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#$Date: 2016-03-21 08:15:32 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178599 $
#$URL: svn://www.crystallography.net/cod/cif/4/07/10/4071000.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4071000
loop_
_publ_author_name
'Okazaki, Masaaki'
'Yamahira, Nobukazu'
'Minglana, Jim Josephus Gabrillo'
'Komuro, Takashi'
'Ogino, Hiroshi'
'Tobita, Hiromi'
_publ_section_title
;
 [Ru(xantsil)(CO)(η6-toluene)]: Synthon for a Highly Unsaturated
 Ruthenium(II) Complex through Facile Dissociation of the Toluene Ligand
 [xantsil = (9,9-dimethylxanthene-4,5-diyl)bis(dimethylsilyl)]
;
_journal_issue                   5
_journal_name_full               Organometallics
_journal_page_first              918
_journal_paper_doi               10.1021/om701194e
_journal_volume                  27
_journal_year                    2008
_chemical_formula_moiety         'C40 H48 O4 Ru2 Si4'
_chemical_formula_sum            'C40 H48 O4 Ru2 Si4'
_chemical_formula_weight         907.28
_chemical_name_common            'complex 10'
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                93.4825(14)
_cell_angle_beta                 115.9243(10)
_cell_angle_gamma                109.649(3)
_cell_formula_units_Z            1
_cell_length_a                   10.3381(4)
_cell_length_b                   10.4244(6)
_cell_length_c                   10.4263(5)
_cell_measurement_reflns_used    11298
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      70.91
_cell_measurement_theta_min      4.48
_cell_volume                     922.64(8)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      150(2)
_diffrn_measured_fraction_theta_full 0.976
_diffrn_measured_fraction_theta_max 0.976
_diffrn_measurement_device_type  'Rigaku RAXIS-RAPID Imaging Plate'
_diffrn_measurement_method       ω
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71069
_diffrn_reflns_av_R_equivalents  0.0609
_diffrn_reflns_av_sigmaI/netI    0.0460
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_limit_l_min       -12
_diffrn_reflns_number            8263
_diffrn_reflns_theta_full        27.50
_diffrn_reflns_theta_max         27.50
_diffrn_reflns_theta_min         2.35
_diffrn_source                   'fine-focus sealed tube'
_exptl_absorpt_coefficient_mu    0.991
_exptl_absorpt_correction_T_max  0.9074
_exptl_absorpt_correction_T_min  0.7554
_exptl_absorpt_correction_type   integration
_exptl_absorpt_process_details   Higashi
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.633
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             464
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.10
_refine_diff_density_max         0.813
_refine_diff_density_min         -0.807
_refine_diff_density_rms         0.203
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.155
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     232
_refine_ls_number_reflns         4155
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.155
_refine_ls_R_factor_all          0.0491
_refine_ls_R_factor_gt           0.0420
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0749P)²+1.6258P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1175
_refine_ls_wR_factor_ref         0.1265
_reflns_number_gt                3818
_reflns_number_total             4155
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            om701194e-file003.cif
_cod_data_source_block           9
_cod_original_cell_volume        922.65(8)
_cod_database_code               4071000
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ru1 Ru 0.21599(3) -0.01212(3) 0.21004(3) 0.01237(12) Uani 1 1 d .
Si1 Si 0.42240(11) 0.19888(10) 0.22381(11) 0.0160(2) Uani 1 1 d .
Si2 Si 0.05454(11) 0.10626(10) 0.22457(10) 0.0140(2) Uani 1 1 d .
O1 O 0.1620(3) 0.2732(3) 0.0588(3) 0.0155(5) Uani 1 1 d .
C1 C 0.3176(4) 0.0635(4) 0.4071(4) 0.0184(7) Uani 1 1 d .
O2 O 0.3825(4) 0.1102(3) 0.5334(3) 0.0294(7) Uani 1 1 d .
C2 C 0.5986(4) 0.1587(4) 0.2589(5) 0.0236(8) Uani 1 1 d .
H1 H 0.6849 0.2443 0.2709 0.035 Uiso 1 1 calc R
H2 H 0.5703 0.0864 0.1754 0.035 Uiso 1 1 calc R
H3 H 0.6320 0.1246 0.3486 0.035 Uiso 1 1 calc R
C3 C 0.5106(5) 0.3627(4) 0.3741(5) 0.0246(8) Uani 1 1 d .
