#------------------------------------------------------------------------------
#$Date: 2016-03-21 07:20:56 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178560 $
#$URL: svn://www.crystallography.net/cod/cif/4/06/68/4066881.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4066881
loop_
_publ_author_name
'Brown, Timothy J.'
'Sugie, Atsushi'
'Dickens, Marina G.'
'Widenhoefer, Ross A.'
_publ_section_title
;
 Solid-State and Dynamic Solution Behavior of a Cationic, Two-Coordinate
 Gold(I) π-Allene Complex
;
_journal_issue                   19
_journal_name_full               Organometallics
_journal_page_first              4207
_journal_paper_doi               10.1021/om100688t
_journal_volume                  29
_journal_year                    2010
_chemical_formula_moiety         '2(C25 H35 Au P), 2(F6 Sb), C H2 Cl2)'
_chemical_formula_sum            'C51 H72 Au2 Cl2 F12 P2 Sb2'
_chemical_formula_weight         1683.39
_chemical_name_common            Allene1
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                98.452(8)
_cell_angle_beta                 94.196(8)
_cell_angle_gamma                96.769(8)
_cell_formula_units_Z            1
_cell_length_a                   7.8865(11)
_cell_length_b                   11.4932(16)
_cell_length_c                   16.466(2)
_cell_measurement_reflns_used    8140
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      26.46
_cell_measurement_theta_min      2.98
_cell_volume                     1459.8(3)
_computing_cell_refinement       SAINT
_computing_data_collection       'Apex II 2.0 Rev.2 (Bruker, 2005)'
_computing_data_reduction        'SAINT 7.12A (Bruker, 2004)'
_computing_molecular_graphics    'SHELXTL 5.1, XP (Sheldrick, 1994)'
_computing_publication_material  'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      173(2)
_diffrn_detector_area_resol_mean 8.3
_diffrn_measured_fraction_theta_full 0.912
_diffrn_measured_fraction_theta_max 0.912
_diffrn_measurement_device_type  'Bruker SMART Apex II'
_diffrn_measurement_method       ω
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0342
_diffrn_reflns_av_sigmaI/netI    0.0321
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            20096
_diffrn_reflns_theta_full        26.46
_diffrn_reflns_theta_max         26.46
_diffrn_reflns_theta_min         3.25
_exptl_absorpt_coefficient_mu    6.142
_exptl_absorpt_correction_T_max  0.5787
_exptl_absorpt_correction_T_min  0.4398
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS 2.10 (Sheldrick, 2004)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.915
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       hexagonal
_exptl_crystal_F_000             810
_exptl_crystal_size_max          0.16
_exptl_crystal_size_mid          0.13
_exptl_crystal_size_min          0.10
_refine_diff_density_max         1.412
_refine_diff_density_min         -1.149
_refine_diff_density_rms         0.136
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.287
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     328
_refine_ls_number_reflns         5510
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.287
_refine_ls_R_factor_all          0.0440
_refine_ls_R_factor_gt           0.0324
_refine_ls_shift/su_max          0.144
_refine_ls_shift/su_mean         0.006
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0360P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0722
_refine_ls_wR_factor_ref         0.0770
_reflns_number_gt                4741
_reflns_number_total             5510
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            om100688t_si_001.cif
_cod_data_source_block           md130x
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from
2010-06-29.

'_exptl_absorpt_correction_type' value 'Multi-scan'
changed to 'multi-scan' according to
/home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_sg_symbol_H-M      'P-1   '
_cod_database_code               4066881
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Sb1 Sb -0.94176(5) 1.21283(4) 0.23096(2) 0.03278(11) Uani 1 1 d .
F1 F -0.9365(6) 1.3630(4) 0.2918(3) 0.0744(14) Uani 1 1 d .
F2 F -1.1799(5) 1.1888(4) 0.2263(3) 0.0666(12) Uani 1 1 d .
