#------------------------------------------------------------------------------
#$Date: 2016-02-14 06:40:26 +0200 (Sun, 14 Feb 2016) $
#$Revision: 176432 $
#$URL: svn://www.crystallography.net/cod/cif/4/06/59/4065930.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4065930
loop_
_publ_author_name
'Arita, Manabu'
'Naka, Kensuke'
'Shimamoto, Tatsuo'
'Yumura, Takashi'
'Nakahashi, Akiko'
'Morisaki, Yasuhiro'
'Chujo, Yoshiki'
_publ_section_title
;
 1,4-Dihydro-1,4-diarsinine-Bridged Dinucleartrans-Dihaloplatinum(II)
 Complexes: Synthesis and Controlled Pt−Pt Interaction by Halogen
 Substitution Induced Conformational Change§
;
_journal_issue                   21
_journal_name_full               Organometallics
_journal_page_first              4992
_journal_paper_doi               10.1021/om100201x
_journal_volume                  29
_journal_year                    2010
_chemical_formula_sum            'C52 H84 As4 I4 O16 Pt2'
_chemical_formula_weight         2162.65
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                97.33(5)
_cell_angle_beta                 93.63(3)
_cell_angle_gamma                100.79(4)
_cell_formula_units_Z            1
_cell_length_a                   10.661(9)
_cell_length_b                   12.368(7)
_cell_length_c                   13.577(13)
_cell_measurement_temperature    110(2)
_cell_volume                     1737(2)
_computing_cell_refinement       PROCESS-AUTO
_computing_data_collection       PROCESS-AUTO
_computing_data_reduction        'Yadokari-XG (Wakita, 2000)'
_computing_molecular_graphics    'Yadokari-XG (Wakita, 2000)'
_computing_publication_material  'Yadokari-XG (Wakita, 2000)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'Dirdif99.2(Beurskens et al., 1999)'
_diffrn_ambient_temperature      110(2)
_diffrn_measured_fraction_theta_full 0.986
_diffrn_measured_fraction_theta_max 0.986
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71075
_diffrn_reflns_av_R_equivalents  0.0812
_diffrn_reflns_av_sigmaI/netI    0.1535
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            16443
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_diffrn_reflns_theta_min         3.04
_exptl_absorpt_coefficient_mu    7.747
_exptl_absorpt_correction_T_max  0.5113
_exptl_absorpt_correction_T_min  0.5113
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
    Higashi, T. (1995). Program for Absorption Correction.
    Rigaku Corporation, Tokyo, Japan.
;
_exptl_crystal_density_diffrn    2.067
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1024
_exptl_crystal_size_max          0.10
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.10
_refine_diff_density_max         1.242
_refine_diff_density_min         -1.037
_refine_diff_density_rms         0.180
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.817
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     366
_refine_ls_number_reflns         7852
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.817
_refine_ls_R_factor_all          0.1054
_refine_ls_R_factor_gt           0.0450
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0149P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0585
_refine_ls_wR_factor_ref         0.0659
_reflns_number_gt                4431
_reflns_number_total             7852
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            om100201x_si_002.cif
_cod_data_source_block           trans-Pt2I4(cis-DHDAtBu)2
_cod_original_sg_symbol_Hall     -p_1
_cod_original_sg_symbol_H-M      p_-1
_cod_database_code               4065930
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Pt1 Pt 0.13605(3) 0.05277(2) 0.46360(3) 0.02435(9) Uani 1 1 d .
I2 I 0.32383(5) 0.06878(4) 0.60185(4) 0.03253(14) Uani 1 1 d .
I3 I 0.00773(5) 0.06195(4) 0.29473(4) 0.03416(15) Uani 1 1 d .
As4 As 0.11962(7) 0.23813(5) 0.52881(6) 0.0246(2) Uani 1 1 d .
As5 As 0.16266(7) -0.13167(6) 0.40394(6) 0.0258(2) Uani 1 1 d .
O6 O -0.0888(5) 0.4348(4) 0.4000(4) 0.0335(14) Uani 1 1 d .
O7 O 0.2416(4) 0.2593(4) 0.8022(4) 0.0286(13) Uani 1 1 d .
O8 O 0.2953(5) -0.2230(3) 0.6386(4) 0.0277(13) Uani 1 1 d .
O9 O 0.3380(5) -0.3152(4) 0.4917(5) 0.0455(16) Uani 1 1 d .
O10 O 0.1506(5) -0.1568(4) 0.1764(4) 0.0356(14) Uani 1 1 d .