H4 H 0.6138 0.4238 0.3882 0.037 Uiso 1 1 calc R
H5 H 0.5225 0.3363 0.4660 0.037 Uiso 1 1 calc R
H6 H 0.4411 0.4127 0.3460 0.037 Uiso 1 1 calc R
C4 C -0.0851(5) 0.0093(4) 0.2904(4) 0.0199(7) Uani 1 1 d .
H7 H -0.0270 -0.0142 0.3821 0.030 Uiso 1 1 calc R
H8 H -0.1664 -0.0772 0.2155 0.030 Uiso 1 1 calc R
H9 H -0.1344 0.0689 0.3079 0.030 Uiso 1 1 calc R
C5 C 0.1528(5) 0.2868(4) 0.3537(4) 0.0222(8) Uani 1 1 d .
H10 H 0.0731 0.3121 0.3617 0.033 Uiso 1 1 calc R
H11 H 0.2073 0.3561 0.3150 0.033 Uiso 1 1 calc R
H12 H 0.2290 0.2856 0.4511 0.033 Uiso 1 1 calc R
C6 C 0.3794(4) 0.2652(4) 0.0492(4) 0.0177(7) Uani 1 1 d .
C7 C 0.4698(4) 0.2896(4) -0.0220(5) 0.0219(8) Uani 1 1 d .
H13 H 0.5632 0.2733 0.0177 0.026 Uiso 1 1 calc R
C8 C 0.4250(5) 0.3375(4) -0.1501(5) 0.0235(8) Uani 1 1 d .
H14 H 0.4900 0.3560 -0.1947 0.028 Uiso 1 1 calc R
C9 C 0.2866(5) 0.3585(4) -0.2135(4) 0.0220(8) Uani 1 1 d .
H15 H 0.2564 0.3885 -0.3024 0.026 Uiso 1 1 calc R
C10 C 0.1921(4) 0.3359(4) -0.1475(4) 0.0164(7) Uani 1 1 d .
C11 C 0.2462(4) 0.2943(4) -0.0173(4) 0.0152(7) Uani 1 1 d .
C12 C 0.0775(4) -0.1384(4) -0.0423(4) 0.0133(6) Uani 1 1 d .
C13 C 0.2402(4) -0.1081(4) 0.0228(4) 0.0157(7) Uani 1 1 d .
H16 H 0.3048 -0.0453 -0.0152 0.019 Uiso 1 1 calc R
C14 C 0.3155(4) -0.1549(4) 0.1493(4) 0.0167(7) Uani 1 1 d .
H17 H 0.4320 -0.1256 0.1981 0.020 Uiso 1 1 calc R
C15 C 0.2320(4) -0.2217(4) 0.2196(4) 0.0169(7) Uani 1 1 d .
H18 H 0.2898 -0.2402 0.3172 0.020 Uiso 1 1 calc R
C16 C -0.0662(4) 0.2619(4) -0.1545(4) 0.0152(7) Uani 1 1 d .
C17 C -0.0032(4) -0.2230(4) 0.0227(4) 0.0150(6) Uani 1 1 d .
C18 C 0.0383(4) 0.3574(4) -0.2074(4) 0.0176(7) Uani 1 1 d .
C19 C -0.0454(5) 0.3303(5) -0.3749(4) 0.0274(9) Uani 1 1 d .
H19 H -0.0706 0.2332 -0.4184 0.041 Uiso 1 1 calc R
H20 H 0.0234 0.3950 -0.4052 0.041 Uiso 1 1 calc R
H21 H -0.1426 0.3451 -0.4086 0.041 Uiso 1 1 calc R
C20 C 0.0775(5) 0.5104(4) -0.1383(5) 0.0223(8) Uani 1 1 d .
H22 H -0.0201 0.5247 -0.1716 0.033 Uiso 1 1 calc R
H23 H 0.1456 0.5757 -0.1688 0.033 Uiso 1 1 calc R
H24 H 0.1316 0.5278 -0.0309 0.033 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C1 Ru1 C15 97.62(15) . .
C1 Ru1 C14 112.17(15) . .
C15 Ru1 C14 36.25(13) . .
C1 Ru1 C13 143.91(15) . .
C15 Ru1 C13 65.34(13) . .
C14 Ru1 C13 36.33(13) . .
