#------------------------------------------------------------------------------
#$Date: 2016-03-21 07:44:06 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178579 $
#$URL: svn://www.crystallography.net/cod/cif/4/06/89/4068906.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4068906
loop_
_publ_author_name
'Gaviglio, Carina'
'Ben-David, Yehoshoa'
'Shimon, Linda J. W.'
'Doctorovich, Fabio'
'Milstein, David'
_publ_section_title
;
 Synthesis, Structure, and Reactivity of Nitrosyl Pincer-Type Rhodium
 Complexes
;
_journal_issue                   6
_journal_name_full               Organometallics
_journal_page_first              1917
_journal_paper_doi               10.1021/om8011536
_journal_volume                  28
_journal_year                    2009
_chemical_formula_moiety         'C27 H47 N O2 P2 Rh, B F4'
_chemical_formula_sum            'C27 H47 B F4 N O2 P2 Rh'
_chemical_formula_weight         669.32
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           4
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  'P 2yb'
_symmetry_space_group_name_H-M   'P 1 21 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 93.05(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   8.2140(16)
_cell_length_b                   22.253(5)
_cell_length_c                   8.3550(17)
_cell_measurement_reflns_used    39832
_cell_measurement_temperature    120(2)
_cell_measurement_theta_max      26.37
_cell_measurement_theta_min      2.55
_cell_volume                     1525.0(6)
_computing_cell_refinement       HKL
_computing_data_collection       'Collect package (Bruker Nonius)'
_computing_data_reduction        HKL
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      120(2)
_diffrn_measured_fraction_theta_full 0.988
_diffrn_measured_fraction_theta_max 0.988
_diffrn_measurement_device_type  'Nonius KappaCCD'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1100
_diffrn_reflns_av_sigmaI/netI    0.0425
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       27
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       10
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_number            20071
_diffrn_reflns_theta_full        26.25
_diffrn_reflns_theta_max         26.25
_diffrn_reflns_theta_min         3.05
_exptl_absorpt_coefficient_mu    0.714
_exptl_absorpt_correction_T_max  0.9859
_exptl_absorpt_correction_T_min  0.9652
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   'SHELXL-97 (Sheldrick, 1997)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.458
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             696
_exptl_crystal_size_max          0.05
_exptl_crystal_size_mid          0.02
_exptl_crystal_size_min          0.02
_refine_diff_density_max         0.897
_refine_diff_density_min         -0.799
_refine_diff_density_rms         0.132
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.00(6)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.092
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     342
_refine_ls_number_reflns         3138
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      1.092
_refine_ls_R_factor_all          0.0608
_refine_ls_R_factor_gt           0.0514
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0651P)²+5.8690P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1234
_refine_ls_wR_factor_ref         0.1297
_reflns_number_gt                2879
_reflns_number_total             3138
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            om8011536_si_002.cif
_cod_data_source_block           m460a
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_sg_symbol_H-M      P2(1)
_cod_database_code               4068906
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Rh1 Rh 0.24821(7) 0.69495(3) 0.06760(6) 0.01668(17) Uani 1 1 d .
P2 P 0.2697(3) 0.79121(10) -0.0456(2) 0.0159(4) Uani 1 1 d .
P3 P 0.3394(3) 0.59942(10) 0.1651(3) 0.0197(5) Uani 1 1 d .
C1 C 0.0570(13) 0.6654(5) -0.0649(11) 0.027(2) Uani 1 1 d .
O2 O -0.0565(10) 0.6508(4) -0.1341(9) 0.044(2) Uani 1 1 d .
N3 N 0.1004(10) 0.7153(4) 0.2384(9) 0.0263(18) Uani 1 1 d .
O4 O 0.1261(8) 0.7546(3) 0.3270(8) 0.0301(15) Uani 1 1 d .
C11 C 0.4554(10) 0.7247(4) 0.2010(10) 0.0180(17) Uani 1 1 d .
C12 C 0.4891(10) 0.7865(4) 0.2102(9) 0.0163(17) Uani 1 1 d .
C13 C 0.6238(11) 0.8086(4) 0.3049(10) 0.0207(18) Uani 1 1 d .
C14 C 0.7165(10) 0.7668(4) 0.3958(10) 0.0213(18) Uani 1 1 d .
