#------------------------------------------------------------------------------
#$Date: 2016-03-21 07:07:43 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178550 $
#$URL: svn://www.crystallography.net/cod/cif/4/06/57/4065734.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4065734
loop_
_publ_author_name
'Wooles, Ashley J.'
'Cooper, Oliver J.'
'McMaster, Jonathan'
'Lewis, William'
'Blake, Alexander J.'
'Liddle, Stephen T.'
_publ_section_title
;
 Synthesis and Characterization of Dysprosium and Lanthanum
 Bis(iminophosphorano)methanide and -methanediide Complexes
;
_journal_issue                   10
_journal_name_full               Organometallics
_journal_page_first              2315
_journal_paper_doi               10.1021/om100104s
_journal_volume                  29
_journal_year                    2010
_chemical_formula_moiety         'C62 H78 Dy2 I2 N4 O P4 Si4, 4(C7 H8)'
_chemical_formula_sum            'C90 H110 Dy2 I2 N4 O P4 Si4'
_chemical_formula_weight         2078.86
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   'geom, Me from difmap'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           'enCIFer editing of SHELXL97 CIF output'
_cell_angle_alpha                97.652(2)
_cell_angle_beta                 92.036(2)
_cell_angle_gamma                105.320(2)
_cell_formula_units_Z            1
_cell_length_a                   12.1810(8)
_cell_length_b                   13.0289(9)
_cell_length_c                   15.6920(10)
_cell_measurement_reflns_used    11166
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      2.25
_cell_volume                     2374.0(3)
_computing_cell_refinement       'Bruker SAINT version 6.36a (Bruker, 2000)'
_computing_data_collection       'Bruker SMART version 5.625 (Bruker, 2001)'
_computing_data_reduction        'Bruker SAINT; Bruker SHELXTL (Bruker, 2001)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material
'enCIFer(Allen et al.,2004);PLATON(Spek,2003)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'Bruker SHELXTL'
_diffrn_ambient_temperature      150(2)
_diffrn_measured_fraction_theta_full 0.992
_diffrn_measured_fraction_theta_max 0.992
_diffrn_measurement_device_type  'Bruker SMART APEX CCD diffractometer'
_diffrn_measurement_method       'ω rotation with narrow frames'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'normal-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0221
_diffrn_reflns_av_sigmaI/netI    0.0307
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            17437
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         2.25
_diffrn_standards_decay_%        0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    2.374
_exptl_absorpt_correction_T_max  0.54
_exptl_absorpt_correction_T_min  0.29
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Bruker, 2001)'
_exptl_crystal_colour            Colourless
_exptl_crystal_density_diffrn    1.454
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Block
_exptl_crystal_F_000             1040
_exptl_crystal_size_max          0.65
_exptl_crystal_size_mid          0.46
_exptl_crystal_size_min          0.28
_refine_diff_density_max         2.072
_refine_diff_density_min         -1.134
_refine_diff_density_rms         0.108
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.063
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     428
_refine_ls_number_reflns         8302
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.063
_refine_ls_R_factor_all          0.0351
_refine_ls_R_factor_gt           0.0311
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0575P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0827
_refine_ls_wR_factor_ref         0.0848
_reflns_number_gt                7437
_reflns_number_total             8302
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            om100104s_si_001.cif
_cod_data_source_block           4
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_database_code               4065734
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Dy1 Dy 0.503003(12) 0.474078(11) 0.369427(9) 0.02953(7) Uani 1 1 d .
I1 I 0.36792(2) 0.242629(18) 0.32765(2) 0.05456(9) Uani 1 1 d .
O1 O 0.5000 0.5000 0.5000 0.0384(7) Uani 1 2 d S
C1 C 0.6266(3) 0.6641(2) 0.3332(2) 0.0308(7) Uani 1 1 d .
H1B H 0.6481 0.7228 0.3837 0.037 Uiso 1 1 calc R
P1 P 0.50531(7) 0.66322(7) 0.26967(5) 0.03203(18) Uani 1 1 d .
C2 C 0.4638(3) 0.7811(3) 0.3181(2) 0.0380(8) Uani 1 1 d .
C3 C 0.4453(3) 0.7910(3) 0.4042(2) 0.0434(8) Uani 1 1 d .