C1 Ru1 C12 173.14(14) . .
C15 Ru1 C12 75.92(12) . .
C14 Ru1 C12 63.91(12) . .
C13 Ru1 C12 35.15(11) . .
C1 Ru1 C16 110.39(14) . 2
C15 Ru1 C16 35.42(12) . 2
C14 Ru1 C16 63.43(13) . 2
C13 Ru1 C16 74.85(13) . 2
C12 Ru1 C16 62.98(12) . 2
C1 Ru1 Si2 79.49(12) . .
C15 Ru1 Si2 139.74(10) . .
C14 Ru1 Si2 166.92(9) . .
C13 Ru1 Si2 134.47(9) . .
C12 Ru1 Si2 103.86(8) . .
C16 Ru1 Si2 107.72(9) 2 .
C1 Ru1 Si1 81.40(12) . .
C15 Ru1 Si1 124.26(10) . .
C14 Ru1 Si1 92.46(10) . .
C13 Ru1 Si1 83.19(9) . .
C12 Ru1 Si1 104.07(9) . .
C16 Ru1 Si1 155.55(9) 2 .
Si2 Ru1 Si1 95.26(3) . .
C1 Ru1 C17 140.51(15) . .
C15 Ru1 C17 60.97(12) . .
C14 Ru1 C17 71.26(12) . .
C13 Ru1 C17 60.50(12) . .
C12 Ru1 C17 33.91(12) . .
C16 Ru1 C17 33.45(11) 2 .
Si2 Ru1 C17 96.03(8) . .
Si1 Ru1 C17 137.97(9) . .
C3 Si1 C2 102.76(19) . .
C3 Si1 C6 104.12(18) . .
C2 Si1 C6 102.69(18) . .
C3 Si1 Ru1 119.64(14) . .
C2 Si1 Ru1 108.60(13) . .
C6 Si1 Ru1 116.91(11) . .
C4 Si2 C5 100.28(18) . .
C4 Si2 C12 104.29(16) . 2
C5 Si2 C12 101.50(16) . 2
C4 Si2 Ru1 113.86(13) . .
C5 Si2 Ru1 119.37(13) . .
C12 Si2 Ru1 115.31(11) 2 .
C17 O1 C11 117.0(3) 2 .
O2 C1 Ru1 179.1(3) . .
C11 C6 C7 114.6(3) . .
C11 C6 Si1 118.8(3) . .
C7 C6 Si1 126.6(3) . .
C8 C7 C6 121.1(4) . .
C9 C8 C7 121.0(4) . .
C8 C9 C10 120.4(4) . .
C11 C10 C9 115.9(3) . .
C11 C10 C18 119.5(3) . .
C9 C10 C18 124.5(3) . .
C10 C11 O1 120.0(3) . .
C10 C11 C6 126.9(3) . .
O1 C11 C6 113.1(3) . .
C13 C12 C17 115.5(3) . .
C13 C12 Si2 128.5(3) . 2
C17 C12 Si2 115.2(2) . 2
C13 C12 Ru1 68.39(19) . .
C17 C12 Ru1 75.6(2) . .
Si2 C12 Ru1 134.24(17) 2 .
C12 C13 C14 121.0(3) . .
C12 C13 Ru1 76.5(2) . .
C14 C13 Ru1 71.2(2) . .
C15 C14 C13 120.0(3) . .
C15 C14 Ru1 71.0(2) . .
C13 C14 Ru1 72.4(2) . .
C14 C15 C16 121.0(3) . 2
C14 C15 Ru1 72.7(2) . .
C16 C15 Ru1 78.6(2) 2 .
C17 C16 C15 115.6(3) 2 2
C17 C16 C18 119.4(3) 2 .
C15 C16 C18 124.5(3) 2 .
C17 C16 Ru1 75.0(2) 2 2
C15 C16 Ru1 65.99(19) 2 2
C18 C16 Ru1 135.6(2) . 2
O1 C17 C16 120.2(3) 2 2
O1 C17 C12 113.8(3) 2 .
C16 C17 C12 126.0(3) 2 .
O1 C17 Ru1 138.6(2) 2 .
C16 C17 Ru1 71.6(2) 2 .
C12 C17 Ru1 70.49(19) . .
C16 C18 C19 111.4(3) . .
C16 C18 C10 108.5(3) . .
C19 C18 C10 112.0(3) . .
