#------------------------------------------------------------------------------
#$Date: 2016-02-16 22:30:59 +0200 (Tue, 16 Feb 2016) $
#$Revision: 176467 $
#$URL: svn://www.crystallography.net/cod/cif/4/06/23/4062344.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4062344
loop_
_publ_author_name
'H. Schmidbaur'
'B. Djordjevic'
'K. A. Porter'
'A. Schier'
'S. Nogai'
_publ_section_title
;
Dinuclear Gold(I) "A-Frame" Complexes from Geminal Diauration of
2,4-Diketones, Methylene-Disulfones and Cyanomethylsulfones
;
_journal_name_full               Organometallics
_journal_year                    2003
_chemical_formula_sum            'C45.25 H37.5 Au2 Cl2.5 N O2 P2 S'
_chemical_formula_weight         1203.82
_chemical_name_common            (Ph3PAu)2C(SO2Ph)CN
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 94.8214(4)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   18.69290(10)
_cell_length_b                   26.5958(2)
_cell_length_c                   17.5871(2)
_cell_measurement_temperature    143(2)
_cell_volume                     8712.53(13)
_diffrn_ambient_temperature      143(2)
_exptl_crystal_density_diffrn    1.836
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_original_formula_sum        'C45.25 H37.50 Au2 Cl2.50 N O2 P2 S'
_cod_database_code               4062344
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.161414(14) 0.396215(10) 0.598885(15) 0.02672(7) Uani 1 1 d . . .
P1 P 0.14328(10) 0.38119(7) 0.72313(10) 0.0284(4) Uani 1 1 d . . .
S1 S 0.26323(10) 0.37563(7) 0.46706(11) 0.0309(4) Uani 1 1 d . . .
Au2 Au 0.093706(15) 0.353575(10) 0.454287(15) 0.02717(7) Uani 1 1 d . . .
P2 P -0.00110(10) 0.30037(7) 0.43241(10) 0.0263(4) Uani 1 1 d . . .
S2 S 0.23957(10) 0.62899(7) 1.04616(10) 0.0288(4) Uani 1 1 d . . .
Au3 Au 0.406701(15) 0.650878(10) 1.049092(16) 0.02940(8) Uani 1 1 d . A .
P3 P 0.50084(10) 0.70503(8) 1.06590(11) 0.0323(4) Uani 1 1 d . . .
Au4 Au 0.333850(14) 0.606874(10) 0.907437(14) 0.02487(7) Uani 1 1 d . . .
P4 P 0.35130(10) 0.61877(7) 0.78234(10) 0.0279(4) Uani 1 1 d . A .
O11 O 0.2765(3) 0.3788(2) 0.3878(3) 0.0408(13) Uani 1 1 d . . .
C11 C 0.1809(4) 0.4022(3) 0.4835(4) 0.0262(15) Uani 1 1 d . . .
N11 N 0.1704(4) 0.4917(2) 0.4260(4) 0.0385(16) Uani 1 1 d . . .
C12 C 0.1743(4) 0.4517(3) 0.4499(4) 0.0269(15) Uani 1 1 d . . .
O12 O 0.2688(3) 0.3267(2) 0.5022(3) 0.0449(14) Uani 1 1 d . . .
C21 C 0.3195(4) 0.6022(3) 1.0242(4) 0.0229(14) Uani 1 1 d . A .
O21 O 0.2311(3) 0.6245(2) 1.1269(3) 0.0381(13) Uani 1 1 d . . .
N21 N 0.3347(4) 0.5127(2) 1.0806(4) 0.0389(16) Uani 1 1 d . A .
C22 C 0.3272(4) 0.5525(2) 1.0584(4) 0.0224(14) Uani 1 1 d . . .
O22 O 0.2338(3) 0.6786(2) 1.0135(3) 0.0448(14) Uani 1 1 d . . .
C111 C 0.1679(4) 0.3169(3) 0.7476(4) 0.0284(16) Uani 1 1 d . . .
C112 C 0.1676(5) 0.2977(3) 0.8207(5) 0.049(2) Uani 1 1 d . . .
