#------------------------------------------------------------------------------
#$Date: 2016-03-21 07:16:20 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178556 $
#$URL: svn://www.crystallography.net/cod/cif/4/06/64/4066470.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4066470
loop_
_publ_author_name
'Leung, Sammual Yu-Lut'
'Lam, Wai Han'
'Zhu, Nianyong'
'Yam, Vivian Wing-Wah'
_publ_section_title
;
 Synthesis, Structural Characterization, and Photophysical Study of
 Luminescent Face-to-Face Dinuclear Platinum(II) Alkynyl Phosphine
 Complexes and Their Tetranuclear Mixed-Metal
 Platinum(II)−Silver(I) and −Copper(I) Complexes†
;
_journal_issue                   21
_journal_name_full               Organometallics
_journal_page_first              5558
_journal_paper_doi               10.1021/om100473q
_journal_volume                  29
_journal_year                    2010
_chemical_formula_moiety
'C98 H94 Cu2 N2 O12 P4 Pt2, 4(C3 H6 O), 2(F6 P)'
_chemical_formula_sum            'C110 H118 Cu2 F12 N2 O16 P6 Pt2'
_chemical_formula_weight         2655.14
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      15
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 102.229(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   23.973(3)
_cell_length_b                   22.983(2)
_cell_length_c                   21.570(2)
_cell_measurement_reflns_used    29412
_cell_measurement_temperature    297(2)
_cell_measurement_theta_max      25.03
_cell_measurement_theta_min      1.77
_cell_volume                     11615(2)
_computing_cell_refinement       'SAINT (Bruker AXS Inc, 2006)'
_computing_data_collection       'SMART (Bruker AXS Inc, 1998)'
_computing_data_reduction
;
SAINT (Bruker AXS Inc, 2006) & 
CrystalStructure (Rigaku/MSC and Rigaku Corporation, 2006)
;
_computing_molecular_graphics
'ORTEP-II (Johnson, 1976) & MERCURY (Macrae et al., 2008)'
_computing_publication_material  'SHELX (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      297(2)
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'Bruker SMART 1000 CCD'
_diffrn_measurement_method       ω
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0223
_diffrn_reflns_av_sigmaI/netI    0.0255
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_h_min       -28
_diffrn_reflns_limit_k_max       27
_diffrn_reflns_limit_k_min       -25
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_number            29002
_diffrn_reflns_theta_full        25.03
_diffrn_reflns_theta_max         25.03
_diffrn_reflns_theta_min         1.77
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    2.925
_exptl_absorpt_correction_T_max  0.7204
_exptl_absorpt_correction_T_min  0.4108
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS (Sheldrick, 1996)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.518
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             5328
_exptl_crystal_size_max          0.37
_exptl_crystal_size_mid          0.28
_exptl_crystal_size_min          0.12
_refine_diff_density_max         1.323
_refine_diff_density_min         -1.120
_refine_diff_density_rms         0.107
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.055
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     676
_refine_ls_number_reflns         10214
_refine_ls_number_restraints     41
_refine_ls_restrained_S_all      1.066
_refine_ls_R_factor_all          0.0484
_refine_ls_R_factor_gt           0.0358
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0645P)²+44.0022P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1005
_refine_ls_wR_factor_ref         0.1109
_reflns_number_gt                8396
_reflns_number_total             10214
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            om100473q_si_006.cif
_cod_data_source_block           wt1793w-shelxl
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               4066470
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Pt1 Pt 0.494470(7) 0.228466(7) 0.679146(8) 0.03134(8) Uani 1 1 d .
Cu1 Cu 0.5000 0.36941(4) 0.7500 0.0514(3) Uani 1 2 d S
Cu2 Cu 0.5000 0.08854(4) 0.7500 0.0453(2) Uani 1 2 d S
P1 P 0.39836(5) 0.25150(6) 0.66255(6) 0.0352(3) Uani 1 1 d .
P2 P 0.59118(6) 0.21201(6) 0.69344(6) 0.0354(3) Uani 1 1 d .
P3 P 0.32214(10) 0.20882(15) 0.29265(13) 0.0977(7) Uani 1 1 d .
F1 F 0.2899(4) 0.2704(4) 0.2728(5) 0.1851(14) Uani 1 1 d .
F2 F 0.3779(4) 0.2364(4) 0.2870(5) 0.1851(14) Uani 1 1 d .
F3 F 0.3277(4) 0.2306(4) 0.3621(5) 0.1851(14) Uani 1 1 d .
F4 F 0.3470(4) 0.1516(5) 0.3127(4) 0.1851(14) Uani 1 1 d .
F5 F 0.2600(4) 0.1882(4) 0.2891(4) 0.1851(14) Uani 1 1 d .
F6 F 0.3149(4) 0.1902(4) 0.2219(4) 0.1851(14) Uani 1 1 d .
