#------------------------------------------------------------------------------
#$Date: 2016-03-21 06:20:14 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178504 $
#$URL: svn://www.crystallography.net/cod/cif/4/06/60/4066032.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4066032
loop_
_publ_author_name
'Takeda, Nobuhiro'
'Watanabe, Daisuke'
'Nakamura, Tetsu'
'Unno, Masafumi'
_publ_section_title
;
 Synthesis and Complexation of a New Tripodal Tetradentate Ligand, a Silyl
 Ligand Tethered with Three Thioether Moieties
;
_journal_issue                   13
_journal_name_full               Organometallics
_journal_page_first              2839
_journal_paper_doi               10.1021/om100255p
_journal_volume                  29
_journal_year                    2010
_chemical_formula_moiety         'C33 H45 Cl Pt S3 Si 0.375(C6H14)'
_chemical_formula_sum            'C35.25 H50.25 Cl Pt S3 Si'
_chemical_formula_weight         828.81
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                109.292(2)
_cell_angle_beta                 100.7572(19)
_cell_angle_gamma                97.7360(18)
_cell_formula_units_Z            4
_cell_length_a                   11.1478(8)
_cell_length_b                   18.9318(17)
_cell_length_c                   19.6732(17)
_cell_measurement_reflns_used    20178
_cell_measurement_temperature    123(2)
_cell_measurement_theta_max      28.2812
_cell_measurement_theta_min      2.9015
_cell_volume                     3762.7(5)
_computing_cell_refinement       'CrystalClear (Rigaku Corp., 2000)'
_computing_data_collection       'CrystalClear (Rigaku Corp., 2000)'
_computing_data_reduction        'CrystalClear (Rigaku Corp., 2000)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      123(2)
_diffrn_detector_area_resol_mean 10.0000
_diffrn_measured_fraction_theta_full 0.935
_diffrn_measured_fraction_theta_max 0.935
_diffrn_measurement_device_type
;
RAXIS conversion
;
_diffrn_measurement_method       dtprofit.ref
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71070
_diffrn_reflns_av_R_equivalents  0.0351
_diffrn_reflns_av_sigmaI/netI    0.0515
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            25793
_diffrn_reflns_theta_full        25.50
_diffrn_reflns_theta_max         25.50
_diffrn_reflns_theta_min         2.90
_exptl_absorpt_coefficient_mu    4.021
_exptl_absorpt_correction_T_max  0.8243
_exptl_absorpt_correction_T_min  0.3784
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            Colorless
_exptl_crystal_density_diffrn    1.463
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Prism
_exptl_crystal_F_000             1675
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.05
_refine_diff_density_max         0.953
_refine_diff_density_min         -1.600
_refine_diff_density_rms         0.151
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.327
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     731
_refine_ls_number_reflns         13087
_refine_ls_number_restraints     6
_refine_ls_restrained_S_all      1.327
_refine_ls_R_factor_all          0.0719
_refine_ls_R_factor_gt           0.0692
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0000P)²+44.1873P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1286
_refine_ls_wR_factor_ref         0.1296
_reflns_number_gt                12783
_reflns_number_total             13087
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            om100255p_si_001.cif
_cod_data_source_block           ptsisbu
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_absorpt_correction_type' value 'Multi-scan' changed to
'multi-scan' according to
/home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               4066032
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.35485(3) 0.22952(2) 0.232618(19) 0.02017(10) Uani 1 1 d . . .
Cl1 Cl 0.4766(2) 0.15517(15) 0.28879(14) 0.0312(5) Uani 1 1 d . . .
Si1 Si 0.2219(2) 0.30330(15) 0.19823(14) 0.0206(5) Uani 1 1 d . . .
S1 S 0.1939(2) 0.15452(14) 0.25241(13) 0.0224(5) Uani 1 1 d . . .
S2 S 0.5137(2) 0.30647(14) 0.21362(12) 0.0223(5) Uani 1 1 d . . .
S3 S 0.2422(3) 0.13259(18) -0.04774(14) 0.0384(7) Uani 1 1 d . . .
C1 C 0.1442(8) 0.3325(6) 0.2780(5) 0.024(2) Uani 1 1 d . . .
C2 C 0.0813(9) 0.2776(6) 0.3000(6) 0.027(2) Uani 1 1 d . . .
C3 C 0.0367(9) 0.2995(7) 0.3644(6) 0.033(2) Uani 1 1 d . . .
H1 H -0.0057 0.2617 0.3785 0.040 Uiso 1 1 calc R . .
C4 C 0.0545(9) 0.3762(7) 0.4074(5) 0.033(2) Uani 1 1 d . . .
H2 H 0.0255 0.3909 0.4515 0.040 Uiso 1 1 calc R . .
C5 C 0.1143(9) 0.4320(7) 0.3865(5) 0.031(2) Uani 1 1 d . . .
H3 H 0.1239 0.4847 0.4152 0.038 Uiso 1 1 calc R . .
C6 C 0.1602(9) 0.4103(6) 0.3233(5) 0.025(2) Uani 1 1 d . . .
H4 H 0.2034 0.4487 0.3103 0.030 Uiso 1 1 calc R . .
C7 C 0.0542(8) 0.1948(6) 0.2515(6) 0.030(2) Uani 1 1 d . . .
H5 H 0.0152 0.1888 0.1999 0.036 Uiso 1 1 calc R . .
H6 H -0.0065 0.1656 0.2685 0.036 Uiso 1 1 calc R . .
C8 C 0.2935(9) 0.3958(6) 0.1880(5) 0.026(2) Uani 1 1 d . . .
C9 C 0.4192(9) 0.4341(5) 0.2247(5) 0.023(2) Uani 1 1 d . . .
C10 C 0.4675(11) 0.5028(6) 0.2183(6) 0.037(3) Uani 1 1 d . . .
H7 H 0.5520 0.5280 0.2422 0.045 Uiso 1 1 calc R . .
C11 C 0.3918(12) 0.5343(6) 0.1769(6) 0.045(3) Uani 1 1 d . . .
H8 H 0.4243 0.5809 0.1720 0.054 Uiso 1 1 calc R . .
C12 C 0.2676(12) 0.4968(7) 0.1427(7) 0.042(3) Uani 1 1 d . . .
H9 H 0.2147 0.5191 0.1158 0.051 Uiso 1 1 calc R . .
C13 C 0.2208(11) 0.4283(6) 0.1473(6) 0.033(2) Uani 1 1 d . . .
H10 H 0.1368 0.4028 0.1219 0.039 Uiso 1 1 calc R . .
C14 C 0.5024(9) 0.4028(6) 0.2711(5) 0.028(2) Uani 1 1 d . . .