H11A H 0.1485 0.3175 0.8591 0.058 Uiso 1 1 calc R . .
C113 C 0.1943(5) 0.2509(3) 0.8388(5) 0.048(2) Uani 1 1 d . . .
H11B H 0.1938 0.2389 0.8896 0.057 Uiso 1 1 calc R . .
C114 C 0.2215(5) 0.2214(4) 0.7851(5) 0.052(2) Uani 1 1 d . . .
H11C H 0.2379 0.1885 0.7979 0.063 Uiso 1 1 calc R . .
C115 C 0.2250(7) 0.2394(4) 0.7125(6) 0.069(3) Uani 1 1 d . . .
H11D H 0.2464 0.2198 0.6754 0.083 Uiso 1 1 calc R . .
C116 C 0.1968(6) 0.2866(3) 0.6936(5) 0.052(2) Uani 1 1 d . . .
H11E H 0.1974 0.2984 0.6427 0.062 Uiso 1 1 calc R . .
C121 C 0.0508(4) 0.3892(3) 0.7452(4) 0.0364(18) Uani 1 1 d . . .
C122 C 0.0025(5) 0.3486(4) 0.7345(5) 0.049(2) Uani 1 1 d . . .
H12A H 0.0191 0.3165 0.7198 0.058 Uiso 1 1 calc R . .
C123 C -0.0698(5) 0.3559(5) 0.7456(6) 0.064(3) Uani 1 1 d . . .
H12B H -0.1027 0.3287 0.7381 0.077 Uiso 1 1 calc R . .
C124 C -0.0938(6) 0.4022(5) 0.7674(5) 0.064(3) Uani 1 1 d . . .
H12C H -0.1431 0.4067 0.7752 0.077 Uiso 1 1 calc R . .
C125 C -0.0484(6) 0.4410(4) 0.7778(6) 0.067(3) Uani 1 1 d . . .
H12D H -0.0658 0.4727 0.7927 0.080 Uiso 1 1 calc R . .
C126 C 0.0252(5) 0.4353(4) 0.7667(6) 0.061(3) Uani 1 1 d . . .
H12E H 0.0570 0.4631 0.7740 0.073 Uiso 1 1 calc R . .
C131 C 0.1979(4) 0.4189(3) 0.7911(4) 0.0343(17) Uani 1 1 d . . .
C132 C 0.1849(5) 0.4232(4) 0.8674(5) 0.050(2) Uani 1 1 d . . .
H13A H 0.1427 0.4089 0.8849 0.060 Uiso 1 1 calc R . .
C133 C 0.2333(6) 0.4483(4) 0.9181(6) 0.060(3) Uani 1 1 d . . .
H13B H 0.2243 0.4507 0.9703 0.072 Uiso 1 1 calc R . .
C134 C 0.2939(6) 0.4695(4) 0.8935(6) 0.068(3) Uani 1 1 d . . .
H13C H 0.3270 0.4866 0.9285 0.081 Uiso 1 1 calc R . .
C135 C 0.3064(6) 0.4661(4) 0.8189(6) 0.074(3) Uani 1 1 d . . .
H13D H 0.3487 0.4807 0.8021 0.088 Uiso 1 1 calc R . .
C136 C 0.2585(5) 0.4416(4) 0.7663(5) 0.057(3) Uani 1 1 d . . .
H13E H 0.2674 0.4404 0.7140 0.068 Uiso 1 1 calc R . .
C141 C 0.0246(4) 0.2361(3) 0.4604(4) 0.0272(15) Uani 1 1 d . . .
C142 C 0.0810(4) 0.2293(3) 0.5127(5) 0.0399(19) Uani 1 1 d . . .
H14A H 0.1072 0.2576 0.5330 0.048 Uiso 1 1 calc R . .
C143 C 0.1010(5) 0.1810(3) 0.5373(5) 0.048(2) Uani 1 1 d . . .
H14B H 0.1405 0.1762 0.5742 0.057 Uiso 1 1 calc R . .
C144 C 0.0625(5) 0.1398(3) 0.5070(5) 0.044(2) Uani 1 1 d . . .
H14C H 0.0751 0.1069 0.5242 0.053 Uiso 1 1 calc R . .
