#------------------------------------------------------------------------------
#$Date: 2021-08-30 09:29:47 +0300 (Mon, 30 Aug 2021) $
#$Revision: 268283 $
#$URL: file:///home/coder/svn-repositories/cod/cif/4/06/37/4063783.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4063783
loop_
_publ_author_name
'Gopi, Kanniyappan'
'Thirupathi, Natesan'
'Nethaji, Munirathinam'
_publ_section_title
;
 Synthesis, Reactivity, Structural Aspects, and Solution Dynamics of
 Cyclopalladated Compounds
 ofN,N′,N′′-Tris(2-anisyl)guanidine
;
_journal_issue                   3
_journal_name_full               Organometallics
_journal_page_first              572
_journal_paper_doi               10.1021/om1009445
_journal_volume                  30
_journal_year                    2011
_chemical_formula_moiety         'C50 H46 Cl6 F6 N6 O10 Pd2'
_chemical_formula_sum            'C50 H46 Cl6 F6 N6 O10 Pd2'
_chemical_formula_weight         1430.42
_chemical_name_systematic
;

 ?

;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 108.0110(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   20.5592(16)
_cell_length_b                   13.8844(11)
_cell_length_c                   21.5284(17)
_cell_measurement_reflns_used    687
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      27.50
_cell_measurement_theta_min      2.50
_cell_volume                     5844.2(8)
_computing_cell_refinement       'BRUKER SMART APEX CCD'
_computing_data_collection       'BRUKER SMART APEX CCD'
_computing_data_reduction        'BRUKER SAINT'
_computing_molecular_graphics    ORTEP-III
_computing_publication_material  'WINGX V1.64.05'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    SHELXS-97
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean 0.3
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'BRUKER SMART APEX CCD'
_diffrn_measurement_method       OMEGA
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0267
_diffrn_reflns_av_sigmaI/netI    0.0204
_diffrn_reflns_limit_h_max       27
_diffrn_reflns_limit_h_min       -26
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       28
_diffrn_reflns_limit_l_min       -28
_diffrn_reflns_number            31794
_diffrn_reflns_theta_full        27.50
_diffrn_reflns_theta_max         27.50
_diffrn_reflns_theta_min         1.80
_exptl_absorpt_coefficient_mu    0.968
_exptl_absorpt_correction_T_max  0.7974
_exptl_absorpt_correction_T_min  0.7189
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            COLORLESS
_exptl_crystal_density_diffrn    1.626
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       RECTANGULAR
_exptl_crystal_F_000             2864
_exptl_crystal_size_max          0.37
_exptl_crystal_size_mid          0.29
_exptl_crystal_size_min          0.25
_refine_diff_density_max         1.019
_refine_diff_density_min         -1.058
_refine_diff_density_rms         0.071
_refine_ls_extinction_coef       0.00270(13)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   0.700
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           fullcycle
_refine_ls_number_parameters     365
_refine_ls_number_reflns         6689
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.700
_refine_ls_R_factor_all          0.0455
_refine_ls_R_factor_gt           0.0396
_refine_ls_shift/su_max          0.018
_refine_ls_shift/su_mean         0.002
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1136P)²+20.7278P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1158
_refine_ls_wR_factor_ref         0.1254
_reflns_number_gt                5769
_reflns_number_total             6689
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            om1009445_si_001.cif
_cod_data_source_block           demo_3
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'MONOCLINIC' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from
2010-06-29.

'_exptl_absorpt_correction_type' value 'EMPIRICAL'
changed to 'empirical' according to
/home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 

2021-08-27
Formula fixed to be consistent with given Z
                 miguel
;
_cod_original_formula_sum            'C25 H23 Cl3 F3 N3 O5 Pd'
_cod_original_formula_weight         715.21
_cod_original_formula_moiety         'C25 H23 CL3 F3 N3 O5 PD'
_cod_original_sg_symbol_H-M      C2/c
_cod_database_code               4063783
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
C1 C -0.04039(13) -0.20528(18) 0.16282(12) 0.0494(6) Uani 1 1 d .
