#------------------------------------------------------------------------------
#$Date: 2016-03-21 07:37:51 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178574 $
#$URL: svn://www.crystallography.net/cod/cif/4/06/84/4068464.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4068464
loop_
_publ_author_name
'Knispel, Christina'
'Limberg, Christian'
'Mehring, Michael'
_publ_section_title
;
 Opening of Bent Bi−C Bonds by Silanols To Give Stable
 Cp2Mo(μ-BiOR)2MoCp2Complexes
;
_journal_issue                   2
_journal_name_full               Organometallics
_journal_page_first              646
_journal_paper_doi               10.1021/om8008662
_journal_volume                  28
_journal_year                    2009
_chemical_formula_moiety         'C82 H70 Bi2 Mo O4 Si4'
_chemical_formula_sum            'C82 H70 Bi2 Mo O4 Si4'
_chemical_formula_weight         1745.64
_chemical_name_systematic
; 
 Di(η⁵-cyclopentadienyl)molybdenum-bis(bismuthdi(tri
phenylsilanolat)) 
;
_space_group_IT_number           13
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yac'
_symmetry_space_group_name_H-M   'P 1 2/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 107.421(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   23.6397(4)
_cell_length_b                   11.3979(2)
_cell_length_c                   27.0463(4)
_cell_measurement_reflns_used    5000
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      25
_cell_measurement_theta_min      5
_cell_volume                     6953.2(2)
_computing_cell_refinement       'X-AREA (Stoe & Cie, 2002)'
_computing_data_collection       'X-AREA (Stoe & Cie, 2002)'
_computing_data_reduction        'X-RED (Stoe & Cie, 2002)'
_computing_molecular_graphics    'DIAMOND (Brandenburg & Berndt, 1999)'
_computing_publication_material  'SHELXL97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 1997)'
_computing_structure_solution    'SIR2004 (Burla et al., 2005)'
_diffrn_ambient_temperature      150(2)
_diffrn_detector_area_resol_mean 6.67
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device       'Stoe IPDS-2t diffractometer'
_diffrn_measurement_method       'ω-rotation,ω-incr.=1°,270 exposures'
_diffrn_radiation_collimation    '0.5 mm diameter monocapillary'
_diffrn_radiation_monochromator  'planar graphite'
_diffrn_radiation_source         'long fine focus sealed X-ray tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1468
_diffrn_reflns_av_sigmaI/netI    0.0344
_diffrn_reflns_limit_h_max       28
_diffrn_reflns_limit_h_min       -29
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       33
_diffrn_reflns_limit_l_min       -34
_diffrn_reflns_number            105865
_diffrn_reflns_theta_full        26.50
_diffrn_reflns_theta_max         26.50
_diffrn_reflns_theta_min         3.24
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    5.348
_exptl_absorpt_correction_T_max  0.2771
_exptl_absorpt_correction_T_min  0.1795
_exptl_absorpt_correction_type   refdelf
_exptl_absorpt_process_details
;
The correction was carried out by ABSCOR (Stoe, 1997), a modification of
DIFABS (Walker, N. & Stuart, D. (1983). Acta Cryst. A39, 158-166.
In contrary to DIFABS, ABSCOR loads F² values instead of F ones.
;
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.668
_exptl_crystal_density_method    none
_exptl_crystal_description       block
_exptl_crystal_F_000             3432
_exptl_crystal_size_max          0.40
_exptl_crystal_size_mid          0.36
_exptl_crystal_size_min          0.24
_refine_diff_density_max         1.133
_refine_diff_density_min         -1.041
_refine_diff_density_rms         0.091
_refine_ls_extinction_coef       0.00017(2)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   0.931
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     840
_refine_ls_number_reflns         14379
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.931
_refine_ls_R_factor_all          0.0393
_refine_ls_R_factor_gt           0.0266
_refine_ls_shift/su_max          0.005
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0305P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0511
_refine_ls_wR_factor_ref         0.0536
_reflns_number_gt                11765
_reflns_number_total             14379
_reflns_threshold_expression     I>2sigma(I)
_cod_data_source_file            om8008662_si_001.cif
_cod_data_source_block           3
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_sg_symbol_H-M      'P 2/n'
_cod_database_code               4068464
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y, -z+1/2'
'-x, -y, -z'
'x-1/2, -y, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
C1 C 0.27824(17) 0.5692(4) 0.67476(16) 0.0316(9) Uani 1 1 d .
H1 H 0.2601 0.6189 0.6436 0.038 Uiso 1 1 calc R
C2 C 0.26164(17) 0.4549(4) 0.68249(16) 0.0324(9) Uani 1 1 d .
H2 H 0.2301 0.4077 0.6575 0.039 Uiso 1 1 calc R
C3 C 0.30189(17) 0.4132(3) 0.72959(15) 0.0288(8) Uani 1 1 d .
H3 H 0.3034 0.3313 0.7432 0.035 Uiso 1 1 calc R
C4 C 0.34242(16) 0.5034(4) 0.75144(15) 0.0300(8) Uani 1 1 d .
H4A H 0.3778 0.4968 0.7828 0.036 Uiso 1 1 calc R
C5 C 0.32791(17) 0.5997(4) 0.71727(16) 0.0305(9) Uani 1 1 d .
H5 H 0.3509 0.6746 0.7209 0.037 Uiso 1 1 calc R
C6 C 0.19784(17) 1.0436(3) 0.84127(15) 0.0287(8) Uani 1 1 d .
C7 C 0.23853(17) 0.9898(4) 0.88350(15) 0.0312(8) Uani 1 1 d .
H7 H 0.2479 0.9093 0.8810 0.037 Uiso 1 1 calc R
C8 C 0.2657(2) 1.0501(4) 0.92893(18) 0.0439(11) Uani 1 1 d .
H8A H 0.2938 1.0114 0.9567 0.053 Uiso 1 1 calc R
C9 C 0.2520(2) 1.1668(4) 0.93387(18) 0.0487(12) Uani 1 1 d .
H9 H 0.2702 1.2081 0.9651 0.058 Uiso 1 1 calc R
C10 C 0.2117(2) 1.2225(4) 0.89298(19) 0.0479(12) Uani 1 1 d .
H10 H 0.2018 1.3024 0.8960 0.058 Uiso 1 1 calc R
C11 C 0.1855(2) 1.1619(4) 0.84750(17) 0.0367(9) Uani 1 1 d .
H11 H 0.1583 1.2020 0.8196 0.044 Uiso 1 1 calc R
C12 C 0.08750(16) 0.9024(4) 0.79896(15) 0.0302(8) Uani 1 1 d .
C13 C 0.07413(18) 0.9422(4) 0.84270(17) 0.0376(10) Uani 1 1 d .
H13 H 0.0980 1.0018 0.8633 0.045 Uiso 1 1 calc R
C14 C 0.0269(2) 0.8972(5) 0.8573(2) 0.0499(12) Uani 1 1 d .
H14 H 0.0189 0.9259 0.8875 0.060 Uiso 1 1 calc R
C15 C -0.00786(19) 0.8116(5) 0.8281(2) 0.0518(13) Uani 1 1 d .
H15 H -0.0398 0.7797 0.8382 0.062 Uiso 1 1 calc R
C16 C 0.00341(19) 0.7717(5) 0.7839(2) 0.0518(13) Uani 1 1 d .
H16 H -0.0213 0.7132 0.7633 0.062 Uiso 1 1 calc R
C17 C 0.05062(18) 0.8163(4) 0.76942(17) 0.0395(10) Uani 1 1 d .
H17 H 0.0580 0.7877 0.7389 0.047 Uiso 1 1 calc R
C18 C 0.12989(17) 1.0697(3) 0.72772(15) 0.0293(8) Uani 1 1 d .
C19 C 0.0759(2) 1.1282(4) 0.71651(17) 0.0442(11) Uani 1 1 d .
H19 H 0.0492 1.1104 0.7356 0.053 Uiso 1 1 calc R
C20 C 0.0607(3) 1.2121(5) 0.6778(2) 0.0563(14) Uani 1 1 d .
H20 H 0.0241 1.2528 0.6711 0.068 Uiso 1 1 calc R
C21 C 0.0976(3) 1.2366(4) 0.64933(19) 0.0560(14) Uani 1 1 d .
H21 H 0.0863 1.2932 0.6224 0.067 Uiso 1 1 calc R
C22 C 0.1513(2) 1.1800(4) 0.65913(17) 0.0430(11) Uani 1 1 d .
H22 H 0.1771 1.1972 0.6391 0.052 Uiso 1 1 calc R
C23 C 0.16710(18) 1.0982(3) 0.69836(16) 0.0317(9) Uani 1 1 d .
H23 H 0.2045 1.0602 0.7055 0.038 Uiso 1 1 calc R
C24 C 0.01323(15) 0.8080(4) 0.58319(15) 0.0289(8) Uani 1 1 d .
C25 C 0.01634(18) 0.9197(4) 0.60424(17) 0.0367(10) Uani 1 1 d .
H25 H 0.0431 0.9348 0.6376 0.044 Uiso 1 1 calc R
C26 C -0.0194(2) 1.0100(4) 0.5770(2) 0.0480(12) Uani 1 1 d .
H26 H -0.0169 1.0861 0.5918 0.058 Uiso 1 1 calc R
C27 C -0.0583(2) 0.9889(5) 0.52847(19) 0.0473(12) Uani 1 1 d .
H27 H -0.0827 1.0503 0.5100 0.057 Uiso 1 1 calc R
C28 C -0.06162(18) 0.8797(5) 0.50709(18) 0.0458(12) Uani 1 1 d .
H28 H -0.0883 0.8652 0.4736 0.055 Uiso 1 1 calc R
C29 C -0.02611(17) 0.7900(4) 0.53422(16) 0.0381(10) Uani 1 1 d .
