#------------------------------------------------------------------------------
#$Date: 2016-03-21 07:29:14 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178567 $
#$URL: svn://www.crystallography.net/cod/cif/4/06/76/4067666.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4067666
loop_
_publ_author_name
'Mendoza, Consuelo'
'Bernès, Sylvain'
'Torrens, Hugo'
'Arroyo, Maribel'
_publ_section_title
;
 Carbon−Fluorine Bond Activation in Thermolysis Reactions of the
 Osmium(IV) Perfluorothiolate Compounds [Os(SC6F5)4(P(C6H4X-4)3)] (X =
 CF3, Cl, F, H, CH3, and OCH3)
;
_journal_issue                   12
_journal_name_full               Organometallics
_journal_page_first              2646
_journal_paper_doi               10.1021/om901065g
_journal_volume                  29
_journal_year                    2010
_chemical_compound_source        'CH2Cl2/hexane (1:4)'
_chemical_formula_moiety         'C31 H7 F19 O Os S4'
_chemical_formula_sum            'C31 H7 F19 O Os S4'
_chemical_formula_weight         1074.81
_chemical_melting_point          453
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_date             2009-03-11
_audit_creation_method           SHELXTL-Plus
_cell_angle_alpha                80.587(5)
_cell_angle_beta                 78.904(4)
_cell_angle_gamma                75.411(6)
_cell_formula_units_Z            2
_cell_length_a                   11.2820(7)
_cell_length_b                   12.5292(8)
_cell_length_c                   12.6534(7)
_cell_measurement_pressure       101(2)
_cell_measurement_reflns_used    95
_cell_measurement_temperature    297(1)
_cell_measurement_theta_max      13.78
_cell_measurement_theta_min      4.63
_cell_volume                     1686.07(18)
_computing_cell_refinement       XSCANS
_computing_data_collection       'XSCANS (Siemens, 1996)'
_computing_data_reduction        XSCANS
_computing_molecular_graphics    SHELXTL-Plus
_computing_publication_material  SHELXTL-Plus
_computing_structure_refinement  SHELXTL-Plus
_computing_structure_solution    'SHELXTL-Plus (Sheldrick, 1998)'
_diffrn_ambient_pressure         101(2)
_diffrn_ambient_temperature      297(1)
_diffrn_detector                 'Scintillation counter'
_diffrn_measured_fraction_theta_full 0.993
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device_type  'Bruker P4'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0197
_diffrn_reflns_av_sigmaI/netI    0.0376
_diffrn_reflns_limit_h_max       3
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            11808
_diffrn_reflns_theta_full        29.00
_diffrn_reflns_theta_max         29.00
_diffrn_reflns_theta_min         1.89
_diffrn_source                   'fine-focus sealed tube'
_diffrn_source_current           30
_diffrn_source_power             1.5
_diffrn_source_type              FN4
_diffrn_source_voltage           50
_diffrn_standards_decay_%        <1
_diffrn_standards_interval_count 97
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    4.164
_exptl_absorpt_correction_T_max  0.437
_exptl_absorpt_correction_T_min  0.276
_exptl_absorpt_correction_type   psi-scan
_exptl_absorpt_process_details   'XSCANS (Siemens, 1996)'
_exptl_crystal_colour            'dark green'
_exptl_crystal_density_diffrn    2.117
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       irregular
_exptl_crystal_F_000             1024
_exptl_crystal_size_max          0.55
_exptl_crystal_size_mid          0.28
_exptl_crystal_size_min          0.20
_refine_diff_density_max         0.635
_refine_diff_density_min         -1.229
_refine_diff_density_rms         0.094
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.053
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_constraints    0
_refine_ls_number_parameters     506
_refine_ls_number_reflns         8897
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.053
_refine_ls_R_factor_all          0.0380
_refine_ls_R_factor_gt           0.0295
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0344P)²+0.3322P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0668
_refine_ls_wR_factor_ref         0.0704
_reflns_number_gt                7768
_reflns_number_total             8897
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            om901065g_si_001.cif
_cod_data_source_block           6b
_cod_database_code               4067666
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Os1 Os 0.328286(12) 0.200122(9) 0.424060(9) 0.03573(5) Uani 1 1 d .