C2 C -0.05969(17) -0.2880(2) 0.11256(16) 0.0680(8) Uani 1 1 d .
C3 C 0.19127(13) -0.04581(19) 0.34745(13) 0.0486(6) Uani 1 1 d .
C4 C 0.24118(16) -0.0700(2) 0.32002(18) 0.0636(8) Uani 1 1 d .
H4 H 0.2366 -0.0501 0.2776 0.076 Uiso 1 1 calc R
C5 C 0.29845(17) -0.1235(3) 0.3541(2) 0.0841(11) Uani 1 1 d .
H5 H 0.3317 -0.1391 0.3347 0.101 Uiso 1 1 calc R
C6 C 0.30510(18) -0.1525(3) 0.4161(2) 0.0870(12) Uani 1 1 d .
H6 H 0.3433 -0.1879 0.4393 0.104 Uiso 1 1 calc R
C7 C 0.25546(18) -0.1299(2) 0.44501(16) 0.0701(9) Uani 1 1 d .
H7 H 0.2607 -0.1497 0.4875 0.084 Uiso 1 1 calc R
C8 C 0.19815(16) -0.0778(2) 0.41073(14) 0.0562(7) Uani 1 1 d .
C9 C 0.1543(3) -0.0727(4) 0.50119(18) 0.0995(15) Uani 1 1 d .
H9A H 0.1606 -0.1407 0.5090 0.149 Uiso 1 1 calc R
H9B H 0.1145 -0.0519 0.5117 0.149 Uiso 1 1 calc R
H9C H 0.1937 -0.0389 0.5280 0.149 Uiso 1 1 calc R
C10 C 0.12370(12) 0.0968(2) 0.32048(12) 0.0462(5) Uani 1 1 d .
C11 C 0.15699(15) 0.2325(2) 0.40024(19) 0.0709(9) Uani 1 1 d .
C12 C 0.1649(2) 0.3092(3) 0.3633(3) 0.0972(15) Uani 1 1 d .
H12 H 0.1679 0.2992 0.3216 0.117 Uiso 1 1 calc R
C13 C 0.1686(3) 0.4029(4) 0.3886(4) 0.135(3) Uani 1 1 d .
H13 H 0.1722 0.4552 0.3630 0.162 Uiso 1 1 calc R
C14 C 0.1669(3) 0.4172(4) 0.4502(5) 0.154(3) Uani 1 1 d .
H14 H 0.1702 0.4795 0.4667 0.185 Uiso 1 1 calc R
C15 C 0.1604(2) 0.3422(4) 0.4885(3) 0.130(2) Uani 1 1 d .
H15 H 0.1594 0.3540 0.5307 0.156 Uiso 1 1 calc R
C16 C 0.15523(17) 0.2473(3) 0.4652(2) 0.0896(12) Uani 1 1 d .
C17 C 0.1460(3) 0.1778(5) 0.5629(2) 0.135(2) Uani 1 1 d .
H17A H 0.1888 0.2016 0.5910 0.203 Uiso 1 1 calc R
H17B H 0.1363 0.1164 0.5787 0.203 Uiso 1 1 calc R
H17C H 0.1102 0.2224 0.5626 0.203 Uiso 1 1 calc R
C18 C 0.06174(12) 0.1334(2) 0.20630(13) 0.0479(6) Uani 1 1 d .
C19 C 0.05508(12) 0.0420(2) 0.18070(12) 0.0477(5) Uani 1 1 d .
C20 C 0.03259(16) 0.0312(3) 0.11245(14) 0.0640(8) Uani 1 1 d .
H20 H 0.0284 -0.0300 0.0940 0.077 Uiso 1 1 calc R
C21 C 0.01665(18) 0.1122(3) 0.07260(16) 0.0766(10) Uani 1 1 d .
