#------------------------------------------------------------------------------
#$Date: 2016-03-21 08:20:38 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178603 $
#$URL: svn://www.crystallography.net/cod/cif/4/07/14/4071429.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4071429
loop_
_publ_author_name
'Zang, Shuang-Quan'
'Zhao, Liang'
'Mak, Thomas C. W.'
_publ_section_title
;
 Diverse Intermolecular Interactions in Metal−Organic Frameworks
 Constructed with the New Supramolecular Synthon
 Agn−L−Agn(n= 4, 5) (H2L =
 2,2′-Bis(prop-2-ynyloxy)biphenyl)
;
_journal_issue                   11
_journal_name_full               Organometallics
_journal_page_first              2396
_journal_paper_doi               10.1021/om800165x
_journal_volume                  27
_journal_year                    2008
_chemical_formula_moiety         'C17 H10 Ag5 F12 O11'
_chemical_formula_sum            'C17 H10 Ag5 F12 O11'
_chemical_formula_weight         1157.60
_chemical_name_common            '[Ag(L)0.5(AgCF3COO)4(H2O)2]'
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           13
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yc'
_symmetry_space_group_name_H-M   'P 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 120.287(4)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   11.6074(15)
_cell_length_b                   12.2988(15)
_cell_length_c                   22.4969(19)
_cell_measurement_temperature    293(2)
_cell_volume                     2773.2(6)
_computing_cell_refinement       SMART
_computing_data_collection       'SMART (Bruker, 2000)'
_computing_data_reduction        'SAINT (Bruker, 2000)'
_computing_molecular_graphics    SHELXTL
_computing_publication_material  SHELXTL
_computing_structure_refinement  SHELXTL
_computing_structure_solution    'SHELXTL (Bruker, 2000)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0361
_diffrn_reflns_av_sigmaI/netI    0.0363
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_number            15387
_diffrn_reflns_theta_full        25.50
_diffrn_reflns_theta_max         25.50
_diffrn_reflns_theta_min         1.96
_exptl_absorpt_coefficient_mu    3.603
_exptl_absorpt_correction_T_max  0.695
_exptl_absorpt_correction_T_min  0.431
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS(Bruker, 2000)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    2.773
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_F_000             2172
_exptl_crystal_size_max          0.3
_exptl_crystal_size_mid          0.2
_exptl_crystal_size_min          0.1
_refine_diff_density_max         1.616
_refine_diff_density_min         -1.686
_refine_diff_density_rms         0.164
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.057
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     406
_refine_ls_number_reflns         5155
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.057
_refine_ls_R_factor_all          0.0481
_refine_ls_R_factor_gt           0.0408
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0545P)²+8.1570P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1033
_refine_ls_wR_factor_ref         0.1072
_reflns_number_gt                4467
_reflns_number_total             5155
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            om800165x-file003.cif
_cod_data_source_block           complex_2
_cod_original_sg_symbol_H-M      'P 2/c'
_cod_database_code               4071429
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag 0.62333(5) 0.29287(4) 0.35944(3) 0.04741(15) Uani 1 1 d .
Ag2 Ag 0.42003(4) 0.44512(4) 0.28230(2) 0.04129(14) Uani 1 1 d .
Ag3 Ag 0.59654(5) 0.48705(5) 0.42718(3) 0.05624(17) Uani 1 1 d .
Ag4 Ag 0.86569(4) 0.40394(4) 0.44631(3) 0.04663(15) Uani 1 1 d .
Ag5 Ag 0.57854(6) 0.01348(4) 0.39905(3) 0.05782(17) Uani 1 1 d .
C1 C 0.6562(5) 0.4649(4) 0.3475(3) 0.0303(11) Uani 1 1 d .
C2 C 0.7392(5) 0.5283(4) 0.3490(3) 0.0307(11) Uani 1 1 d .
C3 C 0.8162(5) 0.6191(4) 0.3429(3) 0.0330(11) Uani 1 1 d .
H3A H 0.8838 0.6430 0.3884 0.040 Uiso 1 1 calc R
H3B H 0.8608 0.5945 0.3187 0.040 Uiso 1 1 calc R
O1 O 0.7297(4) 0.7079(3) 0.3064(2) 0.0365(9) Uani 1 1 d .
C4 C 0.6586(5) 0.7522(4) 0.3343(3) 0.0313(11) Uani 1 1 d .
C5 C 0.7130(6) 0.7634(5) 0.4049(3) 0.0425(14) Uani 1 1 d .