H11 H 0.4681 0.4005 0.3134 0.033 Uiso 1 1 calc R . .
H12 H 0.5866 0.4367 0.2912 0.033 Uiso 1 1 calc R . .
C15 C 0.0920(9) 0.2571(5) 0.1087(5) 0.024(2) Uani 1 1 d . . .
C16 C 0.1150(9) 0.2243(6) 0.0382(5) 0.031(2) Uani 1 1 d . . .
C17 C 0.0177(11) 0.2021(8) -0.0248(6) 0.049(3) Uani 1 1 d . . .
H13 H 0.0335 0.1806 -0.0724 0.059 Uiso 1 1 calc R . .
C18 C -0.1013(11) 0.2106(8) -0.0198(6) 0.054(4) Uani 1 1 d . . .
H14 H -0.1662 0.1950 -0.0639 0.065 Uiso 1 1 calc R . .
C19 C -0.1275(11) 0.2412(8) 0.0478(7) 0.049(3) Uani 1 1 d . . .
H15 H -0.2102 0.2460 0.0508 0.059 Uiso 1 1 calc R . .
C20 C -0.0312(9) 0.2653(7) 0.1122(6) 0.035(2) Uani 1 1 d . . .
H16 H -0.0486 0.2876 0.1593 0.041 Uiso 1 1 calc R . .
C21 C 0.2463(9) 0.2161(7) 0.0327(5) 0.033(2) Uani 1 1 d . . .
H17 H 0.2921 0.2109 0.0784 0.040 Uiso 1 1 calc R . .
H18 H 0.2911 0.2626 0.0282 0.040 Uiso 1 1 calc R . .
C22 C 0.1354(11) 0.0598(6) 0.1723(6) 0.036(3) Uani 1 1 d . . .
C23 C 0.2345(14) 0.0132(8) 0.1798(8) 0.066(4) Uani 1 1 d . . .
H19 H 0.2451 0.0067 0.2278 0.100 Uiso 1 1 calc R . .
H20 H 0.3138 0.0401 0.1769 0.100 Uiso 1 1 calc R . .
H21 H 0.2084 -0.0371 0.1395 0.100 Uiso 1 1 calc R . .
C24 C 0.0159(13) 0.0220(8) 0.1855(9) 0.067(4) Uani 1 1 d . . .
H22 H 0.0355 0.0151 0.2333 0.101 Uiso 1 1 calc R . .
H23 H -0.0190 -0.0280 0.1455 0.101 Uiso 1 1 calc R . .
H24 H -0.0453 0.0547 0.1862 0.101 Uiso 1 1 calc R . .
C25 C 0.1130(14) 0.0695(7) 0.0987(6) 0.056(4) Uani 1 1 d . . .
H25 H 0.0479 0.0991 0.0953 0.085 Uiso 1 1 calc R . .
H26 H 0.0860 0.0191 0.0586 0.085 Uiso 1 1 calc R . .
H27 H 0.1904 0.0968 0.0940 0.085 Uiso 1 1 calc R . .
C26 C 0.6770(9) 0.3020(6) 0.2549(5) 0.031(2) Uani 1 1 d . . .
C27 C 0.7644(9) 0.3619(6) 0.2388(7) 0.039(3) Uani 1 1 d . . .
H28 H 0.7542 0.4134 0.2664 0.059 Uiso 1 1 calc R . .
H29 H 0.7430 0.3523 0.1854 0.059 Uiso 1 1 calc R . .
H30 H 0.8512 0.3581 0.2543 0.059 Uiso 1 1 calc R . .
C28 C 0.7012(9) 0.3202(7) 0.3383(5) 0.035(3) Uani 1 1 d . . .
H31 H 0.6894 0.3721 0.3629 0.053 Uiso 1 1 calc R . .
H32 H 0.7870 0.3169 0.3576 0.053 Uiso 1 1 calc R . .
H33 H 0.6426 0.2833 0.3479 0.053 Uiso 1 1 calc R . .
C29 C 0.6942(9) 0.2228(6) 0.2113(6) 0.032(2) Uani 1 1 d . . .
H34 H 0.6775 0.2149 0.1583 0.048 Uiso 1 1 calc R . .
H35 H 0.6360 0.1840 0.2187 0.048 Uiso 1 1 calc R . .
H36 H 0.7801 0.2184 0.2288 0.048 Uiso 1 1 calc R . .
C30 C 0.4037(11) 0.1182(8) -0.0346(6) 0.043(3) Uani 1 1 d . . .
C31 C 0.4936(12) 0.1905(9) -0.0257(10) 0.073(5) Uani 1 1 d . . .
H37 H 0.4947 0.2314 0.0207 0.109 Uiso 1 1 calc R . .
H38 H 0.4663 0.2064 -0.0677 0.109 Uiso 1 1 calc R . .
H39 H 0.5777 0.1803 -0.0244 0.109 Uiso 1 1 calc R . .
C32 C 0.4409(13) 0.0959(8) 0.0331(6) 0.053(4) Uani 1 1 d . . .
H40 H 0.3836 0.0488 0.0266 0.080 Uiso 1 1 calc R . .
H41 H 0.4364 0.1372 0.0778 0.080 Uiso 1 1 calc R . .
H42 H 0.5264 0.0875 0.0382 0.080 Uiso 1 1 calc R . .
C33 C 0.3986(13) 0.0522(9) -0.1058(6) 0.062(4) Uani 1 1 d . . .
H43 H 0.3411 0.0065 -0.1091 0.093 Uiso 1 1 calc R . .
H44 H 0.4822 0.0414 -0.1053 0.093 Uiso 1 1 calc R . .
H45 H 0.3692 0.0662 -0.1487 0.093 Uiso 1 1 calc R . .
Pt2 Pt 0.81415(3) 0.68607(2) 0.430069(19) 0.01974(10) Uani 1 1 d . . .
Cl2 Cl 0.7733(2) 0.54842(13) 0.40785(13) 0.0252(5) Uani 1 1 d . . .
Si2 Si 0.8704(2) 0.81563(15) 0.45118(13) 0.0195(5) Uani 1 1 d . . .
S4 S 0.6319(2) 0.71334(14) 0.46045(12) 0.0210(5) Uani 1 1 d . . .
S5 S 1.0086(2) 0.66777(14) 0.41272(13) 0.0218(5) Uani 1 1 d . . .
S6 S 0.5366(3) 0.75133(17) 0.22266(15) 0.0406(7) Uani 1 1 d . . .
C34 C 0.7658(8) 0.8801(6) 0.4908(5) 0.023(2) Uani 1 1 d . . .