H21 H 0.0022 0.1043 0.0275 0.092 Uiso 1 1 calc R
C22 C 0.02166(16) 0.2038(3) 0.09814(17) 0.0723(9) Uani 1 1 d .
H22 H 0.0103 0.2572 0.0708 0.087 Uiso 1 1 calc R
C23 C 0.04391(14) 0.2147(2) 0.16505(16) 0.0602(7) Uani 1 1 d .
C24 C 0.0201(2) 0.3844(3) 0.1605(2) 0.0965(14) Uani 1 1 d .
H24A H 0.0448 0.4005 0.1306 0.145 Uiso 1 1 calc R
H24B H 0.0224 0.4374 0.1897 0.145 Uiso 1 1 calc R
H24C H -0.0268 0.3714 0.1365 0.145 Uiso 1 1 calc R
C25 C 0.3049(2) 0.1690(3) 0.22524(19) 0.0833(10) Uani 1 1 d .
H25 H 0.3198 0.2195 0.2008 0.100 Uiso 1 1 calc R
Cl1 Cl 0.28530(17) 0.2194(2) 0.28881(9) 0.2369(14) Uani 1 1 d .
Cl2 Cl 0.36995(9) 0.08719(15) 0.25411(12) 0.1648(8) Uani 1 1 d .
Cl3 Cl 0.23228(9) 0.11364(12) 0.17448(8) 0.1347(6) Uani 1 1 d .
F1 F -0.02970(18) -0.36731(18) 0.13722(16) 0.1375(12) Uani 1 1 d .
F2 F -0.04347(18) -0.2689(2) 0.05934(13) 0.1377(11) Uani 1 1 d .
F3 F -0.12568(12) -0.3058(2) 0.09227(13) 0.1080(8) Uani 1 1 d .
N1 N 0.13307(10) 0.00665(15) 0.30824(10) 0.0448(4) Uani 1 1 d .
N2 N 0.15445(13) 0.13523(18) 0.38083(12) 0.0625(6) Uani 1 1 d .
H2 H 0.1749 0.0949 0.4109 0.075 Uiso 1 1 calc R
N3 N 0.08354(11) 0.15391(16) 0.27379(11) 0.0507(5) Uani 1 1 d .
H3 H 0.0701 0.2072 0.2860 0.061 Uiso 1 1 calc R
O1 O 0.01259(9) -0.16191(15) 0.16327(9) 0.0558(5) Uani 1 1 d .
O2 O -0.07892(9) -0.19417(13) 0.19627(9) 0.0521(4) Uani 1 1 d .
O3 O 0.14557(13) -0.05298(19) 0.43375(10) 0.0725(6) Uani 1 1 d .
O4 O 0.14979(14) 0.1671(2) 0.49777(12) 0.0968(9) Uani 1 1 d .
O5 O 0.04990(13) 0.30128(16) 0.19708(13) 0.0801(7) Uani 1 1 d .
Pd1 Pd 0.068246(8) -0.071114(13) 0.237665(8) 0.04189(6) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pd Pd -0.9988 1.0072 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O2 C1 O1 130.9(2) . .
O2 C1 C2 115.5(2) . .
O1 C1 C2 113.6(2) . .
F1 C2 F3 106.8(3) . .
F1 C2 F2 108.1(3) . .
F3 C2 F2 105.2(3) . .
F1 C2 C1 111.1(3) . .
F3 C2 C1 112.8(3) . .
F2 C2 C1 112.4(3) . .
C4 C3 C8 118.5(3) . .
C4 C3 N1 118.0(2) . .
C8 C3 N1 123.4(3) . .
C3 C4 C5 121.7(3) . .
C3 C4 H4 119.1 . .
C5 C4 H4 119.1 . .
C6 C5 C4 119.1(4) . .
