#------------------------------------------------------------------------------
#$Date: 2017-02-15 13:07:33 +0200 (Wed, 15 Feb 2017) $
#$Revision: 192146 $
#$URL: file:///home/coder/svn-repositories/cod/cif/4/06/23/4062395.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4062395
loop_
_publ_author_name
'Alonso, Ester'
'Forniés, Juan'
'Fortuño, Consuelo'
'Martín, Antonio'
'Orpen, A. Guy'
_publ_section_title
;
 Reactivity of [NBu₄][(C₆F₅)₂M(μ-PPh₂)₂M'(acac-O,O')]
 (M, M' = Pt, Pd) toward Silver Centers. Synthesis of Polynuclear
 Complexes Containing M-Ag Bonds (M = Pd, Pt)
;
_journal_issue                   24
_journal_name_full               Organometallics
_journal_page_first              5011
_journal_page_last               5019
_journal_paper_doi               10.1021/om034047f
_journal_volume                  22
_journal_year                    2003
_chemical_formula_sum            'C60 H43 Ag Cl3 F10 O2 P3 Pt2'
_chemical_formula_weight         1683.25
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 96.63(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   13.261(5)
_cell_length_b                   22.962(7)
_cell_length_c                   20.048(7)
_cell_measurement_temperature    293(2)
_cell_volume                     6063.8(36)
_diffrn_ambient_temperature      293(2)
_exptl_crystal_density_diffrn    1.844
_refine_ls_R_factor_obs          0.0414
_refine_ls_wR_factor_obs         0.0968
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               4062395
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_thermal_displace_type
_atom_site_occupancy
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_group
Pt1 Pt 0.48989(2) 0.115900(13) 0.322241(14) 0.04009(9) Uani 1 d . .
Pt2 Pt 0.66117(2) 0.079384(13) 0.207583(14) 0.03737(9) Uani 1 d . .
Ag Ag 0.54470(6) 0.19415(3) 0.22606(4) 0.0620(2) Uani 1 d . .
P1 P 0.49730(15) 0.06542(8) 0.22287(9) 0.0380(4) Uani 1 d . .
P2 P 0.66290(15) 0.10563(9) 0.31596(9) 0.0391(4) Uani 1 d . .
C1 C 0.4996(6) 0.1674(5) 0.4085(4) 0.067(3) Uani 1 d . .
C2 C 0.4817(8) 0.1443(7) 0.4687(5) 0.087(4) Uani 1 d . .
C3 C 0.4803(10) 0.1778(9) 0.5267(6) 0.114(6) Uani 1 d . .
C4 C 0.4985(12) 0.2343(11) 0.5240(10) 0.147(10) Uani 1 d . .
C5 C 0.5169(10) 0.2605(7) 0.4634(8) 0.112(5) Uani 1 d . .
C6 C 0.5166(8) 0.2269(5) 0.4088(6) 0.078(3) Uani 1 d . .
F2 F 0.4647(6) 0.0876(4) 0.4746(3) 0.119(3) Uani 1 d . .
F3 F 0.4598(8) 0.1537(6) 0.5844(3) 0.202(6) Uani 1 d . .
F4 F 0.4987(8) 0.2697(6) 0.5788(5) 0.231(7) Uani 1 d . .
F5 F 0.5367(8) 0.3179(4) 0.4624(6) 0.192(6) Uani 1 d . .
F6 F 0.5344(6) 0.2536(3) 0.3523(4) 0.100(2) Uani 1 d . .
C7 C 0.3335(6) 0.1233(4) 0.3177(4) 0.047(2) Uani 1 d . .
C8 C 0.2711(6) 0.0817(4) 0.3444(4) 0.051(2) Uani 1 d . .
C9 C 0.1702(7) 0.0886(5) 0.3435(5) 0.068(3) Uani 1 d . .
C10 C 0.1205(7) 0.1376(5) 0.3169(6) 0.077(3) Uani 1 d . .
