#------------------------------------------------------------------------------
#$Date: 2016-03-21 07:19:46 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178559 $
#$URL: svn://www.crystallography.net/cod/cif/4/06/67/4066773.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4066773
loop_
_publ_author_name
'Borguet, Yannick'
'Sauvage, Xavier'
'Zaragoza, Guillermo'
'Demonceau, Albert'
'Delaude, Lionel'
_publ_section_title
;
 Homobimetallic Ruthenium−Arene Complexes Bearing Vinylidene
 Ligands: Synthesis, Characterization, and Catalytic Application in Olefin
 Metathesis
;
_journal_issue                   24
_journal_name_full               Organometallics
_journal_page_first              6675
_journal_paper_doi               10.1021/om1006177
_journal_volume                  29
_journal_year                    2010
_chemical_compound_source        'synthesis as described'
_chemical_formula_moiety         '2(C36 H52 Cl5 P Ru2), 2(C H2 Cl2)'
_chemical_formula_sum            'C74 H108 Cl14 P2 Ru4'
_chemical_formula_weight         1960.12
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_conform_dict_location     ftp://ftp.iucr.org/pub/cif_core.dic
_audit_conform_dict_name         cif_core.dic
_audit_conform_dict_version      2.3
_audit_creation_date             2010-05-31T14:02:21-00:00
_audit_creation_method           'WinGX routine CIF_UPDATE'
_cell_angle_alpha                97.864(2)
_cell_angle_beta                 100.105(2)
_cell_angle_gamma                100.515(2)
_cell_formula_units_Z            2
_cell_length_a                   10.0332(5)
_cell_length_b                   19.4865(8)
_cell_length_c                   22.0613(10)
_cell_measurement_reflns_used    1941
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      26.4
_cell_measurement_theta_min      2.62
_cell_measurement_wavelength     0.71073
_cell_volume                     4111.0(3)
_computing_cell_refinement       'APPEX2 (BRUKER AXS, 2005)'
_computing_data_collection       'APPEX2 (BRUKER AXS, 2005)'
_computing_data_reduction        'APPEX2 (BRUKER AXS, 2005)'
_computing_molecular_graphics    'Ortep-3 for Windows (Farrugia, 1997)'
_computing_publication_material  'WinGX publication routines (Farrugia, 1999)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'DIRDIF 2007 (Beurskens et all, 2008)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'BRUKER APPEX-II CCD'
_diffrn_measurement_method       'omega and phi scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_probe          x-ray
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.0651
_diffrn_reflns_av_unetI/netI     0.0411
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       23
_diffrn_reflns_limit_k_min       -24
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_number            129087
_diffrn_reflns_theta_full        26.02
_diffrn_reflns_theta_max         26.02
_diffrn_reflns_theta_min         0.95
_exptl_absorpt_coefficient_mu    1.255
_exptl_absorpt_correction_T_max  0.904
_exptl_absorpt_correction_T_min  0.794
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'BRUKER SADABS'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.583
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             1992
_exptl_crystal_size_max          0.31
_exptl_crystal_size_mid          0.1
_exptl_crystal_size_min          0.08
_refine_diff_density_max         0.978
_refine_diff_density_min         -0.683
_refine_diff_density_rms         0.095
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.919
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     885
_refine_ls_number_reflns         16116
_refine_ls_number_restraints     15
_refine_ls_restrained_S_all      0.919
_refine_ls_R_factor_all          0.0459
_refine_ls_R_factor_gt           0.0321
_refine_ls_shift/su_max          0.011
_refine_ls_shift/su_mean         0
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0233P)²+10.8174P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.065
_refine_ls_wR_factor_ref         0.0721
_reflns_number_gt                13114
_reflns_number_total             16116
_reflns_threshold_expression     >2σ(I)
_cod_data_source_file            om1006177_si_002.cif
_cod_data_source_block           Complex8
_cod_database_code               4066773
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.8947(3) 0.18972(17) 0.34332(14) 0.0181(7) Uani 1 1 d . . .
C2 C 0.9253(3) 0.25893(17) 0.34870(15) 0.0205(7) Uani 1 1 d . . .
H2 H 0.9769 0.2783 0.3205 0.025 Uiso 1 1 calc R . .
C3 C 0.8858(3) 0.30866(18) 0.39495(15) 0.0230(7) Uani 1 1 d . . .
C4 C 0.9264(4) 0.38211(18) 0.39804(16) 0.0256(8) Uani 1 1 d . . .
H4 H 0.9814 0.3995 0.3702 0.031 Uiso 1 1 calc R . .
C5 C 0.8881(4) 0.42952(19) 0.44059(16) 0.0288(8) Uani 1 1 d . . .
H5 H 0.9174 0.4791 0.4424 0.035 Uiso 1 1 calc R . .
C6 C 0.8073(4) 0.40451(19) 0.48035(16) 0.0278(8) Uani 1 1 d . . .
C7 C 0.7684(4) 0.33288(19) 0.48016(17) 0.0284(8) Uani 1 1 d . . .
H7 H 0.7144 0.3162 0.5086 0.034 Uiso 1 1 calc R . .
C8 C 0.8088(3) 0.28583(18) 0.43822(16) 0.0244(8) Uani 1 1 d . . .
H8 H 0.7837 0.2365 0.4387 0.029 Uiso 1 1 calc R . .
C9 C 1.2047(3) -0.07155(18) 0.39463(17) 0.0253(8) Uani 1 1 d . A 1
C10 C 1.1865(3) -0.04871(19) 0.45704(17) 0.0253(8) Uani 1 1 d . A 1
H10 H 1.1301 -0.0803 0.476 0.03 Uiso 1 1 calc R A 1
C11 C 1.2501(3) 0.0187(2) 0.48998(16) 0.0268(8) Uani 1 1 d . A 1
H11 H 1.2364 0.0321 0.5311 0.032 Uiso 1 1 calc R A 1
C12 C 1.3354(3) 0.06837(18) 0.46358(15) 0.0207(7) Uani 1 1 d . A 1
C13 C 1.3525(3) 0.04605(18) 0.40223(15) 0.0204(7) Uani 1 1 d . A 1
H13 H 1.4082 0.0779 0.3832 0.024 Uiso 1 1 calc R A 1
C14 C 1.2884(3) -0.02282(18) 0.36845(16) 0.0231(7) Uani 1 1 d . A 1
H14 H 1.3025 -0.0362 0.3274 0.028 Uiso 1 1 calc R A 1
C15 C 1.1321(4) -0.1423(2) 0.3591(2) 0.0384(10) Uani 1 1 d . A 1
H15A H 1.1343 -0.1438 0.3148 0.058 Uiso 1 1 calc R A 1
H15B H 1.0357 -0.1516 0.3642 0.058 Uiso 1 1 calc R A 1
H15C H 1.1782 -0.1784 0.3749 0.058 Uiso 1 1 calc R A 1
C16 C 1.3931(4) 0.14261(19) 0.49986(17) 0.0290(8) Uani 1 1 d . A 1
H16 H 1.3228 0.1557 0.5238 0.035 Uiso 1 1 calc R A 1
C17 C 1.4228(4) 0.1987(2) 0.4596(2) 0.0377(10) Uani 1 1 d . A 1
H17A H 1.497 0.1894 0.4381 0.057 Uiso 1 1 calc R A 1
H17B H 1.4517 0.2456 0.4861 0.057 Uiso 1 1 calc R A 1
H17C H 1.339 0.1971 0.4286 0.057 Uiso 1 1 calc R A 1
C18 C 1.5240(4) 0.1419(2) 0.5475(2) 0.0497(12) Uani 1 1 d . A 1
H18A H 1.5014 0.1074 0.5746 0.075 Uiso 1 1 calc R A 1
H18B H 1.5594 0.1892 0.5731 0.075 Uiso 1 1 calc R A 1
H18C H 1.5946 0.1287 0.5254 0.075 Uiso 1 1 calc R A 1
C19 C 0.6509(3) -0.02656(17) 0.22845(15) 0.0210(7) Uani 1 1 d . . .
H19 H 0.7359 -0.0468 0.236 0.025 Uiso 1 1 calc R . .
C20 C 0.5602(4) -0.05697(17) 0.27208(18) 0.0268(8) Uani 1 1 d . . .
H20A H 0.6055 -0.0369 0.3161 0.032 Uiso 1 1 calc R . .
H20B H 0.4693 -0.0433 0.2636 0.032 Uiso 1 1 calc R . .
C21 C 0.5386(4) -0.13802(18) 0.26199(18) 0.0310(9) Uani 1 1 d . . .
H21A H 0.6288 -0.1514 0.2742 0.037 Uiso 1 1 calc R . .
H21B H 0.4771 -0.1567 0.2892 0.037 Uiso 1 1 calc R . .
C22 C 0.4744(4) -0.17150(19) 0.1937(2) 0.0391(10) Uani 1 1 d . . .
H22A H 0.4706 -0.2232 0.1881 0.047 Uiso 1 1 calc R . .
H22B H 0.3784 -0.1643 0.1834 0.047 Uiso 1 1 calc R . .
C23 C 0.5583(4) -0.13903(18) 0.14955(18) 0.0347(9) Uani 1 1 d . . .
H23A H 0.5101 -0.1587 0.1058 0.042 Uiso 1 1 calc R . .
H23B H 0.6501 -0.1519 0.156 0.042 Uiso 1 1 calc R . .
C24 C 0.5780(4) -0.05825(18) 0.16029(17) 0.0312(9) Uani 1 1 d . . .
H24A H 0.4867 -0.0451 0.1512 0.037 Uiso 1 1 calc R . .
H24B H 0.6344 -0.0387 0.1316 0.037 Uiso 1 1 calc R . .
C25 C 0.5553(3) 0.10865(16) 0.25032(14) 0.0172(7) Uani 1 1 d . . .
H25 H 0.4961 0.0775 0.2721 0.021 Uiso 1 1 calc R . .
C26 C 0.4665(3) 0.10445(18) 0.18505(15) 0.0235(7) Uani 1 1 d . . .
H26A H 0.5165 0.1375 0.1622 0.028 Uiso 1 1 calc R . .
H26B H 0.4507 0.0559 0.1611 0.028 Uiso 1 1 calc R . .
