#------------------------------------------------------------------------------
#$Date: 2016-03-21 08:04:25 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178593 $
#$URL: svn://www.crystallography.net/cod/cif/4/07/04/4070469.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4070469
loop_
_publ_author_name
'Oguadinma, Paul O.'
'Schaper, Frank'
_publ_section_title
;
 π Back-Bonding in Dibenzyl-β-diketiminato Copper Olefin Complexes
;
_journal_issue                   23
_journal_name_full               Organometallics
_journal_page_first              6721
_journal_paper_doi               10.1021/om900840f
_journal_volume                  28
_journal_year                    2009
_chemical_compound_source        'Synthesized by the authors. See text'
_chemical_formula_moiety         'C37 H36 Cu N2 P'
_chemical_formula_sum            'C37 H36 Cu N2 P'
_chemical_formula_weight         603.19
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                101.041(3)
_cell_angle_beta                 107.854(2)
_cell_angle_gamma                92.613(3)
_cell_formula_units_Z            2
_cell_length_a                   11.1477(11)
_cell_length_b                   11.2906(11)
_cell_length_c                   12.9378(13)
_cell_measurement_reflns_used    17249
_cell_measurement_temperature    150
_cell_measurement_theta_max      30.94
_cell_measurement_theta_min      2.52
_cell_volume                     1511.8(3)
_computing_cell_refinement       'APEX II (Bruker, 2006)'
_computing_data_collection       'APEX II (Bruker, 2006)'
_computing_data_reduction        'SAINT (Bruker, 2004)'
_computing_molecular_graphics    'SHELXTL (Bruker, 1997)'
_computing_publication_material  'UdMX (local program)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      150
_diffrn_detector_area_resol_mean 8.3
_diffrn_measured_fraction_theta_full 1.0
_diffrn_measured_fraction_theta_max 0.936
_diffrn_measurement_device_type  APEX2
_diffrn_measurement_method       ω
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'X-ray Sealed Tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.023
_diffrn_reflns_av_sigmaI/netI    0.0260
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            35181
_diffrn_reflns_theta_full        26.0
_diffrn_reflns_theta_max         31.34
_diffrn_reflns_theta_min         1.69
_diffrn_standards_decay_%        0.00
_diffrn_standards_number         5
_exptl_absorpt_coefficient_mu    0.804
_exptl_absorpt_correction_T_max  0.8114
_exptl_absorpt_correction_T_min  0.7518
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Sadabs (Sheldrick,1996)'
_exptl_crystal_colour            Colorless
_exptl_crystal_density_diffrn    1.325
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       chunk
_exptl_crystal_F_000             632
_exptl_crystal_size_max          0.32
_exptl_crystal_size_mid          0.28
_exptl_crystal_size_min          0.26
_refine_diff_density_max         0.634
_refine_diff_density_min         -0.410
_refine_diff_density_rms         0.059
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.099
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     372
_refine_ls_number_reflns         9302
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.099
_refine_ls_R_factor_all          0.0371
_refine_ls_R_factor_gt           0.0304
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0517P)²+0.0499P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0858
_refine_ls_wR_factor_ref         0.0882
_reflns_number_gt                7909
_reflns_number_total             9302
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            om900840f_si_001.cif
_cod_data_source_block           comp8
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from
2011-04-26.

'_geom_bond_publ_flag' value 'Y' changed to 'y'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26 (46
times).

'_geom_angle_publ_flag' value 'Y' changed to 'y' according
to /home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary
named 'cif_core.dic' version 2.4.2 from 2011-04-26 (64
times).

'_geom_torsion_publ_flag' value 'Y' changed to 'y' according
to /home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary
named 'cif_core.dic' version 2.4.2 from 2011-04-26 (92 times).

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               4070469
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Cu1 Cu 0.569262(13) 0.790190(13) 0.239180(12) 0.01647(5) Uani 1 1 d .
P1 P 0.65119(3) 0.63629(3) 0.29808(3) 0.01637(7) Uani 1 1 d .
N1 N 0.66755(10) 0.91375(9) 0.20195(9) 0.0183(2) Uani 1 1 d .
N2 N 0.40739(9) 0.85458(9) 0.21034(8) 0.01689(19) Uani 1 1 d .
