#------------------------------------------------------------------------------
#$Date: 2016-03-21 07:16:20 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178556 $
#$URL: svn://www.crystallography.net/cod/cif/4/06/64/4066485.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4066485
loop_
_publ_author_name
'Lei, Hao'
'Fettinger, James C.'
'Power, Philip P.'
_publ_section_title
;
 Synthesis and Structures of Low-Valent Alkynyl Tin and Germanium
 Complexes Supported by Terphenyl Ligands: Heavier Group 14 Element
 Enediyne Analogues†
;
_journal_issue                   21
_journal_name_full               Organometallics
_journal_page_first              5585
_journal_paper_doi               10.1021/om100492u
_journal_volume                  29
_journal_year                    2010
_chemical_formula_moiety         'C70 H92 Ge2 Si2'
_chemical_formula_sum            'C70 H92 Ge2 Si2'
_chemical_formula_weight         1134.80
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                115.8480(10)
_cell_angle_beta                 98.2320(10)
_cell_angle_gamma                107.5880(10)
_cell_formula_units_Z            1
_cell_length_a                   12.4748(14)
_cell_length_b                   12.5284(8)
_cell_length_c                   12.7044(8)
_cell_measurement_reflns_used    7198
_cell_measurement_temperature    90(2)
_cell_measurement_theta_max      27.51
_cell_measurement_theta_min      2.49
_cell_volume                     1613.5(2)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      90(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0302
_diffrn_reflns_av_sigmaI/netI    0.0332
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            17403
_diffrn_reflns_theta_full        25.25
_diffrn_reflns_theta_max         25.25
_diffrn_reflns_theta_min         2.49
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.007
_exptl_absorpt_correction_T_max  0.9329
_exptl_absorpt_correction_T_min  0.8887
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.168
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             604
_exptl_crystal_size_max          0.12
_exptl_crystal_size_mid          0.11
_exptl_crystal_size_min          0.07
_refine_diff_density_max         0.602
_refine_diff_density_min         -0.303
_refine_diff_density_rms         0.054
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.024
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     334
_refine_ls_number_reflns         5815
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.024
_refine_ls_R_factor_all          0.0381
_refine_ls_R_factor_gt           0.0302
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0400P)²+0.8324P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0755
_refine_ls_wR_factor_ref         0.0776
_reflns_number_gt                5093
_reflns_number_total             5815
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            om100492u_si_001.cif
_cod_data_source_block           hl51_Ar'(Me3SiCC)GeGe(CCSiMe3)Ar'
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from
2010-06-29.

'_refine_ls_hydrogen_treatment' value 'CONSTR' changed
to 'constr' according to
/home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_database_code               4066485
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ge1 Ge 0.088584(18) 0.09205(2) 0.057237(19) 0.01477(8) Uani 1 1 d .
Si1 Si 0.33089(5) 0.01580(6) 0.33562(6) 0.02406(15) Uani 1 1 d .
C1 C 0.08311(17) 0.26311(18) 0.11082(18) 0.0149(4) Uani 1 1 d .
C2 C 0.01391(17) 0.31202(19) 0.18142(18) 0.0167(4) Uani 1 1 d .
C3 C 0.00393(18) 0.4251(2) 0.1935(2) 0.0217(5) Uani 1 1 d .
H3A H -0.0438 0.4579 0.2394 0.026 Uiso 1 1 calc R
C4 C 0.06214(19) 0.4895(2) 0.1402(2) 0.0247(5) Uani 1 1 d .
H4A H 0.0510 0.5634 0.1459 0.030 Uiso 1 1 calc R
C5 C 0.13676(19) 0.4466(2) 0.0782(2) 0.0222(5) Uani 1 1 d .
H5A H 0.1802 0.4940 0.0456 0.027 Uiso 1 1 calc R
C6 C 0.14834(17) 0.33402(19) 0.06363(18) 0.0171(4) Uani 1 1 d .
C7 C -0.04174(17) 0.26060(19) 0.25622(19) 0.0171(4) Uani 1 1 d .
C8 C -0.16533(18) 0.1887(2) 0.21717(19) 0.0197(4) Uani 1 1 d .
