#------------------------------------------------------------------------------
#$Date: 2016-03-21 07:31:44 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178569 $
#$URL: svn://www.crystallography.net/cod/cif/4/06/78/4067873.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4067873
loop_
_publ_author_name
'Fier, Patrick S.'
'Reinig, Regina R.'
'King, Janeth'
'Dickerson, Christopher'
'Chin, Robert M.'
'Doucouré, Mantia'
'Brennessel, William'
_publ_section_title
;
 Selective Dialkylation of a Doubly Linked Dicyclopentadiene Ligand and
 the Ensuing Ruthenium Complexes
;
_journal_issue                   1
_journal_name_full               Organometallics
_journal_page_first              261
_journal_paper_doi               10.1021/om200854n
_journal_volume                  31
_journal_year                    2012
_chemical_formula_moiety         'C32 H46 Cl N4 Ru2, 0.5(Cl6 Zn2), C2 H3 N'
_chemical_formula_sum            'C34 H49 Cl4 N5 Ru2 Zn'
_chemical_formula_weight         937.09
_chemical_name_common            unimc15
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                110.431(5)
_cell_angle_beta                 107.181(5)
_cell_angle_gamma                94.532(5)
_cell_formula_units_Z            4
_cell_length_a                   13.441(4)
_cell_length_b                   17.036(5)
_cell_length_c                   19.978(6)
_cell_measurement_reflns_used    3744
_cell_measurement_temperature    100.0(1)
_cell_measurement_theta_max      30.17
_cell_measurement_theta_min      2.30
_cell_volume                     4010(2)
_computing_cell_refinement       'SAINT (Bruker, 2009)'
_computing_data_collection       'APEX2 (Bruker, 2011)'
_computing_data_reduction        'SAINT (Bruker, 2009)'
_computing_molecular_graphics    'SHELXTL (Sheldrick, 2008)'
_computing_publication_material  'SHELXTL (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SIR97 (Altomare et al., 1999)'
_diffrn_ambient_temperature      100.0(1)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Bruker SMART APEX II CCD Platform'
_diffrn_measurement_method       'area detector, ω scans per φ'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0982
_diffrn_reflns_av_sigmaI/netI    0.1163
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       23
_diffrn_reflns_limit_k_min       -23
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_number            68896
_diffrn_reflns_theta_full        29.57
_diffrn_reflns_theta_max         29.57
_diffrn_reflns_theta_min         1.30
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.633
_exptl_absorpt_correction_T_max  0.8804
_exptl_absorpt_correction_T_min  0.6577
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS (Sheldrick, 2008)'
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.552
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             1896
_exptl_crystal_size_max          0.28
_exptl_crystal_size_mid          0.24
_exptl_crystal_size_min          0.08
_refine_diff_density_max         2.720
_refine_diff_density_min         -1.806
_refine_diff_density_rms         0.201
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.018
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     858
_refine_ls_number_reflns         22445
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.018
_refine_ls_R_factor_all          0.1521
_refine_ls_R_factor_gt           0.0750
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1015P)²+17.3823P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1882
_refine_ls_wR_factor_ref         0.2336
_reflns_number_gt                12065
_reflns_number_total             22445
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            om200854n_si_001.cif
_cod_data_source_block           6
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               4067873
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ru1 Ru 0.20034(5) 0.89540(4) 0.27089(4) 0.02459(15) Uani 1 1 d .
Ru2 Ru -0.08978(5) 0.78920(4) 0.26309(4) 0.02348(14) Uani 1 1 d .
Cl1 Cl 0.03911(16) 0.78162(13) 0.19573(12) 0.0326(4) Uani 1 1 d .
N1 N 0.1810(6) 0.9032(4) 0.1655(4) 0.0349(16) Uani 1 1 d .
N2 N 0.2765(6) 0.7990(5) 0.2261(4) 0.0352(16) Uani 1 1 d .
N3 N -0.1944(5) 0.7893(4) 0.1626(4) 0.0294(15) Uani 1 1 d .
N4 N -0.1292(5) 0.6568(4) 0.2028(4) 0.0299(15) Uani 1 1 d .
C1 C 0.1741(8) 0.8936(6) 0.1039(6) 0.040(2) Uani 1 1 d .
C2 C 0.1692(10) 0.8807(6) 0.0282(6) 0.053(3) Uani 1 1 d .
H2A H 0.1514 0.9309 0.0177 0.080 Uiso 1 1 calc R
H2B H 0.1146 0.8300 -0.0083 0.080 Uiso 1 1 calc R
H2C H 0.2384 0.8723 0.0232 0.080 Uiso 1 1 calc R
C3 C 0.3164(7) 0.7477(5) 0.1945(5) 0.0335(18) Uani 1 1 d .
C4 C 0.3665(8) 0.6847(6) 0.1540(6) 0.048(2) Uani 1 1 d .
H4A H 0.3965 0.6528 0.1848 0.071 Uiso 1 1 calc R
H4B H 0.4234 0.7135 0.1442 0.071 Uiso 1 1 calc R
H4C H 0.3135 0.6452 0.1055 0.071 Uiso 1 1 calc R
C5 C -0.2485(8) 0.7843(6) 0.1066(6) 0.043(2) Uani 1 1 d .
C6 C -0.3187(8) 0.7767(6) 0.0316(6) 0.050(3) Uani 1 1 d .
H6A H -0.3767 0.8067 0.0376 0.075 Uiso 1 1 calc R
H6B H -0.3483 0.7161 -0.0011 0.075 Uiso 1 1 calc R
H6C H -0.2778 0.8021 0.0083 0.075 Uiso 1 1 calc R
C7 C -0.1559(6) 0.5851(5) 0.1660(5) 0.0302(17) Uani 1 1 d .
C8 C -0.1944(8) 0.4947(5) 0.1184(5) 0.040(2) Uani 1 1 d .
H8A H -0.1381 0.4634 0.1303 0.060 Uiso 1 1 calc R
H8B H -0.2147 0.4865 0.0647 0.060 Uiso 1 1 calc R
H8C H -0.2563 0.4732 0.1280 0.060 Uiso 1 1 calc R
C21 C 0.1423(6) 0.9779(5) 0.3536(4) 0.0237(15) Uani 1 1 d .
C22 C 0.1932(6) 0.9182(5) 0.3812(4) 0.0249(16) Uani 1 1 d .
C23 C 0.2998(6) 0.9332(5) 0.3850(5) 0.0263(16) Uani 1 1 d .
H23A H 0.3513 0.9028 0.4020 0.032 Uiso 1 1 calc R
C24 C 0.3207(6) 0.9999(5) 0.3600(4) 0.0244(15) Uani 1 1 d .
C25 C 0.2214(6) 1.0268(4) 0.3414(4) 0.0238(15) Uani 1 1 d .
H25A H 0.2097 1.0712 0.3233 0.029 Uiso 1 1 calc R
C26 C -0.0279(6) 0.9136(5) 0.3512(4) 0.0229(15) Uani 1 1 d .
C27 C 0.0220(6) 0.8533(4) 0.3774(4) 0.0226(15) Uani 1 1 d .
C28 C -0.0615(6) 0.7931(5) 0.3754(4) 0.0259(16) Uani 1 1 d .
H28A H -0.0511 0.7460 0.3899 0.031 Uiso 1 1 calc R
C29 C -0.1620(6) 0.8146(5) 0.3485(5) 0.0279(17) Uani 1 1 d .
C30 C -0.1399(6) 0.8906(5) 0.3345(5) 0.0286(17) Uani 1 1 d .
H30A H -0.1915 0.9207 0.3170 0.034 Uiso 1 1 calc R
C31 C 0.0327(6) 0.9907(5) 0.3473(5) 0.0258(16) Uani 1 1 d .
C32 C -0.0251(6) 1.0046(5) 0.2758(5) 0.0302(18) Uani 1 1 d .
H32A H -0.0234 0.9574 0.2310 0.045 Uiso 1 1 calc R
H32B H 0.0099 1.0587 0.2782 0.045 Uiso 1 1 calc R
H32C H -0.0992 1.0067 0.2720 0.045 Uiso 1 1 calc R
C33 C 0.0367(6) 1.0699(5) 0.4184(5) 0.0288(17) Uani 1 1 d .
H33A H 0.0745 1.1216 0.4185 0.043 Uiso 1 1 calc R
H33B H 0.0739 1.0617 0.4649 0.043 Uiso 1 1 calc R
H33C H -0.0360 1.0761 0.4162 0.043 Uiso 1 1 calc R
C34 C 0.1413(6) 0.8587(5) 0.4073(4) 0.0238(15) Uani 1 1 d .
C35 C 0.1699(6) 0.7706(5) 0.3820(5) 0.0311(18) Uani 1 1 d .
H35A H 0.1458 0.7444 0.3263 0.047 Uiso 1 1 calc R
H35B H 0.1351 0.7342 0.4006 0.047 Uiso 1 1 calc R
H35C H 0.2472 0.7766 0.4028 0.047 Uiso 1 1 calc R
C36 C 0.1782(6) 0.8995(5) 0.4942(5) 0.0301(17) Uani 1 1 d .
H36A H 0.1638 0.9575 0.5104 0.045 Uiso 1 1 calc R
H36B H 0.2547 0.9023 0.5154 0.045 Uiso 1 1 calc R
H36C H 0.1397 0.8651 0.5125 0.045 Uiso 1 1 calc R
C37 C 0.4270(6) 1.0420(5) 0.3637(5) 0.0300(18) Uani 1 1 d .
C38 C 0.4117(7) 1.0855(7) 0.3079(6) 0.051(3) Uani 1 1 d .
H38A H 0.3680 1.0442 0.2568 0.076 Uiso 1 1 calc R
H38B H 0.4812 1.1071 0.3074 0.076 Uiso 1 1 calc R
H38C H 0.3760 1.1332 0.3233 0.076 Uiso 1 1 calc R
C39 C 0.4999(7) 0.9785(6) 0.3495(7) 0.050(3) Uani 1 1 d .
H39A H 0.4660 0.9329 0.2988 0.075 Uiso 1 1 calc R
H39B H 0.5128 0.9537 0.3880 0.075 Uiso 1 1 calc R
H39C H 0.5676 1.0081 0.3526 0.075 Uiso 1 1 calc R
C40 C 0.4795(8) 1.1115(7) 0.4457(6) 0.052(3) Uani 1 1 d .
H40A H 0.4295 1.1484 0.4577 0.077 Uiso 1 1 calc R
H40B H 0.5440 1.1461 0.4490 0.077 Uiso 1 1 calc R
H40C H 0.4980 1.0839 0.4820 0.077 Uiso 1 1 calc R
C41 C -0.2700(6) 0.7731(6) 0.3435(5) 0.0351(19) Uani 1 1 d .
C42 C -0.3587(7) 0.7781(7) 0.2781(6) 0.051(3) Uani 1 1 d .
H42A H -0.3478 0.7477 0.2300 0.077 Uiso 1 1 calc R
H42B H -0.3582 0.8382 0.2856 0.077 Uiso 1 1 calc R
H42C H -0.4274 0.7517 0.2764 0.077 Uiso 1 1 calc R
C43 C -0.2723(8) 0.6789(6) 0.3304(6) 0.048(3) Uani 1 1 d .