S1 S 0.42266(8) 0.27211(6) 0.24469(6) 0.04053(16) Uani 1 1 d .
S2 S 0.39963(9) 0.03353(6) 0.37331(7) 0.04438(18) Uani 1 1 d .
S3 S 0.44238(9) 0.26576(8) 0.50970(7) 0.04758(19) Uani 1 1 d .
S4 S 0.14273(9) 0.30193(7) 0.39748(7) 0.04778(19) Uani 1 1 d .
C1 C 0.4814(3) 0.0473(3) 0.2394(3) 0.0409(7) Uani 1 1 d .
C2 C 0.5355(4) -0.0476(3) 0.1891(3) 0.0497(8) Uani 1 1 d .
F2 F 0.5197(2) -0.14697(17) 0.2379(2) 0.0615(6) Uani 1 1 d .
C3 C 0.6052(4) -0.0412(3) 0.0867(3) 0.0552(9) Uani 1 1 d .
F3 F 0.6565(3) -0.1345(2) 0.0401(2) 0.0774(8) Uani 1 1 d .
C4 C 0.6213(4) 0.0584(4) 0.0324(3) 0.0584(10) Uani 1 1 d .
F4 F 0.6887(3) 0.0648(3) -0.0670(2) 0.0801(8) Uani 1 1 d .
C5 C 0.5654(3) 0.1551(3) 0.0794(3) 0.0487(8) Uani 1 1 d .
F5 F 0.5786(3) 0.2532(2) 0.0250(2) 0.0698(7) Uani 1 1 d .
C6 C 0.4956(3) 0.1492(3) 0.1823(3) 0.0429(7) Uani 1 1 d .
C7 C 0.3201(3) 0.3399(3) 0.1502(2) 0.0416(7) Uani 1 1 d .
C8 C 0.3316(4) 0.4437(3) 0.0968(3) 0.0510(8) Uani 1 1 d .
F8 F 0.4149(3) 0.4933(2) 0.1185(2) 0.0724(7) Uani 1 1 d .
C9 C 0.2584(4) 0.4970(3) 0.0186(3) 0.0598(10) Uani 1 1 d .
F9 F 0.2717(3) 0.5958(2) -0.0335(3) 0.0922(10) Uani 1 1 d .
C10 C 0.1750(4) 0.4466(4) -0.0059(3) 0.0570(10) Uani 1 1 d .
F10 F 0.1046(3) 0.4971(3) -0.0821(2) 0.0794(8) Uani 1 1 d .
C11 C 0.1611(4) 0.3441(3) 0.0467(3) 0.0510(8) Uani 1 1 d .
F11 F 0.0798(2) 0.2956(2) 0.0203(2) 0.0731(7) Uani 1 1 d .
C12 C 0.2331(3) 0.2921(3) 0.1245(3) 0.0451(7) Uani 1 1 d .
F12 F 0.2209(2) 0.19099(17) 0.17228(18) 0.0541(5) Uani 1 1 d .
C13 C 0.5172(3) 0.3648(3) 0.4231(3) 0.0445(7) Uani 1 1 d .
C14 C 0.6448(4) 0.3453(3) 0.4015(3) 0.0528(8) Uani 1 1 d .
F14 F 0.7136(3) 0.2485(2) 0.4400(3) 0.0786(8) Uani 1 1 d .
C15 C 0.7064(4) 0.4233(4) 0.3391(4) 0.0639(11) Uani 1 1 d .
F15 F 0.8298(3) 0.4006(3) 0.3186(3) 0.0972(10) Uani 1 1 d .
C16 C 0.6376(5) 0.5234(4) 0.2989(3) 0.0623(11) Uani 1 1 d .
F16 F 0.6956(3) 0.5996(2) 0.2387(2) 0.0892(9) Uani 1 1 d .
C17 C 0.5113(4) 0.5456(3) 0.3200(3) 0.0588(10) Uani 1 1 d .
F17 F 0.4455(3) 0.6439(2) 0.2814(3) 0.0919(10) Uani 1 1 d .
C18 C 0.4519(4) 0.4680(3) 0.3824(3) 0.0523(8) Uani 1 1 d .
F18 F 0.3277(2) 0.4930(2) 0.4011(3) 0.0800(8) Uani 1 1 d .