H14 H 0.8041 0.7810 0.4643 0.026 Uiso 1 1 calc R
C15 C 0.6864(10) 0.7054(4) 0.3906(9) 0.021(2) Uani 1 1 d .
C16 C 0.5526(10) 0.6840(4) 0.2942(9) 0.019(2) Uani 1 1 d .
C17 C 0.6611(11) 0.8750(4) 0.3169(11) 0.0236(19) Uani 1 1 d .
H17A H 0.7560 0.8813 0.3911 0.035 Uiso 1 1 calc R
H17B H 0.5668 0.8962 0.3565 0.035 Uiso 1 1 calc R
H17C H 0.6847 0.8905 0.2108 0.035 Uiso 1 1 calc R
C18 C 0.7877(12) 0.6640(5) 0.4973(11) 0.026(2) Uani 1 1 d .
H18A H 0.8931 0.6829 0.5253 0.039 Uiso 1 1 calc R
H18B H 0.8052 0.6261 0.4409 0.039 Uiso 1 1 calc R
H18C H 0.7308 0.6560 0.5952 0.039 Uiso 1 1 calc R
C21 C 0.3843(10) 0.8317(4) 0.1131(9) 0.0167(17) Uani 1 1 d .
H21A H 0.4546 0.8624 0.0660 0.020 Uiso 1 1 calc R
H21B H 0.3085 0.8522 0.1834 0.020 Uiso 1 1 calc R
C22 C 0.4035(11) 0.7867(4) -0.2219(10) 0.0220(18) Uani 1 1 d .
C23 C 0.0855(11) 0.8387(4) -0.0929(10) 0.0192(18) Uani 1 1 d .
C24 C 0.3305(11) 0.7409(5) -0.3431(11) 0.0247(19) Uani 1 1 d .
H24A H 0.3945 0.7407 -0.4388 0.037 Uiso 1 1 calc R
H24B H 0.2175 0.7520 -0.3732 0.037 Uiso 1 1 calc R
H24C H 0.3328 0.7008 -0.2946 0.037 Uiso 1 1 calc R
C25 C 0.4251(13) 0.8472(5) -0.3072(12) 0.030(2) Uani 1 1 d .
H25A H 0.3231 0.8581 -0.3663 0.044 Uiso 1 1 calc R
H25B H 0.5125 0.8437 -0.3821 0.044 Uiso 1 1 calc R
H25C H 0.4536 0.8783 -0.2276 0.044 Uiso 1 1 calc R
C26 C 0.5731(11) 0.7644(5) -0.1598(11) 0.0243(19) Uani 1 1 d .
H26A H 0.6439 0.7603 -0.2499 0.036 Uiso 1 1 calc R
H26B H 0.5621 0.7253 -0.1074 0.036 Uiso 1 1 calc R
H26C H 0.6210 0.7934 -0.0825 0.036 Uiso 1 1 calc R
C27 C -0.0046(11) 0.8209(4) -0.2532(10) 0.0230(19) Uani 1 1 d .
H27A H -0.1116 0.8405 -0.2615 0.035 Uiso 1 1 calc R
H27B H -0.0189 0.7772 -0.2569 0.035 Uiso 1 1 calc R
H27C H 0.0596 0.8337 -0.3426 0.035 Uiso 1 1 calc R
C28 C 0.1251(12) 0.9069(4) -0.0947(11) 0.027(2) Uani 1 1 d .
H28A H 0.1804 0.9184 0.0076 0.040 Uiso 1 1 calc R
H28B H 0.0237 0.9299 -0.1105 0.040 Uiso 1 1 calc R
H28C H 0.1963 0.9156 -0.1824 0.040 Uiso 1 1 calc R
C29 C -0.0344(11) 0.8297(4) 0.0409(10) 0.0234(19) Uani 1 1 d .
H29A H -0.0701 0.7877 0.0420 0.035 Uiso 1 1 calc R
H29B H -0.1292 0.8559 0.0212 0.035 Uiso 1 1 calc R
H29C H 0.0200 0.8399 0.1447 0.035 Uiso 1 1 calc R
C31 C 0.5264(12) 0.6168(4) 0.2838(12) 0.027(2) Uani 1 1 d .
H31A H 0.5196 0.6000 0.3930 0.032 Uiso 1 1 calc R
H31B H 0.6203 0.5978 0.2340 0.032 Uiso 1 1 calc R
C32 C 0.4089(13) 0.5520(4) -0.0017(12) 0.029(2) Uani 1 1 d .