C11 C 0.1785(8) 0.1798(4) 0.2904(6) 0.072(3) Uani 1 d . .
C12 C 0.2804(7) 0.1712(4) 0.2918(5) 0.058(2) Uani 1 d . .
F8 F 0.3135(4) 0.0321(3) 0.3701(3) 0.083(2) Uani 1 d . .
F9 F 0.1141(5) 0.0458(3) 0.3692(3) 0.101(2) Uani 1 d . .
F10 F 0.0205(4) 0.1442(4) 0.3161(4) 0.118(3) Uani 1 d . .
F11 F 0.1318(5) 0.2275(3) 0.2623(4) 0.126(3) Uani 1 d . .
F12 F 0.3321(4) 0.2151(3) 0.2662(4) 0.091(2) Uani 1 d . .
C13 C 0.4095(6) 0.0924(3) 0.1519(4) 0.043(2) Uani 1 d . .
C14 C 0.4457(7) 0.1206(3) 0.0976(4) 0.051(2) Uani 1 d . .
H14 H 0.5175(7) 0.1254(3) 0.0965(4) 0.103(6) Uiso 1 d R .
C15 C 0.3779(8) 0.1412(4) 0.0452(5) 0.070(3) Uani 1 d . .
H15 H 0.4028(8) 0.1594(4) 0.0072(5) 0.103(6) Uiso 1 d R .
C17 C 0.2393(7) 0.1096(4) 0.1004(6) 0.073(3) Uani 1 d . .
H17 H 0.1675(7) 0.1063(4) 0.1020(6) 0.103(6) Uiso 1 d R .
C16 C 0.2748(9) 0.1370(5) 0.0470(5) 0.080(3) Uani 1 d . .
H16 H 0.2283(9) 0.1524(5) 0.0111(5) 0.103(6) Uiso 1 d R .
C18 C 0.3060(6) 0.0881(4) 0.1518(5) 0.061(2) Uani 1 d . .
H18 H 0.2798(6) 0.0688(4) 0.1887(5) 0.103(6) Uiso 1 d R .
C19 C 0.4717(6) -0.0131(3) 0.2192(4) 0.046(2) Uani 1 d . .
C20 C 0.4747(7) -0.0418(4) 0.1597(5) 0.060(2) Uani 1 d . .
H20 H 0.4879(7) -0.0206(4) 0.1204(5) 0.103(6) Uiso 1 d R .
C21 C 0.4580(9) -0.1007(5) 0.1575(7) 0.088(4) Uani 1 d . .
H21 H 0.4607(9) -0.1203(5) 0.1154(7) 0.103(6) Uiso 1 d R .
C22 C 0.4404(9) -0.1310(4) 0.2096(8) 0.095(4) Uani 1 d . .
H22 H 0.4289(9) -0.1721(4) 0.2047(8) 0.103(6) Uiso 1 d R .
C23 C 0.4361(8) -0.1048(5) 0.2705(6) 0.081(3) Uani 1 d . .
H23 H 0.4235(8) -0.1284(5) 0.3082(6) 0.103(6) Uiso 1 d R .
C24 C 0.4513(7) -0.0441(4) 0.2765(5) 0.068(3) Uani 1 d . .
H24 H 0.4488(7) -0.0249(4) 0.3188(5) 0.103(6) Uiso 1 d R .
C25 C 0.7275(6) 0.0516(3) 0.3713(4) 0.045(2) Uani 1 d . .
C26 C 0.6782(7) 0.0193(4) 0.4167(4) 0.056(2) Uani 1 d . .
H26 H 0.6064(7) 0.0242(4) 0.4174(4) 0.103(6) Uiso 1 d R .
C27 C 0.7306(9) -0.0189(4) 0.4592(5) 0.075(3) Uani 1 d . .
H27 H 0.6961(9) -0.0388(4) 0.4921(5) 0.103(6) Uiso 1 d R .
C28 C 0.8334(9) -0.0284(5) 0.4571(5) 0.079(3) Uani 1 d . .