O1 O 0.5329(2) 0.55160(19) 0.5682(2) 0.0674(12) Uani 1 1 d .
O2 O 0.6466(2) 0.5572(2) 0.5998(2) 0.0733(14) Uani 1 1 d .
O3 O 0.7086(2) 0.4705(2) 0.6616(3) 0.0808(15) Uani 1 1 d .
O4 O 0.4888(2) -0.0913(2) 0.5488(3) 0.102(2) Uani 1 1 d .
O5 O 0.3781(3) -0.1063(2) 0.5141(3) 0.0911(17) Uani 1 1 d .
O6 O 0.3046(2) -0.0272(2) 0.5411(3) 0.0961(19) Uani 1 1 d .
O7 O 0.1539(5) 0.0854(5) 0.9160(6) 0.207(5) Uani 1 1 d .
O8 O 0.0024(11) 0.1704(8) 0.6489(11) 0.348(14) Uani 1 1 d D
N1 N 0.4725(4) 0.4548(3) 0.7336(4) 0.044(2) Uani 0.50 1 d P
N2 N 0.5255(4) 0.0031(4) 0.7481(5) 0.053(3) Uani 0.50 1 d P
C1 C 0.5168(2) 0.3129(2) 0.6804(2) 0.0395(11) Uani 1 1 d .
C2 C 0.5363(2) 0.3606(2) 0.6700(2) 0.0434(12) Uani 1 1 d .
C3 C 0.5644(2) 0.4108(2) 0.6497(2) 0.0433(12) Uani 1 1 d .
C4 C 0.5321(3) 0.4562(2) 0.6171(3) 0.0477(13) Uani 1 1 d .
H4 H 0.4926 0.4537 0.6063 0.057 Uiso 1 1 calc R
C5 C 0.5602(3) 0.5054(2) 0.6009(3) 0.0505(14) Uani 1 1 d .
C6 C 0.6191(3) 0.5090(3) 0.6174(3) 0.0542(15) Uani 1 1 d .
C7 C 0.6507(3) 0.4632(3) 0.6483(3) 0.0562(15) Uani 1 1 d .
C8 C 0.6233(3) 0.4139(3) 0.6645(3) 0.0529(14) Uani 1 1 d .
H8 H 0.6445 0.3830 0.6852 0.063 Uiso 1 1 calc R
C9 C 0.4730(3) 0.5527(3) 0.5549(3) 0.0713(19) Uani 1 1 d .
H9A H 0.4598 0.5877 0.5323 0.086 Uiso 1 1 calc R
H9B H 0.4598 0.5515 0.5938 0.086 Uiso 1 1 calc R
H9C H 0.4586 0.5196 0.5293 0.086 Uiso 1 1 calc R
C10 C 0.6587(5) 0.6007(4) 0.6463(5) 0.123(4) Uani 1 1 d .
H10A H 0.6577 0.6381 0.6262 0.147 Uiso 1 1 calc R
H10B H 0.6960 0.5943 0.6722 0.147 Uiso 1 1 calc R
H10C H 0.6309 0.5996 0.6723 0.147 Uiso 1 1 calc R
C11 C 0.7431(3) 0.4228(3) 0.6880(5) 0.098(3) Uani 1 1 d .
H11A H 0.7825 0.4340 0.6959 0.118 Uiso 1 1 calc R
H11B H 0.7368 0.3908 0.6588 0.118 Uiso 1 1 calc R
H11C H 0.7332 0.4114 0.7271 0.118 Uiso 1 1 calc R
C12 C 0.4749(2) 0.1435(2) 0.6699(2) 0.0362(11) Uani 1 1 d .
C13 C 0.4622(2) 0.0942(2) 0.6512(2) 0.0410(12) Uani 1 1 d .
C14 C 0.4403(2) 0.0423(2) 0.6151(2) 0.0437(12) Uani 1 1 d .
C15 C 0.4778(3) 0.0017(3) 0.5995(3) 0.0522(14) Uani 1 1 d .
H15 H 0.5170 0.0077 0.6113 0.063 Uiso 1 1 calc R
C16 C 0.4563(3) -0.0484(3) 0.5660(3) 0.0617(17) Uani 1 1 d .
C17 C 0.3980(3) -0.0572(3) 0.5481(3) 0.0594(16) Uani 1 1 d .
C18 C 0.3606(3) -0.0157(3) 0.5627(3) 0.0573(16) Uani 1 1 d .
C19 C 0.3823(2) 0.0344(2) 0.5957(3) 0.0496(14) Uani 1 1 d .
H19 H 0.3573 0.0626 0.6046 0.060 Uiso 1 1 calc R
C20 C 0.5475(4) -0.0836(4) 0.5577(5) 0.105(3) Uani 1 1 d .
