#------------------------------------------------------------------------------
#$Date: 2016-03-21 07:16:20 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178556 $
#$URL: svn://www.crystallography.net/cod/cif/4/06/64/4066469.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4066469
loop_
_publ_author_name
'Leung, Sammual Yu-Lut'
'Lam, Wai Han'
'Zhu, Nianyong'
'Yam, Vivian Wing-Wah'
_publ_section_title
;
 Synthesis, Structural Characterization, and Photophysical Study of
 Luminescent Face-to-Face Dinuclear Platinum(II) Alkynyl Phosphine
 Complexes and Their Tetranuclear Mixed-Metal
 Platinum(II)−Silver(I) and −Copper(I) Complexes†
;
_journal_issue                   21
_journal_name_full               Organometallics
_journal_page_first              5558
_journal_paper_doi               10.1021/om100473q
_journal_volume                  29
_journal_year                    2010
_chemical_formula_moiety
'C98 H94 Ag2 N2 O12 P4 Pt2, 4(C3 H6 O), 2(B F4)'
_chemical_formula_sum            'C110 H118 Ag2 B2 F8 N2 O16 P4 Pt2'
_chemical_formula_weight         2627.48
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      15
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 102.1840(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   23.472(2)
_cell_length_b                   23.370(2)
_cell_length_c                   21.290(2)
_cell_measurement_reflns_used    32015
_cell_measurement_temperature    298(2)
_cell_measurement_theta_max      25.03
_cell_measurement_theta_min      1.70
_cell_volume                     11415.4(17)
_computing_cell_refinement       'SAINT (Bruker AXS Inc, 2006)'
_computing_data_collection       'SMART (Bruker AXS Inc, 1998)'
_computing_data_reduction
;
SAINT (Bruker AXS Inc, 2006) & 
CrystalStructure (Rigaku/MSC and Rigaku Corporation, 2006)
;
_computing_molecular_graphics
'ORTEP-II (Johnson, 1976) & MERCURY (Macrae et al., 2008)'
_computing_publication_material  'SHELX (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      298(2)
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'Bruker SMART 1000 CCD'
_diffrn_measurement_method       ω
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0191
_diffrn_reflns_av_sigmaI/netI    0.0200
_diffrn_reflns_limit_h_max       27
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       27
_diffrn_reflns_limit_k_min       -27
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_number            31572
_diffrn_reflns_theta_full        25.03
_diffrn_reflns_theta_max         25.03
_diffrn_reflns_theta_min         1.69
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    2.911
_exptl_absorpt_correction_T_max  0.7796
_exptl_absorpt_correction_T_min  0.3296
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS (Sheldrick, 1996)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.529
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       rod
_exptl_crystal_F_000             5248
_exptl_crystal_size_max          0.49
_exptl_crystal_size_mid          0.14
_exptl_crystal_size_min          0.09
_refine_diff_density_max         1.508
_refine_diff_density_min         -1.359
_refine_diff_density_rms         0.109
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.048
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     670
_refine_ls_number_reflns         10050
_refine_ls_number_restraints     44
_refine_ls_restrained_S_all      1.051
_refine_ls_R_factor_all          0.0443
_refine_ls_R_factor_gt           0.0349
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0607P)²+50.2897P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0967
_refine_ls_wR_factor_ref         0.1056
_reflns_number_gt                8563
_reflns_number_total             10050
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            om100473q_si_005.cif
_cod_data_source_block           wt1788w-shelxl
_cod_original_cell_volume        11415.9(18)
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               4066469
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Pt1 Pt 0.494791(7) 0.230639(7) 0.673795(8) 0.03154(8) Uani 1 1 d .
Ag1 Ag 0.5000 0.37332(3) 0.7500 0.0708(2) Uani 1 2 d S
Ag2 Ag 0.5000 0.09274(3) 0.7500 0.05625(17) Uani 1 2 d S
P1 P 0.39698(5) 0.25457(5) 0.66039(6) 0.0342(3) Uani 1 1 d .
P2 P 0.59343(5) 0.21272(5) 0.69317(6) 0.0350(3) Uani 1 1 d .
B1 B 0.3101(6) 0.2022(5) 0.2875(6) 0.121(4) Uani 1 1 d DU
F1 F 0.2557(4) 0.1873(5) 0.2833(5) 0.2006(18) Uani 1 1 d D
F2 F 0.3287(4) 0.1930(5) 0.2338(5) 0.2006(18) Uani 1 1 d D
F3 F 0.3101(4) 0.2581(5) 0.3020(5) 0.2006(18) Uani 1 1 d D
F4 F 0.3449(4) 0.1727(5) 0.3319(5) 0.2006(18) Uani 1 1 d D
O1 O 0.5403(2) 0.55181(18) 0.5732(2) 0.0677(12) Uani 1 1 d .