C35 C 0.6939(9) 0.8661(5) 0.5385(5) 0.023(2) Uani 1 1 d . . .
C36 C 0.6220(9) 0.9170(6) 0.5701(6) 0.030(2) Uani 1 1 d . . .
H46 H 0.5726 0.9059 0.6012 0.036 Uiso 1 1 calc R . .
C37 C 0.6238(10) 0.9841(6) 0.5554(6) 0.036(3) Uani 1 1 d . . .
H47 H 0.5775 1.0199 0.5779 0.043 Uiso 1 1 calc R . .
C38 C 0.6924(10) 0.9988(6) 0.5084(6) 0.032(2) Uani 1 1 d . . .
H48 H 0.6905 1.0437 0.4970 0.039 Uiso 1 1 calc R . .
C39 C 0.7647(9) 0.9483(6) 0.4774(5) 0.027(2) Uani 1 1 d . . .
H49 H 0.8142 0.9603 0.4466 0.032 Uiso 1 1 calc R . .
C40 C 0.6876(9) 0.7917(5) 0.5526(5) 0.024(2) Uani 1 1 d . . .
H50 H 0.6290 0.7881 0.5840 0.028 Uiso 1 1 calc R . .
H51 H 0.7711 0.7888 0.5781 0.028 Uiso 1 1 calc R . .
C41 C 1.0235(8) 0.8516(5) 0.5249(5) 0.0213(19) Uani 1 1 d . . .
C42 C 1.1241(9) 0.8152(5) 0.5160(5) 0.023(2) Uani 1 1 d . . .
C43 C 1.2310(9) 0.8368(6) 0.5750(5) 0.026(2) Uani 1 1 d . . .
H52 H 1.2977 0.8108 0.5688 0.031 Uiso 1 1 calc R . .
C44 C 1.2413(10) 0.8949(6) 0.6415(6) 0.032(2) Uani 1 1 d . . .
H53 H 1.3143 0.9090 0.6809 0.039 Uiso 1 1 calc R . .
C45 C 1.1426(10) 0.9328(6) 0.6503(6) 0.031(2) Uani 1 1 d . . .
H54 H 1.1494 0.9741 0.6954 0.037 Uiso 1 1 calc R . .
C46 C 1.0348(8) 0.9102(6) 0.5933(5) 0.025(2) Uani 1 1 d . . .
H55 H 0.9671 0.9350 0.6007 0.030 Uiso 1 1 calc R . .
C47 C 1.1241(9) 0.7577(6) 0.4423(5) 0.028(2) Uani 1 1 d . . .
H56 H 1.2083 0.7459 0.4447 0.033 Uiso 1 1 calc R . .
H57 H 1.1078 0.7809 0.4041 0.033 Uiso 1 1 calc R . .
C48 C 0.8905(9) 0.8372(5) 0.3665(5) 0.024(2) Uani 1 1 d . . .
C49 C 0.7953(10) 0.8121(6) 0.3000(5) 0.028(2) Uani 1 1 d . . .
C50 C 0.8179(11) 0.8277(7) 0.2390(6) 0.039(3) Uani 1 1 d . . .
H58 H 0.7531 0.8099 0.1945 0.047 Uiso 1 1 calc R . .
C51 C 0.9314(12) 0.8682(7) 0.2409(6) 0.044(3) Uani 1 1 d . . .
H59 H 0.9459 0.8771 0.1980 0.053 Uiso 1 1 calc R . .
C52 C 1.0253(11) 0.8962(6) 0.3074(6) 0.035(2) Uani 1 1 d . . .
H60 H 1.1037 0.9253 0.3102 0.042 Uiso 1 1 calc R . .
C53 C 1.0040(9) 0.8815(6) 0.3686(6) 0.027(2) Uani 1 1 d . . .
H61 H 1.0677 0.9019 0.4136 0.032 Uiso 1 1 calc R . .
C54 C 0.6711(10) 0.7628(6) 0.2960(6) 0.035(2) Uani 1 1 d . . .
H62 H 0.6492 0.7850 0.3441 0.042 Uiso 1 1 calc R . .
H63 H 0.6854 0.7112 0.2915 0.042 Uiso 1 1 calc R . .
C55 C 0.5264(9) 0.6413(6) 0.4806(5) 0.028(2) Uani 1 1 d . . .
C56 C 0.5933(9) 0.6166(6) 0.5410(5) 0.026(2) Uani 1 1 d . . .
H64 H 0.6235 0.6609 0.5877 0.038 Uiso 1 1 calc R . .
H65 H 0.6643 0.5957 0.5263 0.038 Uiso 1 1 calc R . .
H66 H 0.5352 0.5773 0.5478 0.038 Uiso 1 1 calc R . .
C57 C 0.4748(9) 0.5757(6) 0.4058(5) 0.029(2) Uani 1 1 d . . .
H67 H 0.4332 0.5950 0.3693 0.044 Uiso 1 1 calc R . .
H68 H 0.4146 0.5362 0.4110 0.044 Uiso 1 1 calc R . .
H69 H 0.5435 0.5536 0.3890 0.044 Uiso 1 1 calc R . .
C58 C 0.4188(9) 0.6796(6) 0.5031(6) 0.035(3) Uani 1 1 d . . .
H70 H 0.3781 0.6949 0.4632 0.053 Uiso 1 1 calc R . .
H71 H 0.4522 0.7249 0.5487 0.053 Uiso 1 1 calc R . .
H72 H 0.3577 0.6432 0.5118 0.053 Uiso 1 1 calc R . .
C59 C 1.0154(9) 0.6248(6) 0.3128(6) 0.031(2) Uani 1 1 d . . .
C60 C 0.9322(10) 0.5452(6) 0.2814(6) 0.036(3) Uani 1 1 d . . .
H73 H 0.8450 0.5494 0.2790 0.054 Uiso 1 1 calc R . .
H74 H 0.9568 0.5169 0.3135 0.054 Uiso 1 1 calc R . .
H75 H 0.9411 0.5179 0.2313 0.054 Uiso 1 1 calc R . .
C61 C 1.1517(10) 0.6168(7) 0.3157(6) 0.040(3) Uani 1 1 d . . .
H76 H 1.2064 0.6678 0.3355 0.060 Uiso 1 1 calc R . .
H77 H 1.1594 0.5890 0.2655 0.060 Uiso 1 1 calc R . .
H78 H 1.1761 0.5886 0.3480 0.060 Uiso 1 1 calc R . .
C62 C 0.9751(14) 0.6728(7) 0.2681(6) 0.051(3) Uani 1 1 d . . .
