#------------------------------------------------------------------------------
#$Date: 2016-02-16 22:30:59 +0200 (Tue, 16 Feb 2016) $
#$Revision: 176467 $
#$URL: svn://www.crystallography.net/cod/cif/4/07/11/4071106.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4071106
loop_
_publ_author_name
'Lambert, Joseph B.'
'Liu, Zhongqiang'
'Liu, Chunqing'
_publ_section_title
;
 Metal−Organic Frameworks from Silicon- and Germanium-Centered
 Tetrahedral Ligands
;
_journal_issue                   7
_journal_name_full               Organometallics
_journal_page_first              1464
_journal_paper_doi               10.1021/om701262m
_journal_volume                  27
_journal_year                    2008
_chemical_formula_sum            'C32.5 H16 N1.5 O11.5 Si Zn2'
_chemical_formula_weight         770.30
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           52
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  '-P 2a 2bc'
_symmetry_space_group_name_H-M   'P n n a'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   12.4868(7)
_cell_length_b                   13.0255(7)
_cell_length_c                   23.7555(13)
_cell_measurement_reflns_used    6294
_cell_measurement_temperature    153(2)
_cell_measurement_theta_max      28.69
_cell_measurement_theta_min      2.26
_cell_volume                     3863.8(4)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      153(2)
_diffrn_measured_fraction_theta_full 0.947
_diffrn_measured_fraction_theta_max 0.947
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0337
_diffrn_reflns_av_sigmaI/netI    0.0178
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       32
_diffrn_reflns_limit_l_min       -31
_diffrn_reflns_number            34162
_diffrn_reflns_theta_full        28.94
_diffrn_reflns_theta_max         28.94
_diffrn_reflns_theta_min         1.71
_exptl_absorpt_coefficient_mu    1.327
_exptl_absorpt_correction_T_max  0.7546
_exptl_absorpt_correction_T_min  0.5082
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   face-indexed
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.324
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       columnar
_exptl_crystal_F_000             1550
_exptl_crystal_size_max          0.540
_exptl_crystal_size_mid          0.318
_exptl_crystal_size_min          0.262
_refine_diff_density_max         1.655
_refine_diff_density_min         -0.489
_refine_diff_density_rms         0.127
_refine_ls_extinction_coef       0.0003(3)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.122
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     242
_refine_ls_number_reflns         4852
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.122
_refine_ls_R_factor_all          0.0633
_refine_ls_R_factor_gt           0.0537
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1109P)²+6.1029P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1802
_refine_ls_wR_factor_ref         0.1906
_reflns_number_gt                4042
_reflns_number_total             4852
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            om701262m-file004.cif
_cod_data_source_block           s84o
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Orthorhombic' changed to
'orthorhombic' according to
/home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_sg_symbol_H-M      Pnna
_cod_original_formula_sum        'C32.50 H16 N1.50 O11.50 Si Zn2'
_cod_database_code               4071106
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, -y, z'
'-x+1/2, y+1/2, -z+1/2'
'x, -y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, y, -z'
'x-1/2, -y-1/2, z-1/2'
'-x, y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Zn1 Zn 0.24070(4) 0.7500 0.7500 0.02231(17) Uani 1 2 d S . .
Zn2 Zn 0.7500 0.0000 0.29852(2) 0.02202(17) Uani 1 2 d S . .
Si1 Si 0.7500 0.5000 0.53842(5) 0.0208(3) Uani 1 2 d S . .
O1 O 0.7778(2) 0.14939(18) 0.32341(9) 0.0291(5) Uani 1 1 d . . .
O2 O 0.6577(3) 0.0703(2) 0.37567(11) 0.0527(8) Uani 1 1 d . . .
O3 O 0.33891(19) 0.66292(17) 0.70685(9) 0.0304(5) Uani 1 1 d . . .
O4 O 0.3703(2) 0.50861(17) 0.74518(10) 0.0339(6) Uani 1 1 d . . .
O5 O 0.0845(3) 0.7500 0.7500 0.0380(8) Uani 1 2 d S . .
C1 C 0.7390(2) 0.3864(3) 0.49050(12) 0.0252(6) Uani 1 1 d . . .
C2 C 0.6628(3) 0.3087(3) 0.49549(13) 0.0349(7) Uani 1 1 d . . .
H2 H 0.6135 0.3101 0.5260 0.042 Uiso 1 1 calc R . .
C3 C 0.6579(3) 0.2296(3) 0.45660(14) 0.0387(8) Uani 1 1 d . . .
