) 0.2664(3) 0.00801(13) 0.036(3) Uiso 1 1 d G . .
C232 C 0.6111(3) 0.2583(3) -0.01504(17) 0.044(3) Uiso 1 1 d G . .
H232 H 0.6723 0.2888 -0.0129 0.053 Uiso 1 1 calc R . .
C233 C 0.5754(4) 0.2057(4) -0.04126(14) 0.049(3) Uiso 1 1 d G . .
H233 H 0.6122 0.2002 -0.0570 0.059 Uiso 1 1 calc R . .
C234 C 0.4858(5) 0.1612(3) -0.04443(13) 0.040(3) Uiso 1 1 d G . .
C235 C 0.4319(3) 0.1693(3) -0.02137(16) 0.036(3) Uiso 1 1 d G . .
H235 H 0.3706 0.1388 -0.0235 0.043 Uiso 1 1 calc R . .
C236 C 0.4676(4) 0.2219(4) 0.00485(14) 0.039(3) Uiso 1 1 d G . .
H236 H 0.4307 0.2274 0.0206 0.047 Uiso 1 1 calc R . .
C237 C 0.4454(7) 0.1027(6) -0.0727(2) 0.053(3) Uiso 1 1 d . . .
H23A H 0.4840 0.1134 -0.0894 0.079 Uiso 1 1 calc R . .
H23B H 0.3831 0.1088 -0.0811 0.079 Uiso 1 1 calc R . .
H23C H 0.4431 0.0483 -0.0658 0.079 Uiso 1 1 calc R . .
C241 C 0.1325(4) 0.5098(4) 0.07981(15) 0.038(3) Uiso 1 1 d G . .
C242 C 0.1506(4) 0.5278(4) 0.04932(17) 0.049(3) Uiso 1 1 d G . .
H242 H 0.2047 0.5177 0.0428 0.059 Uiso 1 1 calc R . .
C243 C 0.0895(5) 0.5604(4) 0.02841(12) 0.041(3) Uiso 1 1 d G . .
H243 H 0.1018 0.5727 0.0076 0.049 Uiso 1 1 calc R . .
C244 C 0.0103(4) 0.5750(4) 0.03799(15) 0.039(3) Uiso 1 1 d G . .
C245 C -0.0078(4) 0.5571(4) 0.06848(17) 0.042(3) Uiso 1 1 d G . .
H245 H -0.0619 0.5671 0.0750 0.051 Uiso 1 1 calc R . .
C246 C 0.0534(5) 0.5244(4) 0.08939(12) 0.045(3) Uiso 1 1 d G . .
H246 H 0.0410 0.5121 0.1102 0.054 Uiso 1 1 calc R . .
C247 C -0.0552(7) 0.6128(6) 0.0156(2) 0.054(4) Uiso 1 1 d . . .
H24A H -0.1187 0.5879 0.0176 0.081 Uiso 1 1 calc R . .
H24B H -0.0456 0.6049 -0.0064 0.081 Uiso 1 1 calc R . .
H24C H -0.0435 0.6699 0.0211 0.081 Uiso 1 1 calc R . .
C251 C 0.3249(4) 0.5331(4) 0.10330(15) 0.034(3) Uiso 1 1 d G . .
C252 C 0.3364(4) 0.6151(4) 0.10742(15) 0.052(3) Uiso 1 1 d G . .
H252 H 0.2872 0.6370 0.1123 0.062 Uiso 1 1 calc R . .
C253 C 0.4198(5) 0.6650(3) 0.10436(15) 0.043(3) Uiso 1 1 d G . .
H253 H 0.4277 0.7211 0.1072 0.051 Uiso 1 1 calc R . .
C254 C 0.4919(4) 0.6329(4) 0.09718(15) 0.034(3) Uiso 1 1 d G . .
C255 C 0.4804(4) 0.5509(4) 0.09307(15) 0.049(3) Uiso 1 1 d G . .
H255 H 0.5297 0.5290 0.0882 0.059 Uiso 1 1 calc R . .
C256 C 0.3970(5) 0.5010(3) 0.09612(15) 0.038(3) Uiso 1 1 d G . .
H256 H 0.3892 0.4450 0.0933 0.046 Uiso 1 1 calc R . .
C257 C 0.5821(7) 0.6883(6) 0.0936(3) 0.056(4) Uiso 1 1 d . . .