H29 H -0.0288 0.7144 0.5189 0.046 Uiso 1 1 calc R
C30 C 0.11483(15) 0.6517(4) 0.57957(14) 0.0276(8) Uani 1 1 d .
C31 C 0.13920(15) 0.7454(4) 0.55927(14) 0.0300(9) Uani 1 1 d .
H31 H 0.1261 0.8230 0.5627 0.036 Uiso 1 1 calc R
C32 C 0.18202(17) 0.7278(5) 0.53430(16) 0.0417(11) Uani 1 1 d .
H32 H 0.1984 0.7929 0.5214 0.050 Uiso 1 1 calc R
C33 C 0.20055(17) 0.6164(5) 0.52828(17) 0.0426(11) Uani 1 1 d .
H33 H 0.2296 0.6040 0.5110 0.051 Uiso 1 1 calc R
C34 C 0.17688(19) 0.5218(5) 0.54743(17) 0.0442(11) Uani 1 1 d .
H34 H 0.1894 0.4444 0.5429 0.053 Uiso 1 1 calc R
C35 C 0.13482(17) 0.5398(4) 0.57329(16) 0.0353(9) Uani 1 1 d .
H35 H 0.1195 0.4743 0.5869 0.042 Uiso 1 1 calc R
C36 C 0.01329(15) 0.5560(3) 0.61736(14) 0.0255(8) Uani 1 1 d .
C37 C -0.00694(17) 0.4848(4) 0.57374(16) 0.0346(9) Uani 1 1 d .
H37 H 0.0078 0.4971 0.5451 0.042 Uiso 1 1 calc R
C38 C -0.04809(18) 0.3961(4) 0.57112(18) 0.0413(11) Uani 1 1 d .
H38 H -0.0613 0.3487 0.5409 0.050 Uiso 1 1 calc R
C39 C -0.06944(18) 0.3773(4) 0.61210(19) 0.0422(11) Uani 1 1 d .
H39 H -0.0978 0.3171 0.6104 0.051 Uiso 1 1 calc R
C40 C -0.04982(18) 0.4461(4) 0.65614(18) 0.0393(10) Uani 1 1 d .
H40 H -0.0646 0.4328 0.6847 0.047 Uiso 1 1 calc R
C41 C -0.00872(16) 0.5341(4) 0.65867(15) 0.0306(8) Uani 1 1 d .
H41 H 0.0047 0.5804 0.6892 0.037 Uiso 1 1 calc R
C42 C 0.3480(2) 0.3831(6) 0.2670(5) 0.104(4) Uani 1 1 d .
H42 H 0.3686 0.4600 0.2769 0.124 Uiso 1 1 calc R
C43 C 0.3284(3) 0.3340(10) 0.2169(3) 0.096(3) Uani 1 1 d .
H43 H 0.3314 0.3705 0.1842 0.116 Uiso 1 1 calc R
C44 C 0.3114(3) 0.2275(9) 0.2224(3) 0.092(3) Uani 1 1 d .
H44 H 0.2981 0.1686 0.1939 0.110 Uiso 1 1 calc R
C45 C 0.3204(3) 0.2051(6) 0.2724(4) 0.091(3) Uani 1 1 d .
H45 H 0.3152 0.1269 0.2872 0.109 Uiso 1 1 calc R
C46 C 0.3420(3) 0.2977(10) 0.2994(2) 0.090(3) Uani 1 1 d .
H46 H 0.3567 0.3015 0.3381 0.108 Uiso 1 1 calc R
C47 C 0.26613(19) 0.3826(4) 0.43017(15) 0.0343(9) Uani 1 1 d .
C48 C 0.21291(18) 0.4367(4) 0.42622(18) 0.0408(10) Uani 1 1 d .
H48 H 0.2113 0.5200 0.4261 0.049 Uiso 1 1 calc R
C49 C 0.16146(19) 0.3737(4) 0.42243(19) 0.0437(11) Uani 1 1 d .
H49 H 0.1259 0.4145 0.4206 0.052 Uiso 1 1 calc R
C50 C 0.1613(2) 0.2543(4) 0.42129(17) 0.0391(10) Uani 1 1 d .
H50 H 0.1262 0.2113 0.4192 0.047 Uiso 1 1 calc R
C51 C 0.2124(3) 0.1989(5) 0.4232(3) 0.080(2) Uani 1 1 d .
H51 H 0.2133 0.1157 0.4219 0.096 Uiso 1 1 calc R
C52 C 0.2631(3) 0.2621(5) 0.4271(3) 0.081(2) Uani 1 1 d .
H52 H 0.2980 0.2202 0.4277 0.097 Uiso 1 1 calc R
C53 C 0.4001(2) 0.3640(5) 0.46510(17) 0.0515(14) Uani 1 1 d .
C54 C 0.4444(3) 0.3515(7) 0.4453(2) 0.084(2) Uani 1 1 d .
H54 H 0.4423 0.3929 0.4143 0.101 Uiso 1 1 calc R
C55 C 0.4948(3) 0.2809(7) 0.4669(3) 0.095(3) Uani 1 1 d .
H55 H 0.5258 0.2779 0.4513 0.114 Uiso 1 1 calc R
C56 C 0.4985(3) 0.2206(7) 0.5082(3) 0.094(3) Uani 1 1 d .
H56 H 0.5337 0.1781 0.5245 0.113 Uiso 1 1 calc R
C57 C 0.4498(3) 0.2171(7) 0.5297(3) 0.086(2) Uani 1 1 d .
H57 H 0.4508 0.1671 0.5581 0.104 Uiso 1 1 calc R
C58 C 0.4018(3) 0.2880(5) 0.5083(2) 0.0644(15) Uani 1 1 d .
H58 H 0.3692 0.2870 0.5220 0.077 Uiso 1 1 calc R
C59 C 0.33805(16) 0.5941(4) 0.47944(15) 0.0334(9) Uani 1 1 d .
C60 C 0.35437(16) 0.5828(4) 0.53303(16) 0.0353(9) Uani 1 1 d .
H60 H 0.3656 0.5079 0.5481 0.042 Uiso 1 1 calc R
C61 C 0.35469(17) 0.6774(4) 0.56482(16) 0.0403(11) Uani 1 1 d .
H61 H 0.3665 0.6674 0.6014 0.048 Uiso 1 1 calc R
C62 C 0.33803(18) 0.7857(4) 0.54376(18) 0.0430(11) Uani 1 1 d .
H62 H 0.3380 0.8509 0.5656 0.052 Uiso 1 1 calc R
C63 C 0.3213(2) 0.8002(5) 0.4907(2) 0.0496(12) Uani 1 1 d .
H63 H 0.3093 0.8752 0.4760 0.060 Uiso 1 1 calc R
C64 C 0.3220(2) 0.7056(5) 0.45899(19) 0.0490(12) Uani 1 1 d .
H64 H 0.3113 0.7167 0.4225 0.059 Uiso 1 1 calc R
C65 C 0.44505(16) 0.6694(4) 0.30830(15) 0.0300(8) Uani 1 1 d .
C66 C 0.48640(17) 0.6849(4) 0.28193(16) 0.0308(8) Uani 1 1 d .
H66 H 0.4772 0.7360 0.2528 0.037 Uiso 1 1 calc R
C67 C 0.54097(17) 0.6284(4) 0.29652(17) 0.0365(9) Uani 1 1 d .
H67 H 0.5682 0.6401 0.2773 0.044 Uiso 1 1 calc R
C68 C 0.55505(19) 0.5568(5) 0.3383(2) 0.0504(13) Uani 1 1 d .
H68 H 0.5922 0.5174 0.3483 0.060 Uiso 1 1 calc R
C69 C 0.5155(2) 0.5409(6) 0.3663(2) 0.073(2) Uani 1 1 d .
H69 H 0.5255 0.4911 0.3958 0.088 Uiso 1 1 calc R
C70 C 0.46118(19) 0.5979(6) 0.3512(2) 0.0573(15) Uani 1 1 d .
H70 H 0.4345 0.5872 0.3710 0.069 Uiso 1 1 calc R
C71 C 0.36319(19) 0.8485(4) 0.33670(19) 0.0404(10) Uani 1 1 d .
C72 C 0.4120(2) 0.9002(5) 0.3716(2) 0.0620(15) Uani 1 1 d .
H72 H 0.4504 0.8759 0.3716 0.074 Uiso 1 1 calc R
C73 C 0.4073(3) 0.9858(6) 0.4066(3) 0.081(2) Uani 1 1 d .
H73 H 0.4420 1.0192 0.4297 0.097 Uiso 1 1 calc R
C74 C 0.3545(3) 1.0208(5) 0.4078(3) 0.0737(18) Uani 1 1 d .
H74 H 0.3510 1.0762 0.4330 0.088 Uiso 1 1 calc R
C75 C 0.3050(3) 0.9771(5) 0.3727(3) 0.0706(18) Uani 1 1 d .
H75 H 0.2672 1.0067 0.3720 0.085 Uiso 1 1 calc R
C76 C 0.3085(2) 0.8900(4) 0.3377(2) 0.0486(12) Uani 1 1 d .
H76 H 0.2733 0.8588 0.3145 0.058 Uiso 1 1 calc R
C77 C 0.36851(17) 0.8317(4) 0.22835(19) 0.0368(10) Uani 1 1 d .
C78 C 0.4001(2) 0.9369(4) 0.2354(2) 0.0568(14) Uani 1 1 d .
H78 H 0.4186 0.9648 0.2695 0.068 Uiso 1 1 calc R
C79 C 0.4047(3) 1.0013(5) 0.1932(3) 0.0694(18) Uani 1 1 d .
H79 H 0.4277 1.0711 0.1988 0.083 Uiso 1 1 calc R
C80 C 0.3769(2) 0.9660(5) 0.1440(3) 0.0610(16) Uani 1 1 d .
