#------------------------------------------------------------------------------
#$Date: 2015-01-27 21:58:39 +0200 (Tue, 27 Jan 2015) $
#$Revision: 130149 $
#$URL: svn://www.crystallography.net/cod/cif/4/06/19/4061930.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4061930
_journal_name_full               Organometallics
_journal_year                    2003
_chemical_formula_sum            'C26 H34 Cl4 N2 Si2 Sn'
_chemical_formula_weight         691.22
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                115.860(10)
_cell_angle_beta                 91.670(10)
_cell_angle_gamma                110.830(10)
_cell_formula_units_Z            2
_cell_length_a                   11.1390(10)
_cell_length_b                   12.6950(10)
_cell_length_c                   13.9690(10)
_cell_measurement_temperature    293(2)
_cell_volume                     1621.0(2)
_diffrn_ambient_temperature      293(2)
_exptl_crystal_density_diffrn    1.416
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'TRICLINIC' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_database_code               4061930
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Sn1 Sn -0.00695(2) -0.00236(2) 0.253213(18) 0.03895(11) Uani 1 1 d . . .
Cl1 Cl 0.02817(13) 0.16020(12) 0.44329(9) 0.0598(3) Uani 1 1 d . . .
Cl2 Cl 0.17310(11) 0.13704(13) 0.20838(11) 0.0667(3) Uani 1 1 d . . .
Si1 Si -0.20928(13) 0.14652(13) 0.23890(11) 0.0548(3) Uani 1 1 d . . .
Si2 Si 0.26442(12) -0.05795(13) 0.30695(10) 0.0526(3) Uani 1 1 d . . .
N1 N -0.2174(3) -0.1403(3) 0.2642(3) 0.0433(7) Uani 1 1 d . . .
N2 N -0.0403(3) -0.1990(3) 0.0846(3) 0.0446(7) Uani 1 1 d . . .
C1 C -0.3587(5) -0.1670(5) 0.0131(4) 0.0575(11) Uani 1 1 d . . .
H1A H -0.3364 -0.1251 -0.0309 0.080 Uiso 1 1 d R . .
C2 C -0.4742(5) -0.2811(6) -0.0255(4) 0.0701(14) Uani 1 1 d . . .
H2A H -0.5302 -0.3137 -0.0944 0.080 Uiso 1 1 d R . .
C3 C -0.5073(5) -0.3446(5) 0.0330(4) 0.0679(13) Uani 1 1 d . . .
H3A H -0.5880 -0.4202 0.0056 0.080 Uiso 1 1 d R . .
C4 C -0.4246(4) -0.2978(4) 0.1347(4) 0.0528(10) Uani 1 1 d . . .
C5 C -0.3082(4) -0.1849(4) 0.1711(3) 0.0425(8) Uani 1 1 d . . .
C6 C -0.2757(4) -0.1148(4) 0.1130(3) 0.0462(9) Uani 1 1 d . . .
C7 C -0.4488(5) -0.3575(5) 0.2014(4) 0.0651(12) Uani 1 1 d . . .
H7A H -0.5282 -0.4330 0.1798 0.080 Uiso 1 1 d R . .
C8 C -0.3627(5) -0.3085(5) 0.2948(4) 0.0646(12) Uani 1 1 d . . .
H8A H -0.3803 -0.3488 0.3402 0.080 Uiso 1 1 d R . .
C9 C -0.2443(4) -0.1995(5) 0.3231(4) 0.0530(10) Uani 1 1 d . . .
H9A H -0.1822 -0.1658 0.3892 0.080 Uiso 1 1 d R . .
C10 C -0.1574(4) 0.0098(4) 0.1617(3) 0.0441(8) Uani 1 1 d . . .
H10A H -0.1233 0.0210 0.1029 0.080 Uiso 1 1 d R . .
C11 C -0.3009(6) 0.1187(6) 0.3404(5) 0.0741(15) Uani 1 1 d . . .
H11A H -0.3754 0.0373 0.3042 0.080 Uiso 1 1 d R . .
H11B H -0.2444 0.1191 0.3938 0.080 Uiso 1 1 d R . .
H11C H -0.3307 0.1858 0.3756 0.080 Uiso 1 1 d R . .
C12 C -0.3196(8) 0.1493(7) 0.1383(6) 0.093(2) Uani 1 1 d . . .
H12A H -0.3947 0.0684 0.1014 0.080 Uiso 1 1 d R . .
H12B H -0.3485 0.2165 0.1757 0.080 Uiso 1 1 d R . .
H12C H -0.2725 0.1648 0.0860 0.080 Uiso 1 1 d R . .
C13 C -0.0637(6) 0.3053(5) 0.3059(5) 0.0809(16) Uani 1 1 d . . .
H13A H -0.0932 0.3718 0.3443 0.080 Uiso 1 1 d R . .
H13B H -0.0050 0.3041 0.3568 0.080 Uiso 1 1 d R . .
H13C H -0.0186 0.3212 0.2530 0.080 Uiso 1 1 d R . .
C14 C -0.0864(5) -0.2365(5) -0.0182(4) 0.0586(11) Uani 1 1 d . . .
H14A H -0.0757 -0.1718 -0.0394 0.080 Uiso 1 1 d R . .