C19 C 0.0318(3) 0.2892(3) 0.5169(3) 0.0490(8) Uani 1 1 d .
C20 C -0.0349(4) 0.2082(4) 0.5389(4) 0.0664(11) Uani 1 1 d .
F20 F -0.0176(3) 0.1353(3) 0.4683(3) 0.0930(9) Uani 1 1 d .
C21 C -0.1168(5) 0.1980(5) 0.6334(5) 0.0854(16) Uani 1 1 d .
F21 F -0.1782(4) 0.1170(4) 0.6537(4) 0.1428(18) Uani 1 1 d .
C22 C -0.1338(5) 0.2702(6) 0.7076(5) 0.096(2) Uani 1 1 d .
F22 F -0.2121(4) 0.2609(4) 0.8013(3) 0.149(2) Uani 1 1 d .
C23 C -0.0705(5) 0.3541(5) 0.6877(4) 0.0841(17) Uani 1 1 d .
F23 F -0.0854(4) 0.4239(3) 0.7616(3) 0.1289(16) Uani 1 1 d .
C24 C 0.0117(4) 0.3636(3) 0.5933(3) 0.0574(10) Uani 1 1 d .
F24 F 0.0771(3) 0.4406(2) 0.5785(2) 0.0788(8) Uani 1 1 d .
C25 C 0.2588(3) 0.1257(3) 0.5779(3) 0.0410(7) Uani 1 1 d .
C26 C 0.2307(4) 0.0221(3) 0.5941(3) 0.0572(10) Uani 1 1 d .
H26A H 0.2470 -0.0178 0.5351 0.069 Uiso 1 1 calc R
C27 C 0.1794(4) -0.0252(3) 0.6942(3) 0.0632(11) Uani 1 1 d .
H27A H 0.1630 -0.0954 0.7010 0.076 Uiso 1 1 calc R
C28 C 0.1528(4) 0.0319(3) 0.7831(3) 0.0560(9) Uani 1 1 d .
C29 C 0.1769(4) 0.1364(3) 0.7704(3) 0.0500(8) Uani 1 1 d .
H29A H 0.1571 0.1768 0.8293 0.060 Uiso 1 1 calc R
C30 C 0.2300(3) 0.1816(3) 0.6708(3) 0.0437(7) Uani 1 1 d .
H30A H 0.2473 0.2513 0.6649 0.052 Uiso 1 1 calc R
O31 O 0.1040(4) -0.0065(3) 0.8860(3) 0.0854(11) Uani 1 1 d .
C32 C 0.0712(9) -0.1107(6) 0.9002(5) 0.135(3) Uani 1 1 d .
H32A H 0.0477 -0.1328 0.9761 0.202 Uiso 1 1 calc R
H32B H 0.1408 -0.1654 0.8712 0.202 Uiso 1 1 calc R
H32C H 0.0028 -0.1044 0.8628 0.202 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Os Os -1.2165 7.6030 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
C25 Os1 S2 88.50(9)
C25 Os1 S3 86.52(9)
S2 Os1 S3 118.83(4)
C25 Os1 S4 92.93(10)
S2 Os1 S4 122.14(4)
S3 Os1 S4 118.99(4)
C25 Os1 S1 175.17(9)
S2 Os1 S1 87.31(3)
S3 Os1 S1 93.40(3)
S4 Os1 S1 91.33(3)
C6 S1 C7 99.29(15)
C6 S1 Os1 103.06(12)
C7 S1 Os1 116.95(11)
C1 S2 Os1 108.07(11)
C13 S3 Os1 112.00(11)
C19 S4 Os1 110.58(12)
C2 C1 C6 118.1(3)
C2 C1 S2 118.9(3)
C6 C1 S2 123.0(2)
F2 C2 C3 118.5(3)
F2 C2 C1 120.6(3)
C3 C2 C1 120.8(4)
F3 C3 C4 119.8(4)
F3 C3 C2 119.5(4)
C4 C3 C2 120.7(3)
F4 C4 C3 120.8(4)