F3 F -0.9482(6) 1.0636(4) 0.1690(3) 0.0661(12) Uani 1 1 d .
F4 F -0.9241(5) 1.1461(4) 0.3273(2) 0.0649(12) Uani 1 1 d .
F5 F -0.7043(5) 1.2350(4) 0.2341(4) 0.0823(16) Uani 1 1 d .
F6 F -0.9586(7) 1.2802(5) 0.1343(3) 0.0843(15) Uani 1 1 d .
Au1 Au -1.42714(3) 0.838313(19) 0.198206(12) 0.02446(8) Uani 1 1 d .
P1 P -1.28322(16) 0.68033(12) 0.21988(7) 0.0212(3) Uani 1 1 d .
C1 C -1.5520(7) 0.9967(5) 0.1882(3) 0.0295(13) Uani 1 1 d .
H1A H -1.6503 1.0063 0.2216 0.035 Uiso 1 1 calc R
H1B H -1.4739 1.0716 0.1912 0.035 Uiso 1 1 calc R
C2 C -1.5899(7) 0.9328(5) 0.1128(3) 0.0287(13) Uani 1 1 d .
C3 C -1.6522(7) 0.8921(5) 0.0366(3) 0.0306(13) Uani 1 1 d .
C4 C -1.6199(8) 0.7787(6) -0.0132(4) 0.0436(17) Uani 1 1 d .
H4A H -1.5378 0.7412 0.0185 0.065 Uiso 1 1 calc R
H4B H -1.5729 0.7954 -0.0644 0.065 Uiso 1 1 calc R
H4C H -1.7279 0.7253 -0.0264 0.065 Uiso 1 1 calc R
C5 C -1.7707(7) 0.9657(6) -0.0030(3) 0.0374(14) Uani 1 1 d .
H5A H -1.7790 1.0382 0.0353 0.056 Uiso 1 1 calc R
H5B H -1.8848 0.9199 -0.0167 0.056 Uiso 1 1 calc R
H5C H -1.7254 0.9869 -0.0535 0.056 Uiso 1 1 calc R
C6 C -1.1025(7) 0.6795(5) 0.1512(3) 0.0277(12) Uani 1 1 d .
C7 C -1.0317(8) 0.5617(6) 0.1308(4) 0.0396(15) Uani 1 1 d .
H7A H -0.9394 0.5711 0.0945 0.059 Uiso 1 1 calc R
H7B H -1.1236 0.5011 0.1028 0.059 Uiso 1 1 calc R
H7C H -0.9866 0.5373 0.1818 0.059 Uiso 1 1 calc R
C8 C -0.9605(8) 0.7746(6) 0.1924(4) 0.0426(15) Uani 1 1 d .
H8A H -0.8637 0.7766 0.1583 0.064 Uiso 1 1 calc R
H8B H -0.9228 0.7568 0.2467 0.064 Uiso 1 1 calc R
H8C H -1.0031 0.8518 0.1987 0.064 Uiso 1 1 calc R
C9 C -1.1676(8) 0.7149(6) 0.0681(3) 0.0432(17) Uani 1 1 d .
H9A H -1.0756 0.7145 0.0312 0.065 Uiso 1 1 calc R
H9B H -1.2021 0.7946 0.0782 0.065 Uiso 1 1 calc R
H9C H -1.2661 0.6580 0.0425 0.065 Uiso 1 1 calc R
C10 C -1.4371(6) 0.5400(5) 0.2045(3) 0.0266(12) Uani 1 1 d .
C11 C -1.5773(7) 0.5643(6) 0.2634(4) 0.0367(14) Uani 1 1 d .
H11A H -1.6618 0.4934 0.2584 0.055 Uiso 1 1 calc R
H11B H -1.6344 0.6307 0.2487 0.055 Uiso 1 1 calc R
H11C H -1.5247 0.5844 0.3203 0.055 Uiso 1 1 calc R
C12 C -1.5195(8) 0.5149(6) 0.1159(3) 0.0400(15) Uani 1 1 d .