H80 H 0.3800 1.0113 0.1154 0.073 Uiso 1 1 calc R
C81 C 0.3444(2) 0.8644(5) 0.1358(2) 0.0519(13) Uani 1 1 d .
H81 H 0.3239 0.8401 0.1015 0.062 Uiso 1 1 calc R
C82 C 0.3413(2) 0.7971(4) 0.17770(18) 0.0399(10) Uani 1 1 d .
H82 H 0.3199 0.7254 0.1715 0.048 Uiso 1 1 calc R
Bi1 Bi 0.192850(5) 0.767692(11) 0.695508(5) 0.02006(4) Uani 1 1 d .
Bi2 Bi 0.264580(6) 0.548211(13) 0.314532(5) 0.02613(4) Uani 1 1 d .
Mo1 Mo 0.2500 0.56508(4) 0.7500 0.01928(9) Uani 1 2 d S
Mo2 Mo 0.2500 0.34794(4) 0.2500 0.02528(10) Uani 1 2 d S
O1 O 0.19287(10) 0.8585(2) 0.76689(9) 0.0234(5) Uani 1 1 d .
O2 O 0.09959(10) 0.7208(2) 0.67671(9) 0.0255(5) Uani 1 1 d .
O3 O 0.34020(11) 0.5073(3) 0.37978(10) 0.0350(7) Uani 1 1 d .
O4 O 0.31722(11) 0.6449(2) 0.27426(10) 0.0304(6) Uani 1 1 d .
Si1 Si 0.15365(4) 0.96156(9) 0.78199(4) 0.0245(2) Uani 1 1 d .
Si2 Si 0.06218(4) 0.68527(9) 0.61797(4) 0.0235(2) Uani 1 1 d .
Si3 Si 0.33672(5) 0.46550(11) 0.43567(4) 0.0329(3) Uani 1 1 d .
Si4 Si 0.37015(4) 0.74134(10) 0.28700(4) 0.0295(2) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Bi Bi -4.1077 10.2566 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Mo Mo -1.6832 0.6857 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C2 C1 C5 108.0(4) . .
C2 C1 Mo1 71.5(2) . .
C5 C1 Mo1 71.4(2) . .
C2 C1 H1 125.9 . .
C5 C1 H1 125.9 . .
Mo1 C1 H1 125.9 . .
C1 C2 C3 107.7(4) . .
C1 C2 Mo1 73.4(2) . .
C3 C2 Mo1 71.3(2) . .
C1 C2 H2 126.0 . .
C3 C2 H2 126.0 . .
Mo1 C2 H2 126.0 . .
C4 C3 C2 108.6(4) . .
C4 C3 Mo1 72.1(2) . .
C2 C3 Mo1 72.5(2) . .
C4 C3 H3 125.6 . .
C2 C3 H3 125.6 . .
Mo1 C3 H3 125.6 . .
C3 C4 C5 107.0(3) . .
C3 C4 Mo1 72.0(2) . .
C5 C4 Mo1 72.9(2) . .
C3 C4 H4A 126.3 . .
C5 C4 H4A 126.3 . .
Mo1 C4 H4A 126.3 . .
C4 C5 C1 108.7(4) . .
C4 C5 Mo1 71.3(2) . .
C1 C5 Mo1 72.9(2) . .
C4 C5 H5 125.6 . .
C1 C5 H5 125.6 . .
Mo1 C5 H5 125.6 . .
C7 C6 C11 116.2(4) . .
C7 C6 Si1 123.4(3) . .
C11 C6 Si1 119.9(3) . .
C8 C7 C6 122.0(4) . .
C8 C7 H7 119.0 . .
C6 C7 H7 119.0 . .
C9 C8 C7 120.1(4) . .
C9 C8 H8A 119.9 . .
C7 C8 H8A 119.9 . .
C10 C9 C8 119.4(4) . .
C10 C9 H9 120.3 . .
C8 C9 H9 120.3 . .
C9 C10 C11 120.0(4) . .
C9 C10 H10 120.0 . .
C11 C10 H10 120.0 . .
C10 C11 C6 122.3(4) . .
C10 C11 H11 118.9 . .
C6 C11 H11 118.9 . .
C13 C12 C17 117.1(4) . .
C13 C12 Si1 120.6(3) . .
C17 C12 Si1 122.3(3) . .
C14 C13 C12 122.0(4) . .
C14 C13 H13 119.0 . .
C12 C13 H13 119.0 . .
C15 C14 C13 119.7(5) . .
C15 C14 H14 120.2 . .
C13 C14 H14 120.2 . .
C14 C15 C16 120.0(4) . .
C14 C15 H15 120.0 . .
C16 C15 H15 120.0 . .
C15 C16 C17 120.4(5) . .
C15 C16 H16 119.8 . .
C17 C16 H16 119.8 . .
C16 C17 C12 120.9(4) . .
C16 C17 H17 119.5 . .
C12 C17 H17 119.5 . .
C23 C18 C19 117.4(4) . .
C23 C18 Si1 120.7(3) . .
C19 C18 Si1 121.8(3) . .
C20 C19 C18 120.6(5) . .
C20 C19 H19 119.7 . .
C18 C19 H19 119.7 . .
C21 C20 C19 120.5(5) . .
C21 C20 H20 119.8 . .
C19 C20 H20 119.8 . .
C20 C21 C22 120.5(4) . .
C20 C21 H21 119.7 . .
C22 C21 H21 119.7 . .
C21 C22 C23 119.2(5) . .
C21 C22 H22 120.4 . .
C23 C22 H22 120.4 . .
C22 C23 C18 121.7(4) . .
C22 C23 H23 119.1 . .
C18 C23 H23 119.1 . .
C29 C24 C25 117.7(4) . .
C29 C24 Si2 120.3(3) . .
C25 C24 Si2 121.9(3) . .
C24 C25 C26 120.7(4) . .
C24 C25 H25 119.6 . .
C26 C25 H25 119.6 . .
C27 C26 C25 120.0(5) . .
C27 C26 H26 120.0 . .
C25 C26 H26 120.0 . .
C28 C27 C26 120.0(4) . .
C28 C27 H27 120.0 . .
C26 C27 H27 120.0 . .
C27 C28 C29 120.0(4) . .
C27 C28 H28 120.0 . .
C29 C28 H28 120.0 . .
C28 C29 C24 121.6(5) . .
C28 C29 H29 119.2 . .
C24 C29 H29 119.2 . .
C35 C30 C31 117.2(4) . .
C35 C30 Si2 124.0(3) . .
C31 C30 Si2 118.6(3) . .
C32 C31 C30 121.6(4) . .
C32 C31 H31 119.2 . .
C30 C31 H31 119.2 . .
C33 C32 C31 119.9(4) . .
C33 C32 H32 120.1 . .
C31 C32 H32 120.1 . .
C32 C33 C34 119.9(4) . .
C32 C33 H33 120.1 . .
C34 C33 H33 120.1 . .
C33 C34 C35 120.2(4) . .
C33 C34 H34 119.9 . .
C35 C34 H34 119.9 . .
C30 C35 C34 121.2(4) . .
C30 C35 H35 119.4 . .
C34 C35 H35 119.4 . .
C41 C36 C37 117.4(4) . .
C41 C36 Si2 120.9(3) . .
C37 C36 Si2 121.4(3) . .
C38 C37 C36 121.6(4) . .
C38 C37 H37 119.2 . .
C36 C37 H37 119.2 . .
C39 C38 C37 119.7(4) . .
C39 C38 H38 120.2 . .
C37 C38 H38 120.2 . .
C38 C39 C40 120.0(4) . .
C38 C39 H39 120.0 . .
C40 C39 H39 120.0 . .
C41 C40 C39 120.1(4) . .
C41 C40 H40 119.9 . .
C39 C40 H40 119.9 . .
C40 C41 C36 121.1(4) . .
C40 C41 H41 119.4 . .
C36 C41 H41 119.4 . .
C46 C42 C43 105.6(6) . .
C46 C42 Mo2 72.7(4) . .
C43 C42 Mo2 73.3(3) . .
C46 C42 H42 126.8 . .
C43 C42 H42 126.8 . .
Mo2 C42 H42 126.8 . .
C44 C43 C42 106.5(6) . .
C44 C43 Mo2 72.9(4) . .
C42 C43 Mo2 70.6(3) . .
C44 C43 H43 126.6 . .
C42 C43 H43 126.6 . .
Mo2 C43 H43 126.6 . .
C43 C44 C45 109.6(7) . .
C43 C44 Mo2 74.1(4) . .
C45 C44 Mo2 73.0(3) . .
C43 C44 H44 125.0 . .
C45 C44 H44 125.0 . .
Mo2 C44 H44 125.0 . .
C46 C45 C44 109.4(7) . .
C46 C45 Mo2 72.6(3) . .
C44 C45 Mo2 73.1(4) . .
C46 C45 H45 125.2 . .
C44 C45 H45 125.2 . .
Mo2 C45 H45 125.2 . .
C45 C46 C42 108.9(6) . .
C45 C46 Mo2 74.2(4) . .
C42 C46 Mo2 72.7(3) . .
C45 C46 H46 125.3 . .
C42 C46 H46 125.3 . .
Mo2 C46 H46 125.3 . .
C52 C47 C48 114.3(4) . .
C52 C47 Si3 122.3(4) . .
C48 C47 Si3 123.3(3) . .
C47 C48 C49 122.2(4) . .
C47 C48 H48 118.9 . .
C49 C48 H48 118.9 . .
C50 C49 C48 121.0(4) . .
C50 C49 H49 119.5 . .
C48 C49 H49 119.5 . .
C51 C50 C49 118.0(5) . .
C51 C50 H50 121.0 . .
C49 C50 H50 121.0 . .
C50 C51 C52 120.5(5) . .
C50 C51 H51 119.8 . .
C52 C51 H51 119.8 . .