C1 C 0.68736(13) 1.10015(12) 0.13069(12) 0.0264(3) Uani 1 1 d .
H1A H 0.7296 1.0582 0.0804 0.040 Uiso 1 1 calc R
H1B H 0.7510 1.1507 0.1965 0.040 Uiso 1 1 calc R
H1C H 0.6285 1.1516 0.0923 0.040 Uiso 1 1 calc R
C2 C 0.61453(12) 1.00729(11) 0.16610(10) 0.0188(2) Uani 1 1 d .
C3 C 0.48978(12) 1.03029(11) 0.16041(10) 0.0197(2) Uani 1 1 d .
H3A H 0.4660 1.1040 0.1390 0.024 Uiso 1 1 calc R
C4 C 0.39486(11) 0.96159(11) 0.18131(10) 0.0180(2) Uani 1 1 d .
C5 C 0.27077(13) 1.01716(13) 0.16708(12) 0.0266(3) Uani 1 1 d .
H5A H 0.2434 1.0150 0.2319 0.040 Uiso 1 1 calc R
H5B H 0.2059 0.9708 0.0998 0.040 Uiso 1 1 calc R
H5C H 0.2830 1.1015 0.1604 0.040 Uiso 1 1 calc R
C6 C 0.81522(12) 0.83581(12) 0.09800(10) 0.0200(2) Uani 1 1 d .
C7 C 0.72428(13) 0.74524(12) 0.02259(11) 0.0229(3) Uani 1 1 d .
H7A H 0.6473 0.7268 0.0364 0.027 Uiso 1 1 calc R
C8 C 0.74478(14) 0.68151(13) -0.07260(11) 0.0271(3) Uani 1 1 d .
H8A H 0.6823 0.6194 -0.1229 0.033 Uiso 1 1 calc R
C9 C 0.85583(14) 0.70825(14) -0.09436(12) 0.0293(3) Uani 1 1 d .
H9A H 0.8699 0.6646 -0.1593 0.035 Uiso 1 1 calc R
C10 C 0.94637(13) 0.79899(15) -0.02081(12) 0.0309(3) Uani 1 1 d .
H10A H 1.0226 0.8180 -0.0355 0.037 Uiso 1 1 calc R
C11 C 0.92605(12) 0.86241(13) 0.07465(12) 0.0257(3) Uani 1 1 d .
H11A H 0.9886 0.9247 0.1245 0.031 Uiso 1 1 calc R
C12 C 0.79905(11) 0.90102(12) 0.20613(10) 0.0211(2) Uani 1 1 d .
H12A H 0.8377 0.8564 0.2647 0.025 Uiso 1 1 calc R
H12B H 0.8465 0.9830 0.2283 0.025 Uiso 1 1 calc R
C13 C 0.27041(11) 0.82264(11) 0.32943(10) 0.0178(2) Uani 1 1 d .
C14 C 0.15093(13) 0.78632(14) 0.33394(11) 0.0289(3) Uani 1 1 d .
H14A H 0.0863 0.7458 0.2678 0.035 Uiso 1 1 calc R
C15 C 0.12554(15) 0.80881(16) 0.43414(13) 0.0371(4) Uani 1 1 d .
H15A H 0.0440 0.7835 0.4361 0.044 Uiso 1 1 calc R
C16 C 0.21881(14) 0.86802(14) 0.53109(12) 0.0296(3) Uani 1 1 d .
H16A H 0.2016 0.8826 0.5997 0.036 Uiso 1 1 calc R
C17 C 0.33679(13) 0.90575(12) 0.52776(11) 0.0240(3) Uani 1 1 d .
H17A H 0.4007 0.9472 0.5940 0.029 Uiso 1 1 calc R
C18 C 0.36244(12) 0.88319(12) 0.42724(10) 0.0212(2) Uani 1 1 d .
H18A H 0.4439 0.9096 0.4256 0.025 Uiso 1 1 calc R
C19 C 0.29453(11) 0.78992(11) 0.21883(10) 0.0181(2) Uani 1 1 d .
H19A H 0.3019 0.7017 0.2027 0.022 Uiso 1 1 calc R
H19B H 0.2193 0.8051 0.1602 0.022 Uiso 1 1 calc R
C20 C 0.77852(11) 0.68276(11) 0.43193(10) 0.0190(2) Uani 1 1 d .