C145 C 0.0062(5) 0.1465(3) 0.4523(5) 0.047(2) Uani 1 1 d . . .
H14D H -0.0195 0.1183 0.4310 0.057 Uiso 1 1 calc R . .
C146 C -0.0130(4) 0.1955(3) 0.4283(5) 0.0380(18) Uani 1 1 d . . .
H14E H -0.0515 0.2006 0.3904 0.046 Uiso 1 1 calc R . .
C151 C -0.0355(4) 0.2961(3) 0.3325(4) 0.0304(16) Uani 1 1 d . . .
C152 C -0.1066(5) 0.2923(4) 0.3084(5) 0.057(3) Uani 1 1 d . . .
H15A H -0.1412 0.2932 0.3450 0.068 Uiso 1 1 calc R . .
C153 C -0.1292(6) 0.2871(5) 0.2325(5) 0.070(3) Uani 1 1 d . . .
H15B H -0.1789 0.2843 0.2168 0.084 Uiso 1 1 calc R . .
C154 C -0.0794(6) 0.2862(4) 0.1798(5) 0.061(3) Uani 1 1 d . . .
H15C H -0.0944 0.2816 0.1273 0.073 Uiso 1 1 calc R . .
C155 C -0.0085(6) 0.2918(4) 0.2023(5) 0.060(3) Uani 1 1 d . . .
H15D H 0.0259 0.2922 0.1654 0.073 Uiso 1 1 calc R . .
C156 C 0.0136(5) 0.2971(3) 0.2788(5) 0.046(2) Uani 1 1 d . . .
H15E H 0.0631 0.3015 0.2944 0.055 Uiso 1 1 calc R . .
C161 C -0.0767(4) 0.3158(3) 0.4861(4) 0.0268(15) Uani 1 1 d . . .
C162 C -0.0815(4) 0.3642(3) 0.5147(5) 0.0400(19) Uani 1 1 d . . .
H16A H -0.0454 0.3883 0.5066 0.048 Uiso 1 1 calc R . .
C163 C -0.1395(5) 0.3774(3) 0.5553(5) 0.045(2) Uani 1 1 d . . .
H16B H -0.1433 0.4108 0.5736 0.055 Uiso 1 1 calc R . .
C164 C -0.1906(5) 0.3432(3) 0.5690(5) 0.042(2) Uani 1 1 d . . .
H16C H -0.2297 0.3529 0.5969 0.050 Uiso 1 1 calc R . .
C165 C -0.1862(4) 0.2935(3) 0.5422(5) 0.0389(19) Uani 1 1 d . . .
H16D H -0.2212 0.2692 0.5529 0.047 Uiso 1 1 calc R . .
C166 C -0.1302(4) 0.2809(3) 0.5002(4) 0.0335(17) Uani 1 1 d . . .
H16E H -0.1276 0.2478 0.4803 0.040 Uiso 1 1 calc R . .
C171 C 0.3285(4) 0.4154(3) 0.5169(4) 0.0335(17) Uani 1 1 d . . .
C172 C 0.3579(4) 0.4540(3) 0.4767(6) 0.045(2) Uani 1 1 d . . .
H17A H 0.3434 0.4593 0.4242 0.054 Uiso 1 1 calc R . .
C173 C 0.4083(5) 0.4845(4) 0.5144(8) 0.064(3) Uani 1 1 d . . .
H17B H 0.4290 0.5111 0.4877 0.077 Uiso 1 1 calc R . .
C174 C 0.4299(5) 0.4766(5) 0.5933(8) 0.073(4) Uani 1 1 d . . .
H17C H 0.4648 0.4978 0.6192 0.087 Uiso 1 1 calc R . .
C175 C 0.3999(5) 0.4384(5) 0.6310(7) 0.070(3) Uani 1 1 d . . .
H17D H 0.4141 0.4330 0.6835 0.084 Uiso 1 1 calc R . .
C176 C 0.3486(4) 0.4072(4) 0.5931(5) 0.054(2) Uani 1 1 d . . .
H17E H 0.3277 0.3805 0.6195 0.065 Uiso 1 1 calc R . .