H43A H -0.2606 0.6491 0.2825 0.071 Uiso 1 1 calc R
H43B H -0.3417 0.6526 0.3277 0.071 Uiso 1 1 calc R
H43C H -0.2162 0.6746 0.3726 0.071 Uiso 1 1 calc R
C44 C -0.2869(7) 0.8188(7) 0.4190(5) 0.048(3) Uani 1 1 d .
H44A H -0.2838 0.8796 0.4287 0.072 Uiso 1 1 calc R
H44B H -0.2312 0.8128 0.4604 0.072 Uiso 1 1 calc R
H44C H -0.3567 0.7933 0.4163 0.072 Uiso 1 1 calc R
Ru3 Ru 0.19321(5) 0.42564(4) 0.27592(4) 0.02557(15) Uani 1 1 d .
Ru4 Ru -0.08477(5) 0.28798(4) 0.25840(4) 0.02455(15) Uani 1 1 d .
Cl2 Cl 0.03913(15) 0.30532(12) 0.19173(11) 0.0300(4) Uani 1 1 d .
N5 N 0.1413(5) 0.4769(4) 0.1943(4) 0.0344(16) Uani 1 1 d .
N6 N 0.2806(5) 0.3575(4) 0.2129(4) 0.0300(15) Uani 1 1 d .
N7 N -0.1983(5) 0.2949(4) 0.1647(4) 0.0282(14) Uani 1 1 d .
N8 N -0.1178(6) 0.1577(4) 0.1880(4) 0.0342(16) Uani 1 1 d .
C9 C 0.1135(6) 0.5124(5) 0.1565(5) 0.0266(16) Uani 1 1 d .
C10 C 0.0775(7) 0.5594(6) 0.1079(5) 0.039(2) Uani 1 1 d .
H10A H 0.0724 0.6168 0.1392 0.058 Uiso 1 1 calc R
H10B H 0.0076 0.5288 0.0696 0.058 Uiso 1 1 calc R
H10C H 0.1286 0.5641 0.0825 0.058 Uiso 1 1 calc R
C11 C 0.3386(7) 0.3250(5) 0.1878(5) 0.0348(19) Uani 1 1 d .
C12 C 0.4208(8) 0.2867(7) 0.1602(6) 0.054(3) Uani 1 1 d .
H12A H 0.4465 0.2485 0.1856 0.082 Uiso 1 1 calc R
H12B H 0.4802 0.3321 0.1716 0.082 Uiso 1 1 calc R
H12C H 0.3904 0.2539 0.1051 0.082 Uiso 1 1 calc R
C13 C -0.2624(7) 0.2906(5) 0.1098(5) 0.0342(19) Uani 1 1 d .
C14 C -0.3416(7) 0.2880(6) 0.0417(5) 0.042(2) Uani 1 1 d .
H14A H -0.3857 0.3297 0.0556 0.062 Uiso 1 1 calc R
H14B H -0.3865 0.2305 0.0137 0.062 Uiso 1 1 calc R
H14C H -0.3063 0.3019 0.0096 0.062 Uiso 1 1 calc R
C15 C -0.1517(8) 0.0860(6) 0.1510(5) 0.040(2) Uani 1 1 d .
C16 C -0.1970(9) -0.0041(6) 0.1044(6) 0.052(3) Uani 1 1 d .
H16A H -0.1398 -0.0348 0.0974 0.078 Uiso 1 1 calc R
H16B H -0.2459 -0.0103 0.0547 0.078 Uiso 1 1 calc R
H16C H -0.2358 -0.0280 0.1298 0.078 Uiso 1 1 calc R
C71 C 0.1402(6) 0.4860(5) 0.3689(5) 0.0285(17) Uani 1 1 d .
C72 C 0.1964(6) 0.4198(4) 0.3822(4) 0.0230(15) Uani 1 1 d .
C73 C 0.3024(6) 0.4406(5) 0.3840(4) 0.0255(16) Uani 1 1 d .
H73A H 0.3554 0.4076 0.3912 0.031 Uiso 1 1 calc R
C74 C 0.3165(6) 0.5192(5) 0.3731(5) 0.0250(16) Uani 1 1 d .
C75 C 0.2167(6) 0.5453(5) 0.3641(5) 0.0276(17) Uani 1 1 d .
H75A H 0.2028 0.5956 0.3559 0.033 Uiso 1 1 calc R
C76 C -0.0254(6) 0.4053(5) 0.3582(4) 0.0245(15) Uani 1 1 d .
C77 C 0.0298(6) 0.3390(5) 0.3722(4) 0.0229(15) Uani 1 1 d .
C78 C -0.0485(6) 0.2710(5) 0.3640(4) 0.0261(16) Uani 1 1 d .
H78A H -0.0342 0.2200 0.3706 0.031 Uiso 1 1 calc R
C79 C -0.1529(6) 0.2918(5) 0.3439(5) 0.0268(17) Uani 1 1 d .
C80 C -0.1356(6) 0.3744(5) 0.3405(5) 0.0296(17) Uani 1 1 d .
H80A H -0.1902 0.4044 0.3281 0.035 Uiso 1 1 calc R
C81 C 0.0288(6) 0.4910(5) 0.3670(5) 0.0268(16) Uani 1 1 d .
C82 C -0.0321(6) 0.5165(5) 0.3025(5) 0.0332(19) Uani 1 1 d .
H82A H -0.0344 0.4742 0.2537 0.050 Uiso 1 1 calc R
H82B H 0.0038 0.5729 0.3102 0.050 Uiso 1 1 calc R
H82C H -0.1048 0.5187 0.3025 0.050 Uiso 1 1 calc R
C83 C 0.0338(7) 0.5598(5) 0.4437(5) 0.037(2) Uani 1 1 d .
H83A H 0.0720 0.5439 0.4856 0.055 Uiso 1 1 calc R
H83B H -0.0386 0.5636 0.4437 0.055 Uiso 1 1 calc R
H83C H 0.0712 0.6153 0.4505 0.055 Uiso 1 1 calc R
C84 C 0.1495(6) 0.3473(5) 0.3984(5) 0.0255(16) Uani 1 1 d .
C85 C 0.1793(6) 0.2636(5) 0.3578(5) 0.0315(18) Uani 1 1 d .
H85A H 0.1517 0.2188 0.3717 0.047 Uiso 1 1 calc R
H85B H 0.2569 0.2714 0.3730 0.047 Uiso 1 1 calc R
H85C H 0.1484 0.2468 0.3026 0.047 Uiso 1 1 calc R
C86 C 0.1916(6) 0.3721(6) 0.4838(5) 0.0346(19) Uani 1 1 d .
H86A H 0.1729 0.4264 0.5091 0.052 Uiso 1 1 calc R
H86B H 0.2691 0.3785 0.5014 0.052 Uiso 1 1 calc R
H86C H 0.1600 0.3274 0.4960 0.052 Uiso 1 1 calc R
C87 C 0.4192(7) 0.5698(5) 0.3800(5) 0.0342(19) Uani 1 1 d .
C88 C 0.3977(7) 0.6079(7) 0.3194(6) 0.051(3) Uani 1 1 d .
H88A H 0.3649 0.5618 0.2688 0.076 Uiso 1 1 calc R
H88B H 0.4650 0.6385 0.3227 0.076 Uiso 1 1 calc R
H88C H 0.3496 0.6477 0.3280 0.076 Uiso 1 1 calc R
C89 C 0.5006(7) 0.5129(6) 0.3693(6) 0.043(2) Uani 1 1 d .
H89A H 0.4713 0.4658 0.3191 0.064 Uiso 1 1 calc R
H89B H 0.5168 0.4896 0.4089 0.064 Uiso 1 1 calc R
H89C H 0.5659 0.5469 0.3731 0.064 Uiso 1 1 calc R
C90 C 0.4627(7) 0.6412(6) 0.4600(6) 0.045(2) Uani 1 1 d .
H90A H 0.4102 0.6772 0.4669 0.068 Uiso 1 1 calc R
H90B H 0.5288 0.6761 0.4661 0.068 Uiso 1 1 calc R
H90C H 0.4769 0.6158 0.4981 0.068 Uiso 1 1 calc R
C91 C -0.2570(6) 0.2414(5) 0.3364(5) 0.0324(18) Uani 1 1 d .
C92 C -0.3509(7) 0.2544(7) 0.2788(6) 0.047(3) Uani 1 1 d .
H92A H -0.3472 0.2277 0.2277 0.071 Uiso 1 1 calc R
H92B H -0.3481 0.3157 0.2918 0.071 Uiso 1 1 calc R
H92C H -0.4176 0.2280 0.2798 0.071 Uiso 1 1 calc R
C93 C -0.2557(7) 0.1461(5) 0.3119(6) 0.040(2) Uani 1 1 d .
H93A H -0.2424 0.1253 0.2636 0.060 Uiso 1 1 calc R
H93B H -0.3245 0.1147 0.3053 0.060 Uiso 1 1 calc R
H93C H -0.1993 0.1371 0.3510 0.060 Uiso 1 1 calc R
C94 C -0.2703(7) 0.2754(6) 0.4148(5) 0.041(2) Uani 1 1 d .
H94A H -0.2711 0.3366 0.4306 0.062 Uiso 1 1 calc R
H94B H -0.2109 0.2668 0.4522 0.062 Uiso 1 1 calc R
H94C H -0.3374 0.2446 0.4116 0.062 Uiso 1 1 calc R
Zn1 Zn 0.46211(8) 0.48274(6) 0.06467(6) 0.0333(2) Uani 1 1 d .
Cl3 Cl 0.29196(19) 0.45962(15) 0.05222(16) 0.0491(6) Uani 1 1 d .
Cl4 Cl 0.5716(2) 0.47044(19) 0.16509(16) 0.0578(7) Uani 1 1 d .
Cl5 Cl 0.47775(17) 0.39375(12) -0.05045(13) 0.0362(5) Uani 1 1 d .
Zn2 Zn 0.47652(10) 0.99744(7) 0.07406(7) 0.0481(3) Uani 1 1 d .
Cl6 Cl 0.3548(2) 1.06698(19) 0.10627(18) 0.0621(7) Uani 1 1 d .
Cl7 Cl 0.5485(3) 0.9214(2) 0.1372(2) 0.0729(9) Uani 1 1 d .
Cl8 Cl 0.5943(2) 1.09136(16) 0.05767(16) 0.0524(6) Uani 1 1 d .
N9 N -0.1208(7) 0.3391(5) -0.0044(5) 0.046(2) Uani 1 1 d .
C17 C -0.0398(8) 0.3199(6) 0.0017(5) 0.040(2) Uani 1 1 d .
C18 C 0.0638(7) 0.2960(7) 0.0091(6) 0.046(2) Uani 1 1 d .
H18A H 0.1032 0.3273 -0.0111 0.069 Uiso 1 1 calc R
H18B H 0.0536 0.2344 -0.0195 0.069 Uiso 1 1 calc R
H18C H 0.1040 0.3104 0.0630 0.069 Uiso 1 1 calc R
N10 N 0.0819(17) 0.1001(13) 0.0126(9) 0.167(9) Uani 1 1 d .
C19 C 0.1005(13) 0.1015(10) 0.0748(9) 0.086(5) Uani 1 1 d .
C20 C 0.1234(11) 0.1026(8) 0.1489(7) 0.067(4) Uani 1 1 d .