H3 H 0.6059 0.1769 0.4608 0.046 Uiso 1 1 calc R . .
C4 C 0.7291(3) 0.2268(3) 0.41129(13) 0.0303(7) Uani 1 1 d . . .
C5 C 0.8070(3) 0.3020(3) 0.40609(13) 0.0316(7) Uani 1 1 d . . .
H5 H 0.8566 0.3000 0.3758 0.038 Uiso 1 1 calc R . .
C6 C 0.8117(3) 0.3803(3) 0.44568(13) 0.0314(7) Uani 1 1 d . . .
H6 H 0.8658 0.4312 0.4423 0.038 Uiso 1 1 calc R . .
C7 C 0.7191(3) 0.1444(3) 0.36812(13) 0.0333(7) Uani 1 1 d . . .
C8 C 0.6324(2) 0.5188(2) 0.58606(12) 0.0230(6) Uani 1 1 d . . .
C9 C 0.5999(3) 0.4431(2) 0.62422(13) 0.0291(6) Uani 1 1 d . . .
H9 H 0.6330 0.3775 0.6230 0.035 Uiso 1 1 calc R . .
C10 C 0.5207(3) 0.4617(2) 0.66366(13) 0.0280(6) Uani 1 1 d . . .
H10 H 0.4999 0.4089 0.6891 0.034 Uiso 1 1 calc R . .
C11 C 0.4713(2) 0.5571(2) 0.66618(12) 0.0239(6) Uani 1 1 d . . .
C12 C 0.5015(3) 0.6327(3) 0.62850(16) 0.0395(9) Uani 1 1 d . . .
H12 H 0.4677 0.6980 0.6297 0.047 Uiso 1 1 calc R . .
C13 C 0.5808(3) 0.6137(3) 0.58886(15) 0.0381(8) Uani 1 1 d . . .
H13 H 0.6003 0.6663 0.5631 0.046 Uiso 1 1 calc R . .
C14 C 0.3862(2) 0.5779(2) 0.70955(12) 0.0243(6) Uani 1 1 d . . .
O6 O 0.9487(4) 0.6845(4) 0.8272(2) 0.0345(10) Uiso 0.50 1 d P A 1
N1 N 0.8907(16) 0.5368(17) 0.8774(8) 0.139(6) Uiso 0.50 1 d P A 1
C15 C 0.9533(14) 0.6058(13) 0.8343(7) 0.097(4) Uiso 0.50 1 d P A 1
C16 C 0.808(2) 0.596(2) 0.9032(10) 0.157(8) Uiso 0.50 1 d P A 1
C17 C 0.888(3) 0.423(3) 0.8912(13) 0.207(13) Uiso 0.50 1 d P A 1
O7 O 0.8057(19) 0.5464(18) 0.7773(10) 0.104(6) Uiso 0.25 1 d P . 2
N2 N 0.8288(16) 0.3775(14) 0.7711(8) 0.066(5) Uiso 0.25 1 d P . 2
C18 C 0.785(3) 0.455(3) 0.7569(15) 0.105(10) Uiso 0.25 1 d P . 2
C19 C 0.906(3) 0.383(3) 0.8008(17) 0.123(12) Uiso 0.25 1 d P . 2
C20 C 0.790(4) 0.281(5) 0.744(4) 0.18(2) Uiso 0.25 1 d P . 2
O8 O 0.004(2) 0.5599(17) 0.9322(12) 0.128(10) Uani 0.25 1 d P . .
O9 O 0.072(3) 0.5407(19) 0.9909(13) 0.161(13) Uani 0.25 1 d P . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O5 Zn1 O3 128.73(7) . 4_566
O5 Zn1 O3 128.73(7) . .
O3 Zn1 O3 102.53(15) 4_566 .
O5 Zn1 O1 83.97(7) . 5_666
O3 Zn1 O1 97.81(9) 4_566 5_666
O3 Zn1 O1 89.76(9) . 5_666
O5 Zn1 O1 83.97(7) . 8_666
O3 Zn1 O1 89.76(9) 4_566 8_666
O3 Zn1 O1 97.81(9) . 8_666
O1 Zn1 O1 167.93(13) 5_666 8_666
O4 Zn2 O4 99.86(17) 8_655 7_665
O4 Zn2 O1 105.01(9) 8_655 .
O4 Zn2 O1 96.32(9) 7_665 .
