#------------------------------------------------------------------------------
#$Date: 2016-03-21 07:42:50 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178578 $
#$URL: svn://www.crystallography.net/cod/cif/4/06/88/4068888.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4068888
loop_
_publ_author_name
'Zang, Shuang-Quan'
'Han, Jie'
'Mak, Thomas C. W.'
_publ_section_title
;
 Silver(I)−Organic Networks Assembled with the Flexible
 Prop-2-ynyloxybenzene Ligand:In SituRecrystallization and Unusual
 Silver−Aromatic Interaction
;
_journal_issue                   9
_journal_name_full               Organometallics
_journal_page_first              2677
_journal_paper_doi               10.1021/om801143q
_journal_volume                  28
_journal_year                    2009
_chemical_formula_moiety         'C37 H17 Ag9 F40 N2 O19'
_chemical_formula_sum            'C37 H17 Ag9 F40 N2 O19'
_chemical_formula_weight         2524.36
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                98.128(4)
_cell_angle_beta                 99.459(4)
_cell_angle_gamma                98.479(4)
_cell_formula_units_Z            2
_cell_length_a                   12.388(3)
_cell_length_b                   14.823(3)
_cell_length_c                   18.741(4)
_cell_measurement_reflns_used    803
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      26.587
_cell_measurement_theta_min      2.308
_cell_volume                     3308.7(13)
_computing_cell_refinement       SMART
_computing_data_collection       'SMART (Bruker, 2000)'
_computing_data_reduction        'SAINT (Bruker, 2000)'
_computing_molecular_graphics    SHELXTL
_computing_publication_material  SHELXTL
_computing_structure_refinement  SHELXTL
_computing_structure_solution    'SHELXTL (Bruker, 2000)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.994
_diffrn_measured_fraction_theta_max 0.994
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0559
_diffrn_reflns_av_sigmaI/netI    0.1041
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            18156
_diffrn_reflns_theta_full        25.05
_diffrn_reflns_theta_max         25.05
_diffrn_reflns_theta_min         1.41
_exptl_absorpt_coefficient_mu    2.780
_exptl_absorpt_correction_T_max  0.571
_exptl_absorpt_correction_T_min  0.478
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS(Bruker, 2000)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    2.534
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             2376
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.25
_exptl_crystal_size_min          0.20
_refine_diff_density_max         1.077
_refine_diff_density_min         -0.914
_refine_diff_density_rms         0.158
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.956
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     966
_refine_ls_number_reflns         11667
_refine_ls_number_restraints     52
_refine_ls_restrained_S_all      0.955
_refine_ls_R_factor_all          0.1278
_refine_ls_R_factor_gt           0.0699
_refine_ls_shift/su_max          0.039
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0782P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1516
_refine_ls_wR_factor_ref         0.1730
_reflns_number_gt                6644
_reflns_number_total             11667
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            om801143q_si_001.cif
_cod_data_source_block           3
_cod_database_code               4068888
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag 0.33646(7) 0.22794(6) 0.38401(5) 0.0519(3) Uani 1 1 d .
Ag2 Ag 0.47629(8) 0.37286(6) 0.48781(5) 0.0535(3) Uani 1 1 d .
Ag3 Ag 0.52647(9) 0.33104(7) 0.33871(5) 0.0607(3) Uani 1 1 d .
Ag4 Ag 0.48548(10) 0.12351(7) 0.31221(5) 0.0632(3) Uani 1 1 d .
Ag5 Ag 0.43485(8) 0.08606(7) 0.45153(5) 0.0536(3) Uani 1 1 d .
Ag6 Ag 0.05654(8) 0.21584(9) 0.33568(7) 0.0772(4) Uani 1 1 d .
Ag7 Ag 0.41481(8) 0.40877(8) 0.17872(5) 0.0635(3) Uani 1 1 d .
Ag8 Ag 0.37394(10) 0.46024(10) 0.03461(6) 0.0829(4) Uani 1 1 d .
Ag9 Ag 0.55120(11) -0.02555(9) 0.18153(7) 0.0869(4) Uani 1 1 d .
C1 C 0.5135(10) 0.2387(8) 0.4274(6) 0.043(3) Uani 1 1 d .
C2 C 0.5936(10) 0.2119(9) 0.4543(6) 0.052(3) Uani 1 1 d .
C3 C 0.7019(11) 0.1932(12) 0.4889(8) 0.076(4) Uani 1 1 d .
H3A H 0.7503 0.2512 0.5118 0.091 Uiso 1 1 calc R
H3B H 0.6915 0.1563 0.5268 0.091 Uiso 1 1 calc R
O1 O 0.7530(8) 0.1446(7) 0.4351(7) 0.084(3) Uani 1 1 d .
C4 C 0.7882(10) 0.1894(12) 0.3824(8) 0.069(4) Uani 1 1 d .
C5 C 0.8307(12) 0.1328(12) 0.3262(10) 0.085(5) Uani 1 1 d .
H5 H 0.8307 0.0706 0.3287 0.102 Uiso 1 1 calc R
C6 C 0.8701(12) 0.1683(15) 0.2711(9) 0.084(5) Uani 1 1 d .