H20A H 0.5635 -0.1148 0.5376 0.125 Uiso 1 1 calc R
H20B H 0.5642 -0.0834 0.6022 0.125 Uiso 1 1 calc R
H20C H 0.5553 -0.0472 0.5393 0.125 Uiso 1 1 calc R
C21 C 0.3529(5) -0.1488(4) 0.5447(6) 0.131(4) Uani 1 1 d .
H21A H 0.3510 -0.1846 0.5215 0.157 Uiso 1 1 calc R
H21B H 0.3150 -0.1368 0.5469 0.157 Uiso 1 1 calc R
H21C H 0.3752 -0.1544 0.5868 0.157 Uiso 1 1 calc R
C22 C 0.2641(3) 0.0141(4) 0.5445(5) 0.096(3) Uani 1 1 d .
H22A H 0.2268 -0.0019 0.5291 0.115 Uiso 1 1 calc R
H22B H 0.2695 0.0471 0.5191 0.115 Uiso 1 1 calc R
H22C H 0.2677 0.0262 0.5878 0.115 Uiso 1 1 calc R
C23 C 0.5000 0.5016(4) 0.7500 0.088(4) Uani 1 2 d S
C24 C 0.5506(8) 0.5340(11) 0.7676(9) 0.113(6) Uani 0.50 1 d PU
H24A H 0.5424 0.5745 0.7596 0.136 Uiso 0.50 1 calc PR
H24B H 0.5775 0.5213 0.7432 0.136 Uiso 0.50 1 calc PR
H24C H 0.5665 0.5283 0.8119 0.136 Uiso 0.50 1 calc PR
C25 C 0.5000 -0.0475(5) 0.7500 0.086(3) Uani 1 2 d SU
C26 C 0.4483(7) -0.0779(10) 0.7403(8) 0.102(6) Uani 0.50 1 d P
H26A H 0.4556 -0.1180 0.7518 0.123 Uiso 0.50 1 calc PR
H26B H 0.4295 -0.0755 0.6964 0.123 Uiso 0.50 1 calc PR
H26C H 0.4243 -0.0611 0.7660 0.123 Uiso 0.50 1 calc PR
C27 C 0.3695(2) 0.2496(3) 0.7350(2) 0.0411(11) Uani 1 1 d .
H27A H 0.3319 0.2320 0.7239 0.049 Uiso 1 1 calc R
H27B H 0.3641 0.2895 0.7469 0.049 Uiso 1 1 calc R
C28 C 0.3818(2) 0.3250(2) 0.6315(3) 0.0441(12) Uani 1 1 d .
C29 C 0.3511(3) 0.3657(3) 0.6573(3) 0.0631(17) Uani 1 1 d .
H29 H 0.3379 0.3567 0.6937 0.076 Uiso 1 1 calc R
C30 C 0.3396(4) 0.4205(3) 0.6291(5) 0.086(2) Uani 1 1 d .
H30 H 0.3188 0.4479 0.6465 0.103 Uiso 1 1 calc R
C31 C 0.3592(3) 0.4331(3) 0.5757(5) 0.084(3) Uani 1 1 d .
H31 H 0.3527 0.4699 0.5577 0.101 Uiso 1 1 calc R
C32 C 0.3877(3) 0.3938(3) 0.5487(4) 0.075(2) Uani 1 1 d .
H32 H 0.3994 0.4031 0.5114 0.090 Uiso 1 1 calc R
C33 C 0.4000(3) 0.3387(3) 0.5761(3) 0.0615(16) Uani 1 1 d .
H33 H 0.4200 0.3116 0.5574 0.074 Uiso 1 1 calc R
C34 C 0.3496(2) 0.2101(2) 0.6019(2) 0.0410(12) Uani 1 1 d .
C35 C 0.2915(2) 0.2095(3) 0.5995(3) 0.0553(15) Uani 1 1 d .
H35 H 0.2773 0.2241 0.6333 0.066 Uiso 1 1 calc R
C36 C 0.2547(3) 0.1870(3) 0.5471(3) 0.0669(18) Uani 1 1 d .
H36 H 0.2157 0.1868 0.5458 0.080 Uiso 1 1 calc R
C37 C 0.2746(3) 0.1650(3) 0.4970(3) 0.0696(19) Uani 1 1 d .
H37 H 0.2494 0.1499 0.4619 0.083 Uiso 1 1 calc R
C38 C 0.3331(3) 0.1656(3) 0.4989(3) 0.0686(19) Uani 1 1 d .
H38 H 0.3470 0.1511 0.4648 0.082 Uiso 1 1 calc R
C39 C 0.3705(3) 0.1876(3) 0.5513(3) 0.0508(14) Uani 1 1 d .
H39 H 0.4095 0.1873 0.5528 0.061 Uiso 1 1 calc R
C40 C 0.6227(2) 0.2456(2) 0.6321(2) 0.0416(12) Uani 1 1 d .
