#------------------------------------------------------------------------------
#$Date: 2016-03-21 06:22:36 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178506 $
#$URL: svn://www.crystallography.net/cod/cif/4/06/80/4068048.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4068048
loop_
_publ_author_name
'Khlebnikov, Vsevolod'
'Meduri, Angelo'
'Mueller-Bunz, Helge'
'Montini, Tiziano'
'Fornasiero, Paolo'
'Zangrando, Ennio'
'Milani, Barbara'
'Albrecht, Martin'
_publ_section_title
;
 Palladium Carbene Complexes for Selective Alkene Di- and Oligomerization
;
_journal_issue                   3
_journal_name_full               Organometallics
_journal_page_first              976
_journal_paper_doi               10.1021/om201027y
_journal_volume                  31
_journal_year                    2012
_chemical_formula_moiety         'C28 H31 N4 Pd, F6 P'
_chemical_formula_sum            'C28 H31 F6 N4 P Pd'
_chemical_formula_weight         674.94
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 99.506(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   13.2126(3)
_cell_length_b                   11.4202(3)
_cell_length_c                   19.3576(5)
_cell_measurement_reflns_used    28646
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      29.5292
_cell_measurement_theta_min      3.3158
_cell_volume                     2880.77(13)
_computing_cell_refinement
; 
CrysAlisPro, Oxford Diffraction Ltd., 
Version 1.171.34.36 (release 02-08-2010 CrysAlis171 .NET) 
(compiled Aug  2 2010,13:00:58) 
;
_computing_data_collection
; 
CrysAlisPro, Oxford Diffraction Ltd., 
Version 1.171.34.36 (release 02-08-2010 CrysAlis171 .NET) 
(compiled Aug  2 2010,13:00:58) 
;
_computing_data_reduction
; 
CrysAlisPro, Oxford Diffraction Ltd., 
Version 1.171.34.36 (release 02-08-2010 CrysAlis171 .NET) 
(compiled Aug  2 2010,13:00:58) 
;
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      100(2)
_diffrn_detector_area_resol_mean 10.3196
_diffrn_measured_fraction_theta_full 0.990
_diffrn_measured_fraction_theta_max 0.926
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, Atlas'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_source         'SuperNova (Mo) X-ray Source'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0288
_diffrn_reflns_av_sigmaI/netI    0.0183
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_number            50061
_diffrn_reflns_theta_full        28.00
_diffrn_reflns_theta_max         29.59
_diffrn_reflns_theta_min         3.32
_exptl_absorpt_coefficient_mu    0.764
_exptl_absorpt_correction_T_max  0.947
_exptl_absorpt_correction_T_min  0.908
_exptl_absorpt_correction_type   analytical
_exptl_absorpt_process_details
; 
CrysAlisPro, Oxford Diffraction Ltd., 
Version 1.171.34.36 (release 02-08-2010 CrysAlis171 .NET) 
(compiled Aug  2 2010,13:00:58) 
Analytical numeric absorption correction using a multifaceted crystal
model based on expressions derived by R.C. Clark & J.S. Reid.
(Clark, R. C. & Reid, J. S. (1995). Acta Cryst. A51, 887-897)
;
_exptl_crystal_colour            black
_exptl_crystal_density_diffrn    1.556
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1368
_exptl_crystal_size_max          0.1980
_exptl_crystal_size_mid          0.1349
_exptl_crystal_size_min          0.0978
_refine_diff_density_max         0.447
_refine_diff_density_min         -0.835
_refine_diff_density_rms         0.064
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.051
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     368
_refine_ls_number_reflns         7495
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.051
_refine_ls_R_factor_all          0.0272
_refine_ls_R_factor_gt           0.0231
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0267P)²+1.8646P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0560
_refine_ls_wR_factor_ref         0.0587
_reflns_number_gt                6823
_reflns_number_total             7495
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            om201027y_si_002.cif
_cod_data_source_block           alb69(6c)
_cod_original_cell_volume        2880.77(12)
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               4068048
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Pd Pd 0.137597(8) 0.469666(9) 0.173197(5) 0.01403(4) Uani 1 1 d .
C1 C 0.38883(11) 0.61554(13) 0.18539(7) 0.0168(3) Uani 1 1 d .
C2 C 0.47181(11) 0.54730(14) 0.17387(8) 0.0199(3) Uani 1 1 d .
C7 C 0.51072(14) 0.44635(16) 0.22115(9) 0.0290(4) Uani 1 1 d .