H5 H 0.8011 0.7434 0.4348 0.051 Uiso 1 1 calc R
C6 C 0.6361(7) 0.8045(5) 0.4307(3) 0.0430(14) Uani 1 1 d .
H6 H 0.6730 0.8129 0.4780 0.052 Uiso 1 1 calc R
C7 C 0.5041(7) 0.8331(4) 0.3864(3) 0.0397(13) Uani 1 1 d .
H7 H 0.4521 0.8602 0.4038 0.048 Uiso 1 1 d R
C8 C 0.4520(6) 0.8255(4) 0.3153(3) 0.0360(12) Uani 1 1 d .
H8 H 0.3647 0.8475 0.2856 0.043 Uiso 1 1 calc R
C9 C 0.5279(6) 0.7858(4) 0.2882(3) 0.0315(11) Uani 1 1 d .
O2 O 0.4673(5) 0.1563(4) 0.3163(3) 0.0585(13) Uani 1 1 d .
O3 O 0.3158(5) 0.2699(4) 0.2416(3) 0.0568(12) Uani 1 1 d .
C10 C 0.3555(7) 0.1825(5) 0.2690(4) 0.0529(17) Uani 1 1 d .
C11 C 0.2510(10) 0.0873(7) 0.2384(7) 0.109(5) Uani 1 1 d .
F1 F 0.2962(10) 0.0152(5) 0.2064(3) 0.141(3) Uani 1 1 d .
F2 F 0.2509(6) 0.0289(5) 0.2862(5) 0.120(3) Uani 1 1 d .
F3 F 0.1387(8) 0.1182(6) 0.1945(7) 0.276(9) Uani 1 1 d .
O4 O 0.7355(5) 0.1560(3) 0.4403(2) 0.0532(12) Uani 1 1 d .
O5 O 0.9207(4) 0.2492(4) 0.5079(2) 0.0488(11) Uani 1 1 d .
C12 C 0.8469(7) 0.1706(5) 0.4933(3) 0.0433(14) Uani 1 1 d .
C13 C 0.8967(9) 0.0790(7) 0.5474(4) 0.069(2) Uani 1 1 d .
F4 F 0.8096(9) 0.0605(6) 0.5675(4) 0.136(3) Uani 1 1 d .
F5 F 0.8943(8) -0.0163(4) 0.5188(4) 0.120(2) Uani 1 1 d .
F6 F 1.0072(9) 0.0942(7) 0.5980(4) 0.205(6) Uani 1 1 d .
O6 O 0.7286(4) 0.5643(4) 0.5342(2) 0.0463(10) Uani 1 1 d .
O7 O 0.9208(4) 0.5465(4) 0.5348(2) 0.0464(10) Uani 1 1 d .
C14 C 0.8475(6) 0.5823(5) 0.5558(3) 0.0383(13) Uani 1 1 d .
C15 C 0.9142(7) 0.6623(6) 0.6162(4) 0.0558(18) Uani 1 1 d .
F7 F 1.0295(6) 0.6290(6) 0.6659(3) 0.115(2) Uani 1 1 d .
F8 F 0.9365(10) 0.7535(5) 0.5959(4) 0.149(4) Uani 1 1 d .
F9 F 0.8438(7) 0.6812(8) 0.6450(4) 0.144(3) Uani 1 1 d .
O8 O 0.2767(5) 0.5351(4) 0.3044(3) 0.0535(12) Uani 1 1 d .
O9 O 0.4179(4) 0.5927(4) 0.4111(2) 0.0484(11) Uani 1 1 d .
C16 C 0.3095(6) 0.5881(5) 0.3572(3) 0.0384(13) Uani 1 1 d .
C17 C 0.1984(7) 0.6604(6) 0.3546(4) 0.0563(18) Uani 1 1 d .
F10 F 0.0893(5) 0.6040(5) 0.3364(4) 0.1005(19) Uani 1 1 d .
F11 F 0.1668(6) 0.7381(4) 0.3103(3) 0.100(2) Uani 1 1 d .
F12 F 0.2331(7) 0.7026(6) 0.4151(3) 0.123(3) Uani 1 1 d .
O10 O 0.4865(5) 0.3325(4) 0.4572(2) 0.0525(11) Uani 1 1 d .
H10A H 0.5235 0.3261 0.4992 0.063 Uiso 1 1 d R
H10B H 0.4043 0.3465 0.4409 0.063 Uiso 1 1 d R
O11 O 0.4626(9) 0.1005(5) 0.4536(4) 0.110(3) Uani 1 1 d .
