#------------------------------------------------------------------------------
#$Date: 2016-03-21 07:42:50 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178578 $
#$URL: svn://www.crystallography.net/cod/cif/4/06/88/4068891.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4068891
loop_
_publ_author_name
'Brown, David H.'
'Nealon, Gareth L.'
'Simpson, Peter V.'
'Skelton, Brian W.'
'Wang, Zhisen'
_publ_section_title
;
 Silver and Palladium Complexes of a Bis(benzimidazolin-2-ylidene)pyridine
 Pincer Ligand
;
_journal_issue                   6
_journal_name_full               Organometallics
_journal_page_first              1965
_journal_paper_doi               10.1021/om801144m
_journal_volume                  28
_journal_year                    2009
_chemical_formula_moiety         'C54 H58 Ag2 N10, 2(C24 H20 B)'
_chemical_formula_sum            'C102 H98 Ag2 B2 N10'
_chemical_formula_weight         1701.26
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-I 2ya'
_symmetry_space_group_name_H-M   'I 1 2/a 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_date             2008-09-03T10:37:20-00:00
_audit_creation_method           'WinGX routine CIF_UPDATE'
_cell_angle_alpha                90
_cell_angle_beta                 104.162(4)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   24.0034(13)
_cell_length_b                   17.3322(5)
_cell_length_c                   20.4685(7)
_cell_measurement_reflns_used    5922
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      34.7468
_cell_measurement_theta_min      3.3951
_cell_volume                     8256.7(6)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.947
_diffrn_measurement_device_type
;
 Oxford Diffraction Gemini diffractometer
;
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0429
_diffrn_reflns_av_unetI/netI     0.0501
_diffrn_reflns_limit_h_max       31
_diffrn_reflns_limit_h_min       -38
_diffrn_reflns_limit_k_max       24
_diffrn_reflns_limit_k_min       -27
_diffrn_reflns_limit_l_max       32
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_number            61107
_diffrn_reflns_theta_full        32.5
_diffrn_reflns_theta_max         34.88
_diffrn_reflns_theta_min         3.3
_exptl_absorpt_coefficient_mu    .531
_exptl_absorpt_correction_T_max  1
_exptl_absorpt_correction_T_min  0.810
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
        CrysAlis RED, Oxford Diffraction Ltd.,
        Version 1.171.32.15 (release 10-01-2008 CrysAlis171 .NET)
        (compiled Jan 10 2008,16:37:18)
        Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.369
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             3536
_exptl_crystal_size_max          .41
_exptl_crystal_size_mid          .33
_exptl_crystal_size_min          .30
_refine_diff_density_max         2.022
_refine_diff_density_min         -0.461
_refine_diff_density_rms         0.096
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.957
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     525
_refine_ls_number_reflns         17061
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.957
_refine_ls_R_factor_all          0.0624
_refine_ls_R_factor_gt           0.0377
_refine_ls_shift/su_max          0.008
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0604P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0928
_refine_ls_wR_factor_ref         0.1006
_reflns_number_gt                12189
_reflns_number_total             17061
_reflns_threshold_expression     I>2sigma(I)
_cod_data_source_file            om801144m_si_001.cif
_cod_data_source_block           zwb002
_cod_original_sg_symbol_H-M      I2/a
_cod_database_code               4068891
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y, -z'
'x+1/2, y+1/2, z+1/2'
'-x+1, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y, z'
'-x+1/2, -y+1/2, -z+1/2'
'x, -y+1/2, z+1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag 0.177448(5) 0.062167(6) 0.437441(5) 0.01494(3) Uani 1 1 d .
N11 N 0.17828(5) 0.23473(7) 0.39572(6) 0.0143(2) Uani 1 1 d .
C12 C 0.20051(6) 0.16356(8) 0.39514(7) 0.0136(2) Uani 1 1 d .
N13 N 0.24879(5) 0.17281(6) 0.37160(6) 0.0133(2) Uani 1 1 d .
C13A C 0.25751(6) 0.25095(8) 0.35842(7) 0.0129(2) Uani 1 1 d .
C14 C 0.30145(6) 0.28974(8) 0.33879(7) 0.0153(3) Uani 1 1 d .
H14 H 0.332 0.2629 0.3268 0.018 Uiso 1 1 calc R
C15 C 0.29850(7) 0.36979(8) 0.33764(8) 0.0185(3) Uani 1 1 d .