C41 C 0.5894(3) 0.2684(3) 0.5776(3) 0.0534(15) Uani 1 1 d .
H41 H 0.5498 0.2654 0.5702 0.064 Uiso 1 1 calc R
C42 C 0.6153(4) 0.2961(4) 0.5337(3) 0.076(2) Uani 1 1 d .
H42 H 0.5928 0.3125 0.4976 0.091 Uiso 1 1 calc R
C43 C 0.6732(4) 0.2996(4) 0.5428(4) 0.079(2) Uani 1 1 d .
H43 H 0.6900 0.3174 0.5126 0.095 Uiso 1 1 calc R
C44 C 0.7065(3) 0.2767(3) 0.5966(4) 0.075(2) Uani 1 1 d .
H44 H 0.7460 0.2796 0.6034 0.090 Uiso 1 1 calc R
C45 C 0.6817(3) 0.2491(3) 0.6411(3) 0.0578(15) Uani 1 1 d .
H45 H 0.7046 0.2329 0.6772 0.069 Uiso 1 1 calc R
C46 C 0.6182(2) 0.1383(2) 0.6960(3) 0.0416(12) Uani 1 1 d .
C47 C 0.6455(3) 0.1113(3) 0.7512(3) 0.0640(18) Uani 1 1 d .
H47 H 0.6501 0.1308 0.7898 0.077 Uiso 1 1 calc R
C48 C 0.6661(4) 0.0555(3) 0.7494(4) 0.083(2) Uani 1 1 d .
H48 H 0.6845 0.0375 0.7867 0.100 Uiso 1 1 calc R
C49 C 0.6596(4) 0.0263(3) 0.6933(4) 0.080(2) Uani 1 1 d .
H49 H 0.6739 -0.0113 0.6926 0.096 Uiso 1 1 calc R
C50 C 0.6322(3) 0.0521(3) 0.6379(4) 0.0639(17) Uani 1 1 d .
H50 H 0.6278 0.0321 0.5997 0.077 Uiso 1 1 calc R
C51 C 0.6113(3) 0.1075(3) 0.6392(3) 0.0529(14) Uani 1 1 d .
H51 H 0.5922 0.1248 0.6017 0.063 Uiso 1 1 calc R
C52 C 0.2304(7) 0.0941(10) 0.8678(11) 0.274(11) Uani 1 1 d DU
H52A H 0.2291 0.0527 0.8617 0.328 Uiso 1 1 calc R
H52B H 0.2618 0.1038 0.9019 0.328 Uiso 1 1 calc R
H52C H 0.2352 0.1129 0.8296 0.328 Uiso 1 1 calc R
C53 C 0.1764(5) 0.1140(5) 0.8838(6) 0.127(4) Uani 1 1 d D
C54 C 0.1504(8) 0.1671(7) 0.8481(9) 0.217(8) Uani 1 1 d DU
H54A H 0.1115 0.1590 0.8279 0.260 Uiso 1 1 calc R
H54B H 0.1716 0.1771 0.8165 0.260 Uiso 1 1 calc R
H54C H 0.1515 0.1990 0.8771 0.260 Uiso 1 1 calc R
C55 C -0.0146(9) 0.2715(8) 0.6466(13) 0.252(11) Uani 1 1 d DU
H55A H -0.0083 0.2708 0.6921 0.303 Uiso 1 1 calc R
H55B H -0.0548 0.2744 0.6290 0.303 Uiso 1 1 calc R
H55C H 0.0046 0.3045 0.6335 0.303 Uiso 1 1 calc R
C56 C 0.0083(7) 0.2163(8) 0.6234(9) 0.200(10) Uani 1 1 d D
C57 C 0.0375(10) 0.2234(9) 0.5686(10) 0.241(10) Uani 1 1 d DU
H57A H 0.0284 0.1909 0.5404 0.290 Uiso 1 1 calc R
H57B H 0.0781 0.2252 0.5843 0.290 Uiso 1 1 calc R
H57C H 0.0247 0.2587 0.5463 0.290 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C12 Pt1 C1 174.4(2) . .
C12 Pt1 P2 93.50(14) . .
C1 Pt1 P2 84.20(16) . .
C12 Pt1 P1 90.17(14) . .
C1 Pt1 P1 92.01(16) . .
P2 Pt1 P1 176.03(5) . .
C12 Pt1 Pt1 93.96(14) . 2_656
C1 Pt1 Pt1 91.14(14) . 2_656
P2 Pt1 Pt1 89.68(3) . 2_656
P1 Pt1 Pt1 91.59(3) . 2_656
N1 Cu1 N1 38.2(5) 2_656 .
N1 Cu1 C1 127.4(3) 2_656 .
N1 Cu1 C1 124.6(3) . .