C27 C 0.3272(3) 0.12349(18) 0.19011(17) 0.0246(8) Uani 1 1 d . . .
H27A H 0.2725 0.1211 0.1476 0.03 Uiso 1 1 calc R . .
H27B H 0.2749 0.0884 0.2105 0.03 Uiso 1 1 calc R . .
C28 C 0.3453(3) 0.19749(17) 0.22761(16) 0.0226(7) Uani 1 1 d . . .
H28A H 0.3868 0.2333 0.2047 0.027 Uiso 1 1 calc R . .
H28B H 0.2538 0.2065 0.2329 0.027 Uiso 1 1 calc R . .
C29 C 0.4383(3) 0.20435(17) 0.29134(15) 0.0210(7) Uani 1 1 d . . .
H29A H 0.3897 0.1735 0.3163 0.025 Uiso 1 1 calc R . .
H29B H 0.4556 0.2539 0.3134 0.025 Uiso 1 1 calc R . .
C30 C 0.5771(3) 0.18405(16) 0.28728(14) 0.0172(7) Uani 1 1 d . . .
H30A H 0.631 0.1867 0.33 0.021 Uiso 1 1 calc R . .
H30B H 0.6309 0.2181 0.2665 0.021 Uiso 1 1 calc R . .
C31 C 0.7780(3) 0.09543(17) 0.18052(14) 0.0187(7) Uani 1 1 d . . .
H31 H 0.6961 0.0819 0.1449 0.022 Uiso 1 1 calc R . .
C32 C 0.8342(4) 0.17494(18) 0.18496(17) 0.0262(8) Uani 1 1 d . . .
H32A H 0.9205 0.1904 0.2174 0.031 Uiso 1 1 calc R . .
H32B H 0.7656 0.2018 0.1973 0.031 Uiso 1 1 calc R . .
C33 C 0.8638(4) 0.19054(19) 0.12168(17) 0.0299(8) Uani 1 1 d . . .
H33A H 0.7758 0.1786 0.0903 0.036 Uiso 1 1 calc R . .
H33B H 0.9028 0.2418 0.1256 0.036 Uiso 1 1 calc R . .
C34 C 0.9645(4) 0.14850(19) 0.09930(17) 0.0291(8) Uani 1 1 d . . .
H34A H 1.0566 0.1652 0.1275 0.035 Uiso 1 1 calc R . .
H34B H 0.9744 0.1566 0.0568 0.035 Uiso 1 1 calc R . .
C35 C 0.9148(4) 0.06955(19) 0.09796(15) 0.0274(8) Uani 1 1 d . . .
H35A H 0.9863 0.044 0.0869 0.033 Uiso 1 1 calc R . .
H35B H 0.8293 0.0514 0.0654 0.033 Uiso 1 1 calc R . .
C36 C 0.8856(4) 0.05481(18) 0.16144(15) 0.0234(7) Uani 1 1 d . . .
H36A H 0.8507 0.0034 0.1588 0.028 Uiso 1 1 calc R . .
H36B H 0.9725 0.0695 0.1935 0.028 Uiso 1 1 calc R . .
C37 C 0.8178(3) 0.71272(16) 0.20063(13) 0.0148(6) Uani 1 1 d . . .
C38 C 0.8705(3) 0.78176(16) 0.21472(14) 0.0175(7) Uani 1 1 d . . .
H38 H 0.8487 0.8076 0.25 0.021 Uiso 1 1 calc R . .
C39 C 0.9601(3) 0.82103(16) 0.17973(15) 0.0179(7) Uani 1 1 d . . .
C40 C 1.0136(3) 0.89369(17) 0.19946(16) 0.0231(7) Uani 1 1 d . . .
H40 H 0.9931 0.9172 0.2363 0.028 Uiso 1 1 calc R . .
C41 C 1.0961(3) 0.93189(17) 0.16607(16) 0.0234(7) Uani 1 1 d . . .
H41 H 1.1326 0.9812 0.1801 0.028 Uiso 1 1 calc R . .
C42 C 1.1247(3) 0.89800(18) 0.11253(16) 0.0230(7) Uani 1 1 d . . .
C43 C 1.0742(4) 0.82577(19) 0.09209(17) 0.0277(8) Uani 1 1 d . . .
H43 H 1.0957 0.8027 0.0553 0.033 Uiso 1 1 calc R . .
C44 C 0.9929(4) 0.78777(18) 0.12535(15) 0.0242(8) Uani 1 1 d . . .
H44 H 0.9585 0.7383 0.1114 0.029 Uiso 1 1 calc R . .
C45 C 0.2644(3) 0.63488(18) 0.04123(15) 0.0223(7) Uani 1 1 d . . .
C46 C 0.2895(3) 0.57638(17) 0.00117(14) 0.0194(7) Uani 1 1 d . . .
H46 H 0.3184 0.584 -0.0366 0.023 Uiso 1 1 calc R . .
C47 C 0.2723(3) 0.50790(17) 0.01640(14) 0.0186(7) Uani 1 1 d . . .
H47 H 0.2903 0.4702 -0.011 0.022 Uiso 1 1 calc R . .
C48 C 0.2279(3) 0.49425(18) 0.07299(15) 0.0219(7) Uani 1 1 d . . .
C49 C 0.2029(3) 0.5523(2) 0.11184(16) 0.0256(8) Uani 1 1 d U . .
H49 H 0.1732 0.5451 0.1495 0.031 Uiso 1 1 calc R . .
C50 C 0.2210(3) 0.62137(19) 0.09632(16) 0.0261(8) Uani 1 1 d U . .
H50 H 0.2033 0.6591 0.1238 0.031 Uiso 1 1 calc R . .
C51 C 0.2921(4) 0.70797(18) 0.02553(18) 0.0306(9) Uani 1 1 d . . .
H51A H 0.2128 0.7136 -0.0049 0.046 Uiso 1 1 calc R . .
H51B H 0.3753 0.7149 0.0076 0.046 Uiso 1 1 calc R . .
H51C H 0.3063 0.7432 0.0636 0.046 Uiso 1 1 calc R . .
C52 C 0.2165(3) 0.42059(19) 0.08789(16) 0.0258(8) Uani 1 1 d . . .
H52 H 0.2891 0.3996 0.0709 0.031 Uiso 1 1 calc R . .
C53 C 0.0737(4) 0.3754(2) 0.05317(18) 0.0393(10) Uani 1 1 d . . .
H53A H 0.0004 0.3947 0.069 0.059 Uiso 1 1 calc R . .
H53B H 0.0672 0.3264 0.0601 0.059 Uiso 1 1 calc R . .
H53C H 0.0628 0.3764 0.0083 0.059 Uiso 1 1 calc R . .
C54 C 0.2386(4) 0.4177(2) 0.15768(17) 0.0358(9) Uani 1 1 d . . .
H54A H 0.3265 0.4494 0.1794 0.054 Uiso 1 1 calc R . .
H54B H 0.2413 0.3691 0.1639 0.054 Uiso 1 1 calc R . .
H54C H 0.1624 0.4327 0.1745 0.054 Uiso 1 1 calc R . .
C55 C 0.7915(3) 0.48943(16) 0.25776(15) 0.0187(7) Uani 1 1 d . . .
H55 H 0.849 0.4792 0.2959 0.022 Uiso 1 1 calc R . .
C56 C 0.8335(3) 0.44994(16) 0.20094(16) 0.0208(7) Uani 1 1 d . . .
H56A H 0.7879 0.4637 0.1623 0.025 Uiso 1 1 calc R . .
H56B H 0.9349 0.4642 0.2048 0.025 Uiso 1 1 calc R . .
C57 C 0.7926(4) 0.36929(17) 0.19593(18) 0.0276(8) Uani 1 1 d . . .
H57A H 0.8145 0.3457 0.1573 0.033 Uiso 1 1 calc R . .
H57B H 0.8469 0.3546 0.2321 0.033 Uiso 1 1 calc R . .
C58 C 0.6383(4) 0.34614(17) 0.19464(17) 0.0284(8) Uani 1 1 d . . .
H58A H 0.5838 0.3589 0.1575 0.034 Uiso 1 1 calc R . .
H58B H 0.6136 0.294 0.1916 0.034 Uiso 1 1 calc R . .
C59 C 0.6034(4) 0.38205(17) 0.25369(17) 0.0283(8) Uani 1 1 d . . .
H59A H 0.6552 0.3674 0.2905 0.034 Uiso 1 1 calc R . .
H59B H 0.5032 0.3663 0.2525 0.034 Uiso 1 1 calc R . .
C60 C 0.6395(3) 0.46293(17) 0.26077(16) 0.0209(7) Uani 1 1 d . . .
H60A H 0.6225 0.4844 0.3013 0.025 Uiso 1 1 calc R . .
H60B H 0.5788 0.4781 0.227 0.025 Uiso 1 1 calc R . .
C61 C 1.0320(3) 0.60301(16) 0.27190(15) 0.0172(7) Uani 1 1 d . . .
H61 H 1.0513 0.5901 0.2293 0.021 Uiso 1 1 calc R . .
C62 C 1.1027(3) 0.68135(17) 0.29348(17) 0.0234(7) Uani 1 1 d . . .
H62A H 1.0565 0.7103 0.2664 0.028 Uiso 1 1 calc R . .
H62B H 1.0931 0.6968 0.3369 0.028 Uiso 1 1 calc R . .
C63 C 1.2564(3) 0.69340(18) 0.29074(17) 0.0259(8) Uani 1 1 d . . .
H63A H 1.2656 0.6815 0.2468 0.031 Uiso 1 1 calc R . .
H63B H 1.3 0.7441 0.306 0.031 Uiso 1 1 calc R . .
C64 C 1.3310(3) 0.64861(19) 0.32997(16) 0.0267(8) Uani 1 1 d . . .
H64A H 1.3307 0.664 0.3746 0.032 Uiso 1 1 calc R . .
H64B H 1.4285 0.6554 0.3251 0.032 Uiso 1 1 calc R . .
C65 C 1.2612(3) 0.57066(19) 0.31019(17) 0.0276(8) Uani 1 1 d . . .
