#------------------------------------------------------------------------------
#$Date: 2016-03-21 07:49:12 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178583 $
#$URL: svn://www.crystallography.net/cod/cif/4/06/94/4069476.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4069476
loop_
_publ_author_name
'Takaoka, Ayumi'
'Mendiratta, Arjun'
'Peters, Jonas C.'
_publ_section_title
;
 E-H Bond Activation Reactions (E = H, C, Si, Ge) at Ruthenium:
 Terminal Phosphides, Silylenes, and Germylenes
;
_journal_issue                   13
_journal_name_full               Organometallics
_journal_page_first              3744
_journal_paper_doi               10.1021/om900216u
_journal_volume                  28
_journal_year                    2009
_chemical_formula_sum            'C69 H65 P4 Ru Si'
_chemical_formula_weight         1147.25
_chemical_name_common            '[SiPPh3]RuPiPr2'
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 110.7580(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   20.4546(3)
_cell_length_b                   13.5713(2)
_cell_length_c                   21.5505(3)
_cell_measurement_reflns_used    9847
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      68.47
_cell_measurement_theta_min      2.31
_cell_volume                     5593.98(14)
_computing_cell_refinement       'SAINT 7.46A (Bruker-AXS, 2008)'
_computing_data_collection       'APEX2 3.0 (Bruker-AXS, 2008)'
_computing_data_reduction        'SAINT 7.46A (Bruker-AXS, 2008)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      100(2)
_diffrn_detector_area_resol_mean 8.3
_diffrn_measured_fraction_theta_full 0.992
_diffrn_measured_fraction_theta_max 0.992
_diffrn_measurement_device_type  'Bruker Smart APEX CCD'
_diffrn_measurement_method       'omega and phi scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54178
_diffrn_reflns_av_R_equivalents  0.0287
_diffrn_reflns_av_sigmaI/netI    0.0207
_diffrn_reflns_limit_h_max       24
_diffrn_reflns_limit_h_min       -24
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_number            46997
_diffrn_reflns_theta_full        65.07
_diffrn_reflns_theta_max         65.07
_diffrn_reflns_theta_min         2.56
_exptl_absorpt_coefficient_mu    3.878
_exptl_absorpt_correction_T_max  0.9265
_exptl_absorpt_correction_T_min  0.3891
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS (Sheldrick, 2008)'
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.362
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             2388
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.02
_refine_diff_density_max         0.369
_refine_diff_density_min         -0.374
_refine_diff_density_rms         0.051
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.022
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     680
_refine_ls_number_reflns         9438
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.022
_refine_ls_R_factor_all          0.0265
_refine_ls_R_factor_gt           0.0236
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0319P)²+3.4623P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0583
_refine_ls_wR_factor_ref         0.0600
_reflns_number_gt                8709
_reflns_number_total             9438
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            om900216u_si_002.cif
_cod_data_source_block           d8-08067f
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 

Some obvious sintax errors have been fixed miguel

The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'not measured' was changed to '?'
- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 
;
_cod_original_sg_symbol_H-M      'P2(1)/n  '
_cod_database_code               4069476
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ru Ru 0.976570(6) 1.825765(9) 0.231228(6) 0.00906(5) Uani 1 1 d .
Si Si 0.86857(2) 1.78005(3) 0.24036(2) 0.01013(9) Uani 1 1 d .
P1 P 0.95854(2) 1.67506(3) 0.17536(2) 0.01112(9) Uani 1 1 d .
P2 P 0.98784(2) 1.89719(3) 0.33318(2) 0.01057(9) Uani 1 1 d .
P3 P 0.90380(2) 1.93292(3) 0.15680(2) 0.01159(9) Uani 1 1 d .
P4 P 1.09210(2) 1.83506(3) 0.24909(2) 0.01258(9) Uani 1 1 d .
C1 C 0.83720(9) 1.65431(13) 0.20410(8) 0.0129(3) Uani 1 1 d .
C2 C 0.77678(9) 1.60498(13) 0.20436(9) 0.0153(4) Uani 1 1 d .
H2 H 0.7460 1.6373 0.2219 0.018 Uiso 1 1 calc R
C3 C 0.76134(9) 1.51033(14) 0.17949(9) 0.0162(4) Uani 1 1 d .