H79 H 1.0312 0.7235 0.2894 0.077 Uiso 1 1 calc R . .
H80 H 0.8895 0.6786 0.2695 0.077 Uiso 1 1 calc R . .
H81 H 0.9787 0.6476 0.2165 0.077 Uiso 1 1 calc R . .
C63 C 0.4515(10) 0.8241(7) 0.2656(6) 0.038(3) Uani 1 1 d . . .
C64 C 0.3396(13) 0.8133(10) 0.2035(8) 0.071(5) Uani 1 1 d . . .
H82 H 0.3680 0.8219 0.1621 0.106 Uiso 1 1 calc R . .
H83 H 0.2880 0.8499 0.2217 0.106 Uiso 1 1 calc R . .
H84 H 0.2901 0.7610 0.1864 0.106 Uiso 1 1 calc R . .
C65 C 0.4097(12) 0.8115(8) 0.3313(7) 0.049(3) Uani 1 1 d . . .
H85 H 0.4832 0.8200 0.3714 0.074 Uiso 1 1 calc R . .
H86 H 0.3621 0.7589 0.3153 0.074 Uiso 1 1 calc R . .
H87 H 0.3568 0.8474 0.3491 0.074 Uiso 1 1 calc R . .
C66 C 0.5317(13) 0.9053(7) 0.2906(7) 0.049(3) Uani 1 1 d . . .
H88 H 0.6040 0.9124 0.3311 0.073 Uiso 1 1 calc R . .
H89 H 0.4816 0.9431 0.3081 0.073 Uiso 1 1 calc R . .
H90 H 0.5608 0.9120 0.2487 0.073 Uiso 1 1 calc R . .
C67 C 0.747(2) 0.6382(14) 0.0704(14) 0.125(8) Uiso 1 1 d D A .
C68 C 0.608(2) 0.6064(13) 0.0348(15) 0.132(9) Uiso 1 1 d D . .
C69 C 0.513(5) 0.612(5) -0.027(3) 0.24(4) Uiso 0.50 1 d PD A 1
C70 C 0.405(6) 0.599(4) 0.007(3) 0.17(2) Uiso 0.50 1 d PD A 1
C71 C 0.294(6) 0.581(4) -0.059(3) 0.18(3) Uiso 0.50 1 d PD A 1
C72 C 0.165(6) 0.574(4) -0.042(4) 0.17(2) Uiso 0.50 1 d PD A 1
C73 C 0.569(2) 0.5200(13) 0.0224(14) 0.049(6) Uiso 0.50 1 d PD . 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_3
S2 Pt1 S1 178.83(9) .
S2 Pt1 Si1 87.43(9) .
S1 Pt1 Si1 91.59(9) .
S2 Pt1 Cl1 99.85(8) .
S1 Pt1 Cl1 81.04(8) .
Si1 Pt1 Cl1 169.12(9) .
C1 Si1 C15 107.3(4) .
C1 Si1 C8 106.6(4) .
C15 Si1 C8 101.5(4) .
C1 Si1 Pt1 103.0(3) .
C15 Si1 Pt1 119.1(3) .
C8 Si1 Pt1 118.6(3) .
C7 S1 C22 101.9(5) .
C7 S1 Pt1 112.3(3) .
C22 S1 Pt1 110.9(3) .
C14 S2 C26 102.3(4) .
C14 S2 Pt1 102.3(3) .
C26 S2 Pt1 116.4(4) .
C21 S3 C30 104.7(5) .
C2 C1 C6 117.3(9) .
C2 C1 Si1 121.2(8) .
C6 C1 Si1 121.1(8) .
C3 C2 C1 121.0(10) .
C3 C2 C7 119.3(9) .
C1 C2 C7 119.6(9) .
C4 C3 C2 120.0(10) .
C4 C3 H1 120.0 .
C2 C3 H1 120.0 .
C3 C4 C5 120.4(9) .
C3 C4 H2 119.8 .
C5 C4 H2 119.8 .
C4 C5 C6 119.6(10) .
C4 C5 H3 120.2 .
C6 C5 H3 120.2 .
C5 C6 C1 121.7(10) .
C5 C6 H4 119.1 .
C1 C6 H4 119.1 .
C2 C7 S1 112.7(7) .
C2 C7 H5 109.1 .
S1 C7 H5 109.1 .
C2 C7 H6 109.1 .
S1 C7 H6 109.1 .
H5 C7 H6 107.8 .
C13 C8 C9 118.8(9) .
C13 C8 Si1 119.8(8) .
C9 C8 Si1 121.3(8) .
C10 C9 C8 120.0(10) .
C10 C9 C14 118.4(9) .
C8 C9 C14 121.6(9) .
C11 C10 C9 119.9(11) .
C11 C10 H7 120.1 .
C9 C10 H7 120.1 .
C10 C11 C12 119.3(11) .
C10 C11 H8 120.3 .
C12 C11 H8 120.3 .
C13 C12 C11 120.9(11) .
C13 C12 H9 119.5 .
C11 C12 H9 119.5 .
C12 C13 C8 121.0(11) .
C12 C13 H10 119.5 .
C8 C13 H10 119.5 .
C9 C14 S2 109.3(6) .
C9 C14 H11 109.8 .
S2 C14 H11 109.8 .
C9 C14 H12 109.8 .
S2 C14 H12 109.8 .
H11 C14 H12 108.3 .
C16 C15 C20 118.2(9) .
C16 C15 Si1 123.1(7) .
C20 C15 Si1 118.1(7) .
C17 C16 C15 119.4(9) .
C17 C16 C21 121.3(9) .
C15 C16 C21 119.3(8) .
C18 C17 C16 121.2(10) .
C18 C17 H13 119.4 .
C16 C17 H13 119.4 .
C19 C18 C17 120.9(10) .
C19 C18 H14 119.5 .
C17 C18 H14 119.5 .
C18 C19 C20 119.2(11) .
C18 C19 H15 120.4 .
C20 C19 H15 120.4 .
C19 C20 C15 121.0(10) .
C19 C20 H16 119.5 .
C15 C20 H16 119.5 .
C16 C21 S3 110.3(7) .
C16 C21 H17 109.6 .
S3 C21 H17 109.6 .
C16 C21 H18 109.6 .
S3 C21 H18 109.6 .
H17 C21 H18 108.1 .
C25 C22 C23 111.5(11) .
C25 C22 C24 112.3(11) .
C23 C22 C24 109.0(12) .
C25 C22 S1 112.0(8) .
C23 C22 S1 106.0(8) .
C24 C22 S1 105.6(8) .
C22 C23 H19 109.5 .
C22 C23 H20 109.5 .