C6 C5 H5 120.4 . .
C4 C5 H5 120.4 . .
C5 C6 C7 120.6(3) . .
C5 C6 H6 119.7 . .
C7 C6 H6 119.7 . .
C8 C7 C6 120.2(3) . .
C8 C7 H7 119.9 . .
C6 C7 H7 119.9 . .
O3 C8 C7 125.3(3) . .
O3 C8 C3 114.9(2) . .
C7 C8 C3 119.9(3) . .
O3 C9 H9A 109.5 . .
O3 C9 H9B 109.5 . .
H9A C9 H9B 109.5 . .
O3 C9 H9C 109.5 . .
H9A C9 H9C 109.5 . .
H9B C9 H9C 109.5 . .
N1 C10 N3 120.6(2) . .
N1 C10 N2 120.8(2) . .
N3 C10 N2 118.5(3) . .
C12 C11 N2 125.0(4) . .
C12 C11 C16 120.1(4) . .
N2 C11 C16 114.8(3) . .
C11 C12 C13 119.8(6) . .
C11 C12 H12 120.1 . .
C13 C12 H12 120.1 . .
C14 C13 C12 120.2(6) . .
C14 C13 H13 119.9 . .
C12 C13 H13 119.9 . .
C13 C14 C15 121.3(5) . .
C13 C14 H14 119.4 . .
C15 C14 H14 119.4 . .
C14 C15 C16 120.8(6) . .
C14 C15 H15 119.6 . .
C16 C15 H15 119.6 . .
O4 C16 C15 127.0(5) . .
O4 C16 C11 115.2(3) . .
C15 C16 C11 117.7(5) . .
O4 C17 H17A 109.5 . .
O4 C17 H17B 109.5 . .
H17A C17 H17B 109.5 . .
O4 C17 H17C 109.5 . .
H17A C17 H17C 109.5 . .
H17B C17 H17C 109.5 . .
C19 C18 N3 124.1(2) . .
C19 C18 C23 120.8(3) . .
N3 C18 C23 115.1(2) . .
C18 C19 C20 118.6(3) . .
C18 C19 Pd1 120.81(19) . .
C20 C19 Pd1 120.4(2) . .
C21 C20 C19 119.8(3) . .
C21 C20 H20 120.1 . .
C19 C20 H20 120.1 . .
C22 C21 C20 121.8(3) . .
C22 C21 H21 119.1 . .
C20 C21 H21 119.1 . .
C21 C22 C23 118.6(3) . .
C21 C22 H22 120.7 . .
C23 C22 H22 120.7 . .
O5 C23 C22 124.8(3) . .
O5 C23 C18 114.8(3) . .
C22 C23 C18 120.4(3) . .
O5 C24 H24A 109.5 . .
O5 C24 H24B 109.5 . .
H24A C24 H24B 109.5 . .
O5 C24 H24C 109.5 . .
H24A C24 H24C 109.5 . .
H24B C24 H24C 109.5 . .
Cl1 C25 Cl2 109.5(3) . .
Cl1 C25 Cl3 108.5(3) . .
Cl2 C25 Cl3 110.9(3) . .
Cl1 C25 H25 109.3 . .
Cl2 C25 H25 109.3 . .
Cl3 C25 H25 109.3 . .
C10 N1 C3 121.1(2) . .
C10 N1 Pd1 124.46(16) . .
C3 N1 Pd1 114.36(16) . .
C10 N2 C11 128.3(3) . .
C10 N2 H2 115.8 . .
C11 N2 H2 115.8 . .
C10 N3 C18 125.2(2) . .
C10 N3 H3 117.4 . .
C18 N3 H3 117.4 . .
C1 O1 Pd1 124.89(13) . .
C1 O2 Pd1 121.53(12) . 2
C8 O3 C9 117.0(2) . .
C16 O4 C17 117.7(3) . .
C23 O5 C24 118.4(2) . .
