#------------------------------------------------------------------------------
#$Date: 2016-03-21 07:49:12 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178583 $
#$URL: svn://www.crystallography.net/cod/cif/4/06/94/4069422.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4069422
loop_
_publ_author_name
'Au, Richard H. W.'
'Jennings, Michael C.'
'Puddephatt, Richard J.'
_publ_section_title
;
 Binuclear Platinum(IV) Complexes with Bridging Amidoalkyl Groups and
 Their Self-Assembly through Hydrogen Bonding
;
_journal_issue                   13
_journal_name_full               Organometallics
_journal_page_first              3734
_journal_paper_doi               10.1021/om9001878
_journal_volume                  28
_journal_year                    2009
_chemical_formula_moiety         'C64 H82 Cl2 N6 O2 Pt2'
_chemical_formula_sum            'C64 H82 Cl2 N6 O2 Pt2'
_chemical_formula_weight         1428.44
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 130.06(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   27.917(6)
_cell_length_b                   18.462(4)
_cell_length_c                   20.296(4)
_cell_measurement_reflns_used    14478
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      25.03
_cell_measurement_theta_min      2.04
_cell_volume                     8006(5)
_computing_cell_refinement       'DENZO-SMN (Otwinowski & Minor, 1997)'
_computing_data_collection       'COLLECT (Nonius, 1997-2001)'
_computing_data_reduction        DENZO-SMN
_computing_molecular_graphics    'SHELXTL/PC (Sheldrick, 2001)'
_computing_publication_material  SHELXTL/PC
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      150(2)
_diffrn_measured_fraction_theta_full 0.898
_diffrn_measured_fraction_theta_max 0.898
_diffrn_measurement_device_type  'Nonius Kappa-CCD'
_diffrn_measurement_method       'φ scans, and ω scans with κ offsets'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.171
_diffrn_reflns_av_sigmaI/netI    0.2943
_diffrn_reflns_limit_h_max       31
_diffrn_reflns_limit_h_min       -32
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_number            29205
_diffrn_reflns_theta_full        25.02
_diffrn_reflns_theta_max         25.02
_diffrn_reflns_theta_min         2.57
_exptl_absorpt_coefficient_mu    3.593
_exptl_absorpt_correction_T_max  0.8066
_exptl_absorpt_correction_T_min  0.5640
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'DENZO-SMN (Otwinowski & Minor, 1997)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.185
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             2856
_exptl_crystal_size_max          0.18
_exptl_crystal_size_mid          0.11
_exptl_crystal_size_min          0.06
_refine_diff_density_max         1.014
_refine_diff_density_min         -0.524
_refine_diff_density_rms         0.143
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.769
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     309