H15 H 0.3279 0.3984 0.3249 0.022 Uiso 1 1 calc R
C16 C 0.25315(7) 0.40938(9) 0.35491(8) 0.0195(3) Uani 1 1 d .
H16 H 0.2527 0.4642 0.3537 0.023 Uiso 1 1 calc R
C17 C 0.20907(7) 0.37070(8) 0.37359(8) 0.0176(3) Uani 1 1 d .
H17 H 0.1781 0.3975 0.3848 0.021 Uiso 1 1 calc R
C17A C 0.21235(6) 0.29029(8) 0.37515(7) 0.0138(2) Uani 1 1 d .
C1 C 0.12600(6) 0.25265(9) 0.41776(7) 0.0161(3) Uani 1 1 d .
H1A H 0.0992 0.2085 0.4072 0.019 Uiso 1 1 calc R
H1B H 0.1069 0.298 0.3925 0.019 Uiso 1 1 calc R
C2 C 0.13893(7) 0.26952(9) 0.49325(8) 0.0185(3) Uani 1 1 d .
H2A H 0.1733 0.3029 0.5061 0.022 Uiso 1 1 calc R
H2B H 0.1476 0.2205 0.5185 0.022 Uiso 1 1 calc R
C3 C 0.08856(7) 0.30930(9) 0.51278(8) 0.0205(3) Uani 1 1 d .
H3A H 0.0523 0.2838 0.4891 0.025 Uiso 1 1 calc R
H3B H 0.0927 0.303 0.5618 0.025 Uiso 1 1 calc R
C4 C 0.08472(9) 0.39457(10) 0.49568(10) 0.0303(4) Uani 1 1 d .
H4A H 0.1199 0.4205 0.5202 0.045 Uiso 1 1 calc R
H4B H 0.0516 0.4171 0.5087 0.045 Uiso 1 1 calc R
H4C H 0.0802 0.4012 0.4471 0.045 Uiso 1 1 calc R
C5 C 0.36049(6) -0.12028(9) 0.62736(7) 0.0159(3) Uani 1 1 d .
H5A H 0.3734 -0.0707 0.6501 0.019 Uiso 1 1 calc R
H5B H 0.3909 -0.1591 0.644 0.019 Uiso 1 1 calc R
C6 C 0.30547(7) -0.14574(9) 0.64457(8) 0.0183(3) Uani 1 1 d .
H6A H 0.2953 -0.1982 0.6264 0.022 Uiso 1 1 calc R
H6B H 0.274 -0.1105 0.6227 0.022 Uiso 1 1 calc R
C7 C 0.31074(8) -0.14634(10) 0.72048(8) 0.0223(3) Uani 1 1 d .
H7A H 0.2793 -0.1781 0.73 0.027 Uiso 1 1 calc R
H7B H 0.3476 -0.1708 0.7434 0.027 Uiso 1 1 calc R
C8 C 0.30804(9) -0.06569(10) 0.74937(9) 0.0277(4) Uani 1 1 d .
H8A H 0.3396 -0.0343 0.741 0.042 Uiso 1 1 calc R
H8B H 0.3116 -0.0693 0.798 0.042 Uiso 1 1 calc R
H8C H 0.2712 -0.0416 0.7276 0.042 Uiso 1 1 calc R
N21 N 0.29422(5) 0.05666(6) 0.41090(6) 0.0127(2) Uani 1 1 d .
C22 C 0.28547(6) 0.11078(8) 0.36304(7) 0.0127(2) Uani 1 1 d .
C23 C 0.30847(6) 0.10868(8) 0.30735(7) 0.0150(3) Uani 1 1 d .
H23 H 0.2996 0.1475 0.2736 0.018 Uiso 1 1 calc R
C24 C 0.34496(7) 0.04798(8) 0.30229(8) 0.0161(3) Uani 1 1 d .
H24 H 0.3616 0.0447 0.2648 0.019 Uiso 1 1 calc R
C25 C 0.35685(6) -0.00777(8) 0.35247(7) 0.0148(3) Uani 1 1 d .
H25 H 0.3831 -0.0485 0.3515 0.018 Uiso 1 1 calc R
C26 C 0.32891(6) -0.00169(8) 0.40426(7) 0.0129(2) Uani 1 1 d .
N31 N 0.35186(5) -0.11091(7) 0.55421(6) 0.0138(2) Uani 1 1 d .
C32 C 0.34180(6) -0.04277(8) 0.52207(7) 0.0135(2) Uani 1 1 d .
N33 N 0.33701(5) -0.05879(6) 0.45539(6) 0.0126(2) Uani 1 1 d .
