#------------------------------------------------------------------------------
#$Date: 2016-03-21 07:20:56 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178560 $
#$URL: svn://www.crystallography.net/cod/cif/4/06/68/4066882.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4066882
loop_
_publ_author_name
'Yuki, Masahiro'
'Miyake, Yoshihiro'
'Nishibayashi, Yoshiaki'
_publ_section_title
;
 Preparation and Reactivity of a Ruthenium Complex Bearing a
 2,6-Bis(trimethylsilyl)benzenethiolate Ligand
;
_journal_issue                   18
_journal_name_full               Organometallics
_journal_page_first              4148
_journal_paper_doi               10.1021/om100689f
_journal_volume                  29
_journal_year                    2010
_chemical_formula_sum            'C47 H79 Ru2 S2 Si4'
_chemical_formula_weight         1022.72
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                92.9640(10)
_cell_angle_beta                 108.1060(10)
_cell_angle_gamma                107.0730(10)
_cell_formula_units_Z            2
_cell_length_a                   11.1331(4)
_cell_length_b                   15.9138(5)
_cell_length_c                   16.1451(5)
_cell_measurement_temperature    173(1)
_cell_volume                     2566.61(15)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      173(1)
_diffrn_measured_fraction_theta_full 0.993
_diffrn_measured_fraction_theta_max 0.993
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71069
_diffrn_reflns_av_R_equivalents  0.0409
_diffrn_reflns_av_sigmaI/netI    0.0560
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            25328
_diffrn_reflns_theta_full        27.47
_diffrn_reflns_theta_max         27.47
_diffrn_reflns_theta_min         3.00
_exptl_absorpt_coefficient_mu    0.793
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_correction_T_min  0.7356
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.323
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       platelet
_exptl_crystal_F_000             1074
_exptl_crystal_size_max          0.54
_exptl_crystal_size_mid          0.23
_exptl_crystal_size_min          0.02
_refine_diff_density_max         0.910
_refine_diff_density_min         -1.400
_refine_diff_density_rms         0.123
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.093
_refine_ls_hydrogen_treatment    riding
_refine_ls_matrix_type           full
_refine_ls_number_parameters     518
_refine_ls_number_reflns         11693
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.093
_refine_ls_R_factor_all          0.0667
_refine_ls_R_factor_gt           0.0393
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0236P)²+5.8787P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0764
_refine_ls_wR_factor_ref         0.1075
_reflns_number_gt                8579
_reflns_number_total             11693
_reflns_threshold_expression     >2σ(I)
_cod_data_source_file            om100689f_si_001.cif
_cod_data_source_block           1
_cod_database_code               4066882
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ru1 Ru 0.47683(3) 0.71239(2) 0.81901(2) 0.02848(9) Uani 1 1 d .
Ru2 Ru 0.88362(3) 0.19419(2) 0.70441(2) 0.02623(8) Uani 1 1 d .
S1 S 0.46637(12) 0.85743(7) 0.63914(8) 0.0396(3) Uani 1 1 d .
Si3 Si 0.91782(12) 0.41332(7) 0.82934(8) 0.0333(3) Uani 1 1 d .
S2 S 1.20226(11) 0.37718(8) 0.84907(7) 0.0409(3) Uani 1 1 d .
Si4 Si 1.24000(11) 0.25157(8) 0.69492(8) 0.0360(3) Uani 1 1 d .
Si1 Si 0.25464(13) 0.85713(8) 0.74377(8) 0.0399(3) Uani 1 1 d .
Si2 Si 0.57090(12) 0.68614(8) 0.61315(7) 0.0331(3) Uani 1 1 d .
C1 C 0.4079(4) 0.7637(2) 0.6827(2) 0.0259(8) Uani 1 1 d .
C17 C 0.5535(5) 0.7888(3) 0.9513(3) 0.0400(10) Uani 1 1 d .
C6 C 0.4529(4) 0.6880(2) 0.6749(2) 0.0279(8) Uani 1 1 d .
C23 C 1.0679(4) 0.3287(2) 0.7534(3) 0.0283(8) Uani 1 1 d .
C37 C 0.7623(4) 0.0557(3) 0.6562(3) 0.0339(9) Uani 1 1 d .
C35 C 0.8924(4) 0.1052(3) 0.8033(3) 0.0398(10) Uani 1 1 d .
C2 C 0.3174(4) 0.7606(3) 0.7304(3) 0.0316(9) Uani 1 1 d .
C24 C 0.9415(4) 0.3427(2) 0.7422(3) 0.0282(8) Uani 1 1 d .
C16 C 0.5183(5) 0.6961(3) 0.9572(3) 0.0412(11) Uani 1 1 d .
C28 C 1.0770(4) 0.2711(2) 0.6858(3) 0.0263(8) Uani 1 1 d .
C39 C 0.7734(4) 0.1270(3) 0.7871(3) 0.0341(9) Uani 1 1 d .
C27 C 0.9691(4) 0.2418(3) 0.6035(3) 0.0307(9) Uani 1 1 d .
H27 H 0.9778 0.2082 0.5581 0.037 Uiso 1 1 calc R
C14 C 0.6871(4) 0.7323(3) 0.8972(3) 0.0411(10) Uani 1 1 d .
C36 C 0.8857(4) 0.0596(3) 0.7221(3) 0.0372(10) Uani 1 1 d .
C5 C 0.3902(4) 0.6080(2) 0.7034(2) 0.0307(9) Uani 1 1 d .
H5 H 0.4140 0.5578 0.6945 0.037 Uiso 1 1 calc R
C26 C 0.8507(4) 0.2622(3) 0.5889(3) 0.0310(9) Uani 1 1 d .
H26 H 0.7822 0.2432 0.5345 0.037 Uiso 1 1 calc R
C15 C 0.6006(5) 0.6611(3) 0.9231(3) 0.0411(11) Uani 1 1 d .
C30 C 0.7349(5) 0.3986(3) 0.7948(4) 0.0512(12) Uani 1 1 d .
H30A H 0.7170 0.4268 0.8415 0.077 Uiso 1 1 calc R
H30B H 0.6845 0.3363 0.7823 0.077 Uiso 1 1 calc R
H30C H 0.7095 0.4252 0.7428 0.077 Uiso 1 1 calc R
C25 C 0.8375(4) 0.3119(2) 0.6584(3) 0.0283(8) Uani 1 1 d .
H25 H 0.7588 0.3251 0.6494 0.034 Uiso 1 1 calc R
C3 C 0.2594(4) 0.6789(3) 0.7576(3) 0.0335(9) Uani 1 1 d .
H3 H 0.1965 0.6758 0.7851 0.040 Uiso 1 1 calc R
C38 C 0.6925(4) 0.0976(3) 0.6959(3) 0.0306(9) Uani 1 1 d .
C13 C 0.6557(4) 0.8112(3) 0.9130(3) 0.0423(11) Uani 1 1 d .
C4 C 0.2958(4) 0.6028(3) 0.7436(3) 0.0368(10) Uani 1 1 d .
H4 H 0.2567 0.5499 0.7612 0.044 Uiso 1 1 calc R
C12 C 0.6104(5) 0.5795(3) 0.6264(4) 0.0528(13) Uani 1 1 d .
H12A H 0.5296 0.5298 0.6012 0.079 Uiso 1 1 calc R
H12B H 0.6495 0.5776 0.6880 0.079 Uiso 1 1 calc R
H12C H 0.6721 0.5767 0.5969 0.079 Uiso 1 1 calc R
C21 C 0.4176(6) 0.6449(4) 0.9952(3) 0.0646(16) Uani 1 1 d .
H21A H 0.3722 0.5862 0.9616 0.097 Uiso 1 1 calc R
H21B H 0.3538 0.6750 0.9930 0.097 Uiso 1 1 calc R
H21C H 0.4621 0.6407 1.0554 0.097 Uiso 1 1 calc R
C32 C 1.3140(5) 0.2048(3) 0.7937(3) 0.0508(12) Uani 1 1 d .
H32A H 1.4093 0.2228 0.8081 0.076 Uiso 1 1 calc R
H32B H 1.2776 0.1410 0.7816 0.076 Uiso 1 1 calc R
H32C H 1.2935 0.2264 0.8425 0.076 Uiso 1 1 calc R
C44 C 0.7303(6) 0.1641(3) 0.8565(3) 0.0576(15) Uani 1 1 d .
H44A H 0.6784 0.1160 0.8774 0.086 Uiso 1 1 calc R
H44B H 0.6773 0.2004 0.8316 0.086 Uiso 1 1 calc R
H44C H 0.8079 0.1995 0.9048 0.086 Uiso 1 1 calc R
C10 C 0.7310(5) 0.7813(3) 0.6502(3) 0.0490(12) Uani 1 1 d .
H10A H 0.7399 0.8112 0.6012 0.073 Uiso 1 1 calc R
H10B H 0.8047 0.7594 0.6726 0.073 Uiso 1 1 calc R
H10C H 0.7307 0.8223 0.6959 0.073 Uiso 1 1 calc R
C9 C 0.1478(6) 0.8693(4) 0.6327(3) 0.0581(14) Uani 1 1 d .
H9A H 0.1232 0.9217 0.6379 0.087 Uiso 1 1 calc R
H9B H 0.0687 0.8180 0.6107 0.087 Uiso 1 1 calc R
H9C H 0.1970 0.8743 0.5927 0.087 Uiso 1 1 calc R
C20 C 0.5976(6) 0.5660(3) 0.9178(3) 0.0613(15) Uani 1 1 d .
H20A H 0.6588 0.5584 0.9715 0.092 Uiso 1 1 calc R
H20B H 0.6233 0.5510 0.8690 0.092 Uiso 1 1 calc R
H20C H 0.5089 0.5277 0.9096 0.092 Uiso 1 1 calc R
C42 C 0.7111(5) 0.0116(3) 0.5617(3) 0.0494(12) Uani 1 1 d .