_refine_ls_number_reflns         6344
_refine_ls_number_restraints     127
_refine_ls_restrained_S_all      0.767
_refine_ls_R_factor_all          0.2098
_refine_ls_R_factor_gt           0.0728
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1074P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1925
_refine_ls_wR_factor_ref         0.2184
_reflns_number_gt                1837
_reflns_number_total             6344
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            om9001878_si_001.cif
_cod_data_source_block           18b
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_cell_volume        8007(3)
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               4069422
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Pt Pt 0.20084(4) 0.41791(4) 0.46883(4) 0.1065(4) Uani 1 1 d U
Cl Cl 0.1962(3) 0.5001(2) 0.3687(3) 0.1183(19) Uani 1 1 d U
C1 C 0.1476(11) 0.3418(9) 0.3671(10) 0.187(8) Uani 1 1 d U
H1A H 0.1637 0.2930 0.3896 0.280 Uiso 1 1 calc R
H1B H 0.1508 0.3530 0.3229 0.280 Uiso 1 1 calc R
H1C H 0.1037 0.3444 0.3420 0.280 Uiso 1 1 calc R
C2 C 0.2895(10) 0.3694(14) 0.5143(12) 0.212(9) Uani 1 1 d U
H2A H 0.3217 0.3771 0.5765 0.317 Uiso 1 1 calc R
H2B H 0.3027 0.3922 0.4846 0.317 Uiso 1 1 calc R
H2C H 0.2836 0.3173 0.5021 0.317 Uiso 1 1 calc R
N11 N 0.2403(6) 0.5025(5) 0.5633(6) 0.085(3) Uani 1 1 d GU
C12 C 0.3028(5) 0.5079(7) 0.6369(8) 0.141(7) Uani 1 1 d GU
H12A H 0.3330 0.4763 0.6447 0.169 Uiso 1 1 calc R
C13 C 0.3213(5) 0.5597(8) 0.6990(6) 0.156(8) Uani 1 1 d GU
H13A H 0.3640 0.5635 0.7492 0.187 Uiso 1 1 calc R
C14 C 0.2772(7) 0.6060(5) 0.6875(7) 0.121(6) Uani 1 1 d GDU
C15 C 0.2147(6) 0.6006(5) 0.6140(8) 0.115(6) Uani 1 1 d GU
H15A H 0.1845 0.6322 0.6062 0.138 Uiso 1 1 calc R
C16 C 0.1962(4) 0.5488(6) 0.5519(5) 0.094(4) Uani 1 1 d GU
N22 N 0.1169(6) 0.4713(7) 0.4335(8) 0.132(4) Uani 1 1 d GU
C17 C 0.1351(6) 0.5349(8) 0.4807(8) 0.155(9) Uani 1 1 d GU
C18 C 0.0904(9) 0.5856(8) 0.4598(12) 0.226(13) Uani 1 1 d GU
H18A H 0.1029 0.6291 0.4921 0.271 Uiso 1 1 calc R
C19 C 0.0274(8) 0.5725(11) 0.3917(14) 0.35(2) Uani 1 1 d GDU
C20 C 0.0092(5) 0.5089(12) 0.3445(12) 0.41(3) Uani 1 1 d GU
H20A H -0.0339 0.5000 0.2979 0.487 Uiso 1 1 calc R
C21 C 0.0539(7) 0.4582(9) 0.3654(9) 0.254(15) Uani 1 1 d GU
H21A H 0.0414 0.4147 0.3331 0.304 Uiso 1 1 calc R
C23 C 0.3005(13) 0.6500(10) 0.7734(14) 0.230(11) Uani 1 1 d DU
C24 C 0.3748(15) 0.643(2) 0.8402(17) 0.44(2) Uani 1 1 d DU
H24A H 0.3931 0.6822 0.8301 0.664 Uiso 1 1 calc R
H24B H 0.3871 0.5962 0.8325 0.664 Uiso 1 1 calc R
H24C H 0.3898 0.6467 0.8990 0.664 Uiso 1 1 calc R
C25 C 0.2407(17) 0.659(2) 0.768(2) 0.40(2) Uani 1 1 d DU
H25A H 0.2431 0.7063 0.7923 0.603 Uiso 1 1 calc R
H25B H 0.2402 0.6204 0.8000 0.603 Uiso 1 1 calc R
H25C H 0.2024 0.6573 0.7073 0.603 Uiso 1 1 calc R
C26 C 0.2929(12) 0.7275(10) 0.7347(12) 0.207(10) Uani 1 1 d DU
H26A H 0.3236 0.7607 0.7813 0.311 Uiso 1 1 calc R