H3A H 0.4587 0.7391 0.4375 0.052 Uiso 1 1 calc R
C4 C 0.4070(4) 0.8767(3) 0.4435(3) 0.0571(10) Uani 1 1 d .
H4A H 0.3918 0.8819 0.5026 0.068 Uiso 1 1 calc R
C5 C 0.3914(4) 0.9539(3) 0.3952(3) 0.0630(12) Uani 1 1 d .
H5A H 0.3674 1.0134 0.4218 0.076 Uiso 1 1 calc R
C6 C 0.4101(4) 0.9454(3) 0.3098(3) 0.0624(12) Uani 1 1 d .
H6A H 0.3982 0.9985 0.2772 0.075 Uiso 1 1 calc R
C7 C 0.4463(4) 0.8597(3) 0.2703(3) 0.0507(10) Uani 1 1 d .
H7A H 0.4593 0.8543 0.2108 0.061 Uiso 1 1 calc R
C8 C 0.5315(3) 0.6828(3) 0.1596(2) 0.0394(8) Uani 1 1 d .
C9 C 0.4667(3) 0.6132(3) 0.0900(2) 0.0452(9) Uani 1 1 d .
H9A H 0.4072 0.5531 0.0999 0.054 Uiso 1 1 calc R
C10 C 0.4881(4) 0.6305(4) 0.0066(3) 0.0598(11) Uani 1 1 d .
H10A H 0.4426 0.5832 -0.0405 0.072 Uiso 1 1 calc R
C11 C 0.5738(4) 0.7150(5) -0.0084(3) 0.0724(14) Uani 1 1 d .
H11A H 0.5889 0.7259 -0.0659 0.087 Uiso 1 1 calc R
C12 C 0.6394(4) 0.7853(4) 0.0594(3) 0.0756(15) Uani 1 1 d .
H12A H 0.6990 0.8447 0.0484 0.091 Uiso 1 1 calc R
C13 C 0.6187(4) 0.7695(4) 0.1425(3) 0.0596(11) Uani 1 1 d .
H13A H 0.6641 0.8182 0.1890 0.072 Uiso 1 1 calc R
P2 P 0.73157(7) 0.59874(7) 0.30813(5) 0.03139(18) Uani 1 1 d .
C14 C 0.8451(3) 0.6593(3) 0.3923(2) 0.0323(7) Uani 1 1 d .
C15 C 0.8180(3) 0.6888(3) 0.4758(2) 0.0360(7) Uani 1 1 d .
H15A H 0.7402 0.6771 0.4882 0.043 Uiso 1 1 calc R
C16 C 0.9034(3) 0.7353(3) 0.5413(2) 0.0388(8) Uani 1 1 d .
H16A H 0.8839 0.7552 0.5980 0.047 Uiso 1 1 calc R
C17 C 1.0166(3) 0.7525(3) 0.5239(2) 0.0433(8) Uani 1 1 d .
H17A H 1.0749 0.7858 0.5685 0.052 Uiso 1 1 calc R
C18 C 1.0456(3) 0.7216(3) 0.4423(3) 0.0444(9) Uani 1 1 d .
H18A H 1.1236 0.7318 0.4311 0.053 Uiso 1 1 calc R
C19 C 0.9615(3) 0.6757(3) 0.3767(2) 0.0406(8) Uani 1 1 d .
H19A H 0.9820 0.6549 0.3205 0.049 Uiso 1 1 calc R
C20 C 0.7971(3) 0.6270(3) 0.2083(2) 0.0407(8) Uani 1 1 d .
C21 C 0.7786(4) 0.5480(4) 0.1373(2) 0.0540(10) Uani 1 1 d .
H21A H 0.7328 0.4774 0.1403 0.065 Uiso 1 1 calc R
C22 C 0.8280(5) 0.5731(5) 0.0608(3) 0.0746(14) Uani 1 1 d .
H22A H 0.8157 0.5189 0.0119 0.090 Uiso 1 1 calc R
C23 C 0.8927(5) 0.6729(5) 0.0556(3) 0.0813(17) Uani 1 1 d .
H23A H 0.9266 0.6885 0.0035 0.098 Uiso 1 1 calc R
C24 C 0.9097(4) 0.7534(4) 0.1265(3) 0.0742(15) Uani 1 1 d .