H12A H -1.5999 0.4415 0.1080 0.060 Uiso 1 1 calc R
H12B H -1.4302 0.5063 0.0779 0.060 Uiso 1 1 calc R
H12C H -1.5813 0.5809 0.1049 0.060 Uiso 1 1 calc R
C13 C -1.3588(8) 0.4312(6) 0.2254(4) 0.0383(14) Uani 1 1 d .
H13A H -1.4476 0.3621 0.2162 0.057 Uiso 1 1 calc R
H13B H -1.3122 0.4459 0.2834 0.057 Uiso 1 1 calc R
H13C H -1.2666 0.4157 0.1901 0.057 Uiso 1 1 calc R
C14 C -1.1864(6) 0.6961(5) 0.3258(3) 0.0243(11) Uani 1 1 d .
C15 C -1.2160(7) 0.7860(5) 0.3886(3) 0.0286(12) Uani 1 1 d .
C16 C -1.1270(9) 0.7938(7) 0.4663(4) 0.0509(19) Uani 1 1 d .
H16A H -1.1448 0.8552 0.5089 0.061 Uiso 1 1 calc R
C17 C -1.0146(9) 0.7159(7) 0.4829(4) 0.058(2) Uani 1 1 d .
H17A H -0.9572 0.7234 0.5366 0.070 Uiso 1 1 calc R
C18 C -0.9846(8) 0.6260(7) 0.4215(4) 0.0480(18) Uani 1 1 d .
H18A H -0.9060 0.5723 0.4322 0.058 Uiso 1 1 calc R
C19 C -1.0725(7) 0.6164(5) 0.3438(3) 0.0322(13) Uani 1 1 d .
H19A H -1.0548 0.5541 0.3018 0.039 Uiso 1 1 calc R
C20 C -1.3377(7) 0.8748(5) 0.3814(3) 0.0284(13) Uani 1 1 d .
C21 C -1.5100(7) 0.8509(6) 0.3934(3) 0.0359(14) Uani 1 1 d .
H21A H -1.5576 0.7728 0.3986 0.043 Uiso 1 1 calc R
C22 C -1.6127(8) 0.9414(6) 0.3980(3) 0.0399(16) Uani 1 1 d .
H22A H -1.7304 0.9241 0.4063 0.048 Uiso 1 1 calc R
C23 C -1.5474(9) 1.0566(6) 0.3908(3) 0.0426(17) Uani 1 1 d .
H23A H -1.6189 1.1178 0.3943 0.051 Uiso 1 1 calc R
C24 C -1.3783(9) 1.0802(6) 0.3787(3) 0.0462(17) Uani 1 1 d .
H24A H -1.3330 1.1590 0.3741 0.055 Uiso 1 1 calc R
C25 C -1.2704(8) 0.9929(6) 0.3728(3) 0.0374(15) Uani 1 1 d .
H25A H -1.1537 1.0113 0.3632 0.045 Uiso 1 1 calc R
Cl1 Cl -0.4243(4) 0.3987(3) 0.46387(17) 0.1008(9) Uani 1 1 d .
C1X C -0.599(4) 0.439(3) 0.480(2) 0.108(10) Uani 0.50 1 d P
H1X H -0.612(14) 0.466(10) 0.467(6) 0.050 Uiso 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
F5 Sb1 F3 90.2(2) . .
F5 Sb1 F2 179.1(2) . .
F3 Sb1 F2 88.9(2) . .
F5 Sb1 F1 90.0(2) . .
F3 Sb1 F1 179.2(2) . .
F2 Sb1 F1 90.8(2) . .
F5 Sb1 F4 89.3(2) . .
F3 Sb1 F4 89.8(2) . .
F2 Sb1 F4 91.00(19) . .
F1 Sb1 F4 91.0(2) . .
F5 Sb1 F6 90.5(2) . .