H65A H 1.3079 0.5427 0.3381 0.033 Uiso 1 1 calc R . .
H65B H 1.2711 0.554 0.2671 0.033 Uiso 1 1 calc R . .
C66 C 1.1067(3) 0.55795(19) 0.31266(18) 0.0283(8) Uani 1 1 d . . .
H66A H 1.0637 0.5072 0.2977 0.034 Uiso 1 1 calc R . .
H66B H 1.0967 0.5703 0.3564 0.034 Uiso 1 1 calc R . .
C67 C 0.7847(3) 0.62420(16) 0.33154(14) 0.0167(7) Uani 1 1 d . . .
H67 H 0.6833 0.6037 0.3252 0.02 Uiso 1 1 calc R . .
C68 C 0.8523(4) 0.6010(2) 0.39105(16) 0.0307(9) Uani 1 1 d . . .
H68A H 0.835 0.5486 0.3846 0.037 Uiso 1 1 calc R . .
H68B H 0.9537 0.6193 0.3993 0.037 Uiso 1 1 calc R . .
C69 C 0.7964(4) 0.6280(2) 0.44754(17) 0.0371(9) Uani 1 1 d . . .
H69A H 0.6963 0.6068 0.4408 0.045 Uiso 1 1 calc R . .
H69B H 0.8444 0.6131 0.4851 0.045 Uiso 1 1 calc R . .
C70 C 0.8177(4) 0.7080(2) 0.45816(16) 0.0319(9) Uani 1 1 d . . .
H70A H 0.9181 0.7293 0.4681 0.038 Uiso 1 1 calc R . .
H70B H 0.7779 0.7242 0.4942 0.038 Uiso 1 1 calc R . .
C71 C 0.7488(4) 0.73243(19) 0.40036(15) 0.0258(8) Uani 1 1 d . . .
H71A H 0.7691 0.7849 0.4073 0.031 Uiso 1 1 calc R . .
H71B H 0.6472 0.7157 0.3936 0.031 Uiso 1 1 calc R . .
C72 C 0.7988(4) 0.70463(17) 0.34169(15) 0.0232(7) Uani 1 1 d . . .
H72A H 0.7443 0.7177 0.3047 0.028 Uiso 1 1 calc R . .
H72B H 0.8972 0.7277 0.3456 0.028 Uiso 1 1 calc R . .
Cl1R Cl 0.74937(11) 0.46436(5) 0.53122(5) 0.0387(2) Uani 1 1 d . . .
Cl2R Cl 1.22286(9) 0.94628(5) 0.06863(4) 0.0334(2) Uani 1 1 d . . .
Cl1 Cl 0.68564(7) 0.08870(4) 0.39855(3) 0.01825(16) Uani 1 1 d . . .
P1 P 0.71374(8) 0.07128(4) 0.25001(4) 0.01535(17) Uani 1 1 d . . .
P2 P 0.83888(8) 0.58652(4) 0.26008(4) 0.01441(16) Uani 1 1 d . . .
Ru3 Ru 0.73371(2) 0.622862(13) 0.171409(11) 0.01266(6) Uani 1 1 d . . .
Ru4 Ru 0.40846(2) 0.582381(14) 0.094126(11) 0.01620(6) Uani 1 1 d . . .
Ru1 Ru 0.87015(2) 0.097204(13) 0.344777(11) 0.01416(6) Uani 1 1 d . . .
Ru2 Ru 1.13394(4) 0.02891(3) 0.400590(17) 0.01299(11) Uani 0.9333(17) 1 d P A 1
Ru2B Ru 1.1078(5) -0.0025(4) 0.3881(3) 0.01299(11) Uani 0.0667(17) 1 d P A 2
Cl2 Cl 1.08173(8) 0.08591(4) 0.31028(3) 0.01999(17) Uani 1 1 d . . .
Cl3 Cl 1.03699(8) 0.12105(4) 0.44810(3) 0.02045(17) Uani 1 1 d . . .
Cl4 Cl 0.89019(8) -0.03091(4) 0.36096(4) 0.01985(16) Uani 1 1 d . . .
C73 C 0.7264(4) 0.6553(2) 0.61992(19) 0.0420(10) Uani 1 1 d . . .
H73A H 0.7292 0.7068 0.6264 0.05 Uiso 1 1 calc R . .
H73B H 0.7948 0.646 0.5942 0.05 Uiso 1 1 calc R . .
Cl9 Cl 0.77296(11) 0.62960(6) 0.69303(5) 0.0431(2) Uani 1 1 d . . .
Cl10 Cl 0.56096(13) 0.60981(7) 0.57979(6) 0.0652(4) Uani 1 1 d . . .
Cl5 Cl 0.90689(7) 0.59515(4) 0.11838(3) 0.01767(16) Uani 1 1 d . . .
Cl6 Cl 0.51988(7) 0.63088(4) 0.20385(3) 0.01656(16) Uani 1 1 d . . .
Cl7 Cl 0.60989(8) 0.65962(4) 0.07569(4) 0.01989(17) Uani 1 1 d . . .
Cl8 Cl 0.56936(7) 0.50542(4) 0.11080(3) 0.01751(16) Uani 1 1 d . . .
C74 C 0.2676(14) 0.1963(6) -0.0043(5) 0.040(3) Uani 0.565(4) 1 d PD B 1
H74A H 0.182 0.2147 -0.0043 0.048 Uiso 0.565(4) 1 calc PR B 1
H74B H 0.3033 0.2081 -0.0415 0.048 Uiso 0.565(4) 1 calc PR B 1
Cl11 Cl 0.3906(3) 0.2395(2) 0.06282(16) 0.0594(11) Uani 0.565(4) 1 d PD B 1
Cl12 Cl 0.2262(2) 0.10564(10) -0.01107(10) 0.0505(7) Uani 0.565(4) 1 d PD B 1
C74B C 0.297(3) 0.1686(10) -0.0058(9) 0.101(10) Uani 0.435(4) 1 d PD B 2
H74C H 0.2002 0.1407 -0.0154 0.122 Uiso 0.435(4) 1 calc PR B 2
H74D H 0.313 0.1892 -0.0431 0.122 Uiso 0.435(4) 1 calc PR B 2
Cl1C Cl 0.3151(8) 0.2367(4) 0.0565(3) 0.100(2) Uani 0.435(4) 1 d PD B 2
Cl2C Cl 0.4090(5) 0.1124(2) 0.00865(16) 0.0934(16) Uani 0.435(4) 1 d PD B 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0 0 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.006 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
C2 C1 Ru1 172.6(3)
C1 C2 C3 124.9(3)
C1 C2 H2 117.6
C3 C2 H2 117.6
C8 C3 C4 117.1(3)
C8 C3 C2 122.2(3)
C4 C3 C2 120.7(3)
C5 C4 C3 121.3(3)
C5 C4 H4 119.3
C3 C4 H4 119.3
C6 C5 C4 119.5(3)
C6 C5 H5 120.3
C4 C5 H5 120.3
C5 C6 C7 121.1(3)
C5 C6 Cl1R 119.7(3)
C7 C6 Cl1R 119.2(3)
C8 C7 C6 119.1(3)
C8 C7 H7 120.5
C6 C7 H7 120.5
C7 C8 C3 121.8(3)
C7 C8 H8 119.1
C3 C8 H8 119.1
C14 C9 C10 117.3(3)
C14 C9 C15 121.9(3)
C10 C9 C15 120.7(3)
C14 C9 Ru2 69.98(19)
C10 C9 Ru2 69.61(19)
C15 C9 Ru2 129.2(2)
C11 C10 C9 121.2(3)
C11 C10 Ru2 71.1(2)
C9 C10 Ru2 71.83(19)
C11 C10 H10 119.4
C9 C10 H10 119.4
Ru2 C10 H10 130.4
C10 C11 C12 121.7(3)
C10 C11 Ru2 71.5(2)
C12 C11 Ru2 71.65(19)
C10 C11 H11 119.2
C12 C11 H11 119.2
Ru2 C11 H11 130.5
C13 C12 C11 117.1(3)
C13 C12 C16 123.7(3)
C11 C12 C16 119.1(3)
C13 C12 Ru2 69.72(18)
C11 C12 Ru2 70.03(18)
C16 C12 Ru2 127.2(2)
C12 C13 C14 121.6(3)
C12 C13 Ru2 72.21(18)
C14 C13 Ru2 71.32(18)
C12 C13 H13 119.2
C14 C13 H13 119.2
Ru2 C13 H13 129.9
C9 C14 C13 121.2(3)
C9 C14 Ru2 72.46(19)
C13 C14 Ru2 70.28(18)
C9 C14 H14 119.4
C13 C14 H14 119.4
Ru2 C14 H14 130.6
C12 C16 C17 114.5(3)
C12 C16 C18 108.6(3)
C17 C16 C18 110.8(3)
C12 C16 H16 107.6
C17 C16 H16 107.6
C18 C16 H16 107.6
C20 C19 C24 108.6(3)
C20 C19 P1 112.6(2)
C24 C19 P1 118.5(2)
C20 C19 H19 105.3
C24 C19 H19 105.3
P1 C19 H19 105.3
C21 C20 C19 110.4(3)