H20A H 0.0789 0.0527 0.1467 0.101 Uiso 1 1 calc R
H20B H 0.1087 0.1550 0.1816 0.101 Uiso 1 1 calc R
H20C H 0.1986 0.1007 0.1698 0.101 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N2 Ru1 N1 80.0(3) . .
N2 Ru1 C23 95.7(3) . .
N1 Ru1 C23 146.6(3) . .
N2 Ru1 C25 145.1(3) . .
N1 Ru1 C25 100.7(3) . .
C23 Ru1 C25 64.5(3) . .
N2 Ru1 C22 117.7(3) . .
N1 Ru1 C22 162.3(3) . .
C23 Ru1 C22 38.8(3) . .
C25 Ru1 C22 65.3(3) . .
N2 Ru1 C24 107.3(3) . .
N1 Ru1 C24 110.1(3) . .
C23 Ru1 C24 39.3(3) . .
C25 Ru1 C24 39.2(3) . .
C22 Ru1 C24 66.6(3) . .
N2 Ru1 C21 157.0(3) . .
N1 Ru1 C21 123.0(3) . .
C23 Ru1 C21 65.2(3) . .
C25 Ru1 C21 39.0(2) . .
C22 Ru1 C21 39.4(3) . .
C24 Ru1 C21 66.6(3) . .
N2 Ru1 Cl1 83.3(2) . .
N1 Ru1 Cl1 82.99(19) . .
C23 Ru1 Cl1 129.7(2) . .
C25 Ru1 Cl1 131.5(2) . .
C22 Ru1 Cl1 98.09(19) . .
C24 Ru1 Cl1 164.1(2) . .
C21 Ru1 Cl1 99.0(2) . .
N3 Ru2 N4 83.2(3) . .
N3 Ru2 C30 94.1(3) . .
N4 Ru2 C30 141.6(3) . .
N3 Ru2 C26 113.3(3) . .
N4 Ru2 C26 163.3(3) . .
C30 Ru2 C26 39.4(3) . .
N3 Ru2 C29 110.7(3) . .
N4 Ru2 C29 105.9(3) . .
C30 Ru2 C29 39.6(3) . .
C26 Ru2 C29 66.6(3) . .
N3 Ru2 C28 149.3(3) . .
N4 Ru2 C28 99.1(3) . .
C30 Ru2 C28 65.1(3) . .
C26 Ru2 C28 65.5(3) . .
C29 Ru2 C28 39.0(3) . .
N3 Ru2 C27 152.2(3) . .
N4 Ru2 C27 124.5(3) . .
C30 Ru2 C27 65.7(3) . .
C26 Ru2 C27 39.1(3) . .
C29 Ru2 C27 66.4(3) . .
C28 Ru2 C27 39.2(3) . .
N3 Ru2 Cl1 82.98(19) . .
N4 Ru2 Cl1 83.44(19) . .
C30 Ru2 Cl1 134.4(2) . .
C26 Ru2 Cl1 100.71(19) . .
C29 Ru2 Cl1 163.9(2) . .
C28 Ru2 Cl1 127.8(2) . .
C27 Ru2 Cl1 97.5(2) . .
Ru1 Cl1 Ru2 112.25(8) . .
C1 N1 Ru1 168.2(7) . .
C3 N2 Ru1 172.7(8) . .
C5 N3 Ru2 175.3(8) . .
C7 N4 Ru2 175.5(7) . .
N1 C1 C2 177.8(11) . .
C1 C2 H2A 109.5 . .
C1 C2 H2B 109.5 . .
H2A C2 H2B 109.5 . .
C1 C2 H2C 109.5 . .
H2A C2 H2C 109.5 . .
H2B C2 H2C 109.5 . .
N2 C3 C4 178.7(10) . .
C3 C4 H4A 109.5 . .
C3 C4 H4B 109.5 . .
H4A C4 H4B 109.5 . .
C3 C4 H4C 109.5 . .
H4A C4 H4C 109.5 . .
H4B C4 H4C 109.5 . .
N3 C5 C6 178.7(12) . .
C5 C6 H6A 109.5 . .
C5 C6 H6B 109.5 . .
H6A C6 H6B 109.5 . .
C5 C6 H6C 109.5 . .
H6A C6 H6C 109.5 . .
H6B C6 H6C 109.5 . .
N4 C7 C8 177.5(10) . .
C7 C8 H8A 109.5 . .
C7 C8 H8B 109.5 . .
H8A C8 H8B 109.5 . .
C7 C8 H8C 109.5 . .
H8A C8 H8C 109.5 . .
H8B C8 H8C 109.5 . .
C25 C21 C22 106.5(6) . .
C25 C21 C31 127.4(7) . .
C22 C21 C31 125.8(6) . .
C25 C21 Ru1 69.7(4) . .
C22 C21 Ru1 69.6(4) . .
C31 C21 Ru1 130.1(6) . .
C23 C22 C21 107.0(6) . .
C23 C22 C34 128.3(7) . .
C21 C22 C34 124.4(6) . .
C23 C22 Ru1 69.6(4) . .
C21 C22 Ru1 71.0(4) . .
C34 C22 Ru1 128.9(5) . .
C22 C23 C24 111.5(7) . .
C22 C23 Ru1 71.6(5) . .
C24 C23 Ru1 71.7(5) . .
C22 C23 H23A 124.2 . .
C24 C23 H23A 124.2 . .
Ru1 C23 H23A 124.1 . .
C23 C24 C25 104.2(6) . .
C23 C24 C37 128.1(7) . .
C25 C24 C37 127.1(7) . .
C23 C24 Ru1 69.0(4) . .
C25 C24 Ru1 70.0(4) . .
C37 C24 Ru1 131.4(6) . .
C21 C25 C24 110.8(7) . .
C21 C25 Ru1 71.3(4) . .
C24 C25 Ru1 70.8(4) . .
C21 C25 H25A 124.6 . .
C24 C25 H25A 124.6 . .
Ru1 C25 H25A 124.8 . .
C30 C26 C27 108.0(6) . .
C30 C26 C31 127.9(7) . .
C27 C26 C31 124.0(6) . .
C30 C26 Ru2 70.1(4) . .
C27 C26 Ru2 71.4(4) . .
C31 C26 Ru2 126.8(5) . .
C26 C27 C28 106.8(6) . .
C26 C27 C34 125.0(6) . .
C28 C27 C34 128.0(7) . .
C26 C27 Ru2 69.5(4) . .
C28 C27 Ru2 69.8(4) . .
C34 C27 Ru2 129.5(5) . .
C29 C28 C27 110.0(7) . .
C29 C28 Ru2 70.5(4) . .
C27 C28 Ru2 71.0(4) . .
C29 C28 H28A 125.0 . .
C27 C28 H28A 125.0 . .
Ru2 C28 H28A 125.1 . .
C28 C29 C30 106.0(6) . .
C28 C29 C41 127.8(7) . .
C30 C29 C41 125.9(7) . .
C28 C29 Ru2 70.5(4) . .
C30 C29 Ru2 69.6(4) . .
C41 C29 Ru2 129.5(6) . .
C26 C30 C29 109.2(7) . .
C26 C30 Ru2 70.6(4) . .
C29 C30 Ru2 70.7(4) . .
C26 C30 H30A 125.4 . .
C29 C30 H30A 125.4 . .
Ru2 C30 H30A 124.9 . .
C21 C31 C32 113.1(6) . .
C21 C31 C26 108.1(6) . .
C32 C31 C26 111.3(6) . .
C21 C31 C33 109.3(6) . .
C32 C31 C33 108.7(6) . .
C26 C31 C33 106.0(6) . .
C31 C32 H32A 109.5 . .
C31 C32 H32B 109.5 . .
H32A C32 H32B 109.5 . .
C31 C32 H32C 109.5 . .
H32A C32 H32C 109.5 . .
H32B C32 H32C 109.5 . .
C31 C33 H33A 109.5 . .
C31 C33 H33B 109.5 . .
H33A C33 H33B 109.5 . .
C31 C33 H33C 109.5 . .
H33A C33 H33C 109.5 . .
H33B C33 H33C 109.5 . .
C22 C34 C27 107.7(6) . .
C22 C34 C35 112.2(6) . .
C27 C34 C35 111.9(6) . .
C22 C34 C36 107.8(6) . .
C27 C34 C36 107.5(6) . .
C35 C34 C36 109.7(7) . .
C34 C35 H35A 109.5 . .
C34 C35 H35B 109.5 . .
H35A C35 H35B 109.5 . .
C34 C35 H35C 109.5 . .
H35A C35 H35C 109.5 . .
H35B C35 H35C 109.5 . .
C34 C36 H36A 109.5 . .
C34 C36 H36B 109.5 . .
H36A C36 H36B 109.5 . .
C34 C36 H36C 109.5 . .
H36A C36 H36C 109.5 . .
H36B C36 H36C 109.5 . .
C38 C37 C24 110.9(7) . .
C38 C37 C39 110.3(8) . .
C24 C37 C39 111.9(7) . .
C38 C37 C40 108.5(8) . .
C24 C37 C40 106.2(7) . .
C39 C37 C40 108.8(8) . .
C37 C38 H38A 109.5 . .
C37 C38 H38B 109.5 . .
H38A C38 H38B 109.5 . .
C37 C38 H38C 109.5 . .
H38A C38 H38C 109.5 . .
H38B C38 H38C 109.5 . .
C37 C39 H39A 109.5 . .
C37 C39 H39B 109.5 . .
H39A C39 H39B 109.5 . .
C37 C39 H39C 109.5 . .
H39A C39 H39C 109.5 . .
H39B C39 H39C 109.5 . .
C37 C40 H40A 109.5 . .
C37 C40 H40B 109.5 . .
H40A C40 H40B 109.5 . .
C37 C40 H40C 109.5 . .
H40A C40 H40C 109.5 . .
H40B C40 H40C 109.5 . .
C42 C41 C29 110.9(7) . .
C42 C41 C43 108.5(8) . .
C29 C41 C43 109.7(7) . .
C42 C41 C44 110.3(8) . .
C29 C41 C44 108.7(7) . .
C43 C41 C44 108.7(8) . .
C41 C42 H42A 109.5 . .
C41 C42 H42B 109.5 . .
H42A C42 H42B 109.5 . .
C41 C42 H42C 109.5 . .
H42A C42 H42C 109.5 . .
H42B C42 H42C 109.5 . .
C41 C43 H43A 109.5 . .
C41 C43 H43B 109.5 . .
H43A C43 H43B 109.5 . .
C41 C43 H43C 109.5 . .
H43A C43 H43C 109.5 . .
H43B C43 H43C 109.5 . .
C41 C44 H44A 109.5 . .
C41 C44 H44B 109.5 . .
H44A C44 H44B 109.5 . .
C41 C44 H44C 109.5 . .
H44A C44 H44C 109.5 . .
H44B C44 H44C 109.5 . .
N5 Ru3 N6 88.7(3) . .
N5 Ru3 C75 91.1(3) . .
N6 Ru3 C75 137.8(3) . .
N5 Ru3 C73 148.0(3) . .
N6 Ru3 C73 95.1(3) . .
C75 Ru3 C73 65.2(3) . .
N5 Ru3 C74 108.9(3) . .