F3 Sb1 F6 90.3(2) . .
F2 Sb1 F6 89.2(2) . .
F1 Sb1 F6 88.9(2) . .
F4 Sb1 F6 179.8(2) . .
C1 Au1 C2 34.55(19) . .
C1 Au1 P1 174.84(14) . .
C2 Au1 P1 150.49(14) . .
C14 P1 C10 105.2(2) . .
C14 P1 C6 106.9(2) . .
C10 P1 C6 115.2(2) . .
C14 P1 Au1 112.16(18) . .
C10 P1 Au1 110.10(16) . .
C6 P1 Au1 107.31(17) . .
C2 C1 Au1 77.4(3) . .
C2 C1 H1A 115.6 . .
Au1 C1 H1A 115.6 . .
C2 C1 H1B 115.6 . .
Au1 C1 H1B 115.6 . .
H1A C1 H1B 112.6 . .
C3 C2 C1 165.0(5) . .
C3 C2 Au1 126.9(4) . .
C1 C2 Au1 68.0(3) . .
C2 C3 C4 126.0(5) . .
C2 C3 C5 116.5(5) . .
C4 C3 C5 117.5(5) . .
C3 C4 H4A 109.5 . .
C3 C4 H4B 109.5 . .
H4A C4 H4B 109.5 . .
C3 C4 H4C 109.5 . .
H4A C4 H4C 109.5 . .
H4B C4 H4C 109.5 . .
C3 C5 H5A 109.5 . .
C3 C5 H5B 109.5 . .
H5A C5 H5B 109.5 . .
C3 C5 H5C 109.5 . .
H5A C5 H5C 109.5 . .
H5B C5 H5C 109.5 . .
C8 C6 C7 109.9(5) . .
C8 C6 C9 108.0(5) . .
C7 C6 C9 107.0(4) . .
C8 C6 P1 107.2(4) . .
C7 C6 P1 116.3(4) . .
C9 C6 P1 108.1(3) . .
C6 C7 H7A 109.5 . .
C6 C7 H7B 109.5 . .
H7A C7 H7B 109.5 . .
C6 C7 H7C 109.5 . .
H7A C7 H7C 109.5 . .
H7B C7 H7C 109.5 . .
C6 C8 H8A 109.5 . .
C6 C8 H8B 109.5 . .
H8A C8 H8B 109.5 . .
C6 C8 H8C 109.5 . .
H8A C8 H8C 109.5 . .
H8B C8 H8C 109.5 . .
C6 C9 H9A 109.5 . .
C6 C9 H9B 109.5 . .
H9A C9 H9B 109.5 . .
C6 C9 H9C 109.5 . .
H9A C9 H9C 109.5 . .
H9B C9 H9C 109.5 . .
C12 C10 C13 109.8(5) . .
C12 C10 C11 108.9(4) . .
C13 C10 C11 108.1(5) . .
C12 C10 P1 109.6(4) . .
C13 C10 P1 114.7(4) . .
C11 C10 P1 105.6(4) . .
C10 C11 H11A 109.5 . .
C10 C11 H11B 109.5 . .
H11A C11 H11B 109.5 . .
C10 C11 H11C 109.5 . .
H11A C11 H11C 109.5 . .
H11B C11 H11C 109.5 . .
C10 C12 H12A 109.5 . .
C10 C12 H12B 109.5 . .
H12A C12 H12B 109.5 . .
C10 C12 H12C 109.5 . .
H12A C12 H12C 109.5 . .
H12B C12 H12C 109.5 . .
C10 C13 H13A 109.5 . .
C10 C13 H13B 109.5 . .
H13A C13 H13B 109.5 . .
C10 C13 H13C 109.5 . .
H13A C13 H13C 109.5 . .
H13B C13 H13C 109.5 . .
C15 C14 C19 119.0(4) . .
C15 C14 P1 123.2(4) . .
C19 C14 P1 117.8(4) . .
C16 C15 C14 118.3(5) . .