O11 O 0.2322(5) 0.4211(4) 0.7413(4) 0.0371(14) Uani 1 1 d .
O12 O 0.0753(5) 0.3556(3) 0.3501(4) 0.0291(13) Uani 1 1 d .
O13 O -0.0056(5) -0.3101(4) 0.1358(4) 0.0367(14) Uani 1 1 d .
C14 C -0.0150(8) 0.3945(6) 0.1891(6) 0.050(3) Uani 1 1 d .
H1 H -0.0404 0.3145 0.1663 0.075 Uiso 1 1 calc R
H2 H 0.0050 0.4336 0.1319 0.075 Uiso 1 1 calc R
H3 H -0.0854 0.4213 0.2212 0.075 Uiso 1 1 calc R
C15 C 0.3143(8) 0.3994(7) 0.9489(6) 0.057(3) Uani 1 1 d .
H4 H 0.2268 0.3744 0.9661 0.085 Uiso 1 1 calc R
H5 H 0.3188 0.4672 0.9178 0.085 Uiso 1 1 calc R
H6 H 0.3736 0.4149 1.0094 0.085 Uiso 1 1 calc R
C16 C 0.0559(7) -0.2336(6) 0.1972(7) 0.032(2) Uani 1 1 d .
C17 C 0.3683(9) 0.2095(7) 0.9280(7) 0.073(4) Uani 1 1 d .
H7 H 0.4392 0.2316 0.9805 0.109 Uiso 1 1 calc R
H8 H 0.3876 0.1517 0.8781 0.109 Uiso 1 1 calc R
H9 H 0.2893 0.1804 0.9572 0.109 Uiso 1 1 calc R
C18 C 0.4144(7) -0.2324(6) 0.6957(7) 0.039(2) Uani 1 1 d .
C19 C 0.3506(8) 0.3110(7) 0.8779(7) 0.044(2) Uani 1 1 d .
C20 C 0.4678(7) 0.3513(6) 0.8236(7) 0.049(3) Uani 1 1 d .
H10 H 0.5439 0.3727 0.8716 0.073 Uiso 1 1 calc R
H11 H 0.4549 0.4156 0.7918 0.073 Uiso 1 1 calc R
H12 H 0.4799 0.2914 0.7727 0.073 Uiso 1 1 calc R
C21 C 0.1951(7) 0.3230(6) 0.7434(6) 0.032(2) Uani 1 1 d .
C22 C 0.3216(7) -0.1416(5) 0.3548(6) 0.035(2) Uani 1 1 d .
H13 H 0.3902 -0.1145 0.4087 0.053 Uiso 1 1 calc R
H14 H 0.3353 -0.0962 0.3009 0.053 Uiso 1 1 calc R
H15 H 0.3221 -0.2193 0.3292 0.053 Uiso 1 1 calc R
C23 C 0.1466(8) 0.5366(6) 0.2986(7) 0.048(3) Uani 1 1 d .
H16 H 0.0733 0.5690 0.3186 0.073 Uiso 1 1 calc R
H17 H 0.1847 0.5733 0.2447 0.073 Uiso 1 1 calc R
H18 H 0.2107 0.5471 0.3558 0.073 Uiso 1 1 calc R
C24 C 0.1029(7) 0.4167(6) 0.2635(6) 0.0298(19) Uani 1 1 d .
C25 C 0.1470(7) -0.2372(5) 0.5004(6) 0.0263(18) Uani 1 1 d .
C26 C 0.4130(8) -0.3523(6) 0.7054(8) 0.071(4) Uani 1 1 d .
H19 H 0.3303 -0.3860 0.7266 0.106 Uiso 1 1 calc R
H20 H 0.4820 -0.3570 0.7550 0.106 Uiso 1 1 calc R
H21 H 0.4260 -0.3921 0.6408 0.106 Uiso 1 1 calc R
C27 C 0.2654(6) 0.3537(5) 0.5248(6) 0.034(2) Uani 1 1 d .
H22 H 0.2459 0.4254 0.5518 0.052 Uiso 1 1 calc R
H23 H 0.2862 0.3554 0.4557 0.052 Uiso 1 1 calc R
H24 H 0.3387 0.3395 0.5649 0.052 Uiso 1 1 calc R
C28 C -0.0221(7) 0.3693(5) 0.4035(6) 0.0266(19) Uani 1 1 d .
C29 C 0.2054(8) 0.3634(6) 0.2189(6) 0.052(3) Uani 1 1 d .
