#------------------------------------------------------------------------------
#$Date: 2015-01-27 21:58:39 +0200 (Tue, 27 Jan 2015) $
#$Revision: 130149 $
#$URL: svn://www.crystallography.net/cod/cif/4/06/19/4061929.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4061929
_journal_name_full               Organometallics
_journal_year                    2003
_chemical_formula_sum            'C27 H34 Cl2 F2 N2 Si2 Sn'
_chemical_formula_weight         670.33
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                112.90(3)
_cell_angle_beta                 93.79(3)
_cell_angle_gamma                109.62(3)
_cell_formula_units_Z            2
_cell_length_a                   11.283(2)
_cell_length_b                   12.240(2)
_cell_length_c                   13.236(3)
_cell_measurement_temperature    293(2)
_cell_volume                     1544.8(5)
_diffrn_ambient_temperature      293(2)
_exptl_crystal_density_diffrn    1.441
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'TRICLINIC' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_database_code               4061929
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Sn1 Sn 0.49314(3) 0.72888(3) 0.50404(3) 0.05186(19) Uani 1 1 d . . .
Si1 Si 0.55738(16) 0.70906(15) 0.23456(14) 0.0553(4) Uani 1 1 d . . .
Si2 Si 0.32531(18) 0.71108(17) 0.69328(17) 0.0667(5) Uani 1 1 d . . .
Cl4 Cl 0.1317(3) 0.6936(3) 0.0544(3) 0.1223(10) Uani 1 1 d . . .
F1 F 0.3682(4) 0.5692(4) 0.4679(5) 0.114(2) Uani 1 1 d . . .
F2 F 0.3690(4) 0.7615(4) 0.3662(3) 0.0809(13) Uani 1 1 d . . .
Cl1 Cl -0.0454(3) 0.5902(3) 0.1678(4) 0.1683(19) Uani 1 1 d . . .
N1 N 0.6773(5) 0.9144(4) 0.5426(5) 0.0582(13) Uani 1 1 d . . .
N2 N 0.6401(5) 0.7142(4) 0.7025(4) 0.0527(12) Uani 1 1 d . . .
C1 C 0.8485(7) 0.7536(8) 0.5054(7) 0.078(2) Uani 1 1 d . . .
H1A H 0.8356 0.6678 0.4636 0.094 Uiso 1 1 calc R . .
C2 C 0.9786(8) 0.8346(10) 0.5787(8) 0.094(3) Uani 1 1 d . . .
H2A H 1.0383 0.7976 0.5795 0.113 Uiso 1 1 calc R . .
C3 C 1.0073(7) 0.9404(9) 0.6340(7) 0.087(3) Uani 1 1 d . . .
H3 H 1.0881 0.9965 0.6813 0.105 Uiso 1 1 calc R . .
C4 C 0.9076(6) 0.9733(7) 0.6211(6) 0.0698(19) Uani 1 1 d . . .
C5 C 0.7790(6) 0.8921(5) 0.5508(5) 0.0548(14) Uani 1 1 d . . .
C6 C 0.7468(6) 0.7792(5) 0.4877(5) 0.0541(14) Uani 1 1 d . . .
C7 C 0.9271(8) 1.0813(7) 0.6743(8) 0.096(3) Uani 1 1 d . . .
H7 H 1.0061 1.1439 0.7213 0.115 Uiso 1 1 calc R . .
C8 C 0.8231(9) 1.1025(7) 0.6588(8) 0.102(3) Uani 1 1 d . . .
H8A H 0.8334 1.1882 0.6960 0.122 Uiso 1 1 calc R . .
C9 C 0.7013(8) 1.0183(6) 0.5965(6) 0.076(2) Uani 1 1 d . . .
H9 H 0.6360 1.0491 0.5993 0.091 Uiso 1 1 calc R . .
C10 C 0.6102(5) 0.7003(5) 0.4106(5) 0.0543(15) Uani 1 1 d . . .
H10A H 0.5973 0.6102 0.3887 0.065 Uiso 1 1 calc R . .
C11 C 0.3952(7) 0.5895(7) 0.1425(7) 0.084(2) Uani 1 1 d . . .
H11A H 0.3829 0.6002 0.0750 0.126 Uiso 1 1 calc R . .
H11B H 0.3292 0.6031 0.1819 0.126 Uiso 1 1 calc R . .
H11C H 0.3904 0.5037 0.1232 0.126 Uiso 1 1 calc R . .
C12 C 0.6741(8) 0.6931(8) 0.1708(7) 0.084(3) Uani 1 1 d . . .
H12A H 0.6578 0.6963 0.1001 0.126 Uiso 1 1 calc R . .
H12B H 0.6783 0.6118 0.1578 0.126 Uiso 1 1 calc R . .
H12C H 0.7547 0.7618 0.2172 0.126 Uiso 1 1 calc R . .
C13 C 0.5574(10) 0.8473(8) 0.2157(8) 0.087(2) Uani 1 1 d . . .
H13A H 0.5326 0.8233 0.1368 0.131 Uiso 1 1 calc R . .
H13B H 0.6424 0.9147 0.2463 0.131 Uiso 1 1 calc R . .
H13C H 0.4972 0.8775 0.2538 0.131 Uiso 1 1 calc R . .