N6 Ru3 C74 101.8(3) . .
C75 Ru3 C74 39.3(3) . .
C73 Ru3 C74 39.2(3) . .
N5 Ru3 C71 109.3(3) . .
N6 Ru3 C71 161.0(3) . .
C75 Ru3 C71 39.4(3) . .
C73 Ru3 C71 66.4(3) . .
C74 Ru3 C71 67.0(3) . .
N5 Ru3 C72 149.1(3) . .
N6 Ru3 C72 122.2(3) . .
C75 Ru3 C72 65.5(3) . .
C73 Ru3 C72 38.9(3) . .
C74 Ru3 C72 66.1(3) . .
C71 Ru3 C72 39.9(3) . .
N5 Ru3 Cl2 85.2(2) . .
N6 Ru3 Cl2 86.74(19) . .
C75 Ru3 Cl2 135.3(2) . .
C73 Ru3 Cl2 126.63(19) . .
C74 Ru3 Cl2 163.4(2) . .
C71 Ru3 Cl2 100.7(2) . .
C72 Ru3 Cl2 97.36(19) . .
N7 Ru4 N8 83.2(3) . .
N7 Ru4 C80 95.4(3) . .
N8 Ru4 C80 140.4(3) . .
N7 Ru4 C78 148.7(3) . .
N8 Ru4 C78 96.3(3) . .
C80 Ru4 C78 65.3(3) . .
N7 Ru4 C79 110.1(3) . .
N8 Ru4 C79 104.1(3) . .
C80 Ru4 C79 39.4(3) . .
C78 Ru4 C79 39.5(3) . .
N7 Ru4 C76 115.3(3) . .
N8 Ru4 C76 160.9(3) . .
C80 Ru4 C76 39.0(3) . .
C78 Ru4 C76 65.7(3) . .
C79 Ru4 C76 66.5(3) . .
N7 Ru4 C77 154.9(3) . .
N8 Ru4 C77 121.9(3) . .
C80 Ru4 C77 65.7(3) . .
C78 Ru4 C77 38.9(3) . .
C79 Ru4 C77 66.4(3) . .
C76 Ru4 C77 39.7(3) . .
N7 Ru4 Cl2 83.59(18) . .
N8 Ru4 Cl2 85.48(19) . .
C80 Ru4 Cl2 133.8(2) . .
C78 Ru4 Cl2 127.7(2) . .
C79 Ru4 Cl2 163.9(2) . .
C76 Ru4 Cl2 100.38(19) . .
C77 Ru4 Cl2 97.54(19) . .
Ru4 Cl2 Ru3 111.54(8) . .
C9 N5 Ru3 172.5(7) . .
C11 N6 Ru3 170.9(7) . .
C13 N7 Ru4 173.7(7) . .
C15 N8 Ru4 168.9(8) . .
N5 C9 C10 179.4(9) . .
C9 C10 H10A 109.5 . .
C9 C10 H10B 109.5 . .
H10A C10 H10B 109.5 . .
C9 C10 H10C 109.5 . .
H10A C10 H10C 109.5 . .
H10B C10 H10C 109.5 . .
N6 C11 C12 175.8(10) . .
C11 C12 H12A 109.5 . .
C11 C12 H12B 109.5 . .
H12A C12 H12B 109.5 . .
C11 C12 H12C 109.5 . .
H12A C12 H12C 109.5 . .
H12B C12 H12C 109.5 . .
N7 C13 C14 178.3(8) . .
C13 C14 H14A 109.5 . .
C13 C14 H14B 109.5 . .
H14A C14 H14B 109.5 . .
C13 C14 H14C 109.5 . .
H14A C14 H14C 109.5 . .
H14B C14 H14C 109.5 . .
N8 C15 C16 178.6(11) . .
C15 C16 H16A 109.5 . .
C15 C16 H16B 109.5 . .
H16A C16 H16B 109.5 . .
C15 C16 H16C 109.5 . .
H16A C16 H16C 109.5 . .
H16B C16 H16C 109.5 . .
C75 C71 C72 105.2(7) . .
C75 C71 C81 129.1(7) . .
C72 C71 C81 125.5(6) . .
C75 C71 Ru3 68.9(4) . .
C72 C71 Ru3 70.3(4) . .
C81 C71 Ru3 128.2(6) . .
C73 C72 C71 108.2(6) . .
C73 C72 C84 127.6(7) . .
C71 C72 C84 123.9(6) . .
C73 C72 Ru3 70.1(4) . .
C71 C72 Ru3 69.8(4) . .
C84 C72 Ru3 130.1(5) . .
C72 C73 C74 109.4(7) . .
C72 C73 Ru3 71.0(4) . .
C74 C73 Ru3 70.5(5) . .
C72 C73 H73A 125.3 . .
C74 C73 H73A 125.3 . .
Ru3 C73 H73A 124.8 . .
C75 C74 C73 105.8(6) . .
C75 C74 C87 126.7(7) . .
C73 C74 C87 127.1(7) . .
C75 C74 Ru3 68.9(4) . .
C73 C74 Ru3 70.3(4) . .
C87 C74 Ru3 131.0(6) . .
C74 C75 C71 111.4(7) . .
C74 C75 Ru3 71.7(4) . .
C71 C75 Ru3 71.7(5) . .
C74 C75 H75A 124.3 . .
C71 C75 H75A 124.3 . .
Ru3 C75 H75A 123.8 . .
C80 C76 C77 106.5(6) . .
C80 C76 C81 128.8(7) . .
C77 C76 C81 124.6(6) . .
C80 C76 Ru4 68.9(4) . .
C77 C76 Ru4 70.2(4) . .
C81 C76 Ru4 128.8(5) . .
C78 C77 C76 107.4(6) . .
C78 C77 C84 127.7(7) . .
C76 C77 C84 124.7(6) . .
C78 C77 Ru4 70.3(4) . .
C76 C77 Ru4 70.1(4) . .
C84 C77 Ru4 129.4(5) . .
C77 C78 C79 109.7(6) . .
C77 C78 Ru4 70.8(4) . .
C79 C78 Ru4 70.3(4) . .
C77 C78 H78A 125.2 . .
C79 C78 H78A 125.2 . .
Ru4 C78 H78A 125.3 . .
C80 C79 C78 105.4(6) . .
C80 C79 C91 127.1(7) . .
C78 C79 C91 127.2(7) . .
C80 C79 Ru4 68.9(4) . .
C78 C79 Ru4 70.2(4) . .
C91 C79 Ru4 129.9(6) . .
C76 C80 C79 110.9(7) . .
C76 C80 Ru4 72.1(5) . .
C79 C80 Ru4 71.7(5) . .
C76 C80 H80A 124.5 . .
C79 C80 H80A 124.5 . .
Ru4 C80 H80A 123.3 . .
C71 C81 C76 108.3(6) . .
C71 C81 C82 111.4(6) . .
C76 C81 C82 111.1(7) . .
C71 C81 C83 108.3(7) . .
C76 C81 C83 109.1(6) . .
C82 C81 C83 108.6(7) . .
C81 C82 H82A 109.5 . .
C81 C82 H82B 109.5 . .
H82A C82 H82B 109.5 . .
C81 C82 H82C 109.5 . .
H82A C82 H82C 109.5 . .
H82B C82 H82C 109.5 . .
C81 C83 H83A 109.5 . .
C81 C83 H83B 109.5 . .
H83A C83 H83B 109.5 . .
C81 C83 H83C 109.5 . .
H83A C83 H83C 109.5 . .
H83B C83 H83C 109.5 . .
C77 C84 C86 108.8(6) . .
C77 C84 C72 107.8(6) . .
C86 C84 C72 107.8(6) . .
C77 C84 C85 110.8(6) . .
C86 C84 C85 110.4(7) . .
C72 C84 C85 111.2(6) . .
C84 C85 H85A 109.5 . .
C84 C85 H85B 109.5 . .
H85A C85 H85B 109.5 . .
C84 C85 H85C 109.5 . .
H85A C85 H85C 109.5 . .
H85B C85 H85C 109.5 . .
C84 C86 H86A 109.5 . .
C84 C86 H86B 109.5 . .
H86A C86 H86B 109.5 . .
C84 C86 H86C 109.5 . .
H86A C86 H86C 109.5 . .
H86B C86 H86C 109.5 . .
C74 C87 C88 109.8(7) . .
C74 C87 C89 111.0(6) . .
C88 C87 C89 108.7(8) . .
C74 C87 C90 107.3(7) . .
C88 C87 C90 110.4(8) . .
C89 C87 C90 109.6(8) . .
C87 C88 H88A 109.5 . .
C87 C88 H88B 109.5 . .
H88A C88 H88B 109.5 . .
C87 C88 H88C 109.5 . .
H88A C88 H88C 109.5 . .
H88B C88 H88C 109.5 . .
C87 C89 H89A 109.5 . .
C87 C89 H89B 109.5 . .
H89A C89 H89B 109.5 . .
C87 C89 H89C 109.5 . .
H89A C89 H89C 109.5 . .
H89B C89 H89C 109.5 . .
C87 C90 H90A 109.5 . .
C87 C90 H90B 109.5 . .
H90A C90 H90B 109.5 . .
C87 C90 H90C 109.5 . .
H90A C90 H90C 109.5 . .
H90B C90 H90C 109.5 . .
C79 C91 C92 110.6(7) . .
C79 C91 C93 110.9(7) . .
C92 C91 C93 109.3(8) . .
C79 C91 C94 107.7(7) . .
C92 C91 C94 108.7(8) . .
C93 C91 C94 109.5(7) . .
C91 C92 H92A 109.5 . .
C91 C92 H92B 109.5 . .
H92A C92 H92B 109.5 . .
C91 C92 H92C 109.5 . .
H92A C92 H92C 109.5 . .
H92B C92 H92C 109.5 . .
C91 C93 H93A 109.5 . .
C91 C93 H93B 109.5 . .
H93A C93 H93B 109.5 . .
C91 C93 H93C 109.5 . .
H93A C93 H93C 109.5 . .
H93B C93 H93C 109.5 . .
C91 C94 H94A 109.5 . .
C91 C94 H94B 109.5 . .
H94A C94 H94B 109.5 . .
C91 C94 H94C 109.5 . .
H94A C94 H94C 109.5 . .
H94B C94 H94C 109.5 . .
Cl4 Zn1 Cl3 114.95(11) . .
Cl4 Zn1 Cl5 111.77(11) . 2_665
Cl3 Zn1 Cl5 115.09(10) . 2_665
Cl4 Zn1 Cl5 113.22(11) . .
Cl3 Zn1 Cl5 107.49(10) . .
Cl5 Zn1 Cl5 92.08(8) 2_665 .
Zn1 Cl5 Zn1 87.92(8) 2_665 .
Cl7 Zn2 Cl6 119.21(13) . .
Cl7 Zn2 Cl8 116.20(13) . .
Cl6 Zn2 Cl8 107.23(11) . .
Cl7 Zn2 Cl8 108.79(13) . 2_675
Cl6 Zn2 Cl8 108.89(12) . 2_675
Cl8 Zn2 Cl8 93.31(9) . 2_675
Zn2 Cl8 Zn2 86.69(9) . 2_675
N9 C17 C18 179.5(10) . .
C17 C18 H18A 109.5 . .