H6 H 0.8932 0.1312 0.2343 0.101 Uiso 1 1 calc R
C7 C 0.8745(12) 0.2615(15) 0.2718(9) 0.087(5) Uani 1 1 d .
H7 H 0.9043 0.2885 0.2358 0.105 Uiso 1 1 calc R
C8 C 0.8356(11) 0.3164(12) 0.3248(9) 0.079(4) Uani 1 1 d .
H8 H 0.8381 0.3792 0.3233 0.095 Uiso 1 1 calc R
C9 C 0.7944(10) 0.2797(9) 0.3782(7) 0.054(3) Uani 1 1 d .
H9 H 0.7694 0.3179 0.4134 0.065 Uiso 1 1 calc R
O2 O 0.2040(6) 0.3092(6) 0.4258(5) 0.060(2) Uani 1 1 d .
O3 O 0.3084(6) 0.3910(6) 0.5297(4) 0.054(2) Uani 1 1 d .
C10 C 0.2188(10) 0.3607(9) 0.4863(7) 0.054(3) Uani 1 1 d .
C11 C 0.1158(11) 0.3916(10) 0.5099(8) 0.067(4) Uani 1 1 d .
C12 C 0.0595(11) 0.3278(13) 0.5500(8) 0.133(9) Uani 1 1 d D
F1 F 0.1354(7) 0.4751(7) 0.5490(6) 0.121(4) Uani 1 1 d .
F2 F 0.0372(6) 0.3925(6) 0.4513(5) 0.090(3) Uani 1 1 d .
F3 F -0.0343(8) 0.3479(11) 0.5664(6) 0.186(7) Uani 1 1 d D
F4 F 0.0360(10) 0.2422(8) 0.5143(8) 0.163(6) Uani 1 1 d D
F5 F 0.1248(9) 0.3265(12) 0.6124(6) 0.203(8) Uani 1 1 d D
O4 O 0.4284(7) 0.5021(6) 0.4240(5) 0.059(2) Uani 1 1 d .
O5 O 0.3763(7) 0.4210(6) 0.3118(4) 0.058(2) Uani 1 1 d .
C13 C 0.3755(11) 0.4851(8) 0.3595(7) 0.047(3) Uani 1 1 d .
C14 C 0.3066(18) 0.5571(13) 0.3345(13) 0.125(9) Uani 1 1 d .
C15 C 0.194(3) 0.5324(12) 0.3251(7) 0.163(12) Uani 1 1 d D
F6 F 0.3368(11) 0.6393(7) 0.3745(8) 0.152(5) Uani 1 1 d .
F7 F 0.305(2) 0.5650(13) 0.2593(9) 0.293(15) Uani 1 1 d .
F8 F 0.1499(11) 0.4501(11) 0.2849(10) 0.245(11) Uani 1 1 d D
F9 F 0.1318(11) 0.5923(9) 0.3024(6) 0.159(5) Uani 1 1 d D
F10 F 0.1816(16) 0.5261(12) 0.3940(10) 0.287(14) Uani 1 1 d D
O6 O 0.5307(8) 0.2878(6) 0.2155(5) 0.069(3) Uani 1 1 d .
O7 O 0.5756(8) 0.1496(6) 0.2141(5) 0.069(3) Uani 1 1 d .
C16 C 0.5622(12) 0.2167(11) 0.1876(7) 0.063(4) Uani 1 1 d .
C17 C 0.608(2) 0.2232(16) 0.1150(10) 0.123(8) Uani 1 1 d .
C18 C 0.538(2) 0.1911(12) 0.0534(16) 0.207(17) Uani 1 1 d D
F11 F 0.7027(9) 0.1791(10) 0.1083(6) 0.132(4) Uani 1 1 d .
F12 F 0.6567(12) 0.3156(8) 0.1124(7) 0.160(6) Uani 1 1 d .
F13 F 0.5038(12) 0.0988(8) 0.0558(7) 0.165(6) Uani 1 1 d D
F14 F 0.5835(14) 0.2015(9) -0.0082(6) 0.195(7) Uani 1 1 d D
F15 F 0.4528(11) 0.2406(11) 0.0568(6) 0.177(6) Uani 1 1 d D
O8 O 0.5595(9) -0.0119(6) 0.3196(5) 0.074(3) Uani 1 1 d .
O9 O 0.5389(8) -0.0341(6) 0.4323(5) 0.064(2) Uani 1 1 d .
C19 C 0.5667(12) -0.0544(9) 0.3723(7) 0.060(4) Uani 1 1 d D
C20 C 0.6375(19) -0.1357(15) 0.3650(9) 0.21(2) Uani 1 1 d D
C21 C 0.572(2) -0.220(3) 0.3331(11) 0.25(2) Uani 1 1 d D
F16 F 0.7027(18) -0.1384(14) 0.4318(7) 0.246(11) Uani 1 1 d D
F17 F 0.7216(11) -0.1207(10) 0.3257(9) 0.164(5) Uani 1 1 d D
F18 F 0.509(2) -0.2233(11) 0.3807(14) 0.36(2) Uani 1 1 d D
F19 F 0.634(3) -0.2814(16) 0.3322(11) 0.52(3) Uani 1 1 d D
F20 F 0.5231(17) -0.2100(9) 0.2704(10) 0.220(10) Uani 1 1 d D
O10 O 0.3174(8) 0.0798(7) 0.2259(6) 0.078(3) Uani 1 1 d .