C16 C18 C20 106.7(3) . .
C19 C18 C20 109.6(3) . .
C10 C18 C20 108.4(3) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ru1 C1 1.818(4) .
Ru1 C15 2.251(3) .
Ru1 C14 2.272(4) .
Ru1 C13 2.288(4) .
Ru1 C12 2.392(3) .
Ru1 C16 2.415(3) 2
Ru1 Si2 2.4321(10) .
Ru1 Si1 2.4392(10) .
Ru1 C17 2.458(3) .
Si1 C3 1.892(4) .
Si1 C2 1.891(4) .
Si1 C6 1.908(4) .
Si2 C4 1.883(4) .
Si2 C5 1.897(4) .
Si2 C12 1.925(4) 2
O1 C17 1.356(4) 2
O1 C11 1.389(4) .
C1 O2 1.163(5) .
C6 C11 1.393(5) .
C6 C7 1.399(5) .
C7 C8 1.394(6) .
C8 C9 1.391(6) .
C9 C10 1.392(5) .
C10 C11 1.384(5) .
C10 C18 1.535(5) .
C12 C13 1.417(5) .
C12 C17 1.416(5) .
C12 Si2 1.925(4) 2
C13 C14 1.422(5) .
C14 C15 1.407(5) .
C15 C16 1.428(5) 2
C16 C17 1.403(5) 2
C16 C15 1.428(5) 2
C16 C18 1.526(5) .
C16 Ru1 2.415(3) 2
C17 O1 1.356(4) 2
C17 C16 1.403(5) 2
C18 C19 1.527(5) .
C18 C20 1.548(5) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C1 Ru1 Si1 C3 -28.5(2) . .
C15 Ru1 Si1 C3 -121.92(19) . .
C14 Ru1 Si1 C3 -140.59(19) . .
C13 Ru1 Si1 C3 -175.79(18) . .
C12 Ru1 Si1 C3 155.71(18) . .
C16 Ru1 Si1 C3 -149.8(3) 2 .
Si2 Ru1 Si1 C3 49.98(16) . .
C17 Ru1 Si1 C3 155.0(2) . .
C1 Ru1 Si1 C2 88.83(19) . .
C15 Ru1 Si1 C2 -4.56(19) . .
C14 Ru1 Si1 C2 -23.23(17) . .
C13 Ru1 Si1 C2 -58.43(17) . .
C12 Ru1 Si1 C2 -86.93(17) . .
C16 Ru1 Si1 C2 -32.4(3) 2 .
Si2 Ru1 Si1 C2 167.34(15) . .
C17 Ru1 Si1 C2 -87.60(19) . .
C1 Ru1 Si1 C6 -155.66(18) . .
C15 Ru1 Si1 C6 110.95(18) . .
C14 Ru1 Si1 C6 92.28(17) . .
C13 Ru1 Si1 C6 57.09(16) . .
C12 Ru1 Si1 C6 28.59(16) . .
C16 Ru1 Si1 C6 83.1(2) 2 .
Si2 Ru1 Si1 C6 -77.15(14) . .
C17 Ru1 Si1 C6 27.92(19) . .
C1 Ru1 Si2 C4 -77.62(18) . .
C15 Ru1 Si2 C4 11.8(2) . .
C14 Ru1 Si2 C4 76.2(5) . .
C13 Ru1 Si2 C4 116.54(18) . .
C12 Ru1 Si2 C4 96.25(16) . .
C16 Ru1 Si2 C4 30.60(17) 2 .
Si1 Ru1 Si2 C4 -157.84(14) . .
C17 Ru1 Si2 C4 62.70(16) . .
C1 Ru1 Si2 C5 40.59(19) . .
C15 Ru1 Si2 C5 130.0(2) . .
C14 Ru1 Si2 C5 -165.6(5) . .
C13 Ru1 Si2 C5 -125.25(19) . .
C12 Ru1 Si2 C5 -145.54(17) . .
C16 Ru1 Si2 C5 148.81(17) 2 .
Si1 Ru1 Si2 C5 -39.63(15) . .
C17 Ru1 Si2 C5 -179.09(17) . .