N1 Cu1 C1 124.6(3) 2_656 2_656
N1 Cu1 C1 127.4(3) . 2_656
C1 Cu1 C1 103.0(3) . 2_656
N1 Cu1 C2 97.1(3) 2_656 2_656
N1 Cu1 C2 93.4(3) . 2_656
C1 Cu1 C2 135.0(2) . 2_656
C1 Cu1 C2 34.2(2) 2_656 2_656
N1 Cu1 C2 93.4(3) 2_656 .
N1 Cu1 C2 97.1(3) . .
C1 Cu1 C2 34.2(2) . .
C1 Cu1 C2 135.0(2) 2_656 .
C2 Cu1 C2 168.9(3) 2_656 .
N2 Cu2 N2 35.1(6) 2_656 .
N2 Cu2 C12 125.8(3) 2_656 2_656
N2 Cu2 C12 123.3(3) . 2_656
N2 Cu2 C12 123.3(3) 2_656 .
N2 Cu2 C12 125.8(3) . .
C12 Cu2 C12 107.0(3) 2_656 .
N2 Cu2 C13 90.7(3) 2_656 .
N2 Cu2 C13 95.9(3) . .
C12 Cu2 C13 139.8(2) 2_656 .
C12 Cu2 C13 33.29(19) . .
N2 Cu2 C13 95.9(3) 2_656 2_656
N2 Cu2 C13 90.7(3) . 2_656
C12 Cu2 C13 33.29(19) 2_656 2_656
C12 Cu2 C13 139.8(2) . 2_656
C13 Cu2 C13 173.1(3) . 2_656
C34 P1 C28 99.4(2) . .
C34 P1 C27 107.3(3) . .
C28 P1 C27 104.0(3) . .
C34 P1 Pt1 117.15(18) . .
C28 P1 Pt1 113.50(18) . .
C27 P1 Pt1 113.82(18) . .
C46 P2 C40 102.6(2) . .
C46 P2 C27 107.2(3) . 2_656
C40 P2 C27 101.1(2) . 2_656
C46 P2 Pt1 120.08(17) . .
C40 P2 Pt1 113.10(19) . .
C27 P2 Pt1 110.89(18) 2_656 .
F4 P3 F2 95.1(5) . .
F4 P3 F5 93.8(5) . .
F2 P3 F5 169.7(6) . .
F4 P3 F3 93.4(5) . .
F2 P3 F3 92.6(5) . .
F5 P3 F3 91.9(5) . .
F4 P3 F6 89.8(5) . .
F2 P3 F6 87.3(5) . .
F5 P3 F6 87.7(5) . .
F3 P3 F6 176.8(6) . .
F4 P3 F1 175.1(5) . .
F2 P3 F1 89.6(5) . .
F5 P3 F1 81.6(5) . .
F3 P3 F1 85.0(5) . .
F6 P3 F1 91.9(5) . .
C5 O1 C9 118.6(5) . .
C6 O2 C10 114.4(6) . .
C7 O3 C11 117.9(5) . .
C16 O4 C20 119.5(6) . .
C17 O5 C21 117.5(7) . .
C18 O6 C22 120.6(6) . .
C23 N1 N1 57.7(5) . 2_656
C23 N1 C24 47.7(7) . 2_656
N1 N1 C24 104.7(7) 2_656 2_656
C23 N1 Cu1 128.6(7) . .
N1 N1 Cu1 70.9(3) 2_656 .
C24 N1 Cu1 171.1(8) 2_656 .
N2 N2 C25 61.9(5) 2_656 .
N2 N2 C26 106.5(6) 2_656 2_656
C25 N2 C26 45.4(6) . 2_656
N2 N2 Cu2 72.5(3) 2_656 .
C25 N2 Cu2 134.3(7) . .
C26 N2 Cu2 171.7(7) 2_656 .
C2 C1 Pt1 165.2(5) . .
C2 C1 Cu1 73.5(3) . .
Pt1 C1 Cu1 121.2(3) . .
C1 C2 C3 169.3(6) . .
C1 C2 Cu1 72.3(3) . .
C3 C2 Cu1 118.1(4) . .
C8 C3 C4 120.6(5) . .
C8 C3 C2 119.2(5) . .
C4 C3 C2 120.3(5) . .
C3 C4 C5 119.1(6) . .
C3 C4 H4 120.5 . .
C5 C4 H4 120.5 . .
O1 C5 C6 116.1(5) . .
O1 C5 C4 123.7(6) . .
C6 C5 C4 120.2(5) . .
O2 C6 C7 119.9(6) . .
O2 C6 C5 119.7(6) . .
C7 C6 C5 120.3(5) . .
O3 C7 C6 115.9(5) . .
O3 C7 C8 124.1(6) . .
C6 C7 C8 120.0(6) . .
C3 C8 C7 119.8(6) . .
C3 C8 H8 120.1 . .
C7 C8 H8 120.1 . .
O1 C9 H9A 109.5 . .
O1 C9 H9B 109.5 . .
H9A C9 H9B 109.5 . .