C21 C20 H20A 109.6
C19 C20 H20A 109.6
C21 C20 H20B 109.6
C19 C20 H20B 109.6
H20A C20 H20B 108.1
C22 C21 C20 111.6(3)
C22 C21 H21A 109.3
C20 C21 H21A 109.3
C22 C21 H21B 109.3
C20 C21 H21B 109.3
H21A C21 H21B 108
C23 C22 C21 111.2(3)
C23 C22 H22A 109.4
C21 C22 H22A 109.4
C23 C22 H22B 109.4
C21 C22 H22B 109.4
H22A C22 H22B 108
C22 C23 C24 111.5(3)
C22 C23 H23A 109.3
C24 C23 H23A 109.3
C22 C23 H23B 109.3
C24 C23 H23B 109.3
H23A C23 H23B 108
C23 C24 C19 110.2(3)
C23 C24 H24A 109.6
C19 C24 H24A 109.6
C23 C24 H24B 109.6
C19 C24 H24B 109.6
H24A C24 H24B 108.1
C26 C25 C30 108.9(3)
C26 C25 P1 114.4(2)
C30 C25 P1 116.3(2)
C26 C25 H25 105.4
C30 C25 H25 105.4
P1 C25 H25 105.4
C27 C26 C25 110.7(3)
C27 C26 H26A 109.5
C25 C26 H26A 109.5
C27 C26 H26B 109.5
C25 C26 H26B 109.5
H26A C26 H26B 108.1
C28 C27 C26 111.8(3)
C28 C27 H27A 109.3
C26 C27 H27A 109.3
C28 C27 H27B 109.3
C26 C27 H27B 109.3
H27A C27 H27B 107.9
C29 C28 C27 110.3(3)
C29 C28 H28A 109.6
C27 C28 H28A 109.6
C29 C28 H28B 109.6
C27 C28 H28B 109.6
H28A C28 H28B 108.1
C28 C29 C30 112.8(3)
C28 C29 H29A 109
C30 C29 H29A 109
C28 C29 H29B 109
C30 C29 H29B 109
H29A C29 H29B 107.8
C29 C30 C25 110.9(2)
C29 C30 H30A 109.5
C25 C30 H30A 109.5
C29 C30 H30B 109.5
C25 C30 H30B 109.5
H30A C30 H30B 108
C32 C31 C36 108.9(3)
C32 C31 P1 114.4(2)
C36 C31 P1 114.3(2)
C32 C31 H31 106.2
C36 C31 H31 106.2
P1 C31 H31 106.2
C31 C32 C33 110.2(3)
C31 C32 H32A 109.6
C33 C32 H32A 109.6
C31 C32 H32B 109.6
C33 C32 H32B 109.6
H32A C32 H32B 108.1
C34 C33 C32 111.8(3)
C34 C33 H33A 109.3
C32 C33 H33A 109.3
C34 C33 H33B 109.3
C32 C33 H33B 109.3
H33A C33 H33B 107.9
C33 C34 C35 111.2(3)
C33 C34 H34A 109.4
C35 C34 H34A 109.4
C33 C34 H34B 109.4
C35 C34 H34B 109.4
H34A C34 H34B 108
C34 C35 C36 111.4(3)
C34 C35 H35A 109.3
C36 C35 H35A 109.3
C34 C35 H35B 109.3
C36 C35 H35B 109.3
H35A C35 H35B 108
C31 C36 C35 110.3(3)
C31 C36 H36A 109.6
C35 C36 H36A 109.6
C31 C36 H36B 109.6
C35 C36 H36B 109.6
H36A C36 H36B 108.1
C38 C37 Ru3 171.6(3)
C37 C38 C39 124.7(3)
C37 C38 H38 117.7
C39 C38 H38 117.7
C40 C39 C44 118.2(3)
C40 C39 C38 120.2(3)
C44 C39 C38 121.6(3)
C41 C40 C39 120.9(3)
C41 C40 H40 119.5
C39 C40 H40 119.5
C42 C41 C40 119.5(3)
C42 C41 H41 120.2
C40 C41 H41 120.2
C41 C42 C43 120.9(3)
C41 C42 Cl2R 119.8(3)
C43 C42 Cl2R 119.3(3)
C44 C43 C42 119.6(3)
C44 C43 H43 120.2
C42 C43 H43 120.2
C43 C44 C39 120.9(3)
C43 C44 H44 119.5
C39 C44 H44 119.5
C50 C45 C46 117.4(3)
C50 C45 C51 122.3(3)
C46 C45 C51 120.1(3)
C50 C45 Ru4 70.19(19)
C46 C45 Ru4 69.87(18)
C51 C45 Ru4 128.3(2)
C47 C46 C45 121.6(3)
C47 C46 Ru4 71.16(17)
C45 C46 Ru4 71.65(18)
C47 C46 H46 119.2
C45 C46 H46 119.2
Ru4 C46 H46 130.8
C46 C47 C48 120.8(3)
C46 C47 Ru4 70.85(17)
C48 C47 Ru4 71.68(17)
C46 C47 H47 119.6
C48 C47 H47 119.6
Ru4 C47 H47 130.6
C49 C48 C47 116.9(3)
C49 C48 C52 124.7(3)
C47 C48 C52 118.4(3)
C49 C48 Ru4 69.77(18)
C47 C48 Ru4 69.74(17)
C52 C48 Ru4 129.3(2)
C48 C49 C50 122.0(3)
C48 C49 Ru4 72.35(18)
C50 C49 Ru4 70.86(18)
C48 C49 H49 119
C50 C49 H49 119
Ru4 C49 H49 130.6
C45 C50 C49 121.3(3)
C45 C50 Ru4 72.13(18)
C49 C50 Ru4 70.71(19)
C45 C50 H50 119.4
C49 C50 H50 119.4
Ru4 C50 H50 130.5
C45 C51 H51A 109.5
C45 C51 H51B 109.5
H51A C51 H51B 109.5
C45 C51 H51C 109.5
H51A C51 H51C 109.5
H51B C51 H51C 109.5
C48 C52 C54 114.2(3)
C48 C52 C53 108.5(3)
C54 C52 C53 110.6(3)
C48 C52 H52 107.7
C54 C52 H52 107.7
C53 C52 H52 107.7
C52 C53 H53A 109.5
C52 C53 H53B 109.5
H53A C53 H53B 109.5
C52 C53 H53C 109.5
H53A C53 H53C 109.5
H53B C53 H53C 109.5
C52 C54 H54A 109.5
C52 C54 H54B 109.5
H54A C54 H54B 109.5
C52 C54 H54C 109.5
H54A C54 H54C 109.5
H54B C54 H54C 109.5
C60 C55 C56 113.0(3)
C60 C55 P2 113.4(2)
C56 C55 P2 109.8(2)
C60 C55 H55 106.7
C56 C55 H55 106.7
P2 C55 H55 106.7
C57 C56 C55 111.7(3)
C57 C56 H56A 109.3
C55 C56 H56A 109.3
C57 C56 H56B 109.3
C55 C56 H56B 109.3
H56A C56 H56B 107.9
C58 C57 C56 110.6(3)
C58 C57 H57A 109.5
C56 C57 H57A 109.5
C58 C57 H57B 109.5
C56 C57 H57B 109.5
H57A C57 H57B 108.1
C59 C58 C57 110.0(3)
C59 C58 H58A 109.7
C57 C58 H58A 109.7
C59 C58 H58B 109.7
C57 C58 H58B 109.7
H58A C58 H58B 108.2
C58 C59 C60 111.8(3)
C58 C59 H59A 109.2
C60 C59 H59A 109.2
C58 C59 H59B 109.2
C60 C59 H59B 109.2
H59A C59 H59B 107.9
C59 C60 C55 111.2(3)
C59 C60 H60A 109.4
C55 C60 H60A 109.4
C59 C60 H60B 109.4
C55 C60 H60B 109.4
H60A C60 H60B 108
C62 C61 C66 109.4(3)
C62 C61 P2 113.4(2)
C66 C61 P2 117.4(2)
C62 C61 H61 105.2
C66 C61 H61 105.2
P2 C61 H61 105.2
C63 C62 C61 111.0(3)
C63 C62 H62A 109.4
C61 C62 H62A 109.4
C63 C62 H62B 109.4
C61 C62 H62B 109.4
H62A C62 H62B 108
C64 C63 C62 111.5(3)
C64 C63 H63A 109.3
C62 C63 H63A 109.3
C64 C63 H63B 109.3
C62 C63 H63B 109.3
H63A C63 H63B 108
C63 C64 C65 110.7(3)
C63 C64 H64A 109.5
C65 C64 H64A 109.5
C63 C64 H64B 109.5
C65 C64 H64B 109.5
H64A C64 H64B 108.1
C64 C65 C66 111.6(3)
C64 C65 H65A 109.3
C66 C65 H65A 109.3
C64 C65 H65B 109.3
C66 C65 H65B 109.3
H65A C65 H65B 108
C61 C66 C65 110.8(3)
C61 C66 H66A 109.5
C65 C66 H66A 109.5
C61 C66 H66B 109.5
C65 C66 H66B 109.5
H66A C66 H66B 108.1