C14 C 0.6284(7) 0.9535(5) 0.8663(6) 0.0706(19) Uani 1 1 d . . .
H14A H 0.5878 1.0105 0.8765 0.085 Uiso 1 1 calc R . .
C15 C 0.7446(8) 0.9951(6) 0.9744(6) 0.084(2) Uani 1 1 d . . .
H15A H 0.7583 1.0742 1.0333 0.100 Uiso 1 1 calc R . .
C16 C 0.8226(7) 0.9433(6) 0.9974(6) 0.074(2) Uani 1 1 d . . .
H16A H 0.8843 0.9723 1.0623 0.088 Uiso 1 1 calc R . .
C17 C 0.7897(6) 0.8459(5) 0.9081(5) 0.0572(15) Uani 1 1 d . . .
C18 C 0.6748(6) 0.8058(5) 0.7979(5) 0.0517(14) Uani 1 1 d . . .
C19 C 0.5885(6) 0.8575(5) 0.7745(5) 0.0547(15) Uani 1 1 d . . .
C20 C 0.8657(7) 0.7869(7) 0.9239(6) 0.0641(17) Uani 1 1 d . . .
H20A H 0.9278 0.8087 0.9860 0.077 Uiso 1 1 calc R . .
C21 C 0.8265(7) 0.6947(7) 0.8296(7) 0.076(2) Uani 1 1 d . . .
H21A H 0.8642 0.6351 0.8177 0.091 Uiso 1 1 calc R . .
C22 C 0.7145(6) 0.6612(5) 0.7194(6) 0.0613(16) Uani 1 1 d . . .
H22A H 0.7046 0.5870 0.6562 0.074 Uiso 1 1 calc R . .
C23 C 0.4657(6) 0.8077(5) 0.6578(5) 0.0572(16) Uani 1 1 d . . .
H23A H 0.4522 0.8852 0.6651 0.069 Uiso 1 1 calc R . .
C24 C 0.3607(9) 0.5989(8) 0.7645(10) 0.101(3) Uani 1 1 d . . .
H24A H 0.4325 0.6518 0.8284 0.152 Uiso 1 1 calc R . .
H24B H 0.3805 0.5322 0.7100 0.152 Uiso 1 1 calc R . .
H24C H 0.2855 0.5605 0.7883 0.152 Uiso 1 1 calc R . .
C25 C 0.3001(9) 0.7971(9) 0.8118(8) 0.108(4) Uani 1 1 d . . .
H25A H 0.3688 0.8197 0.8723 0.162 Uiso 1 1 calc R . .
H25B H 0.2194 0.7483 0.8223 0.162 Uiso 1 1 calc R . .
H25C H 0.2972 0.8742 0.8109 0.162 Uiso 1 1 calc R . .
C26 C 0.1748(7) 0.6501(9) 0.5434(8) 0.104(3) Uani 1 1 d . . .
H26A H 0.1822 0.7233 0.5298 0.156 Uiso 1 1 calc R . .
H26B H 0.0909 0.6145 0.5566 0.156 Uiso 1 1 calc R . .
H26C H 0.1863 0.5860 0.4790 0.156 Uiso 1 1 calc R . .
C27 C 0.0983(9) 0.6049(9) 0.1593(9) 0.115(4) Uani 1 1 d . . .
H27A H 0.1046 0.5217 0.1268 0.137 Uiso 1 1 calc R . .
H27B H 0.1578 0.6582 0.2324 0.137 Uiso 1 1 calc R . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Sn1 F1 1.836(4) . ?
Sn1 C10 1.894(5) . ?
Sn1 C23 1.981(5) . ?
Sn1 N1 2.350(5) . ?
Sn1 F2 2.461(5) . ?
Si1 C12 1.636(7) . ?
Si1 C13 1.804(8) . ?
Si1 C11 1.869(8) . ?
Si1 C10 2.418(7) . ?
Si2 C25 1.620(7) . ?
Si2 C23 1.844(6) . ?
Si2 C24 2.064(10) . ?
Si2 C26 2.219(11) . ?
Cl4 C27 2.053(14) . ?
Cl1 C27 1.586(10) . ?
N1 C9 1.113(7) . ?
N1 C5 1.272(8) . ?
N2 C18 1.242(6) . ?
N2 C22 1.276(8) . ?
N2 C19 1.944(6) . ?
C1 C6 1.316(9) . ?
C1 C2 1.472(12) . ?
C2 C3 1.126(12) . ?
C3 C4 1.337(11) . ?
C4 C7 1.162(10) . ?
C4 C5 1.447(9) . ?
C5 C6 1.210(7) . ?
C6 C10 1.542(9) . ?
C7 C8 1.305(14) . ?
C8 C9 1.367(12) . ?
C14 C19 1.233(8) . ?
C14 C15 1.661(12) . ?
C15 C16 1.327(12) . ?
C16 C17 1.226(8) . ?
C16 C20 2.020(9) . ?
C17 C20 1.346(10) . ?
C17 C18 1.678(10) . ?
C18 C19 1.403(9) . ?
C19 C23 1.760(10) . ?
C20 C21 1.234(10) . ?
C21 C22 1.685(11) . ?