C17 C18 H18B 109.5 . .
H18A C18 H18B 109.5 . .
C17 C18 H18C 109.5 . .
H18A C18 H18C 109.5 . .
H18B C18 H18C 109.5 . .
N10 C19 C20 179.4(16) . .
C19 C20 H20A 109.5 . .
C19 C20 H20B 109.5 . .
H20A C20 H20B 109.5 . .
C19 C20 H20C 109.5 . .
H20A C20 H20C 109.5 . .
H20B C20 H20C 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ru1 N2 2.080(7) .
Ru1 N1 2.097(7) .
Ru1 C23 2.106(8) .
Ru1 C25 2.130(7) .
Ru1 C22 2.132(8) .
Ru1 C24 2.142(8) .
Ru1 C21 2.152(7) .
Ru1 Cl1 2.468(2) .
Ru2 N3 2.083(7) .
Ru2 N4 2.087(7) .
Ru2 C30 2.123(8) .
Ru2 C26 2.129(7) .
Ru2 C29 2.137(7) .
Ru2 C28 2.138(7) .
Ru2 C27 2.153(8) .
Ru2 Cl1 2.474(2) .
N1 C1 1.157(11) .
N2 C3 1.156(11) .
N3 C5 1.111(11) .
N4 C7 1.145(10) .
C1 C2 1.432(13) .
C2 H2A 0.9800 .
C2 H2B 0.9800 .
C2 H2C 0.9800 .
C3 C4 1.445(12) .
C4 H4A 0.9800 .
C4 H4B 0.9800 .
C4 H4C 0.9800 .
C5 C6 1.470(14) .
C6 H6A 0.9800 .
C6 H6B 0.9800 .
C6 H6C 0.9800 .
C7 C8 1.451(11) .
C8 H8A 0.9800 .
C8 H8B 0.9800 .
C8 H8C 0.9800 .
C21 C25 1.428(9) .
C21 C22 1.443(11) .
C21 C31 1.482(10) .
C22 C23 1.410(10) .
C22 C34 1.505(9) .
C23 C24 1.430(10) .
C23 H23A 0.9500 .
C24 C25 1.434(10) .
C24 C37 1.517(10) .
C25 H25A 0.9500 .
C26 C30 1.432(10) .
C26 C27 1.434(10) .
C26 C31 1.528(10) .
C27 C28 1.441(10) .
C27 C34 1.519(10) .
C28 C29 1.426(11) .
C28 H28A 0.9500 .
C29 C30 1.444(11) .
C29 C41 1.524(10) .
C30 H30A 0.9500 .
C31 C32 1.521(11) .
C31 C33 1.564(11) .
C32 H32A 0.9800 .
C32 H32B 0.9800 .
C32 H32C 0.9800 .
C33 H33A 0.9800 .
C33 H33B 0.9800 .
C33 H33C 0.9800 .
C34 C35 1.528(11) .
C34 C36 1.528(11) .
C35 H35A 0.9800 .
C35 H35B 0.9800 .
C35 H35C 0.9800 .
C36 H36A 0.9800 .
C36 H36B 0.9800 .
C36 H36C 0.9800 .
C37 C38 1.515(12) .
C37 C39 1.527(12) .
C37 C40 1.553(13) .
C38 H38A 0.9800 .
C38 H38B 0.9800 .
C38 H38C 0.9800 .
C39 H39A 0.9800 .
C39 H39B 0.9800 .
C39 H39C 0.9800 .
C40 H40A 0.9800 .
C40 H40B 0.9800 .
C40 H40C 0.9800 .
C41 C42 1.521(13) .
C41 C43 1.529(13) .
C41 C44 1.531(12) .
C42 H42A 0.9800 .
C42 H42B 0.9800 .
C42 H42C 0.9800 .
C43 H43A 0.9800 .
C43 H43B 0.9800 .
C43 H43C 0.9800 .
C44 H44A 0.9800 .
C44 H44B 0.9800 .
C44 H44C 0.9800 .
Ru3 N5 2.080(7) .
Ru3 N6 2.092(7) .
Ru3 C75 2.102(8) .
Ru3 C73 2.136(8) .
Ru3 C74 2.139(8) .
Ru3 C71 2.140(8) .
Ru3 C72 2.147(7) .
Ru3 Cl2 2.487(2) .
Ru4 N7 2.084(7) .
Ru4 N8 2.096(7) .
Ru4 C80 2.111(8) .
Ru4 C78 2.147(7) .
Ru4 C79 2.148(8) .
Ru4 C76 2.153(8) .
Ru4 C77 2.154(8) .
Ru4 Cl2 2.478(2) .
N5 C9 1.124(10) .
N6 C11 1.129(11) .
N7 C13 1.152(11) .
N8 C15 1.153(11) .
C9 C10 1.464(11) .
C10 H10A 0.9800 .
C10 H10B 0.9800 .
C10 H10C 0.9800 .
C11 C12 1.474(12) .
C12 H12A 0.9800 .
C12 H12B 0.9800 .
C12 H12C 0.9800 .
C13 C14 1.442(13) .
C14 H14A 0.9800 .
C14 H14B 0.9800 .
C14 H14C 0.9800 .
C15 C16 1.454(13) .
C16 H16A 0.9800 .
C16 H16B 0.9800 .
C16 H16C 0.9800 .
C71 C75 1.431(10) .
C71 C72 1.463(11) .
C71 C81 1.496(11) .
C72 C73 1.428(9) .
C72 C84 1.517(9) .
C73 C74 1.436(10) .
C73 H73A 0.9500 .
C74 C75 1.428(11) .
C74 C87 1.511(10) .
C75 H75A 0.9500 .
C76 C80 1.425(10) .
C76 C77 1.462(11) .
C76 C81 1.506(9) .
C77 C78 1.431(9) .
C77 C84 1.515(10) .
C78 C79 1.450(10) .
C78 H78A 0.9500 .
C79 C80 1.436(10) .
C79 C91 1.522(10) .
C80 H80A 0.9500 .
C81 C82 1.530(11) .
C81 C83 1.550(11) .
C82 H82A 0.9800 .
C82 H82B 0.9800 .
C82 H82C 0.9800 .
C83 H83A 0.9800 .
C83 H83B 0.9800 .
C83 H83C 0.9800 .
C84 C86 1.517(11) .
C84 C85 1.525(11) .
C85 H85A 0.9800 .
C85 H85B 0.9800 .
C85 H85C 0.9800 .
C86 H86A 0.9800 .
C86 H86B 0.9800 .
C86 H86C 0.9800 .
C87 C88 1.529(12) .
C87 C89 1.531(12) .
C87 C90 1.535(13) .
C88 H88A 0.9800 .
C88 H88B 0.9800 .
C88 H88C 0.9800 .
C89 H89A 0.9800 .
C89 H89B 0.9800 .
C89 H89C 0.9800 .
C90 H90A 0.9800 .
C90 H90B 0.9800 .
C90 H90C 0.9800 .
C91 C92 1.527(12) .
C91 C93 1.527(12) .
C91 C94 1.538(12) .
C92 H92A 0.9800 .
C92 H92B 0.9800 .
C92 H92C 0.9800 .
C93 H93A 0.9800 .
C93 H93B 0.9800 .
C93 H93C 0.9800 .
C94 H94A 0.9800 .
C94 H94B 0.9800 .
C94 H94C 0.9800 .
Zn1 Cl4 2.198(3) .
Zn1 Cl3 2.214(2) .
Zn1 Cl5 2.333(2) 2_665
Zn1 Cl5 2.352(2) .
Cl5 Zn1 2.333(2) 2_665
Zn2 Cl7 2.196(3) .
Zn2 Cl6 2.211(3) .
Zn2 Cl8 2.333(3) .
Zn2 Cl8 2.374(3) 2_675
Cl8 Zn2 2.373(3) 2_675
N9 C17 1.146(12) .
C17 C18 1.461(14) .
C18 H18A 0.9800 .
C18 H18B 0.9800 .
C18 H18C 0.9800 .
N10 C19 1.185(19) .
C19 C20 1.413(19) .
C20 H20A 0.9800 .
C20 H20B 0.9800 .
C20 H20C 0.9800 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
N2 Ru1 Cl1 Ru2 141.6(2) . .
N1 Ru1 Cl1 Ru2 -137.7(2) . .
C23 Ru1 Cl1 Ru2 49.7(3) . .
C25 Ru1 Cl1 Ru2 -39.6(3) . .
C22 Ru1 Cl1 Ru2 24.5(2) . .
C24 Ru1 Cl1 Ru2 8.6(8) . .
C21 Ru1 Cl1 Ru2 -15.3(2) . .
N3 Ru2 Cl1 Ru1 126.6(2) . .
N4 Ru2 Cl1 Ru1 -149.5(2) . .
C30 Ru2 Cl1 Ru1 37.7(3) . .
C26 Ru2 Cl1 Ru1 14.1(2) . .
C29 Ru2 Cl1 Ru1 -22.8(8) . .
C28 Ru2 Cl1 Ru1 -53.1(3) . .
C27 Ru2 Cl1 Ru1 -25.4(2) . .
N2 Ru1 N1 C1 19(4) . .
C23 Ru1 N1 C1 104(4) . .
C25 Ru1 N1 C1 163(4) . .
C22 Ru1 N1 C1 -160(3) . .
C24 Ru1 N1 C1 124(4) . .
C21 Ru1 N1 C1 -162(3) . .
Cl1 Ru1 N1 C1 -66(4) . .
N1 Ru1 N2 C3 1(5) . .
C23 Ru1 N2 C3 -145(5) . .
C25 Ru1 N2 C3 -93(6) . .
C22 Ru1 N2 C3 -179(100) . .
C24 Ru1 N2 C3 -107(6) . .
C21 Ru1 N2 C3 -178(5) . .
Cl1 Ru1 N2 C3 85(6) . .
N4 Ru2 N3 C5 -27(8) . .
C30 Ru2 N3 C5 -168(8) . .
C26 Ru2 N3 C5 156(8) . .
C29 Ru2 N3 C5 -131(8) . .
C28 Ru2 N3 C5 -123(8) . .
C27 Ru2 N3 C5 151(8) . .
Cl1 Ru2 N3 C5 58(8) . .
N3 Ru2 N4 C7 -8(8) . .
C30 Ru2 N4 C7 80(8) . .
C26 Ru2 N4 C7 163(8) . .
C29 Ru2 N4 C7 102(8) . .
C28 Ru2 N4 C7 141(8) . .
C27 Ru2 N4 C7 174(8) . .
Cl1 Ru2 N4 C7 -91(8) . .
Ru1 N1 C1 C2 -50(29) . .
Ru1 N2 C3 C4 20(52) . .
Ru2 N3 C5 C6 -31(52) . .
Ru2 N4 C7 C8 -38(26) . .
N2 Ru1 C21 C25 115.3(7) . .
N1 Ru1 C21 C25 -63.3(5) . .
C23 Ru1 C21 C25 79.5(5) . .
C22 Ru1 C21 C25 117.4(6) . .
C24 Ru1 C21 C25 36.2(4) . .
Cl1 Ru1 C21 C25 -150.8(4) . .
N2 Ru1 C21 C22 -2.1(9) . .
N1 Ru1 C21 C22 179.3(4) . .
C23 Ru1 C21 C22 -37.9(4) . .