O4 Zn2 O1 96.32(9) 8_655 2_655
O4 Zn2 O1 105.01(9) 7_665 2_655
O1 Zn2 O1 146.69(12) . 2_655
O4 Zn2 O2 153.91(10) 8_655 2_655
O4 Zn2 O2 96.07(12) 7_665 2_655
O1 Zn2 O2 93.54(10) . 2_655
O1 Zn2 O2 59.42(10) 2_655 2_655
O4 Zn2 O2 96.07(12) 8_655 .
O4 Zn2 O2 153.91(10) 7_665 .
O1 Zn2 O2 59.42(10) . .
O1 Zn2 O2 93.54(10) 2_655 .
O2 Zn2 O2 77.54(17) 2_655 .
O4 Zn2 C7 105.16(11) 8_655 .
O4 Zn2 C7 125.37(11) 7_665 .
O1 Zn2 C7 30.52(11) . .
O1 Zn2 C7 119.17(11) 2_655 .
O2 Zn2 C7 81.67(12) 2_655 .
O2 Zn2 C7 29.21(11) . .
O4 Zn2 C7 125.37(11) 8_655 2_655
O4 Zn2 C7 105.16(11) 7_665 2_655
O1 Zn2 C7 119.17(11) . 2_655
O1 Zn2 C7 30.52(11) 2_655 2_655
O2 Zn2 C7 29.21(11) 2_655 2_655
O2 Zn2 C7 81.67(12) . 2_655
C7 Zn2 C7 98.52(16) . 2_655
C8 Si1 C8 105.54(19) 2_665 .
C8 Si1 C1 108.77(13) 2_665 .
C8 Si1 C1 114.48(13) . .
C8 Si1 C1 114.48(13) 2_665 2_665
C8 Si1 C1 108.77(13) . 2_665
C1 Si1 C1 105.1(2) . 2_665
C7 O1 Zn2 95.3(2) . .
C7 O1 Zn1 128.6(2) . 5_666
Zn2 O1 Zn1 108.54(9) . 5_666
C7 O2 Zn2 83.6(2) . .
C14 O3 Zn1 141.0(2) . .
C14 O4 Zn2 126.7(2) . 7_566
C2 C1 C6 117.7(3) . .
C2 C1 Si1 124.9(2) . .
C6 C1 Si1 117.4(2) . .
C3 C2 C1 120.9(3) . .
C3 C2 H2 119.6 . .
C1 C2 H2 119.6 . .
C2 C3 C4 120.3(3) . .
C2 C3 H3 119.8 . .
C4 C3 H3 119.8 . .
C5 C4 C3 119.9(3) . .
C5 C4 C7 120.5(3) . .
C3 C4 C7 119.7(3) . .
C4 C5 C6 119.2(3) . .
C4 C5 H5 120.4 . .
C6 C5 H5 120.4 . .
C5 C6 C1 121.9(3) . .
C5 C6 H6 119.0 . .
C1 C6 H6 119.0 . .
O2 C7 O1 120.5(3) . .
O2 C7 C4 120.8(3) . .
O1 C7 C4 118.8(3) . .
O2 C7 Zn2 67.22(19) . .
O1 C7 Zn2 54.18(15) . .
C4 C7 Zn2 166.2(3) . .
C13 C8 C9 117.4(3) . .
C13 C8 Si1 120.5(2) . .
C9 C8 Si1 121.8(2) . .
C10 C9 C8 121.5(3) . .
C10 C9 H9 119.2 . .
C8 C9 H9 119.2 . .
C9 C10 C11 120.1(3) . .
C9 C10 H10 119.9 . .
C11 C10 H10 119.9 . .
C12 C11 C10 119.3(3) . .
C12 C11 C14 120.5(3) . .
C10 C11 C14 120.3(3) . .
C11 C12 C13 120.4(3) . .
C11 C12 H12 119.8 . .
C13 C12 H12 119.8 . .
C12 C13 C8 121.3(3) . .
C12 C13 H13 119.3 . .
C8 C13 H13 119.3 . .
O4 C14 O3 126.5(3) . .
O4 C14 C11 116.4(3) . .
O3 C14 C11 117.1(3) . .
C16 N1 C17 115(2) . .
C16 N1 C15 109.2(19) . .
C17 N1 C15 135(2) . .
O6 C15 N1 129.9(17) . .
C18 O7 C18 70(3) 2_665 .
C18 N2 C19 119(3) . .
C18 N2 C20 116(3) . .
C19 N2 C20 124(3) . .
N2 C18 O7 108(3) . 2_665
N2 C18 O7 125(4) . .
O7 C18 O7 93(3) 2_665 .