H42A H 0.6508 -0.0474 0.5557 0.074 Uiso 1 1 calc R
H42B H 0.7849 0.0084 0.5444 0.074 Uiso 1 1 calc R
H42C H 0.6650 0.0457 0.5247 0.074 Uiso 1 1 calc R
C43 C 0.5602(4) 0.1059(3) 0.6513(3) 0.0471(12) Uani 1 1 d .
H43A H 0.5540 0.1194 0.5932 0.071 Uiso 1 1 calc R
H43B H 0.5485 0.1528 0.6846 0.071 Uiso 1 1 calc R
H43C H 0.4918 0.0508 0.6470 0.071 Uiso 1 1 calc R
C7 C 0.3872(6) 0.9649(3) 0.7995(3) 0.0558(14) Uani 1 1 d .
H7A H 0.4727 0.9608 0.8023 0.084 Uiso 1 1 calc R
H7B H 0.3872 0.9783 0.8581 0.084 Uiso 1 1 calc R
H7C H 0.3702 1.0114 0.7667 0.084 Uiso 1 1 calc R
C40 C 1.0029(5) 0.1217(4) 0.8907(3) 0.0647(16) Uani 1 1 d .
H40A H 1.0414 0.1845 0.9119 0.097 Uiso 1 1 calc R
H40B H 1.0705 0.0989 0.8834 0.097 Uiso 1 1 calc R
H40C H 0.9674 0.0921 0.9324 0.097 Uiso 1 1 calc R
C29 C 0.9718(5) 0.3842(3) 0.9430(3) 0.0465(11) Uani 1 1 d .
H29A H 1.0531 0.4293 0.9791 0.070 Uiso 1 1 calc R
H29B H 0.9866 0.3279 0.9397 0.070 Uiso 1 1 calc R
H29C H 0.9034 0.3806 0.9683 0.070 Uiso 1 1 calc R
C11 C 0.4790(5) 0.6793(3) 0.4934(3) 0.0473(11) Uani 1 1 d .
H11A H 0.3960 0.6310 0.4757 0.071 Uiso 1 1 calc R
H11B H 0.5323 0.6693 0.4597 0.071 Uiso 1 1 calc R
H11C H 0.4612 0.7340 0.4831 0.071 Uiso 1 1 calc R
C22 C 0.5004(6) 0.8528(4) 0.9891(3) 0.0662(16) Uani 1 1 d .
H22A H 0.5519 0.8726 1.0506 0.099 Uiso 1 1 calc R
H22B H 0.4085 0.8234 0.9824 0.099 Uiso 1 1 calc R
H22C H 0.5069 0.9031 0.9584 0.099 Uiso 1 1 calc R
C31 C 1.0046(5) 0.5326(3) 0.8280(3) 0.0462(11) Uani 1 1 d .
H31A H 0.9734 0.5697 0.8592 0.069 Uiso 1 1 calc R
H31B H 0.9858 0.5434 0.7680 0.069 Uiso 1 1 calc R
H31C H 1.0993 0.5462 0.8559 0.069 Uiso 1 1 calc R
C41 C 0.9816(5) 0.0155(3) 0.7096(4) 0.0626(15) Uani 1 1 d .
H41A H 1.0696 0.0468 0.7506 0.094 Uiso 1 1 calc R
H41B H 0.9827 0.0164 0.6504 0.094 Uiso 1 1 calc R
H41C H 0.9542 -0.0450 0.7197 0.094 Uiso 1 1 calc R
C19 C 0.7984(5) 0.7253(4) 0.8681(4) 0.0695(17) Uani 1 1 d .
H19A H 0.8726 0.7260 0.9186 0.104 Uiso 1 1 calc R
H19B H 0.8255 0.7746 0.8388 0.104 Uiso 1 1 calc R
H19C H 0.7691 0.6706 0.8283 0.104 Uiso 1 1 calc R
C18 C 0.7260(6) 0.9013(3) 0.8967(4) 0.0677(17) Uani 1 1 d .
H18A H 0.7031 0.9457 0.9252 0.101 Uiso 1 1 calc R
H18B H 0.6991 0.9027 0.8344 0.101 Uiso 1 1 calc R
H18C H 0.8209 0.9131 0.9200 0.101 Uiso 1 1 calc R
C33 C 1.3602(5) 0.3597(3) 0.6902(4) 0.0531(13) Uani 1 1 d .
H33A H 1.3800 0.4017 0.7415 0.080 Uiso 1 1 calc R
H33B H 1.3213 0.3824 0.6381 0.080 Uiso 1 1 calc R
H33C H 1.4411 0.3508 0.6887 0.080 Uiso 1 1 calc R
C34 C 1.2088(5) 0.1714(3) 0.5949(3) 0.0531(13) Uani 1 1 d .
H34A H 1.2906 0.1612 0.5974 0.080 Uiso 1 1 calc R
H34B H 1.1768 0.1959 0.5426 0.080 Uiso 1 1 calc R
H34C H 1.1431 0.1160 0.5937 0.080 Uiso 1 1 calc R
C8 C 0.1442(6) 0.8272(4) 0.8127(4) 0.0613(14) Uani 1 1 d .
H8A H 0.1120 0.8754 0.8217 0.092 Uiso 1 1 calc R
H8B H 0.1944 0.8162 0.8688 0.092 Uiso 1 1 calc R
H8C H 0.0697 0.7746 0.7829 0.092 Uiso 1 1 calc R
C46 C 0.8674(12) 0.5394(8) 0.5152(12) 0.237(9) Uani 1 1 d .
C45 C 0.9302(9) 0.6297(6) 0.5660(7) 0.123(3) Uani 1 1 d .
C47 C 0.9295(9) 0.4838(7) 0.5009(9) 0.157(5) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_3
C16 Ru1 C15 38.18(17) .
C16 Ru1 C17 38.23(15) .
C15 Ru1 C17 63.65(16) .
C16 Ru1 C13 64.14(17) .
C15 Ru1 C13 63.96(17) .
C17 Ru1 C13 38.03(17) .
C16 Ru1 C4 106.52(16) .
C15 Ru1 C4 108.41(16) .
C17 Ru1 C4 134.72(17) .
C13 Ru1 C4 170.62(16) .
C16 Ru1 C5 127.79(15) .
C15 Ru1 C5 105.82(16) .
C17 Ru1 C5 165.97(16) .
C13 Ru1 C5 147.96(17) .
C4 Ru1 C5 36.86(15) .
C16 Ru1 C3 107.44(17) .
C15 Ru1 C3 132.57(17) .
C17 Ru1 C3 112.60(17) .
C13 Ru1 C3 143.43(17) .
C4 Ru1 C3 37.65(15) .
C5 Ru1 C3 66.74(15) .
C16 Ru1 C14 63.73(18) .
C15 Ru1 C14 38.06(17) .
C17 Ru1 C14 63.31(17) .
C13 Ru1 C14 38.01(17) .
C4 Ru1 C14 138.55(17) .
C5 Ru1 C14 114.90(16) .
C3 Ru1 C14 170.40(16) .
C16 Ru1 C6 160.91(15) .
C15 Ru1 C6 124.62(16) .
C17 Ru1 C6 155.87(16) .
C13 Ru1 C6 120.96(16) .
C4 Ru1 C6 67.50(14) .
C5 Ru1 C6 37.59(13) .
C3 Ru1 C6 79.27(15) .
C14 Ru1 C6 107.91(16) .
C16 Ru1 C2 129.30(17) .
C15 Ru1 C2 166.65(17) .
C17 Ru1 C2 109.33(15) .
C13 Ru1 C2 118.37(16) .
C4 Ru1 C2 67.68(15) .
C5 Ru1 C2 78.93(14) .
C3 Ru1 C2 37.36(14) .
C14 Ru1 C2 151.14(16) .
C6 Ru1 C2 66.67(14) .
C16 Ru1 C1 162.59(15) .
C15 Ru1 C1 157.20(16) .
C17 Ru1 C1 127.61(14) .
C13 Ru1 C1 111.17(14) .
C4 Ru1 C1 78.00(14) .
C5 Ru1 C1 65.70(13) .
C3 Ru1 C1 65.54(14) .
C14 Ru1 C1 124.01(15) .
C6 Ru1 C1 36.40(13) .
C2 Ru1 C1 36.09(14) .
C37 Ru2 C36 38.49(15) .
C37 Ru2 C35 64.17(16) .
C36 Ru2 C35 38.35(16) .
C37 Ru2 C38 38.17(15) .
C36 Ru2 C38 64.24(16) .
C35 Ru2 C38 64.14(16) .
C37 Ru2 C25 127.49(15) .
C36 Ru2 C25 165.80(15) .
C35 Ru2 C25 148.60(17) .
C38 Ru2 C25 105.81(15) .
C37 Ru2 C26 105.71(15) .
C36 Ru2 C26 133.25(16) .
C35 Ru2 C26 169.88(15) .
C38 Ru2 C26 108.31(15) .
C25 Ru2 C26 37.52(14) .
C37 Ru2 C27 106.87(15) .
C36 Ru2 C27 111.32(16) .
C35 Ru2 C27 142.69(17) .
C38 Ru2 C27 132.28(15) .
C25 Ru2 C27 66.96(15) .
C26 Ru2 C27 37.33(15) .
C37 Ru2 C39 63.45(15) .
C36 Ru2 C39 63.44(16) .
C35 Ru2 C39 37.73(16) .
C38 Ru2 C39 38.14(15) .
C25 Ru2 C39 115.76(15) .
C26 Ru2 C39 139.45(16) .
C27 Ru2 C39 169.89(15) .
C37 Ru2 C24 160.86(15) .
C36 Ru2 C24 156.55(16) .
C35 Ru2 C24 121.80(15) .
C38 Ru2 C24 124.90(15) .
C25 Ru2 C24 37.40(14) .
C26 Ru2 C24 67.76(14) .