C221 C 0.4741(4) 0.7669(3) 1.0307(4) 0.0306(16) Uani 1 1 d . A .
C222 C 0.4027(5) 0.7795(4) 1.0236(6) 0.059(3) Uani 1 1 d . . .
H22A H 0.3682 0.7548 1.0339 0.070 Uiso 1 1 calc R A .
C223 C 0.3793(6) 0.8270(4) 1.0019(7) 0.068(3) Uani 1 1 d . A .
H22B H 0.3295 0.8348 0.9989 0.081 Uiso 1 1 calc R . .
C224 C 0.4276(5) 0.8628(4) 0.9849(6) 0.055(2) Uani 1 1 d . . .
H22C H 0.4121 0.8958 0.9710 0.066 Uiso 1 1 calc R A .
C225 C 0.4968(6) 0.8507(4) 0.9879(8) 0.082(4) Uani 1 1 d . A .
H22D H 0.5303 0.8754 0.9747 0.098 Uiso 1 1 calc R . .
C226 C 0.5219(5) 0.8033(4) 1.0098(6) 0.058(3) Uani 1 1 d . . .
H22E H 0.5717 0.7958 1.0104 0.069 Uiso 1 1 calc R A .
C231 C 0.5779(4) 0.6858(3) 1.0161(4) 0.0322(17) Uani 1 1 d . A .
C232 C 0.6451(6) 0.7042(6) 1.0318(10) 0.125(7) Uani 1 1 d . . .
H23A H 0.6540 0.7285 1.0711 0.150 Uiso 1 1 calc R A .
C233 C 0.7003(6) 0.6882(7) 0.9915(11) 0.138(8) Uani 1 1 d . A .
H23B H 0.7460 0.7036 1.0011 0.166 Uiso 1 1 calc R . .
C234 C 0.6928(5) 0.6520(4) 0.9397(6) 0.053(2) Uani 1 1 d . . .
H23C H 0.7328 0.6394 0.9158 0.064 Uiso 1 1 calc R A .
C235 C 0.6292(7) 0.6347(6) 0.9229(8) 0.111(6) Uani 1 1 d . A .
H23D H 0.6223 0.6090 0.8856 0.133 Uiso 1 1 calc R . .
C236 C 0.5697(7) 0.6530(6) 0.9583(7) 0.111(6) Uani 1 1 d . . .
H23E H 0.5229 0.6420 0.9408 0.133 Uiso 1 1 calc R A .
C241 C 0.3392(4) 0.6847(3) 0.7591(4) 0.0314(17) Uani 1 1 d . . .
C242 C 0.3064(5) 0.7018(3) 0.6908(5) 0.0411(19) Uani 1 1 d . A .
H24A H 0.2914 0.6782 0.6521 0.049 Uiso 1 1 calc R . .
C243 C 0.2950(5) 0.7520(3) 0.6774(5) 0.049(2) Uani 1 1 d . . .
H24B H 0.2715 0.7627 0.6302 0.058 Uiso 1 1 calc R A .
C244 C 0.3167(7) 0.7864(4) 0.7307(6) 0.072(3) Uani 1 1 d . A .
H24C H 0.3078 0.8211 0.7214 0.086 Uiso 1 1 calc R . .
C245 C 0.3527(9) 0.7707(4) 0.7999(7) 0.095(5) Uani 1 1 d . . .
H24D H 0.3710 0.7946 0.8367 0.115 Uiso 1 1 calc R A .
C246 C 0.3608(7) 0.7200(4) 0.8135(6) 0.069(3) Uani 1 1 d . A .
H24E H 0.3819 0.7090 0.8617 0.082 Uiso 1 1 calc R . .
C251 C 0.2886(4) 0.5854(3) 0.7156(4) 0.0341(17) Uani 1 1 d . . .
C252 C 0.2207(6) 0.5770(5) 0.7374(5) 0.077(4) Uani 1 1 d . A .
H25A H 0.2087 0.5866 0.7868 0.093 Uiso 1 1 calc R . .
C253 C 0.1692(7) 0.5539(5) 0.6861(6) 0.087(4) Uani 1 1 d . . .
