#------------------------------------------------------------------------------
#$Date: 2016-03-21 07:02:50 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178546 $
#$URL: svn://www.crystallography.net/cod/cif/4/06/53/4065304.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4065304
loop_
_publ_author_name
'MacInnis, Morgan C.'
'McDonald, Robert'
'Turculet, Laura'
_publ_section_title
;
 Synthesis and Characterization of Palladium Complexes Supported by an
 NPN-Phosphido Ancillary Ligand
;
_journal_issue                   23
_journal_name_full               Organometallics
_journal_page_first              6408
_journal_paper_doi               10.1021/om200701h
_journal_volume                  30
_journal_year                    2011
_chemical_formula_moiety         'C32 H40 Cl2 N4 P2 Pd2'
_chemical_formula_sum            'C32 H40 Cl2 N4 P2 Pd2'
_chemical_formula_weight         826.32
_chemical_name_systematic
;

 ?

;
_space_group_IT_number           13
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yac'
_symmetry_space_group_name_H-M   'P 1 2/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 114.9868(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   19.7889(14)
_cell_length_b                   9.4338(7)
_cell_length_c                   20.2742(15)
_cell_measurement_reflns_used    6036
_cell_measurement_temperature    193(2)
_cell_measurement_theta_max      27.42
_cell_measurement_theta_min      2.27
_cell_volume                     3430.6(4)
_computing_cell_refinement       'Bruker SAINT (Bruker, 1997)'
_computing_data_collection       'Bruker SMART (Bruker, 1997)'
_computing_data_reduction        'Bruker SAINT (Bruker, 1997)'
_computing_molecular_graphics    'Bruker SHELXTL (Bruker, 1997)'
_computing_publication_material  'Bruker SHELXTL (Bruker, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'DIRDIF-96 (Beurskens et al., 1996)'
_diffrn_ambient_temperature      193(2)
_diffrn_detector_area_resol_mean 8.192
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type
'Bruker PLATFORM diffractometer/SMART 1000 CCD area detector'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0257
_diffrn_reflns_av_sigmaI/netI    0.0226
_diffrn_reflns_limit_h_max       25
_diffrn_reflns_limit_h_min       -25
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_number            28274
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_diffrn_reflns_theta_min         1.21
_diffrn_standards_decay_%        0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.325
_exptl_absorpt_correction_T_max  0.7592
_exptl_absorpt_correction_T_min  0.6841
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS (Sheldrick, 1996)'
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.600
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             1664
_exptl_crystal_size_max          0.31
_exptl_crystal_size_mid          0.26
_exptl_crystal_size_min          0.22
_refine_diff_density_max         0.558
_refine_diff_density_min         -0.249
_refine_diff_density_rms         0.072
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.055
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     379
_refine_ls_number_reflns         7861
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.055
_refine_ls_R_factor_all          0.0276
_refine_ls_R_factor_gt           0.0220
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0296P)²+1.5311P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0555
_refine_ls_wR_factor_ref         0.0592
_reflns_number_gt                6906
_reflns_number_total             7861
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            om200701h_si_001.cif
_cod_data_source_block           dal0715
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_sg_symbol_H-M      'P 2/n'
_cod_database_code               4065304
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y, -z+1/2'
'-x, -y, -z'
'x-1/2, -y, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Pd1 Pd 0.222383(8) 0.127473(15) 0.312143(8) 0.02129(5) Uani 1 1 d .
Cl1 Cl 0.27823(3) 0.02739(6) 0.43165(3) 0.03568(12) Uani 1 1 d .
P1 P 0.17693(3) 0.21166(5) 0.19932(3) 0.02171(10) Uani 1 1 d .
N1 N 0.11934(9) 0.00195(17) 0.27625(9) 0.0243(3) Uani 1 1 d .
N2 N 0.06448(11) 0.37814(19) 0.23187(11) 0.0330(4) Uani 1 1 d .
C11 C 0.08922(11) 0.1170(2) 0.15680(11) 0.0244(4) Uani 1 1 d .
C12 C 0.06873(11) 0.0255(2) 0.19912(11) 0.0244(4) Uani 1 1 d .
C13 C -0.00042(12) -0.0410(2) 0.16870(12) 0.0311(5) Uani 1 1 d .