C27 Ru2 C24 79.19(14) .
C39 Ru2 C24 109.01(14) .
C37 Ru2 C28 128.92(15) .
C36 Ru2 C28 108.35(15) .
C35 Ru2 C28 118.04(16) .
C38 Ru2 C28 166.30(14) .
C25 Ru2 C28 79.10(14) .
C26 Ru2 C28 67.57(14) .
C27 Ru2 C28 37.38(14) .
C39 Ru2 C28 150.96(15) .
C24 Ru2 C28 66.66(13) .
C37 Ru2 C23 162.59(15) .
C36 Ru2 C23 127.65(15) .
C35 Ru2 C23 111.87(14) .
C38 Ru2 C23 157.68(15) .
C25 Ru2 C23 65.38(13) .
C26 Ru2 C23 77.72(14) .
C27 Ru2 C23 65.21(14) .
C39 Ru2 C23 124.90(14) .
C24 Ru2 C23 36.27(13) .
C28 Ru2 C23 35.95(13) .
C31 Si3 C29 111.3(2) .
C31 Si3 C30 106.5(2) .
C29 Si3 C30 108.3(2) .
C31 Si3 C24 108.50(19) .
C29 Si3 C24 114.8(2) .
C30 Si3 C24 107.0(2) .
C32 Si4 C33 110.5(2) .
C32 Si4 C34 107.5(2) .
C33 Si4 C34 107.6(2) .
C32 Si4 C28 115.8(2) .
C33 Si4 C28 107.4(2) .
C34 Si4 C28 107.8(2) .
C7 Si1 C9 110.4(2) .
C7 Si1 C8 107.5(3) .
C9 Si1 C8 107.3(3) .
C7 Si1 C2 115.0(2) .
C9 Si1 C2 108.9(2) .
C8 Si1 C2 107.4(2) .
C11 Si2 C10 110.5(2) .
C11 Si2 C12 106.8(2) .
C10 Si2 C12 108.8(2) .
C11 Si2 C6 107.9(2) .
C10 Si2 C6 115.5(2) .
C12 Si2 C6 106.9(2) .
C2 C1 C6 118.8(3) .
C2 C1 S1 120.5(3) .
C6 C1 S1 120.7(3) .
C2 C1 Ru1 68.0(2) .
C6 C1 Ru1 67.7(2) .
S1 C1 Ru1 135.83(19) .
C13 C17 C16 108.7(4) .
C13 C17 C22 126.4(4) .
C16 C17 C22 124.5(5) .
C13 C17 Ru1 71.1(2) .
C16 C17 Ru1 70.8(2) .
C22 C17 Ru1 129.1(3) .
C5 C6 C1 118.4(3) .
C5 C6 Si2 119.3(3) .
C1 C6 Si2 121.6(3) .
C5 C6 Ru1 68.6(2) .
C1 C6 Ru1 75.9(2) .
Si2 C6 Ru1 134.3(2) .
C28 C23 C24 118.9(3) .
C28 C23 S2 121.2(3) .
C24 C23 S2 119.9(3) .
C28 C23 Ru2 67.64(19) .
C24 C23 Ru2 67.2(2) .
S2 C23 Ru2 136.6(2) .
C38 C37 C36 108.7(4) .
C38 C37 C42 125.1(4) .
C36 C37 C42 126.2(4) .
C38 C37 Ru2 71.6(2) .
C36 C37 Ru2 71.2(2) .
C42 C37 Ru2 125.1(3) .
C39 C35 C36 107.6(4) .
C39 C35 C40 126.7(5) .
C36 C35 C40 125.6(5) .
C39 C35 Ru2 71.5(2) .
C36 C35 Ru2 70.6(2) .
C40 C35 Ru2 125.9(3) .
C3 C2 C1 119.3(4) .
C3 C2 Si1 118.9(3) .
C1 C2 Si1 121.3(3) .
C3 C2 Ru1 68.8(2) .
C1 C2 Ru1 75.9(2) .
Si1 C2 Ru1 134.09(19) .
C25 C24 C23 118.7(3) .
C25 C24 Si3 118.8(3) .
C23 C24 Si3 121.9(3) .
C25 C24 Ru2 68.8(2) .
C23 C24 Ru2 76.5(2) .
Si3 C24 Ru2 132.58(19) .
C15 C16 C17 107.4(4) .
C15 C16 C21 125.8(4) .
C17 C16 C21 126.7(5) .
C15 C16 Ru1 70.9(2) .
C17 C16 Ru1 71.0(2) .
C21 C16 Ru1 125.2(3) .
C27 C28 C23 118.9(3) .
C27 C28 Si4 118.8(3) .
C23 C28 Si4 121.2(3) .
C27 C28 Ru2 68.6(2) .
C23 C28 Ru2 76.4(2) .
Si4 C28 Ru2 136.09(19) .
C35 C39 C38 109.2(4) .
C35 C39 C44 125.3(4) .
C38 C39 C44 125.0(4) .
C35 C39 Ru2 70.8(2) .
C38 C39 Ru2 70.6(2) .
C44 C39 Ru2 130.9(3) .
C26 C27 C28 122.1(4) .
C26 C27 Ru2 71.3(2) .
C28 C27 Ru2 74.0(2) .
C26 C27 H27 119.0 .
C28 C27 H27 119.0 .
Ru2 C27 H27 128.0 .
C15 C14 C13 107.9(4) .
C15 C14 C19 124.7(5) .
C13 C14 C19 127.1(5) .
C15 C14 Ru1 70.0(2) .
C13 C14 Ru1 70.3(2) .
C19 C14 Ru1 130.0(3) .
C37 C36 C35 107.5(4) .
C37 C36 C41 125.5(4) .
C35 C36 C41 126.7(4) .
C37 C36 Ru2 70.3(2) .
C35 C36 Ru2 71.0(2) .
C41 C36 Ru2 128.7(3) .
C4 C5 C6 122.4(4) .
C4 C5 Ru1 71.4(2) .
C6 C5 Ru1 73.8(2) .
C4 C5 H5 118.8 .
C6 C5 H5 118.8 .
Ru1 C5 H5 128.4 .
C27 C26 C25 118.6(4) .
C27 C26 Ru2 71.4(2) .
C25 C26 Ru2 71.2(2) .
C27 C26 H26 120.7 .
C25 C26 H26 120.7 .
Ru2 C26 H26 128.9 .
C16 C15 C14 108.3(4) .
C16 C15 C20 125.1(5) .
C14 C15 C20 126.5(5) .
C16 C15 Ru1 70.9(2) .
C14 C15 Ru1 71.9(2) .
C20 C15 Ru1 124.0(3) .
Si3 C30 H30A 109.5 .
Si3 C30 H30B 109.5 .
H30A C30 H30B 109.5 .
Si3 C30 H30C 109.5 .
H30A C30 H30C 109.5 .
H30B C30 H30C 109.5 .
C26 C25 C24 121.9(4) .
C26 C25 Ru2 71.3(2) .
C24 C25 Ru2 73.8(2) .
C26 C25 H25 119.0 .
C24 C25 H25 119.0 .
Ru2 C25 H25 128.2 .
C4 C3 C2 121.3(4) .
C4 C3 Ru1 70.8(2) .
C2 C3 Ru1 73.8(2) .
C4 C3 H3 119.4 .
C2 C3 H3 119.4 .
Ru1 C3 H3 128.3 .
C37 C38 C39 107.0(4) .
C37 C38 C43 125.8(4) .
C39 C38 C43 127.2(4) .
C37 C38 Ru2 70.3(2) .
C39 C38 Ru2 71.3(2) .
C43 C38 Ru2 125.1(3) .
C17 C13 C14 107.6(4) .
C17 C13 C18 127.5(5) .
C14 C13 C18 124.8(5) .
C17 C13 Ru1 70.8(2) .
C14 C13 Ru1 71.7(2) .
C18 C13 Ru1 125.8(3) .
C5 C4 C3 119.2(4) .
C5 C4 Ru1 71.7(2) .
C3 C4 Ru1 71.6(2) .
C5 C4 H4 120.4 .
C3 C4 H4 120.4 .
Ru1 C4 H4 128.4 .
Si2 C12 H12A 109.5 .
Si2 C12 H12B 109.5 .
H12A C12 H12B 109.5 .
Si2 C12 H12C 109.5 .
H12A C12 H12C 109.5 .
H12B C12 H12C 109.5 .
C16 C21 H21A 109.5 .
C16 C21 H21B 109.5 .
H21A C21 H21B 109.5 .
C16 C21 H21C 109.5 .
H21A C21 H21C 109.5 .
H21B C21 H21C 109.5 .
Si4 C32 H32A 109.5 .
Si4 C32 H32B 109.5 .
H32A C32 H32B 109.5 .
Si4 C32 H32C 109.5 .
H32A C32 H32C 109.5 .
H32B C32 H32C 109.5 .
C39 C44 H44A 109.5 .
C39 C44 H44B 109.5 .
H44A C44 H44B 109.5 .
C39 C44 H44C 109.5 .
H44A C44 H44C 109.5 .
H44B C44 H44C 109.5 .
Si2 C10 H10A 109.5 .
Si2 C10 H10B 109.5 .
H10A C10 H10B 109.5 .
Si2 C10 H10C 109.5 .
H10A C10 H10C 109.5 .
H10B C10 H10C 109.5 .
Si1 C9 H9A 109.5 .
Si1 C9 H9B 109.5 .
H9A C9 H9B 109.5 .
Si1 C9 H9C 109.5 .
H9A C9 H9C 109.5 .
H9B C9 H9C 109.5 .
C15 C20 H20A 109.5 .
C15 C20 H20B 109.5 .
H20A C20 H20B 109.5 .
C15 C20 H20C 109.5 .
H20A C20 H20C 109.5 .
H20B C20 H20C 109.5 .
C37 C42 H42A 109.5 .
C37 C42 H42B 109.5 .