H28 H 0.8691(9) -0.0573(5) 0.4852(5) 0.103(6) Uiso 1 d R .
C29 C 0.8815(7) 0.0030(4) 0.4128(5) 0.068(3) Uani 1 d . .
H29 H 0.9533(7) -0.0018(4) 0.4119(5) 0.103(6) Uiso 1 d R .
C30 C 0.8316(6) 0.0414(4) 0.3699(4) 0.055(2) Uani 1 d . .
H30 H 0.8669(6) 0.0622(4) 0.3381(4) 0.103(6) Uiso 1 d R .
C31 C 0.7392(5) 0.1701(3) 0.3388(4) 0.042(2) Uani 1 d . .
C32 C 0.7764(6) 0.2059(4) 0.2915(4) 0.051(2) Uani 1 d . .
H32 H 0.7648(6) 0.1957(4) 0.2449(4) 0.103(6) Uiso 1 d R .
C33 C 0.8297(8) 0.2558(4) 0.3110(5) 0.072(3) Uani 1 d . .
H33 H 0.8575(8) 0.2793(4) 0.2779(5) 0.103(6) Uiso 1 d R .
C34 C 0.8436(9) 0.2723(5) 0.3768(6) 0.086(3) Uani 1 d . .
H34 H 0.8764(9) 0.3085(5) 0.3898(6) 0.103(6) Uiso 1 d R .
C35 C 0.8107(9) 0.2361(4) 0.4240(5) 0.081(3) Uani 1 d . .
H35 H 0.8247(9) 0.2464(4) 0.4705(5) 0.103(6) Uiso 1 d R .
C36 C 0.7571(7) 0.1854(4) 0.4066(4) 0.060(2) Uani 1 d . .
H36 H 0.7331(7) 0.1610(4) 0.4404(4) 0.103(6) Uiso 1 d R .
O1 O 0.8148(4) 0.0928(3) 0.2015(3) 0.0554(15) Uani 1 d . .
O2 O 0.6451(4) 0.0476(3) 0.1101(3) 0.059(2) Uani 1 d . .
C37 C 0.9698(8) 0.0953(7) 0.1598(6) 0.121(5) Uani 1 d . .
H37A H 0.9875(8) 0.1117(7) 0.2035(6) 0.103(6) Uiso 1 d R .
H37B H 1.0097(8) 0.0609(7) 0.1551(6) 0.103(6) Uiso 1 d R .
H37C H 0.9828(8) 0.1232(7) 0.1262(6) 0.103(6) Uiso 1 d R .
C38 C 0.8607(7) 0.0796(4) 0.1511(5) 0.065(3) Uani 1 d . .
C39 C 0.8175(8) 0.0546(5) 0.0909(5) 0.075(3) Uani 1 d . .
H39 H 0.8622(8) 0.0464(5) 0.0576(5) 0.103(6) Uiso 1 d R .
C40 C 0.7150(8) 0.0409(4) 0.0743(4) 0.067(3) Uani 1 d . .
C41 C 0.6794(10) 0.0161(7) 0.0044(5) 0.129(6) Uani 1 d . .
H41A H 0.6077(10) 0.0088(7) 0.0012(5) 0.103(6) Uiso 1 d R .
H41B H 0.6931(10) 0.0437(7) -0.0294(5) 0.103(6) Uiso 1 d R .
H41C H 0.7144(10) -0.0197(7) -0.0024(5) 0.103(6) Uiso 1 d R .
P3 P 0.5569(2) 0.27638(9) 0.15416(11) 0.0507(5) Uani 1 d . .
C42 C 0.6379(7) 0.3332(4) 0.1935(5) 0.060(2) Uani 1 d . .
C43 C 0.7212(7) 0.3542(5) 0.1674(6) 0.082(3) Uani 1 d . .
H43 H 0.7381(7) 0.3394(5) 0.1253(6) 0.103(6) Uiso 1 d R .