H13 H -0.0144 -0.1047 0.1970 0.037 Uiso 1 1 calc R
C14 C -0.04895(12) -0.0142(3) 0.09686(12) 0.0356(5) Uani 1 1 d .
H14 H -0.0964 -0.0589 0.0765 0.043 Uiso 1 1 calc R
C15 C -0.02902(12) 0.0770(3) 0.05463(12) 0.0354(5) Uani 1 1 d .
H15 H -0.0627 0.0953 0.0056 0.042 Uiso 1 1 calc R
C16 C 0.04019(12) 0.1411(2) 0.08430(11) 0.0312(5) Uani 1 1 d .
H16 H 0.0545 0.2021 0.0551 0.037 Uiso 1 1 calc R
C17 C 0.14494(14) -0.1489(2) 0.28622(13) 0.0392(5) Uani 1 1 d .
H17A H 0.1794 -0.1648 0.3372 0.047 Uiso 1 1 calc R
H17B H 0.1704 -0.1689 0.2550 0.047 Uiso 1 1 calc R
H17C H 0.1018 -0.2119 0.2730 0.047 Uiso 1 1 calc R
C18 C 0.08120(13) 0.0311(3) 0.32381(12) 0.0363(5) Uani 1 1 d .
H18A H 0.0647 0.1301 0.3179 0.044 Uiso 1 1 calc R
H18B H 0.1158 0.0139 0.3746 0.044 Uiso 1 1 calc R
H18C H 0.0379 -0.0315 0.3103 0.044 Uiso 1 1 calc R
C21 C 0.15004(12) 0.3948(2) 0.17410(11) 0.0264(4) Uani 1 1 d .
C22 C 0.09257(12) 0.4553(2) 0.18745(12) 0.0297(4) Uani 1 1 d .
C23 C 0.06464(16) 0.5872(3) 0.15807(14) 0.0432(6) Uani 1 1 d .
H23 H 0.0241 0.6270 0.1651 0.052 Uiso 1 1 calc R
C24 C 0.09562(18) 0.6608(3) 0.11856(16) 0.0539(7) Uani 1 1 d .
H24 H 0.0763 0.7510 0.0988 0.065 Uiso 1 1 calc R
C25 C 0.15447(19) 0.6040(3) 0.10771(16) 0.0535(7) Uani 1 1 d .
H25 H 0.1769 0.6565 0.0822 0.064 Uiso 1 1 calc R
C26 C 0.18072(14) 0.4698(3) 0.13424(13) 0.0393(5) Uani 1 1 d .
H26 H 0.2198 0.4289 0.1251 0.047 Uiso 1 1 calc R
C27 C 0.09201(15) 0.4371(3) 0.30525(14) 0.0444(6) Uani 1 1 d .
H27A H 0.0728 0.3809 0.3343 0.053 Uiso 1 1 calc R
H27B H 0.0750 0.5354 0.3026 0.053 Uiso 1 1 calc R
H27C H 0.1466 0.4346 0.3280 0.053 Uiso 1 1 calc R
C28 C -0.01671(14) 0.3631(3) 0.19835(17) 0.0485(7) Uani 1 1 d .
H28A H -0.0322 0.3082 0.2307 0.058 Uiso 1 1 calc R
H28B H -0.0324 0.3137 0.1517 0.058 Uiso 1 1 calc R
H28C H -0.0398 0.4571 0.1903 0.058 Uiso 1 1 calc R
Pd2 Pd 0.310829(8) 0.395174(15) 0.717496(8) 0.02000(4) Uani 1 1 d .
Cl2 Cl 0.43249(3) 0.29057(6) 0.76920(3) 0.03494(12) Uani 1 1 d .
P2 P 0.19542(3) 0.47586(5) 0.68082(3) 0.01978(10) Uani 1 1 d .
N3 N 0.27099(9) 0.28696(17) 0.61178(9) 0.0229(3) Uani 1 1 d .
N4 N 0.21327(10) 0.66122(19) 0.56217(10) 0.0299(4) Uani 1 1 d .
C31 C 0.14699(11) 0.37576(19) 0.59812(11) 0.0224(4) Uani 1 1 d .