C72 C67 C68 110.7(3)
C72 C67 P2 114.6(2)
C68 C67 P2 113.5(2)
C72 C67 H67 105.7
C68 C67 H67 105.7
P2 C67 H67 105.7
C69 C68 C67 111.9(3)
C69 C68 H68A 109.2
C67 C68 H68A 109.2
C69 C68 H68B 109.2
C67 C68 H68B 109.2
H68A C68 H68B 107.9
C70 C69 C68 110.9(3)
C70 C69 H69A 109.5
C68 C69 H69A 109.5
C70 C69 H69B 109.5
C68 C69 H69B 109.5
H69A C69 H69B 108
C69 C70 C71 110.6(3)
C69 C70 H70A 109.5
C71 C70 H70A 109.5
C69 C70 H70B 109.5
C71 C70 H70B 109.5
H70A C70 H70B 108.1
C70 C71 C72 112.1(3)
C70 C71 H71A 109.2
C72 C71 H71A 109.2
C70 C71 H71B 109.2
C72 C71 H71B 109.2
H71A C71 H71B 107.9
C67 C72 C71 112.3(3)
C67 C72 H72A 109.1
C71 C72 H72A 109.1
C67 C72 H72B 109.1
C71 C72 H72B 109.1
H72A C72 H72B 107.9
C31 P1 C19 103.11(14)
C31 P1 C25 105.42(14)
C19 P1 C25 105.72(14)
C31 P1 Ru1 117.74(10)
C19 P1 Ru1 108.99(11)
C25 P1 Ru1 114.65(10)
C55 P2 C67 103.34(14)
C55 P2 C61 102.26(14)
C67 P2 C61 110.94(14)
C55 P2 Ru3 113.49(10)
C67 P2 Ru3 112.24(10)
C61 P2 Ru3 113.69(11)
C37 Ru3 P2 91.84(10)
C37 Ru3 Cl5 95.50(10)
P2 Ru3 Cl5 90.97(3)
C37 Ru3 Cl6 96.21(10)
P2 Ru3 Cl6 96.71(3)
Cl5 Ru3 Cl6 165.76(3)
C37 Ru3 Cl7 89.65(10)
P2 Ru3 Cl7 177.61(3)
Cl5 Ru3 Cl7 90.74(3)
Cl6 Ru3 Cl7 81.27(3)
C37 Ru3 Cl8 165.75(10)
P2 Ru3 Cl8 101.60(3)
Cl5 Ru3 Cl8 89.04(3)
Cl6 Ru3 Cl8 77.70(2)
Cl7 Ru3 Cl8 76.77(3)
C49 Ru4 C50 38.43(14)
C49 Ru4 C46 80.88(12)
C50 Ru4 C46 68.23(12)
C49 Ru4 C47 68.41(12)
C50 Ru4 C47 81.27(12)
C46 Ru4 C47 37.99(12)
C49 Ru4 C45 69.05(13)
C50 Ru4 C45 37.68(13)
C46 Ru4 C45 38.48(12)
C47 Ru4 C45 69.49(12)
C49 Ru4 C48 37.87(12)
C50 Ru4 C48 69.40(13)
C46 Ru4 C48 69.37(12)
C47 Ru4 C48 38.58(12)
C45 Ru4 C48 82.88(13)
C49 Ru4 Cl8 119.58(10)
C50 Ru4 Cl8 157.70(10)
C46 Ru4 Cl8 119.36(9)
C47 Ru4 Cl8 93.42(9)
C45 Ru4 Cl8 157.31(9)
C48 Ru4 Cl8 92.95(9)
C49 Ru4 Cl7 157.49(10)
C50 Ru4 Cl7 119.33(10)
C46 Ru4 Cl7 93.57(9)
C47 Ru4 Cl7 119.17(9)
C45 Ru4 Cl7 93.02(9)
C48 Ru4 Cl7 157.22(9)
Cl8 Ru4 Cl7 82.21(3)
C49 Ru4 Cl6 95.36(9)
C50 Ru4 Cl6 96.13(9)
C46 Ru4 Cl6 159.25(9)
C47 Ru4 Cl6 157.03(9)
C45 Ru4 Cl6 121.16(9)
C48 Ru4 Cl6 119.17(9)
Cl8 Ru4 Cl6 80.32(3)
Cl7 Ru4 Cl6 82.11(3)
C1 Ru1 P1 91.34(10)
C1 Ru1 Cl1 97.27(10)
P1 Ru1 Cl1 90.29(3)
C1 Ru1 Cl2 94.08(10)
P1 Ru1 Cl2 100.76(3)
Cl1 Ru1 Cl2 163.97(3)
C1 Ru1 Cl3 90.56(10)
P1 Ru1 Cl3 178.04(3)
Cl1 Ru1 Cl3 88.99(3)
Cl2 Ru1 Cl3 79.58(3)
C1 Ru1 Cl4 167.35(10)
P1 Ru1 Cl4 99.67(3)
Cl1 Ru1 Cl4 88.93(3)
Cl2 Ru1 Cl4 77.85(3)
Cl3 Ru1 Cl4 78.49(3)
C13 Ru2 C14 38.40(12)
C13 Ru2 C10 80.88(13)
C14 Ru2 C10 68.26(13)
C13 Ru2 C11 68.35(13)
C14 Ru2 C11 80.89(13)
C10 Ru2 C11 37.48(13)
C13 Ru2 C9 68.91(13)
C14 Ru2 C9 37.56(13)
C10 Ru2 C9 38.57(13)
C11 Ru2 C9 68.96(13)
C13 Ru2 C12 38.07(12)
C14 Ru2 C12 69.32(12)
C10 Ru2 C12 68.87(13)
C11 Ru2 C12 38.33(13)
C9 Ru2 C12 82.46(12)
C13 Ru2 Cl3 120.40(9)
C14 Ru2 Cl3 158.74(10)
C10 Ru2 Cl3 116.76(10)
C11 Ru2 Cl3 91.92(10)
C9 Ru2 Cl3 154.76(10)
C12 Ru2 Cl3 92.65(9)
C13 Ru2 Cl2 94.46(9)
C14 Ru2 Cl2 96.76(9)
C10 Ru2 Cl2 161.13(10)
C11 Ru2 Cl2 155.26(10)
C9 Ru2 Cl2 122.75(10)
C12 Ru2 Cl2 117.78(9)
Cl3 Ru2 Cl2 81.42(3)
C13 Ru2 Cl4 154.58(9)
C14 Ru2 Cl4 117.04(10)
C10 Ru2 Cl4 95.89(9)
C11 Ru2 Cl4 122.70(10)
C9 Ru2 Cl4 92.80(9)
C12 Ru2 Cl4 160.76(9)
Cl3 Ru2 Cl4 83.70(3)
Cl2 Ru2 Cl4 80.45(3)
Cl4 Ru2B Cl2 83.38(15)
Ru1 Cl2 Ru2 85.75(3)
Ru1 Cl2 Ru2B 86.10(10)
Ru2 Cl3 Ru1 84.43(3)
Ru2B Cl4 Ru1 92.8(2)
Ru2 Cl4 Ru1 81.23(3)
Cl10 C73 Cl9 112.1(2)
Cl10 C73 H73A 109.2
Cl9 C73 H73A 109.2
Cl10 C73 H73B 109.2
Cl9 C73 H73B 109.2
H73A C73 H73B 107.9
Ru3 Cl6 Ru4 85.66(2)
Ru4 Cl7 Ru3 83.99(3)
Ru4 Cl8 Ru3 82.42(2)
Cl12 C74 Cl11 114.5(6)
Cl12 C74 H74A 108.6
Cl11 C74 H74A 108.6
Cl12 C74 H74B 108.6
Cl11 C74 H74B 108.6
H74A C74 H74B 107.6
Cl2C C74B Cl1C 113.1(10)
Cl2C C74B H74C 109
Cl1C C74B H74C 109
Cl2C C74B H74D 109
Cl1C C74B H74D 109
H74C C74B H74D 107.8
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
C1 C2 1.311(5)
C1 Ru1 1.780(3)
C2 C3 1.466(5)
C2 H2 0.95
C3 C8 1.398(5)
C3 C4 1.404(5)
C4 C5 1.379(5)
C4 H4 0.95
C5 C6 1.374(5)
C5 H5 0.95
C6 C7 1.378(5)
C6 Cl1R 1.754(4)
C7 C8 1.377(5)
C7 H7 0.95
C8 H8 0.95
C9 C14 1.404(5)
C9 C10 1.441(5)
C9 C15 1.477(5)
C9 Ru2 2.196(3)
C10 C11 1.390(5)
C10 Ru2 2.166(3)
C10 H10 0.95
C11 C12 1.426(5)
C11 Ru2 2.161(3)
C11 H11 0.95
C12 C13 1.413(4)
C12 C16 1.511(5)
C12 Ru2 2.183(3)
C13 C14 1.419(5)
C13 Ru2 2.150(3)
C13 H13 0.95
C14 Ru2 2.164(3)
C14 H14 0.95
C15 H15A 0.98
C15 H15B 0.98
C15 H15C 0.98
C16 C17 1.520(5)
C16 C18 1.535(5)
C16 H16 1
C17 H17A 0.98
C17 H17B 0.98
C17 H17C 0.98
C18 H18A 0.98
C18 H18B 0.98
C18 H18C 0.98
C19 C20 1.540(5)
C19 C24 1.540(4)
C19 P1 1.862(3)
C19 H19 1
C20 C21 1.534(5)
C20 H20A 0.99
C20 H20B 0.99
C21 C22 1.531(5)
C21 H21A 0.99
C21 H21B 0.99
C22 C23 1.524(6)
C22 H22A 0.99
C22 H22B 0.99
C23 C24 1.530(5)
C23 H23A 0.99
C23 H23B 0.99
C24 H24A 0.99
C24 H24B 0.99
C25 C26 1.538(4)
C25 C30 1.537(4)
C25 P1 1.866(3)
C25 H25 1
C26 C27 1.529(5)
C26 H26A 0.99
C26 H26B 0.99
C27 C28 1.524(4)
C27 H27A 0.99
C27 H27B 0.99
C28 C29 1.519(5)
C28 H28A 0.99
C28 H28B 0.99
C29 C30 1.530(4)
C29 H29A 0.99
C29 H29B 0.99
C30 H30A 0.99
C30 H30B 0.99