H3 H 0.7198 1.4788 0.1792 0.019 Uiso 1 1 calc R
C4 C 0.80692(9) 1.46148(13) 0.15487(9) 0.0167(4) Uani 1 1 d .
H4 H 0.7968 1.3961 0.1384 0.020 Uiso 1 1 calc R
C5 C 0.86694(9) 1.50823(13) 0.15438(9) 0.0157(4) Uani 1 1 d .
H5 H 0.8987 1.4741 0.1389 0.019 Uiso 1 1 calc R
C6 C 0.88103(9) 1.60564(13) 0.17665(8) 0.0128(3) Uani 1 1 d .
C7 C 0.87110(9) 1.78795(13) 0.32883(8) 0.0125(3) Uani 1 1 d .
C8 C 0.82373(9) 1.74719(13) 0.35562(9) 0.0158(4) Uani 1 1 d .
H8 H 0.7857 1.7087 0.3282 0.019 Uiso 1 1 calc R
C9 C 0.83169(9) 1.76223(13) 0.42142(9) 0.0168(4) Uani 1 1 d .
H9 H 0.7989 1.7349 0.4386 0.020 Uiso 1 1 calc R
C10 C 0.88791(10) 1.81756(13) 0.46253(9) 0.0167(4) Uani 1 1 d .
H10 H 0.8937 1.8269 0.5079 0.020 Uiso 1 1 calc R
C11 C 0.93517(9) 1.85876(13) 0.43735(9) 0.0155(4) Uani 1 1 d .
H11 H 0.9733 1.8966 0.4653 0.019 Uiso 1 1 calc R
C12 C 0.92668(9) 1.84453(12) 0.37035(9) 0.0125(3) Uani 1 1 d .
C13 C 0.79482(9) 1.86600(13) 0.19155(8) 0.0130(3) Uani 1 1 d .
C14 C 0.72531(9) 1.86276(14) 0.18894(9) 0.0175(4) Uani 1 1 d .
H14 H 0.7124 1.8168 0.2158 0.021 Uiso 1 1 calc R
C15 C 0.67526(9) 1.92573(15) 0.14766(10) 0.0221(4) Uani 1 1 d .
H15 H 0.6286 1.9233 0.1470 0.027 Uiso 1 1 calc R
C16 C 0.69302(10) 1.99238(14) 0.10723(10) 0.0221(4) Uani 1 1 d .
H16 H 0.6585 2.0350 0.0787 0.027 Uiso 1 1 calc R
C17 C 0.76112(10) 1.99655(14) 0.10859(9) 0.0190(4) Uani 1 1 d .
H17 H 0.7733 2.0413 0.0806 0.023 Uiso 1 1 calc R
C18 C 0.81210(9) 1.93454(13) 0.15146(9) 0.0143(3) Uani 1 1 d .
C19 C 1.02319(9) 1.57509(13) 0.21107(9) 0.0139(3) Uani 1 1 d .
C20 C 1.03337(10) 1.54483(14) 0.27575(9) 0.0186(4) Uani 1 1 d .
H20 H 1.0080 1.5758 0.2997 0.022 Uiso 1 1 calc R
C21 C 1.08022(10) 1.46991(15) 0.30551(10) 0.0224(4) Uani 1 1 d .
H21 H 1.0863 1.4496 0.3494 0.027 Uiso 1 1 calc R
C22 C 1.11838(10) 1.42440(14) 0.27140(10) 0.0219(4) Uani 1 1 d .
H22 H 1.1510 1.3739 0.2921 0.026 Uiso 1 1 calc R
C23 C 1.10826(10) 1.45340(14) 0.20697(10) 0.0196(4) Uani 1 1 d .
H23 H 1.1340 1.4225 0.1833 0.024 Uiso 1 1 calc R
C24 C 1.06053(9) 1.52754(13) 0.17668(9) 0.0164(4) Uani 1 1 d .
H24 H 1.0533 1.5459 0.1322 0.020 Uiso 1 1 calc R
C25 C 0.95369(9) 1.66968(13) 0.08792(9) 0.0149(4) Uani 1 1 d .
C26 C 0.91441(10) 1.60140(14) 0.04087(9) 0.0200(4) Uani 1 1 d .
H26 H 0.8836 1.5579 0.0517 0.024 Uiso 1 1 calc R
C27 C 0.91985(11) 1.59645(15) -0.02153(10) 0.0244(4) Uani 1 1 d .