C32 C 0.18915(11) 0.2967(2) 0.57062(11) 0.0229(4) Uani 1 1 d .
C33 C 0.15318(12) 0.2234(2) 0.50526(11) 0.0304(4) Uani 1 1 d .
H33 H 0.1814 0.1725 0.4851 0.037 Uiso 1 1 calc R
C34 C 0.07603(12) 0.2251(2) 0.46976(12) 0.0342(5) Uani 1 1 d .
H34 H 0.0516 0.1743 0.4255 0.041 Uiso 1 1 calc R
C35 C 0.03406(12) 0.3001(2) 0.49796(12) 0.0323(5) Uani 1 1 d .
H35 H -0.0188 0.2994 0.4735 0.039 Uiso 1 1 calc R
C36 C 0.06948(11) 0.3759(2) 0.56187(11) 0.0270(4) Uani 1 1 d .
H36 H 0.0409 0.4283 0.5811 0.032 Uiso 1 1 calc R
C37 C 0.30996(12) 0.3416(2) 0.56824(12) 0.0319(5) Uani 1 1 d .
H37A H 0.2973 0.4417 0.5565 0.038 Uiso 1 1 calc R
H37B H 0.2943 0.2870 0.5231 0.038 Uiso 1 1 calc R
H37C H 0.3640 0.3322 0.5964 0.038 Uiso 1 1 calc R
C38 C 0.29131(12) 0.1349(2) 0.62979(13) 0.0310(5) Uani 1 1 d .
H38A H 0.3453 0.1269 0.6587 0.037 Uiso 1 1 calc R
H38B H 0.2768 0.0804 0.5847 0.037 Uiso 1 1 calc R
H38C H 0.2652 0.0976 0.6578 0.037 Uiso 1 1 calc R
C41 C 0.16987(10) 0.6607(2) 0.65906(11) 0.0227(4) Uani 1 1 d .
C42 C 0.17814(11) 0.7323(2) 0.60235(11) 0.0261(4) Uani 1 1 d .
C43 C 0.15332(13) 0.8718(2) 0.58721(14) 0.0360(5) Uani 1 1 d .
H43 H 0.1569 0.9195 0.5475 0.043 Uiso 1 1 calc R
C44 C 0.12353(13) 0.9428(2) 0.62880(15) 0.0405(6) Uani 1 1 d .
H44 H 0.1073 1.0383 0.6178 0.049 Uiso 1 1 calc R
C45 C 0.11763(13) 0.8742(2) 0.68609(15) 0.0379(5) Uani 1 1 d .
H45 H 0.0986 0.9228 0.7157 0.046 Uiso 1 1 calc R
C46 C 0.13966(12) 0.7332(2) 0.70039(12) 0.0304(4) Uani 1 1 d .
H46 H 0.1340 0.6854 0.7390 0.037 Uiso 1 1 calc R
C47 C 0.28255(14) 0.7329(3) 0.57141(16) 0.0458(6) Uani 1 1 d .
H47A H 0.3064 0.6801 0.5454 0.055 Uiso 1 1 calc R
H47B H 0.3164 0.7372 0.6233 0.055 Uiso 1 1 calc R
H47C H 0.2712 0.8293 0.5518 0.055 Uiso 1 1 calc R
C48 C 0.16365(16) 0.6438(3) 0.48504(14) 0.0505(7) Uani 1 1 d .
H48A H 0.1900 0.5932 0.4607 0.061 Uiso 1 1 calc R
H48B H 0.1481 0.7372 0.4626 0.061 Uiso 1 1 calc R
H48C H 0.1196 0.5892 0.4802 0.061 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pd Pd -0.9988 1.0072 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N1 Pd1 P1 86.34(4) . .
N1 Pd1 P1 153.53(5) . 2
P1 Pd1 P1 76.00(2) . 2
N1 Pd1 Cl1 95.15(4) . .
P1 Pd1 Cl1 175.65(2) . .
P1 Pd1 Cl1 101.176(19) 2 .
C11 P1 C21 103.10(9) . .
C11 P1 Pd1 101.73(7) . .
C21 P1 Pd1 124.96(7) . .