H26B H 0.2506 0.7457 0.7057 0.311 Uiso 1 1 calc R
H26C H 0.2999 0.7242 0.6932 0.311 Uiso 1 1 calc R
C27 C -0.0234(13) 0.6400(13) 0.351(2) 0.329(19) Uani 1 1 d DU
C28 C -0.0545(15) 0.664(3) 0.256(2) 0.57(4) Uani 1 1 d DU
H28A H -0.0643 0.7161 0.2490 0.857 Uiso 1 1 calc R
H28B H -0.0930 0.6367 0.2145 0.857 Uiso 1 1 calc R
H28C H -0.0252 0.6552 0.2456 0.857 Uiso 1 1 calc R
C29 C -0.0753(14) 0.589(2) 0.335(3) 0.43(2) Uani 1 1 d DU
H29A H -0.1058 0.5762 0.2742 0.644 Uiso 1 1 calc R
H29B H -0.0967 0.6141 0.3525 0.644 Uiso 1 1 calc R
H29C H -0.0557 0.5447 0.3697 0.644 Uiso 1 1 calc R
C30 C 0.0065(10) 0.7138(17) 0.401(2) 0.38(2) Uani 1 1 d DU
H30A H -0.0269 0.7479 0.3836 0.572 Uiso 1 1 calc R
H30B H 0.0319 0.7344 0.3884 0.572 Uiso 1 1 calc R
H30C H 0.0330 0.7049 0.4635 0.572 Uiso 1 1 calc R
C31 C 0.2003(11) 0.3447(9) 0.5442(10) 0.165(7) Uani 1 1 d U
H31A H 0.1564 0.3364 0.5189 0.198 Uiso 1 1 calc R
H31B H 0.2169 0.2981 0.5423 0.198 Uiso 1 1 calc R
C32 C 0.2361(7) 0.3654(6) 0.6336(6) 0.110(6) Uani 1 1 d GU
C33 C 0.2105(5) 0.4074(6) 0.6610(7) 0.104(5) Uani 1 1 d GU
H33A H 0.1688 0.4250 0.6204 0.124 Uiso 1 1 calc R
C34 C 0.2458(6) 0.4237(5) 0.7479(7) 0.097(5) Uani 1 1 d GU
H34A H 0.2283 0.4524 0.7666 0.117 Uiso 1 1 calc R
C35 C 0.3067(6) 0.3980(8) 0.8073(5) 0.142(8) Uani 1 1 d GU
C36 C 0.3323(5) 0.3560(8) 0.7799(9) 0.177(10) Uani 1 1 d GU
H36A H 0.3739 0.3384 0.8205 0.212 Uiso 1 1 calc R
C37 C 0.2970(7) 0.3397(7) 0.6931(10) 0.177(10) Uani 1 1 d GU
H37A H 0.3145 0.3110 0.6744 0.212 Uiso 1 1 calc R
C38 C 0.3435(10) 0.4160(14) 0.9045(11) 0.178(8) Uani 1 1 d U
H38A H 0.3886 0.4217 0.9350 0.214 Uiso 1 1 calc R
H38B H 0.3277 0.4615 0.9103 0.214 Uiso 1 1 calc R
C39 C 0.3331(14) 0.355(2) 0.9401(16) 0.183(12) Uani 1 1 d U
O40 O 0.3666(8) 0.3013(14) 0.9630(11) 0.233(10) Uani 1 1 d U
N41 N 0.2942(8) 0.3587(9) 0.9534(8) 0.117(5) Uani 1 1 d U
H41A H 0.2785 0.4020 0.9465 0.140 Uiso 1 1 calc R
C42 C 0.2719(11) 0.3022(11) 0.9782(11) 0.097(6) Uani 1 1 d U
C43 C 0.3076(7) 0.2483(9) 1.0287(9) 0.070(4) Uani 1 1 d U
H43A H 0.3502 0.2469 1.0531 0.084 Uiso 1 1 calc R
C44 C 0.2150(10) 0.3040(10) 0.9539(11) 0.101(5) Uani 1 1 d U
H44A H 0.1893 0.3449 0.9225 0.121 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C31 Pt C1 87.3(7) . .
C31 Pt N11 93.4(5) . .
C1 Pt N11 170.7(7) . .
C31 Pt N22 91.2(7) . .
C1 Pt N22 92.7(7) . .
N11 Pt N22 78.0(5) . .
C31 Pt C2 88.0(9) . .
C1 Pt C2 91.9(9) . .
N11 Pt C2 97.4(7) . .
N22 Pt C2 175.3(7) . .
C31 Pt Cl 175.7(5) . .
C1 Pt Cl 88.5(5) . .
N11 Pt Cl 90.8(3) . .
N22 Pt Cl 88.6(3) . .
C2 Pt Cl 92.6(6) . .
Pt C1 H1A 109.5 . .
Pt C1 H1B 109.5 . .
H1A C1 H1B 109.5 . .
Pt C1 H1C 109.5 . .
H1A C1 H1C 109.5 . .
H1B C1 H1C 109.5 . .
Pt C2 H2A 109.5 . .
Pt C2 H2B 109.5 . .
H2A C2 H2B 109.5 . .
Pt C2 H2C 109.5 . .
H2A C2 H2C 109.5 . .
H2B C2 H2C 109.5 . .
C12 N11 C16 120.0 . .
C12 N11 Pt 125.4(7) . .
C16 N11 Pt 114.1(7) . .
C13 C12 N11 120.0 . .
C13 C12 H12A 120.0 . .