O2 O 0.6562(2) 0.55594(18) 0.6030(2) 0.0703(12) Uani 1 1 d .
O3 O 0.71913(19) 0.46668(19) 0.6568(3) 0.0775(14) Uani 1 1 d .
O4 O 0.4961(2) -0.0894(2) 0.5565(3) 0.0906(17) Uani 1 1 d .
O5 O 0.3843(2) -0.1063(2) 0.5136(2) 0.0820(15) Uani 1 1 d .
O6 O 0.3056(2) -0.0270(2) 0.5260(3) 0.0825(15) Uani 1 1 d .
C1 C 0.5211(2) 0.31252(19) 0.6727(2) 0.0397(11) Uani 1 1 d .
C2 C 0.5419(2) 0.3581(2) 0.6608(2) 0.0443(12) Uani 1 1 d .
C3 C 0.5716(2) 0.4083(2) 0.6433(2) 0.0423(11) Uani 1 1 d .
C4 C 0.5393(2) 0.4548(2) 0.6148(3) 0.0477(12) Uani 1 1 d .
H4 H 0.4988 0.4530 0.6049 0.057 Uiso 1 1 calc R
C5 C 0.5678(2) 0.5039(2) 0.6011(3) 0.0486(12) Uani 1 1 d .
C6 C 0.6281(3) 0.5066(2) 0.6168(3) 0.0527(14) Uani 1 1 d .
C7 C 0.6603(3) 0.4597(2) 0.6439(3) 0.0544(14) Uani 1 1 d .
C8 C 0.6321(3) 0.4105(2) 0.6571(3) 0.0512(13) Uani 1 1 d .
H8 H 0.6536 0.3790 0.6752 0.061 Uiso 1 1 calc R
C9 C 0.4784(3) 0.5531(3) 0.5611(3) 0.0686(17) Uani 1 1 d .
H9A H 0.4647 0.5892 0.5421 0.082 Uiso 1 1 calc R
H9B H 0.4657 0.5484 0.6008 0.082 Uiso 1 1 calc R
H9C H 0.4629 0.5226 0.5323 0.082 Uiso 1 1 calc R
C10 C 0.6694(5) 0.5952(4) 0.6528(5) 0.121(4) Uani 1 1 d .
H10A H 0.6956 0.6236 0.6425 0.145 Uiso 1 1 calc R
H10B H 0.6876 0.5758 0.6917 0.145 Uiso 1 1 calc R
H10C H 0.6343 0.6134 0.6588 0.145 Uiso 1 1 calc R
C11 C 0.7544(3) 0.4187(3) 0.6785(5) 0.097(3) Uani 1 1 d .
H11A H 0.7947 0.4292 0.6844 0.116 Uiso 1 1 calc R
H11B H 0.7459 0.3886 0.6472 0.116 Uiso 1 1 calc R
H11C H 0.7466 0.4056 0.7185 0.116 Uiso 1 1 calc R
C12 C 0.4728(2) 0.1482(2) 0.6578(2) 0.0388(10) Uani 1 1 d .
C13 C 0.4600(2) 0.1003(2) 0.6367(2) 0.0411(11) Uani 1 1 d .
C14 C 0.4406(2) 0.0471(2) 0.6043(2) 0.0420(11) Uani 1 1 d .
C15 C 0.4808(2) 0.0056(2) 0.5957(3) 0.0493(13) Uani 1 1 d .
H15 H 0.5205 0.0122 0.6100 0.059 Uiso 1 1 calc R
C16 C 0.4617(3) -0.0456(2) 0.5661(3) 0.0576(15) Uani 1 1 d .
C17 C 0.4019(3) -0.0556(2) 0.5445(3) 0.0540(14) Uani 1 1 d .
C18 C 0.3621(3) -0.0135(2) 0.5510(3) 0.0545(14) Uani 1 1 d .
C19 C 0.3812(2) 0.0379(2) 0.5813(3) 0.0478(12) Uani 1 1 d .
H19 H 0.3544 0.0660 0.5862 0.057 Uiso 1 1 calc R
C20 C 0.5565(4) -0.0803(4) 0.5672(5) 0.095(3) Uani 1 1 d .
H20A H 0.5748 -0.1127 0.5519 0.114 Uiso 1 1 calc R
H20B H 0.5719 -0.0755 0.6124 0.114 Uiso 1 1 calc R
H20C H 0.5642 -0.0465 0.5448 0.114 Uiso 1 1 calc R
C21 C 0.3580(5) -0.1457(3) 0.5488(5) 0.115(3) Uani 1 1 d .