C11 P1 Pd1 119.31(7) . 2
C21 P1 Pd1 118.32(7) . 2
Pd1 P1 Pd1 89.375(19) . 2
C12 N1 C18 110.99(16) . .
C12 N1 C17 109.05(16) . .
C18 N1 C17 108.99(18) . .
C12 N1 Pd1 112.90(12) . .
C18 N1 Pd1 109.95(13) . .
C17 N1 Pd1 104.71(13) . .
C22 N2 C27 111.60(18) . .
C22 N2 C28 113.4(2) . .
C27 N2 C28 112.0(2) . .
C12 C11 C16 119.72(19) . .
C12 C11 P1 118.79(15) . .
C16 C11 P1 121.36(16) . .
C13 C12 C11 119.65(19) . .
C13 C12 N1 120.16(18) . .
C11 C12 N1 120.17(17) . .
C14 C13 C12 119.9(2) . .
C15 C14 C13 120.8(2) . .
C16 C15 C14 119.5(2) . .
C15 C16 C11 120.5(2) . .
C26 C21 C22 119.7(2) . .
C26 C21 P1 119.93(17) . .
C22 C21 P1 119.97(16) . .
C23 C22 C21 119.4(2) . .
C23 C22 N2 122.2(2) . .
C21 C22 N2 118.40(18) . .
C24 C23 C22 120.3(2) . .
C25 C24 C23 120.5(2) . .
C24 C25 C26 119.7(2) . .
C25 C26 C21 120.3(2) . .
N3 Pd2 P2 86.45(4) . .
N3 Pd2 P2 156.21(4) . 2_556
P2 Pd2 P2 75.14(2) . 2_556
N3 Pd2 Cl2 96.64(4) . .
P2 Pd2 Cl2 172.32(2) . .
P2 Pd2 Cl2 99.935(19) 2_556 .
C31 P2 C41 106.99(9) . .
C31 P2 Pd2 101.50(7) . .
C41 P2 Pd2 123.54(6) . .
C31 P2 Pd2 117.43(6) . 2_556
C41 P2 Pd2 115.45(7) . 2_556
Pd2 P2 Pd2 91.379(19) . 2_556
C32 N3 C37 111.23(16) . .
C32 N3 C38 108.37(15) . .
C37 N3 C38 108.93(16) . .
C32 N3 Pd2 112.21(12) . .
C37 N3 Pd2 110.80(12) . .
C38 N3 Pd2 105.03(12) . .
C42 N4 C48 112.99(19) . .
C42 N4 C47 111.16(18) . .
C48 N4 C47 110.9(2) . .
C36 C31 C32 119.96(18) . .
C36 C31 P2 121.56(16) . .
C32 C31 P2 118.48(15) . .
C33 C32 C31 119.49(18) . .
C33 C32 N3 120.24(17) . .
C31 C32 N3 120.23(17) . .
C34 C33 C32 119.7(2) . .
C35 C34 C33 120.8(2) . .
C36 C35 C34 119.7(2) . .
C35 C36 C31 120.19(19) . .
C46 C41 C42 118.93(18) . .
C46 C41 P2 118.05(15) . .
C42 C41 P2 123.02(15) . .
C43 C42 C41 118.9(2) . .
C43 C42 N4 121.7(2) . .
C41 C42 N4 119.38(17) . .
C44 C43 C42 121.5(2) . .
C45 C44 C43 119.6(2) . .
C44 C45 C46 119.7(2) . .
C45 C46 C41 121.3(2) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Pd1 N1 2.1991(16) .
Pd1 P1 2.2213(5) .
Pd1 P1 2.2462(5) 2
Pd1 Cl1 2.3918(5) .
P1 C11 1.813(2) .
P1 C21 1.817(2) .
P1 Pd1 2.2462(5) 2
N1 C12 1.475(2) .
N1 C18 1.480(3) .
N1 C17 1.496(3) .
N2 C22 1.440(3) .
N2 C27 1.461(3) .
N2 C28 1.463(3) .
C11 C12 1.393(3) .
C11 C16 1.396(3) .
C12 C13 1.391(3) .
C13 C14 1.388(3) .
C14 C15 1.383(3) .
C15 C16 1.381(3) .
C21 C26 1.392(3) .