H25D H 0.6332 0.6638 0.1022 0.084 Uiso 1 1 calc R . .
H25E H 0.5878 0.7390 0.1053 0.084 Uiso 1 1 calc R . .
H25F H 0.5836 0.6978 0.0710 0.084 Uiso 1 1 calc R . .
C261 C 0.1906(4) 0.4790(4) 0.14650(11) 0.033(3) Uiso 1 1 d G . .
C262 C 0.1809(5) 0.5519(3) 0.15832(15) 0.048(3) Uiso 1 1 d G . .
H262 H 0.1868 0.5966 0.1453 0.057 Uiso 1 1 calc R . .
C263 C 0.1625(5) 0.5592(3) 0.18914(16) 0.049(3) Uiso 1 1 d G . .
H263 H 0.1559 0.6090 0.1972 0.059 Uiso 1 1 calc R . .
C264 C 0.1538(4) 0.4937(4) 0.20814(12) 0.036(3) Uiso 1 1 d G . .
C265 C 0.1635(4) 0.4208(3) 0.19632(14) 0.037(3) Uiso 1 1 d G . .
H265 H 0.1576 0.3760 0.2093 0.044 Uiso 1 1 calc R . .
C266 C 0.1819(4) 0.4134(3) 0.16550(15) 0.035(3) Uiso 1 1 d G . .
H266 H 0.1885 0.3636 0.1574 0.042 Uiso 1 1 calc R . .
C267 C 0.1379(7) 0.5026(6) 0.2421(2) 0.054(4) Uiso 1 1 d . . .
H26D H 0.1972 0.5159 0.2564 0.081 Uiso 1 1 calc R . .
H26E H 0.1015 0.4524 0.2482 0.081 Uiso 1 1 calc R . .
H26F H 0.1046 0.5451 0.2438 0.081 Uiso 1 1 calc R . .
C271 C 0.5948(4) 0.1621(4) 0.20407(12) 0.025(3) Uiso 1 1 d G . .
C272 C 0.5050(4) 0.1226(3) 0.20537(13) 0.038(3) Uiso 1 1 d G . .
H272 H 0.4695 0.0907 0.1875 0.045 Uiso 1 1 calc R . .
C273 C 0.4672(3) 0.1296(3) 0.23281(16) 0.041(3) Uiso 1 1 d G . .
H273 H 0.4058 0.1026 0.2337 0.050 Uiso 1 1 calc R . .
C274 C 0.5192(4) 0.1762(4) 0.25896(12) 0.036(3) Uiso 1 1 d G . .
C275 C 0.6090(4) 0.2157(3) 0.25766(12) 0.033(3) Uiso 1 1 d G . .
H275 H 0.6446 0.2475 0.2755 0.039 Uiso 1 1 calc R . .
C276 C 0.6468(3) 0.2087(3) 0.23022(15) 0.033(3) Uiso 1 1 d G . .
H276 H 0.7082 0.2357 0.2293 0.040 Uiso 1 1 calc R . .
C277 C 0.4768(7) 0.1855(6) 0.2888(2) 0.060(4) Uiso 1 1 d . . .
H27D H 0.4613 0.2379 0.2895 0.089 Uiso 1 1 calc R . .
H27E H 0.5209 0.1806 0.3078 0.089 Uiso 1 1 calc R . .
H27F H 0.4208 0.1439 0.2882 0.089 Uiso 1 1 calc R . .
C281 C 0.7269(4) 0.2378(3) 0.16537(15) 0.023(3) Uiso 1 1 d G . .
C282 C 0.8208(4) 0.2406(3) 0.17143(14) 0.035(3) Uiso 1 1 d G . .
H282 H 0.8425 0.1943 0.1777 0.042 Uiso 1 1 calc R . .
C283 C 0.8830(3) 0.3113(4) 0.16835(15) 0.040(3) Uiso 1 1 d G . .
H283 H 0.9472 0.3133 0.1725 0.048 Uiso 1 1 calc R . .
C284 C 0.8512(4) 0.3791(3) 0.15921(16) 0.043(3) Uiso 1 1 d G . .
C285 C 0.7573(5) 0.3763(3) 0.15315(15) 0.043(3) Uiso 1 1 d G . .
H285 H 0.7356 0.4226 0.1469 0.052 Uiso 1 1 calc R . .
C286 C 0.6951(3) 0.3056(4) 0.15623(14) 0.035(3) Uiso 1 1 d G . .