N11 C12 H12A 120.0 . .
C14 C13 C12 120.0 . .
C14 C13 H13A 120.0 . .
C12 C13 H13A 120.0 . .
C13 C14 C15 120.0 . .
C13 C14 C23 115.2(14) . .
C15 C14 C23 123.0(14) . .
C16 C15 C14 120.0 . .
C16 C15 H15A 120.0 . .
C14 C15 H15A 120.0 . .
C17 C16 C15 124.5(11) . .
C17 C16 N11 115.3(11) . .
C15 C16 N11 120.0 . .
C17 N22 C21 120.0 . .
C17 N22 Pt 108.3(9) . .
C21 N22 Pt 130.5(9) . .
C16 C17 N22 122.6(12) . .
C16 C17 C18 117.3(12) . .
N22 C17 C18 120.0 . .
C19 C18 C17 120.0 . .
C19 C18 H18A 120.0 . .
C17 C18 H18A 120.0 . .
C20 C19 C18 120.0 . .
C20 C19 C27 118.5(17) . .
C18 C19 C27 119.7(17) . .
C21 C20 C19 120.0 . .
C21 C20 H20A 120.0 . .
C19 C20 H20A 120.0 . .
C20 C21 N22 120.0 . .
C20 C21 H21A 120.0 . .
N22 C21 H21A 120.0 . .
C26 C23 C24 100(2) . .
C26 C23 C25 94(2) . .
C24 C23 C25 143(3) . .
C26 C23 C14 94.9(15) . .
C24 C23 C14 106(2) . .
C25 C23 C14 107.2(17) . .
C23 C24 H24A 109.5 . .
C23 C24 H24B 109.5 . .
H24A C24 H24B 109.5 . .
C23 C24 H24C 109.5 . .
H24A C24 H24C 109.5 . .
H24B C24 H24C 109.5 . .
C23 C25 H25A 109.5 . .
C23 C25 H25B 109.5 . .
H25A C25 H25B 109.5 . .
C23 C25 H25C 109.5 . .
H25A C25 H25C 109.5 . .
H25B C25 H25C 109.5 . .
C23 C26 H26A 109.5 . .
C23 C26 H26B 109.5 . .
H26A C26 H26B 109.5 . .
C23 C26 H26C 109.5 . .
H26A C26 H26C 109.5 . .
H26B C26 H26C 109.5 . .
C29 C27 C30 133(3) . .
C29 C27 C28 102(3) . .
C30 C27 C28 101(3) . .
C29 C27 C19 91.9(19) . .
C30 C27 C19 114(2) . .
C28 C27 C19 116(3) . .
C27 C28 H28A 109.5 . .
C27 C28 H28B 109.5 . .
H28A C28 H28B 109.5 . .
C27 C28 H28C 109.5 . .
H28A C28 H28C 109.5 . .
H28B C28 H28C 109.5 . .
C27 C29 H29A 109.5 . .
C27 C29 H29B 109.5 . .
H29A C29 H29B 109.5 . .
C27 C29 H29C 109.5 . .
H29A C29 H29C 109.5 . .
H29B C29 H29C 109.5 . .
C27 C30 H30A 109.5 . .
C27 C30 H30B 109.5 . .
H30A C30 H30B 109.5 . .
C27 C30 H30C 109.5 . .
H30A C30 H30C 109.5 . .
H30B C30 H30C 109.5 . .
C32 C31 Pt 115.5(12) . .
C32 C31 H31A 108.4 . .
Pt C31 H31A 108.4 . .
C32 C31 H31B 108.4 . .
Pt C31 H31B 108.4 . .
H31A C31 H31B 107.5 . .
C33 C32 C37 120.0 . .
C33 C32 C31 122.0(13) . .
C37 C32 C31 118.0(13) . .
C34 C33 C32 120.0 . .
C34 C33 H33A 120.0 . .
C32 C33 H33A 120.0 . .
C33 C34 C35 120.0 . .
C33 C34 H34A 120.0 . .
C35 C34 H34A 120.0 . .
C34 C35 C36 120.0 . .
C34 C35 C38 117.7(13) . .
C36 C35 C38 122.3(13) . .
C37 C36 C35 120.0 . .
C37 C36 H36A 120.0 . .
C35 C36 H36A 120.0 . .