C21 C22 1.397(3) .
C22 C23 1.389(3) .
C23 C24 1.384(4) .
C24 C25 1.381(4) .
C25 C26 1.388(3) .
Pd2 N3 2.1977(16) .
Pd2 P2 2.2166(5) .
Pd2 P2 2.2495(5) 2_556
Pd2 Cl2 2.3952(5) .
P2 C31 1.807(2) .
P2 C41 1.8172(19) .
P2 Pd2 2.2495(5) 2_556
N3 C32 1.478(2) .
N3 C37 1.488(3) .
N3 C38 1.493(3) .
N4 C42 1.441(3) .
N4 C48 1.463(3) .
N4 C47 1.468(3) .
C31 C36 1.393(3) .
C31 C32 1.399(3) .
C32 C33 1.394(3) .
C33 C34 1.386(3) .
C34 C35 1.385(3) .
C35 C36 1.384(3) .
C41 C46 1.397(3) .
C41 C42 1.402(3) .
C42 C43 1.393(3) .
C43 C44 1.388(4) .
C44 C45 1.377(4) .
C45 C46 1.391(3) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
N1 Pd1 P1 C11 -1.13(8) . .
P1 Pd1 P1 C11 158.98(7) 2 .
Cl1 Pd1 P1 C11 109.1(3) . .
N1 Pd1 P1 C21 114.18(10) . .
P1 Pd1 P1 C21 -85.70(8) 2 .
Cl1 Pd1 P1 C21 -135.6(3) . .
N1 Pd1 P1 Pd1 -120.98(5) . 2
P1 Pd1 P1 Pd1 39.13(2) 2 2
Cl1 Pd1 P1 Pd1 -10.7(3) . 2
P1 Pd1 N1 C12 0.12(12) . .
P1 Pd1 N1 C12 -47.66(18) 2 .
Cl1 Pd1 N1 C12 -175.79(12) . .
P1 Pd1 N1 C18 -124.43(13) . .
P1 Pd1 N1 C18 -172.20(11) 2 .
Cl1 Pd1 N1 C18 59.66(14) . .
P1 Pd1 N1 C17 118.62(13) . .
P1 Pd1 N1 C17 70.85(17) 2 .
Cl1 Pd1 N1 C17 -57.28(13) . .
C21 P1 C11 C12 -128.12(16) . .
Pd1 P1 C11 C12 2.36(17) . .
Pd1 P1 C11 C12 98.31(16) 2 .
C21 P1 C11 C16 47.71(19) . .
Pd1 P1 C11 C16 178.18(16) . .
Pd1 P1 C11 C16 -85.86(18) 2 .
C16 C11 C12 C13 0.0(3) . .
P1 C11 C12 C13 175.89(16) . .
C16 C11 C12 N1 -178.54(18) . .
P1 C11 C12 N1 -2.6(3) . .
C18 N1 C12 C13 -53.1(2) . .
C17 N1 C12 C13 67.0(2) . .
Pd1 N1 C12 C13 -177.10(15) . .
C18 N1 C12 C11 125.4(2) . .
C17 N1 C12 C11 -114.5(2) . .
Pd1 N1 C12 C11 1.4(2) . .
C11 C12 C13 C14 -1.0(3) . .
N1 C12 C13 C14 177.53(19) . .
C12 C13 C14 C15 0.8(4) . .
C13 C14 C15 C16 0.4(4) . .
C14 C15 C16 C11 -1.4(4) . .
C12 C11 C16 C15 1.2(3) . .
P1 C11 C16 C15 -174.56(18) . .
C11 P1 C21 C26 -120.30(19) . .
Pd1 P1 C21 C26 125.03(17) . .
Pd1 P1 C21 C26 13.8(2) 2 .
C11 P1 C21 C22 52.47(19) . .
Pd1 P1 C21 C22 -62.20(19) . .
Pd1 P1 C21 C22 -173.40(14) 2 .
C26 C21 C22 C23 2.7(3) . .
P1 C21 C22 C23 -170.06(18) . .
C26 C21 C22 N2 -177.0(2) . .
P1 C21 C22 N2 10.2(3) . .
C27 N2 C22 C23 -76.0(3) . .