H25B H 0.1220 0.5485 0.7007 0.105 Uiso 1 1 calc R A .
C254 C 0.1862(6) 0.5392(4) 0.6150(6) 0.060(3) Uani 1 1 d . A .
H25C H 0.1510 0.5240 0.5802 0.071 Uiso 1 1 calc R . .
C255 C 0.2535(6) 0.5465(4) 0.5956(5) 0.059(3) Uani 1 1 d . . .
H25D H 0.2659 0.5355 0.5470 0.070 Uiso 1 1 calc R A .
C256 C 0.3055(5) 0.5699(3) 0.6449(5) 0.048(2) Uani 1 1 d . A .
H25E H 0.3525 0.5751 0.6296 0.058 Uiso 1 1 calc R . .
C261 C 0.4401(4) 0.6009(3) 0.7584(4) 0.0352(18) Uani 1 1 d . . .
C262 C 0.4740(5) 0.5622(3) 0.8007(5) 0.046(2) Uani 1 1 d . A .
H26A H 0.4507 0.5471 0.8410 0.055 Uiso 1 1 calc R . .
C263 C 0.5414(5) 0.5452(4) 0.7849(5) 0.055(2) Uani 1 1 d . . .
H26B H 0.5647 0.5191 0.8144 0.066 Uiso 1 1 calc R A .
C264 C 0.5735(5) 0.5668(4) 0.7261(5) 0.055(3) Uani 1 1 d . A .
H26C H 0.6197 0.5556 0.7150 0.066 Uiso 1 1 calc R . .
C265 C 0.5407(6) 0.6039(4) 0.6833(7) 0.073(3) Uani 1 1 d . . .
H26D H 0.5637 0.6184 0.6424 0.087 Uiso 1 1 calc R A .
C266 C 0.4732(5) 0.6205(4) 0.6997(6) 0.060(3) Uani 1 1 d . A .
H26E H 0.4500 0.6460 0.6690 0.072 Uiso 1 1 calc R . .
C271 C 0.1707(4) 0.5918(3) 0.9987(5) 0.0368(18) Uani 1 1 d . . .
C272 C 0.1424(5) 0.6057(5) 0.9269(5) 0.060(3) Uani 1 1 d . . .
H27A H 0.1589 0.6351 0.9031 0.072 Uiso 1 1 calc R . .
C273 C 0.0881(6) 0.5751(6) 0.8893(7) 0.085(4) Uani 1 1 d . . .
H27B H 0.0684 0.5841 0.8395 0.102 Uiso 1 1 calc R . .
C274 C 0.0647(5) 0.5348(6) 0.9222(9) 0.100(6) Uani 1 1 d . . .
H27C H 0.0285 0.5150 0.8955 0.120 Uiso 1 1 calc R . .
C275 C 0.0927(5) 0.5195(4) 0.9979(7) 0.060(3) Uani 1 1 d . . .
H27D H 0.0754 0.4903 1.0213 0.072 Uiso 1 1 calc R . .
C276 C 0.1458(4) 0.5494(3) 1.0350(4) 0.044(2) Uani 1 1 d . . .
H27E H 0.1651 0.5409 1.0850 0.052 Uiso 1 1 calc R . .