H286 H 0.6309 0.3036 0.1521 0.042 Uiso 1 1 calc R . .
C287 C 0.9217(7) 0.4559(6) 0.1552(3) 0.056(4) Uiso 1 1 d . . .
H28D H 0.8973 0.4840 0.1371 0.084 Uiso 1 1 calc R . .
H28E H 0.9792 0.4424 0.1513 0.084 Uiso 1 1 calc R . .
H28F H 0.9337 0.4902 0.1746 0.084 Uiso 1 1 calc R . .
C291 C 0.7057(4) 0.0688(3) 0.17460(15) 0.023(3) Uiso 1 1 d G . .
C292 C 0.7128(4) 0.0204(4) 0.14911(11) 0.032(3) Uiso 1 1 d G . .
H292 H 0.6860 0.0293 0.1281 0.038 Uiso 1 1 calc R . .
C293 C 0.7592(4) -0.0412(3) 0.15439(13) 0.042(3) Uiso 1 1 d G . .
H293 H 0.7641 -0.0743 0.1370 0.050 Uiso 1 1 calc R . .
C294 C 0.7985(4) -0.0542(3) 0.18514(16) 0.031(3) Uiso 1 1 d G . .
C295 C 0.7913(4) -0.0057(4) 0.21062(12) 0.040(3) Uiso 1 1 d G . .
H295 H 0.8182 -0.0146 0.2316 0.048 Uiso 1 1 calc R . .
C296 C 0.7450(4) 0.0558(3) 0.20535(13) 0.041(3) Uiso 1 1 d G . .
H296 H 0.7401 0.0889 0.2228 0.049 Uiso 1 1 calc R . .
C297 C 0.8464(7) -0.1236(5) 0.1909(2) 0.045(3) Uiso 1 1 d . . .
H29A H 0.8149 -0.1682 0.1759 0.067 Uiso 1 1 calc R . .
H29B H 0.8444 -0.1403 0.2128 0.067 Uiso 1 1 calc R . .
H29C H 0.9105 -0.1068 0.1877 0.067 Uiso 1 1 calc R . .
Cl1 Cl 0.7693(2) 0.61266(18) 0.15011(9) 0.0640(10) Uani 1 1 d U . .
O1 O 0.8106(6) 0.5819(4) 0.17911(19) 0.070(3) Uiso 1 1 d . . .
O2 O 0.7666(6) 0.6940(5) 0.1546(2) 0.083(3) Uiso 1 1 d . . .
O3 O 0.6862(7) 0.5620(6) 0.1359(2) 0.120(4) Uiso 1 1 d . . .
O4 O 0.8299(7) 0.6096(6) 0.1254(2) 0.113(4) Uiso 1 1 d . . .
Cl2 Cl 0.1389(3) 0.7341(2) 0.32274(11) 0.0986(15) Uani 1 1 d DU . .
O5 O 0.0532(7) 0.7041(7) 0.3111(3) 0.190(6) Uiso 1 1 d D . .
O6 O 0.1864(6) 0.7843(5) 0.3027(2) 0.109(4) Uiso 1 1 d D . .
O7 O 0.1397(9) 0.7893(7) 0.3495(3) 0.203(6) Uiso 1 1 d D . .
O8 O 0.1893(8) 0.6846(7) 0.3368(3) 0.207(6) Uiso 1 1 d D . .
C397 C 0.8825(6) 0.7902(6) 0.1012(2) 0.054(4) Uiso 1 1 d D . .
H397 H 0.8646 0.7508 0.1175 0.065 Uiso 1 1 calc R . .
Cl3 Cl 0.9496(2) 0.87816(17) 0.12160(7) 0.0588(9) Uani 1 1 d DU . .
Cl4 Cl 0.7827(2) 0.80993(19) 0.07973(9) 0.0772(11) Uani 1 1 d DU . .
Cl5 Cl 0.9448(2) 0.74994(19) 0.07754(7) 0.0722(11) Uani 1 1 d DU . .
C398 C 0.3526(7) 0.7139(6) 0.2821(2) 0.065(4) Uiso 1 1 d D . .
H398 H 0.3282 0.7512 0.2949 0.078 Uiso 1 1 calc R . .
Cl6 Cl 0.4679(3) 0.7574(2) 0.27912(10) 0.1020(14) Uani 1 1 d DU . .
Cl7 Cl 0.3497(3) 0.6256(2) 0.30187(9) 0.0977(14) Uani 1 1 d DU . .