C51 C52 C47 123.8(5) . .
C51 C52 H52 118.1 . .
C47 C52 H52 118.1 . .
C54 C53 C58 115.4(5) . .
C54 C53 Si3 121.7(5) . .
C58 C53 Si3 122.7(4) . .
C53 C54 C55 124.5(6) . .
C53 C54 H54 117.7 . .
C55 C54 H54 117.7 . .
C56 C55 C54 119.5(6) . .
C56 C55 H55 120.2 . .
C54 C55 H55 120.2 . .
C55 C56 C57 120.6(6) . .
C55 C56 H56 119.7 . .
C57 C56 H56 119.7 . .
C58 C57 C56 118.2(7) . .
C58 C57 H57 120.9 . .
C56 C57 H57 120.9 . .
C57 C58 C53 121.0(6) . .
C57 C58 H58 119.5 . .
C53 C58 H58 119.5 . .
C60 C59 C64 117.2(4) . .
C60 C59 Si3 122.1(4) . .
C64 C59 Si3 120.7(3) . .
C61 C60 C59 121.8(4) . .
C61 C60 H60 119.1 . .
C59 C60 H60 119.1 . .
C62 C61 C60 120.0(4) . .
C62 C61 H61 120.0 . .
C60 C61 H61 120.0 . .
C61 C62 C63 119.9(4) . .
C61 C62 H62 120.0 . .
C63 C62 H62 120.0 . .
C62 C63 C64 120.0(5) . .
C62 C63 H63 120.0 . .
C64 C63 H63 120.0 . .
C63 C64 C59 121.2(4) . .
C63 C64 H64 119.4 . .
C59 C64 H64 119.4 . .
C70 C65 C66 116.8(4) . .
C70 C65 Si4 121.0(3) . .
C66 C65 Si4 122.2(3) . .
C65 C66 C67 122.3(4) . .
C65 C66 H66 118.9 . .
C67 C66 H66 118.9 . .
C68 C67 C66 119.5(4) . .
C68 C67 H67 120.2 . .
C66 C67 H67 120.2 . .
C67 C68 C69 120.0(4) . .
C67 C68 H68 120.0 . .
C69 C68 H68 120.0 . .
C68 C69 C70 119.8(5) . .
C68 C69 H69 120.1 . .
C70 C69 H69 120.1 . .
C65 C70 C69 121.6(4) . .
C65 C70 H70 119.2 . .
C69 C70 H70 119.2 . .
C72 C71 C76 115.7(4) . .
C72 C71 Si4 122.5(3) . .
C76 C71 Si4 121.6(4) . .
C71 C72 C73 123.0(5) . .
C71 C72 H72 118.5 . .
C73 C72 H72 118.5 . .
C74 C73 C72 119.9(7) . .
C74 C73 H73 120.0 . .
C72 C73 H73 120.0 . .
C73 C74 C75 119.6(6) . .
C73 C74 H74 120.2 . .
C75 C74 H74 120.2 . .
C74 C75 C76 121.4(5) . .
C74 C75 H75 119.3 . .
C76 C75 H75 119.3 . .
C71 C76 C75 120.3(5) . .
C71 C76 H76 119.9 . .
C75 C76 H76 119.9 . .
C82 C77 C78 116.8(5) . .
C82 C77 Si4 124.3(3) . .
C78 C77 Si4 118.7(4) . .
C79 C78 C77 120.8(6) . .
C79 C78 H78 119.6 . .
C77 C78 H78 119.6 . .
C80 C79 C78 121.0(5) . .
C80 C79 H79 119.5 . .
C78 C79 H79 119.5 . .
C79 C80 C81 119.4(5) . .
C79 C80 H80 120.3 . .
C81 C80 H80 120.3 . .
C80 C81 C82 120.0(6) . .
C80 C81 H81 120.0 . .
C82 C81 H81 120.0 . .
C77 C82 C81 121.8(5) . .
C77 C82 H82 119.1 . .
C81 C82 H82 119.1 . .
O2 Bi1 O1 93.15(9) . .
O2 Bi1 Mo1 102.23(7) . .
O1 Bi1 Mo1 92.99(6) . .
O2 Bi1 Bi1 134.40(6) . 2_556
O1 Bi1 Bi1 55.75(6) . 2_556
Mo1 Bi1 Bi1 54.049(6) . 2_556
O3 Bi2 O4 93.49(10) . .
O3 Bi2 Mo2 104.40(8) . .
O4 Bi2 Mo2 94.69(7) . .
O3 Bi2 Bi2 135.67(7) . 2
O4 Bi2 Bi2 56.63(7) . 2
Mo2 Bi2 Bi2 53.733(7) . 2
C3 Mo1 C3 81.3(2) 2_556 .
C3 Mo1 C4 35.94(14) 2_556 2_556
C3 Mo1 C4 110.04(15) . 2_556
C3 Mo1 C4 110.04(15) 2_556 .
C3 Mo1 C4 35.94(14) . .
C4 Mo1 C4 144.1(2) 2_556 .
C3 Mo1 C2 88.76(15) 2_556 .
C3 Mo1 C2 36.22(14) . .
C4 Mo1 C2 99.18(15) 2_556 .
C4 Mo1 C2 60.28(14) . .
C3 Mo1 C2 36.22(14) 2_556 2_556
C3 Mo1 C2 88.76(15) . 2_556
C4 Mo1 C2 60.28(14) 2_556 2_556
C4 Mo1 C2 99.18(15) . 2_556
C2 Mo1 C2 113.8(2) . 2_556
C3 Mo1 C5 59.21(14) 2_556 2_556
C3 Mo1 C5 140.54(15) . 2_556
C4 Mo1 C5 35.79(15) 2_556 2_556
C4 Mo1 C5 156.45(14) . 2_556
C2 Mo1 C5 134.29(15) . 2_556
C2 Mo1 C5 59.28(14) 2_556 2_556
C3 Mo1 C5 140.54(15) 2_556 .
C3 Mo1 C5 59.21(14) . .
C4 Mo1 C5 156.45(14) 2_556 .
C4 Mo1 C5 35.79(15) . .
C2 Mo1 C5 59.28(14) . .
C2 Mo1 C5 134.29(15) 2_556 .
C5 Mo1 C5 160.2(2) 2_556 .
C3 Mo1 C1 59.20(14) 2_556 2_556
C3 Mo1 C1 122.89(15) . 2_556
C4 Mo1 C1 59.82(14) 2_556 2_556
C4 Mo1 C1 121.02(14) . 2_556
C2 Mo1 C1 147.18(16) . 2_556
C2 Mo1 C1 35.11(15) 2_556 2_556
C5 Mo1 C1 35.70(14) 2_556 2_556
C5 Mo1 C1 143.62(14) . 2_556
C3 Mo1 C1 122.89(15) 2_556 .
C3 Mo1 C1 59.20(14) . .
C4 Mo1 C1 121.02(14) 2_556 .
C4 Mo1 C1 59.82(14) . .
C2 Mo1 C1 35.11(15) . .
C2 Mo1 C1 147.18(15) 2_556 .
C5 Mo1 C1 143.62(14) 2_556 .
C5 Mo1 C1 35.70(14) . .
C1 Mo1 C1 177.7(2) 2_556 .
C3 Mo1 Bi1 134.00(10) 2_556 2_556
C3 Mo1 Bi1 122.22(10) . 2_556
C4 Mo1 Bi1 124.09(11) 2_556 2_556
C4 Mo1 Bi1 86.43(10) . 2_556
C2 Mo1 Bi1 134.55(11) . 2_556
C2 Mo1 Bi1 100.52(11) 2_556 2_556
C5 Mo1 Bi1 88.40(10) 2_556 2_556
C5 Mo1 Bi1 75.54(10) . 2_556
C1 Mo1 Bi1 75.34(10) 2_556 2_556
C1 Mo1 Bi1 102.71(11) . 2_556
C3 Mo1 Bi1 122.22(10) 2_556 .
C3 Mo1 Bi1 134.00(10) . .
C4 Mo1 Bi1 86.43(10) 2_556 .
C4 Mo1 Bi1 124.09(11) . .
C2 Mo1 Bi1 100.52(11) . .
C2 Mo1 Bi1 134.55(11) 2_556 .
C5 Mo1 Bi1 75.54(10) 2_556 .
C5 Mo1 Bi1 88.40(10) . .
C1 Mo1 Bi1 102.71(11) 2_556 .
C1 Mo1 Bi1 75.34(10) . .
Bi1 Mo1 Bi1 71.901(11) 2_556 .
C42 Mo2 C42 159.5(3) 2 .
C42 Mo2 C46 34.6(3) 2 2
C42 Mo2 C46 155.9(3) . 2
C42 Mo2 C46 155.9(3) 2 .
C42 Mo2 C46 34.6(3) . .
C46 Mo2 C46 150.6(6) 2 .
C42 Mo2 C45 56.6(3) 2 2
C42 Mo2 C45 143.6(2) . 2
C46 Mo2 C45 33.2(3) 2 2
C46 Mo2 C45 118.3(5) . 2
C42 Mo2 C45 143.6(2) 2 .
C42 Mo2 C45 56.6(3) . .
C46 Mo2 C45 118.3(5) 2 .
C46 Mo2 C45 33.2(3) . .
C45 Mo2 C45 88.7(4) 2 .
C42 Mo2 C44 57.2(2) 2 2
C42 Mo2 C44 139.0(3) . 2
C46 Mo2 C44 56.3(2) 2 2
C46 Mo2 C44 104.4(3) . 2
C45 Mo2 C44 33.9(3) 2 2
C45 Mo2 C44 88.2(3) . 2
C42 Mo2 C44 139.0(3) 2 .
C42 Mo2 C44 57.2(2) . .
C46 Mo2 C44 104.4(3) 2 .
C46 Mo2 C44 56.3(2) . .