O11 O 0.3653(9) -0.0401(8) 0.1630(7) 0.108(4) Uani 1 1 d .
C22 C 0.3041(12) 0.0154(12) 0.1746(9) 0.072(4) Uani 1 1 d .
C23 C 0.1951(18) -0.0045(13) 0.1209(12) 0.100(6) Uani 1 1 d .
C24 C 0.2001(12) 0.0036(11) 0.0492(16) 0.182(15) Uani 1 1 d D
F21 F 0.1427(10) -0.0966(9) 0.1123(9) 0.176(6) Uani 1 1 d .
F22 F 0.1162(9) 0.0366(10) 0.1459(7) 0.145(5) Uani 1 1 d .
F23 F 0.2713(15) -0.0384(15) 0.0192(8) 0.266(13) Uani 1 1 d D
F24 F 0.1053(11) -0.0149(11) 0.0019(8) 0.203(7) Uani 1 1 d D
F25 F 0.2359(13) 0.0934(12) 0.0582(11) 0.254(12) Uani 1 1 d D
O12 O 0.1825(7) 0.1087(6) 0.3728(5) 0.062(2) Uani 1 1 d .
O13 O 0.2682(8) -0.0030(7) 0.4083(7) 0.090(4) Uani 1 1 d .
C25 C 0.1877(11) 0.0271(10) 0.3821(9) 0.068(4) Uani 1 1 d .
C26 C 0.0780(19) -0.0415(15) 0.3608(17) 0.135(10) Uani 1 1 d .
C27 C 0.0779(11) -0.131(3) 0.3251(13) 0.180(16) Uani 1 1 d D
F26 F 0.0253(16) -0.0471(17) 0.4158(11) 0.322(19) Uani 1 1 d .
F27 F 0.0104(9) -0.0140(8) 0.2981(11) 0.194(8) Uani 1 1 d .
F28 F 0.1324(13) -0.1226(12) 0.2698(9) 0.214(8) Uani 1 1 d D
F29 F 0.1316(13) -0.1759(14) 0.3729(12) 0.294(16) Uani 1 1 d D
F30 F -0.0253(12) -0.1792(11) 0.2991(9) 0.243(11) Uani 1 1 d D
O14 O 0.5742(8) 0.5054(6) 0.1961(5) 0.070(3) Uani 1 1 d .
O15 O 0.5677(7) 0.5139(7) 0.0793(5) 0.075(3) Uani 1 1 d .
C28 C 0.6089(11) 0.5303(9) 0.1437(7) 0.058(4) Uani 1 1 d .
C29 C 0.7232(14) 0.5970(13) 0.1648(9) 0.083(5) Uani 1 1 d .
C30 C 0.8206(17) 0.5527(12) 0.1622(6) 0.126(8) Uani 1 1 d D
F31 F 0.7416(11) 0.6453(9) 0.2367(7) 0.164(6) Uani 1 1 d .
F32 F 0.7271(9) 0.6606(7) 0.1210(7) 0.130(4) Uani 1 1 d .
F33 F 0.8207(9) 0.4909(9) 0.2060(7) 0.160(6) Uani 1 1 d D
F34 F 0.8075(9) 0.5117(9) 0.0935(6) 0.141(5) Uani 1 1 d D
F35 F 0.9141(9) 0.6129(9) 0.1807(7) 0.177(6) Uani 1 1 d D
O16 O 0.2429(7) 0.3330(7) 0.1502(5) 0.068(3) Uani 1 1 d .
O17 O 0.2286(8) 0.3451(8) 0.0334(5) 0.088(3) Uani 1 1 d .
C31 C 0.1938(11) 0.3255(9) 0.0887(8) 0.060(3) Uani 1 1 d .
C32 C 0.0659(12) 0.2873(12) 0.0736(8) 0.072(4) Uani 1 1 d .
C33 C -0.0110(13) 0.3540(15) 0.0566(9) 0.151(11) Uani 1 1 d D
F36 F 0.0392(8) 0.2503(10) 0.1278(7) 0.155(6) Uani 1 1 d .
F37 F 0.0380(9) 0.2205(10) 0.0181(9) 0.178(7) Uani 1 1 d .
F38 F 0.0061(13) 0.3772(16) -0.0033(12) 0.36(2) Uani 1 1 d D
F39 F -0.1110(8) 0.3174(10) 0.0527(8) 0.162(5) Uani 1 1 d D
F40 F 0.0214(12) 0.4208(13) 0.1095(12) 0.312(17) Uani 1 1 d D
N1 N 0.314(2) 0.5883(16) 0.0865(12) 0.163(9) Uani 1 1 d .
C34 C 0.287(2) 0.6446(17) 0.1143(12) 0.118(7) Uani 1 1 d .
C35 C 0.241(3) 0.7229(17) 0.1463(15) 0.205(15) Uani 1 1 d .