C33 C 0.1996(12) 0.5592(4) 0.3022(11) 0.026(2) Uani 1 1 d .
C34 C 0.5100(15) 0.5940(6) -0.1062(14) 0.043(3) Uani 1 1 d .
H34A H 0.5421 0.5721 -0.2014 0.064 Uiso 1 1 calc R
H34B H 0.6078 0.6074 -0.0440 0.064 Uiso 1 1 calc R
H34C H 0.4441 0.6290 -0.1393 0.064 Uiso 1 1 calc R
C35 C 0.5166(15) 0.4985(5) 0.0530(13) 0.040(3) Uani 1 1 d .
H35A H 0.5972 0.5118 0.1363 0.060 Uiso 1 1 calc R
H35B H 0.5730 0.4827 -0.0386 0.060 Uiso 1 1 calc R
H35C H 0.4484 0.4669 0.0961 0.060 Uiso 1 1 calc R
C36 C 0.2625(14) 0.5264(5) -0.1070(12) 0.034(2) Uani 1 1 d .
H36A H 0.2070 0.4954 -0.0467 0.052 Uiso 1 1 calc R
H36B H 0.3028 0.5087 -0.2048 0.052 Uiso 1 1 calc R
H36C H 0.1859 0.5589 -0.1355 0.052 Uiso 1 1 calc R
C37 C 0.2554(13) 0.4941(5) 0.3382(13) 0.035(2) Uani 1 1 d .
H37A H 0.2352 0.4693 0.2423 0.052 Uiso 1 1 calc R
H37B H 0.1943 0.4779 0.4261 0.052 Uiso 1 1 calc R
H37C H 0.3722 0.4939 0.3691 0.052 Uiso 1 1 calc R
C38 C 0.0266(12) 0.5587(5) 0.2221(12) 0.030(2) Uani 1 1 d .
H38A H -0.0119 0.6001 0.2071 0.045 Uiso 1 1 calc R
H38B H -0.0469 0.5370 0.2904 0.045 Uiso 1 1 calc R
H38C H 0.0284 0.5387 0.1177 0.045 Uiso 1 1 calc R
C39 C 0.2019(13) 0.5937(5) 0.4616(11) 0.031(2) Uani 1 1 d .
H39A H 0.1208 0.5764 0.5301 0.047 Uiso 1 1 calc R
H39B H 0.1758 0.6360 0.4406 0.047 Uiso 1 1 calc R
H39C H 0.3104 0.5906 0.5156 0.047 Uiso 1 1 calc R
B1 B 0.7954(15) 0.4717(6) 0.5928(12) 0.034(3) Uani 1 1 d .
F1 F 0.6864(13) 0.4641(5) 0.7026(13) 0.091(3) Uiso 1 1 d .
F2 F 0.7264(12) 0.4869(5) 0.4465(12) 0.082(3) Uiso 1 1 d .
F3 F 0.9101(14) 0.5124(6) 0.6478(15) 0.110(4) Uani 1 1 d .
F4 F 0.8585(17) 0.4124(6) 0.5838(16) 0.115(4) Uiso 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
N3 Rh1 C1 88.9(4)
N3 Rh1 C11 93.2(3)
C1 Rh1 C11 177.9(4)
N3 Rh1 P2 98.3(2)
C1 Rh1 P2 98.7(3)
C11 Rh1 P2 81.3(3)
N3 Rh1 P3 98.7(2)
C1 Rh1 P3 96.9(3)
C11 Rh1 P3 82.4(3)
P2 Rh1 P3 157.06(8)
C21 P2 C23 104.8(4)
C21 P2 C22 107.1(4)
C23 P2 C22 111.3(4)
C21 P2 Rh1 101.8(3)
C23 P2 Rh1 121.5(3)
C22 P2 Rh1 108.9(3)
C31 P3 C32 104.1(5)
C31 P3 C33 107.0(4)
C32 P3 C33 113.9(5)
C31 P3 Rh1 103.7(3)
C32 P3 Rh1 110.7(3)
C33 P3 Rh1 116.1(3)
O2 C1 Rh1 175.8(10)
O4 N3 Rh1 122.5(6)
C12 C11 C16 119.6(8)
C12 C11 Rh1 119.5(6)
C16 C11 Rh1 120.7(7)
C11 C12 C13 121.2(8)