C45 Mo2 C44 88.2(3) 2 .
C45 Mo2 C44 33.9(3) . .
C44 Mo2 C44 105.9(6) 2 .
C42 Mo2 C43 36.1(3) 2 2
C42 Mo2 C43 146.4(3) . 2
C46 Mo2 C43 57.6(2) 2 2
C46 Mo2 C43 120.0(3) . 2
C45 Mo2 C43 56.1(2) 2 2
C45 Mo2 C43 117.3(4) . 2
C44 Mo2 C43 33.1(3) 2 2
C44 Mo2 C43 139.0(5) . 2
C42 Mo2 C43 146.4(3) 2 .
C42 Mo2 C43 36.1(3) . .
C46 Mo2 C43 120.0(3) 2 .
C46 Mo2 C43 57.6(2) . .
C45 Mo2 C43 117.3(4) 2 .
C45 Mo2 C43 56.1(2) . .
C44 Mo2 C43 139.0(5) 2 .
C44 Mo2 C43 33.1(3) . .
C43 Mo2 C43 172.0(5) 2 .
C42 Mo2 Bi2 84.9(3) 2 .
C42 Mo2 Bi2 78.64(19) . .
C46 Mo2 Bi2 119.1(3) 2 .
C46 Mo2 Bi2 85.5(2) . .
C45 Mo2 Bi2 133.21(18) 2 .
C45 Mo2 Bi2 117.9(3) . .
C44 Mo2 Bi2 104.8(3) 2 .
C44 Mo2 Bi2 135.67(18) . .
C43 Mo2 Bi2 77.22(17) 2 .
C43 Mo2 Bi2 109.5(3) . .
C42 Mo2 Bi2 78.64(19) 2 2
C42 Mo2 Bi2 84.9(3) . 2
C46 Mo2 Bi2 85.5(2) 2 2
C46 Mo2 Bi2 119.1(3) . 2
C45 Mo2 Bi2 117.9(3) 2 2
C45 Mo2 Bi2 133.21(18) . 2
C44 Mo2 Bi2 135.67(18) 2 2
C44 Mo2 Bi2 104.8(3) . 2
C43 Mo2 Bi2 109.5(3) 2 2
C43 Mo2 Bi2 77.22(17) . 2
Bi2 Mo2 Bi2 72.533(13) . 2
Si1 O1 Bi1 135.61(14) . .
Si2 O2 Bi1 120.51(14) . .
Si3 O3 Bi2 124.76(14) . .
Si4 O4 Bi2 138.99(16) . .
O1 Si1 C18 109.85(16) . .
O1 Si1 C6 111.17(15) . .
C18 Si1 C6 107.53(18) . .
O1 Si1 C12 112.44(16) . .
C18 Si1 C12 110.57(18) . .
C6 Si1 C12 105.09(18) . .
O2 Si2 C36 111.09(15) . .
O2 Si2 C24 112.22(17) . .
C36 Si2 C24 107.22(16) . .
O2 Si2 C30 109.53(15) . .
C36 Si2 C30 110.11(18) . .
C24 Si2 C30 106.55(17) . .
O3 Si3 C53 108.8(2) . .
O3 Si3 C59 111.39(19) . .
C53 Si3 C59 110.74(19) . .
O3 Si3 C47 111.54(16) . .
C53 Si3 C47 107.5(2) . .
C59 Si3 C47 106.78(17) . .
O4 Si4 C71 111.66(17) . .
O4 Si4 C65 111.44(17) . .
C71 Si4 C65 110.13(19) . .
O4 Si4 C77 111.82(17) . .
C71 Si4 C77 105.4(2) . .
C65 Si4 C77 106.07(17) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 C2 1.395(6) .
C1 C5 1.419(6) .
C1 Mo1 2.324(4) .
C1 H1 1.0000 .
C2 C3 1.424(6) .
C2 Mo1 2.299(4) .
C2 H2 1.0000 .
C3 C4 1.409(5) .
C3 Mo1 2.283(4) .
C3 H3 1.0000 .
C4 C5 1.410(6) .
C4 Mo1 2.284(4) .
C4 H4A 1.0000 .
C5 Mo1 2.304(4) .
C5 H5 1.0000 .
C6 C7 1.396(5) .
C6 C11 1.401(6) .
C6 Si1 1.880(4) .
C7 C8 1.387(6) .
C7 H7 0.9500 .
C8 C9 1.385(7) .
C8 H8A 0.9500 .
C9 C10 1.380(7) .
C9 H9 0.9500 .
C10 C11 1.384(6) .
C10 H10 0.9500 .
C11 H11 0.9500 .
C12 C13 1.389(6) .
C12 C17 1.395(6) .
C12 Si1 1.881(4) .
C13 C14 1.389(6) .
C13 H13 0.9500 .
C14 C15 1.365(7) .
C14 H14 0.9500 .
C15 C16 1.376(7) .
C15 H15 0.9500 .
C16 C17 1.386(6) .
C16 H16 0.9500 .
C17 H17 0.9500 .
C18 C23 1.388(6) .
C18 C19 1.391(6) .
C18 Si1 1.870(4) .
C19 C20 1.384(7) .
C19 H19 0.9500 .
C20 C21 1.353(8) .
C20 H20 0.9500 .
C21 C22 1.377(7) .
C21 H21 0.9500 .
C22 C23 1.378(6) .
C22 H22 0.9500 .
C23 H23 0.9500 .
C24 C29 1.387(6) .
C24 C25 1.388(6) .
C24 Si2 1.879(4) .
C25 C26 1.394(6) .
C25 H25 0.9500 .
C26 C27 1.379(7) .
C26 H26 0.9500 .
C27 C28 1.364(7) .
C27 H27 0.9500 .
C28 C29 1.385(6) .
C28 H28 0.9500 .
C29 H29 0.9500 .
C30 C35 1.389(6) .
C30 C31 1.401(5) .
C30 Si2 1.884(4) .
C31 C32 1.390(6) .
C31 H31 0.9500 .
C32 C33 1.368(7) .
C32 H32 0.9500 .
C33 C34 1.385(7) .
C33 H33 0.9500 .
C34 C35 1.391(6) .
C34 H34 0.9500 .
C35 H35 0.9500 .
C36 C41 1.389(5) .
C36 C37 1.394(5) .
C36 Si2 1.869(4) .
C37 C38 1.390(6) .
C37 H37 0.9500 .
C38 C39 1.365(7) .
C38 H38 0.9500 .
C39 C40 1.385(7) .
C39 H39 0.9500 .
C40 C41 1.384(6) .
C40 H40 0.9500 .
C41 H41 0.9500 .
C42 C46 1.344(11) .
C42 C43 1.410(12) .
C42 Mo2 2.258(5) .
C42 H42 1.0000 .
C43 C44 1.301(11) .
C43 Mo2 2.293(5) .
C43 H43 1.0000 .
C44 C45 1.328(11) .
C44 Mo2 2.278(6) .
C44 H44 1.0000 .
C45 C46 1.297(11) .
C45 Mo2 2.277(6) .
C45 H45 1.0000 .
C46 Mo2 2.259(5) .
C46 H46 1.0000 .
C47 C52 1.376(7) .
C47 C48 1.376(6) .
C47 Si3 1.884(5) .
C48 C49 1.390(6) .
C48 H48 0.9500 .
C49 C50 1.360(6) .
C49 H49 0.9500 .
C50 C51 1.351(7) .
C50 H50 0.9500 .
C51 C52 1.375(8) .
C51 H51 0.9500 .
C52 H52 0.9500 .
C53 C54 1.320(7) .
C53 C58 1.445(8) .
C53 Si3 1.872(5) .
C54 C55 1.411(8) .
C54 H54 0.9500 .
C55 C56 1.291(10) .
C55 H55 0.9500 .
C56 C57 1.439(11) .
C56 H56 0.9500 .
C57 C58 1.371(8) .
C57 H57 0.9500 .
C58 H58 0.9500 .
C59 C60 1.390(6) .
C59 C64 1.392(7) .
C59 Si3 1.879(4) .
C60 C61 1.378(6) .
C60 H60 0.9500 .
C61 C62 1.367(7) .
C61 H61 0.9500 .
C62 C63 1.380(7) .
C62 H62 0.9500 .
C63 C64 1.381(7) .
C63 H63 0.9500 .
C64 H64 0.9500 .
C65 C70 1.375(6) .
C65 C66 1.383(5) .
C65 Si4 1.878(4) .
C66 C67 1.389(5) .
C66 H66 0.9500 .
C67 C68 1.352(6) .
C67 H67 0.9500 .
C68 C69 1.379(7) .
C68 H68 0.9500 .
C69 C70 1.387(7) .
C69 H69 0.9500 .
C70 H70 0.9500 .
C71 C72 1.384(7) .
C71 C76 1.385(6) .
C71 Si4 1.860(5) .
C72 C73 1.386(8) .
C72 H72 0.9500 .
C73 C74 1.319(9) .
C73 H73 0.9500 .
C74 C75 1.362(9) .
C74 H74 0.9500 .
C75 C76 1.390(8) .
C75 H75 0.9500 .
C76 H76 0.9500 .
C77 C82 1.385(7) .
C77 C78 1.394(6) .
C77 Si4 1.882(5) .
C78 C79 1.389(8) .
C78 H78 0.9500 .
C79 C80 1.357(9) .
C79 H79 0.9500 .
C80 C81 1.371(8) .
C80 H80 0.9500 .
C81 C82 1.388(6) .
C81 H81 0.9500 .
C82 H82 0.9500 .
Bi1 O2 2.176(2) .
Bi1 O1 2.191(2) .
Bi1 Mo1 2.8528(4) .
Bi1 Bi1 3.3497(3) 2_556
Bi2 O3 2.154(3) .
Bi2 O4 2.182(3) .
Bi2 Mo2 2.8312(4) .