O1 C9 H9C 109.5 . .
H9A C9 H9C 109.5 . .
H9B C9 H9C 109.5 . .
O2 C10 H10A 109.5 . .
O2 C10 H10B 109.5 . .
H10A C10 H10B 109.5 . .
O2 C10 H10C 109.5 . .
H10A C10 H10C 109.5 . .
H10B C10 H10C 109.5 . .
O3 C11 H11A 109.5 . .
O3 C11 H11B 109.5 . .
H11A C11 H11B 109.5 . .
O3 C11 H11C 109.5 . .
H11A C11 H11C 109.5 . .
H11B C11 H11C 109.5 . .
C13 C12 Pt1 166.6(4) . .
C13 C12 Cu2 74.0(3) . .
Pt1 C12 Cu2 118.5(2) . .
C12 C13 C14 166.4(5) . .
C12 C13 Cu2 72.7(3) . .
C14 C13 Cu2 120.7(4) . .
C19 C14 C15 120.1(5) . .
C19 C14 C13 119.8(5) . .
C15 C14 C13 120.1(5) . .
C14 C15 C16 119.5(6) . .
C14 C15 H15 120.2 . .
C16 C15 H15 120.2 . .
O4 C16 C17 114.9(6) . .
O4 C16 C15 124.8(6) . .
C17 C16 C15 120.3(6) . .
O5 C17 C16 119.0(6) . .
O5 C17 C18 121.1(6) . .
C16 C17 C18 119.8(5) . .
O6 C18 C17 115.4(5) . .
O6 C18 C19 124.9(6) . .
C17 C18 C19 119.6(6) . .
C14 C19 C18 120.5(5) . .
C14 C19 H19 119.8 . .
C18 C19 H19 119.8 . .
O4 C20 H20A 109.5 . .
O4 C20 H20B 109.5 . .
H20A C20 H20B 109.5 . .
O4 C20 H20C 109.5 . .
H20A C20 H20C 109.5 . .
H20B C20 H20C 109.5 . .
O5 C21 H21A 109.5 . .
O5 C21 H21B 109.5 . .
H21A C21 H21B 109.5 . .
O5 C21 H21C 109.5 . .
H21A C21 H21C 109.5 . .
H21B C21 H21C 109.5 . .
O6 C22 H22A 109.5 . .
O6 C22 H22B 109.5 . .
H22A C22 H22B 109.5 . .
O6 C22 H22C 109.5 . .
H22A C22 H22C 109.5 . .
H22B C22 H22C 109.5 . .
N1 C23 N1 64.6(9) . 2_656
N1 C23 C24 90.3(11) . 2_656
N1 C23 C24 152.9(12) 2_656 2_656
N1 C23 C24 152.9(12) . .
N1 C23 C24 90.3(11) 2_656 .
C24 C23 C24 116(2) 2_656 .
C23 C24 H24A 109.5 . .
N1 C24 H24A 151.5 2_656 .
C23 C24 H24B 109.5 . .
N1 C24 H24B 86.0 2_656 .
H24A C24 H24B 109.5 . .
C23 C24 H24C 109.5 . .
N1 C24 H24C 86.3 2_656 .
H24A C24 H24C 109.5 . .
H24B C24 H24C 109.5 . .
N2 C25 N2 56.2(10) 2_656 .
N2 C25 C26 92.5(10) 2_656 .
N2 C25 C26 146.9(12) . .
N2 C25 C26 146.9(12) 2_656 2_656
N2 C25 C26 92.5(10) . 2_656
C26 C25 C26 120(2) . 2_656
C25 C26 H26A 109.5 . .
N2 C26 H26A 147.2 2_656 .
C25 C26 H26B 109.5 . .
N2 C26 H26B 98.1 2_656 .
H26A C26 H26B 109.5 . .
C25 C26 H26C 109.5 . .
N2 C26 H26C 76.2 2_656 .
H26A C26 H26C 109.5 . .
H26B C26 H26C 109.5 . .
P1 C27 P2 120.4(3) . 2_656
P1 C27 H27A 107.2 . .
P2 C27 H27A 107.2 2_656 .
P1 C27 H27B 107.2 . .
P2 C27 H27B 107.2 2_656 .
H27A C27 H27B 106.9 . .
C29 C28 C33 118.9(6) . .
C29 C28 P1 124.9(5) . .
C33 C28 P1 116.2(5) . .
C28 C29 C30 120.5(7) . .
C28 C29 H29 119.8 . .
C30 C29 H29 119.8 . .
C31 C30 C29 119.1(8) . .
C31 C30 H30 120.5 . .
C29 C30 H30 120.5 . .
C32 C31 C30 121.6(7) . .
C32 C31 H31 119.2 . .
C30 C31 H31 119.2 . .
C31 C32 C33 120.4(7) . .
C31 C32 H32 119.8 . .