C19 Pd1 N1 88.47(10) . .
C19 Pd1 O1 93.86(8) . .
N1 Pd1 O1 172.15(6) . .
C19 Pd1 O2 176.86(8) . 2
N1 Pd1 O2 91.06(6) . 2
O1 Pd1 O2 87.02(7) . 2
C19 Pd1 Pd1 98.88(7) . 2
N1 Pd1 Pd1 107.72(6) . 2
O1 Pd1 Pd1 79.35(5) . 2
O2 Pd1 Pd1 78.30(5) 2 2
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 O2 1.234(3) .
C1 O1 1.242(3) .
C1 C2 1.543(4) .
C2 F1 1.293(4) .
C2 F3 1.314(4) .
C2 F2 1.315(5) .
C3 C4 1.374(4) .
C3 C8 1.398(4) .
C3 N1 1.432(3) .
C4 C5 1.393(4) .
C4 H4 0.9300 .
C5 C6 1.360(6) .
C5 H5 0.9300 .
C6 C7 1.386(6) .
C6 H6 0.9300 .
C7 C8 1.384(4) .
C7 H7 0.9300 .
C8 O3 1.366(3) .
C9 O3 1.433(4) .
C9 H9A 0.9600 .
C9 H9B 0.9600 .
C9 H9C 0.9600 .
C10 N1 1.306(3) .
C10 N3 1.344(3) .
C10 N2 1.365(3) .
C11 C12 1.368(6) .
C11 N2 1.410(4) .
C11 C16 1.424(6) .
C12 C13 1.403(7) .
C12 H12 0.9300 .
C13 C14 1.352(12) .
C13 H13 0.9300 .
C14 C15 1.360(10) .
C14 H14 0.9300 .
C15 C16 1.402(6) .
C15 H15 0.9300 .
C16 O4 1.339(5) .
C17 O4 1.436(4) .
C17 H17A 0.9600 .
C17 H17B 0.9600 .
C17 H17C 0.9600 .
C18 C19 1.373(4) .
C18 N3 1.411(4) .
C18 C23 1.413(4) .
C19 C20 1.405(4) .
C19 Pd1 1.959(3) .
C20 C21 1.391(5) .
C20 H20 0.9300 .
C21 C22 1.377(6) .
C21 H21 0.9300 .
C22 C23 1.378(5) .
C22 H22 0.9300 .
C23 O5 1.372(3) .
C24 O5 1.425(3) .
C24 H24A 0.9600 .
C24 H24B 0.9600 .
C24 H24C 0.9600 .
C25 Cl1 1.693(4) .
C25 Cl2 1.717(5) .
C25 Cl3 1.734(4) .
C25 H25 0.9800 .
N1 Pd1 2.000(2) .
N2 H2 0.8600 .
N3 H3 0.8600 .
O1 Pd1 2.0810(18) .
O2 Pd1 2.1903(18) 2
Pd1 O2 2.1903(18) 2
Pd1 Pd1 3.0130(4) 2
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_4
O2 C1 C2 F1 -91.6(4) .
O1 C1 C2 F1 87.3(4) .
O2 C1 C2 F3 28.3(4) .
O1 C1 C2 F3 -152.8(3) .
O2 C1 C2 F2 147.1(3) .
O1 C1 C2 F2 -34.0(4) .
C8 C3 C4 C5 -1.3(5) .
N1 C3 C4 C5 -178.0(3) .
C3 C4 C5 C6 0.0(6) .
C4 C5 C6 C7 0.4(6) .
C5 C6 C7 C8 0.5(6) .
C6 C7 C8 O3 178.8(3) .
C6 C7 C8 C3 -1.8(5) .
C4 C3 C8 O3 -178.3(2) .
N1 C3 C8 O3 -1.8(4) .
C4 C3 C8 C7 2.2(4) .
N1 C3 C8 C7 178.7(3) .