C1 Ru1 Si2 C12 161.86(17) . 2
C15 Ru1 Si2 C12 -108.74(19) . 2
C14 Ru1 Si2 C12 -44.3(5) . 2
C13 Ru1 Si2 C12 -3.98(18) . 2
C12 Ru1 Si2 C12 -24.3(2) . 2
C16 Ru1 Si2 C12 -89.92(15) 2 2
Si1 Ru1 Si2 C12 81.64(12) . 2
C17 Ru1 Si2 C12 -57.81(15) . 2
C3 Si1 C6 C11 -78.5(3) . .
C2 Si1 C6 C11 174.6(3) . .
Ru1 Si1 C6 C11 55.9(3) . .
C3 Si1 C6 C7 101.1(4) . .
C2 Si1 C6 C7 -5.7(4) . .
Ru1 Si1 C6 C7 -124.5(3) . .
C11 C6 C7 C8 -0.8(6) . .
Si1 C6 C7 C8 179.6(3) . .
C6 C7 C8 C9 -1.9(6) . .
C7 C8 C9 C10 1.9(6) . .
C8 C9 C10 C11 0.9(5) . .
C8 C9 C10 C18 179.3(4) . .
C9 C10 C11 O1 178.1(3) . .
C18 C10 C11 O1 -0.4(5) . .
C9 C10 C11 C6 -4.0(6) . .
C18 C10 C11 C6 177.5(3) . .
C17 O1 C11 C10 33.5(5) 2 .
C17 O1 C11 C6 -144.7(3) 2 .
C7 C6 C11 C10 3.9(6) . .
Si1 C6 C11 C10 -176.4(3) . .
C7 C6 C11 O1 -178.1(3) . .
Si1 C6 C11 O1 1.6(4) . .
C15 Ru1 C12 C13 -67.0(2) . .
C14 Ru1 C12 C13 -30.4(2) . .
C16 Ru1 C12 C13 -102.4(2) 2 .
Si2 Ru1 C12 C13 154.55(19) . .
Si1 Ru1 C12 C13 55.4(2) . .
C17 Ru1 C12 C13 -125.4(3) . .
C15 Ru1 C12 C17 58.4(2) . .
C14 Ru1 C12 C17 95.0(2) . .
C13 Ru1 C12 C17 125.4(3) . .
C16 Ru1 C12 C17 23.03(19) 2 .
Si2 Ru1 C12 C17 -80.03(19) . .
Si1 Ru1 C12 C17 -179.20(17) . .
C15 Ru1 C12 Si2 169.7(3) . 2
C14 Ru1 C12 Si2 -153.7(3) . 2
C13 Ru1 C12 Si2 -123.3(4) . 2
C16 Ru1 C12 Si2 134.3(3) 2 2
Si2 Ru1 C12 Si2 31.2(3) . 2
Si1 Ru1 C12 Si2 -67.9(2) . 2
C17 Ru1 C12 Si2 111.3(3) . 2
C17 C12 C13 C14 -3.0(5) . .
Si2 C12 C13 C14 -172.0(3) 2 .
Ru1 C12 C13 C14 57.9(3) . .
C17 C12 C13 Ru1 -61.0(3) . .
Si2 C12 C13 Ru1 130.1(3) 2 .
C1 Ru1 C13 C12 168.3(2) . .
C15 Ru1 C13 C12 100.8(2) . .
C14 Ru1 C13 C12 129.9(3) . .
C16 Ru1 C13 C12 64.4(2) 2 .
Si2 Ru1 C13 C12 -35.8(3) . .
Si1 Ru1 C13 C12 -126.5(2) . .
C17 Ru1 C13 C12 31.49(19) . .
C1 Ru1 C13 C14 38.4(3) . .
C15 Ru1 C13 C14 -29.1(2) . .
C12 Ru1 C13 C14 -129.9(3) . .
C16 Ru1 C13 C14 -65.6(2) 2 .
Si2 Ru1 C13 C14 -165.69(17) . .
Si1 Ru1 C13 C14 103.6(2) . .
C17 Ru1 C13 C14 -98.4(2) . .
C12 C13 C14 C15 -5.7(5) . .
Ru1 C13 C14 C15 54.8(3) . .
C12 C13 C14 Ru1 -60.5(3) . .
C1 Ru1 C14 C15 71.7(2) . .
C13 Ru1 C14 C15 -131.6(3) . .
C12 Ru1 C14 C15 -102.1(2) . .
C16 Ru1 C14 C15 -30.81(19) 2 .