H42A C42 H42B 109.5 .
C37 C42 H42C 109.5 .
H42A C42 H42C 109.5 .
H42B C42 H42C 109.5 .
C38 C43 H43A 109.5 .
C38 C43 H43B 109.5 .
H43A C43 H43B 109.5 .
C38 C43 H43C 109.5 .
H43A C43 H43C 109.5 .
H43B C43 H43C 109.5 .
Si1 C7 H7A 109.5 .
Si1 C7 H7B 109.5 .
H7A C7 H7B 109.5 .
Si1 C7 H7C 109.5 .
H7A C7 H7C 109.5 .
H7B C7 H7C 109.5 .
C35 C40 H40A 109.5 .
C35 C40 H40B 109.5 .
H40A C40 H40B 109.5 .
C35 C40 H40C 109.5 .
H40A C40 H40C 109.5 .
H40B C40 H40C 109.5 .
Si3 C29 H29A 109.5 .
Si3 C29 H29B 109.5 .
H29A C29 H29B 109.5 .
Si3 C29 H29C 109.5 .
H29A C29 H29C 109.5 .
H29B C29 H29C 109.5 .
Si2 C11 H11A 109.5 .
Si2 C11 H11B 109.5 .
H11A C11 H11B 109.5 .
Si2 C11 H11C 109.5 .
H11A C11 H11C 109.5 .
H11B C11 H11C 109.5 .
C17 C22 H22A 109.5 .
C17 C22 H22B 109.5 .
H22A C22 H22B 109.5 .
C17 C22 H22C 109.5 .
H22A C22 H22C 109.5 .
H22B C22 H22C 109.5 .
Si3 C31 H31A 109.5 .
Si3 C31 H31B 109.5 .
H31A C31 H31B 109.5 .
Si3 C31 H31C 109.5 .
H31A C31 H31C 109.5 .
H31B C31 H31C 109.5 .
C36 C41 H41A 109.5 .
C36 C41 H41B 109.5 .
H41A C41 H41B 109.5 .
C36 C41 H41C 109.5 .
H41A C41 H41C 109.5 .
H41B C41 H41C 109.5 .
C14 C19 H19A 109.5 .
C14 C19 H19B 109.5 .
H19A C19 H19B 109.5 .
C14 C19 H19C 109.5 .
H19A C19 H19C 109.5 .
H19B C19 H19C 109.5 .
C13 C18 H18A 109.5 .
C13 C18 H18B 109.5 .
H18A C18 H18B 109.5 .
C13 C18 H18C 109.5 .
H18A C18 H18C 109.5 .
H18B C18 H18C 109.5 .
Si4 C33 H33A 109.5 .
Si4 C33 H33B 109.5 .
H33A C33 H33B 109.5 .
Si4 C33 H33C 109.5 .
H33A C33 H33C 109.5 .
H33B C33 H33C 109.5 .
Si4 C34 H34A 109.5 .
Si4 C34 H34B 109.5 .
H34A C34 H34B 109.5 .
Si4 C34 H34C 109.5 .
H34A C34 H34C 109.5 .
H34B C34 H34C 109.5 .
Si1 C8 H8A 109.5 .
Si1 C8 H8B 109.5 .
H8A C8 H8B 109.5 .
Si1 C8 H8C 109.5 .
H8A C8 H8C 109.5 .
H8B C8 H8C 109.5 .
C47 C46 C45 126.6(12) .
C46 C47 C47 122.1(13) 2_766
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ru1 C16 2.179(4) .
Ru1 C15 2.179(4) .
Ru1 C17 2.182(4) .
Ru1 C13 2.185(4) .
Ru1 C4 2.185(4) .
Ru1 C5 2.190(4) .
Ru1 C3 2.196(4) .
Ru1 C14 2.205(4) .
Ru1 C6 2.257(4) .
Ru1 C2 2.263(4) .
Ru1 C1 2.368(4) .
Ru2 C37 2.170(4) .
Ru2 C36 2.182(4) .
Ru2 C35 2.187(4) .
Ru2 C38 2.188(3) .
Ru2 C25 2.190(4) .
Ru2 C26 2.191(4) .
Ru2 C27 2.192(4) .
Ru2 C39 2.197(4) .
Ru2 C24 2.255(4) .
Ru2 C28 2.262(3) .
Ru2 C23 2.378(4) .
S1 C1 1.721(4) .
Si3 C31 1.865(4) .
Si3 C29 1.873(5) .
Si3 C30 1.875(5) .
Si3 C24 1.885(4) .
S2 C23 1.727(4) .
Si4 C32 1.856(5) .
Si4 C33 1.867(5) .
Si4 C34 1.880(5) .
Si4 C28 1.892(4) .
Si1 C7 1.860(5) .
Si1 C9 1.874(5) .
Si1 C8 1.882(5) .
Si1 C2 1.893(4) .
Si2 C11 1.866(5) .
Si2 C10 1.867(5) .
Si2 C12 1.880(5) .
Si2 C6 1.885(4) .
C1 C2 1.438(5) .
C1 C6 1.448(5) .
C17 C13 1.423(7) .
C17 C16 1.428(6) .
C17 C22 1.507(6) .
C6 C5 1.434(5) .
C23 C28 1.436(5) .
C23 C24 1.447(5) .
C37 C38 1.425(6) .
C37 C36 1.434(6) .
C37 C42 1.503(6) .
C35 C39 1.417(6) .
C35 C36 1.435(6) .
C35 C40 1.505(6) .
C2 C3 1.429(5) .
C24 C25 1.426(5) .
C16 C15 1.426(7) .
C16 C21 1.497(7) .
C28 C27 1.429(5) .
C39 C38 1.433(6) .
C39 C44 1.505(6) .
C27 C26 1.402(6) .
C27 H27 0.9300 .
C14 C15 1.430(6) .
C14 C13 1.430(6) .
C14 C19 1.485(7) .
C36 C41 1.495(6) .
C5 C4 1.383(6) .
C5 H5 0.9300 .
C26 C25 1.409(5) .
C26 H26 0.9300 .
C15 C20 1.503(6) .
C30 H30A 0.9600 .
C30 H30B 0.9600 .
C30 H30C 0.9600 .
C25 H25 0.9300 .
C3 C4 1.414(6) .
C3 H3 0.9300 .
C38 C43 1.473(6) .
C13 C18 1.499(6) .
C4 H4 0.9300 .
C12 H12A 0.9600 .
C12 H12B 0.9600 .
C12 H12C 0.9600 .
C21 H21A 0.9600 .
C21 H21B 0.9600 .
C21 H21C 0.9600 .
C32 H32A 0.9600 .
C32 H32B 0.9600 .
C32 H32C 0.9600 .
C44 H44A 0.9600 .
C44 H44B 0.9600 .
C44 H44C 0.9600 .
C10 H10A 0.9600 .
C10 H10B 0.9600 .
C10 H10C 0.9600 .
C9 H9A 0.9600 .
C9 H9B 0.9600 .
C9 H9C 0.9600 .
C20 H20A 0.9600 .
C20 H20B 0.9600 .
C20 H20C 0.9600 .
C42 H42A 0.9600 .
C42 H42B 0.9600 .
C42 H42C 0.9600 .
C43 H43A 0.9600 .
C43 H43B 0.9600 .
C43 H43C 0.9600 .
C7 H7A 0.9600 .
C7 H7B 0.9600 .
C7 H7C 0.9600 .
C40 H40A 0.9600 .
C40 H40B 0.9600 .
C40 H40C 0.9600 .
C29 H29A 0.9600 .
C29 H29B 0.9600 .
C29 H29C 0.9600 .
C11 H11A 0.9600 .
C11 H11B 0.9600 .
C11 H11C 0.9600 .
C22 H22A 0.9600 .
C22 H22B 0.9600 .
C22 H22C 0.9600 .
C31 H31A 0.9600 .
C31 H31B 0.9600 .
C31 H31C 0.9600 .
C41 H41A 0.9600 .
C41 H41B 0.9600 .
C41 H41C 0.9600 .
C19 H19A 0.9600 .
C19 H19B 0.9600 .
C19 H19C 0.9600 .
C18 H18A 0.9600 .
C18 H18B 0.9600 .
C18 H18C 0.9600 .
C33 H33A 0.9600 .
C33 H33B 0.9600 .
C33 H33C 0.9600 .
C34 H34A 0.9600 .
C34 H34B 0.9600 .
C34 H34C 0.9600 .
C8 H8A 0.9600 .
C8 H8B 0.9600 .
C8 H8C 0.9600 .
C46 C47 1.323(13) .
C46 C45 1.469(13) .
C47 C47 1.512(18) 2_766
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_4
C16 Ru1 C1 C2 -38.6(6) .
C15 Ru1 C1 C2 177.6(3) .
C17 Ru1 C1 C2 -69.7(3) .
C13 Ru1 C1 C2 -109.5(2) .
C4 Ru1 C1 C2 68.4(2) .
C5 Ru1 C1 C2 105.2(2) .
C3 Ru1 C1 C2 30.9(2) .
C14 Ru1 C1 C2 -150.2(2) .
C6 Ru1 C1 C2 136.7(3) .
C16 Ru1 C1 C6 -175.3(5) .
C15 Ru1 C1 C6 40.9(5) .
C17 Ru1 C1 C6 153.7(2) .
C13 Ru1 C1 C6 113.8(2) .
C4 Ru1 C1 C6 -68.2(2) .
C5 Ru1 C1 C6 -31.5(2) .
C3 Ru1 C1 C6 -105.8(2) .
C14 Ru1 C1 C6 73.1(3) .
C2 Ru1 C1 C6 -136.7(3) .
C16 Ru1 C1 S1 73.1(6) .
C15 Ru1 C1 S1 -70.7(5) .
C17 Ru1 C1 S1 42.1(4) .
C13 Ru1 C1 S1 2.2(3) .
C4 Ru1 C1 S1 -179.8(3) .