C9 C -0.21517(19) 0.1604(2) 0.2985(2) 0.0242(5) Uani 1 1 d .
H9A H -0.2980 0.1098 0.2724 0.029 Uiso 1 1 calc R
C10 C -0.1459(2) 0.2047(2) 0.4163(2) 0.0264(5) Uani 1 1 d .
H10A H -0.1817 0.1885 0.4720 0.032 Uiso 1 1 calc R
C11 C -0.02442(19) 0.2727(2) 0.4530(2) 0.0233(5) Uani 1 1 d .
H11A H 0.0227 0.3012 0.5335 0.028 Uiso 1 1 calc R
C12 C 0.03033(18) 0.3005(2) 0.37441(19) 0.0187(4) Uani 1 1 d .
C13 C 0.23871(17) 0.29861(19) 0.00533(19) 0.0175(4) Uani 1 1 d .
C14 C 0.35569(18) 0.3485(2) 0.0831(2) 0.0201(4) Uani 1 1 d .
C15 C 0.44202(19) 0.3262(2) 0.0285(2) 0.0259(5) Uani 1 1 d .
H15A H 0.5213 0.3594 0.0794 0.031 Uiso 1 1 calc R
C16 C 0.4143(2) 0.2570(2) -0.0978(2) 0.0290(5) Uani 1 1 d .
H16A H 0.4747 0.2438 -0.1331 0.035 Uiso 1 1 calc R
C17 C 0.2991(2) 0.2064(2) -0.1738(2) 0.0262(5) Uani 1 1 d .
H17A H 0.2807 0.1571 -0.2608 0.031 Uiso 1 1 calc R
C18 C 0.20960(18) 0.2273(2) -0.1236(2) 0.0204(4) Uani 1 1 d .
C19 C -0.24575(18) 0.1449(2) 0.0911(2) 0.0227(5) Uani 1 1 d .
H19A H -0.1949 0.1515 0.0382 0.027 Uiso 1 1 calc R
C20 C -0.33689(19) 0.0031(2) 0.0268(2) 0.0283(5) Uani 1 1 d .
H20A H -0.2953 -0.0535 0.0199 0.042 Uiso 1 1 calc R
H20B H -0.3835 -0.0227 -0.0558 0.042 Uiso 1 1 calc R
H20C H -0.3900 -0.0049 0.0754 0.042 Uiso 1 1 calc R
C21 C -0.3107(2) 0.2341(2) 0.1022(2) 0.0332(6) Uani 1 1 d .
H21A H -0.3619 0.2044 0.0201 0.050 Uiso 1 1 calc R
H21B H -0.2524 0.3234 0.1375 0.050 Uiso 1 1 calc R
H21C H -0.3592 0.2312 0.1559 0.050 Uiso 1 1 calc R
C22 C 0.16501(18) 0.3735(2) 0.4174(2) 0.0230(5) Uani 1 1 d .
H22A H 0.1909 0.3469 0.3424 0.028 Uiso 1 1 calc R
C23 C 0.2303(2) 0.3408(2) 0.5025(2) 0.0273(5) Uani 1 1 d .
H23A H 0.2073 0.2467 0.4609 0.041 Uiso 1 1 calc R
H23B H 0.2094 0.3694 0.5787 0.041 Uiso 1 1 calc R
H23C H 0.3162 0.3854 0.5224 0.041 Uiso 1 1 calc R
C24 C 0.2014(2) 0.5206(2) 0.4810(2) 0.0372(6) Uani 1 1 d .
H24A H 0.1599 0.5409 0.4256 0.056 Uiso 1 1 calc R
H24B H 0.2873 0.5648 0.5011 0.056 Uiso 1 1 calc R
H24C H 0.1803 0.5501 0.5571 0.056 Uiso 1 1 calc R
C25 C 0.38984(19) 0.4280(2) 0.2228(2) 0.0248(5) Uani 1 1 d .
H25A H 0.3146 0.4178 0.2441 0.030 Uiso 1 1 calc R
C26 C 0.4593(2) 0.3796(2) 0.2876(2) 0.0319(6) Uani 1 1 d .