F4 C4 C5 119.4(4)
C3 C4 C5 119.7(3)
F5 C5 C6 120.5(3)
F5 C5 C4 119.7(3)
C6 C5 C4 119.7(4)
C5 C6 C1 120.8(3)
C5 C6 S1 120.7(3)
C1 C6 S1 118.5(2)
C12 C7 C8 118.4(3)
C12 C7 S1 123.1(3)
C8 C7 S1 118.5(3)
F8 C8 C9 118.9(3)
F8 C8 C7 120.6(3)
C9 C8 C7 120.5(4)
F9 C9 C10 120.4(4)
F9 C9 C8 120.1(4)
C10 C9 C8 119.5(4)
F10 C10 C9 119.9(4)
F10 C10 C11 119.1(4)
C9 C10 C11 121.0(4)
F11 C11 C12 120.8(4)
F11 C11 C10 119.9(4)
C12 C11 C10 119.2(4)
F12 C12 C11 118.3(3)
F12 C12 C7 120.3(3)
C11 C12 C7 121.4(3)
C14 C13 C18 116.8(3)
C14 C13 S3 120.5(3)
C18 C13 S3 122.4(3)
F14 C14 C13 120.0(4)
F14 C14 C15 117.8(4)
C13 C14 C15 122.2(4)
F15 C15 C16 120.8(4)
F15 C15 C14 120.3(4)
C16 C15 C14 118.8(4)
F16 C16 C17 120.1(4)
F16 C16 C15 119.6(4)
C17 C16 C15 120.3(4)
F17 C17 C16 119.7(4)
F17 C17 C18 120.2(4)
C16 C17 C18 120.1(4)
F18 C18 C17 118.2(4)
F18 C18 C13 120.0(3)
C17 C18 C13 121.7(4)
C20 C19 C24 117.8(4)
C20 C19 S4 122.9(3)
C24 C19 S4 119.3(3)
F20 C20 C21 118.8(5)
F20 C20 C19 119.5(4)
C21 C20 C19 121.6(5)
F21 C21 C22 119.9(6)
F21 C21 C20 120.4(7)
C22 C21 C20 119.7(5)
F22 C22 C21 120.8(7)
F22 C22 C23 118.8(7)
C21 C22 C23 120.5(5)
F23 C23 C24 119.9(6)
F23 C23 C22 120.5(5)
C24 C23 C22 119.6(5)
F24 C24 C23 118.7(4)
F24 C24 C19 120.4(4)
C23 C24 C19 120.8(5)
C26 C25 C30 115.0(3)
C26 C25 Os1 123.0(3)
C30 C25 Os1 121.9(2)
C25 C26 C27 123.4(3)
C25 C26 H26A 118.3
C27 C26 H26A 118.3
C28 C27 C26 119.9(4)
C28 C27 H27A 120.0
C26 C27 H27A 120.0
O31 C28 C27 125.3(4)
O31 C28 C29 115.9(4)
C27 C28 C29 118.8(3)
C28 C29 C30 120.6(3)
C28 C29 H29A 119.7
C30 C29 H29A 119.7
C29 C30 C25 122.3(3)
C29 C30 H30A 118.9
C25 C30 H30A 118.9
C28 O31 C32 117.1(4)
O31 C32 H32A 109.5
O31 C32 H32B 109.5
H32A C32 H32B 109.5
O31 C32 H32C 109.5
H32A C32 H32C 109.5
H32B C32 H32C 109.5
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
Os1 C25 2.112(3)
Os1 S2 2.1931(8)
Os1 S3 2.2066(9)
Os1 S4 2.2154(9)
Os1 S1 2.4459(8)
S1 C6 1.784(3)
S1 C7 1.788(3)
S2 C1 1.770(3)
S3 C13 1.783(3)
S4 C19 1.780(4)
C1 C2 1.387(5)
C1 C6 1.391(5)
C2 F2 1.335(4)
C2 C3 1.382(5)
C3 F3 1.342(4)
C3 C4 1.359(6)
C4 F4 1.340(4)
C4 C5 1.388(5)
C5 F5 1.335(4)
C5 C6 1.387(5)