H27 H 0.8934 1.5490 -0.0528 0.029 Uiso 1 1 calc R
C28 C 0.96359(11) 1.66046(15) -0.03834(10) 0.0246(4) Uani 1 1 d .
H28 H 0.9683 1.6556 -0.0805 0.029 Uiso 1 1 calc R
C29 C 1.00039(10) 1.73156(15) 0.00648(9) 0.0213(4) Uani 1 1 d .
H29 H 1.0293 1.7769 -0.0055 0.026 Uiso 1 1 calc R
C30 C 0.99505(9) 1.73667(14) 0.06908(9) 0.0173(4) Uani 1 1 d .
H30 H 1.0199 1.7863 0.0993 0.021 Uiso 1 1 calc R
C31 C 1.06961(9) 1.87174(13) 0.40488(8) 0.0134(3) Uani 1 1 d .
C32 C 1.09345(9) 1.77435(14) 0.41571(9) 0.0169(4) Uani 1 1 d .
H32 H 1.0707 1.7248 0.3843 0.020 Uiso 1 1 calc R
C33 C 1.15010(10) 1.74939(15) 0.47198(10) 0.0214(4) Uani 1 1 d .
H33 H 1.1650 1.6827 0.4794 0.026 Uiso 1 1 calc R
C34 C 1.18498(10) 1.82109(16) 0.51733(10) 0.0225(4) Uani 1 1 d .
H34 H 1.2240 1.8039 0.5555 0.027 Uiso 1 1 calc R
C35 C 1.16250(10) 1.91822(15) 0.50670(9) 0.0205(4) Uani 1 1 d .
H35 H 1.1866 1.9679 0.5373 0.025 Uiso 1 1 calc R
C36 C 1.10477(9) 1.94298(14) 0.45128(9) 0.0170(4) Uani 1 1 d .
H36 H 1.0891 2.0094 0.4450 0.020 Uiso 1 1 calc R
C37 C 0.97802(9) 2.03084(13) 0.34411(8) 0.0128(3) Uani 1 1 d .
C38 C 0.92933(9) 2.07144(14) 0.36862(9) 0.0176(4) Uani 1 1 d .
H38 H 0.8982 2.0292 0.3799 0.021 Uiso 1 1 calc R
C39 C 0.92570(10) 2.17241(14) 0.37679(10) 0.0223(4) Uani 1 1 d .
H39 H 0.8917 2.1988 0.3929 0.027 Uiso 1 1 calc R
C40 C 0.97135(10) 2.23513(14) 0.36153(9) 0.0210(4) Uani 1 1 d .
H40 H 0.9694 2.3042 0.3680 0.025 Uiso 1 1 calc R
C41 C 1.01989(10) 2.19616(14) 0.33669(9) 0.0184(4) Uani 1 1 d .
H41 H 1.0513 2.2387 0.3261 0.022 Uiso 1 1 calc R
C42 C 1.02265(9) 2.09553(13) 0.32731(9) 0.0151(4) Uani 1 1 d .
H42 H 1.0553 2.0699 0.3092 0.018 Uiso 1 1 calc R
C43 C 0.92932(9) 2.06349(13) 0.16984(8) 0.0145(3) Uani 1 1 d .
C44 C 0.99302(10) 2.09238(14) 0.16484(9) 0.0176(4) Uani 1 1 d .
H44 H 1.0231 2.0440 0.1575 0.021 Uiso 1 1 calc R
C45 C 1.01283(11) 2.19062(15) 0.17042(10) 0.0230(4) Uani 1 1 d .
H45 H 1.0555 2.2092 0.1656 0.028 Uiso 1 1 calc R
C46 C 0.97059(11) 2.26185(14) 0.18304(9) 0.0238(4) Uani 1 1 d .
H46 H 0.9836 2.3294 0.1859 0.029 Uiso 1 1 calc R
C47 C 0.90916(11) 2.23361(14) 0.19144(9) 0.0224(4) Uani 1 1 d .
H47 H 0.8810 2.2818 0.2019 0.027 Uiso 1 1 calc R
C48 C 0.88827(10) 2.13551(14) 0.18475(9) 0.0183(4) Uani 1 1 d .
H48 H 0.8459 2.1173 0.1903 0.022 Uiso 1 1 calc R
C49 C 0.88782(9) 1.91985(13) 0.06673(9) 0.0147(4) Uani 1 1 d .