C11 C12 C21 120.7(7)
C13 C12 C21 118.1(8)
C14 C13 C12 117.3(8)
C14 C13 C17 120.8(8)
C12 C13 C17 121.8(8)
C15 C14 C13 123.1(8)
C15 C14 H14 118.5
C13 C14 H14 118.5
C14 C15 C16 118.8(8)
C14 C15 C18 119.5(8)
C16 C15 C18 121.5(9)
C15 C16 C11 119.9(8)
C15 C16 C31 118.0(7)
C11 C16 C31 121.8(8)
C13 C17 H17A 109.5
C13 C17 H17B 109.5
H17A C17 H17B 109.5
C13 C17 H17C 109.5
H17A C17 H17C 109.5
H17B C17 H17C 109.5
C15 C18 H18A 109.5
C15 C18 H18B 109.5
H18A C18 H18B 109.5
C15 C18 H18C 109.5
H18A C18 H18C 109.5
H18B C18 H18C 109.5
C12 C21 P2 108.4(6)
C12 C21 H21A 110.0
P2 C21 H21A 110.0
C12 C21 H21B 110.0
P2 C21 H21B 110.0
H21A C21 H21B 108.4
C24 C22 C25 109.0(7)
C24 C22 C26 108.8(8)
C25 C22 C26 108.3(7)
C24 C22 P2 109.1(6)
C25 C22 P2 113.7(6)
C26 C22 P2 107.9(6)
C29 C23 C27 107.5(7)
C29 C23 C28 106.0(8)
C27 C23 C28 109.5(7)
C29 C23 P2 108.3(6)
C27 C23 P2 112.5(6)
C28 C23 P2 112.7(6)
C22 C24 H24A 109.5
C22 C24 H24B 109.5
H24A C24 H24B 109.5
C22 C24 H24C 109.5
H24A C24 H24C 109.5
H24B C24 H24C 109.5
C22 C25 H25A 109.5
C22 C25 H25B 109.5
H25A C25 H25B 109.5
C22 C25 H25C 109.5
H25A C25 H25C 109.5
H25B C25 H25C 109.5
C22 C26 H26A 109.5
C22 C26 H26B 109.5
H26A C26 H26B 109.5
C22 C26 H26C 109.5
H26A C26 H26C 109.5
H26B C26 H26C 109.5
C23 C27 H27A 109.5
C23 C27 H27B 109.5
H27A C27 H27B 109.5
C23 C27 H27C 109.5
H27A C27 H27C 109.5
H27B C27 H27C 109.5
C23 C28 H28A 109.5
C23 C28 H28B 109.5
H28A C28 H28B 109.5
C23 C28 H28C 109.5
H28A C28 H28C 109.5
H28B C28 H28C 109.5
C23 C29 H29A 109.5
C23 C29 H29B 109.5
H29A C29 H29B 109.5
C23 C29 H29C 109.5
H29A C29 H29C 109.5
H29B C29 H29C 109.5
C16 C31 P3 110.7(6)
C16 C31 H31A 109.5
P3 C31 H31A 109.5
C16 C31 H31B 109.5
P3 C31 H31B 109.5
H31A C31 H31B 108.1
C35 C32 C34 108.5(9)
C35 C32 C36 107.3(9)
C34 C32 C36 108.8(9)
C35 C32 P3 114.2(7)
C34 C32 P3 106.0(7)
C36 C32 P3 111.8(7)
C39 C33 C38 110.4(8)
C39 C33 C37 108.0(8)
C38 C33 C37 109.6(8)
C39 C33 P3 108.0(7)
C38 C33 P3 108.5(6)
C37 C33 P3 112.3(7)
C32 C34 H34A 109.5
C32 C34 H34B 109.5
H34A C34 H34B 109.5
C32 C34 H34C 109.5
H34A C34 H34C 109.5
H34B C34 H34C 109.5
C32 C35 H35A 109.5
C32 C35 H35B 109.5
H35A C35 H35B 109.5
C32 C35 H35C 109.5
H35A C35 H35C 109.5
H35B C35 H35C 109.5
C32 C36 H36A 109.5
C32 C36 H36B 109.5