C15 C -0.1472(5) -0.3652(6) -0.0972(4) 0.0713(15) Uani 1 1 d . . .
H15A H -0.1784 -0.3883 -0.1714 0.080 Uiso 1 1 d R . .
C16 C -0.1644(5) -0.4570(5) -0.0682(4) 0.0689(14) Uani 1 1 d . . .
H16A H -0.2050 -0.5459 -0.1222 0.080 Uiso 1 1 d R . .
C17 C -0.1187(4) -0.4229(4) 0.0413(4) 0.0567(11) Uani 1 1 d . . .
C18 C -0.0513(4) -0.2911(4) 0.1151(3) 0.0444(8) Uani 1 1 d . . .
C19 C -0.1372(5) -0.5110(5) 0.0811(5) 0.0715(14) Uani 1 1 d . . .
H19A H -0.1802 -0.6014 0.0318 0.080 Uiso 1 1 d R . .
C20 C -0.0920(6) -0.4684(5) 0.1872(5) 0.0716(14) Uani 1 1 d . . .
H20A H -0.1104 -0.5293 0.2139 0.080 Uiso 1 1 d R . .
C21 C -0.0208(5) -0.3372(5) 0.2601(4) 0.0584(11) Uani 1 1 d . . .
H21A H 0.0128 -0.3104 0.3348 0.080 Uiso 1 1 d R . .
C22 C 0.0022(4) -0.2464(4) 0.2255(3) 0.0450(8) Uani 1 1 d . . .
C23 C 0.0803(4) -0.1053(4) 0.2994(3) 0.0415(8) Uani 1 1 d . . .
H23A H 0.0677 -0.0889 0.3714 0.080 Uiso 1 1 d R . .
C24 C 0.3564(5) 0.1143(6) 0.4068(5) 0.0783(16) Uani 1 1 d . . .
H24A H 0.4488 0.1369 0.4091 0.080 Uiso 1 1 d R . .
H24B H 0.3289 0.1659 0.3852 0.080 Uiso 1 1 d R . .
H24C H 0.3402 0.1292 0.4777 0.080 Uiso 1 1 d R . .
C25 C 0.3158(7) -0.1528(8) 0.3577(6) 0.090(2) Uani 1 1 d . . .
H25A H 0.4083 -0.1299 0.3614 0.080 Uiso 1 1 d R . .
H25B H 0.2985 -0.1339 0.4290 0.080 Uiso 1 1 d R . .
H25C H 0.2680 -0.2428 0.3087 0.080 Uiso 1 1 d R . .
C26 C 0.3011(5) -0.0986(6) 0.1700(4) 0.0723(15) Uani 1 1 d . . .
H26A H 0.3942 -0.0735 0.1757 0.080 Uiso 1 1 d R . .
H26B H 0.2558 -0.1892 0.1223 0.080 Uiso 1 1 d R . .
H26C H 0.2725 -0.0532 0.1410 0.080 Uiso 1 1 d R . .
C27 C 0.7034(10) 0.5365(7) 0.5330(6) 0.142(3) Uani 1 1 d D . .
D27A H 0.7968 0.5846 0.5486 0.080 Uiso 1 1 d R . .
D27B H 0.6645 0.5969 0.5647 0.080 Uiso 1 1 d R . .
Cl3 Cl 0.6765(3) 0.4447(3) 0.5939(2) 0.1769(14) Uani 1 1 d D . .
Cl4 Cl 0.6499(4) 0.4572(3) 0.3975(2) 0.1847(14) Uani 1 1 d D . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Sn1 C23 2.161(4) . ?
Sn1 C10 2.167(4) . ?
Sn1 N1 2.434(3) . ?
Sn1 Cl1 2.4591(12) . ?
Sn1 Cl2 2.4622(11) . ?
Sn1 N2 2.466(3) . ?
Si1 C11 1.854(5) . ?
Si1 C12 1.860(6) . ?
Si1 C13 1.873(6) . ?
Si1 C10 1.905(4) . ?
Si2 C26 1.852(5) . ?
Si2 C24 1.855(6) . ?
Si2 C25 1.868(6) . ?
Si2 C23 1.906(4) . ?
N1 C9 1.312(5) . ?
N1 C5 1.381(5) . ?
N2 C14 1.319(5) . ?
N2 C18 1.377(5) . ?
C1 C6 1.386(6) . ?
C1 C2 1.413(7) . ?
C2 C3 1.354(8) . ?
C3 C4 1.421(6) . ?
C4 C5 1.413(6) . ?
C4 C7 1.414(7) . ?
C5 C6 1.415(5) . ?
C6 C10 1.492(6) . ?
C7 C8 1.343(7) . ?
C8 C9 1.416(6) . ?
C14 C15 1.394(7) . ?
C15 C16 1.348(8) . ?
C16 C17 1.416(7) . ?
C17 C18 1.408(6) . ?
C17 C19 1.409(7) . ?
C18 C22 1.414(5) . ?
C19 C20 1.344(8) . ?
C20 C21 1.406(7) . ?
C21 C22 1.382(6) . ?
C22 C23 1.502(6) . ?
C27 Cl4 1.673(7) . ?
C27 Cl3 1.674(6) . ?