H25 H 0.2807 0.3766 0.2674 0.077 Uiso 1 1 calc R
H26 H 0.2293 0.3955 0.1588 0.077 Uiso 1 1 calc R
H27 H 0.1732 0.2831 0.2014 0.077 Uiso 1 1 calc R
C30 C 0.0752(9) -0.1336(6) 0.0089(7) 0.062(3) Uani 1 1 d .
H28 H 0.0070 -0.2001 0.0012 0.093 Uiso 1 1 calc R
H29 H 0.1014 -0.1191 -0.0569 0.093 Uiso 1 1 calc R
H30 H 0.0435 -0.0697 0.0411 0.093 Uiso 1 1 calc R
C31 C 0.2361(7) -0.2574(6) 0.0378(6) 0.045(2) Uani 1 1 d .
H31 H 0.2986 -0.2688 0.0896 0.068 Uiso 1 1 calc R
H32 H 0.2770 -0.2502 -0.0243 0.068 Uiso 1 1 calc R
H33 H 0.1641 -0.3211 0.0267 0.068 Uiso 1 1 calc R
C32 C 0.1868(9) -0.1516(7) 0.0712(6) 0.045(2) Uani 1 1 d .
C33 C 0.2707(7) -0.2661(6) 0.5425(7) 0.031(2) Uani 1 1 d .
C34 C 0.0256(7) -0.2151(5) 0.3015(6) 0.0262(18) Uani 1 1 d .
C35 C 0.5298(7) -0.1771(6) 0.6504(6) 0.037(2) Uani 1 1 d .
H34 H 0.5384 -0.2211 0.5867 0.056 Uiso 1 1 calc R
H35 H 0.6067 -0.1718 0.6958 0.056 Uiso 1 1 calc R
H36 H 0.5199 -0.1023 0.6391 0.056 Uiso 1 1 calc R
C36 C 0.4008(8) -0.1653(7) 0.7967(7) 0.062(3) Uani 1 1 d .
H37 H 0.3847 -0.0920 0.7862 0.093 Uiso 1 1 calc R
H38 H 0.4801 -0.1562 0.8402 0.093 Uiso 1 1 calc R
H39 H 0.3291 -0.2050 0.8280 0.093 Uiso 1 1 calc R
C37 C 0.0866(7) 0.2549(5) 0.6687(6) 0.0236(18) Uani 1 1 d .
C38 C 0.2956(10) -0.0509(7) 0.0865(7) 0.093(4) Uani 1 1 d .
H40 H 0.2641 0.0147 0.1151 0.139 Uiso 1 1 calc R
H41 H 0.3284 -0.0385 0.0222 0.139 Uiso 1 1 calc R
H42 H 0.3646 -0.0639 0.1320 0.139 Uiso 1 1 calc R
C39 C -0.0344(7) 0.2860(5) 0.4761(5) 0.0253(18) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
As As 0.0499 2.0058 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
I I -0.4742 1.8119 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
As4 Pt1 As5 176.99(3) . .
As4 Pt1 I2 87.71(6) . .
As5 Pt1 I2 89.31(5) . .
As4 Pt1 I3 92.11(6) . .
As5 Pt1 I3 90.59(6) . .
I2 Pt1 I3 162.10(2) . .
As4 Pt1 Pt1 92.79(5) . 2_556
As5 Pt1 Pt1 88.73(5) . 2_556
I2 Pt1 Pt1 111.63(7) . 2_556
I3 Pt1 Pt1 86.27(6) . 2_556
C27 As4 C37 103.2(3) . .
C27 As4 C39 108.6(3) . .
C37 As4 C39 97.5(3) . .
C27 As4 Pt1 117.4(2) . .
C37 As4 Pt1 113.26(19) . .
C39 As4 Pt1 114.6(2) . .
C22 As5 C25 103.0(3) . .
C22 As5 C34 107.9(3) . .
C25 As5 C34 98.5(3) . .
C22 As5 Pt1 115.3(2) . .
C25 As5 Pt1 116.3(2) . .
C34 As5 Pt1 113.99(19) . .
C21 O7 C19 118.8(6) . .
C33 O8 C18 120.8(6) . .
C16 O10 C32 121.6(6) . .
C28 O12 C24 121.3(6) . .
C24 C14 H1 109.5 . .
C24 C14 H2 109.5 . .
H1 C14 H2 109.5 . .
C24 C14 H3 109.5 . .