C50 C 0.91684(9) 1.97957(14) 0.03030(9) 0.0172(4) Uani 1 1 d .
H50 H 0.9490 2.0299 0.0522 0.021 Uiso 1 1 calc R
C51 C 0.89923(10) 1.96615(15) -0.03764(10) 0.0227(4) Uani 1 1 d .
H51 H 0.9194 2.0074 -0.0616 0.027 Uiso 1 1 calc R
C52 C 0.85267(11) 1.89341(16) -0.07054(10) 0.0261(4) Uani 1 1 d .
H52 H 0.8403 1.8850 -0.1171 0.031 Uiso 1 1 calc R
C53 C 0.82403(11) 1.83263(16) -0.03501(10) 0.0271(5) Uani 1 1 d .
H53 H 0.7923 1.7820 -0.0572 0.033 Uiso 1 1 calc R
C54 C 0.84163(10) 1.84567(15) 0.03287(10) 0.0206(4) Uani 1 1 d .
H54 H 0.8219 1.8034 0.0567 0.025 Uiso 1 1 calc R
C55 C 1.15572(9) 1.92585(13) 0.30400(9) 0.0155(4) Uani 1 1 d .
H55 H 1.1301 1.9577 0.3305 0.019 Uiso 1 1 calc R
C56 C 1.22272(9) 1.88518(15) 0.35548(10) 0.0218(4) Uani 1 1 d .
H56A H 1.2538 1.8612 0.3331 0.033 Uiso 1 1 calc R
H56B H 1.2111 1.8308 0.3796 0.033 Uiso 1 1 calc R
H56C H 1.2463 1.9375 0.3868 0.033 Uiso 1 1 calc R
C57 C 1.17309(10) 2.01037(14) 0.26520(10) 0.0227(4) Uani 1 1 d .
H57A H 1.2002 2.0607 0.2963 0.034 Uiso 1 1 calc R
H57B H 1.1296 2.0395 0.2350 0.034 Uiso 1 1 calc R
H57C H 1.2005 1.9849 0.2396 0.034 Uiso 1 1 calc R
C58 C 1.14520(9) 1.74954(14) 0.21830(9) 0.0177(4) Uani 1 1 d .
H58 H 1.1103 1.7072 0.1846 0.021 Uiso 1 1 calc R
C59 C 1.19061(10) 1.67740(15) 0.27095(11) 0.0262(4) Uani 1 1 d .
H59A H 1.2052 1.6229 0.2490 0.039 Uiso 1 1 calc R
H59B H 1.1635 1.6515 0.2968 0.039 Uiso 1 1 calc R
H59C H 1.2320 1.7119 0.3005 0.039 Uiso 1 1 calc R
C60 C 1.18745(11) 1.79877(17) 0.18072(12) 0.0308(5) Uani 1 1 d .
H60A H 1.2272 1.8342 0.2122 0.046 Uiso 1 1 calc R
H60B H 1.1575 1.8453 0.1482 0.046 Uiso 1 1 calc R
H60C H 1.2047 1.7484 0.1578 0.046 Uiso 1 1 calc R
C61 C 0.29117(11) 0.76954(17) 0.07194(10) 0.0262(4) Uani 1 1 d .
H61 H 0.3331 0.7986 0.1010 0.031 Uiso 1 1 calc R
C62 C 0.23610(11) 0.82909(15) 0.03499(10) 0.0257(4) Uani 1 1 d .
H62 H 0.2399 0.8987 0.0391 0.031 Uiso 1 1 calc R
C63 C 0.17545(11) 0.78625(16) -0.00793(10) 0.0256(4) Uani 1 1 d .
H63 H 0.1377 0.8267 -0.0337 0.031 Uiso 1 1 calc R
C64 C 0.16973(11) 0.68529(16) -0.01339(11) 0.0266(4) Uani 1 1 d .
H64 H 0.1279 0.6563 -0.0428 0.032 Uiso 1 1 calc R
C65 C 0.22498(11) 0.62549(16) 0.02396(10) 0.0255(4) Uani 1 1 d .
H65 H 0.2210 0.5558 0.0201 0.031 Uiso 1 1 calc R
C66 C 0.28559(11) 0.66799(16) 0.06676(10) 0.0256(4) Uani 1 1 d .