H11A H 0.4394 0.1622 0.4383 0.132 Uiso 1 1 d R
H11B H 0.3946 0.0628 0.4451 0.132 Uiso 1 1 d R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C1 Ag1 O2 143.52(18) . .
C1 Ag1 O4 136.79(18) . .
O2 Ag1 O4 79.21(16) . .
C1 Ag1 Ag2 55.02(14) . .
O2 Ag1 Ag2 89.36(12) . .
O4 Ag1 Ag2 157.37(14) . .
C1 Ag1 Ag4 56.35(14) . .
O2 Ag1 Ag4 160.04(12) . .
O4 Ag1 Ag4 80.85(11) . .
Ag2 Ag1 Ag4 109.59(2) . .
C1 Ag1 Ag3 49.27(14) . .
O2 Ag1 Ag3 123.19(15) . .
O4 Ag1 Ag3 110.25(13) . .
Ag2 Ag1 Ag3 60.269(18) . .
Ag4 Ag1 Ag3 65.053(19) . .
O8 Ag2 C1 124.23(18) . .
O8 Ag2 O3 103.71(19) . .
C1 Ag2 O3 121.75(17) . .
O8 Ag2 C1 109.35(17) . 2_655
C1 Ag2 C1 108.44(15) . 2_655
O3 Ag2 C1 80.59(17) . 2_655
O8 Ag2 Ag1 132.21(13) . .
C1 Ag2 Ag1 48.92(13) . .
O3 Ag2 Ag1 75.20(11) . .
C1 Ag2 Ag1 117.28(11) 2_655 .
O8 Ag2 Ag2 148.01(13) . 2_655
C1 Ag2 Ag2 58.38(13) . 2_655
O3 Ag2 Ag2 97.84(14) . 2_655
C1 Ag2 Ag2 51.22(12) 2_655 2_655
Ag1 Ag2 Ag2 76.00(2) . 2_655
O8 Ag2 Ag3 81.12(12) . .
C1 Ag2 Ag3 49.13(13) . .
O3 Ag2 Ag3 121.43(12) . .
C1 Ag2 Ag3 153.62(12) 2_655 .
Ag1 Ag2 Ag3 61.789(19) . .
Ag2 Ag2 Ag3 107.37(3) 2_655 .
C1 Ag3 O6 125.01(17) . .
C1 Ag3 O9 123.86(18) . .
O6 Ag3 O9 90.19(16) . .
C1 Ag3 O10 121.12(17) . .
O6 Ag3 O10 100.82(16) . .
O9 Ag3 O10 86.06(16) . .
C1 Ag3 Ag2 53.51(14) . .
O6 Ag3 Ag2 165.95(13) . .
O9 Ag3 Ag2 81.63(11) . .
O10 Ag3 Ag2 90.04(11) . .
C1 Ag3 Ag1 47.83(13) . .
O6 Ag3 Ag1 133.52(12) . .
O9 Ag3 Ag1 134.19(11) . .
O10 Ag3 Ag1 74.37(11) . .
Ag2 Ag3 Ag1 57.943(17) . .
C1 Ag3 Ag4 51.33(14) . .
O6 Ag3 Ag4 84.16(11) . .
O9 Ag3 Ag4 164.98(12) . .
O10 Ag3 Ag4 108.65(11) . .
Ag2 Ag3 Ag4 100.90(2) . .
Ag1 Ag3 Ag4 55.997(16) . .
O5 Ag4 O7 99.23(17) . 3_766
O5 Ag4 C1 131.58(17) . .
O7 Ag4 C1 123.70(17) 3_766 .
O5 Ag4 C2 158.66(17) . .
O7 Ag4 C2 95.78(18) 3_766 .
C1 Ag4 C2 28.98(18) . .
O5 Ag4 O7 103.05(16) . .
O7 Ag4 O7 81.46(15) 3_766 .
C1 Ag4 O7 104.38(17) . .
C2 Ag4 O7 94.09(17) . .
O5 Ag4 Ag1 83.78(11) . .
O7 Ag4 Ag1 146.09(11) 3_766 .
C1 Ag4 Ag1 48.31(12) . .
C2 Ag4 Ag1 75.33(13) . .
O7 Ag4 Ag1 131.09(10) . .
O5 Ag4 Ag3 108.51(12) . .
O7 Ag4 Ag3 145.84(12) 3_766 .
C1 Ag4 Ag3 45.73(13) . .