H26A H 0.4791 0.4333 0.3772 0.048 Uiso 1 1 calc R
H26B H 0.5326 0.3856 0.2664 0.048 Uiso 1 1 calc R
H26C H 0.4108 0.2889 0.2607 0.048 Uiso 1 1 calc R
C27 C 0.4586(2) 0.5727(2) 0.2704(2) 0.0388(6) Uani 1 1 d .
H27A H 0.4793 0.6219 0.3604 0.058 Uiso 1 1 calc R
H27B H 0.4091 0.6031 0.2335 0.058 Uiso 1 1 calc R
H27C H 0.5313 0.5855 0.2475 0.058 Uiso 1 1 calc R
C28 C 0.08506(19) 0.1777(2) -0.2082(2) 0.0242(5) Uani 1 1 d .
H28A H 0.0305 0.1814 -0.1575 0.029 Uiso 1 1 calc R
C29 C 0.0809(2) 0.2661(3) -0.2602(2) 0.0349(6) Uani 1 1 d .
H29A H 0.1101 0.3559 -0.1920 0.052 Uiso 1 1 calc R
H29B H -0.0011 0.2381 -0.3084 0.052 Uiso 1 1 calc R
H29C H 0.1310 0.2612 -0.3134 0.052 Uiso 1 1 calc R
C30 C 0.0403(2) 0.0371(2) -0.3127(2) 0.0294(5) Uani 1 1 d .
H30A H 0.0433 -0.0184 -0.2778 0.044 Uiso 1 1 calc R
H30B H 0.0906 0.0314 -0.3658 0.044 Uiso 1 1 calc R
H30C H -0.0417 0.0081 -0.3615 0.044 Uiso 1 1 calc R
C31 C 0.17579(17) 0.08082(19) 0.18570(18) 0.0172(4) Uani 1 1 d .
C32 C 0.23602(18) 0.0575(2) 0.2486(2) 0.0211(5) Uani 1 1 d .
C33 C 0.2858(3) -0.1627(3) 0.2450(3) 0.0581(9) Uani 1 1 d .
H33A H 0.2961 -0.1868 0.1638 0.087 Uiso 1 1 calc R
H33B H 0.2023 -0.2078 0.2343 0.087 Uiso 1 1 calc R
H33C H 0.3352 -0.1877 0.2889 0.087 Uiso 1 1 calc R
C34 C 0.4870(2) 0.1057(4) 0.3540(3) 0.0576(9) Uani 1 1 d .
H34A H 0.4964 0.0807 0.2725 0.086 Uiso 1 1 calc R
H34B H 0.5394 0.0845 0.3994 0.086 Uiso 1 1 calc R
H34C H 0.5077 0.1993 0.3999 0.086 Uiso 1 1 calc R
C35 C 0.3120(2) 0.0619(2) 0.4898(2) 0.0312(5) Uani 1 1 d .
H35A H 0.3629 0.0388 0.5344 0.047 Uiso 1 1 calc R
H35B H 0.2289 0.0155 0.4795 0.047 Uiso 1 1 calc R
H35C H 0.3343 0.1558 0.5368 0.047 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_3
C31 Ge1 C1 114.21(8) .
C31 Ge1 Ge1 109.68(6) 2
C1 Ge1 Ge1 118.05(6) 2
C32 Si1 C34 107.77(11) .
C32 Si1 C35 110.76(10) .
C34 Si1 C35 109.84(13) .
C32 Si1 C33 107.67(12) .
C34 Si1 C33 111.17(17) .
C35 Si1 C33 109.60(13) .
C6 C1 C2 119.65(18) .
C6 C1 Ge1 114.33(14) .
C2 C1 Ge1 125.82(15) .
C3 C2 C1 118.58(19) .
C3 C2 C7 115.86(18) .
C1 C2 C7 125.29(18) .
C4 C3 C2 121.27(19) .
C4 C3 H3A 119.4 .
C2 C3 H3A 119.4 .
C3 C4 C5 120.08(19) .
C3 C4 H4A 120.0 .
C5 C4 H4A 120.0 .
C4 C5 C6 120.2(2) .