H66 H 0.3234 0.6276 0.0926 0.031 Uiso 1 1 calc R
C67 C 0.53331(11) 0.96883(16) -0.04223(10) 0.0266(4) Uani 1 1 d .
H67 H 0.5562 0.9474 -0.0712 0.032 Uiso 1 1 calc R
C68 C 0.53777(10) 1.06673(15) -0.02273(10) 0.0238(4) Uani 1 1 d .
H68 H 0.5636 1.1123 -0.0384 0.029 Uiso 1 1 calc R
C69 C 0.50451(11) 1.09798(15) 0.01958(10) 0.0269(4) Uani 1 1 d .
H69 H 0.5075 1.1650 0.0331 0.032 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.2541 0.3302 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.2955 0.4335 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru 0.0552 3.2960 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
P4 Ru P3 117.798(16) . .
P4 Ru P1 95.809(16) . .
P3 Ru P1 104.548(16) . .
P4 Ru P2 93.899(15) . .
P3 Ru P2 102.640(16) . .
P1 Ru P2 142.460(16) . .
P4 Ru Si 161.881(17) . .
P3 Ru Si 80.221(16) . .
P1 Ru Si 80.328(15) . .
P2 Ru Si 79.319(15) . .
C1 Si C7 110.58(8) . .
C1 Si C13 103.79(8) . .
C7 Si C13 104.81(7) . .
C1 Si Ru 113.06(6) . .
C7 Si Ru 112.07(6) . .
C13 Si Ru 111.93(6) . .
C6 P1 C25 104.92(8) . .
C6 P1 C19 96.29(8) . .
C25 P1 C19 99.56(8) . .
C6 P1 Ru 114.65(6) . .
C25 P1 Ru 120.03(6) . .
C19 P1 Ru 117.80(6) . .
C37 P2 C12 101.71(8) . .
C37 P2 C31 100.50(8) . .
C12 P2 C31 96.62(8) . .
C37 P2 Ru 123.21(6) . .
C12 P2 Ru 112.96(6) . .
C31 P2 Ru 117.59(6) . .
C18 P3 C43 103.06(8) . .
C18 P3 C49 97.92(8) . .
C43 P3 C49 100.75(8) . .
C18 P3 Ru 116.65(6) . .
C43 P3 Ru 115.28(6) . .
C49 P3 Ru 120.16(6) . .
C58 P4 C55 105.78(8) . .
C58 P4 Ru 127.63(6) . .
C55 P4 Ru 126.43(6) . .
C6 C1 C2 118.11(16) . .
C6 C1 Si 115.17(13) . .
C2 C1 Si 126.68(13) . .
C3 C2 C1 121.34(16) . .
C3 C2 H2 119.3 . .
C1 C2 H2 119.3 . .
C2 C3 C4 119.81(16) . .
C2 C3 H3 120.1 . .
C4 C3 H3 120.1 . .
C5 C4 C3 119.97(17) . .
C5 C4 H4 120.0 . .
C3 C4 H4 120.0 . .
C4 C5 C6 120.31(16) . .
C4 C5 H5 119.8 . .
C6 C5 H5 119.8 . .
C5 C6 C1 120.29(16) . .
C5 C6 P1 123.21(13) . .
C1 C6 P1 116.44(13) . .
C12 C7 C8 118.36(15) . .
C12 C7 Si 113.64(12) . .
C8 C7 Si 127.97(14) . .
C9 C8 C7 121.00(17) . .
C9 C8 H8 119.5 . .
C7 C8 H8 119.5 . .
C8 C9 C10 120.07(16) . .
C8 C9 H9 120.0 . .
C10 C9 H9 120.0 . .
C11 C10 C9 120.09(16) . .
C11 C10 H10 120.0 . .
C9 C10 H10 120.0 . .
C10 C11 C12 119.90(17) . .
C10 C11 H11 120.1 . .
C12 C11 H11 120.1 . .
C7 C12 C11 120.57(16) . .
C7 C12 P2 117.07(13) . .
C11 C12 P2 122.35(13) . .
C18 C13 C14 118.08(16) . .
C18 C13 Si 115.17(13) . .
C14 C13 Si 126.62(14) . .
C15 C14 C13 120.88(17) . .
C15 C14 H14 119.6 . .
C13 C14 H14 119.6 . .
C14 C15 C16 120.35(17) . .
C14 C15 H15 119.8 . .