Cl8 Cl 0.2855(3) 0.6972(2) 0.24466(8) 0.0979(14) Uani 1 1 d DU . .
C399 C 0.1094(7) -0.0502(7) 0.2985(2) 0.074(4) Uiso 1 1 d D . .
H399 H 0.1264 -0.1006 0.3062 0.089 Uiso 1 1 calc R . .
Cl9 Cl 0.1944(3) 0.0006(3) 0.27814(10) 0.1289(17) Uani 1 1 d DU . .
Cl10 Cl 0.0029(3) -0.0736(2) 0.27414(10) 0.1103(16) Uani 1 1 d DU . .
Cl11 Cl 0.1050(2) 0.0097(2) 0.33127(9) 0.0961(13) Uani 1 1 d DU . .
C400 C 0.0799(9) 0.1093(6) 0.1657(2) 0.085(5) Uiso 1 1 d D . .
H400 H 0.1461 0.1163 0.1633 0.102 Uiso 1 1 calc R . .
Cl12 Cl 0.0657(3) 0.2043(2) 0.17342(9) 0.1189(17) Uani 1 1 d DU . .
Cl13 Cl 0.0670(3) 0.0485(3) 0.19689(14) 0.165(2) Uani 1 1 d DU . .
Cl14 Cl 0.0208(5) 0.0705(3) 0.13020(16) 0.276(4) Uani 1 1 d DU . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 C1 1.994(9) . y
Au1 P1 2.275(3) . y
Au1 Ag1 3.2240(9) . y
Au2 C10 1.997(10) . y
Au2 P2 2.270(3) . y
Au2 Ag1 3.1950(9) . y
Au3 C15 1.967(10) . y
Au3 P3 2.275(3) . y
Au3 Ag1 3.3397(9) . y
Au4 C24 2.004(10) . y
Au4 P4 2.277(3) . y
Au4 Ag1 3.2009(9) . y
Ag1 C1 2.451(9) . y
Ag1 C10 2.476(9) . y
Ag1 C15 2.482(9) . y
Ag1 C24 2.482(9) . y
P1 C31 1.809(5) . y
P1 C41 1.821(5) . y
P1 C51 1.831(5) . y
P2 C71 1.819(5) . y
P2 C61 1.820(5) . y
P2 C81 1.829(5) . y
P3 C91 1.813(5) . y
P3 C101 1.817(5) . y
P3 C111 1.822(5) . y
P4 C131 1.808(5) . y
P4 C121 1.818(5) . y
P4 C141 1.822(5) . y
C1 C2 1.199(11) . y
C2 C3 1.456(11) . y
C3 C4 1.389(11) . y
C3 C8 1.416(11) . y
C4 C5 1.420(12) . y
C4 C11 1.500(12) . y
C5 C6 1.389(12) . y
C5 C12 1.522(12) . y
C6 C7 1.393(12) . y
C6 C13 1.513(12) . y
C7 C8 1.395(11) . y
C7 C14 1.513(12) . y
C8 C9 1.456(12) . y
C9 C10 1.184(11) . y
C15 C16 1.221(11) . y
C16 C17 1.459(11) . y
C17 C22 1.402(11) . y
C17 C18 1.407(11) . y
C18 C19 1.414(12) . y
C18 C25 1.511(11) . y
C19 C20 1.370(12) . y
C19 C26 1.532(12) . y
C20 C21 1.393(11) . y
C20 C27 1.515(12) . y
C21 C22 1.381(11) . y
C21 C28 1.493(11) . y
C22 C23 1.456(11) . y
C23 C24 1.193(11) . y
C31 C32 1.3900 . ?
C31 C36 1.3900 . ?
C32 C33 1.3900 . ?
C33 C34 1.3900 . ?
C34 C35 1.3900 . ?
C34 C37 1.498(10) . ?
C35 C36 1.3900 . ?
C41 C42 1.3900 . ?
C41 C46 1.3900 . ?
C42 C43 1.3900 . ?
C43 C44 1.3900 . ?
C44 C45 1.3900 . ?
C44 C47 1.554(10) . ?
C45 C46 1.3900 . ?
C51 C52 1.3900 . ?
C51 C56 1.3900 . ?
C52 C53 1.3900 . ?
C53 C54 1.3900 . ?
C54 C55 1.3900 . ?
C54 C57 1.538(9) . ?