C4 C5 H5A 119.9 .
C6 C5 H5A 119.9 .
C5 C6 C1 119.93(18) .
C5 C6 C13 117.75(18) .
C1 C6 C13 122.15(17) .
C8 C7 C12 120.46(19) .
C8 C7 C2 120.84(18) .
C12 C7 C2 118.18(17) .
C9 C8 C7 118.66(19) .
C9 C8 C19 119.35(18) .
C7 C8 C19 121.96(19) .
C10 C9 C8 121.1(2) .
C10 C9 H9A 119.5 .
C8 C9 H9A 119.5 .
C9 C10 C11 119.9(2) .
C9 C10 H10A 120.1 .
C11 C10 H10A 120.1 .
C10 C11 C12 121.4(2) .
C10 C11 H11A 119.3 .
C12 C11 H11A 119.3 .
C11 C12 C7 118.42(19) .
C11 C12 C22 119.84(19) .
C7 C12 C22 121.74(18) .
C18 C13 C14 120.94(18) .
C18 C13 C6 120.58(18) .
C14 C13 C6 118.25(18) .
C15 C14 C13 118.3(2) .
C15 C14 C25 119.76(19) .
C13 C14 C25 121.91(18) .
C16 C15 C14 121.1(2) .
C16 C15 H15A 119.5 .
C14 C15 H15A 119.5 .
C15 C16 C17 120.5(2) .
C15 C16 H16A 119.8 .
C17 C16 H16A 119.8 .
C16 C17 C18 120.6(2) .
C16 C17 H17A 119.7 .
C18 C17 H17A 119.7 .
C17 C18 C13 118.57(19) .
C17 C18 C28 120.06(19) .
C13 C18 C28 121.33(18) .
C8 C19 C20 112.19(18) .
C8 C19 C21 110.70(18) .
C20 C19 C21 109.64(18) .
C8 C19 H19A 108.1 .
C20 C19 H19A 108.1 .
C21 C19 H19A 108.1 .
C19 C20 H20A 109.5 .
C19 C20 H20B 109.5 .
H20A C20 H20B 109.5 .
C19 C20 H20C 109.5 .
H20A C20 H20C 109.5 .
H20B C20 H20C 109.5 .
C19 C21 H21A 109.5 .
C19 C21 H21B 109.5 .
H21A C21 H21B 109.5 .
C19 C21 H21C 109.5 .
H21A C21 H21C 109.5 .
H21B C21 H21C 109.5 .
C12 C22 C23 112.98(18) .
C12 C22 C24 110.98(18) .
C23 C22 C24 109.88(18) .
C12 C22 H22A 107.6 .
C23 C22 H22A 107.6 .
C24 C22 H22A 107.6 .
C22 C23 H23A 109.5 .
C22 C23 H23B 109.5 .
H23A C23 H23B 109.5 .
C22 C23 H23C 109.5 .
H23A C23 H23C 109.5 .
H23B C23 H23C 109.5 .
C22 C24 H24A 109.5 .
C22 C24 H24B 109.5 .
H24A C24 H24B 109.5 .
C22 C24 H24C 109.5 .
H24A C24 H24C 109.5 .
H24B C24 H24C 109.5 .
C14 C25 C27 110.90(19) .
C14 C25 C26 112.36(18) .
C27 C25 C26 111.10(19) .
C14 C25 H25A 107.4 .
C27 C25 H25A 107.4 .
C26 C25 H25A 107.4 .
C25 C26 H26A 109.5 .
C25 C26 H26B 109.5 .
H26A C26 H26B 109.5 .
C25 C26 H26C 109.5 .
H26A C26 H26C 109.5 .
H26B C26 H26C 109.5 .
C25 C27 H27A 109.5 .
C25 C27 H27B 109.5 .
H27A C27 H27B 109.5 .
C25 C27 H27C 109.5 .
H27A C27 H27C 109.5 .
H27B C27 H27C 109.5 .
C18 C28 C29 110.11(19) .
C18 C28 C30 112.56(18) .
C29 C28 C30 110.49(19) .
C18 C28 H28A 107.8 .
C29 C28 H28A 107.8 .