C25 Ru1 C21 C22 -117.4(6) . .
C24 Ru1 C21 C22 -81.2(4) . .
Cl1 Ru1 C21 C22 91.8(4) . .
N2 Ru1 C21 C31 -122.3(8) . .
N1 Ru1 C21 C31 59.1(7) . .
C23 Ru1 C21 C31 -158.1(7) . .
C25 Ru1 C21 C31 122.4(9) . .
C22 Ru1 C21 C31 -120.2(8) . .
C24 Ru1 C21 C31 158.6(7) . .
Cl1 Ru1 C21 C31 -28.4(7) . .
C25 C21 C22 C23 0.3(9) . .
C31 C21 C22 C23 -174.0(7) . .
Ru1 C21 C22 C23 60.6(5) . .
C25 C21 C22 C34 175.0(7) . .
C31 C21 C22 C34 0.6(12) . .
Ru1 C21 C22 C34 -124.8(7) . .
C25 C21 C22 Ru1 -60.3(5) . .
C31 C21 C22 Ru1 125.3(8) . .
N2 Ru1 C22 C23 61.8(5) . .
N1 Ru1 C22 C23 -119.2(9) . .
C25 Ru1 C22 C23 -79.3(5) . .
C24 Ru1 C22 C23 -36.2(4) . .
C21 Ru1 C22 C23 -117.2(6) . .
Cl1 Ru1 C22 C23 148.5(4) . .
N2 Ru1 C22 C21 179.1(4) . .
N1 Ru1 C22 C21 -2.0(11) . .
C23 Ru1 C22 C21 117.2(6) . .
C25 Ru1 C22 C21 37.9(4) . .
C24 Ru1 C22 C21 81.0(4) . .
Cl1 Ru1 C22 C21 -94.3(4) . .
N2 Ru1 C22 C34 -61.5(7) . .
N1 Ru1 C22 C34 117.4(9) . .
C23 Ru1 C22 C34 -123.4(9) . .
C25 Ru1 C22 C34 157.3(8) . .
C24 Ru1 C22 C34 -159.6(8) . .
C21 Ru1 C22 C34 119.4(8) . .
Cl1 Ru1 C22 C34 25.1(7) . .
C21 C22 C23 C24 -0.8(9) . .
C34 C22 C23 C24 -175.1(7) . .
Ru1 C22 C23 C24 60.8(6) . .
C21 C22 C23 Ru1 -61.6(5) . .
C34 C22 C23 Ru1 124.1(8) . .
N2 Ru1 C23 C22 -128.3(4) . .
N1 Ru1 C23 C22 151.2(5) . .
C25 Ru1 C23 C22 81.7(5) . .
C24 Ru1 C23 C22 121.2(6) . .
C21 Ru1 C23 C22 38.4(4) . .
Cl1 Ru1 C23 C22 -42.3(5) . .
N2 Ru1 C23 C24 110.5(4) . .
N1 Ru1 C23 C24 30.0(7) . .
C25 Ru1 C23 C24 -39.5(4) . .
C22 Ru1 C23 C24 -121.2(6) . .
C21 Ru1 C23 C24 -82.7(4) . .
Cl1 Ru1 C23 C24 -163.5(3) . .
C22 C23 C24 C25 0.8(9) . .
Ru1 C23 C24 C25 61.6(5) . .
C22 C23 C24 C37 172.4(8) . .
Ru1 C23 C24 C37 -126.8(8) . .
C22 C23 C24 Ru1 -60.8(6) . .
N2 Ru1 C24 C23 -77.5(5) . .
N1 Ru1 C24 C23 -162.9(4) . .
C25 Ru1 C24 C23 114.8(6) . .
C22 Ru1 C24 C23 35.8(4) . .
C21 Ru1 C24 C23 78.8(5) . .
Cl1 Ru1 C24 C23 52.9(10) . .
N2 Ru1 C24 C25 167.7(4) . .
N1 Ru1 C24 C25 82.2(5) . .
C23 Ru1 C24 C25 -114.8(6) . .
C22 Ru1 C24 C25 -79.0(4) . .
C21 Ru1 C24 C25 -36.0(4) . .
Cl1 Ru1 C24 C25 -61.9(9) . .
N2 Ru1 C24 C37 45.3(8) . .
N1 Ru1 C24 C37 -40.1(8) . .
C23 Ru1 C24 C37 122.8(9) . .
C25 Ru1 C24 C37 -122.3(9) . .
C22 Ru1 C24 C37 158.6(8) . .
C21 Ru1 C24 C37 -158.3(8) . .
Cl1 Ru1 C24 C37 175.8(5) . .
C22 C21 C25 C24 0.2(9) . .
C31 C21 C25 C24 174.4(7) . .
Ru1 C21 C25 C24 -60.0(5) . .
C22 C21 C25 Ru1 60.2(5) . .
C31 C21 C25 Ru1 -125.5(8) . .
C23 C24 C25 C21 -0.6(9) . .
C37 C24 C25 C21 -172.3(8) . .
Ru1 C24 C25 C21 60.3(5) . .
C23 C24 C25 Ru1 -60.9(5) . .
C37 C24 C25 Ru1 127.4(8) . .
N2 Ru1 C25 C21 -141.9(5) . .
N1 Ru1 C25 C21 130.3(5) . .
C23 Ru1 C25 C21 -81.4(5) . .
C22 Ru1 C25 C21 -38.3(4) . .
C24 Ru1 C25 C21 -121.0(6) . .
Cl1 Ru1 C25 C21 40.1(6) . .
N2 Ru1 C25 C24 -20.9(7) . .
N1 Ru1 C25 C24 -108.8(4) . .
C23 Ru1 C25 C24 39.6(4) . .
C22 Ru1 C25 C24 82.7(5) . .
C21 Ru1 C25 C24 121.0(6) . .
Cl1 Ru1 C25 C24 161.1(3) . .
N3 Ru2 C26 C30 66.3(5) . .
N4 Ru2 C26 C30 -103.8(9) . .
C29 Ru2 C26 C30 -37.2(5) . .
C28 Ru2 C26 C30 -80.0(5) . .
C27 Ru2 C26 C30 -118.0(6) . .
Cl1 Ru2 C26 C30 153.2(4) . .
N3 Ru2 C26 C27 -175.7(4) . .
N4 Ru2 C26 C27 14.2(11) . .
C30 Ru2 C26 C27 118.0(6) . .
C29 Ru2 C26 C27 80.8(5) . .
C28 Ru2 C26 C27 38.0(4) . .
Cl1 Ru2 C26 C27 -88.8(4) . .
N3 Ru2 C26 C31 -56.7(7) . .
N4 Ru2 C26 C31 133.2(9) . .
C30 Ru2 C26 C31 -123.0(9) . .
C29 Ru2 C26 C31 -160.2(7) . .
C28 Ru2 C26 C31 157.0(7) . .
C27 Ru2 C26 C31 119.0(8) . .
Cl1 Ru2 C26 C31 30.2(6) . .
C30 C26 C27 C28 0.6(8) . .
C31 C26 C27 C28 177.5(7) . .
Ru2 C26 C27 C28 -60.2(5) . .
C30 C26 C27 C34 -174.7(7) . .
C31 C26 C27 C34 2.2(12) . .
Ru2 C26 C27 C34 124.5(7) . .
C30 C26 C27 Ru2 60.8(5) . .
C31 C26 C27 Ru2 -122.3(7) . .
N3 Ru2 C27 C26 8.5(8) . .
N4 Ru2 C27 C26 -175.1(4) . .
C30 Ru2 C27 C26 -37.9(4) . .
C29 Ru2 C27 C26 -81.5(4) . .
C28 Ru2 C27 C26 -117.8(6) . .
Cl1 Ru2 C27 C26 97.7(4) . .
N3 Ru2 C27 C28 126.2(6) . .
N4 Ru2 C27 C28 -57.3(5) . .
C30 Ru2 C27 C28 79.8(5) . .
C26 Ru2 C27 C28 117.8(6) . .
C29 Ru2 C27 C28 36.3(4) . .
Cl1 Ru2 C27 C28 -144.5(4) . .
N3 Ru2 C27 C34 -110.7(7) . .
N4 Ru2 C27 C34 65.8(7) . .
C30 Ru2 C27 C34 -157.1(7) . .
C26 Ru2 C27 C34 -119.1(8) . .
C29 Ru2 C27 C34 159.4(7) . .
C28 Ru2 C27 C34 123.1(8) . .
Cl1 Ru2 C27 C34 -21.4(6) . .
C26 C27 C28 C29 0.1(9) . .
C34 C27 C28 C29 175.2(7) . .
Ru2 C27 C28 C29 -59.9(5) . .
C26 C27 C28 Ru2 60.0(5) . .
C34 C27 C28 Ru2 -124.9(8) . .
N3 Ru2 C28 C29 -12.2(8) . .
N4 Ru2 C28 C29 -104.2(5) . .
C30 Ru2 C28 C29 39.1(4) . .
C26 Ru2 C28 C29 82.6(5) . .
C27 Ru2 C28 C29 120.4(6) . .
Cl1 Ru2 C28 C29 167.1(4) . .
N3 Ru2 C28 C27 -132.7(5) . .
N4 Ru2 C28 C27 135.4(4) . .
C30 Ru2 C28 C27 -81.4(5) . .
C26 Ru2 C28 C27 -37.8(4) . .
C29 Ru2 C28 C27 -120.4(6) . .
Cl1 Ru2 C28 C27 46.7(5) . .
C27 C28 C29 C30 -0.8(9) . .
Ru2 C28 C29 C30 -61.0(5) . .
C27 C28 C29 C41 -174.4(8) . .
Ru2 C28 C29 C41 125.4(9) . .
C27 C28 C29 Ru2 60.2(5) . .
N3 Ru2 C29 C28 173.3(4) . .
N4 Ru2 C29 C28 84.7(5) . .
C30 Ru2 C29 C28 -116.3(6) . .
C26 Ru2 C29 C28 -79.3(5) . .
C27 Ru2 C29 C28 -36.5(4) . .
Cl1 Ru2 C29 C28 -39.4(10) . .
N3 Ru2 C29 C30 -70.4(5) . .
N4 Ru2 C29 C30 -159.0(4) . .
C26 Ru2 C29 C30 37.0(5) . .
C28 Ru2 C29 C30 116.3(6) . .
C27 Ru2 C29 C30 79.8(5) . .
Cl1 Ru2 C29 C30 76.9(10) . .
N3 Ru2 C29 C41 49.9(8) . .
N4 Ru2 C29 C41 -38.7(8) . .
C30 Ru2 C29 C41 120.3(9) . .
C26 Ru2 C29 C41 157.2(8) . .
C28 Ru2 C29 C41 -123.4(9) . .
C27 Ru2 C29 C41 -160.0(8) . .
Cl1 Ru2 C29 C41 -162.9(6) . .
C27 C26 C30 C29 -1.2(9) . .
C31 C26 C30 C29 -177.9(7) . .
Ru2 C26 C30 C29 60.5(6) . .
C27 C26 C30 Ru2 -61.6(5) . .
C31 C26 C30 Ru2 121.6(8) . .
C28 C29 C30 C26 1.2(9) . .
C41 C29 C30 C26 175.0(8) . .