C7 C12 1.382(5)
C7 C8 1.389(5)
C8 F8 1.339(5)
C8 C9 1.388(6)
C9 F9 1.334(4)
C9 C10 1.363(6)
C10 F10 1.343(5)
C10 C11 1.378(6)
C11 F11 1.337(5)
C11 C12 1.373(5)
C12 F12 1.340(4)
C13 C14 1.379(5)
C13 C18 1.388(5)
C14 F14 1.337(5)
C14 C15 1.392(6)
C15 F15 1.331(5)
C15 C16 1.375(7)
C16 F16 1.344(5)
C16 C17 1.362(7)
C17 F17 1.338(5)
C17 C18 1.375(5)
C18 F18 1.340(5)
C19 C20 1.374(6)
C19 C24 1.399(6)
C20 F20 1.334(6)
C20 C21 1.372(7)
C21 F21 1.333(7)
C21 C22 1.363(10)
C22 F22 1.343(6)
C22 C23 1.379(9)
C23 F23 1.341(6)
C23 C24 1.373(6)
C24 F24 1.326(5)
C25 C26 1.386(5)
C25 C30 1.409(4)
C26 C27 1.392(5)
C26 H26A 0.9300
C27 C28 1.376(6)
C27 H27A 0.9300
C28 O31 1.371(4)
C28 C29 1.381(5)
C29 C30 1.384(5)
C29 H29A 0.9300
C30 H30A 0.9300
O31 C32 1.420(7)
C32 H32A 0.9600
C32 H32B 0.9600
C32 H32C 0.9600
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
S2 Os1 S1 C6 -1.66(12)
S3 Os1 S1 C6 117.08(12)
S4 Os1 S1 C6 -123.78(12)
S2 Os1 S1 C7 106.02(12)
S3 Os1 S1 C7 -135.24(12)
S4 Os1 S1 C7 -16.10(12)
C25 Os1 S2 C1 -176.96(15)
S3 Os1 S2 C1 -91.77(12)
S4 Os1 S2 C1 90.52(13)
S1 Os1 S2 C1 0.63(12)
C25 Os1 S3 C13 -170.47(16)
S2 Os1 S3 C13 103.16(14)
S4 Os1 S3 C13 -79.05(14)
S1 Os1 S3 C13 14.37(14)
C25 Os1 S4 C19 7.37(17)
S2 Os1 S4 C19 97.44(14)
S3 Os1 S4 C19 -80.27(15)
S1 Os1 S4 C19 -174.90(14)
Os1 S2 C1 C2 -179.9(3)
Os1 S2 C1 C6 1.0(3)
C6 C1 C2 F2 -176.7(3)
S2 C1 C2 F2 4.2(5)
C6 C1 C2 C3 2.3(6)
S2 C1 C2 C3 -176.9(3)
F2 C2 C3 F3 -1.1(6)
C1 C2 C3 F3 179.9(4)
F2 C2 C3 C4 178.4(4)
C1 C2 C3 C4 -0.6(6)
F3 C3 C4 F4 -0.4(6)
C2 C3 C4 F4 -179.9(4)
F3 C3 C4 C5 178.2(4)
C2 C3 C4 C5 -1.3(6)
F4 C4 C5 F5 0.4(6)
C3 C4 C5 F5 -178.3(4)
F4 C4 C5 C6 -179.9(4)
C3 C4 C5 C6 1.4(6)
F5 C5 C6 C1 180.0(3)
C4 C5 C6 C1 0.3(6)
F5 C5 C6 S1 -0.3(5)
C4 C5 C6 S1 180.0(3)
C2 C1 C6 C5 -2.1(5)
S2 C1 C6 C5 177.0(3)
C2 C1 C6 S1 178.2(3)
S2 C1 C6 S1 -2.7(4)
C7 S1 C6 C5 62.4(3)
Os1 S1 C6 C5 -176.9(3)
C7 S1 C6 C1 -117.9(3)
Os1 S1 C6 C1 2.8(3)
C6 S1 C7 C12 57.2(3)
Os1 S1 C7 C12 -52.7(3)
C6 S1 C7 C8 -120.1(3)
Os1 S1 C7 C8 130.0(3)
C12 C7 C8 F8 -179.7(3)
S1 C7 C8 F8 -2.3(5)
C12 C7 C8 C9 -0.8(5)
S1 C7 C8 C9 176.6(3)
F8 C8 C9 F9 0.1(6)
C7 C8 C9 F9 -178.9(4)