H1 C14 H3 109.5 . .
H2 C14 H3 109.5 . .
C19 C15 H4 109.5 . .
C19 C15 H5 109.5 . .
H4 C15 H5 109.5 . .
C19 C15 H6 109.5 . .
H4 C15 H6 109.5 . .
H5 C15 H6 109.5 . .
O13 C16 O10 124.5(8) . .
O13 C16 C34 122.6(7) . .
O10 C16 C34 112.8(7) . .
C19 C17 H7 109.5 . .
C19 C17 H8 109.5 . .
H7 C17 H8 109.5 . .
C19 C17 H9 109.5 . .
H7 C17 H9 109.5 . .
H8 C17 H9 109.5 . .
O8 C18 C35 110.7(6) . .
O8 C18 C26 109.7(6) . .
C35 C18 C26 113.7(7) . .
O8 C18 C36 100.6(7) . .
C35 C18 C36 110.1(6) . .
C26 C18 C36 111.2(8) . .
C15 C19 O7 110.7(7) . .
C15 C19 C20 114.0(7) . .
O7 C19 C20 108.5(7) . .
C15 C19 C17 112.0(8) . .
O7 C19 C17 100.3(6) . .
C20 C19 C17 110.4(7) . .
C19 C20 H10 109.5 . .
C19 C20 H11 109.5 . .
H10 C20 H11 109.5 . .
C19 C20 H12 109.5 . .
H10 C20 H12 109.5 . .
H11 C20 H12 109.5 . .
O11 C21 O7 127.7(7) . .
O11 C21 C37 120.9(7) . .
O7 C21 C37 111.3(6) . .
As5 C22 H13 109.5 . .
As5 C22 H14 109.5 . .
H13 C22 H14 109.5 . .
As5 C22 H15 109.5 . .
H13 C22 H15 109.5 . .
H14 C22 H15 109.5 . .
C24 C23 H16 109.5 . .
C24 C23 H17 109.5 . .
H16 C23 H17 109.5 . .
C24 C23 H18 109.5 . .
H16 C23 H18 109.5 . .
H17 C23 H18 109.5 . .
C23 C24 O12 110.0(7) . .
C23 C24 C29 113.0(7) . .
O12 C24 C29 102.1(6) . .
C23 C24 C14 111.5(6) . .
O12 C24 C14 110.2(6) . .
C29 C24 C14 109.6(7) . .
C39 C25 C33 121.2(7) 2_556 .
C39 C25 As5 121.6(6) 2_556 .
C33 C25 As5 117.0(5) . .
C18 C26 H19 109.5 . .
C18 C26 H20 109.5 . .
H19 C26 H20 109.5 . .
C18 C26 H21 109.5 . .
H19 C26 H21 109.5 . .
H20 C26 H21 109.5 . .
As4 C27 H22 109.5 . .
As4 C27 H23 109.5 . .
H22 C27 H23 109.5 . .
As4 C27 H24 109.5 . .
H22 C27 H24 109.5 . .
H23 C27 H24 109.5 . .
O6 C28 O12 128.6(7) . .
O6 C28 C39 123.1(8) . .
O12 C28 C39 108.2(6) . .
C24 C29 H25 109.5 . .
C24 C29 H26 109.5 . .
H25 C29 H26 109.5 . .
C24 C29 H27 109.5 . .
H25 C29 H27 109.5 . .
H26 C29 H27 109.5 . .
C32 C30 H28 109.5 . .
C32 C30 H29 109.5 . .
H28 C30 H29 109.5 . .
C32 C30 H30 109.5 . .
H28 C30 H30 109.5 . .
H29 C30 H30 109.5 . .
C32 C31 H31 109.5 . .
C32 C31 H32 109.5 . .
H31 C31 H32 109.5 . .
C32 C31 H33 109.5 . .
H31 C31 H33 109.5 . .
H32 C31 H33 109.5 . .
C30 C32 O10 108.8(7) . .
C30 C32 C38 112.0(7) . .
O10 C32 C38 101.4(7) . .
C30 C32 C31 115.6(7) . .
O10 C32 C31 107.1(6) . .
C38 C32 C31 110.7(8) . .
O9 C33 O8 127.0(8) . .
O9 C33 C25 123.1(8) . .
O8 C33 C25 109.7(7) . .
C37 C34 C16 123.2(7) 2_556 .
C37 C34 As5 118.0(6) 2_556 .
C16 C34 As5 118.7(6) . .
C18 C35 H34 109.5 . .