C16 C15 C20 115.6(5) . .
C14 C15 C20 126.1(4) . .
C17 C16 C15 122.2(6) . .
C17 C16 H16A 118.9 . .
C15 C16 H16A 118.9 . .
C16 C17 C18 120.2(5) . .
C16 C17 H17A 119.9 . .
C18 C17 H17A 119.9 . .
C17 C18 C19 118.5(6) . .
C17 C18 H18A 120.8 . .
C19 C18 H18A 120.8 . .
C18 C19 C14 121.9(5) . .
C18 C19 H19A 119.1 . .
C14 C19 H19A 119.1 . .
C21 C20 C25 118.8(5) . .
C21 C20 C15 122.0(6) . .
C25 C20 C15 118.7(5) . .
C22 C21 C20 119.9(7) . .
C22 C21 H21A 120.0 . .
C20 C21 H21A 120.0 . .
C21 C22 C23 121.5(6) . .
C21 C22 H22A 119.3 . .
C23 C22 H22A 119.2 . .
C24 C23 C22 118.7(6) . .
C24 C23 H23A 120.7 . .
C22 C23 H23A 120.7 . .
C23 C24 C25 122.2(7) . .
C23 C24 H24A 118.9 . .
C25 C24 H24A 118.9 . .
C24 C25 C20 118.9(6) . .
C24 C25 H25A 120.5 . .
C20 C25 H25A 120.5 . .
C1X Cl1 C1X 68.2(19) . 2_466
Cl1 C1X Cl1 111.8(19) . 2_466
Cl1 C1X C1X 65.5(19) . 2_466
Cl1 C1X C1X 46.3(17) 2_466 2_466
Cl1 C1X H1X 114(10) . .
Cl1 C1X H1X 61(10) 2_466 .
C1X C1X H1X 81(10) 2_466 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Sb1 F5 1.856(4) .
Sb1 F3 1.856(4) .
Sb1 F2 1.860(4) .
Sb1 F1 1.858(4) .
Sb1 F4 1.865(4) .
Sb1 F6 1.872(4) .
Au1 C1 2.191(5) .
Au1 C2 2.306(5) .
Au1 P1 2.3086(13) .
P1 C14 1.827(5) .
P1 C10 1.874(6) .
P1 C6 1.883(5) .
C1 C2 1.340(7) .
C1 H1A 0.9900 .
C1 H1B 0.9900 .
C2 C3 1.311(7) .
C3 C4 1.493(8) .
C3 C5 1.509(7) .
C4 H4A 0.9800 .
C4 H4B 0.9800 .
C4 H4C 0.9800 .
C5 H5A 0.9800 .
C5 H5B 0.9800 .
C5 H5C 0.9800 .
C6 C8 1.513(9) .
C6 C7 1.526(8) .
C6 C9 1.553(7) .
C7 H7A 0.9800 .
C7 H7B 0.9800 .
C7 H7C 0.9800 .
C8 H8A 0.9800 .
C8 H8B 0.9800 .
C8 H8C 0.9800 .
C9 H9A 0.9800 .
C9 H9B 0.9800 .
C9 H9C 0.9800 .
C10 C12 1.525(7) .
C10 C13 1.530(7) .
C10 C11 1.547(7) .
C11 H11A 0.9800 .
C11 H11B 0.9800 .
C11 H11C 0.9800 .
C12 H12A 0.9800 .
C12 H12B 0.9800 .
C12 H12C 0.9800 .
C13 H13A 0.9800 .
C13 H13B 0.9800 .
C13 H13C 0.9800 .
C14 C15 1.404(7) .
C14 C19 1.403(7) .
C15 C16 1.398(7) .
C15 C20 1.493(7) .
C16 C17 1.374(9) .
C16 H16A 0.9500 .
C17 C18 1.390(9) .
C17 H17A 0.9500 .
C18 C19 1.393(7) .
C18 H18A 0.9500 .