C21 C 0.84816(12) 0.60071(13) 0.48656(11) 0.0243(3) Uani 1 1 d .
H21A H 0.8349 0.5170 0.4516 0.029 Uiso 1 1 calc R
C22 C 0.93693(13) 0.64030(15) 0.59181(12) 0.0316(3) Uani 1 1 d .
H22A H 0.9842 0.5840 0.6287 0.038 Uiso 1 1 calc R
C23 C 0.95603(14) 0.76323(16) 0.64286(12) 0.0338(3) Uani 1 1 d .
H23A H 1.0156 0.7904 0.7152 0.041 Uiso 1 1 calc R
C24 C 0.88908(14) 0.84554(14) 0.58906(12) 0.0320(3) Uani 1 1 d .
H24A H 0.9034 0.9293 0.6239 0.038 Uiso 1 1 calc R
C25 C 0.80044(13) 0.80583(12) 0.48364(11) 0.0241(3) Uani 1 1 d .
H25A H 0.7545 0.8628 0.4466 0.029 Uiso 1 1 calc R
C26 C 0.72515(12) 0.54719(11) 0.20580(10) 0.0187(2) Uani 1 1 d .
C27 C 0.64780(13) 0.46629(12) 0.10962(11) 0.0239(3) Uani 1 1 d .
H27A H 0.5592 0.4533 0.0970 0.029 Uiso 1 1 calc R
C28 C 0.69931(15) 0.40495(13) 0.03258(12) 0.0292(3) Uani 1 1 d .
H28A H 0.6463 0.3493 -0.0318 0.035 Uiso 1 1 calc R
C29 C 0.82849(15) 0.42504(13) 0.04973(12) 0.0298(3) Uani 1 1 d .
H29A H 0.8637 0.3837 -0.0033 0.036 Uiso 1 1 calc R
C30 C 0.90562(13) 0.50511(13) 0.14381(12) 0.0283(3) Uani 1 1 d .
H30A H 0.9939 0.5187 0.1554 0.034 Uiso 1 1 calc R
C31 C 0.85456(12) 0.56628(12) 0.22213(11) 0.0227(2) Uani 1 1 d .
H31A H 0.9083 0.6211 0.2868 0.027 Uiso 1 1 calc R
C32 C 0.54963(12) 0.52204(11) 0.32431(10) 0.0181(2) Uani 1 1 d .
C33 C 0.44632(12) 0.56227(12) 0.35503(11) 0.0214(2) Uani 1 1 d .
H33A H 0.4322 0.6453 0.3607 0.026 Uiso 1 1 calc R
C34 C 0.36410(13) 0.48225(13) 0.37738(11) 0.0259(3) Uani 1 1 d .
H34A H 0.2942 0.5106 0.3984 0.031 Uiso 1 1 calc R
C35 C 0.38390(14) 0.36126(13) 0.36902(11) 0.0276(3) Uani 1 1 d .
H35A H 0.3269 0.3062 0.3831 0.033 Uiso 1 1 calc R
C36 C 0.48724(14) 0.32029(12) 0.33996(11) 0.0268(3) Uani 1 1 d .
H36A H 0.5013 0.2373 0.3352 0.032 Uiso 1 1 calc R
C37 C 0.57015(13) 0.39991(12) 0.31782(11) 0.0227(3) Uani 1 1 d .
H37A H 0.6408 0.3714 0.2983 0.027 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_publ_flag
N2 CU1 N1 100.36(4) y
N2 CU1 P1 137.45(3) y
N1 CU1 P1 122.18(3) y
C32 P1 C26 103.43(6) y
C32 P1 C20 102.74(6) y
C26 P1 C20 104.59(6) y
C32 P1 CU1 118.85(4) y
C26 P1 CU1 113.78(4) y
C20 P1 CU1 111.92(4) y
C2 N1 C12 118.4(1) y
C2 N1 CU1 120.73(8) y
C12 N1 CU1 120.75(8) y
C4 N2 C19 117.38(10) y
C4 N2 CU1 120.03(8) y
C19 N2 CU1 122.59(8) y
C2 C1 H1A 109.5 ?
C2 C1 H1B 109.5 ?
H1A C1 H1B 109.5 ?
C2 C1 H1C 109.5 ?
H1A C1 H1C 109.5 ?