C44 C 0.7809(9) 0.3981(5) 0.2047(9) 0.107(5) Uani 1 d . .
H44 H 0.8418(9) 0.4119(5) 0.1883(9) 0.103(6) Uiso 1 d R .
C45 C 0.7521(11) 0.4211(5) 0.2604(10) 0.119(6) Uani 1 d . .
H45 H 0.7912(11) 0.4522(5) 0.2826(10) 0.103(6) Uiso 1 d R .
C46 C 0.6716(11) 0.3996(5) 0.2865(8) 0.114(5) Uani 1 d . .
H46 H 0.6537(11) 0.4150(5) 0.3281(8) 0.103(6) Uiso 1 d R .
C47 C 0.6137(9) 0.3553(4) 0.2522(6) 0.088(3) Uani 1 d . .
H47 H 0.5543(9) 0.3404(4) 0.2695(6) 0.103(6) Uiso 1 d R .
C48 C 0.6085(7) 0.2574(4) 0.0768(4) 0.058(2) Uani 1 d . .
C49 C 0.5682(10) 0.2786(6) 0.0154(6) 0.096(4) Uani 1 d . .
H49 H 0.5101(10) 0.3038(6) 0.0109(6) 0.103(6) Uiso 1 d R .
C50 C 0.6175(15) 0.2618(8) -0.0416(7) 0.147(7) Uani 1 d . .
H50 H 0.5891(15) 0.2747(8) -0.0853(7) 0.103(6) Uiso 1 d R .
C51 C 0.6979(12) 0.2273(7) -0.0374(7) 0.126(6) Uani 1 d . .
H51 H 0.7306(12) 0.2181(7) -0.0764(7) 0.103(6) Uiso 1 d R .
C52 C 0.7330(10) 0.2065(6) 0.0222(6) 0.094(4) Uani 1 d . .
H52 H 0.7929(10) 0.1827(6) 0.0266(6) 0.103(6) Uiso 1 d R .
C53 C 0.6877(8) 0.2187(5) 0.0782(5) 0.077(3) Uani 1 d . .
H53 H 0.7107(8) 0.1994(5) 0.1197(5) 0.103(6) Uiso 1 d R .
C54 C 0.4373(6) 0.3121(4) 0.1267(4) 0.053(2) Uani 1 d . .
C55 C 0.3480(7) 0.2805(4) 0.1278(5) 0.063(2) Uani 1 d . .
H55 H 0.3498(7) 0.2409(4) 0.1433(5) 0.103(6) Uiso 1 d R .
C56 C 0.2564(8) 0.3084(5) 0.1057(6) 0.088(3) Uani 1 d . .
H56 H 0.1938(8) 0.2872(5) 0.1042(6) 0.103(6) Uiso 1 d R .
C57 C 0.2543(10) 0.3666(5) 0.0861(6) 0.088(4) Uani 1 d . .
H57 H 0.1911(10) 0.3859(5) 0.0725(6) 0.103(6) Uiso 1 d R .
C58 C 0.3410(10) 0.3950(5) 0.0859(6) 0.091(4) Uani 1 d . .
H58 H 0.3400(10) 0.4346(5) 0.0706(6) 0.103(6) Uiso 1 d R .
C59 C 0.4323(8) 0.3695(4) 0.1077(6) 0.080(3) Uani 1 d . .
H59 H 0.4936(8) 0.3920(4) 0.1098(6) 0.103(6) Uiso 1 d R .
C60 C 0.3261(13) 0.4207(6) 0.3251(8) 0.123(5) Uani 1 d . .
H60 H 0.2568(13) 0.4296(6) 0.3303(8) 0.103(6) Uiso 1 d R .
Cl1 Cl 0.3340(3) 0.3466(2) 0.3088(3) 0.162(2) Uani 1 d . .
Cl2 Cl 0.3975(7) 0.4398(3) 0.3970(3) 0.239(3) Uani 1 d . .