H35A H 0.1747 0.7288 0.1138 0.308 Uiso 1 1 calc R
H35B H 0.2945 0.7787 0.1532 0.308 Uiso 1 1 calc R
H35C H 0.2231 0.7126 0.1928 0.308 Uiso 1 1 calc R
N2 N 0.6890(13) -0.0742(10) 0.1489(8) 0.099(5) Uani 1 1 d .
C36 C 0.7598(14) -0.1031(10) 0.1362(8) 0.069(4) Uani 1 1 d .
C37 C 0.8589(15) -0.1460(13) 0.1174(11) 0.109(6) Uani 1 1 d .
H37A H 0.9180 -0.0979 0.1140 0.164 Uiso 1 1 calc R
H37B H 0.8366 -0.1873 0.0712 0.164 Uiso 1 1 calc R
H37C H 0.8844 -0.1797 0.1551 0.164 Uiso 1 1 calc R
O1W O 0.2121(6) 0.2284(5) 0.2681(4) 0.053(2) Uani 1 1 d .
H1WA H 0.2091 0.1816 0.2354 0.063 Uiso 1 1 d R
H1WB H 0.2231 0.2785 0.2511 0.063 Uiso 1 1 d R
O2W O 0.6491(7) 0.4677(6) 0.3402(4) 0.063(2) Uani 1 1 d .
H2WB H 0.6435 0.5081 0.3757 0.076 Uiso 1 1 d R
H2WA H 0.6340 0.4867 0.3014 0.076 Uiso 1 1 d R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C1 Ag1 O2 130.7(3) . .
C1 Ag1 O12 132.4(4) . .
O2 Ag1 O12 77.8(3) . .
C1 Ag1 O1W 139.6(3) . .
O2 Ag1 O1W 79.0(3) . .
O12 Ag1 O1W 72.9(3) . .
C1 Ag1 Ag2 52.5(3) . .
O2 Ag1 Ag2 79.46(19) . .
O12 Ag1 Ag2 141.5(2) . .
O1W Ag1 Ag2 131.85(18) . .
C1 Ag1 Ag5 55.5(3) . .
O2 Ag1 Ag5 126.5(2) . .
O12 Ag1 Ag5 77.0(2) . .
O1W Ag1 Ag5 134.52(19) . .
Ag2 Ag1 Ag5 92.43(4) . .
C1 Ag1 Ag3 51.2(3) . .
O2 Ag1 Ag3 118.7(2) . .
O12 Ag1 Ag3 156.2(2) . .
O1W Ag1 Ag3 92.65(18) . .
Ag2 Ag1 Ag3 61.91(4) . .
Ag5 Ag1 Ag3 102.24(4) . .
C1 Ag1 Ag4 55.9(3) . .
O2 Ag1 Ag4 172.5(2) . .
O12 Ag1 Ag4 99.9(2) . .
O1W Ag1 Ag4 93.49(19) . .
Ag2 Ag1 Ag4 106.05(4) . .
Ag5 Ag1 Ag4 59.09(3) . .
Ag3 Ag1 Ag4 61.41(4) . .
C1 Ag2 O4 137.6(4) . 2_666
C1 Ag2 O3 125.9(3) . .
O4 Ag2 O3 89.9(3) 2_666 .
C1 Ag2 O4 122.7(3) . .
O4 Ag2 O4 80.4(3) 2_666 .
O3 Ag2 O4 81.0(3) . .
C1 Ag2 Ag1 49.1(3) . .
O4 Ag2 Ag1 173.1(2) 2_666 .
O3 Ag2 Ag1 83.4(2) . .
O4 Ag2 Ag1 96.74(19) . .
C1 Ag2 Ag3 50.2(3) . .
O4 Ag2 Ag3 123.9(2) 2_666 .
O3 Ag2 Ag3 132.16(19) . .
O4 Ag2 Ag3 73.8(2) . .
Ag1 Ag2 Ag3 60.62(3) . .
C1 Ag3 O6 128.7(4) . .
C1 Ag3 O2W 130.4(4) . .
O6 Ag3 O2W 89.1(3) . .
C1 Ag3 O5 117.4(3) . .
O6 Ag3 O5 92.9(3) . .
O2W Ag3 O5 86.1(3) . .
C1 Ag3 Ag1 47.6(3) . .
O6 Ag3 Ag1 112.9(2) . .
O2W Ag3 Ag1 151.9(2) . .
O5 Ag3 Ag1 76.0(2) . .
C1 Ag3 Ag2 49.7(3) . .
O6 Ag3 Ag2 169.3(3) . .
O2W Ag3 Ag2 98.8(2) . .
O5 Ag3 Ag2 80.65(19) . .
Ag1 Ag3 Ag2 57.47(3) . .
C1 Ag3 Ag4 54.3(3) . .
O6 Ag3 Ag4 74.7(2) . .
O2W Ag3 Ag4 147.2(2) . .
O5 Ag3 Ag4 122.4(2) . .
Ag1 Ag3 Ag4 59.65(3) . .
Ag2 Ag3 Ag4 101.52(4) . .
O8 Ag4 O7 90.1(3) . .
O8 Ag4 O10 106.0(3) . .
O7 Ag4 O10 87.8(4) . .
O8 Ag4 C1 117.5(3) . .
O7 Ag4 C1 122.9(3) . .