C28 N2 C22 C23 51.5(3) . .
C27 N2 C22 C21 103.7(2) . .
C28 N2 C22 C21 -128.8(2) . .
C21 C22 C23 C24 -2.8(4) . .
N2 C22 C23 C24 176.9(2) . .
C22 C23 C24 C25 0.2(4) . .
C23 C24 C25 C26 2.5(5) . .
C24 C25 C26 C21 -2.6(4) . .
C22 C21 C26 C25 -0.1(4) . .
P1 C21 C26 C25 172.7(2) . .
N3 Pd2 P2 C31 8.75(8) . .
P2 Pd2 P2 C31 -156.04(6) 2_556 .
Cl2 Pd2 P2 C31 -105.22(15) . .
N3 Pd2 P2 C41 -110.76(9) . .
P2 Pd2 P2 C41 84.45(8) 2_556 .
Cl2 Pd2 P2 C41 135.27(15) . .
N3 Pd2 P2 Pd2 127.12(4) . 2_556
P2 Pd2 P2 Pd2 -37.67(2) 2_556 2_556
Cl2 Pd2 P2 Pd2 13.14(15) . 2_556
P2 Pd2 N3 C32 -8.07(12) . .
P2 Pd2 N3 C32 30.9(2) 2_556 .
Cl2 Pd2 N3 C32 164.87(12) . .
P2 Pd2 N3 C37 116.94(13) . .
P2 Pd2 N3 C37 155.88(11) 2_556 .
Cl2 Pd2 N3 C37 -70.13(13) . .
P2 Pd2 N3 C38 -125.59(12) . .
P2 Pd2 N3 C38 -86.65(16) 2_556 .
Cl2 Pd2 N3 C38 47.35(12) . .
C41 P2 C31 C36 -59.51(18) . .
Pd2 P2 C31 C36 169.82(15) . .
Pd2 P2 C31 C36 72.17(17) 2_556 .
C41 P2 C31 C32 120.55(16) . .
Pd2 P2 C31 C32 -10.12(16) . .
Pd2 P2 C31 C32 -107.77(15) 2_556 .
C36 C31 C32 C33 2.8(3) . .
P2 C31 C32 C33 -177.29(15) . .
C36 C31 C32 N3 -175.20(17) . .
P2 C31 C32 N3 4.7(2) . .
C37 N3 C32 C33 61.0(2) . .
C38 N3 C32 C33 -58.7(2) . .
Pd2 N3 C32 C33 -174.21(15) . .
C37 N3 C32 C31 -121.02(19) . .
C38 N3 C32 C31 119.3(2) . .
Pd2 N3 C32 C31 3.7(2) . .
C31 C32 C33 C34 -2.5(3) . .
N3 C32 C33 C34 175.43(19) . .
C32 C33 C34 C35 0.7(3) . .
C33 C34 C35 C36 0.9(4) . .
C34 C35 C36 C31 -0.7(3) . .
C32 C31 C36 C35 -1.2(3) . .
P2 C31 C36 C35 178.90(16) . .
C31 P2 C41 C46 124.80(16) . .
Pd2 P2 C41 C46 -118.29(15) . .
Pd2 P2 C41 C46 -7.96(18) 2_556 .
C31 P2 C41 C42 -54.25(18) . .
Pd2 P2 C41 C42 62.66(18) . .
Pd2 P2 C41 C42 172.99(14) 2_556 .
C46 C41 C42 C43 -2.5(3) . .
P2 C41 C42 C43 176.59(16) . .
C46 C41 C42 N4 176.35(18) . .
P2 C41 C42 N4 -4.6(3) . .
C48 N4 C42 C43 -63.5(3) . .
C47 N4 C42 C43 62.0(3) . .
C48 N4 C42 C41 117.7(2) . .
C47 N4 C42 C41 -116.8(2) . .
C41 C42 C43 C44 2.7(3) . .
N4 C42 C43 C44 -176.1(2) . .
C42 C43 C44 C45 -0.5(4) . .
C43 C44 C45 C46 -1.8(4) . .
C44 C45 C46 C41 2.0(3) . .
C42 C41 C46 C45 0.2(3) . .
P2 C41 C46 C45 -178.90(17) . .