C2 Ag4 Ag3 64.18(13) . .
O7 Ag4 Ag3 73.31(10) . .
Ag1 Ag4 Ag3 58.950(19) . .
C7 Ag5 O4 156.4(2) 1_545 .
C7 Ag5 O2 125.12(19) 1_545 .
O4 Ag5 O2 76.60(15) . .
C7 Ag5 O11 102.1(2) 1_545 .
O4 Ag5 O11 89.4(2) . .
O2 Ag5 O11 81.6(2) . .
C7 Ag5 C6 31.4(2) 1_545 1_545
O4 Ag5 C6 124.99(18) . 1_545
O2 Ag5 C6 151.22(18) . 1_545
O11 Ag5 C6 114.2(2) . 1_545
C2 C1 Ag1 142.5(5) . .
C2 C1 Ag3 117.2(4) . .
Ag1 C1 Ag3 82.89(18) . .
C2 C1 Ag2 136.6(4) . .
Ag1 C1 Ag2 76.06(16) . .
Ag3 C1 Ag2 77.36(17) . .
C2 C1 Ag4 76.3(4) . .
Ag1 C1 Ag4 75.34(16) . .
Ag3 C1 Ag4 82.94(17) . .
Ag2 C1 Ag4 146.9(2) . .
C2 C1 Ag2 84.7(4) . 2_655
Ag1 C1 Ag2 93.74(18) . 2_655
Ag3 C1 Ag2 147.4(2) . 2_655
Ag2 C1 Ag2 70.39(14) . 2_655
Ag4 C1 Ag2 127.7(2) . 2_655
C1 C2 C3 168.6(6) . .
C1 C2 Ag4 74.7(4) . .
C3 C2 Ag4 115.8(4) . .
O1 C3 C2 110.4(4) . .
O1 C3 H3A 109.6 . .
C2 C3 H3A 109.6 . .
O1 C3 H3B 109.6 . .
C2 C3 H3B 109.6 . .
H3A C3 H3B 108.1 . .
C4 O1 C3 116.7(4) . .
O1 C4 C5 122.0(5) . .
O1 C4 C9 117.1(5) . .
C5 C4 C9 120.9(5) . .
C6 C5 C4 120.0(6) . .
C6 C5 H5 120.0 . .
C4 C5 H5 120.0 . .
C5 C6 C7 120.2(6) . .
C5 C6 Ag5 111.6(4) . 1_565
C7 C6 Ag5 61.7(3) . 1_565
C5 C6 H6 119.9 . .
C7 C6 H6 119.9 . .
Ag5 C6 H6 96.2 1_565 .
C6 C7 C8 119.3(5) . .
C6 C7 Ag5 87.0(4) . 1_565
C8 C7 Ag5 97.0(4) . 1_565
C6 C7 H7 120.3 . .
C8 C7 H7 120.4 . .
Ag5 C7 H7 83.5 1_565 .
C9 C8 C7 121.4(6) . .
C9 C8 H8 119.3 . .
C7 C8 H8 119.3 . .
C8 C9 C4 118.0(5) . .
C8 C9 C9 120.0(6) . 2_655
C4 C9 C9 121.8(6) . 2_655
C10 O2 Ag1 115.8(4) . .
C10 O2 Ag5 141.0(4) . .
Ag1 O2 Ag5 101.89(17) . .
C10 O3 Ag2 127.7(4) . .
O3 C10 O2 129.4(6) . .
O3 C10 C11 115.3(6) . .
O2 C10 C11 115.2(6) . .
F3 C11 F2 113.2(13) . .
F3 C11 F1 107.6(13) . .
F2 C11 F1 103.5(7) . .
F3 C11 C10 113.1(7) . .
F2 C11 C10 111.9(9) . .
F1 C11 C10 106.8(10) . .
C12 O4 Ag1 122.7(4) . .
C12 O4 Ag5 134.7(4) . .
Ag1 O4 Ag5 102.30(17) . .
C12 O5 Ag4 124.2(4) . .
O5 C12 O4 128.1(6) . .
O5 C12 C13 115.7(6) . .
O4 C12 C13 116.2(6) . .
F6 C13 F4 109.4(10) . .
F6 C13 F5 109.9(9) . .
F4 C13 F5 100.4(8) . .
F6 C13 C12 114.9(7) . .
F4 C13 C12 110.5(7) . .
F5 C13 C12 110.8(7) . .
C14 O6 Ag3 120.6(4) . .
C14 O7 Ag4 133.9(4) . 3_766
C14 O7 Ag4 127.3(4) . .