H21A H 0.3446 -0.1783 0.5223 0.138 Uiso 1 1 calc R
H21B H 0.3257 -0.1278 0.5620 0.138 Uiso 1 1 calc R
H21C H 0.3860 -0.1579 0.5860 0.138 Uiso 1 1 calc R
C22 C 0.2624(3) 0.0134(4) 0.5275(5) 0.096(3) Uani 1 1 d .
H22A H 0.2248 -0.0034 0.5116 0.115 Uiso 1 1 calc R
H22B H 0.2675 0.0455 0.5011 0.115 Uiso 1 1 calc R
H22C H 0.2650 0.0261 0.5709 0.115 Uiso 1 1 calc R
N1 N 0.4703(5) 0.4710(4) 0.7342(5) 0.069(3) Uani 0.50 1 d PD
C23 C 0.5000 0.5138(5) 0.7500 0.084(3) Uani 1 2 d SD
C24 C 0.5424(10) 0.5579(10) 0.7566(13) 0.154(9) Uani 0.50 1 d PDU
H24A H 0.5800 0.5414 0.7577 0.185 Uiso 0.50 1 calc PR
H24B H 0.5430 0.5786 0.7957 0.185 Uiso 0.50 1 calc PR
H24C H 0.5327 0.5836 0.7207 0.185 Uiso 0.50 1 calc PR
N2 N 0.4717(5) -0.0061(4) 0.7498(5) 0.074(4) Uani 0.50 1 d PD
C25 C 0.5000 -0.0533(6) 0.7500 0.097(4) Uani 1 2 d SDU
C26 C 0.5517(6) -0.0850(9) 0.7653(8) 0.110(7) Uani 0.50 1 d PD
H26A H 0.5716 -0.0829 0.7303 0.132 Uiso 0.50 1 calc PR
H26B H 0.5427 -0.1242 0.7726 0.132 Uiso 0.50 1 calc PR
H26C H 0.5762 -0.0696 0.8034 0.132 Uiso 0.50 1 calc PR
C27 C 0.3686(2) 0.2506(2) 0.7345(2) 0.0415(11) Uani 1 1 d .
H27A H 0.3634 0.2897 0.7474 0.050 Uiso 1 1 calc R
H27B H 0.3300 0.2339 0.7227 0.050 Uiso 1 1 calc R
C28 C 0.3811(2) 0.3285(2) 0.6326(2) 0.0424(11) Uani 1 1 d .
C29 C 0.3532(3) 0.3683(3) 0.6624(3) 0.0665(17) Uani 1 1 d .
H29 H 0.3396 0.3586 0.6990 0.080 Uiso 1 1 calc R
C30 C 0.3454(4) 0.4235(3) 0.6375(5) 0.093(3) Uani 1 1 d .
H30 H 0.3278 0.4511 0.6585 0.111 Uiso 1 1 calc R
C31 C 0.3631(3) 0.4374(3) 0.5826(4) 0.086(3) Uani 1 1 d .
H31 H 0.3574 0.4744 0.5664 0.104 Uiso 1 1 calc R
C32 C 0.3887(3) 0.3981(3) 0.5514(4) 0.072(2) Uani 1 1 d .
H32 H 0.3997 0.4077 0.5133 0.087 Uiso 1 1 calc R
C33 C 0.3986(3) 0.3432(3) 0.5762(3) 0.0604(15) Uani 1 1 d .
H33 H 0.4168 0.3162 0.5550 0.072 Uiso 1 1 calc R
C34 C 0.3465(2) 0.2152(2) 0.5985(2) 0.0409(11) Uani 1 1 d .
C35 C 0.3659(3) 0.1961(2) 0.5453(3) 0.0532(13) Uani 1 1 d .
H35 H 0.4054 0.1980 0.5448 0.064 Uiso 1 1 calc R
C36 C 0.3271(3) 0.1739(3) 0.4923(3) 0.0654(17) Uani 1 1 d .
H36 H 0.3401 0.1627 0.4559 0.078 Uiso 1 1 calc R
C37 C 0.2690(3) 0.1689(3) 0.4946(3) 0.0687(18) Uani 1 1 d .
H37 H 0.2429 0.1531 0.4599 0.082 Uiso 1 1 calc R
C38 C 0.2493(3) 0.1869(3) 0.5471(3) 0.0661(17) Uani 1 1 d .
H38 H 0.2100 0.1830 0.5480 0.079 Uiso 1 1 calc R
C39 C 0.2872(2) 0.2108(3) 0.5990(3) 0.0546(14) Uani 1 1 d .
H39 H 0.2733 0.2239 0.6342 0.065 Uiso 1 1 calc R
C40 C 0.6287(2) 0.2432(2) 0.6320(2) 0.0409(11) Uani 1 1 d .
C41 C 0.5957(3) 0.2628(2) 0.5740(3) 0.0530(14) Uani 1 1 d .