O10 Ag4 C1 124.6(4) . .
O8 Ag4 Ag5 80.1(2) . .
O7 Ag4 Ag5 164.3(3) . .
O10 Ag4 Ag5 106.6(3) . .
C1 Ag4 Ag5 53.7(2) . .
O8 Ag4 Ag1 138.7(2) . .
O7 Ag4 Ag1 131.2(2) . .
O10 Ag4 Ag1 78.3(2) . .
C1 Ag4 Ag1 46.4(3) . .
Ag5 Ag4 Ag1 59.94(3) . .
O8 Ag4 Ag3 147.5(3) . .
O7 Ag4 Ag3 80.7(2) . .
O10 Ag4 Ag3 104.8(3) . .
C1 Ag4 Ag3 48.6(2) . .
Ag5 Ag4 Ag3 101.08(4) . .
Ag1 Ag4 Ag3 58.95(3) . .
O8 Ag4 Ag9 49.5(2) . .
O7 Ag4 Ag9 49.3(2) . .
O10 Ag4 Ag9 77.2(2) . .
C1 Ag4 Ag9 158.1(3) . .
Ag5 Ag4 Ag9 126.78(5) . .
Ag1 Ag4 Ag9 155.48(5) . .
Ag3 Ag4 Ag9 129.97(5) . .
O13 Ag5 O9 95.7(4) . .
O13 Ag5 O9 95.2(4) . 2_656
O9 Ag5 O9 76.7(3) . 2_656
O13 Ag5 C1 130.9(4) . .
O9 Ag5 C1 116.8(3) . .
O9 Ag5 C1 126.1(3) 2_656 .
O13 Ag5 C2 156.5(4) . .
O9 Ag5 C2 94.2(4) . .
O9 Ag5 C2 107.8(3) 2_656 .
C1 Ag5 C2 27.7(4) . .
O13 Ag5 Ag4 97.5(3) . .
O9 Ag5 Ag4 83.47(19) . .
O9 Ag5 Ag4 157.4(2) 2_656 .
C1 Ag5 Ag4 54.9(3) . .
C2 Ag5 Ag4 62.5(3) . .
O13 Ag5 Ag1 84.9(3) . .
O9 Ag5 Ag1 144.1(2) . .
O9 Ag5 Ag1 139.1(2) 2_656 .
C1 Ag5 Ag1 47.0(3) . .
C2 Ag5 Ag1 74.7(3) . .
Ag4 Ag5 Ag1 60.96(3) . .
C6 Ag6 O2 155.7(5) 1_455 .
C6 Ag6 O1W 120.4(5) 1_455 .
O2 Ag6 O1W 77.8(3) . .
C6 Ag6 O12 124.5(6) 1_455 .
O2 Ag6 O12 74.9(3) . .
O1W Ag6 O12 70.5(3) . .
C6 Ag6 C7 31.6(5) 1_455 1_455
O2 Ag6 C7 128.6(5) . 1_455
O1W Ag6 C7 115.5(4) . 1_455
O12 Ag6 C7 156.0(5) . 1_455
O16 Ag7 O14 168.8(3) . .
O16 Ag7 O6 104.4(3) . .
O14 Ag7 O6 86.4(3) . .
O16 Ag7 Ag8 85.9(2) . .
O14 Ag7 Ag8 85.4(2) . .
O6 Ag7 Ag8 125.7(2) . .
N1 Ag8 O17 102.0(8) . .
N1 Ag8 O15 96.9(7) . .
O17 Ag8 O15 144.2(4) . .
N1 Ag8 O15 110.0(6) . 2_665
O17 Ag8 O15 119.9(3) . 2_665
O15 Ag8 O15 80.3(3) . 2_665
N1 Ag8 Ag7 88.2(6) . .
O17 Ag8 Ag7 75.0(2) . .
O15 Ag8 Ag7 75.5(2) . .
O15 Ag8 Ag7 151.3(2) 2_665 .
N2 Ag9 O11 146.9(5) . .
N2 Ag9 O7 114.4(5) . .
O11 Ag9 O7 91.8(4) . .
N2 Ag9 O8 112.3(5) . .
O11 Ag9 O8 90.4(4) . .
O7 Ag9 O8 81.3(3) . .
N2 Ag9 Ag4 141.0(4) . .
O11 Ag9 Ag4 71.9(3) . .
O7 Ag9 Ag4 44.51(19) . .
O8 Ag9 Ag4 44.2(2) . .
C2 C1 Ag1 155.1(10) . .
C2 C1 Ag2 116.7(10) . .
Ag1 C1 Ag2 78.4(4) . .
C2 C1 Ag3 119.5(9) . .
Ag1 C1 Ag3 81.2(4) . .
Ag2 C1 Ag3 80.1(4) . .
C2 C1 Ag5 77.6(8) . .
Ag1 C1 Ag5 77.5(3) . .
Ag2 C1 Ag5 121.6(4) . .
Ag3 C1 Ag5 145.0(5) . .
C2 C1 Ag4 92.8(9) . .
Ag1 C1 Ag4 77.7(4) . .
Ag2 C1 Ag4 149.1(5) . .
Ag3 C1 Ag4 77.1(3) . .