Bi2 Bi2 3.3495(3) 2
Mo1 C3 2.283(4) 2_556
Mo1 C4 2.284(4) 2_556
Mo1 C2 2.299(4) 2_556
Mo1 C5 2.304(4) 2_556
Mo1 C1 2.324(4) 2_556
Mo1 Bi1 2.8528(4) 2_556
Mo2 C42 2.258(5) 2
Mo2 C46 2.259(5) 2
Mo2 C45 2.277(6) 2
Mo2 C44 2.278(6) 2
Mo2 C43 2.293(5) 2
Mo2 Bi2 2.8312(4) 2
O1 Si1 1.622(3) .
O2 Si2 1.621(3) .
O3 Si3 1.610(3) .
O4 Si4 1.623(3) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C5 C1 C2 C3 -1.1(4) . .
Mo1 C1 C2 C3 -63.5(3) . .
C5 C1 C2 Mo1 62.4(3) . .
C1 C2 C3 C4 1.5(4) . .
Mo1 C2 C3 C4 -63.5(3) . .
C1 C2 C3 Mo1 64.9(3) . .
C2 C3 C4 C5 -1.2(4) . .
Mo1 C3 C4 C5 -65.0(3) . .
C2 C3 C4 Mo1 63.7(3) . .
C3 C4 C5 C1 0.5(4) . .
Mo1 C4 C5 C1 -63.8(3) . .
C3 C4 C5 Mo1 64.4(3) . .
C2 C1 C5 C4 0.4(4) . .
Mo1 C1 C5 C4 62.8(3) . .
C2 C1 C5 Mo1 -62.5(3) . .
C11 C6 C7 C8 -0.6(6) . .
Si1 C6 C7 C8 -172.9(3) . .
C6 C7 C8 C9 1.3(7) . .
C7 C8 C9 C10 -0.8(7) . .
C8 C9 C10 C11 -0.3(8) . .
C9 C10 C11 C6 1.0(7) . .
C7 C6 C11 C10 -0.5(6) . .
Si1 C6 C11 C10 172.1(4) . .
C17 C12 C13 C14 1.1(6) . .
Si1 C12 C13 C14 -177.6(4) . .
C12 C13 C14 C15 -0.2(7) . .
C13 C14 C15 C16 -1.1(8) . .
C14 C15 C16 C17 1.2(8) . .
C15 C16 C17 C12 -0.2(8) . .
C13 C12 C17 C16 -0.9(7) . .
Si1 C12 C17 C16 177.8(4) . .
C23 C18 C19 C20 -0.6(7) . .
Si1 C18 C19 C20 176.8(4) . .
C18 C19 C20 C21 1.6(8) . .
C19 C20 C21 C22 -1.2(8) . .
C20 C21 C22 C23 -0.1(7) . .
C21 C22 C23 C18 1.1(7) . .
C19 C18 C23 C22 -0.8(6) . .
Si1 C18 C23 C22 -178.2(3) . .
C29 C24 C25 C26 0.5(6) . .
Si2 C24 C25 C26 178.2(3) . .
C24 C25 C26 C27 -0.1(7) . .
C25 C26 C27 C28 -0.3(7) . .
C26 C27 C28 C29 0.3(7) . .
C27 C28 C29 C24 0.1(7) . .
C25 C24 C29 C28 -0.5(6) . .
Si2 C24 C29 C28 -178.3(3) . .
C35 C30 C31 C32 -0.6(5) . .
Si2 C30 C31 C32 174.6(3) . .
C30 C31 C32 C33 1.2(6) . .
C31 C32 C33 C34 -0.5(6) . .
C32 C33 C34 C35 -0.7(6) . .
C31 C30 C35 C34 -0.6(6) . .
Si2 C30 C35 C34 -175.5(3) . .
C33 C34 C35 C30 1.3(6) . .
C41 C36 C37 C38 0.8(6) . .
Si2 C36 C37 C38 -173.2(3) . .
C36 C37 C38 C39 -0.1(6) . .
C37 C38 C39 C40 -0.4(6) . .
C38 C39 C40 C41 0.2(6) . .
C39 C40 C41 C36 0.5(6) . .
C37 C36 C41 C40 -1.0(6) . .
Si2 C36 C41 C40 173.1(3) . .
C46 C42 C43 C44 1.5(6) . .
Mo2 C42 C43 C44 -64.5(4) . .
C46 C42 C43 Mo2 66.0(4) . .
C42 C43 C44 C45 -1.9(7) . .
Mo2 C43 C44 C45 -64.9(5) . .
C42 C43 C44 Mo2 63.0(4) . .
C43 C44 C45 C46 1.6(8) . .
Mo2 C44 C45 C46 -64.0(4) . .
C43 C44 C45 Mo2 65.6(5) . .
C44 C45 C46 C42 -0.6(7) . .
Mo2 C45 C46 C42 -64.9(4) . .
C44 C45 C46 Mo2 64.3(5) . .
C43 C42 C46 C45 -0.6(7) . .
Mo2 C42 C46 C45 65.9(5) . .
C43 C42 C46 Mo2 -66.4(4) . .
C52 C47 C48 C49 3.5(7) . .
Si3 C47 C48 C49 -179.7(4) . .
C47 C48 C49 C50 -1.5(8) . .
C48 C49 C50 C51 -0.9(8) . .
C49 C50 C51 C52 1.1(10) . .
C50 C51 C52 C47 1.2(13) . .
C48 C47 C52 C51 -3.4(10) . .
Si3 C47 C52 C51 179.8(6) . .
C58 C53 C54 C55 -7.6(11) . .
Si3 C53 C54 C55 176.8(7) . .
C53 C54 C55 C56 2.1(14) . .
C54 C55 C56 C57 5.1(13) . .
C55 C56 C57 C58 -6.0(12) . .
C56 C57 C58 C53 0.1(10) . .
C54 C53 C58 C57 6.3(9) . .
Si3 C53 C58 C57 -178.2(5) . .
C64 C59 C60 C61 0.1(6) . .
Si3 C59 C60 C61 -179.4(3) . .
C59 C60 C61 C62 0.7(6) . .
C60 C61 C62 C63 -0.4(7) . .
C61 C62 C63 C64 -0.6(7) . .
C62 C63 C64 C59 1.5(8) . .
C60 C59 C64 C63 -1.1(7) . .
Si3 C59 C64 C63 178.3(4) . .
C70 C65 C66 C67 2.1(7) . .
Si4 C65 C66 C67 -177.6(3) . .
C65 C66 C67 C68 -0.9(7) . .
C66 C67 C68 C69 -0.5(8) . .
C67 C68 C69 C70 0.5(10) . .
C66 C65 C70 C69 -2.1(8) . .
Si4 C65 C70 C69 177.7(5) . .
C68 C69 C70 C65 0.8(10) . .
C76 C71 C72 C73 1.6(9) . .
Si4 C71 C72 C73 175.7(5) . .
C71 C72 C73 C74 0.5(11) . .
C72 C73 C74 C75 -3.6(11) . .
C73 C74 C75 C76 4.6(10) . .
C72 C71 C76 C75 -0.7(8) . .
Si4 C71 C76 C75 -174.8(4) . .
C74 C75 C76 C71 -2.4(9) . .
C82 C77 C78 C79 -1.5(7) . .
Si4 C77 C78 C79 174.1(4) . .
C77 C78 C79 C80 2.5(9) . .
C78 C79 C80 C81 -0.8(9) . .
C79 C80 C81 C82 -1.6(8) . .
C78 C77 C82 C81 -0.9(6) . .
Si4 C77 C82 C81 -176.2(3) . .
C80 C81 C82 C77 2.5(7) . .
C4 C3 Mo1 C3 -143.2(3) . 2_556
C2 C3 Mo1 C3 99.8(3) . 2_556
C4 C3 Mo1 C4 -165.17(16) . 2_556
C2 C3 Mo1 C4 77.8(3) . 2_556
C2 C3 Mo1 C4 -117.0(4) . .
C4 C3 Mo1 C2 117.0(4) . .
C4 C3 Mo1 C2 -107.6(3) . 2_556
C2 C3 Mo1 C2 135.4(2) . 2_556
C4 C3 Mo1 C5 -141.4(3) . 2_556
C2 C3 Mo1 C5 101.6(3) . 2_556
C4 C3 Mo1 C5 38.1(2) . .
C2 C3 Mo1 C5 -78.9(3) . .
C4 C3 Mo1 C1 -98.8(3) . 2_556
C2 C3 Mo1 C1 144.2(2) . 2_556
C4 C3 Mo1 C1 79.9(3) . .
C2 C3 Mo1 C1 -37.1(2) . .
C4 C3 Mo1 Bi1 -5.9(3) . 2_556
C2 C3 Mo1 Bi1 -122.9(2) . 2_556
C4 C3 Mo1 Bi1 89.7(2) . .
C2 C3 Mo1 Bi1 -27.2(3) . .
C3 C4 Mo1 C3 39.1(3) . 2_556
C5 C4 Mo1 C3 154.1(2) . 2_556
C5 C4 Mo1 C3 115.0(3) . .
C3 C4 Mo1 C4 24.2(2) . 2_556
C5 C4 Mo1 C4 139.2(2) . 2_556
C3 C4 Mo1 C2 -37.3(2) . .
C5 C4 Mo1 C2 77.6(2) . .
C3 C4 Mo1 C2 74.9(3) . 2_556
C5 C4 Mo1 C2 -170.1(2) . 2_556
C3 C4 Mo1 C5 97.3(4) . 2_556
C5 C4 Mo1 C5 -147.7(4) . 2_556
C3 C4 Mo1 C5 -115.0(3) . .
C3 C4 Mo1 C1 104.5(3) . 2_556
C5 C4 Mo1 C1 -140.6(2) . 2_556
C3 C4 Mo1 C1 -78.1(3) . .