H41 H 0.5554 0.2591 0.5651 0.064 Uiso 1 1 calc R
C42 C 0.6231(3) 0.2880(3) 0.5292(3) 0.0712(18) Uani 1 1 d .
H42 H 0.6009 0.3017 0.4907 0.085 Uiso 1 1 calc R
C43 C 0.6826(4) 0.2930(3) 0.5415(4) 0.075(2) Uani 1 1 d .
H43 H 0.7007 0.3096 0.5111 0.090 Uiso 1 1 calc R
C44 C 0.7154(3) 0.2736(3) 0.5981(4) 0.0693(19) Uani 1 1 d .
H44 H 0.7557 0.2774 0.6062 0.083 Uiso 1 1 calc R
C45 C 0.6891(3) 0.2484(3) 0.6435(3) 0.0563(14) Uani 1 1 d .
H45 H 0.7119 0.2349 0.6818 0.068 Uiso 1 1 calc R
C46 C 0.6201(2) 0.1396(2) 0.6991(2) 0.0391(10) Uani 1 1 d .
C47 C 0.6434(3) 0.1135(3) 0.7571(3) 0.0570(14) Uani 1 1 d .
H47 H 0.6452 0.1332 0.7955 0.068 Uiso 1 1 calc R
C48 C 0.6639(3) 0.0577(3) 0.7577(4) 0.077(2) Uani 1 1 d .
H48 H 0.6797 0.0400 0.7966 0.092 Uiso 1 1 calc R
C49 C 0.6610(3) 0.0284(3) 0.7011(4) 0.078(2) Uani 1 1 d .
H49 H 0.6747 -0.0090 0.7017 0.093 Uiso 1 1 calc R
C50 C 0.6380(3) 0.0544(3) 0.6436(3) 0.0648(17) Uani 1 1 d .
H50 H 0.6369 0.0347 0.6054 0.078 Uiso 1 1 calc R
C51 C 0.6165(3) 0.1093(2) 0.6418(3) 0.0519(13) Uani 1 1 d .
H51 H 0.5997 0.1262 0.6027 0.062 Uiso 1 1 calc R
O7 O 0.1453(5) 0.0952(6) 0.9089(7) 0.229(6) Uani 1 1 d .
C52 C 0.1437(7) 0.1730(7) 0.8370(9) 0.207(8) Uani 1 1 d D
H52A H 0.1048 0.1794 0.8433 0.248 Uiso 1 1 calc R
H52B H 0.1424 0.1657 0.7924 0.248 Uiso 1 1 calc R
H52C H 0.1671 0.2062 0.8505 0.248 Uiso 1 1 calc R
C53 C 0.1695(5) 0.1225(6) 0.8759(6) 0.130(4) Uani 1 1 d D
C54 C 0.2284(6) 0.1041(8) 0.8699(12) 0.277(13) Uani 1 1 d D
H54A H 0.2282 0.0638 0.8614 0.333 Uiso 1 1 calc R
H54B H 0.2558 0.1122 0.9093 0.333 Uiso 1 1 calc R
H54C H 0.2395 0.1245 0.8353 0.333 Uiso 1 1 calc R
O8 O 0.0095(12) 0.1746(7) 0.6480(11) 0.379(15) Uani 1 1 d D
C55 C 0.0488(10) 0.2171(9) 0.5698(10) 0.243(10) Uani 1 1 d DU
H55A H 0.0311 0.1864 0.5425 0.292 Uiso 1 1 calc R
H55B H 0.0900 0.2106 0.5823 0.292 Uiso 1 1 calc R
H55C H 0.0417 0.2527 0.5469 0.292 Uiso 1 1 calc R
C56 C 0.0232(8) 0.2195(7) 0.6282(9) 0.181(7) Uani 1 1 d D
C57 C 0.0042(11) 0.2796(8) 0.6366(13) 0.288(12) Uani 1 1 d DU
H57A H 0.0070 0.2872 0.6815 0.346 Uiso 1 1 calc R
H57B H -0.0355 0.2844 0.6141 0.346 Uiso 1 1 calc R
H57C H 0.0287 0.3057 0.6197 0.346 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C12 Pt1 C1 168.7(2) . .
C12 Pt1 P2 93.97(14) . .
C1 Pt1 P2 82.85(15) . .
C12 Pt1 P1 89.86(14) . .
C1 Pt1 P1 93.87(15) . .
P2 Pt1 P1 175.37(4) . .
C12 Pt1 Pt1 97.69(14) . 2_656
C1 Pt1 Pt1 93.06(14) . 2_656
P2 Pt1 Pt1 87.69(3) . 2_656
P1 Pt1 Pt1 89.23(3) . 2_656
C1 Ag1 C1 103.9(2) . 2_656
C1 Ag1 C2 30.46(17) . .