C33A C 0.34227(6) -0.13833(8) 0.44530(7) 0.0128(2) Uani 1 1 d .
C34 C 0.33657(6) -0.18335(8) 0.38755(7) 0.0152(3) Uani 1 1 d .
H34 H 0.3302 -0.161 0.344 0.018 Uiso 1 1 calc R
C35 C 0.34073(6) -0.26255(8) 0.39718(8) 0.0168(3) Uani 1 1 d .
H35 H 0.3372 -0.2953 0.3592 0.02 Uiso 1 1 calc R
C36 C 0.34994(7) -0.29571(8) 0.46143(8) 0.0178(3) Uani 1 1 d .
H36 H 0.353 -0.3502 0.4658 0.021 Uiso 1 1 calc R
C37 C 0.35465(6) -0.25128(8) 0.51866(8) 0.0164(3) Uani 1 1 d .
H37 H 0.36 -0.2738 0.5621 0.02 Uiso 1 1 calc R
C37A C 0.35105(6) -0.17145(8) 0.50901(7) 0.0133(2) Uani 1 1 d .
B1 B 0.97615(7) 0.08962(10) 0.21944(9) 0.0152(3) Uani 1 1 d .
C111 C 0.98659(6) 0.08965(9) 0.30217(8) 0.0163(3) Uani 1 1 d .
C112 C 0.97290(7) 0.15498(9) 0.33661(8) 0.0174(3) Uani 1 1 d .
H112 H 0.9571 0.1989 0.3109 0.021 Uiso 1 1 calc R
C113 C 0.98134(7) 0.15823(10) 0.40609(8) 0.0211(3) Uani 1 1 d .
H113 H 0.9708 0.2033 0.4265 0.025 Uiso 1 1 calc R
C114 C 1.00515(7) 0.09585(11) 0.44597(9) 0.0256(3) Uani 1 1 d .
H114 H 1.0109 0.0976 0.4935 0.031 Uiso 1 1 calc R
C115 C 1.02020(7) 0.03121(11) 0.41464(9) 0.0258(3) Uani 1 1 d .
H115 H 1.0369 -0.0118 0.441 0.031 Uiso 1 1 calc R
C116 C 1.01110(7) 0.02841(9) 0.34468(8) 0.0208(3) Uani 1 1 d .
H116 H 1.022 -0.0169 0.3248 0.025 Uiso 1 1 calc R
C121 C 0.90674(6) 0.09018(8) 0.18127(8) 0.0156(3) Uani 1 1 d .
C122 C 0.86480(7) 0.13113(9) 0.20464(8) 0.0195(3) Uani 1 1 d .
H122 H 0.8759 0.1561 0.2472 0.023 Uiso 1 1 calc R
C123 C 0.80767(7) 0.13667(10) 0.16804(9) 0.0231(3) Uani 1 1 d .
H123 H 0.781 0.1652 0.1859 0.028 Uiso 1 1 calc R
C124 C 0.78949(7) 0.10087(9) 0.10584(9) 0.0238(3) Uani 1 1 d .
H124 H 0.7506 0.1046 0.0809 0.029 Uiso 1 1 calc R
C125 C 0.82913(7) 0.05965(9) 0.08080(9) 0.0216(3) Uani 1 1 d .
H125 H 0.8175 0.0347 0.0383 0.026 Uiso 1 1 calc R
C126 C 0.88614(7) 0.05462(8) 0.11779(9) 0.0187(3) Uani 1 1 d .
H126 H 0.9124 0.0259 0.0994 0.022 Uiso 1 1 calc R
C131 C 1.00397(6) 0.16925(8) 0.19714(8) 0.0154(3) Uani 1 1 d .
C132 C 1.05272(7) 0.20531(9) 0.23785(8) 0.0197(3) Uani 1 1 d .
H132 H 1.0714 0.1818 0.2794 0.024 Uiso 1 1 calc R
C133 C 1.07462(7) 0.27429(10) 0.21944(9) 0.0231(3) Uani 1 1 d .
H133 H 1.1073 0.2972 0.2487 0.028 Uiso 1 1 calc R
C134 C 1.04920(7) 0.30964(9) 0.15889(9) 0.0224(3) Uani 1 1 d .
H134 H 1.0634 0.3574 0.1469 0.027 Uiso 1 1 calc R
C135 C 1.00252(7) 0.27410(9) 0.11594(9) 0.0230(3) Uani 1 1 d .