C30 C28 H28A 107.8 .
C28 C29 H29A 109.5 .
C28 C29 H29B 109.5 .
H29A C29 H29B 109.5 .
C28 C29 H29C 109.5 .
H29A C29 H29C 109.5 .
H29B C29 H29C 109.5 .
C28 C30 H30A 109.5 .
C28 C30 H30B 109.5 .
H30A C30 H30B 109.5 .
C28 C30 H30C 109.5 .
H30A C30 H30C 109.5 .
H30B C30 H30C 109.5 .
C32 C31 Ge1 167.38(18) .
C31 C32 Si1 176.14(19) .
Si1 C33 H33A 109.5 .
Si1 C33 H33B 109.5 .
H33A C33 H33B 109.5 .
Si1 C33 H33C 109.5 .
H33A C33 H33C 109.5 .
H33B C33 H33C 109.5 .
Si1 C34 H34A 109.5 .
Si1 C34 H34B 109.5 .
H34A C34 H34B 109.5 .
Si1 C34 H34C 109.5 .
H34A C34 H34C 109.5 .
H34B C34 H34C 109.5 .
Si1 C35 H35A 109.5 .
Si1 C35 H35B 109.5 .
H35A C35 H35B 109.5 .
Si1 C35 H35C 109.5 .
H35A C35 H35C 109.5 .
H35B C35 H35C 109.5 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ge1 C31 1.911(2) .
Ge1 C1 1.9725(19) .
Ge1 Ge1 2.3224(4) 2
Si1 C32 1.843(2) .
Si1 C34 1.852(3) .
Si1 C35 1.858(2) .
Si1 C33 1.858(3) .
C1 C6 1.406(3) .
C1 C2 1.410(3) .
C2 C3 1.403(3) .
C2 C7 1.501(3) .
C3 C4 1.379(3) .
C3 H3A 0.9500 .
C4 C5 1.385(3) .
C4 H4A 0.9500 .
C5 C6 1.396(3) .
C5 H5A 0.9500 .
C6 C13 1.507(3) .
C7 C8 1.409(3) .
C7 C12 1.414(3) .
C8 C9 1.396(3) .
C8 C19 1.521(3) .
C9 C10 1.382(3) .
C9 H9A 0.9500 .
C10 C11 1.382(3) .
C10 H10A 0.9500 .
C11 C12 1.392(3) .
C11 H11A 0.9500 .
C12 C22 1.527(3) .
C13 C18 1.404(3) .
C13 C14 1.412(3) .
C14 C15 1.394(3) .
C14 C25 1.520(3) .
C15 C16 1.376(3) .
C15 H15A 0.9500 .
C16 C17 1.385(3) .
C16 H16A 0.9500 .
C17 C18 1.399(3) .
C17 H17A 0.9500 .
C18 C28 1.520(3) .
C19 C20 1.538(3) .
C19 C21 1.539(3) .
C19 H19A 1.0000 .
C20 H20A 0.9800 .
C20 H20B 0.9800 .
C20 H20C 0.9800 .
C21 H21A 0.9800 .
C21 H21B 0.9800 .
C21 H21C 0.9800 .
C22 C23 1.528(3) .
C22 C24 1.532(3) .
C22 H22A 1.0000 .
C23 H23A 0.9800 .
C23 H23B 0.9800 .
C23 H23C 0.9800 .
C24 H24A 0.9800 .
C24 H24B 0.9800 .
C24 H24C 0.9800 .
C25 C27 1.531(3) .
C25 C26 1.531(3) .
C25 H25A 1.0000 .
C26 H26A 0.9800 .
C26 H26B 0.9800 .
C26 H26C 0.9800 .
C27 H27A 0.9800 .
C27 H27B 0.9800 .
C27 H27C 0.9800 .
C28 C29 1.526(3) .
C28 C30 1.527(3) .
C28 H28A 1.0000 .
C29 H29A 0.9800 .
C29 H29B 0.9800 .
C29 H29C 0.9800 .
C30 H30A 0.9800 .
C30 H30B 0.9800 .
C30 H30C 0.9800 .
C31 C32 1.205(3) .