C16 C15 H15 119.8 . .
C17 C16 C15 119.86(17) . .
C17 C16 H16 120.1 . .
C15 C16 H16 120.1 . .
C16 C17 C18 119.82(17) . .
C16 C17 H17 120.1 . .
C18 C17 H17 120.1 . .
C13 C18 C17 120.98(16) . .
C13 C18 P3 115.42(13) . .
C17 C18 P3 123.54(14) . .
C20 C19 C24 118.54(17) . .
C20 C19 P1 117.40(13) . .
C24 C19 P1 124.04(14) . .
C21 C20 C19 120.71(17) . .
C21 C20 H20 119.6 . .
C19 C20 H20 119.6 . .
C20 C21 C22 120.37(18) . .
C20 C21 H21 119.8 . .
C22 C21 H21 119.8 . .
C23 C22 C21 119.36(18) . .
C23 C22 H22 120.3 . .
C21 C22 H22 120.3 . .
C22 C23 C24 120.37(17) . .
C22 C23 H23 119.8 . .
C24 C23 H23 119.8 . .
C23 C24 C19 120.63(17) . .
C23 C24 H24 119.7 . .
C19 C24 H24 119.7 . .
C30 C25 C26 118.19(16) . .
C30 C25 P1 116.76(14) . .
C26 C25 P1 124.99(14) . .
C27 C26 C25 120.74(18) . .
C27 C26 H26 119.6 . .
C25 C26 H26 119.6 . .
C28 C27 C26 120.25(18) . .
C28 C27 H27 119.9 . .
C26 C27 H27 119.9 . .
C29 C28 C27 119.81(17) . .
C29 C28 H28 120.1 . .
C27 C28 H28 120.1 . .
C28 C29 C30 120.04(18) . .
C28 C29 H29 120.0 . .
C30 C29 H29 120.0 . .
C29 C30 C25 120.83(17) . .
C29 C30 H30 119.6 . .
C25 C30 H30 119.6 . .
C36 C31 C32 118.34(16) . .
C36 C31 P2 123.35(14) . .
C32 C31 P2 118.08(14) . .
C33 C32 C31 120.61(18) . .
C33 C32 H32 119.7 . .
C31 C32 H32 119.7 . .
C34 C33 C32 120.42(18) . .
C34 C33 H33 119.8 . .
C32 C33 H33 119.8 . .
C33 C34 C35 119.56(18) . .
C33 C34 H34 120.2 . .
C35 C34 H34 120.2 . .
C34 C35 C36 120.13(18) . .
C34 C35 H35 119.9 . .
C36 C35 H35 119.9 . .
C35 C36 C31 120.91(18) . .
C35 C36 H36 119.5 . .
C31 C36 H36 119.5 . .
C38 C37 C42 117.87(16) . .
C38 C37 P2 124.05(14) . .
C42 C37 P2 118.08(13) . .
C39 C38 C37 121.04(17) . .
C39 C38 H38 119.5 . .
C37 C38 H38 119.5 . .
C38 C39 C40 120.37(17) . .
C38 C39 H39 119.8 . .
C40 C39 H39 119.8 . .
C39 C40 C41 119.43(17) . .
C39 C40 H40 120.3 . .
C41 C40 H40 120.3 . .
C42 C41 C40 120.24(17) . .
C42 C41 H41 119.9 . .
C40 C41 H41 119.9 . .
C41 C42 C37 121.02(17) . .
C41 C42 H42 119.5 . .
C37 C42 H42 119.5 . .
C48 C43 C44 118.21(17) . .
C48 C43 P3 123.17(14) . .
C44 C43 P3 118.62(14) . .
C45 C44 C43 120.91(18) . .
C45 C44 H44 119.5 . .
C43 C44 H44 119.5 . .
C46 C45 C44 120.30(18) . .
C46 C45 H45 119.9 . .
C44 C45 H45 119.9 . .
C47 C46 C45 119.33(18) . .
C47 C46 H46 120.3 . .
C45 C46 H46 120.3 . .
C46 C47 C48 120.73(18) . .
C46 C47 H47 119.6 . .
C48 C47 H47 119.6 . .
C47 C48 C43 120.39(18) . .
C47 C48 H48 119.8 . .
C43 C48 H48 119.8 . .
C54 C49 C50 117.88(16) . .