C211 C 0.5291(4) 0.7205(3) 1.1662(4) 0.020(5) Uani 0.546(14) 1 d PR A 1
C212 C 0.5204(4) 0.6834(3) 1.2202(4) 0.059(6) Uani 0.546(14) 1 d PR A 1
H21A H 0.4986 0.6523 1.2053 0.071 Uiso 0.546(14) 1 calc PR A 1
C213 C 0.5441(16) 0.6919(8) 1.2972(10) 0.063(7) Uani 0.546(14) 1 d P A 1
H21B H 0.5377 0.6670 1.3347 0.075 Uiso 0.546(14) 1 calc PR A 1
C214 C 0.5764(16) 0.7366(12) 1.3173(14) 0.051(5) Uani 0.546(14) 1 d P A 1
H21C H 0.5941 0.7419 1.3689 0.061 Uiso 0.546(14) 1 calc PR A 1
C215 C 0.5841(12) 0.7743(8) 1.2646(10) 0.064(6) Uani 0.546(14) 1 d P A 1
H21D H 0.6045 0.8058 1.2803 0.077 Uiso 0.546(14) 1 calc PR A 1
C216 C 0.5616(10) 0.7657(6) 1.1881(9) 0.048(5) Uani 0.546(14) 1 d P A 1
H21E H 0.5686 0.7908 1.1510 0.058 Uiso 0.546(14) 1 calc PR A 1
C211 C 0.5435(13) 0.7044(9) 1.1634(15) 0.035(6) Uani 0.454(14) 1 d P A 2
C212 C 0.6038(14) 0.6791(15) 1.1858(16) 0.106(13) Uani 0.454(14) 1 d P A 2
H21F H 0.6256 0.6580 1.1509 0.127 Uiso 0.454(14) 1 calc PR A 2
C213 C 0.6339(15) 0.6840(17) 1.2599(14) 0.125(17) Uani 0.454(14) 1 d P A 2
H21G H 0.6797 0.6699 1.2743 0.150 Uiso 0.454(14) 1 calc PR A 2
C214 C 0.5968(18) 0.7099(15) 1.3138(16) 0.066(9) Uani 0.454(14) 1 d P A 2
H21H H 0.6153 0.7125 1.3657 0.079 Uiso 0.454(14) 1 calc PR A 2
C215 C 0.534(3) 0.731(2) 1.2888(19) 0.14(3) Uani 0.454(14) 1 d P A 2
H21I H 0.5053 0.7453 1.3246 0.173 Uiso 0.454(14) 1 calc PR A 2
C216 C 0.510(2) 0.7313(16) 1.210(2) 0.13(2) Uani 0.454(14) 1 d P A 2
H21J H 0.4693 0.7510 1.1921 0.155 Uiso 0.454(14) 1 calc PR A 2
Cl1 Cl 0.28142(19) 0.54872(12) 0.33098(16) 0.0800(9) Uani 1 1 d . . .
Cl2 Cl 0.41686(19) 0.58665(16) 0.2868(3) 0.1085(13) Uani 1 1 d . . .
Cl3 Cl 0.0976(2) 0.40535(17) 0.2131(3) 0.1276(16) Uani 1 1 d . . .
Cl4 Cl 0.22861(18) 0.45406(12) 0.17983(16) 0.0771(8) Uani 1 1 d . . .
Cl5 Cl 0.0000 0.5000 0.5000 0.121(2) Uani 1 2 d S . .
Cl6 Cl 0.0093(4) 0.4557(3) 0.3539(5) 0.107(2) Uani 0.50 1 d P . .
C97 C 0.0046(12) 0.5094(8) 0.4041(12) 0.069(6) Uani 0.50 1 d P . .
H97A H -0.0384 0.5285 0.3839 0.083 Uiso 0.50 1 calc PR . .
H97B H 0.0473 0.5302 0.3964 0.083 Uiso 0.50 1 calc PR . .
C98 C 0.1746(5) 0.4358(4) 0.2521(5) 0.058(3) Uani 1 1 d . . .
H98A H 0.2021 0.4129 0.2881 0.069 Uiso 1 1 calc R . .
H98B H 0.1609 0.4658 0.2808 0.069 Uiso 1 1 calc R . .
C99 C 0.3333(6) 0.5634(4) 0.2549(5) 0.058(3) Uani 1 1 d . . .
H99A H 0.3393 0.5328 0.2241 0.070 Uiso 1 1 calc R . .
H99B H 0.3075 0.5887 0.2216 0.070 Uiso 1 1 calc R . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 C11 2.098(7) . ?
Au1 P1 2.2746(18) . ?
Au1 Au2 2.9689(4) . ?
P1 C131 1.809(8) . ?
P1 C111 1.813(7) . ?
P1 C121 1.816(8) . ?
S1 O11 1.439(5) . ?
S1 O12 1.440(5) . ?
S1 C11 1.739(7) . ?
S1 C171 1.788(8) . ?
Au2 C11 2.109(7) . ?