C19 H19A 0.9500 .
C20 C21 1.389(8) .
C20 C25 1.428(9) .
C21 C22 1.388(8) .
C21 H21A 0.9500 .
C22 C23 1.388(10) .
C22 H22A 0.9500 .
C23 C24 1.364(10) .
C23 H23A 0.9500 .
C24 C25 1.388(8) .
C24 H24A 0.9500 .
C25 H25A 0.9500 .
Cl1 C1X 1.54(4) .
Cl1 C1X 1.93(4) 2_466
C1X Cl1 1.93(4) 2_466
C1X C1X 1.97(7) 2_466
C1X H1X 0.41(10) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C2 Au1 P1 C14 -179.3(3) . .
C2 Au1 P1 C10 -62.5(4) . .
C2 Au1 P1 C6 63.6(4) . .
Au1 C1 C2 C3 173(2) . .
C1 Au1 C2 C3 -177.6(8) . .
P1 Au1 C2 C3 4.4(7) . .
P1 Au1 C2 C1 -177.9(3) . .
C1 C2 C3 C4 -176(2) . .
Au1 C2 C3 C4 -4.7(9) . .
C1 C2 C3 C5 2(3) . .
Au1 C2 C3 C5 173.6(4) . .
C14 P1 C6 C8 -42.2(4) . .
C10 P1 C6 C8 -158.7(4) . .
Au1 P1 C6 C8 78.3(4) . .
C14 P1 C6 C7 81.2(5) . .
C10 P1 C6 C7 -35.3(5) . .
Au1 P1 C6 C7 -158.3(4) . .
C14 P1 C6 C9 -158.5(4) . .
C10 P1 C6 C9 85.0(5) . .
Au1 P1 C6 C9 -37.9(4) . .
C14 P1 C10 C12 -177.3(4) . .
C6 P1 C10 C12 -59.8(4) . .
Au1 P1 C10 C12 61.7(4) . .
C14 P1 C10 C13 -53.3(4) . .
C6 P1 C10 C13 64.2(5) . .
Au1 P1 C10 C13 -174.4(3) . .
C14 P1 C10 C11 65.6(4) . .
C6 P1 C10 C11 -176.9(3) . .
Au1 P1 C10 C11 -55.5(4) . .
C10 P1 C14 C15 -111.9(5) . .
C6 P1 C14 C15 125.2(5) . .
Au1 P1 C14 C15 7.8(5) . .
C10 P1 C14 C19 70.4(5) . .
C6 P1 C14 C19 -52.5(5) . .
Au1 P1 C14 C19 -169.9(4) . .
C19 C14 C15 C16 1.5(9) . .
P1 C14 C15 C16 -176.2(5) . .
C19 C14 C15 C20 -177.4(6) . .
P1 C14 C15 C20 4.9(8) . .
C14 C15 C16 C17 -1.0(11) . .
C20 C15 C16 C17 178.0(7) . .
C15 C16 C17 C18 0.6(13) . .
C16 C17 C18 C19 -0.8(12) . .
C17 C18 C19 C14 1.4(10) . .
C15 C14 C19 C18 -1.8(9) . .
P1 C14 C19 C18 176.0(5) . .
C16 C15 C20 C21 -92.9(7) . .
C14 C15 C20 C21 86.0(7) . .
C16 C15 C20 C25 78.5(7) . .
C14 C15 C20 C25 -102.6(7) . .
C25 C20 C21 C22 -0.8(7) . .
C15 C20 C21 C22 170.6(5) . .
C20 C21 C22 C23 0.0(8) . .
C21 C22 C23 C24 0.2(8) . .
C22 C23 C24 C25 0.4(9) . .
C23 C24 C25 C20 -1.3(8) . .
C21 C20 C25 C24 1.5(7) . .
C15 C20 C25 C24 -170.2(5) . .
C1X Cl1 C1X Cl1 0.000(1) 2_466 2_466