F8 C8 C9 C10 178.7(4)
C7 C8 C9 C10 -0.2(6)
F9 C9 C10 F10 -0.8(6)
C8 C9 C10 F10 -179.4(4)
F9 C9 C10 C11 179.4(4)
C8 C9 C10 C11 0.8(6)
F10 C10 C11 F11 1.1(5)
C9 C10 C11 F11 -179.1(4)
F10 C10 C11 C12 179.9(3)
C9 C10 C11 C12 -0.4(6)
F11 C11 C12 F12 0.7(5)
C10 C11 C12 F12 -178.0(3)
F11 C11 C12 C7 178.1(3)
C10 C11 C12 C7 -0.7(5)
C8 C7 C12 F12 178.5(3)
S1 C7 C12 F12 1.2(5)
C8 C7 C12 C11 1.2(5)
S1 C7 C12 C11 -176.1(3)
Os1 S3 C13 C14 -118.2(3)
Os1 S3 C13 C18 67.6(3)
C18 C13 C14 F14 178.7(3)
S3 C13 C14 F14 4.2(5)
C18 C13 C14 C15 -1.9(6)
S3 C13 C14 C15 -176.4(3)
F14 C14 C15 F15 0.5(6)
C13 C14 C15 F15 -178.9(4)
F14 C14 C15 C16 -179.8(4)
C13 C14 C15 C16 0.8(6)
F15 C15 C16 F16 -0.4(6)
C14 C15 C16 F16 179.9(4)
F15 C15 C16 C17 179.7(4)
C14 C15 C16 C17 0.0(6)
F16 C16 C17 F17 -0.7(6)
C15 C16 C17 F17 179.2(4)
F16 C16 C17 C18 -179.4(4)
C15 C16 C17 C18 0.5(6)
F17 C17 C18 F18 1.3(6)
C16 C17 C18 F18 -180.0(4)
F17 C17 C18 C13 179.5(4)
C16 C17 C18 C13 -1.8(6)
C14 C13 C18 F18 -179.4(3)
S3 C13 C18 F18 -5.0(5)
C14 C13 C18 C17 2.4(5)
S3 C13 C18 C17 176.8(3)
Os1 S4 C19 C20 -88.8(3)
Os1 S4 C19 C24 90.4(3)
C24 C19 C20 F20 -179.6(4)
S4 C19 C20 F20 -0.3(6)
C24 C19 C20 C21 -1.5(6)
S4 C19 C20 C21 177.7(4)
F20 C20 C21 F21 -0.3(8)
C19 C20 C21 F21 -178.4(5)
F20 C20 C21 C22 178.6(5)
C19 C20 C21 C22 0.5(8)
F21 C21 C22 F22 0.0(9)
C20 C21 C22 F22 -179.0(5)
F21 C21 C22 C23 179.7(5)
C20 C21 C22 C23 0.8(8)
F22 C22 C23 F23 1.1(8)
C21 C22 C23 F23 -178.7(5)
F22 C22 C23 C24 178.8(5)
C21 C22 C23 C24 -1.0(8)
F23 C23 C24 F24 1.7(7)
C22 C23 C24 F24 -176.0(4)
F23 C23 C24 C19 177.7(4)
C22 C23 C24 C19 0.0(7)
C20 C19 C24 F24 177.2(4)
S4 C19 C24 F24 -2.1(5)
C20 C19 C24 C23 1.2(6)
S4 C19 C24 C23 -178.1(3)
S2 Os1 C25 C26 -24.5(3)
S3 Os1 C25 C26 -143.5(3)
S4 Os1 C25 C26 97.6(3)
S2 Os1 C25 C30 159.7(3)
S3 Os1 C25 C30 40.7(3)
S4 Os1 C25 C30 -78.2(3)
C30 C25 C26 C27 -0.8(6)
Os1 C25 C26 C27 -176.8(4)
C25 C26 C27 C28 0.7(8)
C26 C27 C28 O31 -179.0(5)
C26 C27 C28 C29 0.7(7)
O31 C28 C29 C30 177.8(4)
C27 C28 C29 C30 -1.8(6)
C28 C29 C30 C25 1.8(6)
C26 C25 C30 C29 -0.4(5)
Os1 C25 C30 C29 175.7(3)
C27 C28 O31 C32 -4.2(8)
C29 C28 O31 C32 176.2(6)