C1 Ag1 C2 132.47(18) 2_656 .
C1 Ag1 C2 132.47(18) . 2_656
C1 Ag1 C2 30.46(17) 2_656 2_656
C2 Ag1 C2 162.6(3) . 2_656
C1 Ag1 N1 126.1(3) . 2_656
C1 Ag1 N1 126.1(3) 2_656 2_656
C2 Ag1 N1 95.6(3) . 2_656
C2 Ag1 N1 101.0(3) 2_656 2_656
C1 Ag1 N1 126.1(3) . .
C1 Ag1 N1 126.1(3) 2_656 .
C2 Ag1 N1 101.0(3) . .
C2 Ag1 N1 95.6(3) 2_656 .
N1 Ag1 N1 34.5(6) 2_656 .
C12 Ag2 C12 112.3(2) 2_656 .
C12 Ag2 N2 120.5(3) 2_656 2_656
C12 Ag2 N2 124.3(3) . 2_656
C12 Ag2 N2 124.3(3) 2_656 .
C12 Ag2 N2 120.5(3) . .
N2 Ag2 N2 32.1(6) 2_656 .
C12 Ag2 C13 141.74(17) 2_656 .
C12 Ag2 C13 29.83(17) . .
N2 Ag2 C13 97.0(3) 2_656 .
N2 Ag2 C13 91.1(3) . .
C12 Ag2 C13 29.83(17) 2_656 2_656
C12 Ag2 C13 141.74(17) . 2_656
N2 Ag2 C13 91.1(3) 2_656 2_656
N2 Ag2 C13 97.0(3) . 2_656
C13 Ag2 C13 171.5(2) . 2_656
C34 P1 C28 100.7(2) . .
C34 P1 C27 107.2(2) . .
C28 P1 C27 103.8(2) . .
C34 P1 Pt1 116.25(17) . .
C28 P1 Pt1 113.19(17) . .
C27 P1 Pt1 114.18(16) . .
C46 P2 C40 102.4(2) . .
C46 P2 C27 107.2(3) . 2_656
C40 P2 C27 101.4(2) . 2_656
C46 P2 Pt1 120.19(16) . .
C40 P2 Pt1 113.02(17) . .
C27 P2 Pt1 110.74(17) 2_656 .
F4 B1 F1 111.1(11) . .
F4 B1 F2 105.6(11) . .
F1 B1 F2 113.0(11) . .
F4 B1 F3 112.2(12) . .
F1 B1 F3 103.2(11) . .
F2 B1 F3 111.9(11) . .
C5 O1 C9 117.9(5) . .
C10 O2 C6 115.3(6) . .
C7 O3 C11 118.1(5) . .
C16 O4 C20 118.6(6) . .
C17 O5 C21 115.4(6) . .
C18 O6 C22 119.4(5) . .
C2 C1 Pt1 165.8(4) . .
C2 C1 Ag1 76.5(3) . .
Pt1 C1 Ag1 117.7(2) . .
C1 C2 C3 173.1(5) . .
C1 C2 Ag1 73.1(3) . .
C3 C2 Ag1 113.1(3) . .
C4 C3 C8 120.2(5) . .
C4 C3 C2 119.8(5) . .
C8 C3 C2 120.0(5) . .
C3 C4 C5 119.7(5) . .
C3 C4 H4 120.2 . .
C5 C4 H4 120.2 . .
O1 C5 C6 115.8(5) . .
O1 C5 C4 124.3(5) . .
C6 C5 C4 119.9(5) . .
C5 C6 C7 120.3(5) . .
C5 C6 O2 119.5(5) . .
C7 C6 O2 120.2(5) . .
O3 C7 C8 124.5(5) . .
O3 C7 C6 115.6(5) . .
C8 C7 C6 119.9(5) . .
C7 C8 C3 119.9(5) . .
C7 C8 H8 120.0 . .
C3 C8 H8 120.0 . .
O1 C9 H9A 109.5 . .
O1 C9 H9B 109.5 . .
H9A C9 H9B 109.5 . .
O1 C9 H9C 109.5 . .
H9A C9 H9C 109.5 . .
H9B C9 H9C 109.5 . .
O2 C10 H10A 109.5 . .
O2 C10 H10B 109.5 . .
H10A C10 H10B 109.5 . .
O2 C10 H10C 109.5 . .
H10A C10 H10C 109.5 . .
H10B C10 H10C 109.5 . .
O3 C11 H11A 109.5 . .
O3 C11 H11B 109.5 . .
H11A C11 H11B 109.5 . .
O3 C11 H11C 109.5 . .
H11A C11 H11C 109.5 . .
H11B C11 H11C 109.5 . .
C13 C12 Pt1 168.2(4) . .