H7A H 0.5340 0.4755 0.2687 0.044 Uiso 1 1 calc R
H7B H 0.5681 0.4085 0.2037 0.044 Uiso 1 1 calc R
H7C H 0.4553 0.3895 0.2217 0.044 Uiso 1 1 calc R
C3 C 0.51713(12) 0.57554(15) 0.11591(8) 0.0235(3) Uani 1 1 d .
H3 H 0.5741 0.5307 0.1068 0.028 Uiso 1 1 calc R
C4 C 0.48197(12) 0.66699(15) 0.07095(8) 0.0234(3) Uani 1 1 d .
C8 C 0.53426(15) 0.69634(18) 0.00918(10) 0.0342(4) Uani 1 1 d .
H8A H 0.5867 0.7564 0.0230 0.051 Uiso 1 1 calc R
H8B H 0.4833 0.7258 -0.0295 0.051 Uiso 1 1 calc R
H8C H 0.5667 0.6258 -0.0060 0.051 Uiso 1 1 calc R
C5 C 0.39821(12) 0.73272(14) 0.08433(8) 0.0218(3) Uani 1 1 d .
H5 H 0.3733 0.7951 0.0537 0.026 Uiso 1 1 calc R
C6 C 0.35027(11) 0.70857(13) 0.14186(8) 0.0180(3) Uani 1 1 d .
C9 C 0.25966(12) 0.77933(14) 0.15611(8) 0.0220(3) Uani 1 1 d .
H9A H 0.2469 0.8436 0.1222 0.033 Uiso 1 1 calc R
H9B H 0.2743 0.8115 0.2036 0.033 Uiso 1 1 calc R
H9C H 0.1989 0.7289 0.1517 0.033 Uiso 1 1 calc R
N1 N 0.33905(9) 0.59131(11) 0.24483(6) 0.0168(2) Uani 1 1 d .
C10 C 0.24346(11) 0.54738(12) 0.24077(7) 0.0157(3) Uani 1 1 d .
C11 C 0.37501(12) 0.63381(14) 0.31227(8) 0.0206(3) Uani 1 1 d .
H11 H 0.4403 0.6682 0.3279 0.025 Uiso 1 1 calc R
C12 C 0.30082(12) 0.61726(14) 0.35073(8) 0.0201(3) Uani 1 1 d .
H12 H 0.3029 0.6372 0.3986 0.024 Uiso 1 1 calc R
N2 N 0.21972(9) 0.56458(11) 0.30609(6) 0.0163(2) Uani 1 1 d .
C13 C 0.11944(11) 0.54003(13) 0.31895(8) 0.0171(3) Uani 1 1 d .
C14 C 0.09276(12) 0.55361(14) 0.38454(8) 0.0218(3) Uani 1 1 d .
H14 H 0.1417 0.5767 0.4238 0.026 Uiso 1 1 calc R
C15 C -0.00901(13) 0.53185(15) 0.39045(8) 0.0248(3) Uani 1 1 d .
H15 H -0.0309 0.5384 0.4346 0.030 Uiso 1 1 calc R
C16 C -0.07849(12) 0.50049(15) 0.33155(8) 0.0223(3) Uani 1 1 d .
H16 H -0.1484 0.4868 0.3351 0.027 Uiso 1 1 calc R
C17 C -0.04517(11) 0.48913(13) 0.26722(8) 0.0172(3) Uani 1 1 d .
N3 N 0.05447(9) 0.50662(11) 0.26109(6) 0.0162(2) Uani 1 1 d .
C21 C -0.11963(11) 0.46589(13) 0.20174(8) 0.0172(3) Uani 1 1 d .
C22 C -0.13900(12) 0.55648(14) 0.15235(8) 0.0207(3) Uani 1 1 d .
C27 C -0.08883(14) 0.67496(15) 0.16498(9) 0.0292(4) Uani 1 1 d .
H24A H -0.0156 0.6683 0.1623 0.044 Uiso 1 1 calc R
H24B H -0.0970 0.7033 0.2115 0.044 Uiso 1 1 calc R
H24C H -0.1213 0.7302 0.1293 0.044 Uiso 1 1 calc R
C23 C -0.20772(13) 0.53583(16) 0.09070(9) 0.0260(3) Uani 1 1 d .
H20 H -0.2218 0.5962 0.0567 0.031 Uiso 1 1 calc R
C24 C -0.25552(12) 0.42823(17) 0.07868(9) 0.0277(4) Uani 1 1 d .
H21 H -0.3009 0.4146 0.0360 0.033 Uiso 1 1 calc R
C25 C -0.23761(12) 0.34017(15) 0.12845(9) 0.0253(3) Uani 1 1 d .