C33 C32 H32 119.8 . .
C28 C33 C32 119.4(7) . .
C28 C33 H33 120.3 . .
C32 C33 H33 120.3 . .
C35 C34 C39 119.5(5) . .
C35 C34 P1 121.3(4) . .
C39 C34 P1 118.3(4) . .
C36 C35 C34 120.0(6) . .
C36 C35 H35 120.0 . .
C34 C35 H35 120.0 . .
C37 C36 C35 121.1(6) . .
C37 C36 H36 119.5 . .
C35 C36 H36 119.5 . .
C36 C37 C38 119.4(6) . .
C36 C37 H37 120.3 . .
C38 C37 H37 120.3 . .
C39 C38 C37 120.1(6) . .
C39 C38 H38 119.9 . .
C37 C38 H38 119.9 . .
C38 C39 C34 119.9(6) . .
C38 C39 H39 120.0 . .
C34 C39 H39 120.0 . .
C41 C40 C45 119.2(5) . .
C41 C40 P2 121.6(5) . .
C45 C40 P2 119.2(4) . .
C40 C41 C42 119.5(7) . .
C40 C41 H41 120.3 . .
C42 C41 H41 120.3 . .
C43 C42 C41 121.2(7) . .
C43 C42 H42 119.4 . .
C41 C42 H42 119.4 . .
C42 C43 C44 119.5(6) . .
C42 C43 H43 120.2 . .
C44 C43 H43 120.2 . .
C43 C44 C45 120.4(7) . .
C43 C44 H44 119.8 . .
C45 C44 H44 119.8 . .
C44 C45 C40 120.2(7) . .
C44 C45 H45 119.9 . .
C40 C45 H45 119.9 . .
C47 C46 C51 118.5(5) . .
C47 C46 P2 123.3(5) . .
C51 C46 P2 118.2(4) . .
C48 C47 C46 120.1(6) . .
C48 C47 H47 120.0 . .
C46 C47 H47 120.0 . .
C49 C48 C47 120.7(7) . .
C49 C48 H48 119.7 . .
C47 C48 H48 119.7 . .
C48 C49 C50 120.3(6) . .
C48 C49 H49 119.9 . .
C50 C49 H49 119.9 . .
C49 C50 C51 119.6(7) . .
C49 C50 H50 120.2 . .
C51 C50 H50 120.2 . .
C50 C51 C46 120.9(6) . .
C50 C51 H51 119.6 . .
C46 C51 H51 119.6 . .
C53 C52 H52A 109.5 . .
C53 C52 H52B 109.5 . .
H52A C52 H52B 109.5 . .
C53 C52 H52C 109.5 . .
H52A C52 H52C 109.5 . .
H52B C52 H52C 109.5 . .
O7 C53 C52 120.1(16) . .
O7 C53 C54 124.6(14) . .
C52 C53 C54 114.7(14) . .
C53 C54 H54A 109.5 . .
C53 C54 H54B 109.5 . .
H54A C54 H54B 109.5 . .
C53 C54 H54C 109.5 . .
H54A C54 H54C 109.5 . .
H54B C54 H54C 109.5 . .
C56 C55 H55A 109.5 . .
C56 C55 H55B 109.5 . .
H55A C55 H55B 109.5 . .
C56 C55 H55C 109.5 . .
H55A C55 H55C 109.5 . .
H55B C55 H55C 109.5 . .
O8 C56 C57 124.7(19) . .
O8 C56 C55 120(2) . .
C57 C56 C55 115.6(19) . .
C56 C57 H57A 109.5 . .
C56 C57 H57B 109.5 . .
H57A C57 H57B 109.5 . .
C56 C57 H57C 109.5 . .
H57A C57 H57C 109.5 . .
H57B C57 H57C 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Pt1 C12 2.009(5) .
Pt1 C1 2.012(5) .
Pt1 P2 2.3043(13) .
Pt1 P1 2.3167(13) .
Pt1 Pt1 3.0116(5) 2_656
Cu1 N1 2.077(8) 2_656
Cu1 N1 2.077(8) .
Cu1 C1 2.087(5) .
Cu1 C1 2.087(5) 2_656
Cu1 C2 2.100(5) 2_656
Cu1 C2 2.100(5) .
Cu2 N2 2.060(8) 2_656
Cu2 N2 2.060(8) .
Cu2 C12 2.121(5) 2_656
Cu2 C12 2.121(5) .
Cu2 C13 2.136(5) .
Cu2 C13 2.136(5) 2_656
P1 C34 1.825(5) .
P1 C28 1.828(5) .
P1 C27 1.839(5) .
P2 C46 1.810(5) .
P2 C40 1.829(5) .
P2 C27 1.843(5) 2_656
P3 F4 1.471(10) .
P3 F2 1.508(10) .
P3 F5 1.549(9) .
P3 F3 1.557(10) .