C54 C49 P3 116.77(13) . .
C50 C49 P3 125.33(14) . .
C51 C50 C49 120.81(17) . .
C51 C50 H50 119.6 . .
C49 C50 H50 119.6 . .
C52 C51 C50 120.58(18) . .
C52 C51 H51 119.7 . .
C50 C51 H51 119.7 . .
C51 C52 C53 119.39(18) . .
C51 C52 H52 120.3 . .
C53 C52 H52 120.3 . .
C54 C53 C52 120.18(19) . .
C54 C53 H53 119.9 . .
C52 C53 H53 119.9 . .
C53 C54 C49 121.15(18) . .
C53 C54 H54 119.4 . .
C49 C54 H54 119.4 . .
C56 C55 C57 110.16(15) . .
C56 C55 P4 117.63(13) . .
C57 C55 P4 112.96(13) . .
C56 C55 H55 104.9 . .
C57 C55 H55 104.9 . .
P4 C55 H55 104.9 . .
C55 C56 H56A 109.5 . .
C55 C56 H56B 109.5 . .
H56A C56 H56B 109.5 . .
C55 C56 H56C 109.5 . .
H56A C56 H56C 109.5 . .
H56B C56 H56C 109.5 . .
C55 C57 H57A 109.5 . .
C55 C57 H57B 109.5 . .
H57A C57 H57B 109.5 . .
C55 C57 H57C 109.5 . .
H57A C57 H57C 109.5 . .
H57B C57 H57C 109.5 . .
C60 C58 C59 111.20(16) . .
C60 C58 P4 115.18(14) . .
C59 C58 P4 114.19(13) . .
C60 C58 H58 105.0 . .
C59 C58 H58 105.0 . .
P4 C58 H58 105.0 . .
C58 C59 H59A 109.5 . .
C58 C59 H59B 109.5 . .
H59A C59 H59B 109.5 . .
C58 C59 H59C 109.5 . .
H59A C59 H59C 109.5 . .
H59B C59 H59C 109.5 . .
C58 C60 H60A 109.5 . .
C58 C60 H60B 109.5 . .
H60A C60 H60B 109.5 . .
C58 C60 H60C 109.5 . .
H60A C60 H60C 109.5 . .
H60B C60 H60C 109.5 . .
C66 C61 C62 120.5(2) . .
C66 C61 H61 119.8 . .
C62 C61 H61 119.8 . .
C63 C62 C61 119.5(2) . .
C63 C62 H62 120.3 . .
C61 C62 H62 120.3 . .
C64 C63 C62 120.24(19) . .
C64 C63 H63 119.9 . .
C62 C63 H63 119.9 . .
C63 C64 C65 120.2(2) . .
C63 C64 H64 119.9 . .
C65 C64 H64 119.9 . .
C66 C65 C64 119.7(2) . .
C66 C65 H65 120.2 . .
C64 C65 H65 120.2 . .
C65 C66 C61 119.88(19) . .
C65 C66 H66 120.1 . .
C61 C66 H66 120.1 . .
C68 C67 C69 120.29(19) . 3_675
C68 C67 H67 119.9 . .
C69 C67 H67 119.9 3_675 .
C69 C68 C67 119.90(19) . .
C69 C68 H68 120.0 . .
C67 C68 H68 120.0 . .
C68 C69 C67 119.81(19) . 3_675
C68 C69 H69 120.1 . .
C67 C69 H69 120.1 3_675 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ru P4 2.2592(4) .
Ru P3 2.2827(4) .
Ru P1 2.3354(4) .
Ru P2 2.3368(4) .
Ru Si 2.3690(4) .
Si C1 1.8918(18) .
Si C7 1.8917(17) .
Si C13 1.9021(18) .
P1 C6 1.8530(17) .
P1 C25 1.8530(18) .
P1 C19 1.8601(18) .
P2 C37 1.8491(18) .
P2 C12 1.8514(17) .
P2 C31 1.8634(18) .
P3 C18 1.8381(17) .
P3 C43 1.8405(18) .
P3 C49 1.8592(18) .
P4 C58 1.8648(18) .
P4 C55 1.8763(18) .
C1 C6 1.402(2) .
C1 C2 1.407(2) .
C2 C3 1.384(3) .
C2 H2 0.9500 .
C3 C4 1.393(3) .
C3 H3 0.9500 .
C4 C5 1.385(3) .