Ag5 C1 Ag4 71.4(3) . .
C1 C2 C3 171.3(14) . .
C1 C2 Ag5 74.7(8) . .
C3 C2 Ag5 113.7(9) . .
O1 C3 C2 110.5(11) . .
O1 C3 H3A 109.5 . .
C2 C3 H3A 109.5 . .
O1 C3 H3B 109.5 . .
C2 C3 H3B 109.5 . .
H3A C3 H3B 108.1 . .
C4 O1 C3 118.9(12) . .
C9 C4 O1 127.8(15) . .
C9 C4 C5 116.6(15) . .
O1 C4 C5 115.5(15) . .
C6 C5 C4 122.0(16) . .
C6 C5 H5 119.0 . .
C4 C5 H5 119.0 . .
C5 C6 C7 117.2(17) . .
C5 C6 Ag6 95.8(10) . 1_655
C7 C6 Ag6 83.2(10) . 1_655
C5 C6 H6 121.4 . .
C7 C6 H6 121.4 . .
Ag6 C6 H6 90.9 1_655 .
C6 C7 C8 121.6(16) . .
C6 C7 Ag6 65.2(9) . 1_655
C8 C7 Ag6 107.5(10) . 1_655
C6 C7 H7 119.2 . .
C8 C7 H7 119.2 . .
Ag6 C7 H7 97.0 1_655 .
C9 C8 C7 120.5(17) . .
C9 C8 H8 119.8 . .
C7 C8 H8 119.8 . .
C8 C9 C4 122.0(15) . .
C8 C9 H9 119.0 . .
C4 C9 H9 119.0 . .
C10 O2 Ag1 124.8(8) . .
C10 O2 Ag6 139.8(8) . .
Ag1 O2 Ag6 92.2(3) . .
C10 O3 Ag2 118.3(8) . .
O2 C10 O3 127.4(12) . .
O2 C10 C11 116.7(11) . .
O3 C10 C11 116.0(12) . .
F1 C11 F2 106.3(13) . .
F1 C11 C12 108.5(13) . .
F2 C11 C12 103.2(10) . .
F1 C11 C10 113.8(11) . .
F2 C11 C10 111.2(12) . .
C12 C11 C10 113.2(12) . .
F5 C12 F3 106.5(12) . .
F5 C12 F4 106.5(13) . .
F3 C12 F4 106.1(13) . .
F5 C12 C11 109.5(14) . .
F3 C12 C11 115.2(15) . .
F4 C12 C11 112.5(13) . .
C13 O4 Ag2 140.1(7) . 2_666
C13 O4 Ag2 120.0(7) . .
Ag2 O4 Ag2 99.6(3) 2_666 .
C13 O5 Ag3 115.1(8) . .
O5 C13 O4 128.1(11) . .
O5 C13 C14 114.7(13) . .
O4 C13 C14 117.1(12) . .
F6 C14 C15 109.0(18) . .
F6 C14 F7 109(2) . .
C15 C14 F7 93.9(16) . .
F6 C14 C13 114.3(13) . .
C15 C14 C13 116.1(18) . .
F7 C14 C13 112.6(17) . .
F8 C15 F9 106.9(17) . .
F8 C15 F10 106.3(17) . .
F9 C15 F10 106.7(16) . .
F8 C15 C14 116.6(18) . .
F9 C15 C14 118(2) . .
F10 C15 C14 101(2) . .
C16 O6 Ag3 126.1(8) . .
C16 O6 Ag7 140.4(9) . .
Ag3 O6 Ag7 91.9(3) . .
C16 O7 Ag4 117.3(9) . .
C16 O7 Ag9 141.8(9) . .
Ag4 O7 Ag9 86.2(3) . .
O7 C16 O6 127.9(12) . .
O7 C16 C17 115.4(15) . .
O6 C16 C17 115.8(14) . .
C18 C17 F12 108.0(16) . .
C18 C17 F11 104.5(15) . .
F12 C17 F11 99(2) . .
C18 C17 C16 117(2) . .
F12 C17 C16 111.6(16) . .
F11 C17 C16 115.2(16) . .
C17 C18 F15 104(2) . .
C17 C18 F13 105(2) . .
F15 C18 F13 111.5(16) . .
C17 C18 F14 114(2) . .
F15 C18 F14 110.9(15) . .
F13 C18 F14 111.2(15) . .
C19 O8 Ag4 126.6(8) . .
C19 O8 Ag9 144.9(8) . .
Ag4 O8 Ag9 86.3(3) . .
C19 O9 Ag5 120.5(7) . .
C19 O9 Ag5 136.2(8) . 2_656
Ag5 O9 Ag5 103.3(3) . 2_656
O9 C19 O8 128.2(12) . .
O9 C19 C20 116.8(11) . .
O8 C19 C20 114.2(12) . .
F17 C20 C21 107.6(16) . .
F17 C20 F16 98.1(18) . .
C21 C20 F16 113.0(16) . .
F17 C20 C19 114.4(14) . .
C21 C20 C19 112.2(16) . .
F16 C20 C19 110.8(14) . .
F20 C21 F19 114.9(18) . .
F20 C21 F18 114.1(17) . .
F19 C21 F18 114.5(18) . .