C36 C37 C32 120.0 . .
C36 C37 H37A 120.0 . .
C32 C37 H37A 120.0 . .
C39 C38 C35 106.3(19) . .
C39 C38 H38A 110.5 . .
C35 C38 H38A 110.5 . .
C39 C38 H38B 110.5 . .
C35 C38 H38B 110.5 . .
H38A C38 H38B 108.7 . .
O40 C39 N41 120(3) . .
O40 C39 C38 118(3) . .
N41 C39 C38 122(3) . .
C39 N41 C42 130(2) . .
C39 N41 H41A 115.0 . .
C42 N41 H41A 115.0 . .
C43 C42 C44 116(2) . .
C43 C42 N41 122(2) . .
C44 C42 N41 122(2) . .
C42 C43 C44 120.7(18) . 7_557
C42 C43 H43A 119.7 . .
C44 C43 H43A 119.7 7_557 .
C43 C44 C42 123(2) 7_557 .
C43 C44 H44A 118.4 7_557 .
C42 C44 H44A 118.4 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Pt C31 2.049(14) .
Pt C1 2.120(15) .
Pt N11 2.147(8) .
Pt N22 2.194(11) .
Pt C2 2.200(18) .
Pt Cl 2.470(3) .
C1 H1A 0.9800 .
C1 H1B 0.9800 .
C1 H1C 0.9800 .
C2 H2A 0.9800 .
C2 H2B 0.9800 .
C2 H2C 0.9800 .
N11 C12 1.3900 .
N11 C16 1.3900 .
C12 C13 1.3900 .
C12 H12A 0.9500 .
C13 C14 1.3900 .
C13 H13A 0.9500 .
C14 C15 1.3900 .
C14 C23 1.63(2) .
C15 C16 1.3900 .
C15 H15A 0.9500 .
C16 C17 1.374(14) .
N22 C17 1.3900 .
N22 C21 1.3900 .
C17 C18 1.3900 .
C18 C19 1.3900 .
C18 H18A 0.9500 .
C19 C20 1.3900 .
C19 C27 1.65(2) .
C20 C21 1.3900 .
C20 H20A 0.9500 .
C21 H21A 0.9500 .
C23 C26 1.581(16) .
C23 C24 1.592(17) .
C23 C25 1.606(17) .
C24 H24A 0.9800 .
C24 H24B 0.9800 .
C24 H24C 0.9800 .
C25 H25A 0.9800 .
C25 H25B 0.9800 .
C25 H25C 0.9800 .
C26 H26A 0.9800 .
C26 H26B 0.9800 .
C26 H26C 0.9800 .
C27 C29 1.579(18) .
C27 C30 1.582(17) .
C27 C28 1.591(18) .
C28 H28A 0.9800 .
C28 H28B 0.9800 .
C28 H28C 0.9800 .
C29 H29A 0.9800 .
C29 H29B 0.9800 .
C29 H29C 0.9800 .
C30 H30A 0.9800 .
C30 H30B 0.9800 .
C30 H30C 0.9800 .
C31 C32 1.450(17) .
C31 H31A 0.9900 .
C31 H31B 0.9900 .
C32 C33 1.3900 .
C32 C37 1.3900 .
C33 C34 1.3900 .
C33 H33A 0.9500 .
C34 C35 1.3900 .
C34 H34A 0.9500 .
C35 C36 1.3900 .
C35 C38 1.565(18) .
C36 C37 1.3900 .
C36 H36A 0.9500 .
C37 H37A 0.9500 .
C38 C39 1.47(3) .
C38 H38A 0.9900 .
C38 H38B 0.9900 .
C39 O40 1.23(3) .
C39 N41 1.28(3) .
N41 C42 1.46(2) .
N41 H41A 0.8800 .
C42 C43 1.31(2) .
C42 C44 1.33(2) .
C43 C44 1.32(2) 7_557
C43 H43A 0.9500 .
C44 C43 1.32(2) 7_557
C44 H44A 0.9500 .
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
N41 H41A Cl 0.88 2.52 3.346(17) 155.7 6_566
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_4
C31 Pt N11 C12 77.2(9) .
C1 Pt N11 C12 171(3) .
N22 Pt N11 C12 167.7(7) .
C2 Pt N11 C12 -11.2(8) .