C5 Ru1 C1 S1 -143.1(3) .
C3 Ru1 C1 S1 142.6(3) .
C14 Ru1 C1 S1 -38.5(4) .
C6 Ru1 C1 S1 -111.6(4) .
C2 Ru1 C1 S1 111.7(4) .
C16 Ru1 C17 C13 118.6(4) .
C15 Ru1 C17 C13 80.7(3) .
C4 Ru1 C17 C13 171.0(3) .
C5 Ru1 C17 C13 124.0(7) .
C3 Ru1 C17 C13 -151.6(3) .
C14 Ru1 C17 C13 37.9(3) .
C6 Ru1 C17 C13 -35.8(5) .
C2 Ru1 C17 C13 -111.6(3) .
C1 Ru1 C17 C13 -75.8(3) .
C15 Ru1 C17 C16 -37.9(3) .
C13 Ru1 C17 C16 -118.6(4) .
C4 Ru1 C17 C16 52.4(4) .
C5 Ru1 C17 C16 5.4(8) .
C3 Ru1 C17 C16 89.8(3) .
C14 Ru1 C17 C16 -80.7(3) .
C6 Ru1 C17 C16 -154.4(4) .
C2 Ru1 C17 C16 129.7(3) .
C1 Ru1 C17 C16 165.6(3) .
C16 Ru1 C17 C22 -119.3(6) .
C15 Ru1 C17 C22 -157.3(5) .
C13 Ru1 C17 C22 122.1(6) .
C4 Ru1 C17 C22 -66.9(5) .
C5 Ru1 C17 C22 -113.9(7) .
C3 Ru1 C17 C22 -29.6(5) .
C14 Ru1 C17 C22 160.0(5) .
C6 Ru1 C17 C22 86.3(6) .
C2 Ru1 C17 C22 10.4(5) .
C1 Ru1 C17 C22 46.2(5) .
C2 C1 C6 C5 9.2(5) .
S1 C1 C6 C5 -173.1(3) .
Ru1 C1 C6 C5 55.8(3) .
C2 C1 C6 Si2 179.7(3) .
S1 C1 C6 Si2 -2.6(4) .
Ru1 C1 C6 Si2 -133.7(3) .
C2 C1 C6 Ru1 -46.5(3) .
S1 C1 C6 Ru1 131.1(3) .
C11 Si2 C6 C5 101.3(3) .
C10 Si2 C6 C5 -134.5(3) .
C12 Si2 C6 C5 -13.2(4) .
C11 Si2 C6 C1 -69.1(4) .
C10 Si2 C6 C1 55.1(4) .
C12 Si2 C6 C1 176.4(3) .
C11 Si2 C6 Ru1 -170.8(3) .
C10 Si2 C6 Ru1 -46.6(3) .
C12 Si2 C6 Ru1 74.7(3) .
C16 Ru1 C6 C5 47.0(6) .
C15 Ru1 C6 C5 69.3(3) .
C17 Ru1 C6 C5 172.1(4) .
C13 Ru1 C6 C5 147.3(2) .
C4 Ru1 C6 C5 -28.2(2) .
C3 Ru1 C6 C5 -65.6(2) .
C14 Ru1 C6 C5 107.8(3) .
C2 Ru1 C6 C5 -102.6(3) .
C1 Ru1 C6 C5 -128.7(3) .
C16 Ru1 C6 C1 175.7(4) .
C15 Ru1 C6 C1 -162.0(2) .
C17 Ru1 C6 C1 -59.2(5) .
C13 Ru1 C6 C1 -84.0(3) .
C4 Ru1 C6 C1 100.5(2) .
C5 Ru1 C6 C1 128.7(3) .
C3 Ru1 C6 C1 63.1(2) .
C14 Ru1 C6 C1 -123.5(2) .
C2 Ru1 C6 C1 26.1(2) .
C16 Ru1 C6 Si2 -63.6(6) .
C15 Ru1 C6 Si2 -41.3(3) .
C17 Ru1 C6 Si2 61.5(5) .
C13 Ru1 C6 Si2 36.7(3) .
C4 Ru1 C6 Si2 -138.8(3) .
C5 Ru1 C6 Si2 -110.6(4) .
C3 Ru1 C6 Si2 -176.2(3) .
C14 Ru1 C6 Si2 -2.8(3) .
C2 Ru1 C6 Si2 146.8(3) .
C1 Ru1 C6 Si2 120.7(4) .
C37 Ru2 C23 C28 34.8(6) .
C36 Ru2 C23 C28 67.3(3) .
C35 Ru2 C23 C28 108.0(2) .
C38 Ru2 C23 C28 -177.0(3) .
C25 Ru2 C23 C28 -106.1(2) .
C26 Ru2 C23 C28 -68.6(2) .
C27 Ru2 C23 C28 -31.3(2) .
C39 Ru2 C23 C28 148.6(2) .
C24 Ru2 C23 C28 -137.6(3) .
C37 Ru2 C23 C24 172.4(4) .
C36 Ru2 C23 C24 -155.1(2) .
C35 Ru2 C23 C24 -114.4(2) .
C38 Ru2 C23 C24 -39.4(5) .
C25 Ru2 C23 C24 31.5(2) .
C26 Ru2 C23 C24 69.0(2) .
C27 Ru2 C23 C24 106.3(2) .
C39 Ru2 C23 C24 -73.8(3) .
C28 Ru2 C23 C24 137.6(3) .
C37 Ru2 C23 S2 -77.6(6) .
C36 Ru2 C23 S2 -45.1(4) .
C35 Ru2 C23 S2 -4.4(4) .
C38 Ru2 C23 S2 70.6(5) .
C25 Ru2 C23 S2 141.5(3) .
C26 Ru2 C23 S2 179.0(3) .
C27 Ru2 C23 S2 -143.7(4) .
C39 Ru2 C23 S2 36.2(4) .
C24 Ru2 C23 S2 110.0(4) .
C28 Ru2 C23 S2 -112.4(4) .
C36 Ru2 C37 C38 118.0(4) .
C35 Ru2 C37 C38 80.3(3) .
C25 Ru2 C37 C38 -65.1(3) .
C26 Ru2 C37 C38 -99.8(2) .
C27 Ru2 C37 C38 -138.7(2) .
C39 Ru2 C37 C38 38.1(2) .
C24 Ru2 C37 C38 -32.7(6) .
C28 Ru2 C37 C38 -173.4(2) .
C23 Ru2 C37 C38 161.1(4) .
C35 Ru2 C37 C36 -37.7(3) .
C38 Ru2 C37 C36 -118.0(4) .
C25 Ru2 C37 C36 176.8(2) .
C26 Ru2 C37 C36 142.2(3) .
C27 Ru2 C37 C36 103.2(3) .
C39 Ru2 C37 C36 -79.9(3) .
C24 Ru2 C37 C36 -150.7(4) .
C28 Ru2 C37 C36 68.6(3) .
C23 Ru2 C37 C36 43.1(6) .
C36 Ru2 C37 C42 -121.6(5) .
C35 Ru2 C37 C42 -159.3(4) .
C38 Ru2 C37 C42 120.4(5) .
C25 Ru2 C37 C42 55.3(4) .
C26 Ru2 C37 C42 20.6(4) .
C27 Ru2 C37 C42 -18.3(4) .
C39 Ru2 C37 C42 158.5(4) .
C24 Ru2 C37 C42 87.7(6) .
C28 Ru2 C37 C42 -53.0(4) .
C23 Ru2 C37 C42 -78.5(6) .
C37 Ru2 C35 C39 -79.3(3) .
C36 Ru2 C35 C39 -117.1(3) .
C38 Ru2 C35 C39 -36.7(2) .
C25 Ru2 C35 C39 41.0(4) .
C26 Ru2 C35 C39 -79.9(10) .
C27 Ru2 C35 C39 -163.4(2) .
C24 Ru2 C35 C39 79.9(3) .
C28 Ru2 C35 C39 158.5(2) .
C23 Ru2 C35 C39 119.3(2) .
C37 Ru2 C35 C36 37.8(2) .
C38 Ru2 C35 C36 80.5(3) .
C25 Ru2 C35 C36 158.2(3) .
C26 Ru2 C35 C36 37.2(11) .
C27 Ru2 C35 C36 -46.2(4) .
C39 Ru2 C35 C36 117.1(3) .
C24 Ru2 C35 C36 -163.0(2) .
C28 Ru2 C35 C36 -84.4(3) .
C23 Ru2 C35 C36 -123.6(2) .
C37 Ru2 C35 C40 158.3(5) .
C36 Ru2 C35 C40 120.5(6) .
C38 Ru2 C35 C40 -159.1(5) .
C25 Ru2 C35 C40 -81.3(6) .
C26 Ru2 C35 C40 157.7(8) .
C27 Ru2 C35 C40 74.3(5) .
C39 Ru2 C35 C40 -122.4(6) .
C24 Ru2 C35 C40 -42.5(5) .
C28 Ru2 C35 C40 36.1(5) .
C23 Ru2 C35 C40 -3.1(5) .
C6 C1 C2 C3 -9.0(5) .
S1 C1 C2 C3 173.4(3) .
Ru1 C1 C2 C3 -55.4(3) .
C6 C1 C2 Si1 179.8(3) .
S1 C1 C2 Si1 2.1(4) .
Ru1 C1 C2 Si1 133.4(3) .
C6 C1 C2 Ru1 46.4(3) .
S1 C1 C2 Ru1 -131.3(3) .
C7 Si1 C2 C3 130.0(3) .
C9 Si1 C2 C3 -105.5(4) .
C8 Si1 C2 C3 10.4(4) .
C7 Si1 C2 C1 -58.7(4) .
C9 Si1 C2 C1 65.8(4) .
C8 Si1 C2 C1 -178.3(3) .
C7 Si1 C2 Ru1 42.4(4) .
C9 Si1 C2 Ru1 166.9(3) .