C33 H33A 0.9800 .
C33 H33B 0.9800 .
C33 H33C 0.9800 .
C34 H34A 0.9800 .
C34 H34B 0.9800 .
C34 H34C 0.9800 .
C35 H35A 0.9800 .
C35 H35B 0.9800 .
C35 H35C 0.9800 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
C31 Ge1 C1 C6 110.64(15) .
Ge1 Ge1 C1 C6 -118.23(13) 2
C31 Ge1 C1 C2 -74.63(18) .
Ge1 Ge1 C1 C2 56.50(18) 2
C6 C1 C2 C3 5.5(3) .
Ge1 C1 C2 C3 -168.96(15) .
C6 C1 C2 C7 -168.20(18) .
Ge1 C1 C2 C7 17.3(3) .
C1 C2 C3 C4 -1.4(3) .
C7 C2 C3 C4 172.95(19) .
C2 C3 C4 C5 -3.2(3) .
C3 C4 C5 C6 3.5(3) .
C4 C5 C6 C1 0.7(3) .
C4 C5 C6 C13 -174.76(19) .
C2 C1 C6 C5 -5.2(3) .
Ge1 C1 C6 C5 169.86(15) .
C2 C1 C6 C13 170.01(18) .
Ge1 C1 C6 C13 -14.9(2) .
C3 C2 C7 C8 78.7(2) .
C1 C2 C7 C8 -107.4(2) .
C3 C2 C7 C12 -93.1(2) .
C1 C2 C7 C12 80.8(3) .
C12 C7 C8 C9 1.4(3) .
C2 C7 C8 C9 -170.14(18) .
C12 C7 C8 C19 179.60(18) .
C2 C7 C8 C19 8.0(3) .
C7 C8 C9 C10 1.8(3) .
C19 C8 C9 C10 -176.4(2) .
C8 C9 C10 C11 -3.3(3) .
C9 C10 C11 C12 1.4(3) .
C10 C11 C12 C7 1.8(3) .
C10 C11 C12 C22 -178.8(2) .
C8 C7 C12 C11 -3.2(3) .
C2 C7 C12 C11 168.59(18) .
C8 C7 C12 C22 177.37(19) .
C2 C7 C12 C22 -10.8(3) .
C5 C6 C13 C18 -85.2(2) .
C1 C6 C13 C18 99.4(2) .
C5 C6 C13 C14 89.4(2) .
C1 C6 C13 C14 -86.0(2) .
C18 C13 C14 C15 0.6(3) .
C6 C13 C14 C15 -173.96(18) .
C18 C13 C14 C25 178.92(19) .
C6 C13 C14 C25 4.4(3) .
C13 C14 C15 C16 -0.3(3) .
C25 C14 C15 C16 -178.6(2) .
C14 C15 C16 C17 -0.7(4) .
C15 C16 C17 C18 1.4(4) .
C16 C17 C18 C13 -1.1(3) .
C16 C17 C18 C28 176.6(2) .
C14 C13 C18 C17 0.1(3) .
C6 C13 C18 C17 174.49(19) .
C14 C13 C18 C28 -177.58(19) .
C6 C13 C18 C28 -3.1(3) .
C9 C8 C19 C20 -46.0(3) .
C7 C8 C19 C20 135.9(2) .
C9 C8 C19 C21 76.9(2) .
C7 C8 C19 C21 -101.3(2) .
C11 C12 C22 C23 33.9(3) .
C7 C12 C22 C23 -146.67(19) .
C11 C12 C22 C24 -90.0(2) .
C7 C12 C22 C24 89.4(2) .
C15 C14 C25 C27 74.2(3) .
C13 C14 C25 C27 -104.1(2) .
C15 C14 C25 C26 -50.9(3) .
C13 C14 C25 C26 130.8(2) .
C17 C18 C28 C29 -76.8(3) .
C13 C18 C28 C29 100.8(2) .
C17 C18 C28 C30 47.0(3) .
C13 C18 C28 C30 -135.4(2) .
C1 Ge1 C31 C32 -147.7(8) .
Ge1 Ge1 C31 C32 77.2(8) 2