Ru2 C29 C30 C26 -60.4(6) . .
C28 C29 C30 Ru2 61.6(5) . .
C41 C29 C30 Ru2 -124.6(8) . .
N3 Ru2 C30 C26 -122.6(5) . .
N4 Ru2 C30 C26 153.2(5) . .
C29 Ru2 C30 C26 119.5(7) . .
C28 Ru2 C30 C26 81.0(5) . .
C27 Ru2 C30 C26 37.7(4) . .
Cl1 Ru2 C30 C26 -38.3(6) . .
N3 Ru2 C30 C29 118.0(5) . .
N4 Ru2 C30 C29 33.8(7) . .
C26 Ru2 C30 C29 -119.5(7) . .
C28 Ru2 C30 C29 -38.4(5) . .
C27 Ru2 C30 C29 -81.8(5) . .
Cl1 Ru2 C30 C29 -157.8(4) . .
C25 C21 C31 C32 46.0(11) . .
C22 C21 C31 C32 -140.8(8) . .
Ru1 C21 C31 C32 -48.2(9) . .
C25 C21 C31 C26 169.8(7) . .
C22 C21 C31 C26 -17.0(11) . .
Ru1 C21 C31 C26 75.6(8) . .
C25 C21 C31 C33 -75.3(10) . .
C22 C21 C31 C33 98.0(9) . .
Ru1 C21 C31 C33 -169.4(5) . .
C30 C26 C31 C21 -168.2(8) . .
C27 C26 C31 C21 15.5(10) . .
Ru2 C26 C31 C21 -75.8(8) . .
C30 C26 C31 C32 -43.3(11) . .
C27 C26 C31 C32 140.4(7) . .
Ru2 C26 C31 C32 49.1(8) . .
C30 C26 C31 C33 74.7(10) . .
C27 C26 C31 C33 -101.5(8) . .
Ru2 C26 C31 C33 167.1(5) . .
C23 C22 C34 C27 -169.5(8) . .
C21 C22 C34 C27 17.0(10) . .
Ru1 C22 C34 C27 -75.7(8) . .
C23 C22 C34 C35 -46.0(11) . .
C21 C22 C34 C35 140.6(8) . .
Ru1 C22 C34 C35 47.8(9) . .
C23 C22 C34 C36 74.8(10) . .
C21 C22 C34 C36 -98.6(9) . .
Ru1 C22 C34 C36 168.7(5) . .
C26 C27 C34 C22 -18.3(10) . .
C28 C27 C34 C22 167.4(7) . .
Ru2 C27 C34 C22 73.1(8) . .
C26 C27 C34 C35 -142.0(7) . .
C28 C27 C34 C35 43.7(10) . .
Ru2 C27 C34 C35 -50.6(8) . .
C26 C27 C34 C36 97.6(8) . .
C28 C27 C34 C36 -76.7(9) . .
Ru2 C27 C34 C36 -171.0(5) . .
C23 C24 C37 C38 159.8(9) . .
C25 C24 C37 C38 -30.4(12) . .
Ru1 C24 C37 C38 65.0(10) . .
C23 C24 C37 C39 36.2(12) . .
C25 C24 C37 C39 -154.1(8) . .
Ru1 C24 C37 C39 -58.7(10) . .
C23 C24 C37 C40 -82.4(10) . .
C25 C24 C37 C40 87.3(10) . .
Ru1 C24 C37 C40 -177.3(7) . .
C28 C29 C41 C42 -150.0(9) . .
C30 C29 C41 C42 37.6(12) . .
Ru2 C29 C41 C42 -54.7(11) . .
C28 C29 C41 C43 -30.1(12) . .
C30 C29 C41 C43 157.4(8) . .
Ru2 C29 C41 C43 65.2(10) . .
C28 C29 C41 C44 88.6(11) . .
C30 C29 C41 C44 -83.8(11) . .
Ru2 C29 C41 C44 -176.0(7) . .
N7 Ru4 Cl2 Ru3 126.9(2) . .
N8 Ru4 Cl2 Ru3 -149.4(2) . .
C80 Ru4 Cl2 Ru3 35.6(3) . .
C78 Ru4 Cl2 Ru3 -54.9(3) . .
C79 Ru4 Cl2 Ru3 -22.0(8) . .
C76 Ru4 Cl2 Ru3 12.3(2) . .
C77 Ru4 Cl2 Ru3 -27.8(2) . .
N5 Ru3 Cl2 Ru4 -120.5(2) . .
N6 Ru3 Cl2 Ru4 150.5(2) . .
C75 Ru3 Cl2 Ru4 -33.8(3) . .
C73 Ru3 Cl2 Ru4 56.7(3) . .
C74 Ru3 Cl2 Ru4 28.9(7) . .
C71 Ru3 Cl2 Ru4 -11.8(2) . .
C72 Ru3 Cl2 Ru4 28.5(2) . .
N6 Ru3 N5 C9 -146(5) . .
C75 Ru3 N5 C9 -8(5) . .
C73 Ru3 N5 C9 -49(5) . .
C74 Ru3 N5 C9 -44(5) . .
C71 Ru3 N5 C9 27(5) . .
C72 Ru3 N5 C9 31(5) . .
Cl2 Ru3 N5 C9 127(5) . .
N5 Ru3 N6 C11 130(4) . .
C75 Ru3 N6 C11 40(4) . .
C73 Ru3 N6 C11 -18(4) . .
C74 Ru3 N6 C11 21(4) . .
C71 Ru3 N6 C11 -31(5) . .
C72 Ru3 N6 C11 -48(4) . .
Cl2 Ru3 N6 C11 -145(4) . .
N8 Ru4 N7 C13 5(6) . .
C80 Ru4 N7 C13 -136(6) . .
C78 Ru4 N7 C13 -86(6) . .
C79 Ru4 N7 C13 -98(6) . .
C76 Ru4 N7 C13 -171(6) . .
C77 Ru4 N7 C13 -175(6) . .
Cl2 Ru4 N7 C13 91(6) . .
N7 Ru4 N8 C15 -70(4) . .
C80 Ru4 N8 C15 21(4) . .
C78 Ru4 N8 C15 79(4) . .
C79 Ru4 N8 C15 40(4) . .
C76 Ru4 N8 C15 97(4) . .
C77 Ru4 N8 C15 110(4) . .
Cl2 Ru4 N8 C15 -154(4) . .
Ru3 N5 C9 C10 15(89) . .
Ru3 N6 C11 C12 -14(17) . .
Ru4 N7 C13 C14 -162(29) . .
Ru4 N8 C15 C16 11(46) . .
N5 Ru3 C71 C75 -66.8(5) . .
N6 Ru3 C71 C75 92.8(9) . .
C73 Ru3 C71 C75 79.1(5) . .
C74 Ru3 C71 C75 36.2(5) . .
C72 Ru3 C71 C75 115.8(7) . .
Cl2 Ru3 C71 C75 -155.5(4) . .
N5 Ru3 C71 C72 177.4(4) . .
N6 Ru3 C71 C72 -23.1(10) . .
C75 Ru3 C71 C72 -115.8(7) . .
C73 Ru3 C71 C72 -36.8(4) . .
C74 Ru3 C71 C72 -79.7(4) . .
Cl2 Ru3 C71 C72 88.7(4) . .
N5 Ru3 C71 C81 57.1(7) . .
N6 Ru3 C71 C81 -143.4(8) . .
C75 Ru3 C71 C81 123.9(9) . .
C73 Ru3 C71 C81 -157.1(7) . .
C74 Ru3 C71 C81 160.0(7) . .
C72 Ru3 C71 C81 -120.3(8) . .
Cl2 Ru3 C71 C81 -31.6(7) . .
C75 C71 C72 C73 -0.6(9) . .
C81 C71 C72 C73 -176.7(7) . .
Ru3 C71 C72 C73 59.8(5) . .
C75 C71 C72 C84 174.1(7) . .
C81 C71 C72 C84 -1.9(13) . .
Ru3 C71 C72 C84 -125.4(7) . .
C75 C71 C72 Ru3 -60.4(5) . .
C81 C71 C72 Ru3 123.5(8) . .
N5 Ru3 C72 C73 -124.1(6) . .
N6 Ru3 C72 C73 52.1(5) . .
C75 Ru3 C72 C73 -80.3(5) . .
C74 Ru3 C72 C73 -37.0(4) . .
C71 Ru3 C72 C73 -119.2(6) . .
Cl2 Ru3 C72 C73 142.9(4) . .
N5 Ru3 C72 C71 -4.9(7) . .
N6 Ru3 C72 C71 171.3(4) . .
C75 Ru3 C72 C71 38.9(4) . .
C73 Ru3 C72 C71 119.2(6) . .
C74 Ru3 C72 C71 82.2(4) . .
Cl2 Ru3 C72 C71 -97.9(4) . .
N5 Ru3 C72 C84 113.0(7) . .
N6 Ru3 C72 C84 -70.8(7) . .
C75 Ru3 C72 C84 156.8(8) . .
C73 Ru3 C72 C84 -123.0(9) . .
C74 Ru3 C72 C84 -159.9(8) . .
C71 Ru3 C72 C84 117.8(8) . .
Cl2 Ru3 C72 C84 19.9(7) . .
C71 C72 C73 C74 0.7(9) . .
C84 C72 C73 C74 -173.8(7) . .
Ru3 C72 C73 C74 60.3(6) . .
C71 C72 C73 Ru3 -59.6(5) . .
C84 C72 C73 Ru3 125.9(8) . .
N5 Ru3 C73 C72 126.5(5) . .
N6 Ru3 C73 C72 -137.9(4) . .
C75 Ru3 C73 C72 81.1(5) . .
C74 Ru3 C73 C72 119.7(6) . .
C71 Ru3 C73 C72 37.7(4) . .
Cl2 Ru3 C73 C72 -48.2(5) . .
N5 Ru3 C73 C74 6.9(8) . .
N6 Ru3 C73 C74 102.4(4) . .
C75 Ru3 C73 C74 -38.6(4) . .
C71 Ru3 C73 C74 -82.0(5) . .
C72 Ru3 C73 C74 -119.7(6) . .
Cl2 Ru3 C73 C74 -167.9(3) . .
C72 C73 C74 C75 -0.4(9) . .
Ru3 C73 C74 C75 60.1(5) . .
C72 C73 C74 C87 172.4(8) . .
Ru3 C73 C74 C87 -127.1(8) . .
C72 C73 C74 Ru3 -60.5(5) . .
N5 Ru3 C74 C75 67.2(5) . .
N6 Ru3 C74 C75 159.9(4) . .
C73 Ru3 C74 C75 -116.6(6) . .
C71 Ru3 C74 C75 -36.3(4) . .
C72 Ru3 C74 C75 -79.9(5) . .
Cl2 Ru3 C74 C75 -80.4(8) . .
N5 Ru3 C74 C73 -176.2(4) . .
N6 Ru3 C74 C73 -83.5(5) . .
C75 Ru3 C74 C73 116.6(6) . .
C71 Ru3 C74 C73 80.3(5) . .
C72 Ru3 C74 C73 36.7(4) . .
Cl2 Ru3 C74 C73 36.3(10) . .
N5 Ru3 C74 C87 -53.7(8) . .
N6 Ru3 C74 C87 39.0(8) . .
C75 Ru3 C74 C87 -120.9(9) . .