Au2 P2 2.2751(18) . ?
P2 C161 1.812(7) . ?
P2 C151 1.824(7) . ?
P2 C141 1.831(7) . ?
S2 O22 1.438(5) . ?
S2 O21 1.446(5) . ?
S2 C21 1.728(7) . ?
S2 C271 1.775(8) . ?
Au3 C21 2.098(7) . ?
Au3 P3 2.2740(19) . ?
Au3 Au4 2.9766(4) . ?
P3 C221 1.813(8) . ?
P3 C231 1.821(8) . ?
P3 C211 1.83(3) . ?
P3 C211 1.844(8) . ?
Au4 C21 2.096(6) . ?
Au4 P4 2.2732(18) . ?
P4 C261 1.809(8) . ?
P4 C241 1.811(7) . ?
P4 C251 1.818(8) . ?
C11 C12 1.444(10) . ?
N11 C12 1.144(9) . ?
C21 C22 1.455(9) . ?
N21 C22 1.134(9) . ?
C111 C112 1.383(11) . ?
C111 C116 1.388(11) . ?
C112 C113 1.369(12) . ?
C112 H11A 0.9500 . ?
C113 C114 1.358(13) . ?
C113 H11B 0.9500 . ?
C114 C115 1.371(13) . ?
C114 H11C 0.9500 . ?
C115 C116 1.391(13) . ?
C115 H11D 0.9500 . ?
C116 H11E 0.9500 . ?
C121 C126 1.380(12) . ?
C121 C122 1.410(12) . ?
C122 C123 1.395(13) . ?
C122 H12A 0.9500 . ?
C123 C124 1.377(15) . ?
C123 H12B 0.9500 . ?
C124 C125 1.338(15) . ?
C124 H12C 0.9500 . ?
C125 C126 1.414(13) . ?
C125 H12D 0.9500 . ?
C126 H12E 0.9500 . ?
C131 C136 1.385(11) . ?
C131 C132 1.389(11) . ?
C132 C133 1.386(12) . ?
C132 H13A 0.9500 . ?
C133 C134 1.368(15) . ?
C133 H13B 0.9500 . ?
C134 C135 1.355(14) . ?
C134 H13C 0.9500 . ?
C135 C136 1.394(13) . ?
C135 H13D 0.9500 . ?
C136 H13E 0.9500 . ?
C141 C142 1.352(11) . ?
C141 C146 1.384(10) . ?
C142 C143 1.398(11) . ?
C142 H14A 0.9500 . ?
C143 C144 1.391(13) . ?
C143 H14B 0.9500 . ?
C144 C145 1.377(13) . ?
C144 H14C 0.9500 . ?
C145 C146 1.408(12) . ?
C145 H14D 0.9500 . ?
C146 H14E 0.9500 . ?
C151 C152 1.365(12) . ?
C151 C156 1.370(11) . ?
C152 C153 1.373(13) . ?
C152 H15A 0.9500 . ?
C153 C154 1.369(14) . ?
C153 H15B 0.9500 . ?
C154 C155 1.359(14) . ?
C154 H15C 0.9500 . ?
C155 C156 1.382(12) . ?
C155 H15D 0.9500 . ?
C156 H15E 0.9500 . ?
C161 C162 1.387(10) . ?
C161 C166 1.402(10) . ?
C162 C163 1.392(11) . ?
C162 H16A 0.9500 . ?
C163 C164 1.355(12) . ?
C163 H16B 0.9500 . ?
C164 C165 1.408(11) . ?
C164 H16C 0.9500 . ?
C165 C166 1.373(11) . ?
C165 H16D 0.9500 . ?
C166 H16E 0.9500 . ?
C171 C176 1.379(12) . ?
C171 C172 1.386(11) . ?
C172 C173 1.371(13) . ?
C172 H17A 0.9500 . ?
C173 C174 1.428(16) . ?
C173 H17B 0.9500 . ?
C174 C175 1.358(17) . ?
C174 H17C 0.9500 . ?
C175 C176 1.396(14) . ?
C175 H17D 0.9500 . ?
C176 H17E 0.9500 . ?