Cl Pt N11 C12 -103.9(6) .
C31 Pt N11 C16 -94.8(8) .
C1 Pt N11 C16 -1(3) .
N22 Pt N11 C16 -4.2(5) .
C2 Pt N11 C16 176.8(7) .
Cl Pt N11 C16 84.1(5) .
C16 N11 C12 C13 0.0 .
Pt N11 C12 C13 -171.5(7) .
N11 C12 C13 C14 0.0 .
C12 C13 C14 C15 0.0 .
C12 C13 C14 C23 165.4(12) .
C13 C14 C15 C16 0.0 .
C23 C14 C15 C16 -164.2(13) .
C14 C15 C16 C17 174.3(12) .
C14 C15 C16 N11 0.0 .
C12 N11 C16 C17 -174.8(11) .
Pt N11 C16 C17 -2.4(10) .
C12 N11 C16 C15 0.0 .
Pt N11 C16 C15 172.4(6) .
C31 Pt N22 C17 102.9(9) .
C1 Pt N22 C17 -169.8(8) .
N11 Pt N22 C17 9.7(7) .
C2 Pt N22 C17 23(9) .
Cl Pt N22 C17 -81.4(7) .
C31 Pt N22 C21 -90.2(11) .
C1 Pt N22 C21 -2.8(11) .
N11 Pt N22 C21 176.6(11) .
C2 Pt N22 C21 -170(8) .
Cl Pt N22 C21 85.6(10) .
C15 C16 C17 N22 -161.8(8) .
N11 C16 C17 N22 12.8(15) .
C15 C16 C17 C18 14.2(13) .
N11 C16 C17 C18 -171.2(9) .
C21 N22 C17 C16 175.9(15) .
Pt N22 C17 C16 -15.6(13) .
C21 N22 C17 C18 0.0 .
Pt N22 C17 C18 168.5(9) .
C16 C17 C18 C19 -176.1(14) .
N22 C17 C18 C19 0.0 .
C17 C18 C19 C20 0.0 .
C17 C18 C19 C27 -164(2) .
C18 C19 C20 C21 0.0 .
C27 C19 C20 C21 165(2) .
C19 C20 C21 N22 0.0 .
C17 N22 C21 C20 0.0 .
Pt N22 C21 C20 -165.6(12) .
C13 C14 C23 C26 118.1(14) .
C15 C14 C23 C26 -77.0(18) .
C13 C14 C23 C24 16(2) .
C15 C14 C23 C24 -179.2(18) .
C13 C14 C23 C25 -146(2) .
C15 C14 C23 C25 18(3) .
C20 C19 C27 C29 52(3) .
C18 C19 C27 C29 -143(2) .
C20 C19 C27 C30 -169(2) .
C18 C19 C27 C30 -4(4) .
C20 C19 C27 C28 -53(3) .
C18 C19 C27 C28 112(2) .
C1 Pt C31 C32 176.6(16) .
N11 Pt C31 C32 -12.8(15) .
N22 Pt C31 C32 -90.8(15) .
C2 Pt C31 C32 84.5(15) .
Cl Pt C31 C32 -178(59) .
Pt C31 C32 C33 86.7(15) .
Pt C31 C32 C37 -95.7(13) .
C37 C32 C33 C34 0.0 .
C31 C32 C33 C34 177.6(13) .
C32 C33 C34 C35 0.0 .
C33 C34 C35 C36 0.0 .
C33 C34 C35 C38 -178.2(14) .
C34 C35 C36 C37 0.0 .
C38 C35 C36 C37 178.1(14) .
C35 C36 C37 C32 0.0 .
C33 C32 C37 C36 0.0 .
C31 C32 C37 C36 -177.7(12) .
C34 C35 C38 C39 93(2) .
C36 C35 C38 C39 -85(2) .
C35 C38 C39 O40 83(3) .
C35 C38 C39 N41 -102(3) .
O40 C39 N41 C42 -14(5) .
C38 C39 N41 C42 171.9(19) .
C39 N41 C42 C43 34(3) .
C39 N41 C42 C44 -149(2) .
C44 C42 C43 C44 7(3) 7_557
N41 C42 C43 C44 -176.2(14) 7_557
C43 C42 C44 C43 -7(3) 7_557
N41 C42 C44 C43 176.0(14) 7_557