C31 C32 1.533(5)
C31 C36 1.532(4)
C31 P1 1.850(3)
C31 H31 1
C32 C33 1.535(5)
C32 H32A 0.99
C32 H32B 0.99
C33 C34 1.518(5)
C33 H33A 0.99
C33 H33B 0.99
C34 C35 1.523(5)
C34 H34A 0.99
C34 H34B 0.99
C35 C36 1.534(4)
C35 H35A 0.99
C35 H35B 0.99
C36 H36A 0.99
C36 H36B 0.99
C37 C38 1.325(4)
C37 Ru3 1.776(3)
C38 C39 1.464(4)
C38 H38 0.95
C39 C40 1.398(4)
C39 C44 1.404(4)
C40 C41 1.386(5)
C40 H40 0.95
C41 C42 1.374(5)
C41 H41 0.95
C42 C43 1.388(5)
C42 Cl2R 1.743(3)
C43 C44 1.375(5)
C43 H43 0.95
C44 H44 0.95
C45 C50 1.403(5)
C45 C46 1.432(4)
C45 C51 1.500(5)
C45 Ru4 2.184(3)
C46 C47 1.408(5)
C46 Ru4 2.161(3)
C46 H46 0.95
C47 C48 1.439(4)
C47 Ru4 2.165(3)
C47 H47 0.95
C48 C49 1.411(5)
C48 C52 1.504(5)
C48 Ru4 2.191(3)
C49 C50 1.421(5)
C49 Ru4 2.157(3)
C49 H49 0.95
C50 Ru4 2.159(3)
C50 H50 0.95
C51 H51A 0.98
C51 H51B 0.98
C51 H51C 0.98
C52 C54 1.527(5)
C52 C53 1.545(5)
C52 H52 1
C53 H53A 0.98
C53 H53B 0.98
C53 H53C 0.98
C54 H54A 0.98
C54 H54B 0.98
C54 H54C 0.98
C55 C60 1.534(4)
C55 C56 1.543(4)
C55 P2 1.856(3)
C55 H55 1
C56 C57 1.534(4)
C56 H56A 0.99
C56 H56B 0.99
C57 C58 1.526(5)
C57 H57A 0.99
C57 H57B 0.99
C58 C59 1.520(5)
C58 H58A 0.99
C58 H58B 0.99
C59 C60 1.531(5)
C59 H59A 0.99
C59 H59B 0.99
C60 H60A 0.99
C60 H60B 0.99
C61 C62 1.532(4)
C61 C66 1.537(5)
C61 P2 1.870(3)
C61 H61 1
C62 C63 1.530(4)
C62 H62A 0.99
C62 H62B 0.99
C63 C64 1.513(5)
C63 H63A 0.99
C63 H63B 0.99
C64 C65 1.520(5)
C64 H64A 0.99
C64 H64B 0.99
C65 C66 1.536(5)
C65 H65A 0.99
C65 H65B 0.99
C66 H66A 0.99
C66 H66B 0.99
C67 C72 1.529(4)
C67 C68 1.533(4)
C67 P2 1.857(3)
C67 H67 1
C68 C69 1.522(5)
C68 H68A 0.99
C68 H68B 0.99
C69 C70 1.514(5)
C69 H69A 0.99
C69 H69B 0.99
C70 C71 1.519(5)
C70 H70A 0.99
C70 H70B 0.99
C71 C72 1.535(4)
C71 H71A 0.99
C71 H71B 0.99
C72 H72A 0.99
C72 H72B 0.99
Cl1 Ru1 2.3609(8)
P1 Ru1 2.3150(8)
P2 Ru3 2.3173(8)
Ru3 Cl5 2.3585(8)
Ru3 Cl6 2.4020(7)
Ru3 Cl7 2.5167(8)
Ru3 Cl8 2.5991(8)
Ru4 Cl8 2.4117(8)
Ru4 Cl7 2.4209(8)
Ru4 Cl6 2.4578(7)
Ru1 Cl2 2.4137(8)
Ru1 Cl3 2.5103(8)
Ru1 Cl4 2.6081(8)
Ru2 Cl3 2.3977(9)
Ru2 Cl2 2.4349(8)
Ru2 Cl4 2.4565(9)
Ru2B Cl4 2.107(6)
Ru2B Cl2 2.609(5)
C73 Cl10 1.748(4)
C73 Cl9 1.764(4)
C73 H73A 0.99
C73 H73B 0.99
C74 Cl12 1.718(11)
C74 Cl11 1.750(9)
C74 H74A 0.99
C74 H74B 0.99
C74B Cl2C 1.730(16)
C74B Cl1C 1.735(14)
C74B H74C 0.99
C74B H74D 0.99
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
C1 C2 C3 C8 -0.6(5)
C1 C2 C3 C4 178.4(3)
C8 C3 C4 C5 -2.1(5)
C2 C3 C4 C5 178.9(3)
C3 C4 C5 C6 -0.7(5)
C4 C5 C6 C7 2.6(5)
C4 C5 C6 Cl1R -176.1(3)
C5 C6 C7 C8 -1.6(5)
Cl1R C6 C7 C8 177.1(3)
C6 C7 C8 C3 -1.4(5)
C4 C3 C8 C7 3.1(5)
C2 C3 C8 C7 -177.9(3)
C14 C9 C10 C11 -0.3(5)
C15 C9 C10 C11 -177.5(3)
Ru2 C9 C10 C11 -53.2(3)
C14 C9 C10 Ru2 52.9(3)
C15 C9 C10 Ru2 -124.3(3)
C9 C10 C11 C12 0.2(5)
Ru2 C10 C11 C12 -53.3(3)
C9 C10 C11 Ru2 53.6(3)
C10 C11 C12 C13 0.1(5)
Ru2 C11 C12 C13 -53.1(3)
C10 C11 C12 C16 175.5(3)
Ru2 C11 C12 C16 122.3(3)
C10 C11 C12 Ru2 53.3(3)
C11 C12 C13 C14 -0.4(5)
C16 C12 C13 C14 -175.6(3)
Ru2 C12 C13 C14 -53.7(3)
C11 C12 C13 Ru2 53.3(3)
C16 C12 C13 Ru2 -121.9(3)
C10 C9 C14 C13 0.0(5)
C15 C9 C14 C13 177.2(3)
Ru2 C9 C14 C13 52.8(3)
C10 C9 C14 Ru2 -52.7(3)
C15 C9 C14 Ru2 124.4(3)
C12 C13 C14 C9 0.3(5)
Ru2 C13 C14 C9 -53.8(3)
C12 C13 C14 Ru2 54.1(3)
C13 C12 C16 C17 22.0(5)
C11 C12 C16 C17 -153.1(3)
Ru2 C12 C16 C17 -67.0(4)
C13 C12 C16 C18 -102.3(4)
C11 C12 C16 C18 82.6(4)
Ru2 C12 C16 C18 168.7(3)
C24 C19 C20 C21 59.5(4)
P1 C19 C20 C21 -167.3(2)
C19 C20 C21 C22 -56.8(4)
C20 C21 C22 C23 53.5(4)
C21 C22 C23 C24 -54.2(4)
C22 C23 C24 C19 58.1(4)
C20 C19 C24 C23 -60.1(4)
P1 C19 C24 C23 169.8(3)
C30 C25 C26 C27 -58.3(3)
P1 C25 C26 C27 169.7(2)
C25 C26 C27 C28 58.2(4)
C26 C27 C28 C29 -54.6(4)
C27 C28 C29 C30 53.6(4)
C28 C29 C30 C25 -55.8(4)
C26 C25 C30 C29 56.9(3)
P1 C25 C30 C29 -172.2(2)
C36 C31 C32 C33 59.4(4)
P1 C31 C32 C33 -171.3(2)
C31 C32 C33 C34 -57.1(4)
C32 C33 C34 C35 54.0(4)
C33 C34 C35 C36 -54.0(4)
C32 C31 C36 C35 -59.7(4)
P1 C31 C36 C35 170.9(2)
C34 C35 C36 C31 57.5(4)
C37 C38 C39 C40 -178.3(3)
C37 C38 C39 C44 2.8(5)
C44 C39 C40 C41 0.4(5)
C38 C39 C40 C41 -178.6(3)
C39 C40 C41 C42 0.6(5)
C40 C41 C42 C43 -1.2(5)
C40 C41 C42 Cl2R 177.6(3)
C41 C42 C43 C44 0.9(5)
Cl2R C42 C43 C44 -177.9(3)
C42 C43 C44 C39 0.1(5)
C40 C39 C44 C43 -0.7(5)
C38 C39 C44 C43 178.3(3)
C50 C45 C46 C47 -0.4(4)
C51 C45 C46 C47 176.3(3)
Ru4 C45 C46 C47 52.9(3)
C50 C45 C46 Ru4 -53.3(3)
C51 C45 C46 Ru4 123.4(3)
C45 C46 C47 C48 0.4(4)
Ru4 C46 C47 C48 53.5(3)
C45 C46 C47 Ru4 -53.1(3)
C46 C47 C48 C49 0.0(4)
Ru4 C47 C48 C49 53.1(2)
C46 C47 C48 C52 -177.8(3)
Ru4 C47 C48 C52 -124.6(3)
C46 C47 C48 Ru4 -53.1(3)
C47 C48 C49 C50 -0.2(4)
C52 C48 C49 C50 177.4(3)
Ru4 C48 C49 C50 52.8(3)
C47 C48 C49 Ru4 -53.0(2)
C52 C48 C49 Ru4 124.5(3)
C46 C45 C50 C49 0.2(4)
C51 C45 C50 C49 -176.4(3)
Ru4 C45 C50 C49 -53.0(3)
C46 C45 C50 Ru4 53.2(2)
C51 C45 C50 Ru4 -123.4(3)
C48 C49 C50 C45 0.1(5)
Ru4 C49 C50 C45 53.6(3)
C48 C49 C50 Ru4 -53.5(3)
C49 C48 C52 C54 -25.8(4)
C47 C48 C52 C54 151.8(3)
Ru4 C48 C52 C54 65.6(4)
C49 C48 C52 C53 98.2(4)