H1B C1 H1C 109.5 ?
N1 C2 C3 123.53(11) y
N1 C2 C1 121.38(11) y
C3 C2 C1 115.07(11) y
C4 C3 C2 130.30(12) y
C4 C3 H3A 114.8 ?
C2 C3 H3A 114.8 ?
N2 C4 C3 124.68(11) y
N2 C4 C5 120.27(11) y
C3 C4 C5 115.04(11) y
C4 C5 H5A 109.5 ?
C4 C5 H5B 109.5 ?
H5A C5 H5B 109.5 ?
C4 C5 H5C 109.5 ?
H5A C5 H5C 109.5 ?
H5B C5 H5C 109.5 ?
C11 C6 C7 118.34(12) y
C11 C6 C12 119.72(11) y
C7 C6 C12 121.88(11) y
C8 C7 C6 120.81(12) y
C8 C7 H7A 119.6 ?
C6 C7 H7A 119.6 ?
C9 C8 C7 120.24(13) y
C9 C8 H8A 119.9 ?
C7 C8 H8A 119.9 ?
C8 C9 C10 119.56(13) y
C8 C9 H9A 120.2 ?
C10 C9 H9A 120.2 ?
C9 C10 C11 120.19(13) y
C9 C10 H10A 119.9 ?
C11 C10 H10A 119.9 ?
C6 C11 C10 120.85(13) y
C6 C11 H11A 119.6 ?
C10 C11 H11A 119.6 ?
N1 C12 C6 115.0(1) y
N1 C12 H12A 108.5 ?
C6 C12 H12A 108.5 ?
N1 C12 H12B 108.5 ?
C6 C12 H12B 108.5 ?
H12A C12 H12B 107.5 ?
C18 C13 C14 118.36(11) y
C18 C13 C19 123.29(11) y
C14 C13 C19 118.31(11) y
C15 C14 C13 120.72(13) y
C15 C14 H14A 119.6 ?
C13 C14 H14A 119.6 ?
C16 C15 C14 120.17(13) y
C16 C15 H15A 119.9 ?
C14 C15 H15A 119.9 ?
C17 C16 C15 119.79(12) y
C17 C16 H16A 120.1 ?
C15 C16 H16A 120.1 ?
C16 C17 C18 120.10(12) y
C16 C17 H17A 119.9 ?
C18 C17 H17A 119.9 ?
C13 C18 C17 120.84(12) y
C13 C18 H18A 119.6 ?
C17 C18 H18A 119.6 ?
N2 C19 C13 116.41(10) y
N2 C19 H19A 108.2 ?
C13 C19 H19A 108.2 ?
N2 C19 H19B 108.2 ?
C13 C19 H19B 108.2 ?
H19A C19 H19B 107.3 ?
C21 C20 C25 119.07(12) y
C21 C20 P1 123.16(10) y
C25 C20 P1 117.66(10) y
C20 C21 C22 120.57(13) y
C20 C21 H21A 119.7 ?
C22 C21 H21A 119.7 ?
C21 C22 C23 119.53(14) y
C21 C22 H22A 120.2 ?
C23 C22 H22A 120.2 ?
C24 C23 C22 120.46(13) y
C24 C23 H23A 119.8 ?
C22 C23 H23A 119.8 ?
C23 C24 C25 119.94(14) y
C23 C24 H24A 120 ?
C25 C24 H24A 120 ?
C24 C25 C20 120.41(13) y
C24 C25 H25A 119.8 ?
C20 C25 H25A 119.8 ?
C31 C26 C27 118.83(11) y
C31 C26 P1 121.87(10) y
C27 C26 P1 118.96(10) y
C28 C27 C26 120.65(13) y
C28 C27 H27A 119.7 ?
C26 C27 H27A 119.7 ?
C27 C28 C29 119.94(13) y
C27 C28 H28A 120 ?
C29 C28 H28A 120 ?
C30 C29 C28 119.98(13) y
C30 C29 H29A 120 ?
C28 C29 H29A 120 ?
C29 C30 C31 120.36(13) y
C29 C30 H30A 119.8 ?
C31 C30 H30A 119.8 ?
C26 C31 C30 120.24(12) y
C26 C31 H31A 119.9 ?
C30 C31 H31A 119.9 ?