C4 H4 0.9500 .
C5 C6 1.401(3) .
C5 H5 0.9500 .
C7 C12 1.401(2) .
C7 C8 1.405(2) .
C8 C9 1.384(3) .
C8 H8 0.9500 .
C9 C10 1.396(3) .
C9 H9 0.9500 .
C10 C11 1.383(3) .
C10 H10 0.9500 .
C11 C12 1.405(2) .
C11 H11 0.9500 .
C13 C18 1.397(2) .
C13 C14 1.404(2) .
C14 C15 1.387(3) .
C14 H14 0.9500 .
C15 C16 1.391(3) .
C15 H15 0.9500 .
C16 C17 1.384(3) .
C16 H16 0.9500 .
C17 C18 1.402(3) .
C17 H17 0.9500 .
C19 C20 1.396(3) .
C19 C24 1.397(2) .
C20 C21 1.388(3) .
C20 H20 0.9500 .
C21 C22 1.392(3) .
C21 H21 0.9500 .
C22 C23 1.386(3) .
C22 H22 0.9500 .
C23 C24 1.393(3) .
C23 H23 0.9500 .
C24 H24 0.9500 .
C25 C30 1.397(3) .
C25 C26 1.398(3) .
C26 C27 1.390(3) .
C26 H26 0.9500 .
C27 C28 1.384(3) .
C27 H27 0.9500 .
C28 C29 1.384(3) .
C28 H28 0.9500 .
C29 C30 1.393(3) .
C29 H29 0.9500 .
C30 H30 0.9500 .
C31 C36 1.394(3) .
C31 C32 1.400(3) .
C32 C33 1.390(3) .
C32 H32 0.9500 .
C33 C34 1.384(3) .
C33 H33 0.9500 .
C34 C35 1.388(3) .
C34 H34 0.9500 .
C35 C36 1.391(3) .
C35 H35 0.9500 .
C36 H36 0.9500 .
C37 C38 1.395(2) .
C37 C42 1.403(2) .
C38 C39 1.387(3) .
C38 H38 0.9500 .
C39 C40 1.386(3) .
C39 H39 0.9500 .
C40 C41 1.389(3) .
C40 H40 0.9500 .
C41 C42 1.385(3) .
C41 H41 0.9500 .
C42 H42 0.9500 .
C43 C48 1.398(3) .
C43 C44 1.401(3) .
C44 C45 1.386(3) .
C44 H44 0.9500 .
C45 C46 1.386(3) .
C45 H45 0.9500 .
C46 C47 1.386(3) .
C46 H46 0.9500 .
C47 C48 1.390(3) .
C47 H47 0.9500 .
C48 H48 0.9500 .
C49 C54 1.396(3) .
C49 C50 1.399(3) .
C50 C51 1.390(3) .
C50 H50 0.9500 .
C51 C52 1.380(3) .
C51 H51 0.9500 .
C52 C53 1.389(3) .
C52 H52 0.9500 .
C53 C54 1.388(3) .
C53 H53 0.9500 .
C54 H54 0.9500 .
C55 C56 1.528(3) .
C55 C57 1.533(2) .
C55 H55 1.0000 .
C56 H56A 0.9800 .
C56 H56B 0.9800 .
C56 H56C 0.9800 .
C57 H57A 0.9800 .
C57 H57B 0.9800 .
C57 H57C 0.9800 .
C58 C60 1.531(3) .
C58 C59 1.537(3) .
C58 H58 1.0000 .
C59 H59A 0.9800 .
C59 H59B 0.9800 .
C59 H59C 0.9800 .
C60 H60A 0.9800 .
C60 H60B 0.9800 .
C60 H60C 0.9800 .
C61 C66 1.384(3) .
C61 C62 1.386(3) .
C61 H61 0.9500 .
C62 C63 1.385(3) .
C62 H62 0.9500 .
C63 C64 1.377(3) .
C63 H63 0.9500 .
C64 C65 1.392(3) .
C64 H64 0.9500 .
C65 C66 1.382(3) .
C65 H65 0.9500 .
C66 H66 0.9500 .
C67 C68 1.387(3) .
C67 C69 1.388(3) 3_675
C67 H67 0.9500 .
C68 C69 1.383(3) .
C68 H68 0.9500 .
C69 C67 1.388(3) 3_675
C69 H69 0.9500 .