N2 C18 C18 162(3) . 2_665
O7 C18 C18 58(3) 2_665 2_665
O7 C18 C18 52(3) . 2_665
C20 C20 N2 132(10) 4_556 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Zn1 O5 1.951(4) .
Zn1 O3 1.960(2) 4_566
Zn1 O3 1.960(2) .
Zn1 O1 2.194(2) 5_666
Zn1 O1 2.194(2) 8_666
Zn2 O4 1.968(2) 8_655
Zn2 O4 1.968(2) 7_665
Zn2 O1 2.063(2) .
Zn2 O1 2.063(2) 2_655
Zn2 O2 2.351(3) 2_655
Zn2 O2 2.351(3) .
Zn2 C7 2.533(3) .
Zn2 C7 2.533(3) 2_655
Si1 C8 1.871(3) 2_665
Si1 C8 1.871(3) .
Si1 C1 1.872(3) .
Si1 C1 1.872(3) 2_665
O1 C7 1.292(4) .
O1 Zn1 2.194(2) 5_666
O2 C7 1.244(5) .
O3 C14 1.257(4) .
O4 C14 1.253(4) .
O4 Zn2 1.968(2) 7_566
C1 C2 1.395(5) .
C1 C6 1.401(4) .
C2 C3 1.386(5) .
C2 H2 0.9500 .
C3 C4 1.397(5) .
C3 H3 0.9500 .
C4 C5 1.385(5) .
C4 C7 1.491(4) .
C5 C6 1.389(4) .
C5 H5 0.9500 .
C6 H6 0.9500 .
C8 C13 1.395(4) .
C8 C9 1.399(4) .
C9 C10 1.384(4) .
C9 H9 0.9500 .
C10 C11 1.389(4) .
C10 H10 0.9500 .
C11 C12 1.383(4) .
C11 C14 1.505(4) .
C12 C13 1.389(5) .
C12 H12 0.9500 .
C13 H13 0.9500 .
O6 C15 1.041(16) .
N1 C16 1.42(3) .
N1 C17 1.52(4) .
N1 C15 1.57(2) .
O7 C18 1.23(4) 2_665
O7 C18 1.32(4) .
N2 C18 1.19(4) .
N2 C19 1.19(4) .
N2 C20 1.49(8) .
C18 O7 1.23(4) 2_665
C18 C18 1.47(8) 2_665
C20 C20 0.85(13) 4_556
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O4 Zn2 O1 C7 94.5(2) 8_655 .
O4 Zn2 O1 C7 -163.5(2) 7_665 .
O1 Zn2 O1 C7 -33.50(19) 2_655 .
O2 Zn2 O1 C7 -67.0(2) 2_655 .
O2 Zn2 O1 C7 6.3(2) . .
C7 Zn2 O1 C7 -52.2(3) 2_655 .
O4 Zn2 O1 Zn1 -39.32(14) 8_655 5_666
O4 Zn2 O1 Zn1 62.68(13) 7_665 5_666
O1 Zn2 O1 Zn1 -167.31(11) 2_655 5_666
O2 Zn2 O1 Zn1 159.19(12) 2_655 5_666
O2 Zn2 O1 Zn1 -127.53(15) . 5_666
C7 Zn2 O1 Zn1 -133.8(2) . 5_666
C7 Zn2 O1 Zn1 173.97(11) 2_655 5_666
O4 Zn2 O2 C7 -110.4(2) 8_655 .
O4 Zn2 O2 C7 17.1(4) 7_665 .
O1 Zn2 O2 C7 -6.5(2) . .
O1 Zn2 O2 C7 152.8(2) 2_655 .
O2 Zn2 O2 C7 95.2(2) 2_655 .
C7 Zn2 O2 C7 124.7(2) 2_655 .
O5 Zn1 O3 C14 -88.1(3) . .
O3 Zn1 O3 C14 91.9(3) 4_566 .
O1 Zn1 O3 C14 -170.2(3) 5_666 .
O1 Zn1 O3 C14 0.4(4) 8_666 .
C8 Si1 C1 C2 105.3(3) 2_665 .
C8 Si1 C1 C2 -12.4(3) . .
C1 Si1 C1 C2 -131.6(3) 2_665 .
C8 Si1 C1 C6 -76.0(3) 2_665 .
C8 Si1 C1 C6 166.3(2) . .
C1 Si1 C1 C6 47.0(2) 2_665 .
C6 C1 C2 C3 -1.4(5) . .
Si1 C1 C2 C3 177.3(3) . .
C1 C2 C3 C4 -0.5(6) . .