H36A C36 H36B 109.5
C32 C36 H36C 109.5
H36A C36 H36C 109.5
H36B C36 H36C 109.5
C33 C37 H37A 109.5
C33 C37 H37B 109.5
H37A C37 H37B 109.5
C33 C37 H37C 109.5
H37A C37 H37C 109.5
H37B C37 H37C 109.5
C33 C38 H38A 109.5
C33 C38 H38B 109.5
H38A C38 H38B 109.5
C33 C38 H38C 109.5
H38A C38 H38C 109.5
H38B C38 H38C 109.5
C33 C39 H39A 109.5
C33 C39 H39B 109.5
H39A C39 H39B 109.5
C33 C39 H39C 109.5
H39A C39 H39C 109.5
H39B C39 H39C 109.5
F1 B1 F2 112.9(11)
F1 B1 F3 109.2(11)
F2 B1 F3 112.4(11)
F1 B1 F4 100.4(11)
F2 B1 F4 108.6(10)
F3 B1 F4 112.7(12)
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
Rh1 N3 1.975(8)
Rh1 C1 1.985(10)
Rh1 C11 2.092(8)
Rh1 P2 2.352(2)
Rh1 P3 2.383(2)
P2 C21 1.822(8)
P2 C23 1.871(9)
P2 C22 1.887(9)
P3 C31 1.824(10)
P3 C32 1.862(10)
P3 C33 1.890(9)
C1 O2 1.119(12)
N3 O4 1.158(10)
C11 C12 1.404(13)
C11 C16 1.413(12)
C12 C13 1.414(12)
C12 C21 1.528(12)
C13 C14 1.401(13)
C13 C17 1.511(13)
C14 C15 1.388(14)
C14 H14 0.9500
C15 C16 1.410(12)
C15 C18 1.502(12)
C16 C31 1.513(13)
C17 H17A 0.9800
C17 H17B 0.9800
C17 H17C 0.9800
C18 H18A 0.9800
C18 H18B 0.9800
C18 H18C 0.9800
C21 H21A 0.9900
C21 H21B 0.9900
C22 C24 1.536(13)
C22 C25 1.538(13)
C22 C26 1.543(12)
C23 C29 1.542(12)
C23 C27 1.546(11)
C23 C28 1.552(13)
C24 H24A 0.9800
C24 H24B 0.9800
C24 H24C 0.9800
C25 H25A 0.9800
C25 H25B 0.9800
C25 H25C 0.9800
C26 H26A 0.9800
C26 H26B 0.9800
C26 H26C 0.9800
C27 H27A 0.9800
C27 H27B 0.9800
C27 H27C 0.9800
C28 H28A 0.9800
C28 H28B 0.9800
C28 H28C 0.9800
C29 H29A 0.9800
C29 H29B 0.9800
C29 H29C 0.9800
C31 H31A 0.9900
C31 H31B 0.9900
C32 C35 1.539(14)
C32 C34 1.550(15)
C32 C36 1.559(15)
C33 C39 1.536(13)
C33 C38 1.538(13)
C33 C37 1.543(14)
C34 H34A 0.9800
C34 H34B 0.9800
C34 H34C 0.9800
C35 H35A 0.9800
C35 H35B 0.9800
C35 H35C 0.9800
C36 H36A 0.9800
C36 H36B 0.9800
C36 H36C 0.9800
C37 H37A 0.9800
C37 H37B 0.9800
C37 H37C 0.9800
C38 H38A 0.9800
C38 H38B 0.9800
C38 H38C 0.9800
C39 H39A 0.9800
C39 H39B 0.9800
C39 H39C 0.9800
B1 F1 1.326(15)
B1 F2 1.363(15)
B1 F3 1.370(16)
B1 F4 1.421(19)
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
N3 Rh1 P2 C21 68.5(4)
C1 Rh1 P2 C21 158.6(4)
C11 Rh1 P2 C21 -23.5(4)
P3 Rh1 P2 C21 -68.9(3)
N3 Rh1 P2 C23 -47.2(4)
C1 Rh1 P2 C23 42.9(4)
C11 Rh1 P2 C23 -139.2(4)