C47 C48 C52 C53 -84.3(4)
Ru4 C48 C52 C53 -170.5(3)
C60 C55 C56 C57 -50.7(4)
P2 C55 C56 C57 -178.4(2)
C55 C56 C57 C58 54.9(4)
C56 C57 C58 C59 -59.1(4)
C57 C58 C59 C60 59.4(4)
C58 C59 C60 C55 -54.5(4)
C56 C55 C60 C59 49.9(4)
P2 C55 C60 C59 175.7(2)
C66 C61 C62 C63 57.3(4)
P2 C61 C62 C63 -169.5(2)
C61 C62 C63 C64 -57.4(4)
C62 C63 C64 C65 55.7(4)
C63 C64 C65 C66 -55.4(4)
C62 C61 C66 C65 -56.8(4)
P2 C61 C66 C65 172.1(2)
C64 C65 C66 C61 56.6(4)
C72 C67 C68 C69 54.2(4)
P2 C67 C68 C69 -175.3(3)
C67 C68 C69 C70 -57.6(4)
C68 C69 C70 C71 57.4(4)
C69 C70 C71 C72 -55.3(4)
C68 C67 C72 C71 -51.6(4)
P2 C67 C72 C71 178.4(2)
C70 C71 C72 C67 53.0(4)
C32 C31 P1 C19 178.8(2)
C36 C31 P1 C19 -54.7(3)
C32 C31 P1 C25 68.1(3)
C36 C31 P1 C25 -165.4(2)
C32 C31 P1 Ru1 -61.2(3)
C36 C31 P1 Ru1 65.3(2)
C20 C19 P1 C31 -166.0(2)
C24 C19 P1 C31 -37.8(3)
C20 C19 P1 C25 -55.5(3)
C24 C19 P1 C25 72.7(3)
C20 C19 P1 Ru1 68.2(2)
C24 C19 P1 Ru1 -163.6(2)
C26 C25 P1 C31 37.1(3)
C30 C25 P1 C31 -91.2(2)
C26 C25 P1 C19 -71.7(3)
C30 C25 P1 C19 160.0(2)
C26 C25 P1 Ru1 168.2(2)
C30 C25 P1 Ru1 39.9(3)
C60 C55 P2 C67 53.8(3)
C56 C55 P2 C67 -178.8(2)
C60 C55 P2 C61 169.1(2)
C56 C55 P2 C61 -63.5(2)
C60 C55 P2 Ru3 -68.0(2)
C56 C55 P2 Ru3 59.4(2)
C72 C67 P2 C55 -174.2(2)
C68 C67 P2 C55 57.2(3)
C72 C67 P2 C61 76.8(3)
C68 C67 P2 C61 -51.7(3)
C72 C67 P2 Ru3 -51.6(2)
C68 C67 P2 Ru3 179.9(2)
C62 C61 P2 C55 -164.1(2)
C66 C61 P2 C55 -34.9(3)
C62 C61 P2 C67 -54.5(3)
C66 C61 P2 C67 74.7(3)
C62 C61 P2 Ru3 73.2(2)
C66 C61 P2 Ru3 -157.7(2)
C55 P2 Ru3 C37 -179.11(15)
C67 P2 Ru3 C37 64.17(14)
C61 P2 Ru3 C37 -62.77(14)
C55 P2 Ru3 Cl5 -83.57(11)
C67 P2 Ru3 Cl5 159.71(11)
C61 P2 Ru3 Cl5 32.77(11)
C55 P2 Ru3 Cl6 84.42(11)
C67 P2 Ru3 Cl6 -32.31(11)
C61 P2 Ru3 Cl6 -159.25(11)
C55 P2 Ru3 Cl8 5.65(11)
C67 P2 Ru3 Cl8 -111.07(11)
C61 P2 Ru3 Cl8 121.99(11)
C48 C49 Ru4 C50 134.3(3)
C48 C49 Ru4 C46 68.0(2)
C50 C49 Ru4 C46 -66.3(2)
C48 C49 Ru4 C47 30.6(2)
C50 C49 Ru4 C47 -103.7(2)
C48 C49 Ru4 C45 106.0(2)
C50 C49 Ru4 C45 -28.26(19)
C50 C49 Ru4 C48 -134.3(3)
C48 C49 Ru4 Cl8 -50.7(2)
C50 C49 Ru4 Cl8 175.01(16)
C48 C49 Ru4 Cl7 145.1(2)
C50 C49 Ru4 Cl7 10.8(4)
C48 C49 Ru4 Cl6 -132.59(19)
C50 C49 Ru4 Cl6 93.11(18)
C45 C50 Ru4 C49 -133.7(3)
C45 C50 Ru4 C46 -30.47(19)
C49 C50 Ru4 C46 103.2(2)
C45 C50 Ru4 C47 -67.6(2)
C49 C50 Ru4 C47 66.1(2)
C49 C50 Ru4 C45 133.7(3)
C45 C50 Ru4 C48 -105.7(2)
C49 C50 Ru4 C48 28.00(19)
C45 C50 Ru4 Cl8 -145.2(2)
C49 C50 Ru4 Cl8 -11.5(4)
C45 C50 Ru4 Cl7 51.0(2)
C49 C50 Ru4 Cl7 -175.28(15)
C45 C50 Ru4 Cl6 135.42(18)
C49 C50 Ru4 Cl6 -90.90(18)
C47 C46 Ru4 C49 -66.4(2)
C45 C46 Ru4 C49 67.7(2)
C47 C46 Ru4 C50 -104.2(2)
C45 C46 Ru4 C50 29.9(2)
C45 C46 Ru4 C47 134.1(3)
C47 C46 Ru4 C45 -134.1(3)
C47 C46 Ru4 C48 -28.98(18)
C45 C46 Ru4 C48 105.1(2)
C47 C46 Ru4 Cl8 52.5(2)
C45 C46 Ru4 Cl8 -173.43(16)
C47 C46 Ru4 Cl7 135.53(17)
C45 C46 Ru4 Cl7 -90.37(18)
C47 C46 Ru4 Cl6 -147.4(2)
C45 C46 Ru4 Cl6 -13.3(4)
C46 C47 Ru4 C49 103.3(2)
C48 C47 Ru4 C49 -30.1(2)
C46 C47 Ru4 C50 65.6(2)
C48 C47 Ru4 C50 -67.8(2)
C48 C47 Ru4 C46 -133.4(3)
C46 C47 Ru4 C45 28.49(19)
C48 C47 Ru4 C45 -104.9(2)
C46 C47 Ru4 C48 133.4(3)
C46 C47 Ru4 Cl8 -136.19(17)
C48 C47 Ru4 Cl8 90.44(18)
C46 C47 Ru4 Cl7 -53.2(2)
C48 C47 Ru4 Cl7 173.43(16)
C46 C47 Ru4 Cl6 150.72(19)
C48 C47 Ru4 Cl6 17.3(3)
C50 C45 Ru4 C49 28.78(19)
C46 C45 Ru4 C49 -102.0(2)
C51 C45 Ru4 C49 144.9(3)
C46 C45 Ru4 C50 -130.8(3)
C51 C45 Ru4 C50 116.1(4)
C50 C45 Ru4 C46 130.8(3)
C51 C45 Ru4 C46 -113.1(4)
C50 C45 Ru4 C47 102.7(2)
C46 C45 Ru4 C47 -28.16(19)
C51 C45 Ru4 C47 -141.2(3)
C50 C45 Ru4 C48 65.3(2)
C46 C45 Ru4 C48 -65.6(2)
C51 C45 Ru4 C48 -178.7(3)
C50 C45 Ru4 Cl8 145.8(2)
C46 C45 Ru4 Cl8 15.0(4)
C51 C45 Ru4 Cl8 -98.1(3)
C50 C45 Ru4 Cl7 -137.24(18)
C46 C45 Ru4 Cl7 91.93(18)
C51 C45 Ru4 Cl7 -21.2(3)
C50 C45 Ru4 Cl6 -54.6(2)
C46 C45 Ru4 Cl6 174.53(15)
C51 C45 Ru4 Cl6 61.4(3)
C47 C48 Ru4 C49 130.6(3)
C52 C48 Ru4 C49 -118.8(4)
C49 C48 Ru4 C50 -28.4(2)
C47 C48 Ru4 C50 102.2(2)
C52 C48 Ru4 C50 -147.2(3)
C49 C48 Ru4 C46 -102.0(2)
C47 C48 Ru4 C46 28.57(19)
C52 C48 Ru4 C46 139.2(3)
C49 C48 Ru4 C47 -130.6(3)
C52 C48 Ru4 C47 110.6(4)
C49 C48 Ru4 C45 -64.8(2)
C47 C48 Ru4 C45 65.8(2)
C52 C48 Ru4 C45 176.4(3)
C49 C48 Ru4 Cl8 137.64(19)
C47 C48 Ru4 Cl8 -91.78(18)
C52 C48 Ru4 Cl8 18.8(3)
C49 C48 Ru4 Cl7 -145.5(2)
C47 C48 Ru4 Cl7 -15.0(4)
C52 C48 Ru4 Cl7 95.7(4)
C49 C48 Ru4 Cl6 57.1(2)
C47 C48 Ru4 Cl6 -172.34(16)
C52 C48 Ru4 Cl6 -61.7(3)
C31 P1 Ru1 C1 63.29(15)
C19 P1 Ru1 C1 -179.84(15)
C25 P1 Ru1 C1 -61.60(15)
C31 P1 Ru1 Cl1 160.57(12)
C19 P1 Ru1 Cl1 -82.56(11)
C25 P1 Ru1 Cl1 35.68(12)
C31 P1 Ru1 Cl2 -31.12(12)
C19 P1 Ru1 Cl2 85.75(11)
C25 P1 Ru1 Cl2 -156.01(11)
C31 P1 Ru1 Cl4 -110.46(12)
C19 P1 Ru1 Cl4 6.41(12)
C25 P1 Ru1 Cl4 124.65(11)
C12 C13 Ru2 C14 -133.6(3)
C12 C13 Ru2 C10 -67.2(2)
C14 C13 Ru2 C10 66.3(2)
C12 C13 Ru2 C11 -30.5(2)
C14 C13 Ru2 C11 103.1(2)
C12 C13 Ru2 C9 -105.3(2)
C14 C13 Ru2 C9 28.2(2)
C14 C13 Ru2 C12 133.6(3)
C12 C13 Ru2 Cl3 48.5(2)
C14 C13 Ru2 Cl3 -177.92(16)
C12 C13 Ru2 Cl2 131.19(19)
C14 C13 Ru2 Cl2 -95.25(19)