P3 F6 1.559(9) .
P3 F1 1.626(10) .
O1 C5 1.362(7) .
O1 C9 1.403(9) .
O2 C6 1.382(7) .
O2 C10 1.402(11) .
O3 C7 1.366(8) .
O3 C11 1.418(9) .
O4 C16 1.356(8) .
O4 C20 1.391(10) .
O5 C17 1.375(7) .
O5 C21 1.386(11) .
O6 C18 1.351(8) .
O6 C22 1.371(9) .
O7 C53 1.167(13) .
O8 C56 1.212(10) .
N1 C23 1.272(12) .
N1 N1 1.36(2) 2_656
N1 C24 1.90(2) 2_656
N2 N2 1.24(2) 2_656
N2 C25 1.318(13) .
N2 C26 1.96(2) 2_656
C1 C2 1.230(7) .
C2 C3 1.451(7) .
C3 C8 1.381(8) .
C3 C4 1.397(8) .
C4 C5 1.398(8) .
C4 H4 0.9300 .
C5 C6 1.384(9) .
C6 C7 1.382(9) .
C7 C8 1.394(8) .
C8 H8 0.9300 .
C9 H9A 0.9600 .
C9 H9B 0.9600 .
C9 H9C 0.9600 .
C10 H10A 0.9600 .
C10 H10B 0.9600 .
C10 H10C 0.9600 .
C11 H11A 0.9600 .
C11 H11B 0.9600 .
C11 H11C 0.9600 .
C12 C13 1.220(7) .
C13 C14 1.458(7) .
C14 C19 1.378(8) .
C14 C15 1.386(8) .
C15 C16 1.398(8) .
C15 H15 0.9300 .
C16 C17 1.386(9) .
C17 C18 1.389(9) .
C18 C19 1.395(8) .
C19 H19 0.9300 .
C20 H20A 0.9600 .
C20 H20B 0.9600 .
C20 H20C 0.9600 .
C21 H21A 0.9600 .
C21 H21B 0.9600 .
C21 H21C 0.9600 .
C22 H22A 0.9600 .
C22 H22B 0.9600 .
C22 H22C 0.9600 .
C23 N1 1.272(12) 2_656
C23 C24 1.41(2) 2_656
C23 C24 1.41(2) .
C24 N1 1.90(2) 2_656
C24 H24A 0.9600 .
C24 H24B 0.9600 .
C24 H24C 0.9600 .
C25 N2 1.318(13) 2_656
C25 C26 1.400(19) .
C25 C26 1.400(19) 2_656
C26 N2 1.96(2) 2_656
C26 H26A 0.9600 .
C26 H26B 0.9600 .
C26 H26C 0.9600 .
C27 P2 1.843(5) 2_656
C27 H27A 0.9700 .
C27 H27B 0.9700 .
C28 C29 1.380(8) .
C28 C33 1.393(8) .
C29 C30 1.401(10) .
C29 H29 0.9300 .
C30 C31 1.364(12) .
C30 H30 0.9300 .
C31 C32 1.338(12) .
C31 H31 0.9300 .
C32 C33 1.402(9) .
C32 H32 0.9300 .
C33 H33 0.9300 .
C34 C35 1.383(8) .
C34 C39 1.393(8) .
C35 C36 1.379(9) .
C35 H35 0.9300 .
C36 C37 1.368(10) .
C36 H36 0.9300 .
C37 C38 1.393(10) .
C37 H37 0.9300 .
C38 C39 1.381(8) .
C38 H38 0.9300 .
C39 H39 0.9300 .
C40 C41 1.377(8) .
C40 C45 1.387(8) .
C41 C42 1.392(9) .
C41 H41 0.9300 .
C42 C43 1.362(11) .
C42 H42 0.9300 .
C43 C44 1.367(11) .
C43 H43 0.9300 .
C44 C45 1.386(9) .
C44 H44 0.9300 .
C45 H45 0.9300 .
C46 C47 1.379(8) .
C46 C51 1.394(8) .
C47 C48 1.378(9) .
C47 H47 0.9300 .
C48 C49 1.363(11) .
C48 H48 0.9300 .
C49 C50 1.370(11) .
C49 H49 0.9300 .
C50 C51 1.373(9) .
C50 H50 0.9300 .
C51 H51 0.9300 .
C52 C53 1.480(9) .
C52 H52A 0.9600 .
C52 H52B 0.9600 .
C52 H52C 0.9600 .
C53 C54 1.507(9) .
C54 H54A 0.9600 .
C54 H54B 0.9600 .
C54 H54C 0.9600 .
C55 C56 1.510(10) .
C55 H55A 0.9600 .
C55 H55B 0.9600 .
C55 H55C 0.9600 .
C56 C57 1.504(10) .
C57 H57A 0.9600 .
C57 H57B 0.9600 .
C57 H57C 0.9600 .