H22 H -0.2717 0.2671 0.1198 0.030 Uiso 1 1 calc R
C26 C -0.17000(11) 0.35735(14) 0.19126(8) 0.0201(3) Uani 1 1 d .
C28 C -0.15184(13) 0.26066(15) 0.24476(9) 0.0285(4) Uani 1 1 d .
H25A H -0.1936 0.2746 0.2813 0.043 Uiso 1 1 calc R
H25B H -0.0791 0.2591 0.2658 0.043 Uiso 1 1 calc R
H25C H -0.1710 0.1854 0.2219 0.043 Uiso 1 1 calc R
C18 C 0.23782(12) 0.42935(14) 0.10715(8) 0.0213(3) Uani 1 1 d .
H18A H 0.2527 0.4999 0.0818 0.032 Uiso 1 1 calc R
H18B H 0.2073 0.3698 0.0736 0.032 Uiso 1 1 calc R
H18C H 0.3016 0.3990 0.1343 0.032 Uiso 1 1 calc R
N4 N 0.02904(9) 0.38897(11) 0.10025(6) 0.0188(2) Uani 1 1 d .
C19 C -0.01857(11) 0.34843(13) 0.05165(8) 0.0186(3) Uani 1 1 d .
C20 C -0.07669(12) 0.29817(14) -0.01201(8) 0.0227(3) Uani 1 1 d .
H20A H -0.0894 0.3586 -0.0484 0.034 Uiso 1 1 calc R
H20B H -0.1424 0.2682 -0.0022 0.034 Uiso 1 1 calc R
H20C H -0.0374 0.2339 -0.0283 0.034 Uiso 1 1 calc R
P P 0.82833(3) 0.98735(4) 0.05967(2) 0.02026(8) Uani 1 1 d .
F1 F 0.84647(9) 1.03239(9) -0.01543(5) 0.0330(2) Uani 1 1 d .
F2 F 0.80719(8) 0.94265(10) 0.13434(5) 0.0307(2) Uani 1 1 d .
F3 F 0.77364(9) 0.87141(10) 0.02331(5) 0.0376(3) Uani 1 1 d .
F4 F 0.71946(8) 1.05398(11) 0.04773(6) 0.0395(3) Uani 1 1 d .
F5 F 0.88275(8) 1.10311(9) 0.09547(5) 0.0336(2) Uani 1 1 d .
F6 F 0.93567(8) 0.92136(9) 0.07179(6) 0.0337(2) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pd Pd -0.9988 1.0072 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
C10 Pd C18 93.14(6)
C10 Pd N4 178.42(5)
C18 Pd N4 85.40(6)
C10 Pd N3 77.93(5)
C18 Pd N3 168.87(6)
N4 Pd N3 103.59(5)
C2 C1 C6 123.13(14)
C2 C1 N1 119.65(13)
C6 C1 N1 117.21(13)
C1 C2 C3 116.97(14)
C1 C2 C7 121.93(14)
C3 C2 C7 121.09(15)
C2 C7 H7A 109.5
C2 C7 H7B 109.5
H7A C7 H7B 109.5
C2 C7 H7C 109.5
H7A C7 H7C 109.5
H7B C7 H7C 109.5
C4 C3 C2 122.31(15)
C4 C3 H3 118.8
C2 C3 H3 118.8
C3 C4 C5 118.76(14)
C3 C4 C8 120.81(16)
C5 C4 C8 120.43(15)
C4 C8 H8A 109.5
C4 C8 H8B 109.5
H8A C8 H8B 109.5
C4 C8 H8C 109.5
H8A C8 H8C 109.5
H8B C8 H8C 109.5
C4 C5 C6 121.30(14)
C4 C5 H5 119.4
C6 C5 H5 119.4
C5 C6 C1 117.54(14)
C5 C6 C9 121.24(14)
C1 C6 C9 121.22(13)
C6 C9 H9A 109.5
C6 C9 H9B 109.5
H9A C9 H9B 109.5
C6 C9 H9C 109.5
H9A C9 H9C 109.5
H9B C9 H9C 109.5
C10 N1 C11 110.70(12)
C10 N1 C1 124.77(12)
C11 N1 C1 123.21(12)
N1 C10 N2 104.39(12)
N1 C10 Pd 139.85(11)
N2 C10 Pd 115.76(10)
C12 C11 N1 107.62(13)
C12 C11 H11 126.2
N1 C11 H11 126.2
C11 C12 N2 105.92(13)