C33 C32 C37 118.95(11) y
C33 C32 P1 116.44(9) y
C37 C32 P1 124.59(10) y
C34 C33 C32 120.68(12) y
C34 C33 H33A 119.7 ?
C32 C33 H33A 119.7 ?
C35 C34 C33 120.00(13) y
C35 C34 H34A 120 ?
C33 C34 H34A 120 ?
C34 C35 C36 119.94(13) y
C34 C35 H35A 120 ?
C36 C35 H35A 120 ?
C37 C36 C35 120.38(13) y
C37 C36 H36A 119.8 ?
C35 C36 H36A 119.8 ?
C36 C37 C32 120.03(12) y
C36 C37 H37A 120 ?
C32 C37 H37A 120 ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_publ_flag
Cu1 N2 1.9325(10) y
Cu1 N1 1.9546(10) y
Cu1 P1 2.1585(4) y
P1 C32 1.8251(12) y
P1 C26 1.8265(12) y
P1 C20 1.8347(13) y
N1 C2 1.3253(17) y
N1 C12 1.4649(15) y
N2 C4 1.3332(16) y
N2 C19 1.4696(15) y
C1 C2 1.5174(17) y
C1 H1a 0.98 ?
C1 H1b 0.98 ?
C1 H1c 0.98 ?
C2 C3 1.4086(17) y
C3 C4 1.4055(17) y
C3 H3a 0.95 ?
C4 C5 1.5193(17) y
C5 H5a 0.98 ?
C5 H5b 0.98 ?
C5 H5c 0.98 ?
C6 C11 1.3920(17) y
C6 C7 1.3936(18) y
C6 C12 1.5179(17) y
C7 C8 1.3909(19) y
C7 H7a 0.95 ?
C8 C9 1.384(2) y
C8 H8a 0.95 ?
C9 C10 1.385(2) y
C9 H9a 0.95 ?
C10 C11 1.3917(19) y
C10 H10a 0.95 ?
C11 H11a 0.95 ?
C12 H12a 0.99 ?
C12 H12b 0.99 ?
C13 C18 1.3892(17) y
C13 C14 1.3974(17) y
C13 C19 1.5162(16) y
C14 C15 1.3895(19) y
C14 H14a 0.95 ?
C15 C16 1.385(2) y
C15 H15a 0.95 ?
C16 C17 1.3798(19) y
C16 H16a 0.95 ?
C17 C18 1.3949(18) y
C17 H17a 0.95 ?
C18 H18a 0.95 ?
C19 H19a 0.99 ?
C19 H19b 0.99 ?
C20 C21 1.3930(18) y
C20 C25 1.3967(18) y
C21 C22 1.3905(19) y
C21 H21a 0.95 ?
C22 C23 1.394(2) y
C22 H22a 0.95 ?
C23 C24 1.377(2) y
C23 H23a 0.95 ?
C24 C25 1.392(2) y
C24 H24a 0.95 ?
C25 H25a 0.95 ?
C26 C31 1.3927(17) y
C26 C27 1.4004(17) y
C27 C28 1.3877(19) y
C27 H27a 0.95 ?
C28 C29 1.389(2) y
C28 H28a 0.95 ?
C29 C30 1.380(2) y
C29 H29a 0.95 ?
C30 C31 1.3961(18) y
C30 H30a 0.95 ?
C31 H31a 0.95 ?
C32 C33 1.3965(17) y
C32 C37 1.3989(17) y
C33 C34 1.3881(18) y
C33 H33a 0.95 ?
C34 C35 1.383(2) y
C34 H34a 0.95 ?
C35 C36 1.389(2) y
C35 H35a 0.95 ?
C36 C37 1.3891(19) y
C36 H36a 0.95 ?