H19 C23 H20 109.5 .
C22 C23 H21 109.5 .
H19 C23 H21 109.5 .
H20 C23 H21 109.5 .
C22 C24 H22 109.5 .
C22 C24 H23 109.5 .
H22 C24 H23 109.5 .
C22 C24 H24 109.5 .
H22 C24 H24 109.5 .
H23 C24 H24 109.5 .
C22 C25 H25 109.5 .
C22 C25 H26 109.5 .
H25 C25 H26 109.5 .
C22 C25 H27 109.5 .
H25 C25 H27 109.5 .
H26 C25 H27 109.5 .
C29 C26 C28 113.7(9) .
C29 C26 C27 108.5(8) .
C28 C26 C27 110.2(9) .
C29 C26 S2 106.1(7) .
C28 C26 S2 111.9(7) .
C27 C26 S2 106.1(8) .
C26 C27 H28 109.5 .
C26 C27 H29 109.5 .
H28 C27 H29 109.5 .
C26 C27 H30 109.5 .
H28 C27 H30 109.5 .
H29 C27 H30 109.5 .
C26 C28 H31 109.5 .
C26 C28 H32 109.5 .
H31 C28 H32 109.5 .
C26 C28 H33 109.5 .
H31 C28 H33 109.5 .
H32 C28 H33 109.5 .
C26 C29 H34 109.5 .
C26 C29 H35 109.5 .
H34 C29 H35 109.5 .
C26 C29 H36 109.5 .
H34 C29 H36 109.5 .
H35 C29 H36 109.5 .
C31 C30 C33 111.9(11) .
C31 C30 C32 109.8(11) .
C33 C30 C32 110.6(11) .
C31 C30 S3 110.3(9) .
C33 C30 S3 103.0(8) .
C32 C30 S3 111.1(8) .
C30 C31 H37 109.5 .
C30 C31 H38 109.5 .
H37 C31 H38 109.5 .
C30 C31 H39 109.5 .
H37 C31 H39 109.5 .
H38 C31 H39 109.5 .
C30 C32 H40 109.5 .
C30 C32 H41 109.5 .
H40 C32 H41 109.5 .
C30 C32 H42 109.5 .
H40 C32 H42 109.5 .
H41 C32 H42 109.5 .
C30 C33 H43 109.5 .
C30 C33 H44 109.5 .
H43 C33 H44 109.5 .
C30 C33 H45 109.5 .
H43 C33 H45 109.5 .
H44 C33 H45 109.5 .
S4 Pt2 S5 173.65(8) .
S4 Pt2 Si2 85.69(9) .
S5 Pt2 Si2 91.32(9) .
S4 Pt2 Cl2 99.05(8) .
S5 Pt2 Cl2 83.84(8) .
Si2 Pt2 Cl2 175.12(8) .
C34 Si2 C48 104.1(4) .
C34 Si2 C41 104.5(4) .
C48 Si2 C41 110.0(4) .
C34 Si2 Pt2 118.2(3) .
C48 Si2 Pt2 114.4(3) .
C41 Si2 Pt2 105.2(3) .
C40 S4 C55 101.9(4) .
C40 S4 Pt2 103.2(3) .
C55 S4 Pt2 119.5(3) .
C47 S5 C59 99.7(5) .
C47 S5 Pt2 113.2(3) .
C59 S5 Pt2 115.0(3) .
C54 S6 C63 104.8(5) .
C39 C34 C35 117.2(8) .
C39 C34 Si2 119.6(7) .
C35 C34 Si2 123.0(7) .
C36 C35 C34 121.7(9) .
C36 C35 C40 118.8(9) .
C34 C35 C40 119.4(8) .
C37 C36 C35 119.2(10) .
C37 C36 H46 120.4 .
C35 C36 H46 120.4 .
C38 C37 C36 120.2(9) .
C38 C37 H47 119.9 .
C36 C37 H47 119.9 .
C37 C38 C39 120.5(10) .
C37 C38 H48 119.8 .
C39 C38 H48 119.8 .
C38 C39 C34 121.1(10) .
C38 C39 H49 119.5 .
C34 C39 H49 119.5 .
C35 C40 S4 106.6(6) .
C35 C40 H50 110.4 .
S4 C40 H50 110.4 .
C35 C40 H51 110.4 .
S4 C40 H51 110.4 .
H50 C40 H51 108.6 .
C42 C41 C46 117.9(9) .
C42 C41 Si2 121.0(7) .
C46 C41 Si2 120.7(7) .
C41 C42 C43 120.0(9) .
C41 C42 C47 120.9(8) .
C43 C42 C47 118.9(9) .
C44 C43 C42 121.4(9) .
C44 C43 H52 119.3 .
C42 C43 H52 119.3 .
C43 C44 C45 119.0(9) .
C43 C44 H53 120.5 .
C45 C44 H53 120.5 .
C46 C45 C44 120.0(10) .
C46 C45 H54 120.0 .
C44 C45 H54 120.0 .
C45 C46 C41 121.5(9) .
C45 C46 H55 119.2 .
C41 C46 H55 119.2 .
C42 C47 S5 114.4(7) .
C42 C47 H56 108.7 .
S5 C47 H56 108.7 .
C42 C47 H57 108.7 .
S5 C47 H57 108.7 .
H56 C47 H57 107.6 .
C53 C48 C49 117.1(9) .
C53 C48 Si2 119.6(7) .
C49 C48 Si2 123.3(7) .
C50 C49 C48 120.3(10) .
C50 C49 C54 121.5(9) .
C48 C49 C54 118.1(8) .
C51 C50 C49 121.8(11) .
C51 C50 H58 119.1 .
C49 C50 H58 119.1 .
C50 C51 C52 118.7(11) .
C50 C51 H59 120.6 .
C52 C51 H59 120.6 .
C53 C52 C51 120.1(11) .
C53 C52 H60 120.0 .
C51 C52 H60 120.0 .
C52 C53 C48 121.9(10) .
C52 C53 H61 119.0 .
C48 C53 H61 119.0 .
C49 C54 S6 118.3(7) .
C49 C54 H62 107.7 .
S6 C54 H62 107.7 .
C49 C54 H63 107.7 .
S6 C54 H63 107.7 .
H62 C54 H63 107.1 .
C56 C55 C57 113.2(9) .
C56 C55 C58 111.6(8) .
C57 C55 C58 108.7(8) .
C56 C55 S4 112.6(7) .
C57 C55 S4 104.3(7) .
C58 C55 S4 105.8(7) .
C55 C56 H64 109.5 .
C55 C56 H65 109.5 .
H64 C56 H65 109.5 .