H24A H 0.9542 0.8242 0.1226 0.089 Uiso 1 1 calc R
C25 C 0.8623(4) 0.7301(4) 0.2020(3) 0.0553(10) Uani 1 1 d .
H25A H 0.8741 0.7851 0.2503 0.066 Uiso 1 1 calc R
N1 N 0.4088(2) 0.5538(2) 0.27473(17) 0.0324(6) Uani 1 1 d .
Si1 Si 0.26060(8) 0.52382(8) 0.25992(6) 0.0362(2) Uani 1 1 d .
C26 C 0.2038(3) 0.3958(3) 0.1836(3) 0.0552(10) Uani 1 1 d .
H26A H 0.2226 0.3366 0.2081 0.083 Uiso 1 1 calc R
H26B H 0.2383 0.4030 0.1285 0.083 Uiso 1 1 calc R
H26C H 0.1208 0.3807 0.1743 0.083 Uiso 1 1 calc R
C27 C 0.2083(3) 0.6311(4) 0.2172(3) 0.0576(11) Uani 1 1 d .
H27A H 0.2247 0.6952 0.2610 0.086 Uiso 1 1 calc R
H27B H 0.1258 0.6048 0.2027 0.086 Uiso 1 1 calc R
H27C H 0.2470 0.6494 0.1653 0.086 Uiso 1 1 calc R
C28 C 0.2067(3) 0.5074(3) 0.3679(3) 0.0484(9) Uani 1 1 d .
H28A H 0.2404 0.4572 0.3936 0.073 Uiso 1 1 calc R
H28B H 0.1234 0.4790 0.3619 0.073 Uiso 1 1 calc R
H28C H 0.2277 0.5773 0.4050 0.073 Uiso 1 1 calc R
N2 N 0.6756(2) 0.4725(2) 0.30686(17) 0.0323(6) Uani 1 1 d .
Si2 Si 0.73116(8) 0.36158(8) 0.29567(6) 0.0365(2) Uani 1 1 d .
C29 C 0.8871(3) 0.3965(4) 0.2822(3) 0.0623(12) Uani 1 1 d .
H29A H 0.9036 0.4368 0.2336 0.093 Uiso 1 1 calc R
H29B H 0.9116 0.3304 0.2711 0.093 Uiso 1 1 calc R
H29C H 0.9284 0.4409 0.3350 0.093 Uiso 1 1 calc R
C30 C 0.7058(4) 0.2984(3) 0.3953(3) 0.0532(10) Uani 1 1 d .
H30A H 0.7466 0.3497 0.4450 0.080 Uiso 1 1 calc R
H30B H 0.7335 0.2339 0.3900 0.080 Uiso 1 1 calc R
H30C H 0.6238 0.2784 0.4033 0.080 Uiso 1 1 calc R
C31 C 0.6555(3) 0.2625(3) 0.2015(2) 0.0488(9) Uani 1 1 d .
H31A H 0.6754 0.2922 0.1482 0.073 Uiso 1 1 calc R
H31B H 0.5729 0.2474 0.2061 0.073 Uiso 1 1 calc R
H31C H 0.6784 0.1958 0.2008 0.073 Uiso 1 1 calc R
C32 C 1.0936(4) 0.9780(4) -0.6552(4) 0.0766(14) Uani 1 1 d .
H32A H 1.1068 0.9492 -0.6023 0.115 Uiso 1 1 calc R
H32B H 1.1478 1.0487 -0.6541 0.115 Uiso 1 1 calc R
H32C H 1.1043 0.9289 -0.7053 0.115 Uiso 1 1 calc R
C33 C 0.9732(4) 0.9888(3) -0.6611(3) 0.0525(10) Uani 1 1 d .
C34 C 0.9375(5) 1.0370(4) -0.7259(3) 0.0725(14) Uani 1 1 d .
H34A H 0.9888 1.0647 -0.7667 0.087 Uiso 1 1 calc R
C35 C 0.8281(7) 1.0445(5) -0.7308(5) 0.100(2) Uani 1 1 d .
H35A H 0.8036 1.0758 -0.7767 0.120 Uiso 1 1 calc R
C36 C 0.7532(5) 1.0089(5) -0.6729(6) 0.097(2) Uani 1 1 d .