C221 C222 1.371(12) . ?
C221 C226 1.389(11) . ?
C222 C223 1.379(14) . ?
C222 H22A 0.9500 . ?
C223 C224 1.363(14) . ?
C223 H22B 0.9500 . ?
C224 C225 1.330(14) . ?
C224 H22C 0.9500 . ?
C225 C226 1.389(14) . ?
C225 H22D 0.9500 . ?
C226 H22E 0.9500 . ?
C231 C236 1.338(13) . ?
C231 C232 1.356(13) . ?
C232 C233 1.367(16) . ?
C232 H23A 0.9500 . ?
C233 C234 1.324(15) . ?
C233 H23B 0.9500 . ?
C234 C235 1.285(14) . ?
C234 H23C 0.9500 . ?
C235 C236 1.407(17) . ?
C235 H23D 0.9500 . ?
C236 H23E 0.9500 . ?
C241 C246 1.375(12) . ?
C241 C242 1.379(11) . ?
C242 C243 1.372(12) . ?
C242 H24A 0.9500 . ?
C243 C244 1.346(14) . ?
C243 H24B 0.9500 . ?
C244 C245 1.404(15) . ?
C244 H24C 0.9500 . ?
C245 C246 1.377(14) . ?
C245 H24D 0.9500 . ?
C246 H24E 0.9500 . ?
C251 C256 1.372(11) . ?
C251 C252 1.375(13) . ?
C252 C253 1.403(13) . ?
C252 H25A 0.9500 . ?
C253 C254 1.372(14) . ?
C253 H25B 0.9500 . ?
C254 C255 1.346(14) . ?
C254 H25C 0.9500 . ?
C255 C256 1.393(13) . ?
C255 H25D 0.9500 . ?
C256 H25E 0.9500 . ?
C261 C266 1.352(12) . ?
C261 C262 1.393(11) . ?
C262 C263 1.389(12) . ?
C262 H26A 0.9500 . ?
C263 C264 1.364(13) . ?
C263 H26B 0.9500 . ?
C264 C265 1.356(13) . ?
C264 H26C 0.9500 . ?
C265 C266 1.388(13) . ?
C265 H26D 0.9500 . ?
C266 H26E 0.9500 . ?
C271 C272 1.378(12) . ?
C271 C276 1.395(10) . ?
C272 C273 1.420(16) . ?
C272 H27A 0.9500 . ?
C273 C274 1.31(2) . ?
C273 H27B 0.9500 . ?
C274 C275 1.447(19) . ?
C274 H27C 0.9500 . ?
C275 C276 1.389(12) . ?
C275 H27D 0.9500 . ?
C276 H27E 0.9500 . ?
C211 C216 1.387(17) . ?
C211 C212 1.3900 . ?
C212 C213 1.408(19) . ?
C212 H21A 0.9500 . ?
C213 C214 1.37(4) . ?
C213 H21B 0.9500 . ?
C214 C215 1.38(3) . ?
C214 H21C 0.9500 . ?
C215 C216 1.39(2) . ?
C215 H21D 0.9500 . ?
C216 H21E 0.9500 . ?
C211 C216 1.29(4) . ?
C211 C212 1.34(3) . ?
C212 C213 1.38(4) . ?
C212 H21F 0.9500 . ?
C213 C214 1.40(4) . ?
C213 H21G 0.9500 . ?
C214 C215 1.33(5) . ?
C214 H21H 0.9500 . ?
C215 C216 1.42(5) . ?
C215 H21I 0.9500 . ?
C216 H21J 0.9500 . ?
Cl1 C99 1.761(10) . ?
Cl2 C99 1.730(11) . ?
Cl3 C98 1.742(10) . ?
Cl4 C98 1.756(10) . ?
Cl5 C97 1.71(2) 3_566 ?
Cl5 C97 1.71(2) . ?
Cl6 C97 1.69(2) . ?
C97 H97A 0.9900 . ?
C97 H97B 0.9900 . ?
C98 H98A 0.9900 . ?
C98 H98B 0.9900 . ?
C99 H99A 0.9900 . ?
C99 H99B 0.9900 . ?