C13 C12 Ag2 78.6(3) . .
Pt1 C12 Ag2 112.1(2) . .
C12 C13 C14 172.6(5) . .
C12 C13 Ag2 71.6(3) . .
C14 C13 Ag2 115.6(3) . .
C15 C14 C19 120.2(5) . .
C15 C14 C13 120.5(5) . .
C19 C14 C13 119.3(5) . .
C16 C15 C14 119.9(5) . .
C16 C15 H15 120.0 . .
C14 C15 H15 120.0 . .
O4 C16 C15 125.4(6) . .
O4 C16 C17 114.5(5) . .
C15 C16 C17 120.1(5) . .
O5 C17 C18 121.3(5) . .
O5 C17 C16 118.7(5) . .
C18 C17 C16 119.8(5) . .
O6 C18 C17 114.8(5) . .
O6 C18 C19 125.0(6) . .
C17 C18 C19 120.2(5) . .
C18 C19 C14 119.7(5) . .
C18 C19 H19 120.1 . .
C14 C19 H19 120.1 . .
O4 C20 H20A 109.5 . .
O4 C20 H20B 109.5 . .
H20A C20 H20B 109.5 . .
O4 C20 H20C 109.5 . .
H20A C20 H20C 109.5 . .
H20B C20 H20C 109.5 . .
O5 C21 H21A 109.5 . .
O5 C21 H21B 109.5 . .
H21A C21 H21B 109.5 . .
O5 C21 H21C 109.5 . .
H21A C21 H21C 109.5 . .
H21B C21 H21C 109.5 . .
O6 C22 H22A 109.5 . .
O6 C22 H22B 109.5 . .
H22A C22 H22B 109.5 . .
O6 C22 H22C 109.5 . .
H22A C22 H22C 109.5 . .
H22B C22 H22C 109.5 . .
C23 N1 N1 54.8(6) . 2_656
C23 N1 Ag1 127.5(9) . .
N1 N1 Ag1 72.8(3) 2_656 .
N1 C23 N1 70.5(12) . 2_656
N1 C23 C24 165.2(13) . .
N1 C23 C24 102.7(12) 2_656 .
N1 C23 C24 102.7(12) . 2_656
N1 C23 C24 165.2(13) 2_656 2_656
C24 C23 C24 87(2) . 2_656
C23 C24 C24 46.6(11) . 2_656
C23 C24 H24A 109.5 . .
C24 C24 H24A 155.5 2_656 .
C23 C24 H24B 109.5 . .
C24 C24 H24B 87.3 2_656 .
H24A C24 H24B 109.5 . .
C23 C24 H24C 109.5 . .
C24 C24 H24C 79.9 2_656 .
H24A C24 H24C 109.5 . .
H24B C24 H24C 109.5 . .
C25 N2 N2 59.0(6) . 2_656
C25 N2 C26 46.4(6) . 2_656
N2 N2 C26 104.5(6) 2_656 2_656
C25 N2 Ag2 133.0(9) . .
N2 N2 Ag2 74.0(3) 2_656 .
C26 N2 Ag2 170.7(8) 2_656 .
N2 C25 N2 62.0(13) . 2_656
N2 C25 C26 91.8(10) . 2_656
N2 C25 C26 151.1(12) 2_656 2_656
N2 C25 C26 151.1(12) . .
N2 C25 C26 91.8(10) 2_656 .
C26 C25 C26 116.1(19) 2_656 .
C25 C26 H26A 109.5 . .
N2 C26 H26A 89.5 2_656 .
C25 C26 H26B 109.5 . .
N2 C26 H26B 150.9 2_656 .
H26A C26 H26B 109.5 . .
C25 C26 H26C 109.5 . .
N2 C26 H26C 83.2 2_656 .
H26A C26 H26C 109.5 . .
H26B C26 H26C 109.5 . .
P2 C27 P1 123.0(3) 2_656 .
P2 C27 H27A 106.6 2_656 .
P1 C27 H27A 106.6 . .
P2 C27 H27B 106.6 2_656 .
P1 C27 H27B 106.6 . .
H27A C27 H27B 106.5 . .
C29 C28 C33 119.3(5) . .
C29 C28 P1 125.0(4) . .
C33 C28 P1 115.7(4) . .
C28 C29 C30 119.4(7) . .
C28 C29 H29 120.3 . .
C30 C29 H29 120.3 . .
C31 C30 C29 120.6(8) . .
C31 C30 H30 119.7 . .
C29 C30 H30 119.7 . .
C32 C31 C30 120.6(7) . .
C32 C31 H31 119.7 . .
C30 C31 H31 119.7 . .
C31 C32 C33 120.0(7) . .
C31 C32 H32 120.0 . .
C33 C32 H32 120.0 . .
C32 C33 C28 120.0(7) . .