H36A H 0.6776 1.0158 -0.6775 0.116 Uiso 1 1 calc R
C37 C 0.7891(5) 0.9620(4) -0.6065(4) 0.0814(17) Uani 1 1 d .
H37A H 0.7382 0.9368 -0.5647 0.098 Uiso 1 1 calc R
C38 C 0.8999(4) 0.9523(3) -0.6016(3) 0.0540(10) Uani 1 1 d .
H38A H 0.9246 0.9199 -0.5564 0.065 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
I I -0.4742 1.8119 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_3
O1 Dy1 N1 124.00(7) .
O1 Dy1 N2 119.88(7) .
N1 Dy1 N2 104.17(9) .
O1 Dy1 C1 103.30(7) .
N1 Dy1 C1 65.10(9) .
N2 Dy1 C1 64.47(9) .
O1 Dy1 I1 101.454(8) .
N1 Dy1 I1 101.06(7) .
N2 Dy1 I1 102.18(6) .
C1 Dy1 I1 155.24(7) .
O1 Dy1 P1 118.140(17) .
N1 Dy1 P1 30.69(7) .
N2 Dy1 P1 85.17(7) .
C1 Dy1 P1 34.42(7) .
I1 Dy1 P1 129.282(18) .
O1 Dy1 P2 112.069(17) .
N1 Dy1 P2 88.32(7) .
N2 Dy1 P2 30.67(7) .
C1 Dy1 P2 34.26(7) .
I1 Dy1 P2 131.673(17) .
P1 Dy1 P2 61.31(2) .
Dy1 O1 Dy1 180.0 2_666
P2 C1 P1 128.7(2) .
P2 C1 Dy1 85.78(12) .
P1 C1 Dy1 85.57(12) .
P2 C1 H1B 114.8 .
P1 C1 H1B 114.8 .
Dy1 C1 H1B 114.8 .
N1 P1 C1 108.43(14) .
N1 P1 C8 111.88(16) .
C1 P1 C8 114.31(16) .
N1 P1 C2 111.83(15) .
C1 P1 C2 104.49(16) .
C8 P1 C2 105.69(16) .
N1 P1 Dy1 48.43(9) .
C1 P1 Dy1 60.01(10) .
C8 P1 Dy1 132.58(12) .
C2 P1 Dy1 121.54(12) .
C3 C2 C7 119.0(3) .
C3 C2 P1 118.4(3) .
C7 C2 P1 122.6(3) .
C2 C3 C4 120.7(4) .
C2 C3 H3A 119.7 .
C4 C3 H3A 119.7 .
C5 C4 C3 119.3(4) .
C5 C4 H4A 120.4 .
C3 C4 H4A 120.4 .
C6 C5 C4 120.6(4) .
C6 C5 H5A 119.7 .
C4 C5 H5A 119.7 .
C5 C6 C7 120.3(4) .
C5 C6 H6A 119.8 .
C7 C6 H6A 119.8 .
C6 C7 C2 120.1(4) .
C6 C7 H7A 119.9 .
C2 C7 H7A 119.9 .
C9 C8 C13 118.1(3) .
C9 C8 P1 121.9(3) .
C13 C8 P1 120.0(3) .
C10 C9 C8 120.6(4) .
C10 C9 H9A 119.7 .
C8 C9 H9A 119.7 .
C11 C10 C9 120.1(4) .
C11 C10 H10A 119.9 .
C9 C10 H10A 119.9 .
C10 C11 C12 120.5(4) .
C10 C11 H11A 119.7 .
C12 C11 H11A 119.7 .
C13 C12 C11 120.0(4) .
C13 C12 H12A 120.0 .
C11 C12 H12A 120.0 .
C12 C13 C8 120.6(4) .
C12 C13 H13A 119.7 .
C8 C13 H13A 119.7 .
N2 P2 C1 107.52(15) .
N2 P2 C14 114.35(14) .
C1 P2 C14 104.14(15) .
N2 P2 C20 111.81(16) .
C1 P2 C20 114.27(16) .
C14 P2 C20 104.67(16) .
N2 P2 Dy1 48.53(9) .
C1 P2 Dy1 59.97(10) .
C14 P2 Dy1 115.56(11) .
C20 P2 Dy1 139.63(11) .