Cl3 Cl 0.3590(5) 0.4603(2) 0.2598(3) 0.178(2) Uani 1 d . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 C7 2.072(8) . ?
Pt1 C1 2.087(9) . ?
Pt1 P1 2.317(2) . ?
Pt1 P2 2.324(2) . ?
Pt1 Ag 2.7925(10) . ?
Pt2 O2 2.075(5) . ?
Pt2 O1 2.078(5) . ?
Pt2 P1 2.252(2) . ?
Pt2 P2 2.252(2) . ?
Pt2 Ag 3.0983(11) . ?
Ag P3 2.392(2) . ?
Ag P1 3.021(2) . ?
Ag P2 3.030(2) . ?
P1 C19 1.835(8) . ?
P1 C13 1.838(7) . ?
P2 C25 1.812(8) . ?
P2 C31 1.821(8) . ?
C1 C2 1.363(14) . ?
C1 C6 1.386(15) . ?
C2 F2 1.33(2) . ?
C2 C3 1.40(2) . ?
C3 C4 1.32(3) . ?
C3 F3 1.34(2) . ?
C4 F4 1.366(15) . ?
C4 C5 1.40(3) . ?
C5 C6 1.340(15) . ?
C5 F5 1.34(2) . ?
C6 F6 1.332(13) . ?
C7 C12 1.374(12) . ?
C7 C8 1.410(11) . ?
C8 C9 1.345(12) . ?
C8 F8 1.347(10) . ?
C9 F9 1.370(11) . ?
C9 C10 1.380(14) . ?
C10 F10 1.333(10) . ?
C10 C11 1.381(15) . ?
C11 F11 1.349(11) . ?
C11 C12 1.363(13) . ?
C12 F12 1.355(10) . ?
C13 C18 1.375(12) . ?
C13 C14 1.400(11) . ?
C14 C15 1.386(12) . ?
C15 C16 1.375(14) . ?
C17 C18 1.370(12) . ?
C17 C16 1.372(15) . ?
C19 C20 1.367(11) . ?
C19 C24 1.404(12) . ?
C20 C21 1.370(13) . ?
C21 C22 1.30(2) . ?
C22 C23 1.37(2) . ?
C23 C24 1.412(14) . ?
C25 C26 1.394(11) . ?
C25 C30 1.405(11) . ?
C26 C27 1.357(12) . ?
C27 C28 1.386(14) . ?
C28 C29 1.359(13) . ?
C29 C30 1.350(12) . ?
C31 C32 1.388(11) . ?
C31 C36 1.398(11) . ?
C32 C33 1.379(12) . ?
C33 C34 1.364(14) . ?
C34 C35 1.367(14) . ?
C35 C36 1.387(12) . ?
O1 C38 1.276(10) . ?
O2 C40 1.244(10) . ?
C37 C38 1.481(14) . ?
C38 C39 1.399(13) . ?
C39 C40 1.398(13) . ?
C40 C41 1.537(13) . ?
P3 C42 1.812(9) . ?
P3 C54 1.814(8) . ?
P3 C48 1.818(9) . ?
C42 C47 1.354(14) . ?
C42 C43 1.363(13) . ?
C43 C44 1.44(2) . ?
C44 C45 1.33(2) . ?
C45 C46 1.34(2) . ?
C46 C47 1.40(2) . ?
C48 C49 1.374(13) . ?
C48 C53 1.374(13) . ?
C49 C50 1.43(2) . ?
C50 C51 1.32(2) . ?
C51 C52 1.32(2) . ?
C52 C53 1.362(14) . ?
C54 C59 1.371(12) . ?
C54 C55 1.392(12) . ?
C55 C56 1.400(13) . ?
C56 C57 1.39(2) . ?
C57 C58 1.32(2) . ?
C58 C59 1.370(15) . ?
C60 Cl2 1.69(2) . ?
C60 Cl3 1.69(2) . ?
C60 Cl1 1.737(15) . ?