C8 Si1 C2 Ru1 -77.2(3) .
C16 Ru1 C2 C3 -64.3(3) .
C15 Ru1 C2 C3 -46.2(7) .
C17 Ru1 C2 C3 -102.2(3) .
C13 Ru1 C2 C3 -142.8(2) .
C4 Ru1 C2 C3 29.2(2) .
C5 Ru1 C2 C3 66.0(2) .
C14 Ru1 C2 C3 -171.7(3) .
C6 Ru1 C2 C3 103.4(2) .
C1 Ru1 C2 C3 129.7(3) .
C16 Ru1 C2 C1 166.0(2) .
C15 Ru1 C2 C1 -175.9(6) .
C17 Ru1 C2 C1 128.1(2) .
C13 Ru1 C2 C1 87.5(2) .
C4 Ru1 C2 C1 -100.5(2) .
C5 Ru1 C2 C1 -63.7(2) .
C3 Ru1 C2 C1 -129.7(3) .
C14 Ru1 C2 C1 58.6(4) .
C6 Ru1 C2 C1 -26.3(2) .
C16 Ru1 C2 Si1 45.9(4) .
C15 Ru1 C2 Si1 64.0(8) .
C17 Ru1 C2 Si1 8.0(3) .
C13 Ru1 C2 Si1 -32.7(4) .
C4 Ru1 C2 Si1 139.4(3) .
C5 Ru1 C2 Si1 176.2(3) .
C3 Ru1 C2 Si1 110.2(4) .
C14 Ru1 C2 Si1 -61.6(5) .
C6 Ru1 C2 Si1 -146.5(3) .
C1 Ru1 C2 Si1 -120.1(4) .
C28 C23 C24 C25 -10.9(5) .
S2 C23 C24 C25 171.8(3) .
Ru2 C23 C24 C25 -56.3(3) .
C28 C23 C24 Si3 177.5(3) .
S2 C23 C24 Si3 0.2(4) .
Ru2 C23 C24 Si3 132.1(3) .
C28 C23 C24 Ru2 45.4(3) .
S2 C23 C24 Ru2 -131.9(3) .
C31 Si3 C24 C25 -97.7(3) .
C29 Si3 C24 C25 137.0(3) .
C30 Si3 C24 C25 16.8(4) .
C31 Si3 C24 C23 73.9(4) .
C29 Si3 C24 C23 -51.3(4) .
C30 Si3 C24 C23 -171.6(3) .
C31 Si3 C24 Ru2 175.4(3) .
C29 Si3 C24 Ru2 50.1(3) .
C30 Si3 C24 Ru2 -70.1(3) .
C37 Ru2 C24 C25 -44.5(5) .
C36 Ru2 C24 C25 -174.6(3) .
C35 Ru2 C24 C25 -147.4(2) .
C38 Ru2 C24 C25 -68.5(3) .
C26 Ru2 C24 C25 28.8(2) .
C27 Ru2 C24 C25 66.0(2) .
C39 Ru2 C24 C25 -107.8(2) .
C28 Ru2 C24 C25 103.0(2) .
C23 Ru2 C24 C25 128.6(3) .
C37 Ru2 C24 C23 -173.1(4) .
C36 Ru2 C24 C23 56.8(5) .
C35 Ru2 C24 C23 84.0(3) .
C38 Ru2 C24 C23 162.9(2) .
C25 Ru2 C24 C23 -128.6(3) .
C26 Ru2 C24 C23 -99.7(2) .
C27 Ru2 C24 C23 -62.5(2) .
C39 Ru2 C24 C23 123.6(2) .
C28 Ru2 C24 C23 -25.5(2) .
C37 Ru2 C24 Si3 65.7(6) .
C36 Ru2 C24 Si3 -64.4(5) .
C35 Ru2 C24 Si3 -37.2(3) .
C38 Ru2 C24 Si3 41.7(3) .
C25 Ru2 C24 Si3 110.3(4) .
C26 Ru2 C24 Si3 139.1(3) .
C27 Ru2 C24 Si3 176.3(3) .
C39 Ru2 C24 Si3 2.4(3) .
C28 Ru2 C24 Si3 -146.7(3) .
C23 Ru2 C24 Si3 -121.2(4) .
C13 C17 C16 C15 0.7(5) .
C22 C17 C16 C15 -173.3(4) .
Ru1 C17 C16 C15 62.0(3) .
C13 C17 C16 C21 178.5(4) .
C22 C17 C16 C21 4.6(7) .
Ru1 C17 C16 C21 -120.2(5) .
C13 C17 C16 Ru1 -61.3(3) .
C22 C17 C16 Ru1 124.8(4) .
C17 Ru1 C16 C15 -117.0(4) .
C13 Ru1 C16 C15 -80.0(3) .
C4 Ru1 C16 C15 99.0(3) .
C5 Ru1 C16 C15 64.7(3) .
C3 Ru1 C16 C15 138.4(3) .
C14 Ru1 C16 C15 -37.5(3) .
C6 Ru1 C16 C15 30.3(6) .
C2 Ru1 C16 C15 173.4(2) .
C1 Ru1 C16 C15 -158.3(4) .
C15 Ru1 C16 C17 117.0(4) .
C13 Ru1 C16 C17 36.9(3) .
C4 Ru1 C16 C17 -144.0(3) .
C5 Ru1 C16 C17 -178.3(3) .
C3 Ru1 C16 C17 -104.6(3) .
C14 Ru1 C16 C17 79.5(3) .
C6 Ru1 C16 C17 147.3(4) .
C2 Ru1 C16 C17 -69.7(3) .
C1 Ru1 C16 C17 -41.3(6) .
C15 Ru1 C16 C21 -121.0(5) .
C17 Ru1 C16 C21 122.1(6) .
C13 Ru1 C16 C21 159.0(5) .
C4 Ru1 C16 C21 -22.0(5) .
C5 Ru1 C16 C21 -56.3(5) .
C3 Ru1 C16 C21 17.4(5) .
C14 Ru1 C16 C21 -158.5(5) .
C6 Ru1 C16 C21 -90.7(7) .
C2 Ru1 C16 C21 52.4(5) .
C1 Ru1 C16 C21 80.8(7) .
C24 C23 C28 C27 10.6(5) .
S2 C23 C28 C27 -172.2(3) .
Ru2 C23 C28 C27 55.8(3) .
C24 C23 C28 Si4 178.7(3) .
S2 C23 C28 Si4 -4.0(5) .
Ru2 C23 C28 Si4 -136.1(3) .
C24 C23 C28 Ru2 -45.2(3) .
S2 C23 C28 Ru2 132.0(3) .
C32 Si4 C28 C27 -133.2(3) .
C33 Si4 C28 C27 102.8(3) .
C34 Si4 C28 C27 -12.9(4) .
C32 Si4 C28 C23 58.6(4) .
C33 Si4 C28 C23 -65.3(4) .
C34 Si4 C28 C23 179.0(3) .
C32 Si4 C28 Ru2 -44.8(4) .
C33 Si4 C28 Ru2 -168.8(3) .
C34 Si4 C28 Ru2 75.6(3) .
C37 Ru2 C28 C27 63.7(3) .
C36 Ru2 C28 C27 101.4(3) .
C35 Ru2 C28 C27 141.9(2) .
C38 Ru2 C28 C27 46.3(7) .
C25 Ru2 C28 C27 -66.1(2) .
C26 Ru2 C28 C27 -28.7(2) .
C39 Ru2 C28 C27 169.5(3) .
C24 Ru2 C28 C27 -103.2(3) .
C23 Ru2 C28 C27 -128.9(3) .
C37 Ru2 C28 C23 -167.3(2) .
C36 Ru2 C28 C23 -129.7(2) .
C35 Ru2 C28 C23 -89.1(3) .
C38 Ru2 C28 C23 175.2(5) .
C25 Ru2 C28 C23 62.8(2) .
C26 Ru2 C28 C23 100.2(2) .
C27 Ru2 C28 C23 128.9(3) .
C39 Ru2 C28 C23 -61.6(4) .
C24 Ru2 C28 C23 25.7(2) .
C37 Ru2 C28 Si4 -46.2(4) .
C36 Ru2 C28 Si4 -8.6(3) .
C35 Ru2 C28 Si4 32.0(3) .
C38 Ru2 C28 Si4 -63.6(7) .
C25 Ru2 C28 Si4 -176.1(3) .
C26 Ru2 C28 Si4 -138.7(3) .
C27 Ru2 C28 Si4 -109.9(4) .
C39 Ru2 C28 Si4 59.5(4) .
C24 Ru2 C28 Si4 146.9(3) .
C23 Ru2 C28 Si4 121.1(4) .
C36 C35 C39 C38 -1.3(4) .
C40 C35 C39 C38 -178.1(4) .
Ru2 C35 C39 C38 60.4(3) .
C36 C35 C39 C44 171.2(4) .
C40 C35 C39 C44 -5.5(7) .
Ru2 C35 C39 C44 -127.0(4) .
C36 C35 C39 Ru2 -61.7(3) .
C40 C35 C39 Ru2 121.5(4) .
C37 Ru2 C39 C35 81.4(3) .
C36 Ru2 C39 C35 38.1(2) .
C38 Ru2 C39 C35 119.5(4) .
C25 Ru2 C39 C35 -157.7(2) .
C26 Ru2 C39 C35 164.6(2) .
C27 Ru2 C39 C35 99.0(9) .
C24 Ru2 C39 C35 -117.7(2) .
C28 Ru2 C39 C35 -41.8(4) .
C23 Ru2 C39 C35 -80.8(3) .
C37 Ru2 C39 C38 -38.1(2) .
C36 Ru2 C39 C38 -81.4(3) .
C35 Ru2 C39 C38 -119.5(4) .
C25 Ru2 C39 C38 82.8(3) .
C26 Ru2 C39 C38 45.1(3) .