C15 C14 C19 118.1(3) .
C15 C14 P2 119.7(2) .
C19 C14 P2 122.2(3) .
C16 C15 C14 120.7(3) .
C16 C15 H15A 119.6 .
C14 C15 H15A 119.6 .
C17 C16 C15 120.0(3) .
C17 C16 H16A 120.0 .
C15 C16 H16A 120.0 .
C18 C17 C16 120.3(3) .
C18 C17 H17A 119.8 .
C16 C17 H17A 119.8 .
C17 C18 C19 120.1(3) .
C17 C18 H18A 119.9 .
C19 C18 H18A 119.9 .
C18 C19 C14 120.7(3) .
C18 C19 H19A 119.7 .
C14 C19 H19A 119.7 .
C21 C20 C25 119.3(3) .
C21 C20 P2 120.8(3) .
C25 C20 P2 119.8(3) .
C20 C21 C22 119.3(4) .
C20 C21 H21A 120.3 .
C22 C21 H21A 120.3 .
C23 C22 C21 120.9(4) .
C23 C22 H22A 119.5 .
C21 C22 H22A 119.5 .
C22 C23 C24 119.9(4) .
C22 C23 H23A 120.0 .
C24 C23 H23A 120.0 .
C25 C24 C23 119.9(4) .
C25 C24 H24A 120.1 .
C23 C24 H24A 120.1 .
C24 C25 C20 120.6(4) .
C24 C25 H25A 119.7 .
C20 C25 H25A 119.7 .
P1 N1 Si1 130.50(16) .
P1 N1 Dy1 100.88(13) .
Si1 N1 Dy1 123.09(13) .
N1 Si1 C28 105.98(16) .
N1 Si1 C26 110.02(17) .
C28 Si1 C26 110.05(19) .
N1 Si1 C27 113.88(16) .
C28 Si1 C27 108.8(2) .
C26 Si1 C27 108.0(2) .
Si1 C26 H26A 109.5 .
Si1 C26 H26B 109.5 .
H26A C26 H26B 109.5 .
Si1 C26 H26C 109.5 .
H26A C26 H26C 109.5 .
H26B C26 H26C 109.5 .
Si1 C27 H27A 109.5 .
Si1 C27 H27B 109.5 .
H27A C27 H27B 109.5 .
Si1 C27 H27C 109.5 .
H27A C27 H27C 109.5 .
H27B C27 H27C 109.5 .
Si1 C28 H28A 109.5 .
Si1 C28 H28B 109.5 .
H28A C28 H28B 109.5 .
Si1 C28 H28C 109.5 .
H28A C28 H28C 109.5 .
H28B C28 H28C 109.5 .
P2 N2 Si2 133.05(17) .
P2 N2 Dy1 100.80(12) .
Si2 N2 Dy1 123.75(14) .
N2 Si2 C29 113.58(17) .
N2 Si2 C30 107.54(16) .
C29 Si2 C30 108.0(2) .
N2 Si2 C31 109.73(16) .
C29 Si2 C31 108.9(2) .
C30 Si2 C31 108.98(19) .
Si2 C29 H29A 109.5 .
Si2 C29 H29B 109.5 .
H29A C29 H29B 109.5 .
Si2 C29 H29C 109.5 .
H29A C29 H29C 109.5 .
H29B C29 H29C 109.5 .
Si2 C30 H30A 109.5 .
Si2 C30 H30B 109.5 .
H30A C30 H30B 109.5 .
Si2 C30 H30C 109.5 .
H30A C30 H30C 109.5 .
H30B C30 H30C 109.5 .
Si2 C31 H31A 109.5 .
Si2 C31 H31B 109.5 .
H31A C31 H31B 109.5 .
Si2 C31 H31C 109.5 .
H31A C31 H31C 109.5 .
H31B C31 H31C 109.5 .
C33 C32 H32A 109.5 .
C33 C32 H32B 109.5 .
H32A C32 H32B 109.5 .
C33 C32 H32C 109.5 .
H32A C32 H32C 109.5 .
H32B C32 H32C 109.5 .
C38 C33 C34 119.6(5) .
C38 C33 C32 120.0(4) .
C34 C33 C32 120.4(4) .
C35 C34 C33 119.5(6) .