C32 C33 H33 120.0 . .
C28 C33 H33 120.0 . .
C35 C34 C39 119.0(5) . .
C35 C34 P1 118.6(4) . .
C39 C34 P1 121.8(4) . .
C34 C35 C36 120.7(6) . .
C34 C35 H35 119.6 . .
C36 C35 H35 119.6 . .
C37 C36 C35 119.1(6) . .
C37 C36 H36 120.4 . .
C35 C36 H36 120.4 . .
C38 C37 C36 120.8(6) . .
C38 C37 H37 119.6 . .
C36 C37 H37 119.6 . .
C37 C38 C39 120.5(6) . .
C37 C38 H38 119.7 . .
C39 C38 H38 119.7 . .
C38 C39 C34 119.8(6) . .
C38 C39 H39 120.1 . .
C34 C39 H39 120.1 . .
C41 C40 C45 118.8(5) . .
C41 C40 P2 120.7(4) . .
C45 C40 P2 120.4(4) . .
C42 C41 C40 120.0(6) . .
C42 C41 H41 120.0 . .
C40 C41 H41 120.0 . .
C43 C42 C41 120.3(7) . .
C43 C42 H42 119.8 . .
C41 C42 H42 119.8 . .
C44 C43 C42 120.2(6) . .
C44 C43 H43 119.9 . .
C42 C43 H43 119.9 . .
C43 C44 C45 120.5(7) . .
C43 C44 H44 119.7 . .
C45 C44 H44 119.7 . .
C44 C45 C40 120.1(6) . .
C44 C45 H45 120.0 . .
C40 C45 H45 120.0 . .
C47 C46 C51 119.9(5) . .
C47 C46 P2 122.9(4) . .
C51 C46 P2 117.3(4) . .
C46 C47 C48 119.5(6) . .
C46 C47 H47 120.2 . .
C48 C47 H47 120.2 . .
C49 C48 C47 120.4(6) . .
C49 C48 H48 119.8 . .
C47 C48 H48 119.8 . .
C50 C49 C48 119.9(6) . .
C50 C49 H49 120.0 . .
C48 C49 H49 120.0 . .
C49 C50 C51 120.8(6) . .
C49 C50 H50 119.6 . .
C51 C50 H50 119.6 . .
C50 C51 C46 119.4(6) . .
C50 C51 H51 120.3 . .
C46 C51 H51 120.3 . .
C53 C52 H52A 109.5 . .
C53 C52 H52B 109.5 . .
H52A C52 H52B 109.5 . .
C53 C52 H52C 109.5 . .
H52A C52 H52C 109.5 . .
H52B C52 H52C 109.5 . .
O7 C53 C54 118.0(15) . .
O7 C53 C52 124.6(14) . .
C54 C53 C52 117.3(14) . .
C53 C54 H54A 109.5 . .
C53 C54 H54B 109.5 . .
H54A C54 H54B 109.5 . .
C53 C54 H54C 109.5 . .
H54A C54 H54C 109.5 . .
H54B C54 H54C 109.5 . .
C56 C55 H55A 109.5 . .
C56 C55 H55B 109.5 . .
H55A C55 H55B 109.5 . .
C56 C55 H55C 109.5 . .
H55A C55 H55C 109.5 . .
H55B C55 H55C 109.5 . .
O8 C56 C55 116.4(18) . .
O8 C56 C57 132(2) . .
C55 C56 C57 108.6(17) . .
C56 C57 H57A 109.5 . .
C56 C57 H57B 109.5 . .
H57A C57 H57B 109.5 . .
C56 C57 H57C 109.5 . .
H57A C57 H57C 109.5 . .
H57B C57 H57C 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Pt1 C12 2.005(5) .
Pt1 C1 2.012(5) .
Pt1 P2 2.3029(13) .
Pt1 P1 2.3214(13) .
Pt1 Pt1 3.2022(5) 2_656
Ag1 C1 2.305(5) .
Ag1 C1 2.305(5) 2_656
Ag1 C2 2.343(5) .
Ag1 C2 2.343(5) 2_656
Ag1 N1 2.389(9) 2_656
Ag1 N1 2.389(9) .
Ag2 C12 2.327(5) 2_656
Ag2 C12 2.327(5) .
Ag2 N2 2.403(9) 2_656
Ag2 N2 2.403(9) .
Ag2 C13 2.403(5) .
Ag2 C13 2.403(5) 2_656
P1 C34 1.825(5) .
P1 C28 1.838(5) .
P1 C27 1.840(5) .
P2 C46 1.816(5) .
P2 C40 1.828(5) .
P2 C27 1.835(5) 2_656
B1 F4 1.307(11) .
B1 F1 1.309(11) .
B1 F2 1.324(11) .