Si2 Ru1 C14 C15 -80.4(5) . .
Si1 Ru1 C14 C15 153.42(19) . .
C17 Ru1 C14 C15 -66.2(2) . .
C1 Ru1 C14 C13 -156.7(2) . .
C15 Ru1 C14 C13 131.6(3) . .
C12 Ru1 C14 C13 29.5(2) . .
C16 Ru1 C14 C13 100.8(2) 2 .
Si2 Ru1 C14 C13 51.2(5) . .
Si1 Ru1 C14 C13 -75.0(2) . .
C17 Ru1 C14 C13 65.4(2) . .
C13 C14 C15 C16 9.2(5) . 2
Ru1 C14 C15 C16 64.6(3) . 2
C13 C14 C15 Ru1 -55.5(3) . .
C1 Ru1 C15 C14 -117.5(2) . .
C13 Ru1 C15 C14 29.2(2) . .
C12 Ru1 C15 C14 64.9(2) . .
C16 Ru1 C15 C14 127.8(3) 2 .
Si2 Ru1 C15 C14 159.80(16) . .
Si1 Ru1 C15 C14 -32.7(2) . .
C17 Ru1 C15 C14 97.8(2) . .
C1 Ru1 C15 C16 114.7(2) . 2
C14 Ru1 C15 C16 -127.8(3) . 2
C13 Ru1 C15 C16 -98.6(2) . 2
C12 Ru1 C15 C16 -62.9(2) . 2
Si2 Ru1 C15 C16 32.0(3) . 2
Si1 Ru1 C15 C16 -160.51(17) . 2
C17 Ru1 C15 C16 -30.0(2) . 2
C13 C12 C17 O1 -167.5(3) . 2
Si2 C12 C17 O1 3.0(4) 2 2
Ru1 C12 C17 O1 135.5(3) . 2
C13 C12 C17 C16 9.2(5) . 2
Si2 C12 C17 C16 179.7(3) 2 2
Ru1 C12 C17 C16 -47.9(3) . 2
C13 C12 C17 Ru1 57.1(3) . .
Si2 C12 C17 Ru1 -132.5(2) 2 .
C1 Ru1 C17 O1 82.5(4) . 2
C15 Ru1 C17 O1 146.7(4) . 2
C14 Ru1 C17 O1 -175.1(4) . 2
C13 Ru1 C17 O1 -136.8(4) . 2
C12 Ru1 C17 O1 -104.2(4) . 2
C16 Ru1 C17 O1 115.0(5) 2 2
Si2 Ru1 C17 O1 1.7(4) . 2
Si1 Ru1 C17 O1 -103.0(4) . 2
C1 Ru1 C17 C16 -32.5(3) . 2
C15 Ru1 C17 C16 31.7(2) . 2
C14 Ru1 C17 C16 69.9(2) . 2
C13 Ru1 C17 C16 108.2(2) . 2
C12 Ru1 C17 C16 140.8(3) . 2
Si2 Ru1 C17 C16 -113.3(2) . 2
Si1 Ru1 C17 C16 141.93(18) . 2
C1 Ru1 C17 C12 -173.3(2) . .
C15 Ru1 C17 C12 -109.1(2) . .
C14 Ru1 C17 C12 -70.9(2) . .
C13 Ru1 C17 C12 -32.62(19) . .
C16 Ru1 C17 C12 -140.8(3) 2 .
Si2 Ru1 C17 C12 105.94(19) . .
Si1 Ru1 C17 C12 1.2(3) . .
C17 C16 C18 C19 151.2(4) 2 .
C15 C16 C18 C19 -37.2(5) 2 .
Ru1 C16 C18 C19 52.5(5) 2 .
C17 C16 C18 C10 27.4(4) 2 .
C15 C16 C18 C10 -161.0(3) 2 .
Ru1 C16 C18 C10 -71.2(4) 2 .
C17 C16 C18 C20 -89.2(4) 2 .
C15 C16 C18 C20 82.4(4) 2 .
Ru1 C16 C18 C20 172.2(3) 2 .
C11 C10 C18 C16 -27.9(4) . .
C9 C10 C18 C16 153.6(3) . .
C11 C10 C18 C19 -151.4(3) . .
C9 C10 C18 C19 30.2(5) . .
C11 C10 C18 C20 87.6(4) . .
C9 C10 C18 C20 -90.9(4) . .