C12 C13 Ru2 Cl4 -151.72(18)
C14 C13 Ru2 Cl4 -18.2(3)
C9 C14 Ru2 C13 133.6(3)
C9 C14 Ru2 C10 30.4(2)
C13 C14 Ru2 C10 -103.2(2)
C9 C14 Ru2 C11 67.2(2)
C13 C14 Ru2 C11 -66.5(2)
C13 C14 Ru2 C9 -133.6(3)
C9 C14 Ru2 C12 105.1(2)
C13 C14 Ru2 C12 -28.53(19)
C9 C14 Ru2 Cl3 138.6(2)
C13 C14 Ru2 Cl3 5.0(4)
C9 C14 Ru2 Cl2 -137.70(19)
C13 C14 Ru2 Cl2 88.66(19)
C9 C14 Ru2 Cl4 -55.0(2)
C13 C14 Ru2 Cl4 171.36(16)
C11 C10 Ru2 C13 66.1(2)
C9 C10 Ru2 C13 -67.5(2)
C11 C10 Ru2 C14 103.9(2)
C9 C10 Ru2 C14 -29.69(19)
C9 C10 Ru2 C11 -133.6(3)
C11 C10 Ru2 C9 133.6(3)
C11 C10 Ru2 C12 28.57(19)
C9 C10 Ru2 C12 -105.0(2)
C11 C10 Ru2 Cl3 -53.4(2)
C9 C10 Ru2 Cl3 173.00(16)
C11 C10 Ru2 Cl2 143.1(3)
C9 C10 Ru2 Cl2 9.5(4)
C11 C10 Ru2 Cl4 -139.31(19)
C9 C10 Ru2 Cl4 87.11(18)
C10 C11 Ru2 C13 -103.7(2)
C12 C11 Ru2 C13 30.26(19)
C10 C11 Ru2 C14 -66.0(2)
C12 C11 Ru2 C14 68.0(2)
C12 C11 Ru2 C10 134.0(3)
C10 C11 Ru2 C9 -28.9(2)
C12 C11 Ru2 C9 105.1(2)
C10 C11 Ru2 C12 -134.0(3)
C10 C11 Ru2 Cl3 134.16(19)
C12 C11 Ru2 Cl3 -91.84(18)
C10 C11 Ru2 Cl2 -152.32(19)
C12 C11 Ru2 Cl2 -18.3(3)
C10 C11 Ru2 Cl4 50.4(2)
C12 C11 Ru2 Cl4 -175.59(15)
C14 C9 Ru2 C13 -28.80(19)
C10 C9 Ru2 C13 102.2(2)
C15 C9 Ru2 C13 -144.2(4)
C10 C9 Ru2 C14 131.0(3)
C15 C9 Ru2 C14 -115.4(4)
C14 C9 Ru2 C10 -131.0(3)
C15 C9 Ru2 C10 113.6(4)
C14 C9 Ru2 C11 -102.8(2)
C10 C9 Ru2 C11 28.18(19)
C15 C9 Ru2 C11 141.8(4)
C14 C9 Ru2 C12 -65.7(2)
C10 C9 Ru2 C12 65.3(2)
C15 C9 Ru2 C12 178.9(4)
C14 C9 Ru2 Cl3 -145.8(2)
C10 C9 Ru2 Cl3 -14.8(3)
C15 C9 Ru2 Cl3 98.8(4)
C14 C9 Ru2 Cl2 52.6(2)
C10 C9 Ru2 Cl2 -176.37(16)
C15 C9 Ru2 Cl2 -62.8(4)
C14 C9 Ru2 Cl4 133.07(19)
C10 C9 Ru2 Cl4 -95.93(18)
C15 C9 Ru2 Cl4 17.7(3)
C11 C12 Ru2 C13 -130.6(3)
C16 C12 Ru2 C13 117.5(4)
C13 C12 Ru2 C14 28.8(2)
C11 C12 Ru2 C14 -101.8(2)
C16 C12 Ru2 C14 146.3(3)
C13 C12 Ru2 C10 102.6(2)
C11 C12 Ru2 C10 -28.0(2)
C16 C12 Ru2 C10 -139.9(3)
C13 C12 Ru2 C11 130.6(3)
C16 C12 Ru2 C11 -111.9(4)
C13 C12 Ru2 C9 65.2(2)
C11 C12 Ru2 C9 -65.4(2)
C16 C12 Ru2 C9 -177.3(3)
C13 C12 Ru2 Cl3 -139.69(19)
C11 C12 Ru2 Cl3 89.74(18)
C16 C12 Ru2 Cl3 -22.2(3)
C13 C12 Ru2 Cl2 -58.0(2)
C11 C12 Ru2 Cl2 171.44(17)
C16 C12 Ru2 Cl2 59.5(3)
C13 C12 Ru2 Cl4 141.9(2)
C11 C12 Ru2 Cl4 11.3(4)
C16 C12 Ru2 Cl4 -100.6(4)
C1 Ru1 Cl2 Ru2 128.13(10)
P1 Ru1 Cl2 Ru2 -139.73(3)
Cl1 Ru1 Cl2 Ru2 -6.93(11)
Cl3 Ru1 Cl2 Ru2 38.31(3)
Cl4 Ru1 Cl2 Ru2 -42.02(3)
C1 Ru1 Cl2 Ru2B 141.8(2)
P1 Ru1 Cl2 Ru2B -126.04(18)
Cl1 Ru1 Cl2 Ru2B 6.8(2)
Cl3 Ru1 Cl2 Ru2B 52.00(18)
Cl4 Ru1 Cl2 Ru2B -28.33(18)
C13 Ru2 Cl2 Ru1 -160.31(9)
C14 Ru2 Cl2 Ru1 161.17(9)
C10 Ru2 Cl2 Ru1 125.0(3)
C11 Ru2 Cl2 Ru1 -115.9(2)
C9 Ru2 Cl2 Ru1 131.97(11)
C12 Ru2 Cl2 Ru1 -128.68(10)
Cl3 Ru2 Cl2 Ru1 -40.20(3)
Cl4 Ru2 Cl2 Ru1 44.79(3)
C13 Ru2 Cl2 Ru2B 108.7(4)
C14 Ru2 Cl2 Ru2B 70.2(4)
C10 Ru2 Cl2 Ru2B 34.0(5)
C11 Ru2 Cl2 Ru2B 153.0(5)
C9 Ru2 Cl2 Ru2B 41.0(4)
C12 Ru2 Cl2 Ru2B 140.3(4)
Cl3 Ru2 Cl2 Ru2B -131.2(4)
Cl4 Ru2 Cl2 Ru2B -46.2(4)
Cl4 Ru2B Cl2 Ru1 35.32(17)
Cl4 Ru2B Cl2 Ru2 123.3(5)
C13 Ru2 Cl3 Ru1 128.61(10)
C14 Ru2 Cl3 Ru1 125.0(3)
C10 Ru2 Cl3 Ru1 -136.22(11)
C11 Ru2 Cl3 Ru1 -165.49(10)
C9 Ru2 Cl3 Ru1 -126.0(2)
C12 Ru2 Cl3 Ru1 156.16(9)
Cl2 Ru2 Cl3 Ru1 38.46(3)
Cl4 Ru2 Cl3 Ru1 -42.79(2)
C1 Ru1 Cl3 Ru2 -133.15(10)
Cl1 Ru1 Cl3 Ru2 129.58(3)
Cl2 Ru1 Cl3 Ru2 -39.11(3)
Cl4 Ru1 Cl3 Ru2 40.47(3)
Cl2 Ru2B Cl4 Ru2 -60.0(5)
Cl2 Ru2B Cl4 Ru1 -32.30(14)
C13 Ru2 Cl4 Ru2B 30.6(6)
C14 Ru2 Cl4 Ru2B 18.1(6)
C10 Ru2 Cl4 Ru2B -50.5(6)
C11 Ru2 Cl4 Ru2B -78.6(6)
C9 Ru2 Cl4 Ru2B -11.9(6)
C12 Ru2 Cl4 Ru2B -86.9(6)
Cl3 Ru2 Cl4 Ru2B -166.8(6)
Cl2 Ru2 Cl4 Ru2B 110.8(6)
C13 Ru2 Cl4 Ru1 -121.3(2)
C14 Ru2 Cl4 Ru1 -133.90(10)
C10 Ru2 Cl4 Ru1 157.54(10)
C11 Ru2 Cl4 Ru1 129.41(12)
C9 Ru2 Cl4 Ru1 -163.90(10)
C12 Ru2 Cl4 Ru1 121.1(3)
Cl3 Ru2 Cl4 Ru1 41.18(2)
Cl2 Ru2 Cl4 Ru1 -41.14(2)
C1 Ru1 Cl4 Ru2B -15.2(5)
P1 Ru1 Cl4 Ru2B 134.96(15)
Cl1 Ru1 Cl4 Ru2B -134.93(15)
Cl2 Ru1 Cl4 Ru2B 35.93(15)
Cl3 Ru1 Cl4 Ru2B -45.74(15)
C1 Ru1 Cl4 Ru2 -9.2(5)
P1 Ru1 Cl4 Ru2 141.06(3)
Cl1 Ru1 Cl4 Ru2 -128.83(3)
Cl2 Ru1 Cl4 Ru2 42.03(2)
Cl3 Ru1 Cl4 Ru2 -39.64(2)
C37 Ru3 Cl6 Ru4 126.00(10)
P2 Ru3 Cl6 Ru4 -141.40(3)
Cl5 Ru3 Cl6 Ru4 -19.19(13)
Cl7 Ru3 Cl6 Ru4 37.31(2)
Cl8 Ru3 Cl6 Ru4 -40.94(2)
C49 Ru4 Cl6 Ru3 163.56(10)
C50 Ru4 Cl6 Ru3 -157.81(10)
C46 Ru4 Cl6 Ru3 -118.1(2)
C47 Ru4 Cl6 Ru3 120.1(2)
C45 Ru4 Cl6 Ru3 -127.72(11)
C48 Ru4 Cl6 Ru3 132.39(10)
Cl8 Ru4 Cl6 Ru3 44.42(2)
Cl7 Ru4 Cl6 Ru3 -38.96(3)
C49 Ru4 Cl7 Ru3 121.9(2)
C50 Ru4 Cl7 Ru3 129.62(10)
C46 Ru4 Cl7 Ru3 -163.41(9)
C47 Ru4 Cl7 Ru3 -133.81(10)
C45 Ru4 Cl7 Ru3 158.05(9)
C48 Ru4 Cl7 Ru3 -123.2(2)
Cl8 Ru4 Cl7 Ru3 -44.24(2)
Cl6 Ru4 Cl7 Ru3 36.99(2)
C37 Ru3 Cl7 Ru4 -134.44(10)
Cl5 Ru3 Cl7 Ru4 130.06(3)
Cl6 Ru3 Cl7 Ru4 -38.10(2)
Cl8 Ru3 Cl7 Ru4 41.22(2)
C49 Ru4 Cl8 Ru3 -131.29(10)
C50 Ru4 Cl8 Ru3 -123.1(2)
C46 Ru4 Cl8 Ru3 132.39(10)
C47 Ru4 Cl8 Ru3 161.66(9)
C45 Ru4 Cl8 Ru3 121.8(2)
C48 Ru4 Cl8 Ru3 -159.69(9)
Cl7 Ru4 Cl8 Ru3 42.67(2)
Cl6 Ru4 Cl8 Ru3 -40.60(2)
C37 Ru3 Cl8 Ru4 -23.7(4)
P2 Ru3 Cl8 Ru4 136.64(3)
Cl5 Ru3 Cl8 Ru4 -132.56(3)
Cl6 Ru3 Cl8 Ru4 42.21(2)
Cl7 Ru3 Cl8 Ru4 -41.57(2)