C55 C56 1.3900 . ?
C61 C62 1.3900 . ?
C61 C66 1.3900 . ?
C62 C63 1.3900 . ?
C63 C64 1.3900 . ?
C64 C65 1.3900 . ?
C64 C67 1.520(11) . ?
C65 C66 1.3900 . ?
C71 C72 1.3900 . ?
C71 C76 1.3900 . ?
C72 C73 1.3900 . ?
C73 C74 1.3900 . ?
C74 C75 1.3900 . ?
C74 C77 1.512(10) . ?
C75 C76 1.3900 . ?
C81 C82 1.3900 . ?
C81 C86 1.3900 . ?
C82 C83 1.3900 . ?
C83 C84 1.3900 . ?
C84 C85 1.3900 . ?
C84 C87 1.501(10) . ?
C85 C86 1.3900 . ?
C91 C92 1.3900 . ?
C91 C96 1.3900 . ?
C92 C93 1.3900 . ?
C93 C94 1.3900 . ?
C94 C95 1.3900 . ?
C94 C97 1.529(11) . ?
C95 C96 1.3900 . ?
C101 C102 1.3900 . ?
C101 C106 1.3900 . ?
C102 C103 1.3900 . ?
C103 C104 1.3900 . ?
C104 C105 1.3900 . ?
C104 C107 1.505(12) . ?
C105 C106 1.3900 . ?
C111 C112 1.3900 . ?
C111 C116 1.3900 . ?
C112 C113 1.3900 . ?
C113 C114 1.3900 . ?
C114 C115 1.3900 . ?
C114 C117 1.521(10) . ?
C115 C116 1.3900 . ?
C121 C122 1.3900 . ?
C121 C126 1.3900 . ?
C122 C123 1.3900 . ?
C123 C124 1.3900 . ?
C124 C125 1.3900 . ?
C124 C127 1.516(10) . ?
C125 C126 1.3900 . ?
C131 C132 1.3900 . ?
C131 C136 1.3900 . ?
C132 C133 1.3900 . ?
C133 C134 1.3900 . ?
C134 C135 1.3900 . ?
C134 C137 1.510(10) . ?
C135 C136 1.3900 . ?
C141 C142 1.3900 . ?
C141 C146 1.3900 . ?
C142 C143 1.3900 . ?
C143 C144 1.3900 . ?
C144 C145 1.3900 . ?
C144 C147 1.515(11) . ?
C145 C146 1.3900 . ?
Au5 C151 1.983(10) . y
Au5 P5 2.269(3) . y
Au5 Ag2 3.4457(9) . y
Au8 C174 1.999(10) . y
Au8 P8 2.282(3) . y
Au8 Ag2 3.1662(9) . y
Au6 C160 1.995(10) . y
Au6 P6 2.273(3) . y
Au6 Ag2 3.3328(9) . y
Au7 C165 1.984(10) . y
Au7 P7 2.278(3) . y
Au7 Ag2 3.5134(9) . y
Ag2 C160 2.463(9) . y
Ag2 C165 2.468(10) . y
Ag2 C174 2.480(9) . y
Ag2 C151 2.498(10) . y
Ag2 C166 2.633(9) . y
P5 C191 1.804(5) . y
P5 C201 1.817(5) . y
P5 C181 1.830(5) . y
P6 C221 1.815(5) . y
P6 C231 1.819(5) . y
P6 C211 1.819(5) . y
P7 C261 1.814(5) . y
P7 C251 1.816(5) . y
P7 C241 1.847(5) . y
P8 C281 1.807(5) . y
P8 C271 1.816(5) . y
P8 C291 1.838(5) . y
C151 C152 1.199(11) . y
C152 C153 1.467(11) . y
C153 C154 1.410(12) . y
C153 C158 1.420(11) . y
C154 C155 1.412(12) . y
C154 C161 1.507(12) . y
C155 C156 1.371(12) . y
C155 C162 1.541(13) . y
C156 C157 1.401(12) . y
C156 C163 1.517(12) . y
C157 C158 1.417(12) . y
C157 C164 1.506(12) . y
C158 C159 1.418(12) . y
C159 C160 1.196(11) . y
C165 C166 1.220(11) . y
C166 C167 1.428(12) . y
C167 C168 1.413(12) . y
C167 C172 1.440(12) . y
C168 C169 1.365(12) . y
C168 C175 1.502(12) . y
C169 C170 1.387(12) . y
C169 C176 1.517(13) . y
C170 C171 1.399(12) . y
C170 C177 1.516(12) . y
C171 C172 1.385(12) . y
C171 C178 1.502(12) . y
C172 C173 1.453(12) . y
C173 C174 1.196(11) . y
C181 C182 1.3900 . ?