H135 H 0.9852 0.2967 0.0736 0.028 Uiso 1 1 calc R
C136 C 0.98110(7) 0.20512(9) 0.13513(9) 0.0205(3) Uani 1 1 d .
H136 H 0.9495 0.1814 0.1046 0.025 Uiso 1 1 calc R
C141 C 1.00445(6) 0.01380(8) 0.19220(8) 0.0162(3) Uani 1 1 d .
C142 C 0.98715(7) -0.06143(8) 0.20465(9) 0.0200(3) Uani 1 1 d .
H142 H 0.9601 -0.0673 0.2313 0.024 Uiso 1 1 calc R
C143 C 1.00771(7) -0.12728(9) 0.17988(9) 0.0230(3) Uani 1 1 d .
H143 H 0.9956 -0.1768 0.1907 0.028 Uiso 1 1 calc R
C144 C 1.04600(7) -0.12048(10) 0.13928(10) 0.0264(4) Uani 1 1 d .
H144 H 1.0599 -0.1651 0.1215 0.032 Uiso 1 1 calc R
C145 C 1.06362(8) -0.04776(10) 0.12499(10) 0.0249(3) Uani 1 1 d .
H145 H 1.0895 -0.0425 0.0968 0.03 Uiso 1 1 calc R
C146 C 1.04363(7) 0.01819(9) 0.15161(8) 0.0194(3) Uani 1 1 d .
H146 H 1.057 0.0674 0.1418 0.023 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0 0 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_3
C12 Ag1 C32 176.63(6) 2_556
C12 N11 C17A 111.57(12) .
C12 N11 C1 124.60(12) .
C17A N11 C1 123.79(12) .
N11 C12 N13 105.51(12) .
N11 C12 Ag1 128.38(11) .
N13 C12 Ag1 125.20(10) .
C12 N13 C13A 111.02(12) .
C12 N13 C22 123.76(12) .
C13A N13 C22 125.21(12) .
C14 C13A C17A 121.70(12) .
C14 C13A N13 132.85(13) .
C17A C13A N13 105.25(12) .
C15 C14 C13A 116.67(14) .
C15 C14 H14 121.7 .
C13A C14 H14 121.7 .
C14 C15 C16 121.58(14) .
C14 C15 H15 119.2 .
C16 C15 H15 119.2 .
C17 C16 C15 121.71(14) .
C17 C16 H16 119.1 .
C15 C16 H16 119.1 .
C16 C17 C17A 116.59(14) .
C16 C17 H17 121.7 .
C17A C17 H17 121.7 .
C13A C17A N11 106.60(12) .
C13A C17A C17 121.76(14) .
N11 C17A C17 131.51(14) .
N11 C1 C2 111.97(12) .
N11 C1 H1A 109.2 .
C2 C1 H1A 109.2 .
N11 C1 H1B 109.2 .
C2 C1 H1B 109.2 .
H1A C1 H1B 107.9 .
C1 C2 C3 111.91(13) .
C1 C2 H2A 109.2 .
C3 C2 H2A 109.2 .
C1 C2 H2B 109.2 .
C3 C2 H2B 109.2 .
H2A C2 H2B 107.9 .
C4 C3 C2 112.75(14) .
C4 C3 H3A 109 .
C2 C3 H3A 109 .
C4 C3 H3B 109 .
C2 C3 H3B 109 .
H3A C3 H3B 107.8 .
C3 C4 H4A 109.5 .
C3 C4 H4B 109.5 .
H4A C4 H4B 109.5 .
C3 C4 H4C 109.5 .
H4A C4 H4C 109.5 .
H4B C4 H4C 109.5 .
N31 C5 C6 110.85(12) .
N31 C5 H5A 109.5 .
C6 C5 H5A 109.5 .
N31 C5 H5B 109.5 .
C6 C5 H5B 109.5 .
H5A C5 H5B 108.1 .
C5 C6 C7 112.26(13) .
C5 C6 H6A 109.2 .
C7 C6 H6A 109.2 .
C5 C6 H6B 109.2 .
C7 C6 H6B 109.2 .
H6A C6 H6B 107.9 .
C8 C7 C6 112.78(14) .
C8 C7 H7A 109 .
C6 C7 H7A 109 .
C8 C7 H7B 109 .
C6 C7 H7B 109 .
H7A C7 H7B 107.8 .
C7 C8 H8A 109.5 .
C7 C8 H8B 109.5 .
H8A C8 H8B 109.5 .
C7 C8 H8C 109.5 .