C55 C56 H66 109.5 .
H64 C56 H66 109.5 .
H65 C56 H66 109.5 .
C55 C57 H67 109.5 .
C55 C57 H68 109.5 .
H67 C57 H68 109.5 .
C55 C57 H69 109.5 .
H67 C57 H69 109.5 .
H68 C57 H69 109.5 .
C55 C58 H70 109.5 .
C55 C58 H71 109.5 .
H70 C58 H71 109.5 .
C55 C58 H72 109.5 .
H70 C58 H72 109.5 .
H71 C58 H72 109.5 .
C62 C59 C60 111.5(10) .
C62 C59 C61 111.9(10) .
C60 C59 C61 108.6(9) .
C62 C59 S5 112.6(7) .
C60 C59 S5 106.5(7) .
C61 C59 S5 105.4(7) .
C59 C60 H73 109.5 .
C59 C60 H74 109.5 .
H73 C60 H74 109.5 .
C59 C60 H75 109.5 .
H73 C60 H75 109.5 .
H74 C60 H75 109.5 .
C59 C61 H76 109.5 .
C59 C61 H77 109.5 .
H76 C61 H77 109.5 .
C59 C61 H78 109.5 .
H76 C61 H78 109.5 .
H77 C61 H78 109.5 .
C59 C62 H79 109.5 .
C59 C62 H80 109.5 .
H79 C62 H80 109.5 .
C59 C62 H81 109.5 .
H79 C62 H81 109.5 .
H80 C62 H81 109.5 .
C64 C63 C65 110.6(11) .
C64 C63 C66 109.5(11) .
C65 C63 C66 110.2(10) .
C64 C63 S6 103.9(9) .
C65 C63 S6 111.7(8) .
C66 C63 S6 110.8(8) .
C63 C64 H82 109.5 .
C63 C64 H83 109.5 .
H82 C64 H83 109.5 .
C63 C64 H84 109.5 .
H82 C64 H84 109.5 .
H83 C64 H84 109.5 .
C63 C65 H85 109.5 .
C63 C65 H86 109.5 .
H85 C65 H86 109.5 .
C63 C65 H87 109.5 .
H85 C65 H87 109.5 .
H86 C65 H87 109.5 .
C63 C66 H88 109.5 .
C63 C66 H89 109.5 .
H88 C66 H89 109.5 .
C63 C66 H90 109.5 .
H88 C66 H90 109.5 .
H89 C66 H90 109.5 .
C69 C68 C67 137(4) .
C69 C68 C73 101(4) .
C67 C68 C73 112(2) .
C68 C69 C70 94(4) .
C69 C70 C71 101(5) .
C70 C71 C72 116(6) .
C68 C73 C73 116(2) 2_665
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Pt1 S2 2.304(2) .
Pt1 S1 2.308(2) .
Pt1 Si1 2.326(3) .
Pt1 Cl1 2.455(2) .
Si1 C1 1.894(9) .
Si1 C15 1.912(10) .
Si1 C8 1.913(10) .
S1 C7 1.823(10) .
S1 C22 1.887(11) .
S2 C14 1.836(10) .
S2 C26 1.875(10) .
S3 C21 1.818(10) .
S3 C30 1.840(12) .
C1 C2 1.404(14) .
C1 C6 1.413(14) .
C2 C3 1.403(14) .
C2 C7 1.495(14) .
C3 C4 1.383(16) .
C3 H1 0.9500 .
C4 C5 1.389(15) .
C4 H2 0.9500 .
C5 C6 1.389(13) .
C5 H3 0.9500 .
C6 H4 0.9500 .
C7 H5 0.9900 .
C7 H6 0.9900 .
C8 C13 1.377(14) .
C8 C9 1.419(13) .
C9 C10 1.393(14) .
C9 C14 1.495(14) .
C10 C11 1.389(17) .
C10 H7 0.9500 .
C11 C12 1.395(17) .
C11 H8 0.9500 .
C12 C13 1.368(15) .
C12 H9 0.9500 .
C13 H10 0.9500 .
C14 H11 0.9900 .
C14 H12 0.9900 .
C15 C16 1.406(13) .
C15 C20 1.415(13) .
C16 C17 1.387(14) .
C16 C21 1.513(13) .
C17 C18 1.375(16) .
C17 H13 0.9500 .
C18 C19 1.368(16) .
C18 H14 0.9500 .
C19 C20 1.395(14) .
C19 H15 0.9500 .
C20 H16 0.9500 .
C21 H17 0.9900 .
C21 H18 0.9900 .
C22 C25 1.499(15) .
C22 C23 1.518(17) .
C22 C24 1.534(16) .
C23 H19 0.9800 .
C23 H20 0.9800 .
C23 H21 0.9800 .
C24 H22 0.9800 .
C24 H23 0.9800 .
C24 H24 0.9800 .
C25 H25 0.9800 .
C25 H26 0.9800 .
C25 H27 0.9800 .
C26 C29 1.521(14) .
C26 C28 1.523(14) .
C26 C27 1.546(14) .
C27 H28 0.9800 .
C27 H29 0.9800 .
C27 H30 0.9800 .
C28 H31 0.9800 .
C28 H32 0.9800 .
C28 H33 0.9800 .
C29 H34 0.9800 .
C29 H35 0.9800 .
C29 H36 0.9800 .
C30 C31 1.523(19) .
C30 C33 1.523(16) .
C30 C32 1.527(16) .
C31 H37 0.9800 .
C31 H38 0.9800 .
C31 H39 0.9800 .
C32 H40 0.9800 .
C32 H41 0.9800 .
C32 H42 0.9800 .
C33 H43 0.9800 .
C33 H44 0.9800 .
C33 H45 0.9800 .
Pt2 S4 2.298(2) .
Pt2 S5 2.311(2) .
Pt2 Si2 2.323(3) .
Pt2 Cl2 2.458(2) .
Si2 C34 1.884(9) .
Si2 C48 1.885(10) .
Si2 C41 1.896(10) .
S4 C40 1.851(9) .
S4 C55 1.870(11) .
S5 C47 1.836(10) .
S5 C59 1.882(10) .
S6 C54 1.810(10) .
S6 C63 1.842(11) .
C34 C39 1.402(13) .
C34 C35 1.407(13) .
C35 C36 1.399(13) .
C35 C40 1.518(13) .
C36 C37 1.390(15) .
C36 H46 0.9500 .
C37 C38 1.377(15) .
C37 H47 0.9500 .
C38 C39 1.394(13) .
C38 H48 0.9500 .
C39 H49 0.9500 .
C40 H50 0.9900 .
C40 H51 0.9900 .