C18 C35 H35 109.5 . .
H34 C35 H35 109.5 . .
C18 C35 H36 109.5 . .
H34 C35 H36 109.5 . .
H35 C35 H36 109.5 . .
C18 C36 H37 109.5 . .
C18 C36 H38 109.5 . .
H37 C36 H38 109.5 . .
C18 C36 H39 109.5 . .
H37 C36 H39 109.5 . .
H38 C36 H39 109.5 . .
C34 C37 C21 120.6(7) 2_556 .
C34 C37 As4 122.2(6) 2_556 .
C21 C37 As4 117.1(5) . .
C32 C38 H40 109.5 . .
C32 C38 H41 109.5 . .
H40 C38 H41 109.5 . .
C32 C38 H42 109.5 . .
H40 C38 H42 109.5 . .
H41 C38 H42 109.5 . .
C25 C39 C28 121.7(7) 2_556 .
C25 C39 As4 118.4(6) 2_556 .
C28 C39 As4 119.7(5) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Pt1 As4 2.3921(16) .
Pt1 As5 2.3959(16) .
Pt1 I2 2.6172(19) .
Pt1 I3 2.621(2) .
Pt1 Pt1 3.220(2) 2_556
As4 C27 1.913(6) .
As4 C37 1.946(8) .
As4 C39 1.970(7) .
As5 C22 1.879(7) .
As5 C25 1.957(7) .
As5 C34 1.986(7) .
O6 C28 1.177(8) .
O7 C21 1.327(8) .
O7 C19 1.490(8) .
O8 C33 1.336(9) .
O8 C18 1.476(8) .
O9 C33 1.215(9) .
O10 C16 1.322(8) .
O10 C32 1.509(9) .
O11 C21 1.208(8) .
O12 C28 1.328(9) .
O12 C24 1.492(8) .
O13 C16 1.232(8) .
C14 C24 1.522(10) .
C14 H1 0.9800 .
C14 H2 0.9800 .
C14 H3 0.9800 .
C15 C19 1.486(11) .
C15 H4 0.9800 .
C15 H5 0.9800 .
C15 H6 0.9800 .
C16 C34 1.472(11) .
C17 C19 1.538(10) .
C17 H7 0.9800 .
C17 H8 0.9800 .
C17 H9 0.9800 .
C18 C35 1.499(10) .
C18 C26 1.503(9) .
C18 C36 1.539(12) .
C19 C20 1.527(11) .
C20 H10 0.9800 .
C20 H11 0.9800 .
C20 H12 0.9800 .
C21 C37 1.530(10) .
C22 H13 0.9800 .
C22 H14 0.9800 .
C22 H15 0.9800 .
C23 C24 1.475(9) .
C23 H16 0.9800 .
C23 H17 0.9800 .
C23 H18 0.9800 .
C24 C29 1.499(10) .
C25 C39 1.316(9) 2_556
C25 C33 1.526(10) .
C26 H19 0.9800 .
C26 H20 0.9800 .
C26 H21 0.9800 .
C27 H22 0.9800 .
C27 H23 0.9800 .
C27 H24 0.9800 .
C28 C39 1.508(9) .
C29 H25 0.9800 .
C29 H26 0.9800 .
C29 H27 0.9800 .
C30 C32 1.484(11) .
C30 H28 0.9800 .
C30 H29 0.9800 .
C30 H30 0.9800 .
C31 C32 1.526(10) .
C31 H31 0.9800 .
C31 H32 0.9800 .
C31 H33 0.9800 .
C32 C38 1.517(10) .
C34 C37 1.315(9) 2_556
C35 H34 0.9800 .
C35 H35 0.9800 .
C35 H36 0.9800 .
C36 H37 0.9800 .
C36 H38 0.9800 .
C36 H39 0.9800 .
C37 C34 1.315(9) 2_556
C38 H40 0.9800 .
C38 H41 0.9800 .
C38 H42 0.9800 .
C39 C25 1.316(9) 2_556
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
As5 Pt1 As4 C27 53.2(7) . .
I2 Pt1 As4 C27 62.0(3) . .
I3 Pt1 As4 C27 -100.1(3) . .
Pt1 Pt1 As4 C27 173.5(3) 2_556 .
As5 Pt1 As4 C37 -67.0(7) . .
I2 Pt1 As4 C37 -58.2(2) . .
I3 Pt1 As4 C37 139.7(2) . .
Pt1 Pt1 As4 C37 53.3(2) 2_556 .