C27 Ru2 C39 C38 -20.5(10) .
C24 Ru2 C39 C38 122.8(2) .
C28 Ru2 C39 C38 -161.3(3) .
C23 Ru2 C39 C38 159.7(2) .
C37 Ru2 C39 C44 -158.1(5) .
C36 Ru2 C39 C44 158.7(5) .
C35 Ru2 C39 C44 120.5(5) .
C38 Ru2 C39 C44 -120.0(6) .
C25 Ru2 C39 C44 -37.1(5) .
C26 Ru2 C39 C44 -74.9(5) .
C27 Ru2 C39 C44 -140.5(8) .
C24 Ru2 C39 C44 2.8(5) .
C28 Ru2 C39 C44 78.8(6) .
C23 Ru2 C39 C44 39.7(5) .
C23 C28 C27 C26 -4.7(6) .
Si4 C28 C27 C26 -173.1(3) .
Ru2 C28 C27 C26 55.0(3) .
C23 C28 C27 Ru2 -59.7(3) .
Si4 C28 C27 Ru2 131.9(2) .
C37 Ru2 C27 C26 93.9(2) .
C36 Ru2 C27 C26 134.5(2) .
C35 Ru2 C27 C26 163.3(2) .
C38 Ru2 C27 C26 60.5(3) .
C25 Ru2 C27 C26 -30.3(2) .
C39 Ru2 C27 C26 77.5(9) .
C24 Ru2 C27 C26 -67.3(2) .
C28 Ru2 C27 C26 -132.9(3) .
C23 Ru2 C27 C26 -102.7(2) .
C37 Ru2 C27 C28 -133.2(2) .
C36 Ru2 C27 C28 -92.6(2) .
C35 Ru2 C27 C28 -63.9(3) .
C38 Ru2 C27 C28 -166.6(2) .
C25 Ru2 C27 C28 102.6(2) .
C26 Ru2 C27 C28 132.9(3) .
C39 Ru2 C27 C28 -149.6(8) .
C24 Ru2 C27 C28 65.5(2) .
C23 Ru2 C27 C28 30.2(2) .
C16 Ru1 C14 C15 37.7(3) .
C17 Ru1 C14 C15 80.6(3) .
C13 Ru1 C14 C15 118.6(4) .
C4 Ru1 C14 C15 -47.8(4) .
C5 Ru1 C14 C15 -84.0(3) .
C3 Ru1 C14 C15 13.7(11) .
C6 Ru1 C14 C15 -123.8(3) .
C2 Ru1 C14 C15 162.3(3) .
C1 Ru1 C14 C15 -160.4(2) .
C16 Ru1 C14 C13 -80.9(3) .
C15 Ru1 C14 C13 -118.6(4) .
C17 Ru1 C14 C13 -38.0(3) .
C4 Ru1 C14 C13 -166.3(3) .
C5 Ru1 C14 C13 157.5(2) .
C3 Ru1 C14 C13 -104.8(10) .
C6 Ru1 C14 C13 117.7(3) .
C2 Ru1 C14 C13 43.7(4) .
C1 Ru1 C14 C13 81.0(3) .
C16 Ru1 C14 C19 156.7(5) .
C15 Ru1 C14 C19 119.1(6) .
C17 Ru1 C14 C19 -160.3(5) .
C13 Ru1 C14 C19 -122.4(6) .
C4 Ru1 C14 C19 71.3(6) .
C5 Ru1 C14 C19 35.1(5) .
C3 Ru1 C14 C19 132.8(9) .
C6 Ru1 C14 C19 -4.7(5) .
C2 Ru1 C14 C19 -78.7(6) .
C1 Ru1 C14 C19 -41.3(5) .
C38 C37 C36 C35 -0.5(4) .
C42 C37 C36 C35 -178.2(4) .
Ru2 C37 C36 C35 61.6(3) .
C38 C37 C36 C41 173.8(4) .
C42 C37 C36 C41 -3.9(7) .
Ru2 C37 C36 C41 -124.1(4) .
C38 C37 C36 Ru2 -62.1(3) .
C42 C37 C36 Ru2 120.2(4) .
C39 C35 C36 C37 1.1(4) .
C40 C35 C36 C37 177.9(4) .
Ru2 C35 C36 C37 -61.2(3) .
C39 C35 C36 C41 -173.0(4) .
C40 C35 C36 C41 3.8(7) .
Ru2 C35 C36 C41 124.7(4) .
C39 C35 C36 Ru2 62.3(3) .
C40 C35 C36 Ru2 -120.9(4) .
C35 Ru2 C36 C37 117.5(4) .
C38 Ru2 C36 C37 37.3(2) .
C25 Ru2 C36 C37 -10.3(8) .
C26 Ru2 C36 C37 -54.1(3) .
C27 Ru2 C36 C37 -90.6(3) .
C39 Ru2 C36 C37 80.0(3) .
C24 Ru2 C36 C37 156.2(3) .
C28 Ru2 C36 C37 -130.3(2) .
C23 Ru2 C36 C37 -165.1(2) .
C37 Ru2 C36 C35 -117.5(4) .
C38 Ru2 C36 C35 -80.2(3) .
C25 Ru2 C36 C35 -127.8(6) .
C26 Ru2 C36 C35 -171.6(2) .
C27 Ru2 C36 C35 152.0(2) .
C39 Ru2 C36 C35 -37.5(2) .
C24 Ru2 C36 C35 38.8(5) .
C28 Ru2 C36 C35 112.3(3) .
C23 Ru2 C36 C35 77.5(3) .
C37 Ru2 C36 C41 120.2(6) .
C35 Ru2 C36 C41 -122.3(6) .
C38 Ru2 C36 C41 157.5(5) .
C25 Ru2 C36 C41 109.9(7) .
C26 Ru2 C36 C41 66.1(5) .
C27 Ru2 C36 C41 29.7(5) .
C39 Ru2 C36 C41 -159.8(5) .
C24 Ru2 C36 C41 -83.6(6) .
C28 Ru2 C36 C41 -10.1(5) .
C23 Ru2 C36 C41 -44.8(5) .
C1 C6 C5 C4 -4.8(6) .
Si2 C6 C5 C4 -175.5(3) .
Ru1 C6 C5 C4 54.7(3) .
C1 C6 C5 Ru1 -59.4(3) .
Si2 C6 C5 Ru1 129.8(3) .
C16 Ru1 C5 C4 64.3(3) .
C15 Ru1 C5 C4 99.8(3) .
C17 Ru1 C5 C4 60.0(8) .
C13 Ru1 C5 C4 165.7(3) .
C3 Ru1 C5 C4 -30.3(2) .
C14 Ru1 C5 C4 139.3(3) .
C6 Ru1 C5 C4 -133.4(4) .
C2 Ru1 C5 C4 -67.4(3) .
C1 Ru1 C5 C4 -102.8(3) .
C16 Ru1 C5 C6 -162.4(2) .
C15 Ru1 C5 C6 -126.9(2) .
C17 Ru1 C5 C6 -166.6(6) .
C13 Ru1 C5 C6 -60.9(4) .
C4 Ru1 C5 C6 133.4(4) .
C3 Ru1 C5 C6 103.1(3) .
C14 Ru1 C5 C6 -87.3(3) .
C2 Ru1 C5 C6 66.0(2) .
C1 Ru1 C5 C6 30.5(2) .
C28 C27 C26 C25 -1.0(6) .
Ru2 C27 C26 C25 55.2(3) .
C28 C27 C26 Ru2 -56.2(3) .
C37 Ru2 C26 C27 -97.4(2) .
C36 Ru2 C26 C27 -65.8(3) .
C35 Ru2 C26 C27 -96.8(10) .
C38 Ru2 C26 C27 -137.3(2) .
C25 Ru2 C26 C27 130.4(3) .
C39 Ru2 C26 C27 -164.7(2) .
C24 Ru2 C26 C27 101.7(2) .
C28 Ru2 C26 C27 28.8(2) .
C23 Ru2 C26 C27 65.0(2) .
C37 Ru2 C26 C25 132.2(2) .
C36 Ru2 C26 C25 163.8(2) .
C35 Ru2 C26 C25 132.8(9) .
C38 Ru2 C26 C25 92.3(2) .
C27 Ru2 C26 C25 -130.4(3) .
C39 Ru2 C26 C25 64.9(3) .
C24 Ru2 C26 C25 -28.7(2) .
C28 Ru2 C26 C25 -101.6(2) .
C23 Ru2 C26 C25 -65.4(2) .
C17 C16 C15 C14 0.6(5) .
C21 C16 C15 C14 -177.3(4) .
Ru1 C16 C15 C14 62.6(3) .
C17 C16 C15 C20 179.3(4) .
C21 C16 C15 C20 1.4(7) .
Ru1 C16 C15 C20 -118.7(4) .
C17 C16 C15 Ru1 -62.0(3) .
C21 C16 C15 Ru1 120.2(5) .
C13 C14 C15 C16 -1.6(5) .
C19 C14 C15 C16 172.6(4) .
Ru1 C14 C15 C16 -61.9(3) .
C13 C14 C15 C20 179.7(4) .
C19 C14 C15 C20 -6.1(7) .
Ru1 C14 C15 C20 119.4(4) .
C13 C14 C15 Ru1 60.3(3) .
C19 C14 C15 Ru1 -125.5(4) .
C17 Ru1 C15 C16 38.0(3) .
C13 Ru1 C15 C16 80.6(3) .
C4 Ru1 C15 C16 -93.5(3) .
C5 Ru1 C15 C16 -132.1(3) .
C3 Ru1 C15 C16 -59.3(3) .
C14 Ru1 C15 C16 117.6(4) .
C6 Ru1 C15 C16 -168.4(2) .
C2 Ru1 C15 C16 -22.8(8) .
C1 Ru1 C15 C16 163.4(3) .
C16 Ru1 C15 C14 -117.6(4) .