C11 C12 H12 127.0
N2 C12 H12 127.0
C10 N2 C12 111.38(12)
C10 N2 C13 119.92(12)
C12 N2 C13 128.39(13)
N3 C13 C14 124.81(14)
N3 C13 N2 113.32(13)
C14 C13 N2 121.84(13)
C13 C14 C15 116.91(14)
C13 C14 H14 121.5
C15 C14 H14 121.5
C16 C15 C14 119.74(14)
C16 C15 H15 120.1
C14 C15 H15 120.1
C15 C16 C17 119.64(15)
C15 C16 H16 120.2
C17 C16 H16 120.2
N3 C17 C16 121.25(14)
N3 C17 C21 117.69(13)
C16 C17 C21 120.90(13)
C13 N3 C17 117.59(13)
C13 N3 Pd 111.32(9)
C17 N3 Pd 130.65(10)
C22 C21 C26 121.54(14)
C22 C21 C17 117.87(13)
C26 C21 C17 120.58(13)
C23 C22 C21 118.55(15)
C23 C22 C27 119.78(15)
C21 C22 C27 121.67(14)
C22 C27 H24A 109.5
C22 C27 H24B 109.5
H24A C27 H24B 109.5
C22 C27 H24C 109.5
H24A C27 H24C 109.5
H24B C27 H24C 109.5
C24 C23 C22 120.57(16)
C24 C23 H20 119.7
C22 C23 H20 119.7
C23 C24 C25 120.45(15)
C23 C24 H21 119.8
C25 C24 H21 119.8
C24 C25 C26 120.92(16)
C24 C25 H22 119.5
C26 C25 H22 119.5
C25 C26 C21 117.93(15)
C25 C26 C28 120.09(15)
C21 C26 C28 121.97(14)
C26 C28 H25A 109.5
C26 C28 H25B 109.5
H25A C28 H25B 109.5
C26 C28 H25C 109.5
H25A C28 H25C 109.5
H25B C28 H25C 109.5
Pd C18 H18A 109.5
Pd C18 H18B 109.5
H18A C18 H18B 109.5
Pd C18 H18C 109.5
H18A C18 H18C 109.5
H18B C18 H18C 109.5
C19 N4 Pd 167.31(12)
N4 C19 C20 177.90(16)
C19 C20 H20A 109.5
C19 C20 H20B 109.5
H20A C20 H20B 109.5
C19 C20 H20C 109.5
H20A C20 H20C 109.5
H20B C20 H20C 109.5
F6 P F1 91.30(6)
F6 P F2 90.00(6)
F1 P F2 178.59(6)
F6 P F5 90.09(6)
F1 P F5 90.21(6)
F2 P F5 90.31(6)
F6 P F4 179.73(7)
F1 P F4 88.96(6)
F2 P F4 89.73(6)
F5 P F4 89.92(6)
F6 P F3 89.99(6)
F1 P F3 89.48(6)
F2 P F3 90.00(6)
F5 P F3 179.68(6)
F4 P F3 90.01(7)
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
Pd C10 1.9624(14)
Pd C18 2.0395(15)
Pd N4 2.0571(12)
Pd N3 2.2129(12)
C1 C2 1.393(2)
C1 C6 1.399(2)
C1 N1 1.4432(18)
C2 C3 1.394(2)
C2 C7 1.509(2)
C7 H7A 0.9800
C7 H7B 0.9800
C7 H7C 0.9800
C3 C4 1.389(2)
C3 H3 0.9500
C4 C5 1.396(2)
C4 C8 1.514(2)
C8 H8A 0.9800
C8 H8B 0.9800
C8 H8C 0.9800
C5 C6 1.397(2)
C5 H5 0.9500
C6 C9 1.507(2)
C9 H9A 0.9800
C9 H9B 0.9800
C9 H9C 0.9800
N1 C10 1.3491(19)
N1 C11 1.4003(18)
C10 N2 1.3663(19)
C11 C12 1.339(2)
C11 H11 0.9500
C12 N2 1.3968(19)
C12 H12 0.9500
N2 C13 1.4159(19)
C13 N3 1.3488(19)
C13 C14 1.382(2)
C14 C15 1.391(2)
C14 H14 0.9500
C15 C16 1.388(2)
C15 H15 0.9500
C16 C17 1.394(2)
C16 H16 0.9500
C17 N3 1.3560(19)
C17 C21 1.494(2)
C21 C22 1.403(2)
C21 C26 1.406(2)
C22 C23 1.395(2)