F20 C21 C20 107(2) . .
F19 C21 C20 108(3) . .
F18 C21 C20 97(2) . .
C22 O10 Ag4 121.8(10) . .
C22 O11 Ag9 132.0(11) . .
O11 C22 O10 128.5(15) . .
O11 C22 C23 113.8(16) . .
O10 C22 C23 117.6(16) . .
F22 C23 C24 113.0(16) . .
F22 C23 F21 98.7(18) . .
C24 C23 F21 100.9(17) . .
F22 C23 C22 113.2(16) . .
C24 C23 C22 116.7(18) . .
F21 C23 C22 112.2(15) . .
F23 C24 F24 107.6(17) . .
F23 C24 F25 107.9(17) . .
F24 C24 F25 107.3(16) . .
F23 C24 C23 117.0(19) . .
F24 C24 C23 117(2) . .
F25 C24 C23 99.1(18) . .
C25 O12 Ag1 125.5(8) . .
C25 O12 Ag6 144.8(8) . .
Ag1 O12 Ag6 89.6(3) . .
C25 O13 Ag5 122.8(9) . .
O13 C25 O12 127.8(12) . .
O13 C25 C26 116.1(14) . .
O12 C25 C26 116.0(14) . .
F26 C26 C27 109(2) . .
F26 C26 F27 112(2) . .
C27 C26 F27 95.4(19) . .
F26 C26 C25 113(2) . .
C27 C26 C25 119(2) . .
F27 C26 C25 107.7(16) . .
F29 C27 F28 110(2) . .
F29 C27 F30 109.2(19) . .
F28 C27 F30 110(2) . .
F29 C27 C26 108(2) . .
F28 C27 C26 107(3) . .
F30 C27 C26 113(2) . .
C28 O14 Ag7 119.9(8) . .
C28 O15 Ag8 123.1(8) . .
C28 O15 Ag8 136.6(8) . 2_665
Ag8 O15 Ag8 99.7(3) . 2_665
O15 C28 O14 130.4(12) . .
O15 C28 C29 115.7(11) . .
O14 C28 C29 113.8(12) . .
F32 C29 F31 106.6(15) . .
F32 C29 C30 107.7(13) . .
F31 C29 C30 104.2(14) . .
F32 C29 C28 110.3(13) . .
F31 C29 C28 112.1(13) . .
C30 C29 C28 115.4(14) . .
F33 C30 F34 110.2(13) . .
F33 C30 F35 110.0(13) . .
F34 C30 F35 110.5(13) . .
F33 C30 C29 109.3(15) . .
F34 C30 C29 104.7(15) . .
F35 C30 C29 112.2(17) . .
C31 O16 Ag7 118.5(8) . .
C31 O17 Ag8 124.8(9) . .
O16 C31 O17 129.5(13) . .
O16 C31 C32 117.0(12) . .
O17 C31 C32 113.5(13) . .
F36 C32 F37 104.4(15) . .
F36 C32 C33 108.3(14) . .
F37 C32 C33 104.5(13) . .
F36 C32 C31 110.4(12) . .
F37 C32 C31 111.2(13) . .
C33 C32 C31 117.3(12) . .
F38 C33 F39 111.9(13) . .
F38 C33 F40 111.8(14) . .
F39 C33 F40 112.1(13) . .
F38 C33 C32 106.0(17) . .
F39 C33 C32 111.1(17) . .
F40 C33 C32 103.5(16) . .
C34 N1 Ag8 175(3) . .
N1 C34 C35 174(3) . .
C34 C35 H35A 109.5 . .
C34 C35 H35B 109.5 . .
H35A C35 H35B 109.5 . .
C34 C35 H35C 109.5 . .
H35A C35 H35C 109.5 . .
H35B C35 H35C 109.5 . .
C36 N2 Ag9 174.6(15) . .
N2 C36 C37 178.9(19) . .
C36 C37 H37A 109.5 . .
C36 C37 H37B 109.5 . .
H37A C37 H37B 109.5 . .
C36 C37 H37C 109.5 . .
H37A C37 H37C 109.5 . .
H37B C37 H37C 109.5 . .
Ag1 O1W Ag6 87.6(2) . .
Ag1 O1W H1WA 113.9 . .
Ag6 O1W H1WA 113.9 . .
Ag1 O1W H1WB 114.1 . .
Ag6 O1W H1WB 114.1 . .
H1WA O1W H1WB 111.4 . .
Ag3 O2W H2WB 109.3 . .
Ag3 O2W H2WA 109.7 . .
H2WB O2W H2WA 109.8 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 C1 2.185(12) .
Ag1 O2 2.344(8) .
Ag1 O12 2.361(8) .
Ag1 O1W 2.450(7) .
Ag1 Ag2 2.8307(13) .
Ag1 Ag5 2.9174(14) .
Ag1 Ag3 2.9258(14) .
Ag1 Ag4 2.9471(15) .
Ag2 C1 2.292(11) .
Ag2 O4 2.326(8) 2_666
Ag2 O3 2.379(8) .
Ag2 O4 2.489(8) .
Ag2 Ag3 2.9620(15) .
Ag3 C1 2.309(11) .
Ag3 O6 2.319(9) .