C5 C4 Mo1 C1 36.9(2) . .
C3 C4 Mo1 Bi1 175.0(2) . 2_556
C5 C4 Mo1 Bi1 -70.0(2) . 2_556
C3 C4 Mo1 Bi1 -119.7(2) . .
C5 C4 Mo1 Bi1 -4.7(3) . .
C1 C2 Mo1 C3 167.2(2) . 2_556
C3 C2 Mo1 C3 -77.0(3) . 2_556
C1 C2 Mo1 C3 -115.8(3) . .
C1 C2 Mo1 C4 132.7(2) . 2_556
C3 C2 Mo1 C4 -111.5(2) . 2_556
C1 C2 Mo1 C4 -78.8(3) . .
C3 C2 Mo1 C4 37.0(2) . .
C1 C2 Mo1 C2 -165.9(3) . 2_556
C3 C2 Mo1 C2 -50.0(2) . 2_556
C1 C2 Mo1 C5 124.6(2) . 2_556
C3 C2 Mo1 C5 -119.6(3) . 2_556
C1 C2 Mo1 C5 -37.1(2) . .
C3 C2 Mo1 C5 78.7(3) . .
C3 C2 Mo1 C1 -65.1(4) . 2_556
C3 C2 Mo1 C1 115.8(3) . .
C1 C2 Mo1 Bi1 -30.3(3) . 2_556
C3 C2 Mo1 Bi1 85.5(3) . 2_556
C1 C2 Mo1 Bi1 44.6(2) . .
C3 C2 Mo1 Bi1 160.4(2) . .
C4 C5 Mo1 C3 -40.3(3) . 2_556
C1 C5 Mo1 C3 76.9(3) . 2_556
C4 C5 Mo1 C3 -38.3(2) . .
C1 C5 Mo1 C3 78.9(2) . .
C4 C5 Mo1 C4 -106.6(5) . 2_556
C1 C5 Mo1 C4 10.6(5) . 2_556
C1 C5 Mo1 C4 117.2(3) . .
C4 C5 Mo1 C2 -80.7(2) . .
C1 C5 Mo1 C2 36.5(2) . .
C4 C5 Mo1 C2 13.7(3) . 2_556
C1 C5 Mo1 C2 130.9(3) . 2_556
C4 C5 Mo1 C5 140.9(2) . 2_556
C4 C5 Mo1 C1 66.6(3) . 2_556
C1 C5 Mo1 C1 -176.2(3) . 2_556
C4 C5 Mo1 C1 -117.2(3) . .
C4 C5 Mo1 Bi1 104.4(2) . 2_556
C1 C5 Mo1 Bi1 -138.4(2) . 2_556
C4 C5 Mo1 Bi1 176.1(2) . .
C1 C5 Mo1 Bi1 -66.7(2) . .
C2 C1 Mo1 C3 -15.3(3) . 2_556
C5 C1 Mo1 C3 -132.5(2) . 2_556
C2 C1 Mo1 C3 38.3(2) . .
C5 C1 Mo1 C3 -78.9(2) . .
C2 C1 Mo1 C4 -57.9(3) . 2_556
C5 C1 Mo1 C4 -175.1(2) . 2_556
C2 C1 Mo1 C4 80.2(2) . .
C5 C1 Mo1 C4 -37.0(2) . .
C5 C1 Mo1 C2 -117.2(3) . .
C2 C1 Mo1 C2 24.4(5) . 2_556
C5 C1 Mo1 C2 -92.9(3) . 2_556
C2 C1 Mo1 C5 -96.7(3) . 2_556
C5 C1 Mo1 C5 146.1(4) . 2_556
C2 C1 Mo1 C5 117.2(3) . .
C2 C1 Mo1 Bi1 158.4(2) . 2_556
C5 C1 Mo1 Bi1 41.2(2) . 2_556
C2 C1 Mo1 Bi1 -134.5(2) . .
C5 C1 Mo1 Bi1 108.3(2) . .
O2 Bi1 Mo1 C3 -5.51(14) . 2_556
O1 Bi1 Mo1 C3 88.37(14) . 2_556
Bi1 Bi1 Mo1 C3 131.14(12) 2_556 2_556
O2 Bi1 Mo1 C3 105.69(16) . .
O1 Bi1 Mo1 C3 -160.43(15) . .
Bi1 Bi1 Mo1 C3 -117.66(14) 2_556 .
O2 Bi1 Mo1 C4 -8.97(13) . 2_556
O1 Bi1 Mo1 C4 84.91(12) . 2_556
Bi1 Bi1 Mo1 C4 127.68(11) 2_556 2_556
O2 Bi1 Mo1 C4 150.82(13) . .
O1 Bi1 Mo1 C4 -115.30(13) . .
Bi1 Bi1 Mo1 C4 -72.53(12) 2_556 .
O2 Bi1 Mo1 C2 89.72(12) . .
O1 Bi1 Mo1 C2 -176.40(12) . .
Bi1 Bi1 Mo1 C2 -133.63(10) 2_556 .
O2 Bi1 Mo1 C2 -49.64(16) . 2_556
O1 Bi1 Mo1 C2 44.24(16) . 2_556
Bi1 Bi1 Mo1 C2 87.01(14) 2_556 2_556
O2 Bi1 Mo1 C5 -43.56(13) . 2_556
O1 Bi1 Mo1 C5 50.32(13) . 2_556
Bi1 Bi1 Mo1 C5 93.09(11) 2_556 2_556
O2 Bi1 Mo1 C5 148.05(12) . .
O1 Bi1 Mo1 C5 -118.07(12) . .
Bi1 Bi1 Mo1 C5 -75.30(10) 2_556 .
O2 Bi1 Mo1 C1 -66.93(12) . 2_556
O1 Bi1 Mo1 C1 26.95(12) . 2_556
Bi1 Bi1 Mo1 C1 69.72(10) 2_556 2_556
O2 Bi1 Mo1 C1 114.40(13) . .
O1 Bi1 Mo1 C1 -151.72(12) . .
Bi1 Bi1 Mo1 C1 -108.95(11) 2_556 .
O2 Bi1 Mo1 Bi1 -136.65(7) . 2_556
O1 Bi1 Mo1 Bi1 -42.77(6) . 2_556
C46 C42 Mo2 C42 135.6(6) . 2
C46 C42 Mo2 C46 -121.2(14) . 2
C43 C42 Mo2 C46 -8.4(14) . 2
C43 C42 Mo2 C46 112.8(5) . .
C46 C42 Mo2 C45 -56.0(11) . 2
C43 C42 Mo2 C45 56.8(11) . 2
C46 C42 Mo2 C45 -36.1(4) . .
C43 C42 Mo2 C45 76.7(5) . .
C46 C42 Mo2 C44 -0.9(9) . 2
C43 C42 Mo2 C44 111.9(10) . 2
C46 C42 Mo2 C44 -76.8(5) . .
C43 C42 Mo2 C44 36.0(4) . .
C46 C42 Mo2 C43 53.9(8) . 2
C43 C42 Mo2 C43 166.7(9) . 2
C46 C42 Mo2 C43 -112.8(5) . .
C46 C42 Mo2 Bi2 98.7(6) . .
C43 C42 Mo2 Bi2 -148.5(6) . .
C46 C42 Mo2 Bi2 171.9(5) . 2
C43 C42 Mo2 Bi2 -75.3(5) . 2
C45 C46 Mo2 C42 100.6(8) . 2
C42 C46 Mo2 C42 -143.2(7) . 2
C45 C46 Mo2 C42 -116.2(6) . .
C45 C46 Mo2 C46 18.5(5) . 2
C42 C46 Mo2 C46 134.6(5) . 2
C45 C46 Mo2 C45 29.8(8) . 2
C42 C46 Mo2 C45 146.0(6) . 2
C42 C46 Mo2 C45 116.2(6) . .
C45 C46 Mo2 C44 63.2(7) . 2
C42 C46 Mo2 C44 179.4(6) . 2
C45 C46 Mo2 C44 -36.5(5) . .
C42 C46 Mo2 C44 79.6(5) . .
C45 C46 Mo2 C43 94.9(6) . 2
C42 C46 Mo2 C43 -148.9(6) . 2
C45 C46 Mo2 C43 -76.2(5) . .
C42 C46 Mo2 C43 40.0(4) . .
C45 C46 Mo2 Bi2 167.4(6) . .
C42 C46 Mo2 Bi2 -76.4(5) . .
C45 C46 Mo2 Bi2 -125.4(6) . 2
C42 C46 Mo2 Bi2 -9.3(6) . 2
C46 C45 Mo2 C42 -137.5(6) . 2
C44 C45 Mo2 C42 105.2(7) . 2
C46 C45 Mo2 C42 37.7(5) . .
C44 C45 Mo2 C42 -79.6(6) . .
C46 C45 Mo2 C46 -169.8(4) . 2
C44 C45 Mo2 C46 72.9(6) . 2
C44 C45 Mo2 C46 -117.3(7) . .
C46 C45 Mo2 C45 -154.0(7) . 2
C44 C45 Mo2 C45 88.7(7) . 2
C46 C45 Mo2 C44 -120.1(7) . 2
C44 C45 Mo2 C44 122.6(7) . 2
C46 C45 Mo2 C44 117.3(7) . .
C46 C45 Mo2 C43 -103.8(5) . 2
C44 C45 Mo2 C43 138.9(5) . 2
C46 C45 Mo2 C43 81.4(6) . .
C44 C45 Mo2 C43 -35.9(5) . .
C46 C45 Mo2 Bi2 -14.2(6) . .
C44 C45 Mo2 Bi2 -131.6(6) . .
C46 C45 Mo2 Bi2 77.6(7) . 2
C44 C45 Mo2 Bi2 -39.8(8) . 2
C43 C44 Mo2 C42 124.0(5) . 2
C45 C44 Mo2 C42 -119.2(5) . 2
C43 C44 Mo2 C42 -39.4(5) . .