As5 Pt1 As4 C39 -178(38) . .
I2 Pt1 As4 C39 -168.9(2) . .
I3 Pt1 As4 C39 29.0(2) . .
Pt1 Pt1 As4 C39 -57.3(2) 2_556 .
As4 Pt1 As5 C22 -54.5(7) . .
I2 Pt1 As5 C22 -63.2(3) . .
I3 Pt1 As5 C22 98.9(3) . .
Pt1 Pt1 As5 C22 -174.9(3) 2_556 .
As4 Pt1 As5 C25 66.2(7) . .
I2 Pt1 As5 C25 57.5(2) . .
I3 Pt1 As5 C25 -140.4(2) . .
Pt1 Pt1 As5 C25 -54.2(2) 2_556 .
As4 Pt1 As5 C34 180(100) . .
I2 Pt1 As5 C34 171.1(3) . .
I3 Pt1 As5 C34 -26.8(3) . .
Pt1 Pt1 As5 C34 59.4(3) 2_556 .
C32 O10 C16 O13 4.2(11) . .
C32 O10 C16 C34 -172.5(6) . .
C33 O8 C18 C35 60.2(8) . .
C33 O8 C18 C26 -66.1(9) . .
C33 O8 C18 C36 176.6(6) . .
C21 O7 C19 C15 60.2(9) . .
C21 O7 C19 C20 -65.5(9) . .
C21 O7 C19 C17 178.7(7) . .
C19 O7 C21 O11 1.7(12) . .
C19 O7 C21 C37 178.3(7) . .
C28 O12 C24 C23 67.7(8) . .
C28 O12 C24 C29 -172.1(6) . .
C28 O12 C24 C14 -55.7(9) . .
C22 As5 C25 C39 -154.2(6) . 2_556
C34 As5 C25 C39 -43.5(7) . 2_556
Pt1 As5 C25 C39 78.7(6) . 2_556
C22 As5 C25 C33 22.0(6) . .
C34 As5 C25 C33 132.7(6) . .
Pt1 As5 C25 C33 -105.1(5) . .
C24 O12 C28 O6 -8.8(12) . .
C24 O12 C28 C39 172.8(5) . .
C16 O10 C32 C30 60.9(9) . .
C16 O10 C32 C38 179.1(7) . .
C16 O10 C32 C31 -64.8(9) . .
C18 O8 C33 O9 -0.3(11) . .
C18 O8 C33 C25 -175.9(5) . .
C39 C25 C33 O9 111.0(9) 2_556 .
As5 C25 C33 O9 -65.2(8) . .
C39 C25 C33 O8 -73.2(8) 2_556 .
As5 C25 C33 O8 110.6(6) . .
O13 C16 C34 C37 -20.3(11) . 2_556
O10 C16 C34 C37 156.5(7) . 2_556
O13 C16 C34 As5 156.9(6) . .
O10 C16 C34 As5 -26.4(8) . .
C22 As5 C34 C37 154.9(6) . 2_556
C25 As5 C34 C37 48.3(6) . 2_556
Pt1 As5 C34 C37 -75.6(6) . 2_556
C22 As5 C34 C16 -22.4(6) . .
C25 As5 C34 C16 -129.0(5) . .
Pt1 As5 C34 C16 107.1(5) . .
O11 C21 C37 C34 -111.8(9) . 2_556
O7 C21 C37 C34 71.3(9) . 2_556
O11 C21 C37 As4 64.7(9) . .
O7 C21 C37 As4 -112.2(6) . .
C27 As4 C37 C34 159.1(6) . 2_556
C39 As4 C37 C34 47.9(6) . 2_556
Pt1 As4 C37 C34 -73.0(6) . 2_556
C27 As4 C37 C21 -17.3(6) . .
C39 As4 C37 C21 -128.5(5) . .
Pt1 As4 C37 C21 110.6(5) . .
O6 C28 C39 C25 38.1(11) . 2_556
O12 C28 C39 C25 -143.4(7) . 2_556
O6 C28 C39 As4 -147.4(6) . .
O12 C28 C39 As4 31.1(8) . .
C27 As4 C39 C25 -159.3(6) . 2_556
C37 As4 C39 C25 -52.6(6) . 2_556
Pt1 As4 C39 C25 67.3(6) . 2_556
C27 As4 C39 C28 26.0(6) . .
C37 As4 C39 C28 132.7(6) . .
Pt1 As4 C39 C28 -107.4(5) . .