C73 Ru3 C74 C87 122.5(9) . .
C71 Ru3 C74 C87 -157.2(8) . .
C72 Ru3 C74 C87 159.2(8) . .
Cl2 Ru3 C74 C87 158.7(5) . .
C73 C74 C75 C71 0.0(9) . .
C87 C74 C75 C71 -172.8(8) . .
Ru3 C74 C75 C71 61.0(6) . .
C73 C74 C75 Ru3 -61.0(5) . .
C87 C74 C75 Ru3 126.2(8) . .
C72 C71 C75 C74 0.4(9) . .
C81 C71 C75 C74 176.2(8) . .
Ru3 C71 C75 C74 -61.0(6) . .
C72 C71 C75 Ru3 61.4(5) . .
C81 C71 C75 Ru3 -122.7(9) . .
N5 Ru3 C75 C74 -119.3(4) . .
N6 Ru3 C75 C74 -30.1(6) . .
C73 Ru3 C75 C74 38.5(4) . .
C71 Ru3 C75 C74 120.9(7) . .
C72 Ru3 C75 C74 81.6(5) . .
Cl2 Ru3 C75 C74 156.4(3) . .
N5 Ru3 C75 C71 119.8(5) . .
N6 Ru3 C75 C71 -151.0(5) . .
C73 Ru3 C75 C71 -82.4(5) . .
C74 Ru3 C75 C71 -120.9(7) . .
C72 Ru3 C75 C71 -39.4(5) . .
Cl2 Ru3 C75 C71 35.5(6) . .
N7 Ru4 C76 C80 65.3(5) . .
N8 Ru4 C76 C80 -100.4(9) . .
C78 Ru4 C76 C80 -80.1(5) . .
C79 Ru4 C76 C80 -36.7(5) . .
C77 Ru4 C76 C80 -117.6(6) . .
Cl2 Ru4 C76 C80 153.1(4) . .
N7 Ru4 C76 C77 -177.1(4) . .
N8 Ru4 C76 C77 17.2(10) . .
C80 Ru4 C76 C77 117.6(6) . .
C78 Ru4 C76 C77 37.5(4) . .
C79 Ru4 C76 C77 80.8(4) . .
Cl2 Ru4 C76 C77 -89.3(4) . .
N7 Ru4 C76 C81 -58.1(7) . .
N8 Ru4 C76 C81 136.2(8) . .
C80 Ru4 C76 C81 -123.4(9) . .
C78 Ru4 C76 C81 156.5(8) . .
C79 Ru4 C76 C81 -160.2(8) . .
C77 Ru4 C76 C81 119.0(8) . .
Cl2 Ru4 C76 C81 29.7(7) . .
C80 C76 C77 C78 -1.1(9) . .
C81 C76 C77 C78 175.2(7) . .
Ru4 C76 C77 C78 -60.7(5) . .
C80 C76 C77 C84 -175.6(7) . .
C81 C76 C77 C84 0.7(12) . .
Ru4 C76 C77 C84 124.8(7) . .
C80 C76 C77 Ru4 59.6(5) . .
C81 C76 C77 Ru4 -124.1(7) . .
N7 Ru4 C77 C78 124.1(6) . .
N8 Ru4 C77 C78 -55.6(5) . .
C80 Ru4 C77 C78 80.1(5) . .
C79 Ru4 C77 C78 36.8(4) . .
C76 Ru4 C77 C78 117.9(6) . .
Cl2 Ru4 C77 C78 -144.9(4) . .
N7 Ru4 C77 C76 6.2(8) . .
N8 Ru4 C77 C76 -173.5(4) . .
C80 Ru4 C77 C76 -37.8(4) . .
C78 Ru4 C77 C76 -117.9(6) . .
C79 Ru4 C77 C76 -81.1(4) . .
Cl2 Ru4 C77 C76 97.2(4) . .
N7 Ru4 C77 C84 -112.8(7) . .
N8 Ru4 C77 C84 67.5(7) . .
C80 Ru4 C77 C84 -156.8(7) . .
C78 Ru4 C77 C84 123.1(8) . .
C79 Ru4 C77 C84 159.9(7) . .
C76 Ru4 C77 C84 -119.0(8) . .
Cl2 Ru4 C77 C84 -21.8(6) . .
C76 C77 C78 C79 0.8(9) . .
C84 C77 C78 C79 175.1(7) . .
Ru4 C77 C78 C79 -59.8(6) . .
C76 C77 C78 Ru4 60.6(5) . .
C84 C77 C78 Ru4 -125.1(8) . .
N7 Ru4 C78 C77 -137.5(5) . .
N8 Ru4 C78 C77 135.2(5) . .
C80 Ru4 C78 C77 -81.4(5) . .
C79 Ru4 C78 C77 -120.2(6) . .
C76 Ru4 C78 C77 -38.3(4) . .
Cl2 Ru4 C78 C77 46.0(5) . .
N7 Ru4 C78 C79 -17.3(7) . .
N8 Ru4 C78 C79 -104.6(4) . .
C80 Ru4 C78 C79 38.8(4) . .
C76 Ru4 C78 C79 81.9(5) . .
C77 Ru4 C78 C79 120.2(6) . .
Cl2 Ru4 C78 C79 166.3(3) . .
C77 C78 C79 C80 -0.2(9) . .
Ru4 C78 C79 C80 -60.3(6) . .
C77 C78 C79 C91 -174.2(8) . .
Ru4 C78 C79 C91 125.7(9) . .
C77 C78 C79 Ru4 60.1(6) . .
N7 Ru4 C79 C80 -73.3(5) . .
N8 Ru4 C79 C80 -161.1(5) . .
C78 Ru4 C79 C80 116.2(6) . .
C76 Ru4 C79 C80 36.4(5) . .
C77 Ru4 C79 C80 79.9(5) . .
Cl2 Ru4 C79 C80 73.7(9) . .
N7 Ru4 C79 C78 170.5(4) . .
N8 Ru4 C79 C78 82.7(5) . .
C80 Ru4 C79 C78 -116.2(6) . .
C76 Ru4 C79 C78 -79.8(5) . .
C77 Ru4 C79 C78 -36.3(4) . .
Cl2 Ru4 C79 C78 -42.5(10) . .
N7 Ru4 C79 C91 48.1(7) . .
N8 Ru4 C79 C91 -39.8(7) . .
C80 Ru4 C79 C91 121.4(9) . .
C78 Ru4 C79 C91 -122.5(9) . .
C76 Ru4 C79 C91 157.8(8) . .
C77 Ru4 C79 C91 -158.7(8) . .
Cl2 Ru4 C79 C91 -165.0(5) . .
C77 C76 C80 C79 1.0(9) . .
C81 C76 C80 C79 -175.1(8) . .
Ru4 C76 C80 C79 61.4(6) . .
C77 C76 C80 Ru4 -60.4(5) . .
C81 C76 C80 Ru4 123.5(8) . .
C78 C79 C80 C76 -0.5(9) . .
C91 C79 C80 C76 173.5(8) . .
Ru4 C79 C80 C76 -61.7(6) . .
C78 C79 C80 Ru4 61.2(5) . .
C91 C79 C80 Ru4 -124.8(9) . .
N7 Ru4 C80 C76 -124.4(4) . .
N8 Ru4 C80 C76 149.7(5) . .
C78 Ru4 C80 C76 81.3(5) . .
C79 Ru4 C80 C76 120.2(7) . .
C77 Ru4 C80 C76 38.4(4) . .
Cl2 Ru4 C80 C76 -38.1(6) . .
N7 Ru4 C80 C79 115.4(5) . .
N8 Ru4 C80 C79 29.5(7) . .
C78 Ru4 C80 C79 -38.9(4) . .
C76 Ru4 C80 C79 -120.2(7) . .
C77 Ru4 C80 C79 -81.8(5) . .
Cl2 Ru4 C80 C79 -158.3(4) . .
C75 C71 C81 C76 168.8(8) . .
C72 C71 C81 C76 -16.1(11) . .
Ru3 C71 C81 C76 76.0(8) . .
C75 C71 C81 C82 46.4(11) . .
C72 C71 C81 C82 -138.6(8) . .
Ru3 C71 C81 C82 -46.5(9) . .
C75 C71 C81 C83 -72.9(11) . .
C72 C71 C81 C83 102.1(9) . .
Ru3 C71 C81 C83 -165.8(5) . .
C80 C76 C81 C71 -167.9(8) . .
C77 C76 C81 C71 16.6(11) . .
Ru4 C76 C81 C71 -74.9(9) . .
C80 C76 C81 C82 -45.3(11) . .
C77 C76 C81 C82 139.3(8) . .
Ru4 C76 C81 C82 47.8(9) . .
C80 C76 C81 C83 74.4(10) . .
C77 C76 C81 C83 -101.1(9) . .
Ru4 C76 C81 C83 167.4(6) . .
C78 C77 C84 C86 -75.0(10) . .
C76 C77 C84 C86 98.4(8) . .
Ru4 C77 C84 C86 -169.8(5) . .
C78 C77 C84 C72 168.3(7) . .
C76 C77 C84 C72 -18.3(10) . .
Ru4 C77 C84 C72 73.6(8) . .
C78 C77 C84 C85 46.5(11) . .
C76 C77 C84 C85 -140.2(7) . .
Ru4 C77 C84 C85 -48.3(8) . .
C73 C72 C84 C77 -167.5(7) . .
C71 C72 C84 C77 18.8(10) . .
Ru3 C72 C84 C77 -72.4(8) . .
C73 C72 C84 C86 75.2(10) . .
C71 C72 C84 C86 -98.5(9) . .
Ru3 C72 C84 C86 170.3(6) . .
C73 C72 C84 C85 -45.9(11) . .
C71 C72 C84 C85 140.4(8) . .
Ru3 C72 C84 C85 49.2(9) . .
C75 C74 C87 C88 -45.8(12) . .
C73 C74 C87 C88 142.8(9) . .
Ru3 C74 C87 C88 47.3(10) . .
C75 C74 C87 C89 -166.1(8) . .
C73 C74 C87 C89 22.5(12) . .
Ru3 C74 C87 C89 -73.0(10) . .
C75 C74 C87 C90 74.2(11) . .
C73 C74 C87 C90 -97.2(10) . .
Ru3 C74 C87 C90 167.3(6) . .
C80 C79 C91 C92 36.1(12) . .
C78 C79 C91 C92 -151.2(9) . .
Ru4 C79 C91 C92 -56.5(10) . .
C80 C79 C91 C93 157.6(9) . .
C78 C79 C91 C93 -29.7(12) . .
Ru4 C79 C91 C93 65.0(9) . .
C80 C79 C91 C94 -82.6(11) . .
C78 C79 C91 C94 90.1(10) . .
Ru4 C79 C91 C94 -175.2(6) . .
Cl4 Zn1 Cl5 Zn1 -114.80(11) . 2_665
Cl3 Zn1 Cl5 Zn1 117.15(10) . 2_665
Cl5 Zn1 Cl5 Zn1 0.0 2_665 2_665
Cl7 Zn2 Cl8 Zn2 112.84(14) . 2_675
Cl6 Zn2 Cl8 Zn2 -110.94(13) . 2_675
Cl8 Zn2 Cl8 Zn2 0.0 2_675 2_675