C2 C3 C4 C5 1.9(6) . .
C2 C3 C4 C7 -176.7(3) . .
C3 C4 C5 C6 -1.2(5) . .
C7 C4 C5 C6 177.4(3) . .
C4 C5 C6 C1 -0.8(5) . .
C2 C1 C6 C5 2.1(5) . .
Si1 C1 C6 C5 -176.7(3) . .
Zn2 O2 C7 O1 10.5(3) . .
Zn2 O2 C7 C4 -167.4(3) . .
Zn2 O1 C7 O2 -11.9(4) . .
Zn1 O1 C7 O2 107.0(4) 5_666 .
Zn2 O1 C7 C4 165.9(3) . .
Zn1 O1 C7 C4 -75.2(4) 5_666 .
Zn1 O1 C7 Zn2 118.9(2) 5_666 .
C5 C4 C7 O2 171.8(4) . .
C3 C4 C7 O2 -9.6(6) . .
C5 C4 C7 O1 -6.0(5) . .
C3 C4 C7 O1 172.5(3) . .
C5 C4 C7 Zn2 49.6(12) . .
C3 C4 C7 Zn2 -131.9(10) . .
O4 Zn2 C7 O2 74.9(2) 8_655 .
O4 Zn2 C7 O2 -170.9(2) 7_665 .
O1 Zn2 C7 O2 168.9(4) . .
O1 Zn2 C7 O2 -31.4(3) 2_655 .
O2 Zn2 C7 O2 -79.3(3) 2_655 .
C7 Zn2 C7 O2 -55.4(2) 2_655 .
O4 Zn2 C7 O1 -93.9(2) 8_655 .
O4 Zn2 C7 O1 20.2(3) 7_665 .
O1 Zn2 C7 O1 159.69(14) 2_655 .
O2 Zn2 C7 O1 111.8(2) 2_655 .
O2 Zn2 C7 O1 -168.9(4) . .
C7 Zn2 C7 O1 135.7(2) 2_655 .
O4 Zn2 C7 C4 -157.1(11) 8_655 .
O4 Zn2 C7 C4 -42.9(11) 7_665 .
O1 Zn2 C7 C4 -63.2(11) . .
O1 Zn2 C7 C4 96.5(11) 2_655 .
O2 Zn2 C7 C4 48.6(11) 2_655 .
O2 Zn2 C7 C4 128.0(12) . .
C7 Zn2 C7 C4 72.6(11) 2_655 .
C8 Si1 C8 C13 112.2(3) 2_665 .
C1 Si1 C8 C13 -128.2(3) . .
C1 Si1 C8 C13 -11.1(3) 2_665 .
C8 Si1 C8 C9 -60.9(2) 2_665 .
C1 Si1 C8 C9 58.6(3) . .
C1 Si1 C8 C9 175.8(3) 2_665 .
C13 C8 C9 C10 -0.7(5) . .
Si1 C8 C9 C10 172.6(3) . .
C8 C9 C10 C11 -0.1(5) . .
C9 C10 C11 C12 0.7(5) . .
C9 C10 C11 C14 -179.1(3) . .
C10 C11 C12 C13 -0.5(6) . .
C14 C11 C12 C13 179.3(3) . .
C11 C12 C13 C8 -0.3(6) . .
C9 C8 C13 C12 0.9(6) . .
Si1 C8 C13 C12 -172.5(3) . .
Zn2 O4 C14 O3 12.2(5) 7_566 .
Zn2 O4 C14 C11 -168.4(2) 7_566 .
Zn1 O3 C14 O4 10.2(6) . .
Zn1 O3 C14 C11 -169.2(2) . .
C12 C11 C14 O4 -173.9(3) . .
C10 C11 C14 O4 5.9(4) . .
C12 C11 C14 O3 5.5(5) . .
C10 C11 C14 O3 -174.6(3) . .
C16 N1 C15 O6 9(3) . .
C17 N1 C15 O6 178(2) . .
C19 N2 C18 O7 -116(4) . 2_665
C20 N2 C18 O7 71(4) . 2_665
C19 N2 C18 O7 -9(6) . .
C20 N2 C18 O7 177(4) . .
C19 N2 C18 C18 -83(16) . 2_665
C20 N2 C18 C18 104(15) . 2_665
C18 O7 C18 N2 -158(4) 2_665 .
C18 O7 C18 O7 -44(4) 2_665 2_665
C18 N2 C20 C20 -153(8) . 4_556
C19 N2 C20 C20 34(11) . 4_556