P3 Rh1 P2 C23 175.4(3)
N3 Rh1 P2 C22 -178.5(4)
C1 Rh1 P2 C22 -88.4(4)
C11 Rh1 P2 C22 89.4(4)
P3 Rh1 P2 C22 44.0(4)
N3 Rh1 P3 C31 -93.3(4)
C1 Rh1 P3 C31 176.8(5)
C11 Rh1 P3 C31 -1.2(4)
P2 Rh1 P3 C31 44.1(4)
N3 Rh1 P3 C32 155.6(4)
C1 Rh1 P3 C32 65.7(5)
C11 Rh1 P3 C32 -112.3(4)
P2 Rh1 P3 C32 -67.0(4)
N3 Rh1 P3 C33 23.8(4)
C1 Rh1 P3 C33 -66.2(4)
C11 Rh1 P3 C33 115.9(4)
P2 Rh1 P3 C33 161.1(3)
C1 Rh1 N3 O4 -149.9(8)
C11 Rh1 N3 O4 30.5(8)
P2 Rh1 N3 O4 -51.2(7)
P3 Rh1 N3 O4 113.3(7)
N3 Rh1 C11 C12 -79.1(7)
P2 Rh1 C11 C12 18.8(6)
P3 Rh1 C11 C12 -177.4(7)
N3 Rh1 C11 C16 94.7(7)
P2 Rh1 C11 C16 -167.4(7)
P3 Rh1 C11 C16 -3.7(6)
C16 C11 C12 C13 3.3(13)
Rh1 C11 C12 C13 177.2(6)
C16 C11 C12 C21 -178.9(7)
Rh1 C11 C12 C21 -5.1(11)
C11 C12 C13 C14 -3.5(12)
C21 C12 C13 C14 178.7(7)
C11 C12 C13 C17 -179.6(8)
C21 C12 C13 C17 2.6(11)
C12 C13 C14 C15 3.2(12)
C17 C13 C14 C15 179.3(8)
C13 C14 C15 C16 -2.5(13)
C13 C14 C15 C18 -177.5(8)
C14 C15 C16 C11 2.2(12)
C18 C15 C16 C11 177.1(8)
C14 C15 C16 C31 177.1(8)
C18 C15 C16 C31 -8.0(12)
C12 C11 C16 C15 -2.6(12)
Rh1 C11 C16 C15 -176.4(6)
C12 C11 C16 C31 -177.3(8)
Rh1 C11 C16 C31 8.9(11)
C11 C12 C21 P2 -17.4(10)
C13 C12 C21 P2 160.4(6)
C23 P2 C21 C12 154.7(6)
C22 P2 C21 C12 -86.9(6)
Rh1 P2 C21 C12 27.4(6)
C21 P2 C22 C24 166.9(6)
C23 P2 C22 C24 -79.1(7)
Rh1 P2 C22 C24 57.5(6)
C21 P2 C22 C25 -71.2(7)
C23 P2 C22 C25 42.8(8)
Rh1 P2 C22 C25 179.4(6)
C21 P2 C22 C26 48.8(7)
C23 P2 C22 C26 162.9(6)
Rh1 P2 C22 C26 -60.6(6)
C21 P2 C23 C29 -76.2(7)
C22 P2 C23 C29 168.3(6)
Rh1 P2 C23 C29 38.0(7)
C21 P2 C23 C27 165.1(6)
C22 P2 C23 C27 49.7(7)
Rh1 P2 C23 C27 -80.7(6)
C21 P2 C23 C28 40.8(7)
C22 P2 C23 C28 -74.7(7)
Rh1 P2 C23 C28 155.0(5)
C15 C16 C31 P3 175.9(6)
C11 C16 C31 P3 -9.2(11)
C32 P3 C31 C16 121.1(7)
C33 P3 C31 C16 -117.9(7)
Rh1 P3 C31 C16 5.3(7)
C31 P3 C32 C35 51.4(9)
C33 P3 C32 C35 -64.8(9)
Rh1 P3 C32 C35 162.2(7)
C31 P3 C32 C34 -68.0(8)
C33 P3 C32 C34 175.8(7)
Rh1 P3 C32 C34 42.9(8)
C31 P3 C32 C36 173.6(7)
C33 P3 C32 C36 57.4(8)
Rh1 P3 C32 C36 -75.6(7)
C31 P3 C33 C39 45.5(8)
C32 P3 C33 C39 160.0(7)
Rh1 P3 C33 C39 -69.7(7)
C31 P3 C33 C38 165.1(7)
C32 P3 C33 C38 -80.3(8)
Rh1 P3 C33 C38 50.0(7)
C31 P3 C33 C37 -73.6(8)
C32 P3 C33 C37 41.0(8)
Rh1 P3 C33 C37 171.3(6)