Ag4 O7 Ag4 98.54(15) 3_766 .
O6 C14 O7 129.2(6) . .
O6 C14 C15 115.5(6) . .
O7 C14 C15 115.3(5) . .
F8 C15 F9 108.2(8) . .
F8 C15 F7 106.0(8) . .
F9 C15 F7 105.1(7) . .
F8 C15 C14 110.3(6) . .
F9 C15 C14 113.3(6) . .
F7 C15 C14 113.6(6) . .
C16 O8 Ag2 124.6(4) . .
C16 O9 Ag3 121.1(4) . .
O9 C16 O8 129.7(6) . .
O9 C16 C17 115.4(6) . .
O8 C16 C17 114.9(6) . .
F11 C17 F10 107.2(7) . .
F11 C17 F12 109.0(7) . .
F10 C17 F12 105.9(7) . .
F11 C17 C16 111.3(6) . .
F10 C17 C16 111.3(6) . .
F12 C17 C16 112.0(6) . .
Ag3 O10 H10A 109.5 . .
Ag3 O10 H10B 109.7 . .
H10A O10 H10B 109.8 . .
Ag5 O11 H11A 109.7 . .
Ag5 O11 H11B 109.2 . .
H11A O11 H11B 109.8 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 C1 2.191(5) .
Ag1 O2 2.296(4) .
Ag1 O4 2.335(4) .
Ag1 Ag2 2.8206(7) .
Ag1 Ag4 2.8379(7) .
Ag1 Ag3 2.9327(8) .
Ag2 O8 2.253(4) .
Ag2 C1 2.381(5) .
Ag2 O3 2.414(5) .
Ag2 C1 2.601(5) 2_655
Ag2 Ag2 2.8775(10) 2_655
Ag2 Ag3 2.8900(7) .
Ag3 C1 2.240(5) .
Ag3 O6 2.307(4) .
Ag3 O9 2.316(4) .
Ag3 O10 2.564(5) .
Ag3 Ag4 3.1039(8) .
Ag4 O5 2.249(4) .
Ag4 O7 2.373(4) 3_766
Ag4 C1 2.442(5) .
Ag4 C2 2.459(5) .
Ag4 O7 2.482(4) .
Ag5 C7 2.345(5) 1_545
Ag5 O4 2.355(4) .
Ag5 O2 2.407(5) .
Ag5 O11 2.477(7) .
Ag5 C6 2.661(6) 1_545
C1 C2 1.226(8) .
C1 Ag2 2.601(5) 2_655
C2 C3 1.479(8) .
C3 O1 1.429(6) .
C3 H3A 0.9700 .
C3 H3B 0.9700 .
O1 C4 1.376(7) .
C4 C5 1.389(8) .
C4 C9 1.400(8) .
C5 C6 1.384(9) .
C5 H5 0.9300 .
C6 C7 1.387(9) .
C6 Ag5 2.661(6) 1_565
C6 H6 0.9300 .
C7 C8 1.399(8) .
C7 Ag5 2.345(5) 1_565
C7 H7 0.9298 .
C8 C9 1.388(8) .
C8 H8 0.9300 .
C9 C9 1.502(11) 2_655
O2 C10 1.236(8) .
O3 C10 1.209(8) .
C10 C11 1.572(11) .
C11 F3 1.233(10) .
C11 F2 1.294(14) .
C11 F1 1.400(17) .
O4 C12 1.253(8) .
O5 C12 1.221(8) .
C12 C13 1.541(9) .
C13 F6 1.226(10) .
C13 F4 1.319(12) .
C13 F5 1.330(11) .
O6 C14 1.230(7) .
O7 C14 1.243(7) .
O7 Ag4 2.373(4) 3_766
C14 C15 1.533(9) .
C15 F8 1.286(10) .
C15 F9 1.296(9) .
C15 F7 1.304(9) .
O8 C16 1.234(8) .
O9 C16 1.232(8) .
C16 C17 1.544(9) .
C17 F11 1.293(8) .
C17 F10 1.315(9) .
C17 F12 1.316(9) .
O10 H10A 0.8210 .
O10 H10B 0.8495 .
O11 H11A 0.8206 .
O11 H11B 0.8499 .
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
O10 H10B O6 0.85 2.18 2.893(6) 140.9 3_666
O10 H10A O9 0.82 2.04 2.746(7) 144.3 3_666
O11 H11A O10 0.82 2.15 2.864(8) 145.1 .