C37 H37a 0.95 ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_publ_flag
N2 CU1 P1 C32 4.59(7) y
N1 CU1 P1 C32 -177.11(5) y
N2 CU1 P1 C26 126.76(6) y
N1 CU1 P1 C26 -54.94(6) y
N2 CU1 P1 C20 -114.95(6) y
N1 CU1 P1 C20 63.35(6) y
N2 CU1 N1 C2 -1.09(10) y
P1 CU1 N1 C2 -179.92(8) y
N2 CU1 N1 C12 -177.11(9) y
P1 CU1 N1 C12 4.06(10) y
N1 CU1 N2 C4 -4.01(10) y
P1 CU1 N2 C4 174.53(7) y
N1 CU1 N2 C19 175.90(9) y
P1 CU1 N2 C19 -5.57(11) y
C12 N1 C2 C3 -178.75(11) y
CU1 N1 C2 C3 5.14(16) y
C12 N1 C2 C1 -0.40(17) y
CU1 N1 C2 C1 -176.51(9) y
N1 C2 C3 C4 -5.0(2) y
C1 C2 C3 C4 176.58(12) y
C19 N2 C4 C3 -174.44(11) y
CU1 N2 C4 C3 5.47(16) y
C19 N2 C4 C5 4.74(17) y
CU1 N2 C4 C5 -175.35(9) y
C2 C3 C4 N2 -1.2(2) y
C2 C3 C4 C5 179.55(13) y
C11 C6 C7 C8 1.2(2) y
C12 C6 C7 C8 -175.94(12) y
C6 C7 C8 C9 -0.7(2) y
C7 C8 C9 C10 -0.1(2) y
C8 C9 C10 C11 0.3(2) y
C7 C6 C11 C10 -0.9(2) y
C12 C6 C11 C10 176.27(13) y
C9 C10 C11 C6 0.2(2) y
C2 N1 C12 C6 -85.35(14) y
CU1 N1 C12 C6 90.76(12) y
C11 C6 C12 N1 151.93(12) y
C7 C6 C12 N1 -31.01(17) y
C18 C13 C14 C15 -0.9(2) y
C19 C13 C14 C15 176.92(14) y
C13 C14 C15 C16 0.1(3) y
C14 C15 C16 C17 0.6(3) y
C15 C16 C17 C18 -0.7(2) y
C14 C13 C18 C17 0.9(2) y
C19 C13 C18 C17 -176.84(12) y
C16 C17 C18 C13 -0.1(2) y
C4 N2 C19 C13 -86.33(13) y
CU1 N2 C19 C13 93.76(11) y
C18 C13 C19 N2 -17.23(18) y
C14 C13 C19 N2 165.07(12) y
C32 P1 C20 C21 52.64(12) y
C26 P1 C20 C21 -55.11(12) y
CU1 P1 C20 C21 -178.74(9) y
C32 P1 C20 C25 -123.43(10) y
C26 P1 C20 C25 128.82(10) y
CU1 P1 C20 C25 5.19(11) y
C25 C20 C21 C22 0.97(19) y
P1 C20 C21 C22 -175.05(10) y
C20 C21 C22 C23 0.1(2) y
C21 C22 C23 C24 -1.0(2) y
C22 C23 C24 C25 0.9(2) y
C23 C24 C25 C20 0.2(2) y
C21 C20 C25 C24 -1.09(19) y
P1 C20 C25 C24 175.15(10) y
C32 P1 C26 C31 -134.46(11) y
C20 P1 C26 C31 -27.21(12) y
CU1 P1 C26 C31 95.21(10) y
C32 P1 C26 C27 52.26(11) y
C20 P1 C26 C27 159.5(1) y
CU1 P1 C26 C27 -78.08(10) y
C31 C26 C27 C28 0.8(2) y
P1 C26 C27 C28 174.33(11) y
C26 C27 C28 C29 -1.0(2) y
C27 C28 C29 C30 0.6(2) y
C28 C29 C30 C31 0.0(2) y
C27 C26 C31 C30 -0.26(19) y
P1 C26 C31 C30 -173.56(11) y
C29 C30 C31 C26 -0.1(2) y
C26 P1 C32 C33 -155.97(10) y
C20 P1 C32 C33 95.39(10) y
CU1 P1 C32 C33 -28.76(11) y
C26 P1 C32 C37 25.37(12) y
C20 P1 C32 C37 -83.26(12) y
CU1 P1 C32 C37 152.58(10) y
C37 C32 C33 C34 -0.86(19) y
P1 C32 C33 C34 -179.6(1) y
C32 C33 C34 C35 -0.2(2) y
C33 C34 C35 C36 1.0(2) y
C34 C35 C36 C37 -0.8(2) y
C35 C36 C37 C32 -0.2(2) y
C33 C32 C37 C36 1.06(19) y
P1 C32 C37 C36 179.69(10) y