N2 C11 C12 C13 -178.3(4) .
C16 C11 C12 C13 -2.6(6) .
C11 C12 C13 C14 2.5(7) .
C12 C13 C14 C15 -1.2(9) .
C13 C14 C15 C16 0.0(9) .
C14 C15 C16 O4 178.8(4) .
C14 C15 C16 C11 0.0(7) .
C12 C11 C16 O4 -177.6(3) .
N2 C11 C16 O4 -1.5(4) .
C12 C11 C16 C15 1.3(5) .
N2 C11 C16 C15 177.5(3) .
N3 C18 C19 C20 179.8(2) .
C23 C18 C19 C20 2.4(4) .
N3 C18 C19 Pd1 5.4(3) .
C23 C18 C19 Pd1 -171.95(19) .
C18 C19 C20 C21 -1.0(4) .
Pd1 C19 C20 C21 173.3(2) .
C19 C20 C21 C22 -0.6(5) .
C20 C21 C22 C23 0.8(5) .
C21 C22 C23 O5 -178.5(3) .
C21 C22 C23 C18 0.6(5) .
C19 C18 C23 O5 177.0(2) .
N3 C18 C23 O5 -0.6(3) .
C19 C18 C23 C22 -2.2(4) .
N3 C18 C23 C22 -179.8(3) .
N3 C10 N1 C3 158.5(2) .
N2 C10 N1 C3 -21.4(4) .
N3 C10 N1 Pd1 -23.9(3) .
N2 C10 N1 Pd1 156.2(2) .
C4 C3 N1 C10 -109.7(3) .
C8 C3 N1 C10 73.8(3) .
C4 C3 N1 Pd1 72.5(3) .
C8 C3 N1 Pd1 -104.0(3) .
N1 C10 N2 C11 171.4(3) .
N3 C10 N2 C11 -8.6(5) .
C12 C11 N2 C10 -38.8(5) .
C16 C11 N2 C10 145.3(3) .
N1 C10 N3 C18 -16.0(4) .
N2 C10 N3 C18 163.9(3) .
C19 C18 N3 C10 26.3(4) .
C23 C18 N3 C10 -156.1(2) .
O2 C1 O1 Pd1 14.7(3) .
C2 C1 O1 Pd1 -163.93(16) .
O1 C1 O2 Pd1 8.6(3) 2
C2 C1 O2 Pd1 -172.73(17) 2
C7 C8 O3 C9 7.6(4) .
C3 C8 O3 C9 -171.9(3) .
C15 C16 O4 C17 2.7(5) .
C11 C16 O4 C17 -178.4(3) .
C22 C23 O5 C24 11.8(4) .
C18 C23 O5 C24 -167.4(3) .
C18 C19 Pd1 N1 -29.1(2) .
C20 C19 Pd1 N1 156.7(2) .
C18 C19 Pd1 O1 158.45(19) .
C20 C19 Pd1 O1 -15.8(2) .
C18 C19 Pd1 O2 52.3(15) 2
C20 C19 Pd1 O2 -121.9(13) 2
C18 C19 Pd1 Pd1 78.64(19) 2
C20 C19 Pd1 Pd1 -95.6(2) 2
C10 N1 Pd1 C19 40.4(2) .
C3 N1 Pd1 C19 -141.87(19) .
C10 N1 Pd1 O1 147.8(4) .
C3 N1 Pd1 O1 -34.5(6) .
C10 N1 Pd1 O2 -136.5(2) 2
C3 N1 Pd1 O2 41.24(17) 2
C10 N1 Pd1 Pd1 -58.4(2) 2
C3 N1 Pd1 Pd1 119.30(17) 2
C1 O1 Pd1 C19 -118.80(16) .
C1 O1 Pd1 N1 134.2(5) .
C1 O1 Pd1 O2 58.18(16) 2
C1 O1 Pd1 Pd1 -20.47(14) 2