C181 C186 1.3900 . ?
C182 C183 1.3900 . ?
C183 C184 1.3900 . ?
C184 C185 1.3900 . ?
C184 C187 1.522(11) . ?
C185 C186 1.3900 . ?
C191 C192 1.3900 . ?
C191 C196 1.3900 . ?
C192 C193 1.3900 . ?
C193 C194 1.3900 . ?
C194 C195 1.3900 . ?
C194 C197 1.529(10) . ?
C195 C196 1.3900 . ?
C201 C202 1.3900 . ?
C201 C206 1.3900 . ?
C202 C203 1.3900 . ?
C203 C204 1.3900 . ?
C204 C205 1.3900 . ?
C204 C207 1.510(11) . ?
C205 C206 1.3900 . ?
C211 C212 1.3900 . ?
C211 C216 1.3900 . ?
C212 C213 1.3900 . ?
C213 C214 1.3900 . ?
C214 C215 1.3900 . ?
C214 C217 1.512(11) . ?
C215 C216 1.3900 . ?
C221 C222 1.3900 . ?
C221 C226 1.3900 . ?
C222 C223 1.3900 . ?
C223 C224 1.3900 . ?
C224 C225 1.3900 . ?
C224 C227 1.500(12) . ?
C225 C226 1.3900 . ?
C231 C232 1.3900 . ?
C231 C236 1.3900 . ?
C232 C233 1.3900 . ?
C233 C234 1.3900 . ?
C234 C235 1.3900 . ?
C234 C237 1.519(10) . ?
C235 C236 1.3900 . ?
C241 C242 1.3900 . ?
C241 C246 1.3900 . ?
C242 C243 1.3900 . ?
C243 C244 1.3900 . ?
C244 C245 1.3900 . ?
C244 C247 1.516(10) . ?
C245 C246 1.3900 . ?
C251 C252 1.3900 . ?
C251 C256 1.3900 . ?
C252 C253 1.3900 . ?
C253 C254 1.3900 . ?
C254 C255 1.3900 . ?
C254 C257 1.515(10) . ?
C255 C256 1.3900 . ?
C261 C262 1.3900 . ?
C261 C266 1.3900 . ?
C262 C263 1.3900 . ?
C263 C264 1.3900 . ?
C264 C265 1.3900 . ?
C264 C267 1.511(10) . ?
C265 C266 1.3900 . ?
C271 C272 1.3900 . ?
C271 C276 1.3900 . ?
C272 C273 1.3900 . ?
C273 C274 1.3900 . ?
C274 C275 1.3900 . ?
C274 C277 1.526(10) . ?
C275 C276 1.3900 . ?
C281 C282 1.3900 . ?
C281 C286 1.3900 . ?
C282 C283 1.3900 . ?
C283 C284 1.3900 . ?
C284 C285 1.3900 . ?
C284 C287 1.539(10) . ?
C285 C286 1.3900 . ?
C291 C292 1.3900 . ?
C291 C296 1.3900 . ?
C292 C293 1.3900 . ?
C293 C294 1.3900 . ?
C294 C295 1.3900 . ?
C294 C297 1.525(9) . ?
C295 C296 1.3900 . ?
Cl1 O3 1.408(10) . ?
Cl1 O2 1.420(8) . ?
Cl1 O1 1.451(8) . ?
Cl1 O4 1.503(10) . ?
Cl2 O5 1.301(10) . ?
Cl2 O8 1.344(10) . ?
Cl2 O6 1.387(8) . ?
Cl2 O7 1.470(10) . ?
C397 Cl5 1.712(9) . ?
C397 Cl4 1.736(9) . ?
C397 Cl3 1.763(9) . ?
C398 Cl8 1.732(10) . ?
C398 Cl7 1.742(9) . ?
C398 Cl6 1.764(10) . ?
C399 Cl10 1.735(10) . ?
C399 Cl11 1.740(10) . ?
C399 Cl9 1.743(10) . ?
C400 Cl14 1.680(10) . ?
C400 Cl13 1.707(10) . ?
C400 Cl12 1.727(10) . ?