H8A C8 H8C 109.5 .
H8B C8 H8C 109.5 .
C22 N21 C26 116.52(12) .
N21 C22 C23 124.28(13) .
N21 C22 N13 115.48(12) .
C23 C22 N13 120.23(12) .
C22 C23 C24 117.87(13) .
C22 C23 H23 121.1 .
C24 C23 H23 121.1 .
C23 C24 C25 119.43(14) .
C23 C24 H24 120.3 .
C25 C24 H24 120.3 .
C24 C25 C26 117.46(13) .
C24 C25 H25 121.3 .
C26 C25 H25 121.3 .
N21 C26 C25 124.27(13) .
N21 C26 N33 115.39(12) .
C25 C26 N33 120.33(12) .
C32 N31 C37A 111.36(12) .
C32 N31 C5 124.00(12) .
C37A N31 C5 124.60(12) .
N31 C32 N33 105.71(12) .
N31 C32 Ag1 126.80(11) 2_556
N33 C32 Ag1 126.64(10) 2_556
C32 N33 C33A 110.91(12) .
C32 N33 C26 123.82(11) .
C33A N33 C26 125.26(12) .
C37A C33A C34 121.59(13) .
C37A C33A N33 105.38(12) .
C34 C33A N33 132.86(13) .
C35 C34 C33A 116.39(14) .
C35 C34 H34 121.8 .
C33A C34 H34 121.8 .
C34 C35 C36 121.89(14) .
C34 C35 H35 119.1 .
C36 C35 H35 119.1 .
C37 C36 C35 121.84(13) .
C37 C36 H36 119.1 .
C35 C36 H36 119.1 .
C36 C37 C37A 116.24(14) .
C36 C37 H37 121.9 .
C37A C37 H37 121.9 .
C33A C37A N31 106.56(12) .
C33A C37A C37 122.03(13) .
N31 C37A C37 131.33(14) .
C141 B1 C131 110.37(12) .
C141 B1 C111 112.21(12) .
C131 B1 C111 108.32(12) .
C141 B1 C121 107.26(12) .
C131 B1 C121 107.07(12) .
C111 B1 C121 111.50(12) .
C116 C111 C112 114.13(14) .
C116 C111 B1 124.75(14) .
C112 C111 B1 121.09(13) .
C113 C112 C111 123.36(15) .
C113 C112 H112 118.3 .
C111 C112 H112 118.3 .
C112 C113 C114 120.40(16) .
C112 C113 H113 119.8 .
C114 C113 H113 119.8 .
C115 C114 C113 118.33(16) .
C115 C114 H114 120.8 .
C113 C114 H114 120.8 .
C114 C115 C116 120.74(16) .
C114 C115 H115 119.6 .
C116 C115 H115 119.6 .
C115 C116 C111 123.04(16) .
C115 C116 H116 118.5 .
C111 C116 H116 118.5 .
C122 C121 C126 114.44(14) .
C122 C121 B1 124.22(14) .
C126 C121 B1 121.06(13) .
C123 C122 C121 122.87(16) .
C123 C122 H122 118.6 .
C121 C122 H122 118.6 .
C124 C123 C122 120.59(16) .
C124 C123 H123 119.7 .
C122 C123 H123 119.7 .
C125 C124 C123 118.70(15) .
C125 C124 H124 120.7 .
C123 C124 H124 120.7 .
C124 C125 C126 120.19(16) .
C124 C125 H125 119.9 .
C126 C125 H125 119.9 .
C125 C126 C121 123.21(15) .
C125 C126 H126 118.4 .
C121 C126 H126 118.4 .
C136 C131 C132 115.16(14) .
C136 C131 B1 121.90(13) .
C132 C131 B1 122.93(13) .
C133 C132 C131 122.34(15) .
C133 C132 H132 118.8 .
C131 C132 H132 118.8 .
C134 C133 C132 120.60(15) .
C134 C133 H133 119.7 .
C132 C133 H133 119.7 .
C133 C134 C135 118.81(15) .
C133 C134 H134 120.6 .
C135 C134 H134 120.6 .
C134 C135 C136 119.87(16) .
C134 C135 H135 120.1 .
C136 C135 H135 120.1 .
C135 C136 C131 123.11(15) .
C135 C136 H136 118.4 .
C131 C136 H136 118.4 .
C146 C141 C142 115.30(14) .
C146 C141 B1 123.54(13) .
C142 C141 B1 121.01(14) .
C143 C142 C141 123.20(16) .
C143 C142 H142 118.4 .