C41 C42 1.402(13) .
C41 C46 1.403(13) .
C42 C43 1.404(13) .
C42 C47 1.499(13) .
C43 C44 1.377(14) .
C43 H52 0.9500 .
C44 C45 1.399(14) .
C44 H53 0.9500 .
C45 C46 1.389(13) .
C45 H54 0.9500 .
C46 H55 0.9500 .
C47 H56 0.9900 .
C47 H57 0.9900 .
C48 C53 1.407(14) .
C48 C49 1.414(13) .
C49 C50 1.385(14) .
C49 C54 1.535(15) .
C50 C51 1.376(17) .
C50 H58 0.9500 .
C51 C52 1.404(16) .
C51 H59 0.9500 .
C52 C53 1.377(14) .
C52 H60 0.9500 .
C53 H61 0.9500 .
C54 H62 0.9900 .
C54 H63 0.9900 .
C55 C56 1.523(13) .
C55 C57 1.524(13) .
C55 C58 1.543(13) .
C56 H64 0.9800 .
C56 H65 0.9800 .
C56 H66 0.9800 .
C57 H67 0.9800 .
C57 H68 0.9800 .
C57 H69 0.9800 .
C58 H70 0.9800 .
C58 H71 0.9800 .
C58 H72 0.9800 .
C59 C62 1.515(15) .
C59 C60 1.519(15) .
C59 C61 1.540(14) .
C60 H73 0.9800 .
C60 H74 0.9800 .
C60 H75 0.9800 .
C61 H76 0.9800 .
C61 H77 0.9800 .
C61 H78 0.9800 .
C62 H79 0.9800 .
C62 H80 0.9800 .
C62 H81 0.9800 .
C63 C64 1.513(15) .
C63 C65 1.531(16) .
C63 C66 1.539(17) .
C64 H82 0.9800 .
C64 H83 0.9800 .
C64 H84 0.9800 .
C65 H85 0.9800 .
C65 H86 0.9800 .
C65 H87 0.9800 .
C66 H88 0.9800 .
C66 H89 0.9800 .
C66 H90 0.9800 .
C67 C68 1.521(17) .
C68 C69 1.49(2) .
C68 C73 1.559(18) .
C69 C70 1.51(2) .
C70 C71 1.52(2) .
C71 C72 1.53(2) .
C73 C73 1.57(5) 2_665
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_4
S2 Pt1 Si1 C1 -127.6(3) .
S1 Pt1 Si1 C1 51.8(3) .
Cl1 Pt1 Si1 C1 4.8(6) .
S2 Pt1 Si1 C15 114.0(3) .
S1 Pt1 Si1 C15 -66.7(3) .
Cl1 Pt1 Si1 C15 -113.7(5) .
S2 Pt1 Si1 C8 -10.2(3) .
S1 Pt1 Si1 C8 169.1(3) .
Cl1 Pt1 Si1 C8 122.1(5) .
S2 Pt1 S1 C7 21(4) .
Si1 Pt1 S1 C7 -11.2(4) .
Cl1 Pt1 S1 C7 160.8(4) .
S2 Pt1 S1 C22 135(4) .
Si1 Pt1 S1 C22 102.1(4) .
Cl1 Pt1 S1 C22 -86.0(4) .
S1 Pt1 S2 C14 21(4) .
Si1 Pt1 S2 C14 53.2(3) .
Cl1 Pt1 S2 C14 -118.7(3) .
S1 Pt1 S2 C26 131(4) .
Si1 Pt1 S2 C26 163.8(4) .
Cl1 Pt1 S2 C26 -8.0(4) .
C15 Si1 C1 C2 71.5(8) .
C8 Si1 C1 C2 179.5(7) .
Pt1 Si1 C1 C2 -55.0(8) .
C15 Si1 C1 C6 -116.3(8) .
C8 Si1 C1 C6 -8.3(8) .
Pt1 Si1 C1 C6 117.2(7) .
C6 C1 C2 C3 -0.1(13) .
Si1 C1 C2 C3 172.4(7) .
C6 C1 C2 C7 175.9(8) .
Si1 C1 C2 C7 -11.6(12) .
C1 C2 C3 C4 0.0(15) .
C7 C2 C3 C4 -176.1(9) .
C2 C3 C4 C5 1.2(15) .
C3 C4 C5 C6 -2.1(15) .
C4 C5 C6 C1 2.0(14) .
C2 C1 C6 C5 -0.9(13) .
Si1 C1 C6 C5 -173.4(7) .
C3 C2 C7 S1 -112.1(9) .
C1 C2 C7 S1 71.8(10) .
C22 S1 C7 C2 -168.0(7) .
Pt1 S1 C7 C2 -49.3(8) .
C1 Si1 C8 C13 -84.1(8) .
C15 Si1 C8 C13 28.0(9) .
Pt1 Si1 C8 C13 160.4(7) .
C1 Si1 C8 C9 92.7(8) .
C15 Si1 C8 C9 -155.2(7) .
Pt1 Si1 C8 C9 -22.7(8) .
C13 C8 C9 C10 -0.9(14) .
Si1 C8 C9 C10 -177.8(7) .
C13 C8 C9 C14 178.8(8) .
Si1 C8 C9 C14 1.9(12) .
C8 C9 C10 C11 1.0(15) .
C14 C9 C10 C11 -178.6(9) .
C9 C10 C11 C12 0.5(16) .
C10 C11 C12 C13 -2.2(17) .
C11 C12 C13 C8 2.4(17) .
C9 C8 C13 C12 -0.8(15) .
Si1 C8 C13 C12 176.1(8) .
C10 C9 C14 S2 -121.9(8) .
C8 C9 C14 S2 58.4(10) .
C26 S2 C14 C9 147.2(7) .
Pt1 S2 C14 C9 -91.9(6) .
C1 Si1 C15 C16 -176.2(9) .
C8 Si1 C15 C16 72.3(10) .
Pt1 Si1 C15 C16 -59.9(10) .
C1 Si1 C15 C20 12.5(9) .
C8 Si1 C15 C20 -99.1(8) .
Pt1 Si1 C15 C20 128.7(7) .
C20 C15 C16 C17 0.7(17) .
Si1 C15 C16 C17 -170.6(10) .
C20 C15 C16 C21 178.9(10) .
Si1 C15 C16 C21 7.6(15) .
C15 C16 C17 C18 -1(2) .
C21 C16 C17 C18 -179.0(13) .
C16 C17 C18 C19 0(2) .
C17 C18 C19 C20 1(2) .
C18 C19 C20 C15 -1(2) .
C16 C15 C20 C19 0.3(17) .