C45 C44 Mo2 C42 77.4(6) . .
C43 C44 Mo2 C46 123.5(6) . 2
C45 C44 Mo2 C46 -119.7(6) . 2
C43 C44 Mo2 C46 -81.0(6) . .
C45 C44 Mo2 C46 35.8(5) . .
C43 C44 Mo2 C45 152.8(7) . 2
C45 C44 Mo2 C45 -90.4(8) . 2
C43 C44 Mo2 C45 -116.8(7) . .
C43 C44 Mo2 C44 -178.0(7) . 2
C45 C44 Mo2 C44 -61.1(6) . 2
C45 C44 Mo2 C43 -62.8(6) . 2
C45 C44 Mo2 C43 116.8(7) . .
C43 C44 Mo2 Bi2 -45.7(8) . .
C45 C44 Mo2 Bi2 71.2(8) . .
C43 C44 Mo2 Bi2 34.3(6) . 2
C45 C44 Mo2 Bi2 151.2(5) . 2
C44 C43 Mo2 C42 -100.9(5) . 2
C42 C43 Mo2 C42 144.1(7) . 2
C44 C43 Mo2 C42 115.0(6) . .
C44 C43 Mo2 C46 -68.9(6) . 2
C42 C43 Mo2 C46 176.1(7) . 2
C44 C43 Mo2 C46 76.7(5) . .
C42 C43 Mo2 C46 -38.3(4) . .
C44 C43 Mo2 C45 -31.0(7) . 2
C42 C43 Mo2 C45 -146.0(7) . 2
C44 C43 Mo2 C45 36.9(5) . .
C42 C43 Mo2 C45 -78.2(5) . .
C44 C43 Mo2 C44 3.0(10) . 2
C42 C43 Mo2 C44 -112.1(8) . 2
C42 C43 Mo2 C44 -115.0(6) . .
C44 C43 Mo2 Bi2 148.0(5) . .
C42 C43 Mo2 Bi2 32.9(6) . .
C44 C43 Mo2 Bi2 -146.0(6) . 2
C42 C43 Mo2 Bi2 99.0(6) . 2
O3 Bi2 Mo2 C42 143.6(3) . 2
O4 Bi2 Mo2 C42 -121.5(3) . 2
Bi2 Bi2 Mo2 C42 -79.7(2) 2 2
O3 Bi2 Mo2 C42 -48.5(3) . .
O4 Bi2 Mo2 C42 46.3(3) . .
Bi2 Bi2 Mo2 C42 88.2(3) 2 .
O3 Bi2 Mo2 C46 148.9(2) . 2
O4 Bi2 Mo2 C46 -116.3(2) . 2
Bi2 Bi2 Mo2 C46 -74.41(19) 2 2
O3 Bi2 Mo2 C46 -14.3(3) . .
O4 Bi2 Mo2 C46 80.6(3) . .
Bi2 Bi2 Mo2 C46 122.4(3) 2 .
O3 Bi2 Mo2 C45 111.1(4) . 2
O4 Bi2 Mo2 C45 -154.0(4) . 2
Bi2 Bi2 Mo2 C45 -112.2(4) 2 2
O3 Bi2 Mo2 C45 -6.5(2) . .
O4 Bi2 Mo2 C45 88.4(2) . .
Bi2 Bi2 Mo2 C45 130.2(2) 2 .
O3 Bi2 Mo2 C44 89.49(18) . 2
O4 Bi2 Mo2 C44 -175.69(18) . 2
Bi2 Bi2 Mo2 C44 -133.82(17) 2 2
O3 Bi2 Mo2 C44 -43.1(4) . .
O4 Bi2 Mo2 C44 51.7(4) . .
Bi2 Bi2 Mo2 C44 93.5(4) 2 .
O3 Bi2 Mo2 C43 107.9(3) . 2
O4 Bi2 Mo2 C43 -157.3(3) . 2
Bi2 Bi2 Mo2 C43 -115.4(3) 2 2
O3 Bi2 Mo2 C43 -67.61(16) . .
O4 Bi2 Mo2 C43 27.22(15) . .
Bi2 Bi2 Mo2 C43 69.08(14) 2 .
O3 Bi2 Mo2 Bi2 -136.69(8) . 2
O4 Bi2 Mo2 Bi2 -41.86(7) . 2
O2 Bi1 O1 Si1 -53.2(2) . .
Mo1 Bi1 O1 Si1 -155.7(2) . .
Bi1 Bi1 O1 Si1 162.7(2) 2_556 .
O1 Bi1 O2 Si2 160.28(17) . .
Mo1 Bi1 O2 Si2 -105.96(15) . .
Bi1 Bi1 O2 Si2 -157.02(10) 2_556 .
O4 Bi2 O3 Si3 162.1(2) . .
Mo2 Bi2 O3 Si3 -102.14(19) . .
Bi2 Bi2 O3 Si3 -154.46(13) 2 .
O3 Bi2 O4 Si4 -44.0(2) . .
Mo2 Bi2 O4 Si4 -148.8(2) . .
Bi2 Bi2 O4 Si4 171.1(3) 2 .
Bi1 O1 Si1 C18 -34.3(3) . .
Bi1 O1 Si1 C6 -153.2(2) . .
Bi1 O1 Si1 C12 89.3(2) . .
C23 C18 Si1 O1 -35.8(4) . .
C19 C18 Si1 O1 146.9(3) . .
C23 C18 Si1 C6 85.3(3) . .
C19 C18 Si1 C6 -92.0(4) . .
C23 C18 Si1 C12 -160.5(3) . .
C19 C18 Si1 C12 22.2(4) . .
C7 C6 Si1 O1 -37.6(4) . .
C11 C6 Si1 O1 150.3(3) . .
C7 C6 Si1 C18 -157.9(3) . .
C11 C6 Si1 C18 30.0(4) . .
C7 C6 Si1 C12 84.3(4) . .
C11 C6 Si1 C12 -87.8(3) . .
C13 C12 Si1 O1 133.6(3) . .
C17 C12 Si1 O1 -45.0(4) . .
C13 C12 Si1 C18 -103.2(3) . .
C17 C12 Si1 C18 78.1(4) . .
C13 C12 Si1 C6 12.6(4) . .
C17 C12 Si1 C6 -166.1(3) . .
Bi1 O2 Si2 C36 137.59(17) . .
Bi1 O2 Si2 C24 -102.39(18) . .
Bi1 O2 Si2 C30 15.7(2) . .
C41 C36 Si2 O2 28.6(3) . .
C37 C36 Si2 O2 -157.5(3) . .
C41 C36 Si2 C24 -94.3(3) . .
C37 C36 Si2 C24 79.6(3) . .
C41 C36 Si2 C30 150.2(3) . .
C37 C36 Si2 C30 -36.0(4) . .
C29 C24 Si2 O2 -174.0(3) . .
C25 C24 Si2 O2 8.3(4) . .
C29 C24 Si2 C36 -51.8(4) . .
C25 C24 Si2 C36 130.5(3) . .
C29 C24 Si2 C30 66.1(3) . .
C25 C24 Si2 C30 -111.6(3) . .
C35 C30 Si2 O2 94.1(3) . .
C31 C30 Si2 O2 -80.7(3) . .
C35 C30 Si2 C36 -28.3(4) . .
C31 C30 Si2 C36 156.9(3) . .
C35 C30 Si2 C24 -144.3(3) . .
C31 C30 Si2 C24 40.9(3) . .
Bi2 O3 Si3 C53 148.2(2) . .
Bi2 O3 Si3 C59 -89.5(2) . .
Bi2 O3 Si3 C47 29.7(3) . .
C54 C53 Si3 O3 11.5(6) . .
C58 C53 Si3 O3 -163.7(4) . .
C54 C53 Si3 C59 -111.3(5) . .
C58 C53 Si3 C59 73.5(5) . .
C54 C53 Si3 C47 132.4(5) . .
C58 C53 Si3 C47 -42.8(5) . .
C60 C59 Si3 O3 -159.0(3) . .
C64 C59 Si3 O3 21.6(4) . .
C60 C59 Si3 C53 -37.8(4) . .
C64 C59 Si3 C53 142.8(4) . .
C60 C59 Si3 C47 79.0(3) . .
C64 C59 Si3 C47 -100.4(4) . .
C52 C47 Si3 O3 94.3(5) . .
C48 C47 Si3 O3 -82.3(4) . .
C52 C47 Si3 C53 -24.9(5) . .
C48 C47 Si3 C53 158.5(4) . .
C52 C47 Si3 C59 -143.8(5) . .
C48 C47 Si3 C59 39.6(4) . .
Bi2 O4 Si4 C71 -35.8(3) . .
Bi2 O4 Si4 C65 87.8(3) . .
Bi2 O4 Si4 C77 -153.6(2) . .
C72 C71 Si4 O4 148.2(4) . .
C76 C71 Si4 O4 -38.1(5) . .
C72 C71 Si4 C65 23.8(5) . .
C76 C71 Si4 C65 -162.5(4) . .
C72 C71 Si4 C77 -90.2(5) . .
C76 C71 Si4 C77 83.5(4) . .
C70 C65 Si4 O4 -59.1(4) . .
C66 C65 Si4 O4 120.6(3) . .
C70 C65 Si4 C71 65.4(5) . .
C66 C65 Si4 C71 -114.9(4) . .
C70 C65 Si4 C77 179.0(4) . .
C66 C65 Si4 C77 -1.3(4) . .
C82 C77 Si4 O4 -21.6(4) . .
C78 C77 Si4 O4 163.2(3) . .
C82 C77 Si4 C71 -143.1(4) . .
C78 C77 Si4 C71 41.7(4) . .
C82 C77 Si4 C65 100.1(4) . .
C78 C77 Si4 C65 -75.1(4) . .