C22 C27 1.509(2)
C27 H24A 0.9800
C27 H24B 0.9800
C27 H24C 0.9800
C23 C24 1.384(3)
C23 H20 0.9500
C24 C25 1.386(3)
C24 H21 0.9500
C25 C26 1.399(2)
C25 H22 0.9500
C26 C28 1.506(2)
C28 H25A 0.9800
C28 H25B 0.9800
C28 H25C 0.9800
C18 H18A 0.9800
C18 H18B 0.9800
C18 H18C 0.9800
N4 C19 1.140(2)
C19 C20 1.458(2)
C20 H20A 0.9800
C20 H20B 0.9800
C20 H20C 0.9800
P F6 1.5888(11)
P F1 1.5970(10)
P F2 1.6004(10)
P F5 1.6064(11)
P F4 1.6100(11)
P F3 1.6133(11)
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
C6 C1 C2 C3 0.2(2)
N1 C1 C2 C3 -179.54(13)
C6 C1 C2 C7 -179.08(15)
N1 C1 C2 C7 1.2(2)
C1 C2 C3 C4 -0.2(2)
C7 C2 C3 C4 179.08(15)
C2 C3 C4 C5 -0.1(2)
C2 C3 C4 C8 178.98(15)
C3 C4 C5 C6 0.4(2)
C8 C4 C5 C6 -178.66(15)
C4 C5 C6 C1 -0.4(2)
C4 C5 C6 C9 -179.80(14)
C2 C1 C6 C5 0.1(2)
N1 C1 C6 C5 179.85(12)
C2 C1 C6 C9 179.47(14)
N1 C1 C6 C9 -0.8(2)
C2 C1 N1 C10 -110.89(16)
C6 C1 N1 C10 69.33(19)
C2 C1 N1 C11 83.48(18)
C6 C1 N1 C11 -96.31(17)
C11 N1 C10 N2 0.88(16)
C1 N1 C10 N2 -166.30(13)
C11 N1 C10 Pd -178.04(13)
C1 N1 C10 Pd 14.8(2)
C18 Pd C10 N1 15.65(17)
N3 Pd C10 N1 -171.06(17)
C18 Pd C10 N2 -163.19(11)
N3 Pd C10 N2 10.09(10)
C10 N1 C11 C12 -0.53(18)
C1 N1 C11 C12 166.89(14)
N1 C11 C12 N2 -0.06(17)
N1 C10 N2 C12 -0.93(16)
Pd C10 N2 C12 178.30(10)
N1 C10 N2 C13 173.17(12)
Pd C10 N2 C13 -7.60(17)
C11 C12 N2 C10 0.62(17)
C11 C12 N2 C13 -172.84(14)
C10 N2 C13 N3 -3.46(19)
C12 N2 C13 N3 169.52(14)
C10 N2 C13 C14 178.50(14)
C12 N2 C13 C14 -8.5(2)
N3 C13 C14 C15 -0.5(2)
N2 C13 C14 C15 177.27(14)
C13 C14 C15 C16 -1.3(2)
C14 C15 C16 C17 1.1(3)
C15 C16 C17 N3 0.9(2)
C15 C16 C17 C21 -174.55(15)
C14 C13 N3 C17 2.5(2)
N2 C13 N3 C17 -175.49(13)
C14 C13 N3 Pd -170.77(13)
N2 C13 N3 Pd 11.25(15)
C16 C17 N3 C13 -2.6(2)
C21 C17 N3 C13 172.98(13)
C16 C17 N3 Pd 169.11(12)
C21 C17 N3 Pd -15.3(2)
C10 Pd N3 C13 -11.94(10)
C18 Pd N3 C13 25.3(3)
N4 Pd N3 C13 168.51(10)
C10 Pd N3 C17 175.95(14)
C18 Pd N3 C17 -146.8(3)
N4 Pd N3 C17 -3.61(14)
N3 C17 C21 C22 -66.27(18)
C16 C17 C21 C22 109.33(17)
N3 C17 C21 C26 115.18(16)
C16 C17 C21 C26 -69.2(2)
C26 C21 C22 C23 -2.0(2)
C17 C21 C22 C23 179.50(14)
C26 C21 C22 C27 177.06(14)
C17 C21 C22 C27 -1.5(2)
C21 C22 C23 C24 -0.1(2)
C27 C22 C23 C24 -179.10(15)
C22 C23 C24 C25 1.5(2)
C23 C24 C25 C26 -0.9(2)
C24 C25 C26 C21 -1.0(2)
C24 C25 C26 C28 179.82(15)
C22 C21 C26 C25 2.5(2)
C17 C21 C26 C25 -179.01(13)
C22 C21 C26 C28 -178.39(14)
C17 C21 C26 C28 0.1(2)