C141 C142 H142 118.4 .
C144 C143 C142 119.75(16) .
C144 C143 H143 120.1 .
C142 C143 H143 120.1 .
C145 C144 C143 119.08(15) .
C145 C144 H144 120.5 .
C143 C144 H144 120.5 .
C144 C145 C146 120.65(16) .
C144 C145 H145 119.7 .
C146 C145 H145 119.7 .
C145 C146 C141 122.00(15) .
C145 C146 H146 119 .
C141 C146 H146 119 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 C12 2.0926(14) .
Ag1 C32 2.0966(14) 2_556
N11 C12 1.3452(18) .
N11 C17A 1.3936(19) .
N11 C1 1.4669(19) .
C12 N13 1.3691(19) .
N13 C13A 1.4065(17) .
N13 C22 1.4273(18) .
C13A C14 1.390(2) .
C13A C17A 1.392(2) .
C14 C15 1.389(2) .
C14 H14 0.95 .
C15 C16 1.403(2) .
C15 H15 0.95 .
C16 C17 1.383(2) .
C16 H16 0.95 .
C17 C17A 1.396(2) .
C17 H17 0.95 .
C1 C2 1.528(2) .
C1 H1A 0.99 .
C1 H1B 0.99 .
C2 C3 1.528(2) .
C2 H2A 0.99 .
C2 H2B 0.99 .
C3 C4 1.516(2) .
C3 H3A 0.99 .
C3 H3B 0.99 .
C4 H4A 0.98 .
C4 H4B 0.98 .
C4 H4C 0.98 .
C5 N31 1.4695(18) .
C5 C6 1.513(2) .
C5 H5A 0.99 .
C5 H5B 0.99 .
C6 C7 1.528(2) .
C6 H6A 0.99 .
C6 H6B 0.99 .
C7 C8 1.525(2) .
C7 H7A 0.99 .
C7 H7B 0.99 .
C8 H8A 0.98 .
C8 H8B 0.98 .
C8 H8C 0.98 .
N21 C22 1.3352(18) .
N21 C26 1.3379(18) .
C22 C23 1.383(2) .
C23 C24 1.389(2) .
C23 H23 0.95 .
C24 C25 1.388(2) .
C24 H24 0.95 .
C25 C26 1.390(2) .
C25 H25 0.95 .
C26 N33 1.4188(18) .
N31 C32 1.3447(18) .
N31 C37A 1.3959(18) .
C32 N33 1.3697(19) .
C32 Ag1 2.0966(14) 2_556
N33 C33A 1.4043(17) .
C33A C37A 1.393(2) .
C33A C34 1.395(2) .
C34 C35 1.387(2) .
C34 H34 0.95 .
C35 C36 1.402(2) .
C35 H35 0.95 .
C36 C37 1.383(2) .
C36 H36 0.95 .
C37 C37A 1.3972(19) .
C37 H37 0.95 .
B1 C141 1.638(2) .
B1 C131 1.646(2) .
B1 C111 1.650(2) .
B1 C121 1.658(2) .
C111 C116 1.407(2) .
C111 C112 1.414(2) .
C112 C113 1.388(2) .
C112 H112 0.95 .
C113 C114 1.391(2) .
C113 H113 0.95 .
C114 C115 1.382(3) .
C114 H114 0.95 .
C115 C116 1.396(2) .
C115 H115 0.95 .
C116 H116 0.95 .
C121 C122 1.408(2) .
C121 C126 1.413(2) .
C122 C123 1.396(2) .
C122 H122 0.95 .
C123 C124 1.387(3) .
C123 H123 0.95 .
C124 C125 1.385(2) .
C124 H124 0.95 .
C125 C126 1.395(2) .
C125 H125 0.95 .
C126 H126 0.95 .
C131 C136 1.399(2) .
C131 C132 1.406(2) .
C132 C133 1.395(2) .
C132 H132 0.95 .
C133 C134 1.383(2) .
C133 H133 0.95 .
C134 C135 1.388(2) .
C134 H134 0.95 .
C135 C136 1.395(2) .
C135 H135 0.95 .
C136 H136 0.95 .
C141 C146 1.401(2) .
C141 C142 1.410(2) .
C142 C143 1.388(2) .
C142 H142 0.95 .
C143 C144 1.387(3) .
C143 H143 0.95 .
C144 C145 1.383(2) .
C144 H144 0.95 .
C145 C146 1.401(2) .
C145 H145 0.95 .
C146 H146 0.95 .