C17 Ru1 C15 C14 -79.6(3) .
C13 Ru1 C15 C14 -37.0(3) .
C4 Ru1 C15 C14 148.9(3) .
C5 Ru1 C15 C14 110.4(3) .
C3 Ru1 C15 C14 -176.9(2) .
C6 Ru1 C15 C14 74.0(3) .
C2 Ru1 C15 C14 -140.4(6) .
C1 Ru1 C15 C14 45.8(5) .
C16 Ru1 C15 C20 120.1(6) .
C17 Ru1 C15 C20 158.1(5) .
C13 Ru1 C15 C20 -159.4(5) .
C4 Ru1 C15 C20 26.5(5) .
C5 Ru1 C15 C20 -12.0(5) .
C3 Ru1 C15 C20 60.7(5) .
C14 Ru1 C15 C20 -122.4(6) .
C6 Ru1 C15 C20 -48.4(5) .
C2 Ru1 C15 C20 97.2(7) .
C1 Ru1 C15 C20 -76.5(6) .
C27 C26 C25 C24 0.7(6) .
Ru2 C26 C25 C24 56.0(3) .
C27 C26 C25 Ru2 -55.3(3) .
C23 C24 C25 C26 5.3(6) .
Si3 C24 C25 C26 177.2(3) .
Ru2 C24 C25 C26 -54.9(3) .
C23 C24 C25 Ru2 60.1(3) .
Si3 C24 C25 Ru2 -128.0(2) .
C37 Ru2 C25 C26 -64.0(3) .
C36 Ru2 C25 C26 -55.9(7) .
C35 Ru2 C25 C26 -165.7(3) .
C38 Ru2 C25 C26 -99.6(2) .
C27 Ru2 C25 C26 30.1(2) .
C39 Ru2 C25 C26 -139.2(2) .
C24 Ru2 C25 C26 132.9(3) .
C28 Ru2 C25 C26 67.2(2) .
C23 Ru2 C25 C26 102.3(2) .
C37 Ru2 C25 C24 163.2(2) .
C36 Ru2 C25 C24 171.2(6) .
C35 Ru2 C25 C24 61.5(4) .
C38 Ru2 C25 C24 127.5(2) .
C26 Ru2 C25 C24 -132.9(3) .
C27 Ru2 C25 C24 -102.8(2) .
C39 Ru2 C25 C24 87.9(2) .
C28 Ru2 C25 C24 -65.6(2) .
C23 Ru2 C25 C24 -30.6(2) .
C1 C2 C3 C4 4.1(6) .
Si1 C2 C3 C4 175.6(3) .
Ru1 C2 C3 C4 -54.8(3) .
C1 C2 C3 Ru1 58.9(3) .
Si1 C2 C3 Ru1 -129.7(3) .
C16 Ru1 C3 C4 -94.6(3) .
C15 Ru1 C3 C4 -60.8(3) .
C17 Ru1 C3 C4 -135.1(2) .
C13 Ru1 C3 C4 -164.5(3) .
C5 Ru1 C3 C4 29.7(2) .
C14 Ru1 C3 C4 -72.2(10) .
C6 Ru1 C3 C4 66.9(2) .
C2 Ru1 C3 C4 132.3(4) .
C1 Ru1 C3 C4 102.4(3) .
C16 Ru1 C3 C2 133.0(2) .
C15 Ru1 C3 C2 166.9(2) .
C17 Ru1 C3 C2 92.6(3) .
C13 Ru1 C3 C2 63.2(4) .
C4 Ru1 C3 C2 -132.3(4) .
C5 Ru1 C3 C2 -102.6(3) .
C14 Ru1 C3 C2 155.5(9) .
C6 Ru1 C3 C2 -65.4(2) .
C1 Ru1 C3 C2 -29.9(2) .
C36 C37 C38 C39 -0.3(4) .
C42 C37 C38 C39 177.4(4) .
Ru2 C37 C38 C39 -62.2(3) .
C36 C37 C38 C43 -178.5(4) .
C42 C37 C38 C43 -0.8(6) .
Ru2 C37 C38 C43 119.6(4) .
C36 C37 C38 Ru2 61.9(3) .
C42 C37 C38 Ru2 -120.4(4) .
C35 C39 C38 C37 1.0(4) .
C44 C39 C38 C37 -171.6(4) .
Ru2 C39 C38 C37 61.5(3) .
C35 C39 C38 C43 179.2(4) .
C44 C39 C38 C43 6.6(6) .
Ru2 C39 C38 C43 -120.3(4) .
C35 C39 C38 Ru2 -60.5(3) .
C44 C39 C38 Ru2 126.9(4) .
C36 Ru2 C38 C37 -37.6(2) .
C35 Ru2 C38 C37 -80.4(3) .
C25 Ru2 C38 C37 131.6(2) .
C26 Ru2 C38 C37 92.3(3) .
C27 Ru2 C38 C37 58.6(3) .
C39 Ru2 C38 C37 -116.7(4) .
C24 Ru2 C38 C37 167.5(2) .
C28 Ru2 C38 C37 22.2(7) .
C23 Ru2 C38 C37 -165.2(3) .
C37 Ru2 C38 C39 116.7(4) .
C36 Ru2 C38 C39 79.1(3) .
C35 Ru2 C38 C39 36.3(2) .
C25 Ru2 C38 C39 -111.8(3) .
C26 Ru2 C38 C39 -151.0(2) .
C27 Ru2 C38 C39 175.2(2) .
C24 Ru2 C38 C39 -75.8(3) .
C28 Ru2 C38 C39 138.8(6) .
C23 Ru2 C38 C39 -48.5(5) .
C37 Ru2 C38 C43 -120.5(5) .
C36 Ru2 C38 C43 -158.1(4) .
C35 Ru2 C38 C43 159.1(4) .
C25 Ru2 C38 C43 11.0(4) .
C26 Ru2 C38 C43 -28.2(4) .
C27 Ru2 C38 C43 -62.0(4) .
C39 Ru2 C38 C43 122.8(5) .
C24 Ru2 C38 C43 47.0(4) .
C28 Ru2 C38 C43 -98.4(7) .
C23 Ru2 C38 C43 74.3(5) .
C16 C17 C13 C14 -1.6(5) .
C22 C17 C13 C14 172.1(4) .
Ru1 C17 C13 C14 -62.7(3) .
C16 C17 C13 C18 -178.0(4) .
C22 C17 C13 C18 -4.2(7) .
Ru1 C17 C13 C18 120.9(5) .
C16 C17 C13 Ru1 61.1(3) .
C22 C17 C13 Ru1 -125.1(5) .
C15 C14 C13 C17 2.0(5) .
C19 C14 C13 C17 -172.0(4) .
Ru1 C14 C13 C17 62.1(3) .
C15 C14 C13 C18 178.5(4) .
C19 C14 C13 C18 4.4(7) .
Ru1 C14 C13 C18 -121.4(4) .
C15 C14 C13 Ru1 -60.2(3) .
C19 C14 C13 Ru1 125.8(5) .
C16 Ru1 C13 C17 -37.1(3) .
C15 Ru1 C13 C17 -79.8(3) .
C4 Ru1 C13 C17 -43.0(12) .
C5 Ru1 C13 C17 -157.7(3) .
C3 Ru1 C13 C17 47.4(4) .
C14 Ru1 C13 C17 -116.9(4) .
C6 Ru1 C13 C17 163.8(2) .
C2 Ru1 C13 C17 85.4(3) .
C1 Ru1 C13 C17 124.6(2) .
C16 Ru1 C13 C14 79.7(3) .
C15 Ru1 C13 C14 37.1(3) .
C17 Ru1 C13 C14 116.9(4) .
C4 Ru1 C13 C14 73.9(12) .
C5 Ru1 C13 C14 -40.9(4) .
C3 Ru1 C13 C14 164.3(3) .
C6 Ru1 C13 C14 -79.3(3) .
C2 Ru1 C13 C14 -157.7(2) .
C1 Ru1 C13 C14 -118.6(3) .
C16 Ru1 C13 C18 -160.0(5) .
C15 Ru1 C13 C18 157.3(5) .
C17 Ru1 C13 C18 -122.9(6) .
C4 Ru1 C13 C18 -165.9(9) .
C5 Ru1 C13 C18 79.4(6) .
C3 Ru1 C13 C18 -75.5(6) .
C14 Ru1 C13 C18 120.2(6) .
C6 Ru1 C13 C18 40.9(5) .
C2 Ru1 C13 C18 -37.5(5) .
C1 Ru1 C13 C18 1.6(5) .
C6 C5 C4 C3 -0.2(6) .
Ru1 C5 C4 C3 55.6(3) .
C6 C5 C4 Ru1 -55.8(3) .
C2 C3 C4 C5 0.5(6) .
Ru1 C3 C4 C5 -55.6(3) .
C2 C3 C4 Ru1 56.2(3) .
C16 Ru1 C4 C5 -132.1(3) .
C15 Ru1 C4 C5 -92.0(3) .
C17 Ru1 C4 C5 -162.8(2) .
C13 Ru1 C4 C5 -126.6(11) .
C3 Ru1 C4 C5 130.6(4) .
C14 Ru1 C4 C5 -63.2(3) .
C6 Ru1 C4 C5 28.7(2) .
C2 Ru1 C4 C5 101.6(3) .
C1 Ru1 C4 C5 65.3(2) .
C16 Ru1 C4 C3 97.3(3) .
C15 Ru1 C4 C3 137.4(2) .
C17 Ru1 C4 C3 66.6(3) .
C13 Ru1 C4 C3 102.8(11) .
C5 Ru1 C4 C3 -130.6(4) .
C14 Ru1 C4 C3 166.1(3) .
C6 Ru1 C4 C3 -102.0(3) .
C2 Ru1 C4 C3 -29.0(2) .
C1 Ru1 C4 C3 -65.3(2) .
C45 C46 C47 C47 -28(3) 2_766