B1 F3 1.341(11) .
O1 C5 1.365(7) .
O1 C9 1.422(8) .
O2 C10 1.387(10) .
O2 C6 1.390(6) .
O3 C7 1.360(7) .
O3 C11 1.413(8) .
O4 C16 1.345(7) .
O4 C20 1.403(9) .
O5 C17 1.375(6) .
O5 C21 1.409(10) .
O6 C18 1.358(7) .
O6 C22 1.392(9) .
C1 C2 1.222(7) .
C2 C3 1.453(7) .
C3 C4 1.387(7) .
C3 C8 1.388(8) .
C4 C5 1.391(7) .
C4 H4 0.9300 .
C5 C6 1.384(8) .
C6 C7 1.385(8) .
C7 C8 1.384(8) .
C8 H8 0.9300 .
C9 H9A 0.9600 .
C9 H9B 0.9600 .
C9 H9C 0.9600 .
C10 H10A 0.9600 .
C10 H10B 0.9600 .
C10 H10C 0.9600 .
C11 H11A 0.9600 .
C11 H11B 0.9600 .
C11 H11C 0.9600 .
C12 C13 1.219(7) .
C13 C14 1.449(7) .
C14 C15 1.393(7) .
C14 C19 1.394(7) .
C15 C16 1.382(8) .
C15 H15 0.9300 .
C16 C17 1.401(9) .
C17 C18 1.384(8) .
C18 C19 1.391(7) .
C19 H19 0.9300 .
C20 H20A 0.9600 .
C20 H20B 0.9600 .
C20 H20C 0.9600 .
C21 H21A 0.9600 .
C21 H21B 0.9600 .
C21 H21C 0.9600 .
C22 H22A 0.9600 .
C22 H22B 0.9600 .
C22 H22C 0.9600 .
N1 C23 1.227(11) .
N1 N1 1.42(2) 2_656
C23 N1 1.227(11) 2_656
C23 C24 1.42(2) .
C23 C24 1.42(2) 2_656
C24 C24 1.95(5) 2_656
C24 H24A 0.9600 .
C24 H24B 0.9600 .
C24 H24C 0.9600 .
N2 C25 1.288(13) .
N2 N2 1.33(2) 2_656
N2 C26 1.93(2) 2_656
C25 N2 1.288(13) 2_656
C25 C26 1.400(18) 2_656
C25 C26 1.400(18) .
C26 N2 1.93(2) 2_656
C26 H26A 0.9600 .
C26 H26B 0.9600 .
C26 H26C 0.9600 .
C27 P2 1.835(5) 2_656
C27 H27A 0.9700 .
C27 H27B 0.9700 .
C28 C29 1.369(8) .
C28 C33 1.392(8) .
C29 C30 1.392(9) .
C29 H29 0.9300 .
C30 C31 1.359(12) .
C30 H30 0.9300 .
C31 C32 1.347(11) .
C31 H31 0.9300 .
C32 C33 1.387(9) .
C32 H32 0.9300 .
C33 H33 0.9300 .
C34 C35 1.382(8) .
C34 C39 1.397(8) .
C35 C36 1.391(8) .
C35 H35 0.9300 .
C36 C37 1.380(10) .
C36 H36 0.9300 .
C37 C38 1.362(10) .
C37 H37 0.9300 .
C38 C39 1.383(8) .
C38 H38 0.9300 .
C39 H39 0.9300 .
C40 C41 1.391(8) .
C40 C45 1.392(8) .
C41 C42 1.387(9) .
C41 H41 0.9300 .
C42 C43 1.371(10) .
C42 H42 0.9300 .
C43 C44 1.362(10) .
C43 H43 0.9300 .
C44 C45 1.384(9) .
C44 H44 0.9300 .
C45 H45 0.9300 .
C46 C47 1.381(7) .
C46 C51 1.398(7) .
C47 C48 1.391(8) .
C47 H47 0.9300 .
C48 C49 1.376(10) .
C48 H48 0.9300 .
C49 C50 1.370(10) .
C49 H49 0.9300 .
C50 C51 1.376(8) .
C50 H50 0.9300 .
C51 H51 0.9300 .
O7 C53 1.180(14) .
C52 C53 1.493(9) .
C52 H52A 0.9600 .
C52 H52B 0.9600 .
C52 H52C 0.9600 .
C53 C54 1.480(9) .
C54 H54A 0.9600 .
C54 H54B 0.9600 .
C54 H54C 0.9600 .
O8 C56 1.199(9) .
C55 C56 1.492(10) .
C55 H55A 0.9600 .
C55 H55B 0.9600 .
C55 H55C 0.9600 .
C56 C57 1.495(10) .
C57 H57A 0.9600 .
C57 H57B 0.9600 .
C57 H57C 0.9600 .