Si1 C15 C20 C19 172.1(10) .
C17 C16 C21 S3 -32.8(15) .
C15 C16 C21 S3 149.0(9) .
C30 S3 C21 C16 -167.4(8) .
C7 S1 C22 C25 71.8(10) .
Pt1 S1 C22 C25 -47.8(10) .
C7 S1 C22 C23 -166.3(9) .
Pt1 S1 C22 C23 74.0(9) .
C7 S1 C22 C24 -50.7(10) .
Pt1 S1 C22 C24 -170.4(8) .
C14 S2 C26 C29 178.9(7) .
Pt1 S2 C26 C29 68.3(7) .
C14 S2 C26 C28 54.4(9) .
Pt1 S2 C26 C28 -56.2(9) .
C14 S2 C26 C27 -65.8(8) .
Pt1 S2 C26 C27 -176.4(6) .
C21 S3 C30 C31 -56.0(10) .
C21 S3 C30 C33 -175.5(9) .
C21 S3 C30 C32 66.0(10) .
S4 Pt2 Si2 C34 7.0(3) .
S5 Pt2 Si2 C34 -167.4(3) .
Cl2 Pt2 Si2 C34 -159.6(9) .
S4 Pt2 Si2 C48 -116.1(3) .
S5 Pt2 Si2 C48 69.5(3) .
Cl2 Pt2 Si2 C48 77.3(10) .
S4 Pt2 Si2 C41 123.1(3) .
S5 Pt2 Si2 C41 -51.3(3) .
Cl2 Pt2 Si2 C41 -43.5(11) .
S5 Pt2 S4 C40 7.9(9) .
Si2 Pt2 S4 C40 -54.2(3) .
Cl2 Pt2 S4 C40 124.7(3) .
S5 Pt2 S4 C55 -104.1(9) .
Si2 Pt2 S4 C55 -166.2(4) .
Cl2 Pt2 S4 C55 12.7(4) .
S4 Pt2 S5 C47 -49.0(9) .
Si2 Pt2 S5 C47 12.8(4) .
Cl2 Pt2 S5 C47 -166.5(4) .
S4 Pt2 S5 C59 -162.7(8) .
Si2 Pt2 S5 C59 -100.9(4) .
Cl2 Pt2 S5 C59 79.7(4) .
C48 Si2 C34 C39 -26.4(9) .
C41 Si2 C34 C39 89.0(8) .
Pt2 Si2 C34 C39 -154.6(7) .
C48 Si2 C34 C35 158.5(8) .
C41 Si2 C34 C35 -86.2(8) .
Pt2 Si2 C34 C35 30.3(9) .
C39 C34 C35 C36 1.4(14) .
Si2 C34 C35 C36 176.7(7) .
C39 C34 C35 C40 177.6(8) .
Si2 C34 C35 C40 -7.1(12) .
C34 C35 C36 C37 -1.5(15) .
C40 C35 C36 C37 -177.8(9) .
C35 C36 C37 C38 2.1(16) .
C36 C37 C38 C39 -2.6(16) .
C37 C38 C39 C34 2.5(15) .
C35 C34 C39 C38 -1.9(14) .
Si2 C34 C39 C38 -177.3(8) .
C36 C35 C40 S4 120.4(8) .
C34 C35 C40 S4 -55.9(10) .
C55 S4 C40 C35 -141.5(6) .
Pt2 S4 C40 C35 94.0(6) .
C34 Si2 C41 C42 177.7(8) .
C48 Si2 C41 C42 -71.2(8) .
Pt2 Si2 C41 C42 52.5(8) .
C34 Si2 C41 C46 4.5(9) .
C48 Si2 C41 C46 115.7(8) .
Pt2 Si2 C41 C46 -120.7(7) .
C46 C41 C42 C43 1.2(14) .
Si2 C41 C42 C43 -172.2(7) .
C46 C41 C42 C47 -173.8(9) .
Si2 C41 C42 C47 12.8(12) .
C41 C42 C43 C44 -1.8(15) .
C47 C42 C43 C44 173.3(9) .
C42 C43 C44 C45 0.2(16) .
C43 C44 C45 C46 2.0(16) .
C44 C45 C46 C41 -2.6(16) .
C42 C41 C46 C45 1.0(14) .
Si2 C41 C46 C45 174.4(8) .
C41 C42 C47 S5 -68.8(11) .
C43 C42 C47 S5 116.2(9) .
C59 S5 C47 C42 167.7(7) .
Pt2 S5 C47 C42 45.0(8) .
C34 Si2 C48 C53 105.1(8) .
C41 Si2 C48 C53 -6.3(9) .
Pt2 Si2 C48 C53 -124.4(7) .
C34 Si2 C48 C49 -73.5(9) .
C41 Si2 C48 C49 175.0(8) .
Pt2 Si2 C48 C49 56.9(9) .
C53 C48 C49 C50 3.6(14) .
Si2 C48 C49 C50 -177.7(8) .
C53 C48 C49 C54 179.3(9) .
Si2 C48 C49 C54 -2.0(13) .
C48 C49 C50 C51 -0.7(17) .
C54 C49 C50 C51 -176.4(11) .
C49 C50 C51 C52 -1.8(18) .
C50 C51 C52 C53 1.4(17) .
C51 C52 C53 C48 1.6(15) .
C49 C48 C53 C52 -4.0(14) .
Si2 C48 C53 C52 177.3(7) .
C50 C49 C54 S6 -20.1(14) .
C48 C49 C54 S6 164.2(8) .
C63 S6 C54 C49 -96.1(9) .
C40 S4 C55 C56 -58.2(8) .
Pt2 S4 C55 C56 54.5(8) .
C40 S4 C55 C57 178.7(6) .
Pt2 S4 C55 C57 -68.6(7) .
C40 S4 C55 C58 64.0(7) .
Pt2 S4 C55 C58 176.7(5) .
C47 S5 C59 C62 -62.6(9) .
Pt2 S5 C59 C62 58.8(9) .
C47 S5 C59 C60 174.9(7) .
Pt2 S5 C59 C60 -63.7(8) .
C47 S5 C59 C61 59.7(8) .
Pt2 S5 C59 C61 -178.9(6) .
C54 S6 C63 C64 -179.8(9) .
C54 S6 C63 C65 -60.6(9) .
C54 S6 C63 C66 62.7(9) .
C67 C68 C69 C70 -152(4) .
C73 C68 C69 C70 68(5) .
C68 C69 C70 C71 -165(5) .
C69 C70 C71 C72 -172(6) .
C69 C68 C73 C73 -22(4) 2_665
C67 C68 C73 C73 -173(3) 2_665