C35 C34 H34A 120.3 .
C33 C34 H34A 120.3 .
C36 C35 C34 122.4(6) .
C36 C35 H35A 118.8 .
C34 C35 H35A 118.8 .
C35 C36 C37 118.6(5) .
C35 C36 H36A 120.7 .
C37 C36 H36A 120.7 .
C38 C37 C36 119.6(5) .
C38 C37 H37A 120.2 .
C36 C37 H37A 120.2 .
C33 C38 C37 120.3(5) .
C33 C38 H38A 119.8 .
C37 C38 H38A 119.8 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Dy1 O1 2.03499(19) .
Dy1 N1 2.350(3) .
Dy1 N2 2.355(3) .
Dy1 C1 2.680(3) .
Dy1 I1 3.0009(3) .
Dy1 P1 3.0851(8) .
Dy1 P2 3.0874(8) .
O1 Dy1 2.03499(19) 2_666
C1 P2 1.743(3) .
C1 P1 1.749(3) .
C1 H1B 1.0000 .
P1 N1 1.603(3) .
P1 C8 1.806(3) .
P1 C2 1.821(3) .
C2 C3 1.373(5) .
C2 C7 1.402(5) .
C3 C4 1.400(5) .
C3 H3A 0.9500 .
C4 C5 1.384(6) .
C4 H4A 0.9500 .
C5 C6 1.361(7) .
C5 H5A 0.9500 .
C6 C7 1.386(6) .
C6 H6A 0.9500 .
C7 H7A 0.9500 .
C8 C9 1.391(5) .
C8 C13 1.394(5) .
C9 C10 1.380(5) .
C9 H9A 0.9500 .
C10 C11 1.354(6) .
C10 H10A 0.9500 .
C11 C12 1.379(7) .
C11 H11A 0.9500 .
C12 C13 1.370(6) .
C12 H12A 0.9500 .
C13 H13A 0.9500 .
P2 N2 1.603(3) .
P2 C14 1.815(3) .
P2 C20 1.820(4) .
C14 C15 1.392(5) .
C14 C19 1.412(5) .
C15 C16 1.389(5) .
C15 H15A 0.9500 .
C16 C17 1.381(5) .
C16 H16A 0.9500 .
C17 C18 1.377(5) .
C17 H17A 0.9500 .
C18 C19 1.380(5) .
C18 H18A 0.9500 .
C19 H19A 0.9500 .
C20 C21 1.380(5) .
C20 C25 1.387(5) .
C21 C22 1.401(6) .
C21 H21A 0.9500 .
C22 C23 1.345(7) .
C22 H22A 0.9500 .
C23 C24 1.392(7) .
C23 H23A 0.9500 .
C24 C25 1.371(6) .
C24 H24A 0.9500 .
C25 H25A 0.9500 .
N1 Si1 1.743(3) .
Si1 C28 1.857(4) .
Si1 C26 1.869(4) .
Si1 C27 1.870(4) .
C26 H26A 0.9800 .
C26 H26B 0.9800 .
C26 H26C 0.9800 .
C27 H27A 0.9800 .
C27 H27B 0.9800 .
C27 H27C 0.9800 .
C28 H28A 0.9800 .
C28 H28B 0.9800 .
C28 H28C 0.9800 .
N2 Si2 1.742(3) .
Si2 C29 1.859(4) .
Si2 C30 1.860(4) .
Si2 C31 1.861(4) .
C29 H29A 0.9800 .
C29 H29B 0.9800 .
C29 H29C 0.9800 .
C30 H30A 0.9800 .
C30 H30B 0.9800 .
C30 H30C 0.9800 .
C31 H31A 0.9800 .
C31 H31B 0.9800 .
C31 H31C 0.9800 .
C32 C33 1.511(6) .
C32 H32A 0.9800 .
C32 H32B 0.9800 .
C32 H32C 0.9800 .
C33 C38 1.361(6) .
C33 C34 1.378(6) .
C34 C35 1.362(9) .
C34 H34A 0.9500 .
C35 C36 1.349(10) .
C35 H35A 0.9500 .
C36 C37 1.389(9) .
C36 H36A 0.9500 .
C37 C38 1.389(7) .
C37 H37A 0.9500 .
C38 H38A 0.9500 .