Ag3 O2W 2.339(8) .
Ag3 O5 2.471(9) .
Ag3 Ag4 2.9987(15) .
Ag4 O8 2.338(9) .
Ag4 O7 2.351(8) .
Ag4 O10 2.361(10) .
Ag4 C1 2.497(11) .
Ag4 Ag5 2.8921(14) .
Ag4 Ag9 3.3465(16) .
Ag5 O13 2.237(9) .
Ag5 O9 2.369(9) .
Ag5 O9 2.398(8) 2_656
Ag5 C1 2.461(11) .
Ag5 C2 2.492(12) .
Ag6 C6 2.378(14) 1_455
Ag6 O2 2.384(8) .
Ag6 O1W 2.473(8) .
Ag6 O12 2.476(9) .
Ag6 C7 2.602(16) 1_455
Ag7 O16 2.199(8) .
Ag7 O14 2.209(9) .
Ag7 O6 2.556(9) .
Ag7 Ag8 2.8947(15) .
Ag8 N1 2.29(2) .
Ag8 O17 2.286(10) .
Ag8 O15 2.385(9) .
Ag8 O15 2.425(8) 2_665
Ag9 N2 2.095(13) .
Ag9 O11 2.245(11) .
Ag9 O7 2.543(9) .
Ag9 O8 2.550(9) .
C1 C2 1.185(15) .
C2 C3 1.474(17) .
C3 O1 1.440(18) .
C3 H3A 0.9700 .
C3 H3B 0.9700 .
O1 C4 1.360(17) .
C4 C9 1.344(19) .
C4 C5 1.47(2) .
C5 C6 1.35(2) .
C5 H5 0.9300 .
C6 C7 1.37(2) .
C6 Ag6 2.378(14) 1_655
C6 H6 0.9300 .
C7 C8 1.39(2) .
C7 Ag6 2.602(16) 1_655
C7 H7 0.9300 .
C8 C9 1.340(18) .
C8 H8 0.9300 .
C9 H9 0.9300 .
O2 C10 1.244(14) .
O3 C10 1.244(13) .
C10 C11 1.528(18) .
C11 F1 1.312(15) .
C11 F2 1.346(15) .
C11 C12 1.46(3) .
C12 F5 1.312(11) .
C12 F3 1.313(11) .
C12 F4 1.316(12) .
O4 C13 1.249(13) .
O4 Ag2 2.326(8) 2_666
O5 C13 1.211(13) .
C13 C14 1.54(2) .
C14 F6 1.304(19) .
C14 C15 1.36(3) .
C14 F7 1.43(3) .
C15 F8 1.329(15) .
C15 F9 1.332(14) .
C15 F10 1.341(14) .
O6 C16 1.253(16) .
O7 C16 1.193(15) .
C16 C17 1.57(2) .
C17 C18 1.31(3) .
C17 F12 1.42(2) .
C17 F11 1.44(2) .
C18 F15 1.378(13) .
C18 F13 1.381(13) .
C18 F14 1.382(13) .
O8 C19 1.244(14) .
O9 C19 1.239(15) .
O9 Ag5 2.398(8) 2_656
C19 C20 1.595(16) .
C20 F17 1.381(16) .
C20 C21 1.38(4) .
C20 F16 1.384(17) .
C21 F20 1.269(13) .
C21 F19 1.277(14) .
C21 F18 1.278(13) .
O10 C22 1.227(17) .
O11 C22 1.219(18) .
C22 C23 1.51(2) .
C23 F22 1.34(2) .
C23 C24 1.38(3) .
C23 F21 1.40(2) .
C24 F23 1.306(15) .
C24 F24 1.317(14) .
C24 F25 1.317(14) .
O12 C25 1.255(15) .
O13 C25 1.212(16) .
C25 C26 1.53(2) .
C26 F26 1.31(3) .
C26 C27 1.40(4) .
C26 F27 1.47(3) .
C27 F29 1.335(16) .
C27 F28 1.338(16) .
C27 F30 1.343(16) .
O14 C28 1.216(13) .
O15 C28 1.207(14) .
O15 Ag8 2.425(8) 2_665
C28 C29 1.559(19) .
C29 F32 1.334(17) .
C29 F31 1.399(18) .
C29 C30 1.46(3) .
C30 F33 1.314(11) .
C30 F34 1.316(11) .
C30 F35 1.317(11) .
O16 C31 1.194(15) .
O17 C31 1.239(15) .
C31 C32 1.566(19) .
C32 F36 1.288(16) .
C32 F37 1.294(17) .
C32 C33 1.50(3) .
C33 F38 1.261(12) .
C33 F39 1.263(11) .
C33 F40 1.264(11) .
N1 C34 1.05(3) .
C34 C35 1.46(3) .
C35 H35A 0.9600 .
C35 H35B 0.9600 .
C35 H35C 0.9600 .
N2 C36 1.078(18) .
C36 C37 1.53(2) .
C37 H37A 0.9600 .
C37 H37B 0.9600 .
C37 H37C 0.9600 .
O1W H1WA 0.8499 .
O1W H1WB 0.8500 .
O2W H2WB 0.8501 .
O2W H2WA 0.8199 .
